The title compound(C23H22N2O)3 has been synthesized by the reaction of(S)-(-)-1,1-diphenyl-2-pyrrolidinemethanol 1 with 2-pyridinecarboxaldehyde 2 in refluxing benzene catalyzed by TsOH,and its structure was determine...The title compound(C23H22N2O)3 has been synthesized by the reaction of(S)-(-)-1,1-diphenyl-2-pyrrolidinemethanol 1 with 2-pyridinecarboxaldehyde 2 in refluxing benzene catalyzed by TsOH,and its structure was determined by single-crystal X-ray diffraction.The crystal belongs to orthorhombic,space group P212121 with a=8.4747(8),b=10.8829(10),c=19.777(2),Mr=342.43,V=1824.0(3)3,Dc=1.247 g/cm3,Z=4,m=0.077 mm-1 and F(000)=728.The structure was solved by direct methods and refined by full-matrix least-squares techniques to the final R=0.0497 and wR=0.0927.展开更多
基金the National Natural Science Foundation of China (No. 20172039)
文摘The title compound(C23H22N2O)3 has been synthesized by the reaction of(S)-(-)-1,1-diphenyl-2-pyrrolidinemethanol 1 with 2-pyridinecarboxaldehyde 2 in refluxing benzene catalyzed by TsOH,and its structure was determined by single-crystal X-ray diffraction.The crystal belongs to orthorhombic,space group P212121 with a=8.4747(8),b=10.8829(10),c=19.777(2),Mr=342.43,V=1824.0(3)3,Dc=1.247 g/cm3,Z=4,m=0.077 mm-1 and F(000)=728.The structure was solved by direct methods and refined by full-matrix least-squares techniques to the final R=0.0497 and wR=0.0927.
