Single-atom nanozymes(SAzymes)exhibit exceptional catalytic efficiency due to their maximized atom utilization and precisely modulated metalcarrier interactions,which have attracted significant attention in the biomed...Single-atom nanozymes(SAzymes)exhibit exceptional catalytic efficiency due to their maximized atom utilization and precisely modulated metalcarrier interactions,which have attracted significant attention in the biomedical field.However,stability issues may impede the clinical translation of SAzymes.This review provides a comprehensive overview of the applications of SAzymes in various biomedical fields,including disease diagnosis(e.g.,biosensors and diagnostic imaging),antitumor therapy(e.g.,photothermal therapy,photodynamic therapy,sonodynamic therapy,and immunotherapy),antimicrobial therapy,and anti-oxidative stress therapy.More importantly,the existing challenges of SAzymes are discussed,such as metal atom clustering and active site loss,ligand bond breakage at high temperature,insufficient environment tolerance,biosecurity risks,and limited catalytic long-term stability.Finally,several innovative strategies to address these stability concerns are proposed—synthesis process optimization(space-limited strategy,coordination site design,bimetallic synergistic strategy,defect engineering strategy,atom stripping-capture),surface modification,and dynamic responsive design—that collectively pave the way for robust,clinically viable SAzymes.展开更多
Selective catalytic reduction with NH3(NH3-SCR)is an important means of NO_(x) abatement from stationary and mobile sources,and the key element is efficient and stable NH3-SCR catalysts.In this study,we propose a meth...Selective catalytic reduction with NH3(NH3-SCR)is an important means of NO_(x) abatement from stationary and mobile sources,and the key element is efficient and stable NH3-SCR catalysts.In this study,we propose a method to construct superior Fe-Beta catalysts based on Al-rich zeolites.This strategy successfully promotes the formation of NH3-SCR-active isolated Fe^(3+)species,thus effectively improving the low-temperature activity of the Fe-Beta catalysts.Thanks to the abundant Brønsted acid sites of the Al-rich zeolite,the Fe_(2)O_(3) particles are redispersed and anchored as isolated Fe^(3+)during hydrothermal aging.This dynamic evolution of Fe species makes up for the adverse effect of dealumination of the Al-rich zeolite framework and achieves high stability for the Al-rich Fe-Beta catalyst.This study may promote the understanding of highly efficient and stable catalyst design using Al-rich zeolites.展开更多
MnO_(x)-CeO_(2)catalysts for the low-temperature selective catalytic reduction(SCR)of NO remain vulnerable to water and sulfur poisoning,limting their practical applications.Herein,we report a hydrophobic-modified MnO...MnO_(x)-CeO_(2)catalysts for the low-temperature selective catalytic reduction(SCR)of NO remain vulnerable to water and sulfur poisoning,limting their practical applications.Herein,we report a hydrophobic-modified MnO_(x)-CeO_(2)catalyst that achieves enhanced NO conversion rate and stability under harsh conditions.The catalyst was synthesized by decorating MnOx crystals with amorphous CeO_(2),followed by loading hydrophobic silica on the external surfaces.The hydrophobic silica allowed the adsorption of NH_(3)and NO and diffusion of H,suppressed the adsorption of H_(2)O,and prevented SO_(2)interaction with the Mn active sites,achieving selective molecular discrimination at the catalyst surface.At 120℃,under H_(2)O and SO_(2)exposure,the optimal hydrophobic catalyst maintains 82%NO conversion rate compared with 69%for the unmodified catalyst.The average adsorption energies of NH_(3),H_(2)O,and SO_(2)decreased by 0.05,0.43,and 0.52 eV,respectively.The NO reduction pathway follows the Eley-Rideal mechanism,NH_(3)^(*)+*→NH_(2)^(*)+H^(*)followed by NH_(2)^(*)+NO^(*)→N_(2)^(*)+H_(2)O^(*),with NH_(3)dehydrogenation being the rate determining step.Hydrophobic modification increased the activation energy for H atom transfer,leading to a minor decrease in the NO conversion rate at 120℃.This work demonstrates a viable strategy for developing robust NH_(3)-S CR catalysts capable of efficient operation in water-and sulfur-rich environments.展开更多
AIM:To investigate age-related differences in the irislens angle(ILA)among patients with age-related cortical cataracts and elucidate the impact of age on lens stability.METHODS:A prospective observational study was c...AIM:To investigate age-related differences in the irislens angle(ILA)among patients with age-related cortical cataracts and elucidate the impact of age on lens stability.METHODS:A prospective observational study was conducted on patients with age-related cortical cataracts scheduled for phacoemulsification surgery.Preoperative ultrasound biomicroscopy(UBM)images were collected and analyzed.Initially,patients were stratified into two age groups:<60y and≥60y,with no significant intergroup differences in sex or eye laterality.For further analysis,participants were subdivided into three age strata:<60y,60-75y,and>75y.The ILA was measured in four quadrants(superior,inferior,nasal,and temporal).Intergroup differences in ILA were compared,and correlations between age and ILA parameters were analyzed using statistical methods.RESULTS:The sample data were categorized into three groups according to age,<60y(113 patients;55.8%female),60–75y(245 patients;61.0%female),and>75y(70 patients;50.2%female).The superior quadrant ILA increased progressively with age stratification(P=0.02),and the maximum ILA difference(ΔILA)was significantly higher in patients over 75y(P<0.01).Simple linear regression analysis demonstrated a positive correlation between age and ILA in the superior(Y=7.487+0.096X,R=0.191,P<0.001)and temporal(Y=10.254+0.052X,R=0.104,P=0.032)quadrants.Additionally,the mean ILA across all quadrants(ILAmean)andΔILA were positively correlated with age(ILAmean:Y=9.721+0.055X,R=0.138,P=0.004;ΔILA:Y=3.267+0.044X,R=0.006,P<0.05).CONCLUSION:In patients with age-related cortical cataracts,ILA increases with age,particularly in the superior and temporal quadrants,suggesting that advanced age is associated with greater lens deviation and decreased lens stability.UBM imaging can effectively evaluate the status of the zonule and lens stability,providing crucial evidence for personalized surgical planning based on patients’age.展开更多
The outstanding performance of O3-type NaNi_(1/3)Fe_(1/3)Mn_(1/3)O_(2)(NFM111)at both high and low temperatures coupled with its impressive specific capacity makes it an excellent cathode material for sodium-ion batte...The outstanding performance of O3-type NaNi_(1/3)Fe_(1/3)Mn_(1/3)O_(2)(NFM111)at both high and low temperatures coupled with its impressive specific capacity makes it an excellent cathode material for sodium-ion batteries.However,its poor cycling,owing to highpressure phase transitions,is one of its disadvantages.In this study,Cu/Ti was introduced into NFM111 cathode material using a solidphase method.Through both theoretically and experimentally,this study found that Cu doping provides a higher redox potential in NFM111,improving its reversible capacity and charge compensation process.The introduction of Ti would enhance the cycling stability of the material,smooth its charge and discharge curves,and suppress its high-voltage phase transitions.Accordingly,the NaNi_(0.27)Fe_(0.28)Mn_(0.33)Cu_(0.05)Ti_(0.06)O_(2)sample used in the study exhibited a remarkable rate performance of 142.97 mAh·g^(-1)at 0.1 C(2.0-4.2 V)and an excellent capacity retention of 72.81%after 300 cycles at 1C(1C=150 mA·g^(-1)).展开更多
Distinctness, Uniformity and Stability （DUS） testing is the technical base of Plant Variety Protection （PVP） and the scientific basis for the approval of Plant Breeder＇s Rights （PBR）. DUS Test Guidelines are no...Distinctness, Uniformity and Stability （DUS） testing is the technical base of Plant Variety Protection （PVP） and the scientific basis for the approval of Plant Breeder＇s Rights （PBR）. DUS Test Guidelines are not only the technical manuals for the DUS testing authorities to conduct the testing, but also the technical standards for the competent authorities to examine the DUS of new varieties of plants. Tea plant, originated from Yunnan Province, China, is a very important woody cash species in the world. The International Union for the Protection of New Varieties of Plants （UPOV） DUS Test Guidelines for tea plant is the first Test Guidelines prepared by China for the UPOV. In this article, the subject, selection, and determination of characteristics, states of expression of characteristics and the selection of example varieties, assessment of the UPOV DUS Test Guidelines for tea plant were elucidated in detail. Finally, the proposal of PVP for tea plant in China was also proposed. The preparation of UPOV DUS Test Guidelines for tea plant will have important significance both for promoting the development of PVP and increasing the status of international PVP fields for China.展开更多
In the area of control theory the time-delay systems have been investigated. It's well known that delays often result in instability, therefore, stability analysis of time-delay systems is an important subject in ...In the area of control theory the time-delay systems have been investigated. It's well known that delays often result in instability, therefore, stability analysis of time-delay systems is an important subject in control theory. As a result, many criteria for testing the stability of linear time-delay systems have been proposed. Significant progress has been made in the theory of impulsive systems and impulsive delay systems in recent years. However, the corresponding theory for uncertain impulsive systems and uncertain impulsive delay systems has not been fully developed. In this paper, robust stability criteria are established for uncertain linear delay impulsive systems by using Lyapunov function, Razumikhin techniques and the results obtained. Some examples are given to illustrate our theory.展开更多
In this letter,the Ti-doped NbO_(x)-based selector is applied to SiNOx-based resistive random-access memory(RRAM),forming Pt/NbOx(Ti-doped)/SiNO_(x)/Ti one selector-one RRAM device(1S1R),to suppress the sneak path cur...In this letter,the Ti-doped NbO_(x)-based selector is applied to SiNOx-based resistive random-access memory(RRAM),forming Pt/NbOx(Ti-doped)/SiNO_(x)/Ti one selector-one RRAM device(1S1R),to suppress the sneak path current.The fabricated 1S1R exhibits stable direct current(DC)endurance(>200 cycles),suitable memory window(>40),matched selectivity(>40)and high uniformity of switching parameters.展开更多
In this paper, an improved air discharge fluid model under non-uniform electric field is constructed based on the plasma module COMSOL Multiphysics with artificial stability term, and the boundary conditions developed...In this paper, an improved air discharge fluid model under non-uniform electric field is constructed based on the plasma module COMSOL Multiphysics with artificial stability term, and the boundary conditions developed in the previous paper are applied to the calculation of photoionization rate. Based on the modified model, the characteristics of low temperature subatmospheric air discharge under 13 kV direct current voltage are discussed, including needle-plate and needle-needle electrode structures. Firstly, in order to verify the reliability of the model, a numerical example and an experimental verification were carried out for the modified model respectively. Both verification results show that the model can ensure the accuracy and repeatability of the calculation. Secondly, according to the calculation results of the modified model, under the same voltage and spacing, the reduced electric field under low temperature subatmosphere pressure is larger than that under normal temperature and atmospheric pressure. The high electric field leads to the air discharge at low temperature and sub atmospheric pressure entering the streamer initiation stage earlier, and has a faster propagation speed in the streamer development stage, which shortens the overall discharge time. Finally, the discharge characteristics of the two electrode structures are compared, and it is found that the biggest difference between them is that there is a pre-ionization region near the cathode in the needle-needle electrode structure. When the pre-ionization level reaches 1013 cm-3, the propagation speed of the positive streamer remains unchanged throughout the discharge process, and is no longer affected by the negative streamer. The peak value of electric field decreases with the increase of pre-ionization level, and tends to be constant during streamer propagation. Based on the previous paper, this paper constructs the air discharge model under non-uniform electric field, complements with the previous paper, and forms a relatively complete set of air discharge simulation system under low temperature and sub atmospheric pressure, which provides a certain reference for future research.展开更多
New theorems of asymptotical stability and uniformly asymptotical stability for nonautonomous difference equations are given in this paper. The classical Liapunov asymptotical stability theorem of nonautonomous differ...New theorems of asymptotical stability and uniformly asymptotical stability for nonautonomous difference equations are given in this paper. The classical Liapunov asymptotical stability theorem of nonautonomous difference equations relies on the existence of a positive definite Liapunov function that has an indefinitely small upper bound and whose variation along a given nonautonomous difference equations is negative definite. In this paper, we consider the case that the Liapunov function is only positive definite and its variation is semi-negative definite. At these weaker conditions, we put forward a new asymptotical stability theorem of nonautonomous difference equations by adding to extra conditions on the variation. After that, in addition to the hypotheses of our new asymptotical stability theorem, we obtain a new uniformly asymptotical stability theorem of nonautonomous difference equations provided that the Liapunov function has an indefinitely small upper bound. Example is given to verify our results in the last.展开更多
In order to develop a basic electrode with low fume and good usability, a uew slag system has been designed after analyzing several basic electrode slag systems. Then in view of uniform design method, arranging the ex...In order to develop a basic electrode with low fume and good usability, a uew slag system has been designed after analyzing several basic electrode slag systems. Then in view of uniform design method, arranging the experiment points by it, the influenced laws of the uew system coating compouents on the arc stability had been searched. In the formula, niue coating compouents were taken as independent variables and they were divided into six levels in all twenty-four experiments. The arc stability was taken as function and taken down the data when welding and then put them into the computer to be processed statistically. The analysis results give the mathematical model and trend diagrams between independent variables and the function. They indicate that the effects of many coating compouents on the arc stability are in the mutual form. The mutual effects between CaCO3 and BaF2, BaF2 and BaCO3 , increases the arc stability separately. While the mutual effects between CaF2 and iron powder, the square item of iron powder itself decreases the arc stability separately.展开更多
The global uniform asymptotic stability of competitive neural networks with different time scales and delay is investigated. By the method of variation of parameters and the method of inequality analysis, the conditio...The global uniform asymptotic stability of competitive neural networks with different time scales and delay is investigated. By the method of variation of parameters and the method of inequality analysis, the condition for global uniformly asymptotically stable are given. A strict Lyapunov function for the flow of a competitive neural system with different time scales and delay is presented. Based on the function, the global uniform asymptotic stability of the equilibrium point can be proved.展开更多
Single-walled carbon nanotubes(SWCNTs)are receiving immense research attention due to their tremendous thermal,electrical,structural and mechanical properties.In this paper,an exact solution of the dynamic response of...Single-walled carbon nanotubes(SWCNTs)are receiving immense research attention due to their tremendous thermal,electrical,structural and mechanical properties.In this paper,an exact solution of the dynamic response of SWCNT with a moving uniformly distributed load is presented.The SWCNT is modelled via the theories of Bernoulli-Euler-thermal elasticity mechanics and solved using Integral transforms.The developed closed-form solution in the present work is compared with existing results and excellent agreements are established.The parametric studies show that as the magnitude of the pressure distribution at the surface increases,the deflection associated with the single walled nanotube increases at any mode whilst a corresponding increase in temperature and foundation parameter have an attenuating effect on deflection.Moreover,an increase in the Winkler parameter,as well as a decrease in the SWCNT mass increases its frequency of vibration.Furthermore,an increase in the speed of the external agent decreases the total external pressure as a result of the removal of dead loads.The present work is envisaged to improve the application of SWCNT as nanodevices for structural,electrical and mechanical systems.展开更多
With the aid of a thermal-electrical model, a practical method for designing multi-finger power heterojunction bipolar transistors with finger lengths divided in groups is proposed. The method can effectively enhance ...With the aid of a thermal-electrical model, a practical method for designing multi-finger power heterojunction bipolar transistors with finger lengths divided in groups is proposed. The method can effectively enhance the thermal stability of the devices without sacrificing the design time. Taking a 40-finger heterojunction bipolar transistor for example, the device with non-uniform emitter finger lengths is optimized and fabricated. Both the theoretical and the experimental results show that, for the optimum device, the peak temperature is lowered by 26.19 K and the maximum temperature difference is reduced by 56.67% when compared with the conventional heterojunction bipolar transistor with uniform emitter finger length. Furthermore, the ability to improve the uniformity of the temperature profile and to expand the thermal stable operation range is strengthened as the power level increases, which is ascribed to the improvement of the thermal resistance in the optimum device. A detailed design procedure is also summarized to provide a general guide for designing power heterojunction bipolar transistors with non-uniform finger lengths.展开更多
The linear stability of wall-injected pressure- driven Couette-like flow in power-law fluids is studied. Previous study on this kind of flow for Newtonian fluids by Nicoud and Angilella [Phys. Rev. E 56, 3000 （1997）...The linear stability of wall-injected pressure- driven Couette-like flow in power-law fluids is studied. Previous study on this kind of flow for Newtonian fluids by Nicoud and Angilella [Phys. Rev. E 56, 3000 （1997）] was extended to power-law fluids to understand the effects of shear-thinning/thickening nature on the flow stability. A related expression between the critical crossflow Reynolds number for Newtonian fluids and that for power-law fluids is obtained as the streamwise Reynolds number is large enough based on numerical computations, and verified theoretically in the case of a limiting condition with the power-law index.展开更多
In this paper, to begin with. the nonlinear differential equations of a truncaled shallow spherical shell with variable thickness under uniformal distributed load are linearized by step-by-step loading method. The lin...In this paper, to begin with. the nonlinear differential equations of a truncaled shallow spherical shell with variable thickness under uniformal distributed load are linearized by step-by-step loading method. The linear differential equations can be solved by spline collocanon method. Critical loads have been obtained accordingly.展开更多
Stability, boundedness and persistence are three important aspects for an ecological model. In this paper, a further analysis of a class of anaerobic digestion ecological models is performed. Based on the Liupunov Met...Stability, boundedness and persistence are three important aspects for an ecological model. In this paper, a further analysis of a class of anaerobic digestion ecological models is performed. Based on the Liupunov Method, the local stability of all equilibria in the system is got. According to the vector fields described by the system, the proof of the boundedness of the solution on the anaerobic digestion processes is completed in three steps. The method proposed in the discussion on the boundedness can be generalized to the similar problems. Results in this paper give information on how to run the ecological system well by adjusting the system parameters.展开更多
Fatty acids are the main constituents of vegetable oils.To determine the fatty acid compositions of small trade vegetable oils and some less well studied beneficial vegetable oils,and investigate their relationships w...Fatty acids are the main constituents of vegetable oils.To determine the fatty acid compositions of small trade vegetable oils and some less well studied beneficial vegetable oils,and investigate their relationships with antioxidant activity and oxidative stability,gas chromatography-mass spectrometry was performed to characterize the associated fatty acid profiles.The antioxidant activity of vegetable oils,based on their DPPH-scavenging capacity(expressed as IC_(50) values),was used to assess their impact on human health,and their oxidative stability was characterized by performing lipid oxidation analysis to determine the oxidative induction time of fats and oils.In addition,correlation analyses were performed to examine associations between the fatty acid composition of the oils and DPPH-scavenging capacity and oxidative stability.The results revealed that among the assessed oils,coffee seed oil has the highest saturated fatty acid content(355.10 mg/g),whereas Garddenia jaminoides oil has the highest unsaturated fatty acid content(844.84 mg/g).Coffee seed oil was also found have the lowest DPPH IC_(50) value(2.30 mg/mL)and the longest oxidation induction time(17.09 h).Correlation analysis revealed a significant linear relationship(P<0.05)between oxidative stability and unsaturated fatty acid content,with lower contents tending to be associated with better oxidative stability.The findings of this study provide reference data for the screening of functional edible vegetable oils.展开更多
The objective of this paper is to computationally explore the structural stability and strength of gypsum-protected CFS(cold-formed steel)beam channel sections under non-uniform elevated temperatures when exposed to s...The objective of this paper is to computationally explore the structural stability and strength of gypsum-protected CFS(cold-formed steel)beam channel sections under non-uniform elevated temperatures when exposed to standard fire on one side of the panel and subjected to pure bending.When a CFS member is subjected to fire(or thermal gradients)its material properties change-but this change happens around the cross-section and along the length creating a member which is potentially non-uniform and unsymmetrical in its response even if the apparent geometry is uniform and symmetric.Computational finite element models were analyzed in ABAQUS to establish steady-state thermal gradients of interest.Existing test data were utilized to develop the temperature dependence of the stress-strain response.The time-dependent temperature distribution on the cross-sections obtained from heat transfer analysis was later used in the stability and collapse analyses.The stability of the models was explored to characterize how local,distortional,and global buckling of the member evolves under both uniform and non-uniform temperature distributions.Finally,collapse simulations were performed to characterize the strength under pure bending and explore directly the evolution of strength under the influence of non-uniform temperature.展开更多
基金supported by the National Natural Science Foundation of China[82003956]the National Key Research and Development Program of China[No.2022YFA1205802]+2 种基金financially supported by Henan Province Health Science and Technology Innovation Youth Talent Project(YQRC2023013 and YQRC2024013)the Key Project of Medical Science and Technology of Henan Province(SBGJ202302072)the Science and Technology Research Project of Henan Province(252102311236).
文摘Single-atom nanozymes(SAzymes)exhibit exceptional catalytic efficiency due to their maximized atom utilization and precisely modulated metalcarrier interactions,which have attracted significant attention in the biomedical field.However,stability issues may impede the clinical translation of SAzymes.This review provides a comprehensive overview of the applications of SAzymes in various biomedical fields,including disease diagnosis(e.g.,biosensors and diagnostic imaging),antitumor therapy(e.g.,photothermal therapy,photodynamic therapy,sonodynamic therapy,and immunotherapy),antimicrobial therapy,and anti-oxidative stress therapy.More importantly,the existing challenges of SAzymes are discussed,such as metal atom clustering and active site loss,ligand bond breakage at high temperature,insufficient environment tolerance,biosecurity risks,and limited catalytic long-term stability.Finally,several innovative strategies to address these stability concerns are proposed—synthesis process optimization(space-limited strategy,coordination site design,bimetallic synergistic strategy,defect engineering strategy,atom stripping-capture),surface modification,and dynamic responsive design—that collectively pave the way for robust,clinically viable SAzymes.
基金supported by the National Key R&D Program of China(No.2023YFC3707200)the National Natural Science Foundation of China(Nos.22306191 and 52270112).
文摘Selective catalytic reduction with NH3(NH3-SCR)is an important means of NO_(x) abatement from stationary and mobile sources,and the key element is efficient and stable NH3-SCR catalysts.In this study,we propose a method to construct superior Fe-Beta catalysts based on Al-rich zeolites.This strategy successfully promotes the formation of NH3-SCR-active isolated Fe^(3+)species,thus effectively improving the low-temperature activity of the Fe-Beta catalysts.Thanks to the abundant Brønsted acid sites of the Al-rich zeolite,the Fe_(2)O_(3) particles are redispersed and anchored as isolated Fe^(3+)during hydrothermal aging.This dynamic evolution of Fe species makes up for the adverse effect of dealumination of the Al-rich zeolite framework and achieves high stability for the Al-rich Fe-Beta catalyst.This study may promote the understanding of highly efficient and stable catalyst design using Al-rich zeolites.
基金financially sponsored by the National Natural Science Foundation of China(No.52204414)the National Energy-Saving and Low-Carbon Materials Production and Application Demonstration Platform Program,China(No.TC220H06N)+1 种基金the National Key R&D Program of China(No.2021YFC1910504)the Fundamental Research Funds for the Central Universities,China(No.FRFTP-20-097A1Z)。
文摘MnO_(x)-CeO_(2)catalysts for the low-temperature selective catalytic reduction(SCR)of NO remain vulnerable to water and sulfur poisoning,limting their practical applications.Herein,we report a hydrophobic-modified MnO_(x)-CeO_(2)catalyst that achieves enhanced NO conversion rate and stability under harsh conditions.The catalyst was synthesized by decorating MnOx crystals with amorphous CeO_(2),followed by loading hydrophobic silica on the external surfaces.The hydrophobic silica allowed the adsorption of NH_(3)and NO and diffusion of H,suppressed the adsorption of H_(2)O,and prevented SO_(2)interaction with the Mn active sites,achieving selective molecular discrimination at the catalyst surface.At 120℃,under H_(2)O and SO_(2)exposure,the optimal hydrophobic catalyst maintains 82%NO conversion rate compared with 69%for the unmodified catalyst.The average adsorption energies of NH_(3),H_(2)O,and SO_(2)decreased by 0.05,0.43,and 0.52 eV,respectively.The NO reduction pathway follows the Eley-Rideal mechanism,NH_(3)^(*)+*→NH_(2)^(*)+H^(*)followed by NH_(2)^(*)+NO^(*)→N_(2)^(*)+H_(2)O^(*),with NH_(3)dehydrogenation being the rate determining step.Hydrophobic modification increased the activation energy for H atom transfer,leading to a minor decrease in the NO conversion rate at 120℃.This work demonstrates a viable strategy for developing robust NH_(3)-S CR catalysts capable of efficient operation in water-and sulfur-rich environments.
文摘AIM:To investigate age-related differences in the irislens angle(ILA)among patients with age-related cortical cataracts and elucidate the impact of age on lens stability.METHODS:A prospective observational study was conducted on patients with age-related cortical cataracts scheduled for phacoemulsification surgery.Preoperative ultrasound biomicroscopy(UBM)images were collected and analyzed.Initially,patients were stratified into two age groups:<60y and≥60y,with no significant intergroup differences in sex or eye laterality.For further analysis,participants were subdivided into three age strata:<60y,60-75y,and>75y.The ILA was measured in four quadrants(superior,inferior,nasal,and temporal).Intergroup differences in ILA were compared,and correlations between age and ILA parameters were analyzed using statistical methods.RESULTS:The sample data were categorized into three groups according to age,<60y(113 patients;55.8%female),60–75y(245 patients;61.0%female),and>75y(70 patients;50.2%female).The superior quadrant ILA increased progressively with age stratification(P=0.02),and the maximum ILA difference(ΔILA)was significantly higher in patients over 75y(P<0.01).Simple linear regression analysis demonstrated a positive correlation between age and ILA in the superior(Y=7.487+0.096X,R=0.191,P<0.001)and temporal(Y=10.254+0.052X,R=0.104,P=0.032)quadrants.Additionally,the mean ILA across all quadrants(ILAmean)andΔILA were positively correlated with age(ILAmean:Y=9.721+0.055X,R=0.138,P=0.004;ΔILA:Y=3.267+0.044X,R=0.006,P<0.05).CONCLUSION:In patients with age-related cortical cataracts,ILA increases with age,particularly in the superior and temporal quadrants,suggesting that advanced age is associated with greater lens deviation and decreased lens stability.UBM imaging can effectively evaluate the status of the zonule and lens stability,providing crucial evidence for personalized surgical planning based on patients’age.
基金supported by the Low-Cost Long-Life Batteries program,China(No.WL-24-08-01)the National Natural Science Foundation of China(No.22279007)。
文摘The outstanding performance of O3-type NaNi_(1/3)Fe_(1/3)Mn_(1/3)O_(2)(NFM111)at both high and low temperatures coupled with its impressive specific capacity makes it an excellent cathode material for sodium-ion batteries.However,its poor cycling,owing to highpressure phase transitions,is one of its disadvantages.In this study,Cu/Ti was introduced into NFM111 cathode material using a solidphase method.Through both theoretically and experimentally,this study found that Cu doping provides a higher redox potential in NFM111,improving its reversible capacity and charge compensation process.The introduction of Ti would enhance the cycling stability of the material,smooth its charge and discharge curves,and suppress its high-voltage phase transitions.Accordingly,the NaNi_(0.27)Fe_(0.28)Mn_(0.33)Cu_(0.05)Ti_(0.06)O_(2)sample used in the study exhibited a remarkable rate performance of 142.97 mAh·g^(-1)at 0.1 C(2.0-4.2 V)and an excellent capacity retention of 72.81%after 300 cycles at 1C(1C=150 mA·g^(-1)).
文摘Distinctness, Uniformity and Stability （DUS） testing is the technical base of Plant Variety Protection （PVP） and the scientific basis for the approval of Plant Breeder＇s Rights （PBR）. DUS Test Guidelines are not only the technical manuals for the DUS testing authorities to conduct the testing, but also the technical standards for the competent authorities to examine the DUS of new varieties of plants. Tea plant, originated from Yunnan Province, China, is a very important woody cash species in the world. The International Union for the Protection of New Varieties of Plants （UPOV） DUS Test Guidelines for tea plant is the first Test Guidelines prepared by China for the UPOV. In this article, the subject, selection, and determination of characteristics, states of expression of characteristics and the selection of example varieties, assessment of the UPOV DUS Test Guidelines for tea plant were elucidated in detail. Finally, the proposal of PVP for tea plant in China was also proposed. The preparation of UPOV DUS Test Guidelines for tea plant will have important significance both for promoting the development of PVP and increasing the status of international PVP fields for China.
基金This project was supported by the National Natural Science Foundation of China (60274007) NSERC-Canada.
文摘In the area of control theory the time-delay systems have been investigated. It's well known that delays often result in instability, therefore, stability analysis of time-delay systems is an important subject in control theory. As a result, many criteria for testing the stability of linear time-delay systems have been proposed. Significant progress has been made in the theory of impulsive systems and impulsive delay systems in recent years. However, the corresponding theory for uncertain impulsive systems and uncertain impulsive delay systems has not been fully developed. In this paper, robust stability criteria are established for uncertain linear delay impulsive systems by using Lyapunov function, Razumikhin techniques and the results obtained. Some examples are given to illustrate our theory.
基金financially supported by the National Natural Science Foundation of China(No.61904050)the Science and Technology Major Project of Hubei(Nos.2020AAA005 and 2020AEA017)+1 种基金the Scientific Research Project of Education Department of Hubei Province(No.Q20181009)Hubei Key Laboratory of Advanced Memories。
文摘In this letter,the Ti-doped NbO_(x)-based selector is applied to SiNOx-based resistive random-access memory(RRAM),forming Pt/NbOx(Ti-doped)/SiNO_(x)/Ti one selector-one RRAM device(1S1R),to suppress the sneak path current.The fabricated 1S1R exhibits stable direct current(DC)endurance(>200 cycles),suitable memory window(>40),matched selectivity(>40)and high uniformity of switching parameters.
基金the National Key RESEARCH and Development Program of the Ministry of Science and Technology‘Life Prediction and Operation Risk Assessment of UHV Equipment under long-term Service conditions(No.2017YFB0902705)’for supporting this workthe No.703 Research Institute of CSIC(China Shipbuilding Industry Corporation)Yunnan Electric Test&Research Institute Group CO.,Ltd for assistance in this paper.
文摘In this paper, an improved air discharge fluid model under non-uniform electric field is constructed based on the plasma module COMSOL Multiphysics with artificial stability term, and the boundary conditions developed in the previous paper are applied to the calculation of photoionization rate. Based on the modified model, the characteristics of low temperature subatmospheric air discharge under 13 kV direct current voltage are discussed, including needle-plate and needle-needle electrode structures. Firstly, in order to verify the reliability of the model, a numerical example and an experimental verification were carried out for the modified model respectively. Both verification results show that the model can ensure the accuracy and repeatability of the calculation. Secondly, according to the calculation results of the modified model, under the same voltage and spacing, the reduced electric field under low temperature subatmosphere pressure is larger than that under normal temperature and atmospheric pressure. The high electric field leads to the air discharge at low temperature and sub atmospheric pressure entering the streamer initiation stage earlier, and has a faster propagation speed in the streamer development stage, which shortens the overall discharge time. Finally, the discharge characteristics of the two electrode structures are compared, and it is found that the biggest difference between them is that there is a pre-ionization region near the cathode in the needle-needle electrode structure. When the pre-ionization level reaches 1013 cm-3, the propagation speed of the positive streamer remains unchanged throughout the discharge process, and is no longer affected by the negative streamer. The peak value of electric field decreases with the increase of pre-ionization level, and tends to be constant during streamer propagation. Based on the previous paper, this paper constructs the air discharge model under non-uniform electric field, complements with the previous paper, and forms a relatively complete set of air discharge simulation system under low temperature and sub atmospheric pressure, which provides a certain reference for future research.
文摘New theorems of asymptotical stability and uniformly asymptotical stability for nonautonomous difference equations are given in this paper. The classical Liapunov asymptotical stability theorem of nonautonomous difference equations relies on the existence of a positive definite Liapunov function that has an indefinitely small upper bound and whose variation along a given nonautonomous difference equations is negative definite. In this paper, we consider the case that the Liapunov function is only positive definite and its variation is semi-negative definite. At these weaker conditions, we put forward a new asymptotical stability theorem of nonautonomous difference equations by adding to extra conditions on the variation. After that, in addition to the hypotheses of our new asymptotical stability theorem, we obtain a new uniformly asymptotical stability theorem of nonautonomous difference equations provided that the Liapunov function has an indefinitely small upper bound. Example is given to verify our results in the last.
基金Supported by Research Project of Heilongjiang Education Science and Technology (11521051)
文摘In order to develop a basic electrode with low fume and good usability, a uew slag system has been designed after analyzing several basic electrode slag systems. Then in view of uniform design method, arranging the experiment points by it, the influenced laws of the uew system coating compouents on the arc stability had been searched. In the formula, niue coating compouents were taken as independent variables and they were divided into six levels in all twenty-four experiments. The arc stability was taken as function and taken down the data when welding and then put them into the computer to be processed statistically. The analysis results give the mathematical model and trend diagrams between independent variables and the function. They indicate that the effects of many coating compouents on the arc stability are in the mutual form. The mutual effects between CaCO3 and BaF2, BaF2 and BaCO3 , increases the arc stability separately. While the mutual effects between CaF2 and iron powder, the square item of iron powder itself decreases the arc stability separately.
文摘The global uniform asymptotic stability of competitive neural networks with different time scales and delay is investigated. By the method of variation of parameters and the method of inequality analysis, the condition for global uniformly asymptotically stable are given. A strict Lyapunov function for the flow of a competitive neural system with different time scales and delay is presented. Based on the function, the global uniform asymptotic stability of the equilibrium point can be proved.
文摘Single-walled carbon nanotubes(SWCNTs)are receiving immense research attention due to their tremendous thermal,electrical,structural and mechanical properties.In this paper,an exact solution of the dynamic response of SWCNT with a moving uniformly distributed load is presented.The SWCNT is modelled via the theories of Bernoulli-Euler-thermal elasticity mechanics and solved using Integral transforms.The developed closed-form solution in the present work is compared with existing results and excellent agreements are established.The parametric studies show that as the magnitude of the pressure distribution at the surface increases,the deflection associated with the single walled nanotube increases at any mode whilst a corresponding increase in temperature and foundation parameter have an attenuating effect on deflection.Moreover,an increase in the Winkler parameter,as well as a decrease in the SWCNT mass increases its frequency of vibration.Furthermore,an increase in the speed of the external agent decreases the total external pressure as a result of the removal of dead loads.The present work is envisaged to improve the application of SWCNT as nanodevices for structural,electrical and mechanical systems.
基金Project supported by the National Natural Science Foundation of China (Grant Nos.61006059,60776051,and 61006044)the Beijing Municipal Natural Science Foundation of China (Grant No.4082007)+3 种基金the National Basic Research Program of China,the Beijing Municipal Education Committee of China (Grant Nos.KM200710005015 and KM200910005001)the Beijing Municipal Trans-century Talent Project of China (Grant No.67002013200301)the Beijing Innovatory Talent Training Program of China (Grant No.00200054RA001)the Ph.D.Start Science Foundation of Beijing University of Technology,China (Grant No.X0002013201102)
文摘With the aid of a thermal-electrical model, a practical method for designing multi-finger power heterojunction bipolar transistors with finger lengths divided in groups is proposed. The method can effectively enhance the thermal stability of the devices without sacrificing the design time. Taking a 40-finger heterojunction bipolar transistor for example, the device with non-uniform emitter finger lengths is optimized and fabricated. Both the theoretical and the experimental results show that, for the optimum device, the peak temperature is lowered by 26.19 K and the maximum temperature difference is reduced by 56.67% when compared with the conventional heterojunction bipolar transistor with uniform emitter finger length. Furthermore, the ability to improve the uniformity of the temperature profile and to expand the thermal stable operation range is strengthened as the power level increases, which is ascribed to the improvement of the thermal resistance in the optimum device. A detailed design procedure is also summarized to provide a general guide for designing power heterojunction bipolar transistors with non-uniform finger lengths.
基金supported by the National Natural Science Foundation of China(11172152)
文摘The linear stability of wall-injected pressure- driven Couette-like flow in power-law fluids is studied. Previous study on this kind of flow for Newtonian fluids by Nicoud and Angilella [Phys. Rev. E 56, 3000 （1997）] was extended to power-law fluids to understand the effects of shear-thinning/thickening nature on the flow stability. A related expression between the critical crossflow Reynolds number for Newtonian fluids and that for power-law fluids is obtained as the streamwise Reynolds number is large enough based on numerical computations, and verified theoretically in the case of a limiting condition with the power-law index.
文摘In this paper, to begin with. the nonlinear differential equations of a truncaled shallow spherical shell with variable thickness under uniformal distributed load are linearized by step-by-step loading method. The linear differential equations can be solved by spline collocanon method. Critical loads have been obtained accordingly.
基金Supported by the National Natural Science Foundation of China (No.60372012) and NSF of Chongqing (No.0831)
文摘Stability, boundedness and persistence are three important aspects for an ecological model. In this paper, a further analysis of a class of anaerobic digestion ecological models is performed. Based on the Liupunov Method, the local stability of all equilibria in the system is got. According to the vector fields described by the system, the proof of the boundedness of the solution on the anaerobic digestion processes is completed in three steps. The method proposed in the discussion on the boundedness can be generalized to the similar problems. Results in this paper give information on how to run the ecological system well by adjusting the system parameters.
文摘Fatty acids are the main constituents of vegetable oils.To determine the fatty acid compositions of small trade vegetable oils and some less well studied beneficial vegetable oils,and investigate their relationships with antioxidant activity and oxidative stability,gas chromatography-mass spectrometry was performed to characterize the associated fatty acid profiles.The antioxidant activity of vegetable oils,based on their DPPH-scavenging capacity(expressed as IC_(50) values),was used to assess their impact on human health,and their oxidative stability was characterized by performing lipid oxidation analysis to determine the oxidative induction time of fats and oils.In addition,correlation analyses were performed to examine associations between the fatty acid composition of the oils and DPPH-scavenging capacity and oxidative stability.The results revealed that among the assessed oils,coffee seed oil has the highest saturated fatty acid content(355.10 mg/g),whereas Garddenia jaminoides oil has the highest unsaturated fatty acid content(844.84 mg/g).Coffee seed oil was also found have the lowest DPPH IC_(50) value(2.30 mg/mL)and the longest oxidation induction time(17.09 h).Correlation analysis revealed a significant linear relationship(P<0.05)between oxidative stability and unsaturated fatty acid content,with lower contents tending to be associated with better oxidative stability.The findings of this study provide reference data for the screening of functional edible vegetable oils.
文摘The objective of this paper is to computationally explore the structural stability and strength of gypsum-protected CFS(cold-formed steel)beam channel sections under non-uniform elevated temperatures when exposed to standard fire on one side of the panel and subjected to pure bending.When a CFS member is subjected to fire(or thermal gradients)its material properties change-but this change happens around the cross-section and along the length creating a member which is potentially non-uniform and unsymmetrical in its response even if the apparent geometry is uniform and symmetric.Computational finite element models were analyzed in ABAQUS to establish steady-state thermal gradients of interest.Existing test data were utilized to develop the temperature dependence of the stress-strain response.The time-dependent temperature distribution on the cross-sections obtained from heat transfer analysis was later used in the stability and collapse analyses.The stability of the models was explored to characterize how local,distortional,and global buckling of the member evolves under both uniform and non-uniform temperature distributions.Finally,collapse simulations were performed to characterize the strength under pure bending and explore directly the evolution of strength under the influence of non-uniform temperature.
