in recent years research investigating various health benefits of Taiji practice has markedly increased. Despite this growing scientific interest, essential questions such as to what extent a Taiji course may exert no...in recent years research investigating various health benefits of Taiji practice has markedly increased. Despite this growing scientific interest, essential questions such as to what extent a Taiji course may exert noticeable effects in participants＇ everyday life, what these effects are, and how and where potential transfer effects occur, have hardly been considered. The aim of our study was to explore transfer effects from a Taiji course into participants＇ daily lives. METHODS： We conducted a longitudinal observational study in 45 healthy participants at the end of their three-month Taiji beginner course （tpl） and at two months （tp2） as well as one year after course completion （tp3）. Participants were asked to report their Taiji practice behavior at all time points, as well as to rate and describe perceived transfer effects of Taiji course contents on their daily life at tpl and tp3. RESULTS： Transfer effects were reported by 91.1% of all respondents after course completion （tpl） and persisted in 73.3% at the one-year follow-up assessment （tp3）, counting ＂increase of self-efficacy＂, ＂improvement of stress management＂, and ＂increase of body awareness＂ as the most frequently mentioned effects. Transfer effects predominantly occurred in participants＇ work and social environments, as well as during everyday activities in public areas. While self- reliant Taiji practice frequency significantly decreased from 82.2% at tpl to 55.6% at tp3 （P 〈 0.001）, the magnitude of self-reported transfer effects did not （P = 0.35）. As explorative analyses revealed, regular Taiji course attendance was highly correlated with stronger transfer effects at tpl （r = 0.51; P 〈 0.001） and tp3 （r = 0.35; P = 0.020）. Participants reporting high self-reliant Taiji practice frequency at tp2 were likely to maintain a regular practice routine at tp3 （r = 0.42; P 〈 0.004）, whereas self-reliant practice frequency and transfer effects at tpl were positively correlated with self-reliant practice frequency at tp3 on a trend level （r 〈 0.27; P 〉 0.08）. CONCLUSION： Our data underline the importance of regular course participation for pronounced and long lasting transfer effects into participants＇ everyday life. We discuss that several context and process-related aspects of a Taiji intervention are potentially relevant factors for enhancement of transfer effect.展开更多
The present investigation addresses the simultaneous effects of heat and mass transfer in the mixed convection peristaltic flow of viscous fluid in an asymmetric channel. The channel walls exhibit the convective bound...The present investigation addresses the simultaneous effects of heat and mass transfer in the mixed convection peristaltic flow of viscous fluid in an asymmetric channel. The channel walls exhibit the convective boundary conditions. In addition, the effects due to Soret and Dufour are taken into consideration. Resulting problems are solved for the series solutions. Numerical values of heat and mass transfer rates are displayed and studied. Results indicate that the concentration and temperature of the fluid increase whereas the mass transfer rate at the wall decreases with increase of the mass transfer Biot number. Furthermore, it is observed that the temperature decreases with the increase of the heat transfer Biot number.展开更多
Pseudo-first order reaction rate constants of 5,10,15-tris（pentafluorophenyl）corrole Mn（V）-oxo （F_（15）CMn（V）-oxo）,5,15-bis（pentafluorophenyl）-10-（phenyl）corrole Mn（V）-oxo（F_（10）CMn（V）-oxo）,5,15- ...Pseudo-first order reaction rate constants of 5,10,15-tris（pentafluorophenyl）corrole Mn（V）-oxo （F_（15）CMn（V）-oxo）,5,15-bis（pentafluorophenyl）-10-（phenyl）corrole Mn（V）-oxo（F_（10）CMn（V）-oxo）,5,15- bis（phenyl）-10-（pentafluorophenyl）corrole Mn（V）-oxo（F_5CMn（V）-oxo） and 5,10,15-tris（phenyl）corrole Mn（V）-oxo（F_0CMn（V）-oxo） with a series of alkene substrates in different solvents were determined by UV-vis spectroscopy.The results indicated that the oxygen atom transfer pathway between Mn（V）-oxo corrole and alkene is solvent-dependent.展开更多
Bay-site carboxyl functionalized perylene diimide derivative 1,7-COOH-PDI-C_(12)(PDI-COOH)was synthesized and distinct enhanced fluorescence was observed through combining with calcium ion(Ca^(2+))in THF/H_(2)O soluti...Bay-site carboxyl functionalized perylene diimide derivative 1,7-COOH-PDI-C_(12)(PDI-COOH)was synthesized and distinct enhanced fluorescence was observed through combining with calcium ion(Ca^(2+))in THF/H_(2)O solution.The assembly and fluorescence behavior of PDI-COOH/Ca^(2+)were studied in detail by changing hydration state with different concentrations.Based on the differences in assembly morphology and stoichiometric ratios of PDICOOH/Ca^(2+),we proposed the fluorescence emission mechanism of PDI-COOH/Ca^(2+)in THF/H_(2)O and THF,respectively.This work reveals a novel strategy of aggregated state fluorescence enhancement and reminds us of the important role of water in molecular fluorescence emission and assembly.展开更多
The rotary gas-gas heat exchanger(GGH)is a vital component in waste heat recovery systems,partic-ularly for Selective Catalytic Reduction(SCR)processes employed in cement kiln operations.This study investigates the th...The rotary gas-gas heat exchanger(GGH)is a vital component in waste heat recovery systems,partic-ularly for Selective Catalytic Reduction(SCR)processes employed in cement kiln operations.This study investigates the thermal performance of a rotary GGH in medium-and low-temperature denitrification systems,using a simplified porous medium model based on its actual internal structure.A porous medium representation is developed from the structural characteristics of the most efficient heat transfer element,and a local thermal non-equilibrium(LTNE)model is employed to capture the distinct thermal behaviors of the solid matrix and gas phase.To account for the rotational dynamics of the system,the multiple reference frame(MRF)approach is adopted.Numerical simulation results exhibit an average error of less than 5%,demonstrating the model’s reliability and predictive accuracy.The temperature distributions of both the metallic heat exchange surfaces and the flue gas are systematically analyzed.Results indicate that the solid and gas phases exhibit significant non-equilibrium thermal behavior.Notably,the circumferential temperature fluctuations of both the heat exchange surfaces and flue gas vary markedly with changes in rotational speed.At low rotational speeds,the temperature non-uniformity coefficient reaches 4.296,while at high speeds it decreases to 0.4813-indicating that lower speeds lead to more pronounced temperature fluctuations.The simulated temperature field patterns are consistent with experimental observations,validating the effectiveness of the modeling approach.展开更多
A decomposable and sono-enzyme co-triggered nanoparticle(p TCP-CR NP)with“AND gate”logic was synthesized,combining a meso–carboxyl-porphyrin-based sonosensitizer(5,10,15,20-tetrakis(carboxyl)porphyrin,TCP)and a thi...A decomposable and sono-enzyme co-triggered nanoparticle(p TCP-CR NP)with“AND gate”logic was synthesized,combining a meso–carboxyl-porphyrin-based sonosensitizer(5,10,15,20-tetrakis(carboxyl)porphyrin,TCP)and a thiophenyl-croconium(2,5-bis[(2-(2-(2-hydroxyethoxy)ethoxy)ethyl-4-carboxylate-piperidylamino)thiophenyl]-croconium,CR)via ester groups.TCP releases carbon monoxide(CO)under ultrasound(US)irradiation,offering both sonodynamic and gas therapy.CR decomposes into stronger reactive oxygen species(ROS)compared to oxygen-based radicals.The F?rster resonance energy transfer(FRET)effect between TCP and CR inhibits ROS and CO generation until triggered by tumor cell overexpressed carboxylesterase(CEs).p TCP-CR NPs“AND gate”logic ensures activation only in the presence of both CEs and US,targeting tumor cells while safety in normal tissues.The ROS and CO generation abilities,as well as the releasing of SO_(4)^(·-)have been systemically examined.p TCP-CR can be thoroughly decomposed into low-toxic molecules post the treatment,showing the safety with negligible phototoxic reactions.In vivo anti-cancer therapy has been evaluated using mice bearing hepatocellular carcinoma.展开更多
Remote sensing cross-modal image-text retrieval(RSCIR)can flexibly and subjectively retrieve remote sensing images utilizing query text,which has received more researchers’attention recently.However,with the increasi...Remote sensing cross-modal image-text retrieval(RSCIR)can flexibly and subjectively retrieve remote sensing images utilizing query text,which has received more researchers’attention recently.However,with the increasing volume of visual-language pre-training model parameters,direct transfer learning consumes a substantial amount of computational and storage resources.Moreover,recently proposed parameter-efficient transfer learning methods mainly focus on the reconstruction of channel features,ignoring the spatial features which are vital for modeling key entity relationships.To address these issues,we design an efficient transfer learning framework for RSCIR,which is based on spatial feature efficient reconstruction(SPER).A concise and efficient spatial adapter is introduced to enhance the extraction of spatial relationships.The spatial adapter is able to spatially reconstruct the features in the backbone with few parameters while incorporating the prior information from the channel dimension.We conduct quantitative and qualitative experiments on two different commonly used RSCIR datasets.Compared with traditional methods,our approach achieves an improvement of 3%-11% in sumR metric.Compared with methods finetuning all parameters,our proposed method only trains less than 1% of the parameters,while maintaining an overall performance of about 96%.展开更多
Due to the advantages of low energy consumption and high CO_(2) selectivity, the development of solid amine-based materials has been regarded as a hot research topic in the field of DAC for the past decades.The adsorp...Due to the advantages of low energy consumption and high CO_(2) selectivity, the development of solid amine-based materials has been regarded as a hot research topic in the field of DAC for the past decades.The adsorption capacity and stability over multiple cycles have been the top priorities for evaluation of practical application value. Herein, we synthesized a novel DAC material by loading TEPA onto defect-rich Mg_(0.55)Al-O MMOs with enhanced charge transfer effect. The optimal Mg_(0.55)Al-O-TEPA67% demonstrates the highest CO_(2)uptake of(3.0 mmol g^(-1)) and excellent regenerability, maintaining ~90% of the initial adsorption amount after 80 adsorption/desorption cycles. The in situ DRIFTS experiments suggested the formation of bicarbonate species under wet conditions. DFT calculations indicated that the stronger bonding between Mg_(0.55)Al-O support and solid amine was caused by the abundance of oxygen defects on MMOs confirmed by XPS and ESR, which favors the charge transfer between the support and amine,resulting in intense interaction and excellent regenerability. This work for the first time conducted comprehensive and systematic investigation on the stabilization mechanism for MMOs supported solid amine adsorbents with highest uptake and superior cyclic stability in depth, which is different from the most popular SiO_(2)-support, thus providing facile strategy and comprehensive theoretical mechanism support for future research about DAC materials.展开更多
A heavy-ion irradiation experiment is studied in digital storage cells with different design approaches in 130？nm CMOS bulk Si and silicon-on-insulator （SOI） technologies. The effectiveness of linear energy transf...A heavy-ion irradiation experiment is studied in digital storage cells with different design approaches in 130？nm CMOS bulk Si and silicon-on-insulator （SOI） technologies. The effectiveness of linear energy transfer （LET） with a tilted ion beam at the 130？nm technology node is obtained. Tests of tilted angles θ=0 ° , 30 ° and 60 ° with respect to the normal direction are performed under heavy-ion Kr with certain power whose LET is about 40？MeVcm 2 /mg at normal incidence. Error numbers in D flip-flop chains are used to determine their upset sensitivity at different incidence angles. It is indicated that the effective LETs for SOI and bulk Si are not exactly in inverse proportion to cosθ , furthermore the effective LET for SOI is more closely in inverse proportion to cosθ compared to bulk Si, which are also the well known behavior. It is interesting that, if we design the sample in the dual interlocked storage cell approach, the effective LET in bulk Si will look like inversely proportional to cosθ very well, which is also specifically explained.展开更多
The kinetics of ion exchange between Ca2+, Mg2+, Co(Ⅱ), Cu(Ⅱ),Ni(Ⅱ), Fe(Ⅲ), y3+ or Sm3+ , respectively, in 0.50 mol/L HC1 and H+ on macrorecticular sulfonic ion exchange resin and the kinetics of the same reaction...The kinetics of ion exchange between Ca2+, Mg2+, Co(Ⅱ), Cu(Ⅱ),Ni(Ⅱ), Fe(Ⅲ), y3+ or Sm3+ , respectively, in 0.50 mol/L HC1 and H+ on macrorecticular sulfonic ion exchange resin and the kinetics of the same reactions (M -H exchange) when Mn(Ⅱ) coexisted in resin phase as accelerating ion were studied. The accelerating effect manifested and its rule are consistent with the accelerating effect theory based on the concept concerned with adsorption electrical double layer which has been suggested in a previous paper published.展开更多
We demonstrate a triple-pass scheme for coherent transfer of optical frequency and the delay effect on the fiber phase noise compensation. It is theoretically proved that the delay effect consists of both fiber delay ...We demonstrate a triple-pass scheme for coherent transfer of optical frequency and the delay effect on the fiber phase noise compensation. It is theoretically proved that the delay effect consists of both fiber delay and servo delay. The delay effect confines the servo bandwidth within 1/8 and induces a residual fiber phase noise after noise compensation. For a 25-km-long fiber, the servo bandwidth is found to be around 1 k Hz, and the fiber phase noise is suppressed approaching to the theoretical limitation. The triple-pass scheme enables the simultaneous transfer of optical frequency to multiple remote users. The performance of noise compensator in the triple-pass scheme can achieve a similar level result compared with that in the double-pass scheme.展开更多
Magnetic radiation phenomena appear inevitably in the magnetic-resonance wireless power transfer （MR-WPT） system, and regarding this problem the magnetic-shielding scheme is applied to improve the electromagnetic pe...Magnetic radiation phenomena appear inevitably in the magnetic-resonance wireless power transfer （MR-WPT） system, and regarding this problem the magnetic-shielding scheme is applied to improve the electromagnetic performance in engineering. In this study, the shielding effectiveness of a two-coil MR-WPT system for different material shields is analyzed in theory using Moser＇s formula and Schelkunoff＇s formula. On this basis a candidate magnetic-shielding scheme with a double-layer structure is determined, which has better shielding effectiveness and coils coupling coefficient. Finally, some finite element simulation results validate the correctness of the theoretical analysis, and the shielding effectiveness with the double-layer shield in maximum is 30？dB larger than the one with the single-layer case.展开更多
Alloimmunization was combined with lympho-kine activated killer (LAK) cells to assess its effect on mammary carcinoma in rats. The animals were injected with both irradiated allosplenocytes and syngeneic LAK cells. Me...Alloimmunization was combined with lympho-kine activated killer (LAK) cells to assess its effect on mammary carcinoma in rats. The animals were injected with both irradiated allosplenocytes and syngeneic LAK cells. Metastatic lung nodules were markedly reduced using combined therapy when compared with the transfer of LAK cells or alloimmuni-zation alone. IL-2 activity in the serum of alloim-munized rats could be detected. This activity, maintained in vivo for one week, may be responsible for enhancing the antitumor effect of transferred LAK cells.展开更多
Miniaturization of electronic package leads to high heat density and heat accumulation in electronics device, resulting in short life time and premature failure of the device. Junction temperature and thermal resistan...Miniaturization of electronic package leads to high heat density and heat accumulation in electronics device, resulting in short life time and premature failure of the device. Junction temperature and thermal resistance are the critical parameters that determine the thermal management and reliability in electronics cooling. Metal oxide field effect transistor（MOSFET）is an important semiconductor device for light emitting diode-integrated circuit（LED IC） driver application, and thermal management in MOSFET is a major challenge. In this study, investigations on thermal performance of MOSFET are performed for evaluating the junction temperature and thermal resistance. Suitable modifications in FR4 substrates are proposed by introducing thermal vias and copper layer coating to improve the thermal performance of MOSFET. Experiments are conducted using thermal transient tester（T3ster） at 2.0 A input current and ambient temperature varying from25℃ to 75℃. The thermal parameters are measured for three proposed designs： FR4 with circular thermal vias, FR4 with single strip of copper layer and embedded vias, and FR4 with I-shaped copper layer, and compared with that of plain FR4 substrate. From the experimental results, FR4I-shaped shows promising results by 33.71% reduction in junction temperature and 54.19% reduction in thermal resistance. For elevated temperature, the relative increases in junction temperature and thermal resistance are lower for FR4I-shaped than those for other substrates considered. The introduction of thermal vias and copper layer plays a significant role in thermal performance.展开更多
Obstructive sleep apnea-hypopnea syndrome(OSAHS)significantly impairs children's growth and cognition.This study aims to elucidate the pathophysiological mechanisms underlying OSAHS in children,with a particular f...Obstructive sleep apnea-hypopnea syndrome(OSAHS)significantly impairs children's growth and cognition.This study aims to elucidate the pathophysiological mechanisms underlying OSAHS in children,with a particular focus on the alterations in cortical information interaction during respiratory events.We analyzed sleep electroencephalography before,during,and after events,utilizing Symbolic Transfer Entropy(STE)for brain network construction and information flow assessment.The results showed a significant increase in STE after events in specific frequency bands during N2 and rapid eye movement(REM)stages,along with increased STE during N3 stage events.Moreover,a noteworthy rise in the information flow imbalance within and between hemispheres was found after events,displaying unique patterns in central sleep apnea and hypopnea.Importantly,some of these alterations were correlated with symptom severity.These findings highlight significant changes in brain region coordination and communication during respiratory events,offering novel insights into OSAHS pathophysiology in children.展开更多
The rational design of high-performance catalysts is crucial for advancing energy conversion and storage technologies.Single-atom and nanoparticle synergistic catalysts(SAC-NPs)have garnered significant attention due ...The rational design of high-performance catalysts is crucial for advancing energy conversion and storage technologies.Single-atom and nanoparticle synergistic catalysts(SAC-NPs)have garnered significant attention due to their ability to precisely modulate electronic structures and optimize intermediate adsorption energies.SACs exhibit maximized atomic utilization and well-defined active sites;however,their restricted electronic tunability and inherent instability limit their widespread application.Conversely,NPs provide superior charge transfer capabilities and enhanced catalytic stability,effectively complementing SACs.The SAC-NPs leverage atomic-scale electronic interactions to enhance catalytic activity,stability,and reaction kinetics,making it a promising platform for electrocatalysis.Therefore,elucidating the synergistic catalytic mechanisms of SAC-NPs and refining optimization strategies are crucial for advancing the development of high-performance catalysts.This review systematically summarizes the synthesis strategies and structural modulation approaches of SAC-NPs.Furthermore,the synergistic catalytic mechanisms,encompassing electron transfer,tandem catalysis,and bifunctional catalysis,are critically examined from both experimental and theoretical perspectives.Finally,recent advancements in SAC-NPs for key electrocatalytic reactions are reviewed,along with current challenges and future research directions.This work aims to provide comprehensive theoretical and practical guidance for the development of SAC-NPs,facilitating the rational design of next-generation catalysts and advancing renewable energy technologies.展开更多
With the growing need for greater cooling capacity in electronic and heat exchange systems,significant attention has been directed toward improving the heat transfer by incorporating nanoparticles into the base fluid....With the growing need for greater cooling capacity in electronic and heat exchange systems,significant attention has been directed toward improving the heat transfer by incorporating nanoparticles into the base fluid.While the use of nanoparticles in spray cooling shows promise for enhancing heat transfer,additional clarification is required.The paper compiles empirical data from existing literature focusing on spray cooling using nanofluids.Its objective is to clarify how nanoparticles impact the efficiency of spray heat transfer and investigate the effects of factors such as spray Weber number,nanoparticle concentration and droplet spread.Gathered data reveal that when compared to water droplets,nanofluid droplets exhibited more extensive surface spreading at low impinging droplet Weber numbers.Data also show that the heat transfer effectiveness of nanofluid sprays at the critical heat flux and film boiling temperature decreases with the increase in the spray Weber number.At the critical heat flux temperature and for intermediate spray Weber numbers,sprays utilizing nanofluids are more effective than sprays utilizing pure water;however,the situation reverses when dealing with exceedingly high Weber numbers.The data indicate that for surfaces heated within the film boiling range,it remains unclear whether sprays containing nanoparticles demonstrate higher heat transfer efficiency compared to sprays using pure water alone.For surfaces heated to the critical heat flux temperature,there is a critical nanoparticle concentration below which spraying with pure water is more effective than spraying with a nanofluid.However,for surfaces heated to temperatures near the Leidenfrost point,there is no clear indication that nanoparticle concentration plays a role.With the introduction of nanoparticles into sprays,there is a tendency for both the critical heat flux and the Leidenfrost temperatures to shift to a higher temperature range and to increase with the increase in nanoparticle concentration.展开更多
SiGe based alloy is a promising medium-high temperature thermoelectric material that has been applied in the field of aerospace exploration.So far,utilizing the second phase to promote the scattering of phonons is a c...SiGe based alloy is a promising medium-high temperature thermoelectric material that has been applied in the field of aerospace exploration.So far,utilizing the second phase to promote the scattering of phonons is a common way to improve the thermoelectric performance of SiGe based alloy,but this often deteriorates the electrical properties.In this study,the Si_(80)Ge_(20)P_(1)/CoSi_(2) composites have been prepared by mechanical alloying and spark plasma sintering,and the content of cobalt silicide(CoSi_(2))nanoparticles have been manipulated.Since the CoSi_(2) nanoparticles possess higher carrier concentration and smaller work function than the Si_(80)Ge_(20)P_(1) matrix,the carrier concentrations of composites have been pushed up due the charge transfer effect.Meanwhile,the formation of nano-sized phase interfaces and stacking faults in the composites has enhanced the scattering of low-frequency phonons.As a result,the optimal power factor of 3.41 mW·m^(-1),K^(-2) and thermal conductivity of 2.29 W·m^(-1),K^(-1) have been achieved,and the corresponding zT reaches up to 1.3 in the Si_(80)Ge_(20)P_(1)+0.5%CoSi_(2)(in mole)composite at 873 K.This work provides a new idea for developing the performance of SiGe based alloy.展开更多
Considering the coupled heat transfer effect induced by parallel cross-river road tunnels, the long-term soil temperature variations of shallow sections of cross-river tunnels under the river beach are predicted using...Considering the coupled heat transfer effect induced by parallel cross-river road tunnels, the long-term soil temperature variations of shallow sections of cross-river tunnels under the river beach are predicted using the finite difference method for numerical simulation. The boundary conditions and the initial values are determined by in situ observations and numerical iterations.The simulation results indicate that the ultimate calculated steady heat transfer time is 68 years, and most of the heat transfer is completed in 20 years.The initial constant temperature soil surrounding the tunnels is transformed to an annually variable one.An obvious temperature-varying region of the surrounding soil is discovered within 5 m from the tunnel exterior, as well as within the entire range of soil between the two tunnels.The maximum temperature increase value reaches 7.14 ℃ and the maximum peak-to-valley value of annual temperature increase reaches 10 ℃.The temperature variation of soils surrounding tunnels below 10 m is completely controlled by the heat transfer from the tunnels.The coupled heat transfer effect is confirmed because the ultimate steady temperature of soil between the two tunnels is higher than the ones along other positions.Moreover, the regression model comprising a series of univariate functions is proposed for the annual soil temperature fluctuation estimation for the locations varied distances around the tunnel.This investigation is beneficial to gain an insight into the long-term variation tendencies of local engineering geological conditions of the river beach above shallow sections of the cross-river road tunnels.展开更多
基金Funding for this study was provided by Stiftung für Komplementrmedizin, Gottfried und Julia Bangerter-Rhyner Stiftung and Parrotia Stiftung
文摘in recent years research investigating various health benefits of Taiji practice has markedly increased. Despite this growing scientific interest, essential questions such as to what extent a Taiji course may exert noticeable effects in participants＇ everyday life, what these effects are, and how and where potential transfer effects occur, have hardly been considered. The aim of our study was to explore transfer effects from a Taiji course into participants＇ daily lives. METHODS： We conducted a longitudinal observational study in 45 healthy participants at the end of their three-month Taiji beginner course （tpl） and at two months （tp2） as well as one year after course completion （tp3）. Participants were asked to report their Taiji practice behavior at all time points, as well as to rate and describe perceived transfer effects of Taiji course contents on their daily life at tpl and tp3. RESULTS： Transfer effects were reported by 91.1% of all respondents after course completion （tpl） and persisted in 73.3% at the one-year follow-up assessment （tp3）, counting ＂increase of self-efficacy＂, ＂improvement of stress management＂, and ＂increase of body awareness＂ as the most frequently mentioned effects. Transfer effects predominantly occurred in participants＇ work and social environments, as well as during everyday activities in public areas. While self- reliant Taiji practice frequency significantly decreased from 82.2% at tpl to 55.6% at tp3 （P 〈 0.001）, the magnitude of self-reported transfer effects did not （P = 0.35）. As explorative analyses revealed, regular Taiji course attendance was highly correlated with stronger transfer effects at tpl （r = 0.51; P 〈 0.001） and tp3 （r = 0.35; P = 0.020）. Participants reporting high self-reliant Taiji practice frequency at tp2 were likely to maintain a regular practice routine at tp3 （r = 0.42; P 〈 0.004）, whereas self-reliant practice frequency and transfer effects at tpl were positively correlated with self-reliant practice frequency at tp3 on a trend level （r 〈 0.27; P 〉 0.08）. CONCLUSION： Our data underline the importance of regular course participation for pronounced and long lasting transfer effects into participants＇ everyday life. We discuss that several context and process-related aspects of a Taiji intervention are potentially relevant factors for enhancement of transfer effect.
基金the Higher Education Commission of Pakistan (HEC) for the financial support through Indigenous program
文摘The present investigation addresses the simultaneous effects of heat and mass transfer in the mixed convection peristaltic flow of viscous fluid in an asymmetric channel. The channel walls exhibit the convective boundary conditions. In addition, the effects due to Soret and Dufour are taken into consideration. Resulting problems are solved for the series solutions. Numerical values of heat and mass transfer rates are displayed and studied. Results indicate that the concentration and temperature of the fluid increase whereas the mass transfer rate at the wall decreases with increase of the mass transfer Biot number. Furthermore, it is observed that the temperature decreases with the increase of the heat transfer Biot number.
基金The financial support from the National Natural Science Foundation of China(Nos.20971046 and 21171057)
文摘Pseudo-first order reaction rate constants of 5,10,15-tris（pentafluorophenyl）corrole Mn（V）-oxo （F_（15）CMn（V）-oxo）,5,15-bis（pentafluorophenyl）-10-（phenyl）corrole Mn（V）-oxo（F_（10）CMn（V）-oxo）,5,15- bis（phenyl）-10-（pentafluorophenyl）corrole Mn（V）-oxo（F_5CMn（V）-oxo） and 5,10,15-tris（phenyl）corrole Mn（V）-oxo（F_0CMn（V）-oxo） with a series of alkene substrates in different solvents were determined by UV-vis spectroscopy.The results indicated that the oxygen atom transfer pathway between Mn（V）-oxo corrole and alkene is solvent-dependent.
文摘Bay-site carboxyl functionalized perylene diimide derivative 1,7-COOH-PDI-C_(12)(PDI-COOH)was synthesized and distinct enhanced fluorescence was observed through combining with calcium ion(Ca^(2+))in THF/H_(2)O solution.The assembly and fluorescence behavior of PDI-COOH/Ca^(2+)were studied in detail by changing hydration state with different concentrations.Based on the differences in assembly morphology and stoichiometric ratios of PDICOOH/Ca^(2+),we proposed the fluorescence emission mechanism of PDI-COOH/Ca^(2+)in THF/H_(2)O and THF,respectively.This work reveals a novel strategy of aggregated state fluorescence enhancement and reminds us of the important role of water in molecular fluorescence emission and assembly.
基金supported the Eco-Environment Project of the Key Research and Development Program of Anhui Province(No.202104i07020016).
文摘The rotary gas-gas heat exchanger(GGH)is a vital component in waste heat recovery systems,partic-ularly for Selective Catalytic Reduction(SCR)processes employed in cement kiln operations.This study investigates the thermal performance of a rotary GGH in medium-and low-temperature denitrification systems,using a simplified porous medium model based on its actual internal structure.A porous medium representation is developed from the structural characteristics of the most efficient heat transfer element,and a local thermal non-equilibrium(LTNE)model is employed to capture the distinct thermal behaviors of the solid matrix and gas phase.To account for the rotational dynamics of the system,the multiple reference frame(MRF)approach is adopted.Numerical simulation results exhibit an average error of less than 5%,demonstrating the model’s reliability and predictive accuracy.The temperature distributions of both the metallic heat exchange surfaces and the flue gas are systematically analyzed.Results indicate that the solid and gas phases exhibit significant non-equilibrium thermal behavior.Notably,the circumferential temperature fluctuations of both the heat exchange surfaces and flue gas vary markedly with changes in rotational speed.At low rotational speeds,the temperature non-uniformity coefficient reaches 4.296,while at high speeds it decreases to 0.4813-indicating that lower speeds lead to more pronounced temperature fluctuations.The simulated temperature field patterns are consistent with experimental observations,validating the effectiveness of the modeling approach.
基金supported by grants from the National Natural Science Foundation of China(No.22375027)the Natural Science Foundation of Jiangsu Province(Nos.BK20221265,BK20211100)+1 种基金the Fundamental Research Funds for the Central Universities(No.DUT23YG133)the Research Funds from Liaoning Cancer Hospital(No.2024ZLKF-35)。
文摘A decomposable and sono-enzyme co-triggered nanoparticle(p TCP-CR NP)with“AND gate”logic was synthesized,combining a meso–carboxyl-porphyrin-based sonosensitizer(5,10,15,20-tetrakis(carboxyl)porphyrin,TCP)and a thiophenyl-croconium(2,5-bis[(2-(2-(2-hydroxyethoxy)ethoxy)ethyl-4-carboxylate-piperidylamino)thiophenyl]-croconium,CR)via ester groups.TCP releases carbon monoxide(CO)under ultrasound(US)irradiation,offering both sonodynamic and gas therapy.CR decomposes into stronger reactive oxygen species(ROS)compared to oxygen-based radicals.The F?rster resonance energy transfer(FRET)effect between TCP and CR inhibits ROS and CO generation until triggered by tumor cell overexpressed carboxylesterase(CEs).p TCP-CR NPs“AND gate”logic ensures activation only in the presence of both CEs and US,targeting tumor cells while safety in normal tissues.The ROS and CO generation abilities,as well as the releasing of SO_(4)^(·-)have been systemically examined.p TCP-CR can be thoroughly decomposed into low-toxic molecules post the treatment,showing the safety with negligible phototoxic reactions.In vivo anti-cancer therapy has been evaluated using mice bearing hepatocellular carcinoma.
基金supported by the National Key R&D Program of China(No.2022ZD0118402)。
文摘Remote sensing cross-modal image-text retrieval(RSCIR)can flexibly and subjectively retrieve remote sensing images utilizing query text,which has received more researchers’attention recently.However,with the increasing volume of visual-language pre-training model parameters,direct transfer learning consumes a substantial amount of computational and storage resources.Moreover,recently proposed parameter-efficient transfer learning methods mainly focus on the reconstruction of channel features,ignoring the spatial features which are vital for modeling key entity relationships.To address these issues,we design an efficient transfer learning framework for RSCIR,which is based on spatial feature efficient reconstruction(SPER).A concise and efficient spatial adapter is introduced to enhance the extraction of spatial relationships.The spatial adapter is able to spatially reconstruct the features in the backbone with few parameters while incorporating the prior information from the channel dimension.We conduct quantitative and qualitative experiments on two different commonly used RSCIR datasets.Compared with traditional methods,our approach achieves an improvement of 3%-11% in sumR metric.Compared with methods finetuning all parameters,our proposed method only trains less than 1% of the parameters,while maintaining an overall performance of about 96%.
基金supported by the Fundamental Research Funds for the Central Universities (2019JQ03015)the National Natural Science Foundation of China (42075169, U1810209)the Beijing Municipal Education Commission through the Innovative Transdisciplinary Program “Ecological Restoration Engineering”。
文摘Due to the advantages of low energy consumption and high CO_(2) selectivity, the development of solid amine-based materials has been regarded as a hot research topic in the field of DAC for the past decades.The adsorption capacity and stability over multiple cycles have been the top priorities for evaluation of practical application value. Herein, we synthesized a novel DAC material by loading TEPA onto defect-rich Mg_(0.55)Al-O MMOs with enhanced charge transfer effect. The optimal Mg_(0.55)Al-O-TEPA67% demonstrates the highest CO_(2)uptake of(3.0 mmol g^(-1)) and excellent regenerability, maintaining ~90% of the initial adsorption amount after 80 adsorption/desorption cycles. The in situ DRIFTS experiments suggested the formation of bicarbonate species under wet conditions. DFT calculations indicated that the stronger bonding between Mg_(0.55)Al-O support and solid amine was caused by the abundance of oxygen defects on MMOs confirmed by XPS and ESR, which favors the charge transfer between the support and amine,resulting in intense interaction and excellent regenerability. This work for the first time conducted comprehensive and systematic investigation on the stabilization mechanism for MMOs supported solid amine adsorbents with highest uptake and superior cyclic stability in depth, which is different from the most popular SiO_(2)-support, thus providing facile strategy and comprehensive theoretical mechanism support for future research about DAC materials.
基金Supported by the Key Laboratory of Microsatellites,Chinese Academy of Sciences
文摘A heavy-ion irradiation experiment is studied in digital storage cells with different design approaches in 130？nm CMOS bulk Si and silicon-on-insulator （SOI） technologies. The effectiveness of linear energy transfer （LET） with a tilted ion beam at the 130？nm technology node is obtained. Tests of tilted angles θ=0 ° , 30 ° and 60 ° with respect to the normal direction are performed under heavy-ion Kr with certain power whose LET is about 40？MeVcm 2 /mg at normal incidence. Error numbers in D flip-flop chains are used to determine their upset sensitivity at different incidence angles. It is indicated that the effective LETs for SOI and bulk Si are not exactly in inverse proportion to cosθ , furthermore the effective LET for SOI is more closely in inverse proportion to cosθ compared to bulk Si, which are also the well known behavior. It is interesting that, if we design the sample in the dual interlocked storage cell approach, the effective LET in bulk Si will look like inversely proportional to cosθ very well, which is also specifically explained.
文摘The kinetics of ion exchange between Ca2+, Mg2+, Co(Ⅱ), Cu(Ⅱ),Ni(Ⅱ), Fe(Ⅲ), y3+ or Sm3+ , respectively, in 0.50 mol/L HC1 and H+ on macrorecticular sulfonic ion exchange resin and the kinetics of the same reactions (M -H exchange) when Mn(Ⅱ) coexisted in resin phase as accelerating ion were studied. The accelerating effect manifested and its rule are consistent with the accelerating effect theory based on the concept concerned with adsorption electrical double layer which has been suggested in a previous paper published.
基金Supported by the National Natural Science Foundation of China under Grant No 61378037the Fundamental Research Funds for the Central Universities under Grant No JUSRP51628B
文摘We demonstrate a triple-pass scheme for coherent transfer of optical frequency and the delay effect on the fiber phase noise compensation. It is theoretically proved that the delay effect consists of both fiber delay and servo delay. The delay effect confines the servo bandwidth within 1/8 and induces a residual fiber phase noise after noise compensation. For a 25-km-long fiber, the servo bandwidth is found to be around 1 k Hz, and the fiber phase noise is suppressed approaching to the theoretical limitation. The triple-pass scheme enables the simultaneous transfer of optical frequency to multiple remote users. The performance of noise compensator in the triple-pass scheme can achieve a similar level result compared with that in the double-pass scheme.
基金Supported by the National Natural Science Foundation of China under Grant No 51377185
文摘Magnetic radiation phenomena appear inevitably in the magnetic-resonance wireless power transfer （MR-WPT） system, and regarding this problem the magnetic-shielding scheme is applied to improve the electromagnetic performance in engineering. In this study, the shielding effectiveness of a two-coil MR-WPT system for different material shields is analyzed in theory using Moser＇s formula and Schelkunoff＇s formula. On this basis a candidate magnetic-shielding scheme with a double-layer structure is determined, which has better shielding effectiveness and coils coupling coefficient. Finally, some finite element simulation results validate the correctness of the theoretical analysis, and the shielding effectiveness with the double-layer shield in maximum is 30？dB larger than the one with the single-layer case.
文摘Alloimmunization was combined with lympho-kine activated killer (LAK) cells to assess its effect on mammary carcinoma in rats. The animals were injected with both irradiated allosplenocytes and syngeneic LAK cells. Metastatic lung nodules were markedly reduced using combined therapy when compared with the transfer of LAK cells or alloimmuni-zation alone. IL-2 activity in the serum of alloim-munized rats could be detected. This activity, maintained in vivo for one week, may be responsible for enhancing the antitumor effect of transferred LAK cells.
基金Project supported by the Collaborative Research in Engineering,Science&Technology(Grant No.P28C2-13)
文摘Miniaturization of electronic package leads to high heat density and heat accumulation in electronics device, resulting in short life time and premature failure of the device. Junction temperature and thermal resistance are the critical parameters that determine the thermal management and reliability in electronics cooling. Metal oxide field effect transistor（MOSFET）is an important semiconductor device for light emitting diode-integrated circuit（LED IC） driver application, and thermal management in MOSFET is a major challenge. In this study, investigations on thermal performance of MOSFET are performed for evaluating the junction temperature and thermal resistance. Suitable modifications in FR4 substrates are proposed by introducing thermal vias and copper layer coating to improve the thermal performance of MOSFET. Experiments are conducted using thermal transient tester（T3ster） at 2.0 A input current and ambient temperature varying from25℃ to 75℃. The thermal parameters are measured for three proposed designs： FR4 with circular thermal vias, FR4 with single strip of copper layer and embedded vias, and FR4 with I-shaped copper layer, and compared with that of plain FR4 substrate. From the experimental results, FR4I-shaped shows promising results by 33.71% reduction in junction temperature and 54.19% reduction in thermal resistance. For elevated temperature, the relative increases in junction temperature and thermal resistance are lower for FR4I-shaped than those for other substrates considered. The introduction of thermal vias and copper layer plays a significant role in thermal performance.
基金supported by the National Natural Science Foundation of China (82001919)the Guangdong Basic and Applied Basic Research Foundation (2022A1515010050)+2 种基金the China Postdoctoral Science Foundation (2022M711219)the Key Realm R&D Program of Guangdong Province (2019B03035001)the Foundation of Guangdong Provincial Key Laboratory of Sensor Technology and Biomedical Instruments (2020B1212060077).
文摘Obstructive sleep apnea-hypopnea syndrome(OSAHS)significantly impairs children's growth and cognition.This study aims to elucidate the pathophysiological mechanisms underlying OSAHS in children,with a particular focus on the alterations in cortical information interaction during respiratory events.We analyzed sleep electroencephalography before,during,and after events,utilizing Symbolic Transfer Entropy(STE)for brain network construction and information flow assessment.The results showed a significant increase in STE after events in specific frequency bands during N2 and rapid eye movement(REM)stages,along with increased STE during N3 stage events.Moreover,a noteworthy rise in the information flow imbalance within and between hemispheres was found after events,displaying unique patterns in central sleep apnea and hypopnea.Importantly,some of these alterations were correlated with symptom severity.These findings highlight significant changes in brain region coordination and communication during respiratory events,offering novel insights into OSAHS pathophysiology in children.
基金financially supported by the Innovation Support Programme(Soft Science Research)Project Achievements of Jiangsu Province(No.BK20231514)National Natural Science Foundation of China(No.22479079).
文摘The rational design of high-performance catalysts is crucial for advancing energy conversion and storage technologies.Single-atom and nanoparticle synergistic catalysts(SAC-NPs)have garnered significant attention due to their ability to precisely modulate electronic structures and optimize intermediate adsorption energies.SACs exhibit maximized atomic utilization and well-defined active sites;however,their restricted electronic tunability and inherent instability limit their widespread application.Conversely,NPs provide superior charge transfer capabilities and enhanced catalytic stability,effectively complementing SACs.The SAC-NPs leverage atomic-scale electronic interactions to enhance catalytic activity,stability,and reaction kinetics,making it a promising platform for electrocatalysis.Therefore,elucidating the synergistic catalytic mechanisms of SAC-NPs and refining optimization strategies are crucial for advancing the development of high-performance catalysts.This review systematically summarizes the synthesis strategies and structural modulation approaches of SAC-NPs.Furthermore,the synergistic catalytic mechanisms,encompassing electron transfer,tandem catalysis,and bifunctional catalysis,are critically examined from both experimental and theoretical perspectives.Finally,recent advancements in SAC-NPs for key electrocatalytic reactions are reviewed,along with current challenges and future research directions.This work aims to provide comprehensive theoretical and practical guidance for the development of SAC-NPs,facilitating the rational design of next-generation catalysts and advancing renewable energy technologies.
文摘With the growing need for greater cooling capacity in electronic and heat exchange systems,significant attention has been directed toward improving the heat transfer by incorporating nanoparticles into the base fluid.While the use of nanoparticles in spray cooling shows promise for enhancing heat transfer,additional clarification is required.The paper compiles empirical data from existing literature focusing on spray cooling using nanofluids.Its objective is to clarify how nanoparticles impact the efficiency of spray heat transfer and investigate the effects of factors such as spray Weber number,nanoparticle concentration and droplet spread.Gathered data reveal that when compared to water droplets,nanofluid droplets exhibited more extensive surface spreading at low impinging droplet Weber numbers.Data also show that the heat transfer effectiveness of nanofluid sprays at the critical heat flux and film boiling temperature decreases with the increase in the spray Weber number.At the critical heat flux temperature and for intermediate spray Weber numbers,sprays utilizing nanofluids are more effective than sprays utilizing pure water;however,the situation reverses when dealing with exceedingly high Weber numbers.The data indicate that for surfaces heated within the film boiling range,it remains unclear whether sprays containing nanoparticles demonstrate higher heat transfer efficiency compared to sprays using pure water alone.For surfaces heated to the critical heat flux temperature,there is a critical nanoparticle concentration below which spraying with pure water is more effective than spraying with a nanofluid.However,for surfaces heated to temperatures near the Leidenfrost point,there is no clear indication that nanoparticle concentration plays a role.With the introduction of nanoparticles into sprays,there is a tendency for both the critical heat flux and the Leidenfrost temperatures to shift to a higher temperature range and to increase with the increase in nanoparticle concentration.
基金supported by the National Natural Science Foundation of China(Grant No.U21A2054,51961011,52273285,52262032)National Key Research and Development Program of China(Grant No.2022YFE0119100)Sinoma Institute of Materials Research(Guang Zhou)Co.,Ltd(SIMR)for assisting the characterization of TEM images/SAED patterns.
文摘SiGe based alloy is a promising medium-high temperature thermoelectric material that has been applied in the field of aerospace exploration.So far,utilizing the second phase to promote the scattering of phonons is a common way to improve the thermoelectric performance of SiGe based alloy,but this often deteriorates the electrical properties.In this study,the Si_(80)Ge_(20)P_(1)/CoSi_(2) composites have been prepared by mechanical alloying and spark plasma sintering,and the content of cobalt silicide(CoSi_(2))nanoparticles have been manipulated.Since the CoSi_(2) nanoparticles possess higher carrier concentration and smaller work function than the Si_(80)Ge_(20)P_(1) matrix,the carrier concentrations of composites have been pushed up due the charge transfer effect.Meanwhile,the formation of nano-sized phase interfaces and stacking faults in the composites has enhanced the scattering of low-frequency phonons.As a result,the optimal power factor of 3.41 mW·m^(-1),K^(-2) and thermal conductivity of 2.29 W·m^(-1),K^(-1) have been achieved,and the corresponding zT reaches up to 1.3 in the Si_(80)Ge_(20)P_(1)+0.5%CoSi_(2)(in mole)composite at 873 K.This work provides a new idea for developing the performance of SiGe based alloy.
基金The National Natural Science Foundation of China(No.40902076)the Natural Science Foundation of Jiangsu Province(No.BK20141224)
文摘Considering the coupled heat transfer effect induced by parallel cross-river road tunnels, the long-term soil temperature variations of shallow sections of cross-river tunnels under the river beach are predicted using the finite difference method for numerical simulation. The boundary conditions and the initial values are determined by in situ observations and numerical iterations.The simulation results indicate that the ultimate calculated steady heat transfer time is 68 years, and most of the heat transfer is completed in 20 years.The initial constant temperature soil surrounding the tunnels is transformed to an annually variable one.An obvious temperature-varying region of the surrounding soil is discovered within 5 m from the tunnel exterior, as well as within the entire range of soil between the two tunnels.The maximum temperature increase value reaches 7.14 ℃ and the maximum peak-to-valley value of annual temperature increase reaches 10 ℃.The temperature variation of soils surrounding tunnels below 10 m is completely controlled by the heat transfer from the tunnels.The coupled heat transfer effect is confirmed because the ultimate steady temperature of soil between the two tunnels is higher than the ones along other positions.Moreover, the regression model comprising a series of univariate functions is proposed for the annual soil temperature fluctuation estimation for the locations varied distances around the tunnel.This investigation is beneficial to gain an insight into the long-term variation tendencies of local engineering geological conditions of the river beach above shallow sections of the cross-river road tunnels.
