The importance of equations of state (EOS) has brought about the proliferation of hundreds of EOS. Nearly all prevailing cubic EOS could be regarded as the results of reforming the original vdW EOS. However, the accur...The importance of equations of state (EOS) has brought about the proliferation of hundreds of EOS. Nearly all prevailing cubic EOS could be regarded as the results of reforming the original vdW EOS. However, the accuracy of the vdW EOS is so low. In view of this, a new general equation is proposed that could be used to value or compare vdW type of EOS, and consequently develop a better vdW type of EOS.展开更多
A new approach to the investigation of vdW type of equations of state (EOS) is developed by embedding a vapor pressure equation and a saturated liquid volume equation into vdW type EOS, which results in a new function...A new approach to the investigation of vdW type of equations of state (EOS) is developed by embedding a vapor pressure equation and a saturated liquid volume equation into vdW type EOS, which results in a new function AS(T). The AS(T) possesses the properties of an attractive parameter A(T), and if an EOS is accurate in the whole PVT space, then its numerical value equals A(T). As a useful tool for investigating EOS, the As(T) has been used to make comparisons among RKS, PRSVII, PT and ALS EOS, and to indicate where the shortcomings of the EOS are coming from. Based on the AS(T), a possible way to develop a real predictive equation of state is also suggested.展开更多
从液体的等容线近似是直线的事实出发,通过对原始van der Waals模型中排斥体积的修正,建立了一个液体状态方程式:式中A、B、α和β是四个与温度无关的特性常数。其中A和B彼此相关,都仅是分子大小的函数,α与分子间力的类型有关,β则取...从液体的等容线近似是直线的事实出发,通过对原始van der Waals模型中排斥体积的修正,建立了一个液体状态方程式:式中A、B、α和β是四个与温度无关的特性常数。其中A和B彼此相关,都仅是分子大小的函数,α与分子间力的类型有关,β则取决于分子间力的“偏心”程度。检验表明,这个状态方程能满意地计算压缩液体的摩尔体积。展开更多
文摘The importance of equations of state (EOS) has brought about the proliferation of hundreds of EOS. Nearly all prevailing cubic EOS could be regarded as the results of reforming the original vdW EOS. However, the accuracy of the vdW EOS is so low. In view of this, a new general equation is proposed that could be used to value or compare vdW type of EOS, and consequently develop a better vdW type of EOS.
文摘A new approach to the investigation of vdW type of equations of state (EOS) is developed by embedding a vapor pressure equation and a saturated liquid volume equation into vdW type EOS, which results in a new function AS(T). The AS(T) possesses the properties of an attractive parameter A(T), and if an EOS is accurate in the whole PVT space, then its numerical value equals A(T). As a useful tool for investigating EOS, the As(T) has been used to make comparisons among RKS, PRSVII, PT and ALS EOS, and to indicate where the shortcomings of the EOS are coming from. Based on the AS(T), a possible way to develop a real predictive equation of state is also suggested.
文摘从液体的等容线近似是直线的事实出发,通过对原始van der Waals模型中排斥体积的修正,建立了一个液体状态方程式:式中A、B、α和β是四个与温度无关的特性常数。其中A和B彼此相关,都仅是分子大小的函数,α与分子间力的类型有关,β则取决于分子间力的“偏心”程度。检验表明,这个状态方程能满意地计算压缩液体的摩尔体积。
