The practical deployment of aqueous zinc metal batteries(AZMBs)is critically challenged by uncontrolled dendrite formation and parasitic side reactions,both arising from unstable interfacial chemistry.Herein,we propos...The practical deployment of aqueous zinc metal batteries(AZMBs)is critically challenged by uncontrolled dendrite formation and parasitic side reactions,both arising from unstable interfacial chemistry.Herein,we propose a dual-region interfacial engineering strategy that concurrently regulates both the outer and inner Helmholtz planes(OHP/IHP)by introducing the N,N-dimethylethanolamine(DMEA)into the ZnSO_(4) electrolyte.In the OHP,DMEA coordinates with Zn^(2+)to reshape the solvation structure and attenuate Zn^(2+)-H_(2)O interactions,thereby lowering water activity and suppressing hydrogen evolution.Meanwhile,DMEA molecules chemisorb onto the Zn surface within the IHP,forming a robust organic interphase that homogenizes the electric field and promotes uniform Zn nucleation.This dual functionality guides crystallographic evolution toward the thermodynamically favorable(101)facet,which supports lateral Zn growth and effectively mitigates dendrite propagation.Benefiting from the interfacial-crystallographic synergy,Zn‖Zn symmetric cells exhibit ultralong cycling stability over5000 h at 1 mA cm^(-2) and maintain dendrite-free operation for over 1000 h at 5 mA cm^(-2).Furthermore,Zn‖NH_(4)V_(4)O_(10) full cells deliver high specific capacities with 80.06%capacity retention after1000 cycles at 5 A g^(-1).This work offers a mechanistically guided and scalable electrolyte design that bridges solvation chemistry with crystallographic control,providing a promising route toward dendrite-free,high-efficiency AZMBs.展开更多
The adsorptive denitrification performance of MIL-101(Cr)-0.5 toward pyridine,aniline or quinoline in simulated fuels with basic nitrogen content of 1732μg/g was evaluated separately.Furthermore,the effects of adsorp...The adsorptive denitrification performance of MIL-101(Cr)-0.5 toward pyridine,aniline or quinoline in simulated fuels with basic nitrogen content of 1732μg/g was evaluated separately.Furthermore,the effects of adsorption temperature,adsorption time and adsorbent dosage on their adsorptive denitrification performance were systematically investigated.The experimental results demonstrated that under a fixed adsorbent dosage of 0.05 g and a simulated fuel volume of 10 mL,the optimal removal efficiency for aniline was achieved at 30℃ within 30 min,whereas higher temperatures and longer times(40℃and 40 min)were required for effective removal of pyridine and quinoline.Density Functional Theory(DFT)calculations were conducted via Materials Studio(MS)software to study the adsorptive denitrification mechanism of MIL-101(Cr)toward these three basic nitrogen-containing compounds.The simulation calculation results revealed that the interaction between pyridine and MIL-101(Cr)primarily involved coordination adsorption.In contrast,the interaction between aniline or quinoline and MIL-101(Cr)proceeded mainly through coordination,with additional contributions fromπ-complexation and hydrogen bonding.The overall adsorption strength order is pyridine>aniline>quinoline.During the adsorption process,pyridine and quinoline transfer electrons to the MIL-101(Cr)surface through the H→C→N→Cr^(3+)pathway,while aniline transfers electrons to the MIL-101(Cr)surface through various pathways,including N→Cr^(3+),N→C→Cr^(3+)and N→H→O.Furthermore,adsorption kinetics studies indicated that the adsorption processes for all three basic nitrogen-containing compounds followed the quasi second order kinetic models.The experimental results on the effect of benzene on the adsorptive denitrification performance of MIL-101(Cr)-0.5 demonstrated that benzene exerted a more significant impact on the adsorption of aniline and quinoline.Finally,the adsorbent was regenerated using ethanol washing.It was found that MIL-101(Cr)-0.5 retained stable denitrification performance after two regeneration cycles.展开更多
Near-infrared image sensors are widely used in fields such as material identification,machine vision,and autonomous driving.Lead sulfide colloidal quantum dot-based infrared photodiodes can be integrated with sil⁃icon...Near-infrared image sensors are widely used in fields such as material identification,machine vision,and autonomous driving.Lead sulfide colloidal quantum dot-based infrared photodiodes can be integrated with sil⁃icon-based readout circuits in a single step.Based on this,we propose a photodiode based on an n-i-p structure,which removes the buffer layer and further simplifies the manufacturing process of quantum dot image sensors,thus reducing manufacturing costs.Additionally,for the noise complexity in quantum dot image sensors when capturing images,traditional denoising and non-uniformity methods often do not achieve optimal denoising re⁃sults.For the noise and stripe-type non-uniformity commonly encountered in infrared quantum dot detector imag⁃es,a network architecture has been developed that incorporates multiple key modules.This network combines channel attention and spatial attention mechanisms,dynamically adjusting the importance of feature maps to en⁃hance the ability to distinguish between noise and details.Meanwhile,the residual dense feature fusion module further improves the network's ability to process complex image structures through hierarchical feature extraction and fusion.Furthermore,the pyramid pooling module effectively captures information at different scales,improv⁃ing the network's multi-scale feature representation ability.Through the collaborative effect of these modules,the network can better handle various mixed noise and image non-uniformity issues.Experimental results show that it outperforms the traditional U-Net network in denoising and image correction tasks.展开更多
The Cooling-Storage-Ring External-target Experiment(CEE)at the Heavy Ion Research Facility in Lanzhou(HIRFL)is designed to study the properties of nuclear matter created in heavy-ion collisions at beam energies from a...The Cooling-Storage-Ring External-target Experiment(CEE)at the Heavy Ion Research Facility in Lanzhou(HIRFL)is designed to study the properties of nuclear matter created in heavy-ion collisions at beam energies from a few hundred MeV/u up to 1 GeV/u.It aims to facilitate research on the quantum chromodynamics(QCD)phase structure in the high-baryondensity region.Collective flow is a fundamental observable in heavy-ion collision experiments,providing information on the bulk properties of the produced matter.Although the standard event plane method has been widely used to measure collective flow,it is still important to validate and optimize this method for the CEE spectrometer.In this paper,we study the experimental procedures for measuring directed flow in^(238)U+^(238)U collisions at 500 MeV/u,using event planes reconstructed by Multi-Wire Drift Chamber and Zero Degree Calorimeter,respectively.Jet AA Microscopic(JAM)transport generator is used to generate events,and the detector response is simulated by the CEE Fast Simulation(CFS)package.Finally,the optimal kinematic region for proton directed flow measurements is discussed for the future CEE experiment.展开更多
The advent of artificial intelligence(AI)has propelled augmented reality(AR)display technology to a pivotal juncture,positioning it as a contender for the next generation of mobile intelligent terminals.However,the pu...The advent of artificial intelligence(AI)has propelled augmented reality(AR)display technology to a pivotal juncture,positioning it as a contender for the next generation of mobile intelligent terminals.However,the pursuit of advanced AR displays,particularly those capable of delivering immersive 3D experiences,is significantly hindered by the performance limitations of current hardware and the complexity of system integration.In this study,we present an innovative multi-focal plane AR display system that integrates a non-orthogonal polarization-multiplexing metasurface,freeform optical elements,and an OLED display screen.All optical elements are integrated into a single solid-state architecture,based on a joint optimization design approach of ray tracing and diffraction theory.The multi-focal plane AR visual effect is realized by the compact and multiplexing metasurface,which performs distinct phase functions across diverse polarization channels.Meanwhile,freeform surfaces offer ample design flexibility for the collaborative optimization of multi-focal plane imaging and the see-through systems.Followed by a mechanical design and prototype assembly,we demonstrate the system's capabilities in real-time and multi-focal plane display.The digital images at all virtual image distances seamlessly integrate with the real environment,fully exhibiting the system's high parallelism and real-time interactivity.With the innovative design concept and joint design method,we believe that our work will spur more innovative and compact intelligent solutions for AR displays and inject new vitality into hybrid optical systems.展开更多
基金the financial support from the Scientific Research Fund of Liaoning Provincial Education Department of China(No.JYTQN2023289)the Liaoning Provincial Science and Technology Joint Plan(Fund)Project(No.2023BSBA-259)+4 种基金the opening project of State Key Laboratory of Metastable Materials Science and Technology,Yanshan University(No.202404)the support from the National Natural Science Foundation of China(Grant No.52402279)the China Postdoctoral Science Foundation Special Funding(Grant No.T2025T180002)the China Postdoctoral Science Foundation General Program(Grant No.2024M751753)the opening project of State Key Laboratory of Metastable Materials Science and Technology(Yanshan University)(No.202401)。
文摘The practical deployment of aqueous zinc metal batteries(AZMBs)is critically challenged by uncontrolled dendrite formation and parasitic side reactions,both arising from unstable interfacial chemistry.Herein,we propose a dual-region interfacial engineering strategy that concurrently regulates both the outer and inner Helmholtz planes(OHP/IHP)by introducing the N,N-dimethylethanolamine(DMEA)into the ZnSO_(4) electrolyte.In the OHP,DMEA coordinates with Zn^(2+)to reshape the solvation structure and attenuate Zn^(2+)-H_(2)O interactions,thereby lowering water activity and suppressing hydrogen evolution.Meanwhile,DMEA molecules chemisorb onto the Zn surface within the IHP,forming a robust organic interphase that homogenizes the electric field and promotes uniform Zn nucleation.This dual functionality guides crystallographic evolution toward the thermodynamically favorable(101)facet,which supports lateral Zn growth and effectively mitigates dendrite propagation.Benefiting from the interfacial-crystallographic synergy,Zn‖Zn symmetric cells exhibit ultralong cycling stability over5000 h at 1 mA cm^(-2) and maintain dendrite-free operation for over 1000 h at 5 mA cm^(-2).Furthermore,Zn‖NH_(4)V_(4)O_(10) full cells deliver high specific capacities with 80.06%capacity retention after1000 cycles at 5 A g^(-1).This work offers a mechanistically guided and scalable electrolyte design that bridges solvation chemistry with crystallographic control,providing a promising route toward dendrite-free,high-efficiency AZMBs.
基金Supported by Basic Scientific Research Project of the Liaoning Provincial Department of Education Has Been Unveiled to Facilitate Local Project Funding (JYTMS20230835)Enhanced Scientific Research Project Funded by the Departmentof Higher Education in Liaoning Province (General program)(JYTMS20230852)。
文摘The adsorptive denitrification performance of MIL-101(Cr)-0.5 toward pyridine,aniline or quinoline in simulated fuels with basic nitrogen content of 1732μg/g was evaluated separately.Furthermore,the effects of adsorption temperature,adsorption time and adsorbent dosage on their adsorptive denitrification performance were systematically investigated.The experimental results demonstrated that under a fixed adsorbent dosage of 0.05 g and a simulated fuel volume of 10 mL,the optimal removal efficiency for aniline was achieved at 30℃ within 30 min,whereas higher temperatures and longer times(40℃and 40 min)were required for effective removal of pyridine and quinoline.Density Functional Theory(DFT)calculations were conducted via Materials Studio(MS)software to study the adsorptive denitrification mechanism of MIL-101(Cr)toward these three basic nitrogen-containing compounds.The simulation calculation results revealed that the interaction between pyridine and MIL-101(Cr)primarily involved coordination adsorption.In contrast,the interaction between aniline or quinoline and MIL-101(Cr)proceeded mainly through coordination,with additional contributions fromπ-complexation and hydrogen bonding.The overall adsorption strength order is pyridine>aniline>quinoline.During the adsorption process,pyridine and quinoline transfer electrons to the MIL-101(Cr)surface through the H→C→N→Cr^(3+)pathway,while aniline transfers electrons to the MIL-101(Cr)surface through various pathways,including N→Cr^(3+),N→C→Cr^(3+)and N→H→O.Furthermore,adsorption kinetics studies indicated that the adsorption processes for all three basic nitrogen-containing compounds followed the quasi second order kinetic models.The experimental results on the effect of benzene on the adsorptive denitrification performance of MIL-101(Cr)-0.5 demonstrated that benzene exerted a more significant impact on the adsorption of aniline and quinoline.Finally,the adsorbent was regenerated using ethanol washing.It was found that MIL-101(Cr)-0.5 retained stable denitrification performance after two regeneration cycles.
基金Supported by the National key research and development program in the 14th five year plan 2021YFA1200700)the National Natural Science Foundation of China(62535018,62431025,62561160113)the Natural Science Foundation of Shanghai(23ZR1473400).
文摘Near-infrared image sensors are widely used in fields such as material identification,machine vision,and autonomous driving.Lead sulfide colloidal quantum dot-based infrared photodiodes can be integrated with sil⁃icon-based readout circuits in a single step.Based on this,we propose a photodiode based on an n-i-p structure,which removes the buffer layer and further simplifies the manufacturing process of quantum dot image sensors,thus reducing manufacturing costs.Additionally,for the noise complexity in quantum dot image sensors when capturing images,traditional denoising and non-uniformity methods often do not achieve optimal denoising re⁃sults.For the noise and stripe-type non-uniformity commonly encountered in infrared quantum dot detector imag⁃es,a network architecture has been developed that incorporates multiple key modules.This network combines channel attention and spatial attention mechanisms,dynamically adjusting the importance of feature maps to en⁃hance the ability to distinguish between noise and details.Meanwhile,the residual dense feature fusion module further improves the network's ability to process complex image structures through hierarchical feature extraction and fusion.Furthermore,the pyramid pooling module effectively captures information at different scales,improv⁃ing the network's multi-scale feature representation ability.Through the collaborative effect of these modules,the network can better handle various mixed noise and image non-uniformity issues.Experimental results show that it outperforms the traditional U-Net network in denoising and image correction tasks.
基金supported in part by the National Key R&D Program of China(No.2024YFA1610700)the National Natural Science Foundation of China(No.12475147)。
文摘The Cooling-Storage-Ring External-target Experiment(CEE)at the Heavy Ion Research Facility in Lanzhou(HIRFL)is designed to study the properties of nuclear matter created in heavy-ion collisions at beam energies from a few hundred MeV/u up to 1 GeV/u.It aims to facilitate research on the quantum chromodynamics(QCD)phase structure in the high-baryondensity region.Collective flow is a fundamental observable in heavy-ion collision experiments,providing information on the bulk properties of the produced matter.Although the standard event plane method has been widely used to measure collective flow,it is still important to validate and optimize this method for the CEE spectrometer.In this paper,we study the experimental procedures for measuring directed flow in^(238)U+^(238)U collisions at 500 MeV/u,using event planes reconstructed by Multi-Wire Drift Chamber and Zero Degree Calorimeter,respectively.Jet AA Microscopic(JAM)transport generator is used to generate events,and the detector response is simulated by the CEE Fast Simulation(CFS)package.Finally,the optimal kinematic region for proton directed flow measurements is discussed for the future CEE experiment.
基金funding provided by National Natural Science Foundation of China(U21A20140)National Key Research and Development Program of China(2021YFA1401200)+2 种基金Beijing Natural Science Foundation(JQ24028)Beijing Nova Program(20240484557)Synergetic Extreme Condition User Facility(SECUF).
文摘The advent of artificial intelligence(AI)has propelled augmented reality(AR)display technology to a pivotal juncture,positioning it as a contender for the next generation of mobile intelligent terminals.However,the pursuit of advanced AR displays,particularly those capable of delivering immersive 3D experiences,is significantly hindered by the performance limitations of current hardware and the complexity of system integration.In this study,we present an innovative multi-focal plane AR display system that integrates a non-orthogonal polarization-multiplexing metasurface,freeform optical elements,and an OLED display screen.All optical elements are integrated into a single solid-state architecture,based on a joint optimization design approach of ray tracing and diffraction theory.The multi-focal plane AR visual effect is realized by the compact and multiplexing metasurface,which performs distinct phase functions across diverse polarization channels.Meanwhile,freeform surfaces offer ample design flexibility for the collaborative optimization of multi-focal plane imaging and the see-through systems.Followed by a mechanical design and prototype assembly,we demonstrate the system's capabilities in real-time and multi-focal plane display.The digital images at all virtual image distances seamlessly integrate with the real environment,fully exhibiting the system's high parallelism and real-time interactivity.With the innovative design concept and joint design method,we believe that our work will spur more innovative and compact intelligent solutions for AR displays and inject new vitality into hybrid optical systems.
