The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor ...The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor featuring a broad spectral absorption range,is successfully employed as the electron acceptor to combine with CdS for constructing a S-scheme heterojunction.The optimized photocatalyst(CdSCuO2∶1)delivers an exceptional hydrogen evolution rate of 18.89 mmol/(g·h),4.15-fold higher compared with bare CdS.X-ray photoelectron spectroscopy(XPS)and ultraviolet-visible diffuse reflection absorption spectroscopy(UV-vis DRS)confirmed the S-scheme band structure of the composites.Moreover,the surface photovoltage(SPV)and electron paramagnetic resonance(EPR)indicated that the photogenerated electrons and photogenerated holes of CdS-CuO2∶1 were respectively transferred to the conduction band(CB)of CdS with a higher reduction potential and the valence band(VB)of CuO with a higher oxidation potential under illumination,as expected for the S-scheme mechanism.Density-functional-theory calculations of the electron density difference(EDD)disclose an interfacial electric field oriented from CdS to CuO.This built-in field suppresses charge recombination and accelerates carrier migration,rationalizing the markedly enhanced PHE activity.This study offers a novel strategy for designing S-scheme heterojunctions with high light harvesting and charge utilization toward sustainable solar-tohydrogen conversion.展开更多
多智能体信息融合(multi-agent information fusion,MAIF)系统主要面向多个智能体之间的信息融合、调节、交流和矛盾处理。研究针对数据高度冲突条件下的D-S证据理论失效问题,提出一种将重构的基本概率分配和信念熵相结合的多智能体系...多智能体信息融合(multi-agent information fusion,MAIF)系统主要面向多个智能体之间的信息融合、调节、交流和矛盾处理。研究针对数据高度冲突条件下的D-S证据理论失效问题,提出一种将重构的基本概率分配和信念熵相结合的多智能体系统冲突数据融合方法。该方法使用重构的基本概率分配和信念熵修正证据的可靠性,获得更合理的证据,使用Dempster组合规则将证据进行融合得到结果,在2个实验中均得到了超过90%的置信度。实验表明了该方法的有效性,提高了MAIF系统辨识过程的精度。展开更多
文摘The efficiency and stability of catalysts for photocatalytic hydrogen evolution(PHE)are largely governed by the charge transfer behaviors across the heterojunction interfaces.In this study,CuO,a typical semiconductor featuring a broad spectral absorption range,is successfully employed as the electron acceptor to combine with CdS for constructing a S-scheme heterojunction.The optimized photocatalyst(CdSCuO2∶1)delivers an exceptional hydrogen evolution rate of 18.89 mmol/(g·h),4.15-fold higher compared with bare CdS.X-ray photoelectron spectroscopy(XPS)and ultraviolet-visible diffuse reflection absorption spectroscopy(UV-vis DRS)confirmed the S-scheme band structure of the composites.Moreover,the surface photovoltage(SPV)and electron paramagnetic resonance(EPR)indicated that the photogenerated electrons and photogenerated holes of CdS-CuO2∶1 were respectively transferred to the conduction band(CB)of CdS with a higher reduction potential and the valence band(VB)of CuO with a higher oxidation potential under illumination,as expected for the S-scheme mechanism.Density-functional-theory calculations of the electron density difference(EDD)disclose an interfacial electric field oriented from CdS to CuO.This built-in field suppresses charge recombination and accelerates carrier migration,rationalizing the markedly enhanced PHE activity.This study offers a novel strategy for designing S-scheme heterojunctions with high light harvesting and charge utilization toward sustainable solar-tohydrogen conversion.
文摘多智能体信息融合(multi-agent information fusion,MAIF)系统主要面向多个智能体之间的信息融合、调节、交流和矛盾处理。研究针对数据高度冲突条件下的D-S证据理论失效问题,提出一种将重构的基本概率分配和信念熵相结合的多智能体系统冲突数据融合方法。该方法使用重构的基本概率分配和信念熵修正证据的可靠性,获得更合理的证据,使用Dempster组合规则将证据进行融合得到结果,在2个实验中均得到了超过90%的置信度。实验表明了该方法的有效性,提高了MAIF系统辨识过程的精度。
