Using the ultra-low permeability reservoirs in the L block of the Jiangsu oilfield as an example,a series of experiments,including slim tube displacement experiments of CO_(2)-oil system,injection capacity experiments...Using the ultra-low permeability reservoirs in the L block of the Jiangsu oilfield as an example,a series of experiments,including slim tube displacement experiments of CO_(2)-oil system,injection capacity experiments,and high-temperature,high-pressure online nuclear magnetic resonance(NMR)displacement experiments,are conducted to reveal the oil/gas mass transfer pattern and oil production mechanisms during CO_(2) flooding in ultra-low permeability reservoirs.The impacts of CO_(2) storage pore range and miscibility on oil production and CO_(2) storage characteristics during CO_(2) flooding are clarified.The CO_(2) flooding process is divided into three stages:oil displacement stage by CO_(2),CO_(2) breakthrough stage,CO_(2) extraction stage.Crude oil expansion and viscosity reduction are the main mechanisms for improving recovery in the CO_(2) displacement stage.After CO_(2) breakthrough,the extraction of light components from the crude oil further enhances oil recovery.During CO_(2) flooding,the contribution of crude oil in large pores to the enhanced recovery exceeds 46%,while crude oil in medium pores serves as a reserve for incremental recovery.After CO_(2) breakthrough,a small portion of the crude oil is extracted and carried into nano-scale pores by CO_(2),becoming residual oil that is hard to recover.As the miscibility increases,the CO_(2) front moves more stably and sweeps a larger area,leading to increased CO_(2) storage range and volume.The CO_(2) full-storage stage contributes the most to the overall CO_(2) storage volume.In the CO_(2) escape stage,the storage mechanism involves partial in-situ storage of crude oil within the initial pore range and the CO_(2) carrying crude oil into smaller pores to increase the volume of stored CO_(2).In the CO_(2) leakage stage,as crude oil is produced,a significant amount of CO_(2) leaks out,causing a sharp decline in the storage efficiency.展开更多
This study aims to characterize the physical and mechanical properties of the soils from the Kenendé,Limbita 1,and Limbita 2 sites,located in the Dubréka prefecture,to develop a composite construction materi...This study aims to characterize the physical and mechanical properties of the soils from the Kenendé,Limbita 1,and Limbita 2 sites,located in the Dubréka prefecture,to develop a composite construction material based on soil and plant fibers that is more resistant to climatic and environmental conditions.To achieve this,soil samples were collected and subjected to various laboratory tests.The study assessed the physical and mechanical properties of these soils to develop a composite construction material incorporating soil and plant fibers.Laboratory tests revealed variations in water absorption capacity and compressive strength depending on the applied pressure(3,4,5 MPa)and the sample’s condition(dry or wet).After a 30-day maturation period,Kenendéexhibited a maximum dry-state strength of 2.66 MPa,while Limbita 1 and Limbita 2 recorded 0.95 MPa and 2.57 MPa,respectively.Soils compacted under high pressure demonstrated better performance,particularly in dry conditions.These results confirm the potential of the soils from the three sites for producing durable construction materials suitable for local climatic conditions,provided they undergo appropriate treatment and maturation,thereby contributing to sustainable construction in Guinea.展开更多
The incorporation of fluorine(F_(2)) into hydrogen-air(H_(2)/Air) mixtures presents a novel approach to enhancing the performance of rotating detonation engines(RDEs). This study systematically investigates the effect...The incorporation of fluorine(F_(2)) into hydrogen-air(H_(2)/Air) mixtures presents a novel approach to enhancing the performance of rotating detonation engines(RDEs). This study systematically investigates the effects of F_(2)concentration and inlet mass flow rate on rotating detonation wave(RDW) propagation using two-dimensional numerical simulations, providing the first comprehensive analysis of F_(2)as an oxidizing additive in regulating detonation performance, propagation stability, and heat release dynamics in RDEs. The results indicate that when F_(2)concentration is below 1%, the flow field primarily exhibits a stable single-wave propagation mode. As F_(2)concentration increases, RDW performance initially improves but then deteriorates, reaching its optimal state at 0.8% F_(2). When F_(2)concentration exceeds 1%, the coupled effects of F_(2)concentration and inlet mass flow rate induce a transition from single-wave to multi-wave propagation modes. While a higher inlet mass flow rate promotes increased wave numbers, it also intensifies wave-wave interactions. With further increases in F_(2)concentration, the enhanced heat release leads to intensified local deflagration, frequent hotspot formation, and wave collisions, ultimately degrading RDW performance and destabilizing the multi-wave flow field. Moreover, excessive HF formation is identified as a critical driver of enhanced deflagration, hotspot generation,and the disruption of multi-wave stability. These findings provide a theoretical foundation for integrating F_(2)additives into H_(2)/Air-based RDE systems.展开更多
Asteroids and comets,which have long been of interest to astronomers,are important components of the solar system.They contain rich primitive information about the early solar system,which provide a unique pathway for...Asteroids and comets,which have long been of interest to astronomers,are important components of the solar system.They contain rich primitive information about the early solar system,which provide a unique pathway for studying the formation and evolution of the solar system,and even the origin of life on planet Earth.In this review,the formation,evolution processes and the internal characteristics of the asteroids and comets in the solar system are presented.The focus of this review is on the internal characteristics especially the dielectric properties of asteroids and comets by radar observations.On this basis,the possible internal structure of these celestial bodies is discussed.Combined with the existing theories,simulations and experiments,the possible internal structure of near-Earth asteroid 2016 HO_(3) is a monolith while structure of active asteroid 311P/PANSTARRS remains unknown.In 2025,China will launch Tianwen-2 asteroid-comet exploration mission to detect 2016 HO_(3) and 311P/PANSTARRS,which will carry a penetrating radar to observe the internal characteristics of these two objects.展开更多
Since the first discovery of gold deposits on the northeastern margin of the Jiaolai Basin in Shandong Province at the end of the 20^(th) century,seven medium-sized to large/super-large gold deposits have been identif...Since the first discovery of gold deposits on the northeastern margin of the Jiaolai Basin in Shandong Province at the end of the 20^(th) century,seven medium-sized to large/super-large gold deposits have been identified in this region,with cumulative proven gold resources of 223 t.This study reviewed the metallogenic and geochemical characteristics of various gold deposits in this region,examined the sources of their ore-forming fluids and materials,as well as their gold metallogenic epochs and processes,and developed a gold metallogenic model.The gold deposits in this region are governed by both dense fractures and detachment structural systems along basin margins,primarily categorized into the altered rock type and the pyrite-bearing carbonate vein type.The latter type,a recently discovered mineralization type in the Jiaodong Peninsula,enjoys high gold grade,a large scale,and high gold mineral fineness,suggesting considerable prospecting potential.Both types of gold deposits show metallogenic epochs ranging from 116 Ma to 119 Ma.Their ore-forming fluids are identified as a CO_(2)-NaCl-H_(2)O fluid system characterized by moderate to low temperatures,moderate to low salinity,and low density,with the pyrite-bearing carbonate vein-type gold deposits manifesting slightly higher salinity.The C-H-O,S,and Pb isotopes of hydrothermal minerals reveal that the ore-forming fluids and materials are characteristic of crust-mantle mixing.Specifically,they were derived from mantle fluids in the early stages,mixed with stratum water and meteoric water in the later stages for mineralization.The gold metallogenic process is identified as follows:During the Early Cretaceous,the subduction of the Pacific Plate and the destruction of the North China Craton led to asthenospheric upwelling.The resulting fluids,after metasomatizing the enriched mantle,differentiated and evolved into C-H-O ore-bearing fluids,which were then mixed with crustal fluids.The mixed fluids migrated to the shallow crust,where they mingled with stratum water and meteoric water.Then,the fluids underwent unloading and final mineralization in detachment fault tectonic systems on basin margins.Due to differences in mixed crustal materials or the surrounding rocks involved in water-rock interactions,altered rock-and pyrite-bearing carbonate vein-type gold deposits were formed in acidic and alkaline fluid environments,respectively.展开更多
The La-Mg-Ni-based A2B7-type La0.8-xNdxMg0.2Ni3.15Co0.2Al0.15 (x=0, 0.1, 0.2, 0.3, 0.4) electrode alloys were prepared by casting and annealing. The influences of partial substitution of Nd for La on the structure a...The La-Mg-Ni-based A2B7-type La0.8-xNdxMg0.2Ni3.15Co0.2Al0.15 (x=0, 0.1, 0.2, 0.3, 0.4) electrode alloys were prepared by casting and annealing. The influences of partial substitution of Nd for La on the structure and electrochemical performance of the as-cast and annealed alloys were investigated. It was found that the experimental alloys consist of two major phases, (La, Mg)2Ni7 phase with the hexagonal Ce2Ni7-type structure and LaNi5 phase with the hexagonal CaCu5-type structure, as well as some residual phase LaNi3 and NdNi5. The discharge capacity and high rate discharge ability (HRD) of the as-cast and annealed alloys first increase and then decrease with Nd content growing. The as-cast and annealed alloys (x=0.3) yield the largest discharge capacities of 380.3 and 384.3 mA·h/g, respectively. The electrochemical cycle stability of the as-cast and annealed alloys markedly grows with Nd content rising. As the Nd content increase from 0 to 0.4. The capacity retaining rate (S100) at the 100th charging and discharging cycle increases from 64.98% to 85.17% for the as-cast alloy, and from 76.60% to 96.84% for the as-annealed alloy.展开更多
AIM:To investigate human epidermal growth factor receptor 2(HER2) gene amplification and protein expression in Chinese patients with resectable gastric cancer and the association with clinicopathological characteristi...AIM:To investigate human epidermal growth factor receptor 2(HER2) gene amplification and protein expression in Chinese patients with resectable gastric cancer and the association with clinicopathological characteristics and survival.METHODS:One hundred and ninety-seven gastric cancer patients who underwent curative surgery procedures were enrolled into this study.HER2 gene amplification and protein expression were examined using fluorescence in-situ hybridization(FISH) and immunohistochemistry(IHC) analysis on formalin-fixed paraffinembedded gastric cancer samples from all patients.For scoring,Hofmann's HER2 gastric cancer scoring system was adopted.All cases showing IHC3+ or FISH positiv-ity were defined as HER2 positive.Patient clinicopathological data and survival information were collected.Finally,χ 2 statistical analysis was performed to analyze the HER2 positivity rate amongst the subgroups with different clinicopathological characteristics including;gender,age,tumor location,Lauren classification,differentiation,TNM staging,depth of invasion,lymph node metastases and distant metastasis.The probability of survival for different subgroups with different clinicopathological characteristics was calculated using the Kaplan-Meier method and survival curves plotted using log rank inspection.RESULTS:According to Hofmann's HER2 gastric cancer scoring criteria,31 cases(15.74%) were identified as HER2 gene amplified and 19 cases(9.64%) were scored as strongly positive for HER2 membrane staining(3+),25 cases(12.69%) were moderately positive(2+) and 153 cases(77.66%) were HER2 negative(0/1+).The concordance rate between IHC and FISH analyses was 88.83%(175/197).Thirty-six cases were defined as positive for HER2 gene amplification and/or protein expression,with 24 of these cases being eligible for Herceptin treatment according to United States recommendations,and 29 of these cases eligible according to EU recommendations.Highly consistent results were detected between IHC3+,IHC0/1 and FISH(73.68% and 95.42%),but low consistency was observed between IHC2+ and FISH(40.00%).The positivity rates in intestinal type and well-differentiated gastric cancer were higher than those in diffuse/mixed type and poorly-differentiated gastric cancer respectively(28.57% vs 13.43%,P = 0.0103;37.25% vs 11.64%,P < 0.0001),but were not correlated with gender,age,tumor location or TNM stage,depth of invasion,lymph node metastases and distant metastasis.In poorly-differentiated gastric cancer patients,those without lymph node metastasis showed a higher HER2 positivity rate than those with lymph node metastasis(26.47% vs 7.14%,P = 0.0021).This association was not present in thosepatients with well-differentiated gastric cancer(28.57% vs 43.33%,P = 0.2832).Within our patient cohort,26 cases were lost to follow-up.The median survival time for the remaining 171 patients was 18 mo.The median survival times of the HER2 positive and negative groups were 17 and 18.5 mo respectively.Overall survival was not significantly different between HER2-positive and negative groups(χ 2 = 0.9157,P = 0.3386),but in patients presenting well-differentiated tumors,the overall survival of the HER2-positive group was significantly worse than that of the HER2-negative group(P = 0.0123).In contrast,patients with poorly differentiated and diffuse/mixed subtype gastric cancers showed no significant differences in overall survival associated with HER2.Furthermore,the median survival time of the HER2 positive group did not show any statistically significant differences when compared to the subgroups of gender,age,tumor location,TNM classification,lymph node metastases and distant metastasis.CONCLUSION:Patients with intestinal type gastric cancer(GC),well-differentiated GC and poorly-differentiated GC without lymph node metastasis,may all represent suitable candidates for targeted therapy using Herceptin.展开更多
AIM: TO investigate the characteristics and diagnostic value of annexin A2 (ANXA2) expression in cancerous tissues and sera of patients with hepatitis B virus (HBV)-related hepatocellular carcinoma (HCC). METH...AIM: TO investigate the characteristics and diagnostic value of annexin A2 (ANXA2) expression in cancerous tissues and sera of patients with hepatitis B virus (HBV)-related hepatocellular carcinoma (HCC). METHODS: Levels of liver ANXA2 gene transcription or protein expression were analyzed in HCC-, their self- controlled precancerous-, and distant cancerous- tissues from 30 HCC. Serum levels of ANXA2 expression in 115 patients with HCC, 25 with metastatic liver can cer, 35 with chronic hepatitis, 28 with acute hepatitis, 38 with cirrhosis, and 30 healthy controls were deter- mined. Clinicopathological characteristics of circulating ANXA2 expression were analyzed, and its diagnostic efficiency and clinical values in HCC were evaluated. RESULTS: ANXA2 expression was localized in both cell membrane and cytoplasm in HCC tissue, mainly in the cytoplasm of matched adjacent cancerous tissue, and there was almost no positive staining in matched distant cancerous tissue. Abnormal expression of liver ANXA2 was present in HCC tissues compared with self-con- trolled adjacent- and distant-cancerous tissues at pro- tein or mRNA level. Circulating ANXA2 in HCC patients was significantly higher than that of other liver diseases (P 〈 0.01) except metastatic liver cancer. If the diag- nostic cutoff value of ANXA2 level was more than 18 ng/ mL, the incidence of serum ANXA2 was 86.96% in the HCC group, 80% in the metastatic liver cancer group, 31.58% in the liver cirrhosis group, none in the chronic hepatitis or acute hepatitis or normal control group, respectively. Serum ANXA2 expression in HCC patients was correlated with HBV infection (27.38 ± 5.67 ng/mL vs 18.58 ± 7.83 ng/mL, P 〈 0.01), extrahepatic metas- tasis (26.11±5.43 ng/mL ys 22.79 ± 5.64 ng/mL, P 〈 0.01), and portal vein thrombus (26.03 ± 5.99 ng/mL vs 23.06 ± 5.03 ng/mL, P 〈 0.01), and was significantly higher (P 〈 0.01) in the moderately- (26.19±5.34 ng/ mL) or the poorly- differentiated group (27.05 ± 5.13 ng/mL) than in the well differentiated group (20.43 ± 4.97 ng/mL), and in the tumor node metastasis stages Ⅲ-Ⅳ(P 〈 0.01) than in stages Ⅰ-Ⅱ. ANXA2 was not correlated with patient sex, age, size or α-fetoprotein (AFP) level. Area under the receiver operating charac- teristic curve for the whole range of sensitivities and specificities was 0.796 for ANXA2 and 0.782 for AFP. Combining detection of serum ANXA2 and AFP substan- tially improved the diagnostic efficiency (96.52%) and the neclative predictive value ('96.61%) for HCC.of ANXA2 expression has good diagnostic potential for HCC diagnosis.展开更多
The total coal consumption in China is on the rise.The characteristics of CO2 and SO2 emissions in the whole process of coal processing and utilization in China are worthy of study.Based on the five links of the whole...The total coal consumption in China is on the rise.The characteristics of CO2 and SO2 emissions in the whole process of coal processing and utilization in China are worthy of study.Based on the five links of the whole process of coal production and utilization,including coal production,raw coal processing,logistics and transportation,conversion and utilization and resource utilization,this paper summarized and analyzed the energy consumption and pollutant emission sources of these five links,combined with the US Environmental Protection Agency’s AP-42 method and IPCC method,to calculate total pollutant discharge and emission factors,where the emission factors were corrected by conversion efficiency.At the same time,uncertainty analysis is performed about CO2 and SO2 emissions.The results showed that CO2 emissions were 3.657 billion tons,and emission reductions were 61 million tons,and SO2 emissions were 4,844,500 tons,and emission reductions were 10.3595 million tons in 2015.展开更多
This paper synthesizes the Sr2SiO4:Eu^2+ phosphor by high temperature solid-state reaction. The emission spectrum of Sr2SiO4 : Eu^2+ shows two bands centred at 480 and 547 nm, which agree well with the calculation...This paper synthesizes the Sr2SiO4:Eu^2+ phosphor by high temperature solid-state reaction. The emission spectrum of Sr2SiO4 : Eu^2+ shows two bands centred at 480 and 547 nm, which agree well with the calculation values of emission spectrum, and the location of yellow emission of Sr2SiO4 : Eu^2+ is influenced by the Eu^2+ concentration. The excitation spectrum for 547 nm emission has two bands at 363 and 402 nm. The emission spectrum of white light emitting diodes (w-LEDs) based on Sr2SiO4 : Eu^2+ phosphor + InGaN LED was investigated.展开更多
The statistical probability and their variation regularity of the measurable characteristic parameters in the CO 2 arc welding droplet short circuiting transfer process have been studied. The statistical analysis sh...The statistical probability and their variation regularity of the measurable characteristic parameters in the CO 2 arc welding droplet short circuiting transfer process have been studied. The statistical analysis shows that the sensitivity of each characteristic parameter with regard to the variation of the short circuiting transfer process is different. The sensitivity of 4 kinds among these characteristic parameters is more intense than that of the short circuiting transfer frequency. In order to take account of the synthetic influence of these characteristic parameters, by means of the characteristic parameters synthetic value, a quantitative evaluation function is built up to describe and evaluate the short circuiting transfer process of CO 2 arc welding in real time. The testing shows that the evaluation function can give a suitable synthetic valuation for the short circuiting transfer process with a variety of welding variables.展开更多
"Continuous" tight gas reservoirs are those reservoirs which develop in widespread tight sandstones with a continuous distribution of natural gas. In this paper, we summarize the geological features of the source ro..."Continuous" tight gas reservoirs are those reservoirs which develop in widespread tight sandstones with a continuous distribution of natural gas. In this paper, we summarize the geological features of the source rocks and "'continuous" tight gas reservoirs in the Xujiahe Formation of the middle- south transition region, Sichuan Basin. The source rocks of the Xul Member and reservoir rocks of the Xu2 Member are thick (Xul Member: 40 m, Xu2 Member: 120 m) and are distributed continuously in this study area. The results of drilled wells show that the widespread sandstone reservoirs of the Xu2 Member are charged with natural gas. Therefore, the natural gas reservoirs of the Xu2 Member in the middle-south transition region are "continuous" tight gas reservoirs. The accumulation of "continuous" tight gas reservoirs is controlled by an adequate driving force of the pressure differences between source rocks and reservoirs, which is demonstrated by a "one-dimensional" physical simulation experiment. In this simulation, the natural gas of"continuous" tight gas reservoirs moves tbrward with no preferential petroleum migration pathways (PPMP), and the natural gas saturation of"continuous" tight gas reservoirs is higher than that of conventional reservoirs.展开更多
Porous medium has an obvious effect on the formation of carbon dioxide hydrate. In order to study the characteristics of CO2 hydrate formation in porous medium below the freezing point, the experiment of CO2 hydrate f...Porous medium has an obvious effect on the formation of carbon dioxide hydrate. In order to study the characteristics of CO2 hydrate formation in porous medium below the freezing point, the experiment of CO2 hydrate formation was conducted in a high-pressure 1.8-L cell in the presence of porous media with a particle size of 380 μm, 500 μm and 700 μm, respectively. The test results showed that the porous medium had an important influence on the process of CO2 hydrate formation below the freezing point. Compared with porous media with a particle size of 500 μm and 700 μm, respectively, the average hydrate formation rate and gas storage capacity of carbon dioxide hydrate in the porous medium with a particle size of 380 μm attained 0.016 14 mol/h and 65.094 L/L, respectively. The results also indicated that, within a certain range of particle sizes, the smaller the particle size of porous medium was, the larger the average hydrate formation rate and the gas storage capacity of CO2 hydrate during the process of hydrate formation would be.展开更多
In order to ameliorate the electrochemical cycle stability of the RE-Mg-Ni based A2B7-type electrode alloys, the Mg content in the alloy was reduced and La in the alloy was partially substituted by Sm. The La0.8-xSmxM...In order to ameliorate the electrochemical cycle stability of the RE-Mg-Ni based A2B7-type electrode alloys, the Mg content in the alloy was reduced and La in the alloy was partially substituted by Sm. The La0.8-xSmxMg0.2Ni3.15Co0.2Al0.1Si0.05 (x=0, 0.1, 0.2, 0.3, 0.4) elec-trode alloys were fabricated by casting and annealing. The microstructures of the as-cast and annealed alloys were characterized by XRD and SEM. The electrochemical hydrogen storage characteristics of the as-cast and annealed alloys were measured. The results revealed that all of the experimental alloys mainly consisted of two phases: (La,Mg)2Ni7 phase with the hexagonal Ce2Ni7-type structure and LaNi5 phase with the hexagonal CaCu5-type structure. As Sm content grew from 0 to 0.4, the discharge capacity and the high rate discharge ability (HRD) first in-creased and then decreased for the as-cast and annealed alloys, whereas the capacity retaining rate (S100) after 100 cycles increased continuously.展开更多
The Ba3Y2(BO3)4:Eu^3+ phosphor was synthesized using a high temperature solid-state reaction method and the luminescent characteristics were investigated. The emission spectrum exhibited one strong red emission at...The Ba3Y2(BO3)4:Eu^3+ phosphor was synthesized using a high temperature solid-state reaction method and the luminescent characteristics were investigated. The emission spectrum exhibited one strong red emission at 613 nm, corresponding to the electric dipole 5D0-TF2 transition of Eu^3+, under 365 nm excitation. The excitation spectrum of 613 nm indicated that the Ba3Y2(BO3)n:Eu^3+ phosphor was effectively excited by ultraviolet (UV) (254, 365 and 400 nm) and blue (470 nm) light. The effect of Eu^3+ concentration on the 613 nm emission of the Ba3Y2(BO3)n:Eu^3+ phosphor was measured. The results showed that the emission intensity increased with increasing Eu^3+ concentration, and then decreased. The CIE color coordinates of Ba3Y2(BO3)4:Eu^3+ phosphor were x=0.641 and y=0.359 at 15 mol.% Eu^3+.展开更多
In this paper, we comprehensively investigate the influences of M(M=Cu, Co, Mn) substitution for Ni on the structures and electrochemical hydrogen storage characteristics of the nanocrystalline and amorphous Mg20Ni1...In this paper, we comprehensively investigate the influences of M(M=Cu, Co, Mn) substitution for Ni on the structures and electrochemical hydrogen storage characteristics of the nanocrystalline and amorphous Mg20Ni10-xMx(M=Cu, Co, Mn; x = 0–4) alloys prepared by melt spinning. The as-spun(M=None, Cu) alloys display an entire nanocrystalline structure, whereas the as-spun(M=Co, Mn) alloys hold a mixed structure of both nanocrystalline and amorphous when x = 4(M content). These results indicate that the substitution of M(M=Co, Mn) for Ni facilitates the glass formation in Mg2Ni-type alloy. All the as-spun alloys have the Mg2 Ni major phase, but M(M=Co, Mn) substitution brings on some secondary phases,such as Mg Co2, Mg phases for M=Co, and Mn Ni, Mg phases for M=Mn. The substitution of M(M=Cu, Co, Mn)for Ni also makes a positive contribution to the cycle stability of the alloys in the following orders:(M=Cu) [(M=Co) [(M=Mn) for x = 1 and(M=Co) [(M=Mn)[(M=Cu) for x = 2–4. Meanwhile, it notably enhances the discharge capacity of the alloys in the sequence of(M=Co) [(M=Mn) [(M=Cu). As for the high rate discharge ability, it visibly upgrades with the growing of M content for(M=Cu, Co), while it grows at first and then declines for(M=Mn).展开更多
Normal corn germplasm can be used to improve popcorn (Zea mays L.) through 1-2 backcrosses with popcorn as recurrent parents. Popping characteristics of derived lines from popcorn × dent or flint corn crosses p...Normal corn germplasm can be used to improve popcorn (Zea mays L.) through 1-2 backcrosses with popcorn as recurrent parents. Popping characteristics of derived lines from popcorn × dent or flint corn crosses play a determinant role in popcorn breeding. Advanced backcross QTL methods can effectively combine QTL identification and plant breeding. 220 selected BC2F2 families developed from a cross between Dan 232, a dent corn inbred line, and N04, an elite popcorn inbred line, were evaluated for three popping characteristics, popping volume, flake size, and popping rate, under two environmental conditions. Using composite interval mapping, a total of 10 significant QTLs were detected, and of these, 2 to 4 QTLs were identified for each trait. Six QTLs had favorable alleles contributed by Dan 232. Comparison with the 15 QTLs detected in the F2:3 families showed that 3 QTLs were the same in both populations. The QTLs should be redetected in generations developed through severe selection. Improved N04 and near isogenic lines could be developed from this BC2F2 population through selfing or another 1 to 2 backcrosses with N04.展开更多
The Yb3+:LiGd(WO4)2 crystal with the dimension of Ф15×35 mm3 was grown by Czochralski technique. The spectroscopic characterization and fluorescence dynamics of Yb3+ in yb3+:LiGd(WO4)2 crystal were inve...The Yb3+:LiGd(WO4)2 crystal with the dimension of Ф15×35 mm3 was grown by Czochralski technique. The spectroscopic characterization and fluorescence dynamics of Yb3+ in yb3+:LiGd(WO4)2 crystal were investigated. The yb3+:LiGd(WO4)2 crystal exhibits a broad absorption band centered near 975 nm with the linewidths of 16 and 11 nm and maximal absorption cross-section of 3.60 × 10-20 and 2.90× 10-20 cm2 for π- and σ-polarization, respectively. The emission broadband has an FWHM of 47 and 45 nm with the emission cross sections of 3.92 × 10-20 and 3.34× 10-2o cm2 at 1020 nm for re- and or-polarization, respectively. The measured fluorescence lifetime is 398 gs. The blue light emission around 480 nm through cooperative upconversion from the de-excitation of excited Yb3+-Yb3+ pairs at 4 K was observed under 932-nm excitation and demonstrated.展开更多
Nd2O3 doped BaTiO3ceramics(the additive content was respectively 0.001, 0.002, 0.003, 0.005, 0.01 molar ratio)were prepared by Sol-Gel method to study their dielectric characteristics and electric conductivities thr...Nd2O3 doped BaTiO3ceramics(the additive content was respectively 0.001, 0.002, 0.003, 0.005, 0.01 molar ratio)were prepared by Sol-Gel method to study their dielectric characteristics and electric conductivities through X-ray photoelectron spectrum (XPS). The results showed that the dielectric characteristics of Nd2O3 doped BaTiO3 ceramics were improved by doping. When Nd2O3 content was 0.003 mol, the results were even better, the dielectric constant was increased, the dielectric loss was decreased, the Curie-temperature (Tc) was 110 ℃, and the frequency characteristic was also good. The resistivity of Nd2O3 doped BaTiO3 ceramics was lower than that of pure BaTiO3 ceramics, when Nd2O3 content was 0.001 mol,the resistivity was (2.364×)108 Ω·m, the smallest. The grain resistance of Nd2O3 doped BaTiO3 ceramics exhibited NTC effect, but the grain boundary resistance showed PTC effect, and the grain boundary resistance was larger than that of the grain resistance, so the PTC effect originated from the grain boundary. The analysis of the element binding energy through X-ray photoelectron spectrum were indicated that the quantivalence of Ba2+and Ti4+in Nd2O3 doped BaTiO3 ceramics was variable, and resulted in the improvement of the conductibility of BaTiO3 ceramics.展开更多
We compared the photosynthetic characteristics in relation to yield of two F1 cotton hybrids(Shiza 2-F1 and Xinluzao 43-F1), their parental lines(NT2, H2 and 4-14) and their F2 descendants at different growth and ...We compared the photosynthetic characteristics in relation to yield of two F1 cotton hybrids(Shiza 2-F1 and Xinluzao 43-F1), their parental lines(NT2, H2 and 4-14) and their F2 descendants at different growth and development stages. The two F1 exhibited heterobeltiosis in net photosynthetic rate(Pn) by 8.1-52.1%, canopy apparent photosynthetic rate(CAP) by 8.2-57.6% and canopy respiration rate(CR) by 3.0-78.7% during the growing season. They also exhibited mid-parent heterosis by 2.0-5.2% in leaf chlorophyll content(SPAD) during the late growth and development stages. Regression analysis showed that both parents contributed to increase in Pn, SPAD and CAP in the F1. A low CR in the F1 matched a low CR of the parental line. Photosynthetic characteristics in the F2 were mainly dependent upon the magnitude and degeneration rate of the F1. Mid-parent heterosis in CAP and in CR during the late growth and development stage reduced the degeneration of the F2. Average dry matter accumulation was 10.7-34.7% higher in the parental lines of Xinluzao 43-F1 than in the parental lines of Shiza 2-F1. Heterobeltiosis in dry matter accumulation was 7.0-23.1% greater for Xinluzao 43-F1 than for Shiza 2-F1. Dry matter accumulation in the F1 was affected by either the dry matter accumulation of parents or heterobeltiosis. Dry matter accumulation in the F2 was mainly influenced by dry matter accumulation in the F1. The yields of the two F1 were 39.1-46.3% higher than their respective parents and 26.4-45.9% higher than that of the conventional cultivar Xinluzao 33. The yields of the two F2 were 9.2-12.8% higher than the parents and 14.9-27.4% higher than that of Xinluzao 33. The photosynthetic production and yield of the F1 and F2 were higher than that of their parents. The increases in Pn and CAP of the F1 and F2 were dependent on the photosynthetic characteristics of their parents. It is thus concluded that the photosynthetic performance, light use efficiency and yield of the F1 can be improved by using at least one parent with low CR, but high CAP, Pn and SPAD. This strategy might also improve the value of the F2.展开更多
基金Supported by the National Natural Science Foundation of China(52274053)Natural Science Foundation of Beijing(3232028).
文摘Using the ultra-low permeability reservoirs in the L block of the Jiangsu oilfield as an example,a series of experiments,including slim tube displacement experiments of CO_(2)-oil system,injection capacity experiments,and high-temperature,high-pressure online nuclear magnetic resonance(NMR)displacement experiments,are conducted to reveal the oil/gas mass transfer pattern and oil production mechanisms during CO_(2) flooding in ultra-low permeability reservoirs.The impacts of CO_(2) storage pore range and miscibility on oil production and CO_(2) storage characteristics during CO_(2) flooding are clarified.The CO_(2) flooding process is divided into three stages:oil displacement stage by CO_(2),CO_(2) breakthrough stage,CO_(2) extraction stage.Crude oil expansion and viscosity reduction are the main mechanisms for improving recovery in the CO_(2) displacement stage.After CO_(2) breakthrough,the extraction of light components from the crude oil further enhances oil recovery.During CO_(2) flooding,the contribution of crude oil in large pores to the enhanced recovery exceeds 46%,while crude oil in medium pores serves as a reserve for incremental recovery.After CO_(2) breakthrough,a small portion of the crude oil is extracted and carried into nano-scale pores by CO_(2),becoming residual oil that is hard to recover.As the miscibility increases,the CO_(2) front moves more stably and sweeps a larger area,leading to increased CO_(2) storage range and volume.The CO_(2) full-storage stage contributes the most to the overall CO_(2) storage volume.In the CO_(2) escape stage,the storage mechanism involves partial in-situ storage of crude oil within the initial pore range and the CO_(2) carrying crude oil into smaller pores to increase the volume of stored CO_(2).In the CO_(2) leakage stage,as crude oil is produced,a significant amount of CO_(2) leaks out,causing a sharp decline in the storage efficiency.
文摘This study aims to characterize the physical and mechanical properties of the soils from the Kenendé,Limbita 1,and Limbita 2 sites,located in the Dubréka prefecture,to develop a composite construction material based on soil and plant fibers that is more resistant to climatic and environmental conditions.To achieve this,soil samples were collected and subjected to various laboratory tests.The study assessed the physical and mechanical properties of these soils to develop a composite construction material incorporating soil and plant fibers.Laboratory tests revealed variations in water absorption capacity and compressive strength depending on the applied pressure(3,4,5 MPa)and the sample’s condition(dry or wet).After a 30-day maturation period,Kenendéexhibited a maximum dry-state strength of 2.66 MPa,while Limbita 1 and Limbita 2 recorded 0.95 MPa and 2.57 MPa,respectively.Soils compacted under high pressure demonstrated better performance,particularly in dry conditions.These results confirm the potential of the soils from the three sites for producing durable construction materials suitable for local climatic conditions,provided they undergo appropriate treatment and maturation,thereby contributing to sustainable construction in Guinea.
文摘The incorporation of fluorine(F_(2)) into hydrogen-air(H_(2)/Air) mixtures presents a novel approach to enhancing the performance of rotating detonation engines(RDEs). This study systematically investigates the effects of F_(2)concentration and inlet mass flow rate on rotating detonation wave(RDW) propagation using two-dimensional numerical simulations, providing the first comprehensive analysis of F_(2)as an oxidizing additive in regulating detonation performance, propagation stability, and heat release dynamics in RDEs. The results indicate that when F_(2)concentration is below 1%, the flow field primarily exhibits a stable single-wave propagation mode. As F_(2)concentration increases, RDW performance initially improves but then deteriorates, reaching its optimal state at 0.8% F_(2). When F_(2)concentration exceeds 1%, the coupled effects of F_(2)concentration and inlet mass flow rate induce a transition from single-wave to multi-wave propagation modes. While a higher inlet mass flow rate promotes increased wave numbers, it also intensifies wave-wave interactions. With further increases in F_(2)concentration, the enhanced heat release leads to intensified local deflagration, frequent hotspot formation, and wave collisions, ultimately degrading RDW performance and destabilizing the multi-wave flow field. Moreover, excessive HF formation is identified as a critical driver of enhanced deflagration, hotspot generation,and the disruption of multi-wave stability. These findings provide a theoretical foundation for integrating F_(2)additives into H_(2)/Air-based RDE systems.
基金supported by the National Natural Science Foundation of China(Grant No.12473063,12461160265,and 62227901)Shenzhen Science and Technology Innovation Commission(Grant No.20231121103211001)+5 种基金the Opening Fund of the Key Laboratory of Lunar and Deep Space Exploration,Chinese Academy of Sciences(No.LDSE202005)the Shenzhen University 2035 Program for Excellent Research(Grant No.2024C009)China National University Student Innovation&Entrepreneurship Development Program(No.202410590011)Natural Science Foundation of Guangdong Province(No.2024A1515011275)the Shenzhen Municipal Government Investment Project(No.2106_440300_04_03_901272)the team“Searching For Subglacial Water On Mars With Orbiting Ground Penetrating Radars”of the International Space Science Institute(ISSI).
文摘Asteroids and comets,which have long been of interest to astronomers,are important components of the solar system.They contain rich primitive information about the early solar system,which provide a unique pathway for studying the formation and evolution of the solar system,and even the origin of life on planet Earth.In this review,the formation,evolution processes and the internal characteristics of the asteroids and comets in the solar system are presented.The focus of this review is on the internal characteristics especially the dielectric properties of asteroids and comets by radar observations.On this basis,the possible internal structure of these celestial bodies is discussed.Combined with the existing theories,simulations and experiments,the possible internal structure of near-Earth asteroid 2016 HO_(3) is a monolith while structure of active asteroid 311P/PANSTARRS remains unknown.In 2025,China will launch Tianwen-2 asteroid-comet exploration mission to detect 2016 HO_(3) and 311P/PANSTARRS,which will carry a penetrating radar to observe the internal characteristics of these two objects.
基金supported by the Program of the National Natural Science Foundation of China(Nos.41973048,U2006201)the Open Project of State Key Laboratory of Geological Processes and Mineral Resources(No.GPMR202203)+1 种基金the Key R&D Program of Shandong Province(No.2023CXGC011001),the Taishan Scholars.Program(tstp20240847)the Open Project of Shandong Engineering Research Center of Application and Development of Big Data for Deep Gold Exploration(No.SDK202207)。
文摘Since the first discovery of gold deposits on the northeastern margin of the Jiaolai Basin in Shandong Province at the end of the 20^(th) century,seven medium-sized to large/super-large gold deposits have been identified in this region,with cumulative proven gold resources of 223 t.This study reviewed the metallogenic and geochemical characteristics of various gold deposits in this region,examined the sources of their ore-forming fluids and materials,as well as their gold metallogenic epochs and processes,and developed a gold metallogenic model.The gold deposits in this region are governed by both dense fractures and detachment structural systems along basin margins,primarily categorized into the altered rock type and the pyrite-bearing carbonate vein type.The latter type,a recently discovered mineralization type in the Jiaodong Peninsula,enjoys high gold grade,a large scale,and high gold mineral fineness,suggesting considerable prospecting potential.Both types of gold deposits show metallogenic epochs ranging from 116 Ma to 119 Ma.Their ore-forming fluids are identified as a CO_(2)-NaCl-H_(2)O fluid system characterized by moderate to low temperatures,moderate to low salinity,and low density,with the pyrite-bearing carbonate vein-type gold deposits manifesting slightly higher salinity.The C-H-O,S,and Pb isotopes of hydrothermal minerals reveal that the ore-forming fluids and materials are characteristic of crust-mantle mixing.Specifically,they were derived from mantle fluids in the early stages,mixed with stratum water and meteoric water in the later stages for mineralization.The gold metallogenic process is identified as follows:During the Early Cretaceous,the subduction of the Pacific Plate and the destruction of the North China Craton led to asthenospheric upwelling.The resulting fluids,after metasomatizing the enriched mantle,differentiated and evolved into C-H-O ore-bearing fluids,which were then mixed with crustal fluids.The mixed fluids migrated to the shallow crust,where they mingled with stratum water and meteoric water.Then,the fluids underwent unloading and final mineralization in detachment fault tectonic systems on basin margins.Due to differences in mixed crustal materials or the surrounding rocks involved in water-rock interactions,altered rock-and pyrite-bearing carbonate vein-type gold deposits were formed in acidic and alkaline fluid environments,respectively.
基金Projects(51161015,50961009)supported by the National Natural Science Foundations of ChinaProject(2011AA03A408)supported by the National Hi-tech Research and Development Program of ChinaProjects(2011ZD10,2010ZD05)supported by the Natural Science Foundation of Inner Mongolia,China
文摘The La-Mg-Ni-based A2B7-type La0.8-xNdxMg0.2Ni3.15Co0.2Al0.15 (x=0, 0.1, 0.2, 0.3, 0.4) electrode alloys were prepared by casting and annealing. The influences of partial substitution of Nd for La on the structure and electrochemical performance of the as-cast and annealed alloys were investigated. It was found that the experimental alloys consist of two major phases, (La, Mg)2Ni7 phase with the hexagonal Ce2Ni7-type structure and LaNi5 phase with the hexagonal CaCu5-type structure, as well as some residual phase LaNi3 and NdNi5. The discharge capacity and high rate discharge ability (HRD) of the as-cast and annealed alloys first increase and then decrease with Nd content growing. The as-cast and annealed alloys (x=0.3) yield the largest discharge capacities of 380.3 and 384.3 mA·h/g, respectively. The electrochemical cycle stability of the as-cast and annealed alloys markedly grows with Nd content rising. As the Nd content increase from 0 to 0.4. The capacity retaining rate (S100) at the 100th charging and discharging cycle increases from 64.98% to 85.17% for the as-cast alloy, and from 76.60% to 96.84% for the as-annealed alloy.
文摘AIM:To investigate human epidermal growth factor receptor 2(HER2) gene amplification and protein expression in Chinese patients with resectable gastric cancer and the association with clinicopathological characteristics and survival.METHODS:One hundred and ninety-seven gastric cancer patients who underwent curative surgery procedures were enrolled into this study.HER2 gene amplification and protein expression were examined using fluorescence in-situ hybridization(FISH) and immunohistochemistry(IHC) analysis on formalin-fixed paraffinembedded gastric cancer samples from all patients.For scoring,Hofmann's HER2 gastric cancer scoring system was adopted.All cases showing IHC3+ or FISH positiv-ity were defined as HER2 positive.Patient clinicopathological data and survival information were collected.Finally,χ 2 statistical analysis was performed to analyze the HER2 positivity rate amongst the subgroups with different clinicopathological characteristics including;gender,age,tumor location,Lauren classification,differentiation,TNM staging,depth of invasion,lymph node metastases and distant metastasis.The probability of survival for different subgroups with different clinicopathological characteristics was calculated using the Kaplan-Meier method and survival curves plotted using log rank inspection.RESULTS:According to Hofmann's HER2 gastric cancer scoring criteria,31 cases(15.74%) were identified as HER2 gene amplified and 19 cases(9.64%) were scored as strongly positive for HER2 membrane staining(3+),25 cases(12.69%) were moderately positive(2+) and 153 cases(77.66%) were HER2 negative(0/1+).The concordance rate between IHC and FISH analyses was 88.83%(175/197).Thirty-six cases were defined as positive for HER2 gene amplification and/or protein expression,with 24 of these cases being eligible for Herceptin treatment according to United States recommendations,and 29 of these cases eligible according to EU recommendations.Highly consistent results were detected between IHC3+,IHC0/1 and FISH(73.68% and 95.42%),but low consistency was observed between IHC2+ and FISH(40.00%).The positivity rates in intestinal type and well-differentiated gastric cancer were higher than those in diffuse/mixed type and poorly-differentiated gastric cancer respectively(28.57% vs 13.43%,P = 0.0103;37.25% vs 11.64%,P < 0.0001),but were not correlated with gender,age,tumor location or TNM stage,depth of invasion,lymph node metastases and distant metastasis.In poorly-differentiated gastric cancer patients,those without lymph node metastasis showed a higher HER2 positivity rate than those with lymph node metastasis(26.47% vs 7.14%,P = 0.0021).This association was not present in thosepatients with well-differentiated gastric cancer(28.57% vs 43.33%,P = 0.2832).Within our patient cohort,26 cases were lost to follow-up.The median survival time for the remaining 171 patients was 18 mo.The median survival times of the HER2 positive and negative groups were 17 and 18.5 mo respectively.Overall survival was not significantly different between HER2-positive and negative groups(χ 2 = 0.9157,P = 0.3386),but in patients presenting well-differentiated tumors,the overall survival of the HER2-positive group was significantly worse than that of the HER2-negative group(P = 0.0123).In contrast,patients with poorly differentiated and diffuse/mixed subtype gastric cancers showed no significant differences in overall survival associated with HER2.Furthermore,the median survival time of the HER2 positive group did not show any statistically significant differences when compared to the subgroups of gender,age,tumor location,TNM classification,lymph node metastases and distant metastasis.CONCLUSION:Patients with intestinal type gastric cancer(GC),well-differentiated GC and poorly-differentiated GC without lymph node metastasis,may all represent suitable candidates for targeted therapy using Herceptin.
基金Supported by Priority Academic Program Development of Jiangsu Higher Education Institution (PAPD)the Project of Jiangsu Clinical Medicine (BL2012053)+1 种基金the Programs of Nantong Society Undertaking and Technological Innovation,No.HS2012034 and HS2011012the International S and T Cooperation Program of China
文摘AIM: TO investigate the characteristics and diagnostic value of annexin A2 (ANXA2) expression in cancerous tissues and sera of patients with hepatitis B virus (HBV)-related hepatocellular carcinoma (HCC). METHODS: Levels of liver ANXA2 gene transcription or protein expression were analyzed in HCC-, their self- controlled precancerous-, and distant cancerous- tissues from 30 HCC. Serum levels of ANXA2 expression in 115 patients with HCC, 25 with metastatic liver can cer, 35 with chronic hepatitis, 28 with acute hepatitis, 38 with cirrhosis, and 30 healthy controls were deter- mined. Clinicopathological characteristics of circulating ANXA2 expression were analyzed, and its diagnostic efficiency and clinical values in HCC were evaluated. RESULTS: ANXA2 expression was localized in both cell membrane and cytoplasm in HCC tissue, mainly in the cytoplasm of matched adjacent cancerous tissue, and there was almost no positive staining in matched distant cancerous tissue. Abnormal expression of liver ANXA2 was present in HCC tissues compared with self-con- trolled adjacent- and distant-cancerous tissues at pro- tein or mRNA level. Circulating ANXA2 in HCC patients was significantly higher than that of other liver diseases (P 〈 0.01) except metastatic liver cancer. If the diag- nostic cutoff value of ANXA2 level was more than 18 ng/ mL, the incidence of serum ANXA2 was 86.96% in the HCC group, 80% in the metastatic liver cancer group, 31.58% in the liver cirrhosis group, none in the chronic hepatitis or acute hepatitis or normal control group, respectively. Serum ANXA2 expression in HCC patients was correlated with HBV infection (27.38 ± 5.67 ng/mL vs 18.58 ± 7.83 ng/mL, P 〈 0.01), extrahepatic metas- tasis (26.11±5.43 ng/mL ys 22.79 ± 5.64 ng/mL, P 〈 0.01), and portal vein thrombus (26.03 ± 5.99 ng/mL vs 23.06 ± 5.03 ng/mL, P 〈 0.01), and was significantly higher (P 〈 0.01) in the moderately- (26.19±5.34 ng/ mL) or the poorly- differentiated group (27.05 ± 5.13 ng/mL) than in the well differentiated group (20.43 ± 4.97 ng/mL), and in the tumor node metastasis stages Ⅲ-Ⅳ(P 〈 0.01) than in stages Ⅰ-Ⅱ. ANXA2 was not correlated with patient sex, age, size or α-fetoprotein (AFP) level. Area under the receiver operating charac- teristic curve for the whole range of sensitivities and specificities was 0.796 for ANXA2 and 0.782 for AFP. Combining detection of serum ANXA2 and AFP substan- tially improved the diagnostic efficiency (96.52%) and the neclative predictive value ('96.61%) for HCC.of ANXA2 expression has good diagnostic potential for HCC diagnosis.
基金Supported by the Major Science and Technology Projects of Shanxi Province(No.20181102017)the Open Project Program of State Key Laboratory of Petroleum Pollution Control(No.PPC2017010)+1 种基金CNPC Research Institute of Safety and Environmental Technologythe Fundamental Research Funds for the Central Universities(No.2009QH03).
文摘The total coal consumption in China is on the rise.The characteristics of CO2 and SO2 emissions in the whole process of coal processing and utilization in China are worthy of study.Based on the five links of the whole process of coal production and utilization,including coal production,raw coal processing,logistics and transportation,conversion and utilization and resource utilization,this paper summarized and analyzed the energy consumption and pollutant emission sources of these five links,combined with the US Environmental Protection Agency’s AP-42 method and IPCC method,to calculate total pollutant discharge and emission factors,where the emission factors were corrected by conversion efficiency.At the same time,uncertainty analysis is performed about CO2 and SO2 emissions.The results showed that CO2 emissions were 3.657 billion tons,and emission reductions were 61 million tons,and SO2 emissions were 4,844,500 tons,and emission reductions were 10.3595 million tons in 2015.
基金Project supported by Hebei Provincial Technology Development Foundation of China(Grant No51215103b)
文摘This paper synthesizes the Sr2SiO4:Eu^2+ phosphor by high temperature solid-state reaction. The emission spectrum of Sr2SiO4 : Eu^2+ shows two bands centred at 480 and 547 nm, which agree well with the calculation values of emission spectrum, and the location of yellow emission of Sr2SiO4 : Eu^2+ is influenced by the Eu^2+ concentration. The excitation spectrum for 547 nm emission has two bands at 363 and 402 nm. The emission spectrum of white light emitting diodes (w-LEDs) based on Sr2SiO4 : Eu^2+ phosphor + InGaN LED was investigated.
文摘The statistical probability and their variation regularity of the measurable characteristic parameters in the CO 2 arc welding droplet short circuiting transfer process have been studied. The statistical analysis shows that the sensitivity of each characteristic parameter with regard to the variation of the short circuiting transfer process is different. The sensitivity of 4 kinds among these characteristic parameters is more intense than that of the short circuiting transfer frequency. In order to take account of the synthetic influence of these characteristic parameters, by means of the characteristic parameters synthetic value, a quantitative evaluation function is built up to describe and evaluate the short circuiting transfer process of CO 2 arc welding in real time. The testing shows that the evaluation function can give a suitable synthetic valuation for the short circuiting transfer process with a variety of welding variables.
基金supported by the National Major Grant of"Accumulation Law,Key Technologies and Evaluations of the Stratigraphic Reservoirs"(No.2008ZX05000-001) from the Research Institute of Petroleum Exploration & Development,PetroChina
文摘"Continuous" tight gas reservoirs are those reservoirs which develop in widespread tight sandstones with a continuous distribution of natural gas. In this paper, we summarize the geological features of the source rocks and "'continuous" tight gas reservoirs in the Xujiahe Formation of the middle- south transition region, Sichuan Basin. The source rocks of the Xul Member and reservoir rocks of the Xu2 Member are thick (Xul Member: 40 m, Xu2 Member: 120 m) and are distributed continuously in this study area. The results of drilled wells show that the widespread sandstone reservoirs of the Xu2 Member are charged with natural gas. Therefore, the natural gas reservoirs of the Xu2 Member in the middle-south transition region are "continuous" tight gas reservoirs. The accumulation of "continuous" tight gas reservoirs is controlled by an adequate driving force of the pressure differences between source rocks and reservoirs, which is demonstrated by a "one-dimensional" physical simulation experiment. In this simulation, the natural gas of"continuous" tight gas reservoirs moves tbrward with no preferential petroleum migration pathways (PPMP), and the natural gas saturation of"continuous" tight gas reservoirs is higher than that of conventional reservoirs.
基金financially supported by the Natural Science Foundation of China (No. 51266005)the Science and Technology Research Key Project of the Ministry of Education (No. 1106ZBB007)+1 种基金the Hongliu Outstanding Talent Program of LUT (No. Q201101)the Open Fund of Natural Gas Hydrate Key Laboratory, Chinese Academy of Sciences (No. y007s3)
文摘Porous medium has an obvious effect on the formation of carbon dioxide hydrate. In order to study the characteristics of CO2 hydrate formation in porous medium below the freezing point, the experiment of CO2 hydrate formation was conducted in a high-pressure 1.8-L cell in the presence of porous media with a particle size of 380 μm, 500 μm and 700 μm, respectively. The test results showed that the porous medium had an important influence on the process of CO2 hydrate formation below the freezing point. Compared with porous media with a particle size of 500 μm and 700 μm, respectively, the average hydrate formation rate and gas storage capacity of carbon dioxide hydrate in the porous medium with a particle size of 380 μm attained 0.016 14 mol/h and 65.094 L/L, respectively. The results also indicated that, within a certain range of particle sizes, the smaller the particle size of porous medium was, the larger the average hydrate formation rate and the gas storage capacity of CO2 hydrate during the process of hydrate formation would be.
基金Project supported by National Natural Science Foundations of China (51161015 and 50961009)National High Technology Research and Development Program of China (2011AA03A408)Natural Science Foundations of Inner Mongolia,China (2011ZD10 and 2010ZD05)
文摘In order to ameliorate the electrochemical cycle stability of the RE-Mg-Ni based A2B7-type electrode alloys, the Mg content in the alloy was reduced and La in the alloy was partially substituted by Sm. The La0.8-xSmxMg0.2Ni3.15Co0.2Al0.1Si0.05 (x=0, 0.1, 0.2, 0.3, 0.4) elec-trode alloys were fabricated by casting and annealing. The microstructures of the as-cast and annealed alloys were characterized by XRD and SEM. The electrochemical hydrogen storage characteristics of the as-cast and annealed alloys were measured. The results revealed that all of the experimental alloys mainly consisted of two phases: (La,Mg)2Ni7 phase with the hexagonal Ce2Ni7-type structure and LaNi5 phase with the hexagonal CaCu5-type structure. As Sm content grew from 0 to 0.4, the discharge capacity and the high rate discharge ability (HRD) first in-creased and then decreased for the as-cast and annealed alloys, whereas the capacity retaining rate (S100) after 100 cycles increased continuously.
基金Project supported by the Hebei Provincial Technology Development Foundation (51215103b)Science Foundation of Hebei University (2006Q06)
文摘The Ba3Y2(BO3)4:Eu^3+ phosphor was synthesized using a high temperature solid-state reaction method and the luminescent characteristics were investigated. The emission spectrum exhibited one strong red emission at 613 nm, corresponding to the electric dipole 5D0-TF2 transition of Eu^3+, under 365 nm excitation. The excitation spectrum of 613 nm indicated that the Ba3Y2(BO3)n:Eu^3+ phosphor was effectively excited by ultraviolet (UV) (254, 365 and 400 nm) and blue (470 nm) light. The effect of Eu^3+ concentration on the 613 nm emission of the Ba3Y2(BO3)n:Eu^3+ phosphor was measured. The results showed that the emission intensity increased with increasing Eu^3+ concentration, and then decreased. The CIE color coordinates of Ba3Y2(BO3)4:Eu^3+ phosphor were x=0.641 and y=0.359 at 15 mol.% Eu^3+.
基金financially supported by the National Natural Science Foundations of China (No. 51161015)the Natural Science Foundation of Inner Mongolia, China (Nos. 2011ZD10 and 2010ZD05)
文摘In this paper, we comprehensively investigate the influences of M(M=Cu, Co, Mn) substitution for Ni on the structures and electrochemical hydrogen storage characteristics of the nanocrystalline and amorphous Mg20Ni10-xMx(M=Cu, Co, Mn; x = 0–4) alloys prepared by melt spinning. The as-spun(M=None, Cu) alloys display an entire nanocrystalline structure, whereas the as-spun(M=Co, Mn) alloys hold a mixed structure of both nanocrystalline and amorphous when x = 4(M content). These results indicate that the substitution of M(M=Co, Mn) for Ni facilitates the glass formation in Mg2Ni-type alloy. All the as-spun alloys have the Mg2 Ni major phase, but M(M=Co, Mn) substitution brings on some secondary phases,such as Mg Co2, Mg phases for M=Co, and Mn Ni, Mg phases for M=Mn. The substitution of M(M=Cu, Co, Mn)for Ni also makes a positive contribution to the cycle stability of the alloys in the following orders:(M=Cu) [(M=Co) [(M=Mn) for x = 1 and(M=Co) [(M=Mn)[(M=Cu) for x = 2–4. Meanwhile, it notably enhances the discharge capacity of the alloys in the sequence of(M=Co) [(M=Mn) [(M=Cu). As for the high rate discharge ability, it visibly upgrades with the growing of M content for(M=Cu, Co), while it grows at first and then declines for(M=Mn).
基金funded by the Natural Science Founda-tion of Henan Province of China (0511032900).
文摘Normal corn germplasm can be used to improve popcorn (Zea mays L.) through 1-2 backcrosses with popcorn as recurrent parents. Popping characteristics of derived lines from popcorn × dent or flint corn crosses play a determinant role in popcorn breeding. Advanced backcross QTL methods can effectively combine QTL identification and plant breeding. 220 selected BC2F2 families developed from a cross between Dan 232, a dent corn inbred line, and N04, an elite popcorn inbred line, were evaluated for three popping characteristics, popping volume, flake size, and popping rate, under two environmental conditions. Using composite interval mapping, a total of 10 significant QTLs were detected, and of these, 2 to 4 QTLs were identified for each trait. Six QTLs had favorable alleles contributed by Dan 232. Comparison with the 15 QTLs detected in the F2:3 families showed that 3 QTLs were the same in both populations. The QTLs should be redetected in generations developed through severe selection. Improved N04 and near isogenic lines could be developed from this BC2F2 population through selfing or another 1 to 2 backcrosses with N04.
基金Support by the National Natural Science Foundation of China(No.60808033)train object program of Jiangxi Province Young Scientists,Natural Science Foundation of Jiangxi Province(No.2011BAB206029,2010GQS0064 and 2008GZW0012)excellent young academic talent program of Jiangxi University of Finance and Economics
文摘The Yb3+:LiGd(WO4)2 crystal with the dimension of Ф15×35 mm3 was grown by Czochralski technique. The spectroscopic characterization and fluorescence dynamics of Yb3+ in yb3+:LiGd(WO4)2 crystal were investigated. The yb3+:LiGd(WO4)2 crystal exhibits a broad absorption band centered near 975 nm with the linewidths of 16 and 11 nm and maximal absorption cross-section of 3.60 × 10-20 and 2.90× 10-20 cm2 for π- and σ-polarization, respectively. The emission broadband has an FWHM of 47 and 45 nm with the emission cross sections of 3.92 × 10-20 and 3.34× 10-2o cm2 at 1020 nm for re- and or-polarization, respectively. The measured fluorescence lifetime is 398 gs. The blue light emission around 480 nm through cooperative upconversion from the de-excitation of excited Yb3+-Yb3+ pairs at 4 K was observed under 932-nm excitation and demonstrated.
文摘Nd2O3 doped BaTiO3ceramics(the additive content was respectively 0.001, 0.002, 0.003, 0.005, 0.01 molar ratio)were prepared by Sol-Gel method to study their dielectric characteristics and electric conductivities through X-ray photoelectron spectrum (XPS). The results showed that the dielectric characteristics of Nd2O3 doped BaTiO3 ceramics were improved by doping. When Nd2O3 content was 0.003 mol, the results were even better, the dielectric constant was increased, the dielectric loss was decreased, the Curie-temperature (Tc) was 110 ℃, and the frequency characteristic was also good. The resistivity of Nd2O3 doped BaTiO3 ceramics was lower than that of pure BaTiO3 ceramics, when Nd2O3 content was 0.001 mol,the resistivity was (2.364×)108 Ω·m, the smallest. The grain resistance of Nd2O3 doped BaTiO3 ceramics exhibited NTC effect, but the grain boundary resistance showed PTC effect, and the grain boundary resistance was larger than that of the grain resistance, so the PTC effect originated from the grain boundary. The analysis of the element binding energy through X-ray photoelectron spectrum were indicated that the quantivalence of Ba2+and Ti4+in Nd2O3 doped BaTiO3 ceramics was variable, and resulted in the improvement of the conductibility of BaTiO3 ceramics.
基金the National Natural Science Foundation of China(U1203283,31060176)the Key Technologies R&D Program of China during the 11th Five-Year Plan period(2007BAD44B07)
文摘We compared the photosynthetic characteristics in relation to yield of two F1 cotton hybrids(Shiza 2-F1 and Xinluzao 43-F1), their parental lines(NT2, H2 and 4-14) and their F2 descendants at different growth and development stages. The two F1 exhibited heterobeltiosis in net photosynthetic rate(Pn) by 8.1-52.1%, canopy apparent photosynthetic rate(CAP) by 8.2-57.6% and canopy respiration rate(CR) by 3.0-78.7% during the growing season. They also exhibited mid-parent heterosis by 2.0-5.2% in leaf chlorophyll content(SPAD) during the late growth and development stages. Regression analysis showed that both parents contributed to increase in Pn, SPAD and CAP in the F1. A low CR in the F1 matched a low CR of the parental line. Photosynthetic characteristics in the F2 were mainly dependent upon the magnitude and degeneration rate of the F1. Mid-parent heterosis in CAP and in CR during the late growth and development stage reduced the degeneration of the F2. Average dry matter accumulation was 10.7-34.7% higher in the parental lines of Xinluzao 43-F1 than in the parental lines of Shiza 2-F1. Heterobeltiosis in dry matter accumulation was 7.0-23.1% greater for Xinluzao 43-F1 than for Shiza 2-F1. Dry matter accumulation in the F1 was affected by either the dry matter accumulation of parents or heterobeltiosis. Dry matter accumulation in the F2 was mainly influenced by dry matter accumulation in the F1. The yields of the two F1 were 39.1-46.3% higher than their respective parents and 26.4-45.9% higher than that of the conventional cultivar Xinluzao 33. The yields of the two F2 were 9.2-12.8% higher than the parents and 14.9-27.4% higher than that of Xinluzao 33. The photosynthetic production and yield of the F1 and F2 were higher than that of their parents. The increases in Pn and CAP of the F1 and F2 were dependent on the photosynthetic characteristics of their parents. It is thus concluded that the photosynthetic performance, light use efficiency and yield of the F1 can be improved by using at least one parent with low CR, but high CAP, Pn and SPAD. This strategy might also improve the value of the F2.