This study aims to examine the usability of environmentally harmless vegetable oil in the minimum quantity of lubrication(MQL)system in face milling of AISI O2 steel and to optimize the cutting parameters by different...This study aims to examine the usability of environmentally harmless vegetable oil in the minimum quantity of lubrication(MQL)system in face milling of AISI O2 steel and to optimize the cutting parameters by different statistical methods.Vegetable oil was preferred as cutting fluid,and Taguchi method was used in the preparation of the test pattern.After testing with the prepared test pattern,cutting performance in all parameters has been improved according to dry conditions thanks to the MQL system.The highest tool life was obtained by using cutting parameters of 7.5 m cutting length,100 m/min cutting speed,100 mL/h MQL flow rate and 0.1 mm/tooth feed rate.Optimum cutting parameters were determined according to the Taguchi analysis,and the obtained parameters were confirmed with the verification tests.In addition,the optimum test parameter was determined by applying the gray relational analysis method.After using ANOVA analysis according to the measured surface roughness and cutting force values,the most effective cutting parameter was observed to be the feed rate.In addition,the models for surface roughness and cutting force values were obtained with precisions of 99.63%and 99.68%,respectively.Effective wear mechanisms were found to be abrasion and adhesion.展开更多
Based on chromatographic theory, the moment method and the time-domain fitting analysis were applied to measure and evaluate the adsorption equilibrium constant and mass transfer properties (axial dispersion coefficie...Based on chromatographic theory, the moment method and the time-domain fitting analysis were applied to measure and evaluate the adsorption equilibrium constant and mass transfer properties (axial dispersion coefficient and effective intra-particle diffusivity) for toluene and p-dichlorobenzene on silica gel adsorbent in the subcritical and supercritical CO2. An apparatus based on supercritical fluid chromatography was established and the experiments were performed at temperatures of 298.15-318.15 K and pressures of 7.5-17.8 MPa. The two methods have been compared. The results show that for the systems studied here the moment method can give reasonable values for both adsorption equilibrium constant and mass transfer properties, but the time-domain analysis only can obtain the adsorption equilibrium constant. The dependence of adsorption equilibrium constant and mass transfer properties on temperature and pressure was investigated.展开更多
Catalytic conversion of COinto chemicals and fuels is an alternative to alleviate climate change and ocean acidification.The catalytic reduction of COby Hcan lead to the formation of various products:carbon monoxide,c...Catalytic conversion of COinto chemicals and fuels is an alternative to alleviate climate change and ocean acidification.The catalytic reduction of COby Hcan lead to the formation of various products:carbon monoxide,carboxylic acids,aldehydes,alcohols and hydrocarbons.In this paper,a comprehensive thermodynamics analysis of COhydrogenation is conducted using the Gibbs free energy minimization method.The results show that COreduction to CO needs a high temperature and H/COratio to achieve a high COconversion.However,synthesis of methanol from COneeds a relatively high pressure and low temperature to minimize the reverse water-gas shift reaction.Direct COhydrogenation to formic acid or formaldehyde is thermodynamically limited.On the contrary,production of CHfrom COhydrogenation is the thermodynamically easiest reaction with nearly 100%CH4 yield at moderate conditions.In addition,complex reactions with more than one product are also calculated in this work.Among the considered carboxylic acids（HCOOH,CHCOOH and CHCOOH）,propionic acid dominates in the product stream（selectivity above 90%）.The same trend can also be found in the hydrogenation of COto aldehydes and alcohols with the major product of propionaldehyde and butanol,respectively.In the process of COhydrogenation to alkenes,low temperature,high pressure,and high Hpartial pressure favor the COconversion.CHis the most thermodynamically favorable among all considered alkynes under different temperatures and pressures.The thermodynamic calculations are validated with experimental results,suggesting that the Gibbs free energy minimization method is effective for thermodynamically understanding the reaction network involved in the COhydrogenation process,which is helpful for the development of high-performance catalysts.展开更多
The Soil and Water Assessment Tool （SWAT） was implemented in a small forested watershed of the Soan River Basin innorthern Pakistan through application of the sequential uncertainty fitting （SUFI-2） method to inve...The Soil and Water Assessment Tool （SWAT） was implemented in a small forested watershed of the Soan River Basin innorthern Pakistan through application of the sequential uncertainty fitting （SUFI-2） method to investigate the associateduncertainty in runoff and sediment load estimation. The model was calibrated for a 10-year period （1991–2000） with aninitial 4-year warm-up period （1987–1990）, and was validated for the subsequent 10-year period （2001–2010）. Themodel evaluation indices R2 （the coefficient of determination）, NS （the Nash-Sutcliffe efficiency）, and PBIAS （percentbias） for stream flows simulation indicated that there was a good agreement between the measured and simulated flows.To assess the uncertainty in the model outputs, p-factor （a 95% prediction uncertainty, 95PPU） and r-factors （averagewideness width of the 95PPU band divided by the standard deviation of the observed values） were taken into account.The 95PPU band bracketed 72% of the observed data during the calibration and 67% during the validation. The r-factorwas 0.81 during the calibration and 0.68 during the validation. For monthly sediment yield, the model evaluation coefficients（R2 and NS） for the calibration were computed as 0.81 and 0.79, respectively; for validation, they were 0.78and 0.74, respectively. Meanwhile, the 95PPU covered more than 60% of the observed sediment data during calibrationand validation. Moreover, improved model prediction and parameter estimation were observed with the increasednumber of iterations. However, the model performance became worse after the fourth iterations due to an unreasonableparameter estimation. Overall results indicated the applicability of the SWAT model with moderate levels of uncertaintyduring the calibration and high levels during the validation. Thus, this calibrated SWAT model can be used for assessmentof water balance components, climate change studies, and land use management practices.展开更多
Input-output analysis is widely employed to analyze inventories of a product＇s embodied energy and environmental burdens. However, input-output analysis focuses only on the production stage and ignores other life cyc...Input-output analysis is widely employed to analyze inventories of a product＇s embodied energy and environmental burdens. However, input-output analysis focuses only on the production stage and ignores other life cycle phases. Input-output analysis is not exactly a LCA （life cycle assessment） method in the strict sense of ISO 14040 standards, which must cover all stages of a product＇s life cycle, ＂from the cradle to the grave＂, so to speak. A tiered hybrid LCA is a useful tool that covers all life cycle stages by combining a process analysis with the input-output analysis method. This study aims to extend input-output analysis to the use, disposal, and recycling stages by using matrix-based method. The new method is applied to the analysis of the embodied CO2 emissions of a refrigerator as a case study. The entire life cycle C02 emissions are estimated to be 2.9 tons, including indirect emissions, and the reduction in CO2 emissions due to recycling steel scrap is calculated as 48.5 kg. The authors conclude that the new method enables a consistent inventory analysis for all life cycle stages by combining process and input-output methods.展开更多
A spectrofluorimetric method for the direct analysis of carbendazim [methyl 2-benzimidazole carbamate (MBC)] fungicide and its metabolite 2-aminobenzimidazole (2-AB) in natural waters is described. Very low limit of d...A spectrofluorimetric method for the direct analysis of carbendazim [methyl 2-benzimidazole carbamate (MBC)] fungicide and its metabolite 2-aminobenzimidazole (2-AB) in natural waters is described. Very low limit of detection (LOD) and limit of quantification (LOQ) values of 0.002 - 0.06 ng/mL and 0.006 - 0.2 ng/mL, respectively, were determined by spectrofluorimetric method with small relative standard deviation (RSD) values < 1%. This spectrofluorimetric method was applied to the determination of MBC and 2-AB residues in natural waters, with satisfactory recovery values of (88.5% - 119.2%).展开更多
This paper introduced the basic theory and algorithm of the surrogate data method, which proposed a rigorous way to detect the random and seemingly stochastic characteristics in a system. The Gaussian data and the Ros...This paper introduced the basic theory and algorithm of the surrogate data method, which proposed a rigorous way to detect the random and seemingly stochastic characteristics in a system. The Gaussian data and the Rossler data were used to show the availability and effectivity of this method. According to the analysis by this method based on the short-circuiting current signals under the conditions of the same voltage and different wire feed speeds, it is demonstrated that the electrical signals time series exhibit apparently randomness when the welding parameters do not match. However, the electrical signals time series are deterministic when a match is found. The stability of short-circuiting transfer process could be judged exactly by the method of surrogate data.展开更多
In Europe, computation of displacement demand for seismic assessment of existing buildings is essentially based on a simplified formulation of the N2 method as prescribed by Eurocode 8(EC8). However, a lack of accurac...In Europe, computation of displacement demand for seismic assessment of existing buildings is essentially based on a simplified formulation of the N2 method as prescribed by Eurocode 8(EC8). However, a lack of accuracy of the N2 method in certain conditions has been pointed out by several studies. This paper addresses the assessment of effectiveness of the N2 method in seismic displacement demand determination in non-linear domain. The objective of this work is to investigate the accuracy of the N2 method through comparison with displacement demands computed using non-linear timehistory analysis(NLTHA). Results show that the original N2 method may lead to overestimation or underestimation of displacement demand predictions. This may affect results of mechanical model-based assessment of seismic vulnerability at an urban scale. Hence, the second part of this paper addresses an improvement of the N2 method formula by empirical evaluation of NLTHA results based on EC8 ground-classes. This task is formulated as a mathematical programming problem in which coefficients are obtained by minimizing the overall discrepancy between NLTHA and modified formula results. Various settings of the mathematical programming problem have been solved using a global optimization metaheuristic. An extensive comparison between the original N2 method formulation and optimized formulae highlights benefits of the strategy.展开更多
文摘This study aims to examine the usability of environmentally harmless vegetable oil in the minimum quantity of lubrication(MQL)system in face milling of AISI O2 steel and to optimize the cutting parameters by different statistical methods.Vegetable oil was preferred as cutting fluid,and Taguchi method was used in the preparation of the test pattern.After testing with the prepared test pattern,cutting performance in all parameters has been improved according to dry conditions thanks to the MQL system.The highest tool life was obtained by using cutting parameters of 7.5 m cutting length,100 m/min cutting speed,100 mL/h MQL flow rate and 0.1 mm/tooth feed rate.Optimum cutting parameters were determined according to the Taguchi analysis,and the obtained parameters were confirmed with the verification tests.In addition,the optimum test parameter was determined by applying the gray relational analysis method.After using ANOVA analysis according to the measured surface roughness and cutting force values,the most effective cutting parameter was observed to be the feed rate.In addition,the models for surface roughness and cutting force values were obtained with precisions of 99.63%and 99.68%,respectively.Effective wear mechanisms were found to be abrasion and adhesion.
基金Supported by research grant 02KJB530002 from Jiangsu Provincial Committee of Education.
文摘Based on chromatographic theory, the moment method and the time-domain fitting analysis were applied to measure and evaluate the adsorption equilibrium constant and mass transfer properties (axial dispersion coefficient and effective intra-particle diffusivity) for toluene and p-dichlorobenzene on silica gel adsorbent in the subcritical and supercritical CO2. An apparatus based on supercritical fluid chromatography was established and the experiments were performed at temperatures of 298.15-318.15 K and pressures of 7.5-17.8 MPa. The two methods have been compared. The results show that for the systems studied here the moment method can give reasonable values for both adsorption equilibrium constant and mass transfer properties, but the time-domain analysis only can obtain the adsorption equilibrium constant. The dependence of adsorption equilibrium constant and mass transfer properties on temperature and pressure was investigated.
基金funded by the National Research Foundation(NRF)Prime Minister’s Office,Singapore under its Campus for Research Excellence and Technological Enterprise(CREATE)Program
文摘Catalytic conversion of COinto chemicals and fuels is an alternative to alleviate climate change and ocean acidification.The catalytic reduction of COby Hcan lead to the formation of various products:carbon monoxide,carboxylic acids,aldehydes,alcohols and hydrocarbons.In this paper,a comprehensive thermodynamics analysis of COhydrogenation is conducted using the Gibbs free energy minimization method.The results show that COreduction to CO needs a high temperature and H/COratio to achieve a high COconversion.However,synthesis of methanol from COneeds a relatively high pressure and low temperature to minimize the reverse water-gas shift reaction.Direct COhydrogenation to formic acid or formaldehyde is thermodynamically limited.On the contrary,production of CHfrom COhydrogenation is the thermodynamically easiest reaction with nearly 100%CH4 yield at moderate conditions.In addition,complex reactions with more than one product are also calculated in this work.Among the considered carboxylic acids（HCOOH,CHCOOH and CHCOOH）,propionic acid dominates in the product stream（selectivity above 90%）.The same trend can also be found in the hydrogenation of COto aldehydes and alcohols with the major product of propionaldehyde and butanol,respectively.In the process of COhydrogenation to alkenes,low temperature,high pressure,and high Hpartial pressure favor the COconversion.CHis the most thermodynamically favorable among all considered alkynes under different temperatures and pressures.The thermodynamic calculations are validated with experimental results,suggesting that the Gibbs free energy minimization method is effective for thermodynamically understanding the reaction network involved in the COhydrogenation process,which is helpful for the development of high-performance catalysts.
基金supported by the Centre of Excellence in Water Resources Engineering, University of Engineering and Technology Lahore, and local authorities in Pakistan
文摘The Soil and Water Assessment Tool （SWAT） was implemented in a small forested watershed of the Soan River Basin innorthern Pakistan through application of the sequential uncertainty fitting （SUFI-2） method to investigate the associateduncertainty in runoff and sediment load estimation. The model was calibrated for a 10-year period （1991–2000） with aninitial 4-year warm-up period （1987–1990）, and was validated for the subsequent 10-year period （2001–2010）. Themodel evaluation indices R2 （the coefficient of determination）, NS （the Nash-Sutcliffe efficiency）, and PBIAS （percentbias） for stream flows simulation indicated that there was a good agreement between the measured and simulated flows.To assess the uncertainty in the model outputs, p-factor （a 95% prediction uncertainty, 95PPU） and r-factors （averagewideness width of the 95PPU band divided by the standard deviation of the observed values） were taken into account.The 95PPU band bracketed 72% of the observed data during the calibration and 67% during the validation. The r-factorwas 0.81 during the calibration and 0.68 during the validation. For monthly sediment yield, the model evaluation coefficients（R2 and NS） for the calibration were computed as 0.81 and 0.79, respectively; for validation, they were 0.78and 0.74, respectively. Meanwhile, the 95PPU covered more than 60% of the observed sediment data during calibrationand validation. Moreover, improved model prediction and parameter estimation were observed with the increasednumber of iterations. However, the model performance became worse after the fourth iterations due to an unreasonableparameter estimation. Overall results indicated the applicability of the SWAT model with moderate levels of uncertaintyduring the calibration and high levels during the validation. Thus, this calibrated SWAT model can be used for assessmentof water balance components, climate change studies, and land use management practices.
文摘Input-output analysis is widely employed to analyze inventories of a product＇s embodied energy and environmental burdens. However, input-output analysis focuses only on the production stage and ignores other life cycle phases. Input-output analysis is not exactly a LCA （life cycle assessment） method in the strict sense of ISO 14040 standards, which must cover all stages of a product＇s life cycle, ＂from the cradle to the grave＂, so to speak. A tiered hybrid LCA is a useful tool that covers all life cycle stages by combining a process analysis with the input-output analysis method. This study aims to extend input-output analysis to the use, disposal, and recycling stages by using matrix-based method. The new method is applied to the analysis of the embodied CO2 emissions of a refrigerator as a case study. The entire life cycle C02 emissions are estimated to be 2.9 tons, including indirect emissions, and the reduction in CO2 emissions due to recycling steel scrap is calculated as 48.5 kg. The authors conclude that the new method enables a consistent inventory analysis for all life cycle stages by combining process and input-output methods.
基金the Service of Cooperation and Cultural Action of the Embassy of France for financial support
文摘A spectrofluorimetric method for the direct analysis of carbendazim [methyl 2-benzimidazole carbamate (MBC)] fungicide and its metabolite 2-aminobenzimidazole (2-AB) in natural waters is described. Very low limit of detection (LOD) and limit of quantification (LOQ) values of 0.002 - 0.06 ng/mL and 0.006 - 0.2 ng/mL, respectively, were determined by spectrofluorimetric method with small relative standard deviation (RSD) values < 1%. This spectrofluorimetric method was applied to the determination of MBC and 2-AB residues in natural waters, with satisfactory recovery values of (88.5% - 119.2%).
基金supported by the Young Scientists Fund of the National Natural Science Foundation of China(Grant No.51205283)
文摘This paper introduced the basic theory and algorithm of the surrogate data method, which proposed a rigorous way to detect the random and seemingly stochastic characteristics in a system. The Gaussian data and the Rossler data were used to show the availability and effectivity of this method. According to the analysis by this method based on the short-circuiting current signals under the conditions of the same voltage and different wire feed speeds, it is demonstrated that the electrical signals time series exhibit apparently randomness when the welding parameters do not match. However, the electrical signals time series are deterministic when a match is found. The stability of short-circuiting transfer process could be judged exactly by the method of surrogate data.
文摘In Europe, computation of displacement demand for seismic assessment of existing buildings is essentially based on a simplified formulation of the N2 method as prescribed by Eurocode 8(EC8). However, a lack of accuracy of the N2 method in certain conditions has been pointed out by several studies. This paper addresses the assessment of effectiveness of the N2 method in seismic displacement demand determination in non-linear domain. The objective of this work is to investigate the accuracy of the N2 method through comparison with displacement demands computed using non-linear timehistory analysis(NLTHA). Results show that the original N2 method may lead to overestimation or underestimation of displacement demand predictions. This may affect results of mechanical model-based assessment of seismic vulnerability at an urban scale. Hence, the second part of this paper addresses an improvement of the N2 method formula by empirical evaluation of NLTHA results based on EC8 ground-classes. This task is formulated as a mathematical programming problem in which coefficients are obtained by minimizing the overall discrepancy between NLTHA and modified formula results. Various settings of the mathematical programming problem have been solved using a global optimization metaheuristic. An extensive comparison between the original N2 method formulation and optimized formulae highlights benefits of the strategy.
