Two kinds of high pure silver materials with 5.3 ppm oxygen and 32.7 ppm oxygen were prepared by various melting processes, both samples were subjected to accumulative rolling with 95% thickness reduction. Their mecha...Two kinds of high pure silver materials with 5.3 ppm oxygen and 32.7 ppm oxygen were prepared by various melting processes, both samples were subjected to accumulative rolling with 95% thickness reduction. Their mechanical properties were tested during long natural aging. Results showed that the Ag sheet with 5.3 ppm oxygen is at full annealed state when natural aging 58 days or kept at 150℃ for 30 minutes, and the Ag sheet with 32.7 ppm oxygen is a little of recovery when natural aging a year. It is suggested that appropriate oxygen interstitial solute in Ag solid solution and a few of Ag2O particles at Ag grain boundaries impede the recovery and recrystallization of Ag sheets.展开更多
This study evaluated the Cretaceous(Campanian–Maastrichtian) kaolinitic sediments of the Ajali/Mamu and Enugu/Nkporo Formations from the Lower Benue Trough of Nigeria. A combined method of inductively coupled plasma...This study evaluated the Cretaceous(Campanian–Maastrichtian) kaolinitic sediments of the Ajali/Mamu and Enugu/Nkporo Formations from the Lower Benue Trough of Nigeria. A combined method of inductively coupled plasma–mass spectrometry and isotope ratio mass spectrometry was used to investigate trace and rareearth element geochemistry and hydrogen and oxygen isotopic compositions. These data were then used to infer the sediments' provenance and paleoclimatic conditions during their deposition. The sediments contained low concentrations of most trace elements, with the exceptions of Zr(651–1352 ppm), Ba(56–157 ppm), V(38–90 ppm),and Sr(15.1–59.6 ppm). Average values of Co and Ni were1.5 and 0.7 ppm, respectively. Trace and rare earth element values were lower than corresponding values for upper continental crust and Post-Archean Australian Shale, with the exception of Zr. The samples showed only slight light rare-earth enrichment and nearly flat heavy rare-earth depletion patterns, with negative Eu and Tm anomalies,typical of felsic sources. Geochemical parameters such as La/Sc, Th/Sc, and Th/Co ratios support that the kaolinitic sediments were derived from a felsic rock source, likely deposited in an oxic environment.^(18 )O values ranged from+ 15.4 to + 21.2% for the investigated samples, consistent with a residual material derived from chemicalweathering of felsic rock and redeposited in a sedimentary basin(typical values of + 19 to + 21.2%). While in the basin, the sediments experienced extended interactions with meteoric water enriched in d D and d16 O. However,the variation in d D and d16 O values for the investigated samples is attributed to the high temperature of formation(54–91 °C). The d D and d^(18 )O values suggest that the sediments, although obtained from different localities within the Lower Benue Trough, formed under similar hot,tropical climatic conditions.展开更多
Organic semiconductors(OSCs)are showing great promise in large-area wearable devices,optoelectronic displays,logic circuits,and next-generation optoelectronic applications[1-9].Examples include organic field-effect tr...Organic semiconductors(OSCs)are showing great promise in large-area wearable devices,optoelectronic displays,logic circuits,and next-generation optoelectronic applications[1-9].Examples include organic field-effect transistors(OFETs),organic light-emitting diodes(OLEDs),organic photovoltaic cells(OPVs),and sensing devices.However,OSCs encounter significant challenges in widespread commercialization[10-13].Compared with their inorganic counterparts connected by strong covalent bonds,the structural characteristics of OSCs films are predominantly governed by van der Waals interactions[14-19],rendering their optoelectronic properties typically dependent on the synergistic effects between intrinsic properties and extrinsic effects,such as impurities and defects[20-26].展开更多
Major elements, trace elements and Sr isotopic compositions of apatite from the granite in the Chengchao skarn-type Fe deposit of Edong ore district of Middle-Lower Yangtze River metallogenic belt were measured using ...Major elements, trace elements and Sr isotopic compositions of apatite from the granite in the Chengchao skarn-type Fe deposit of Edong ore district of Middle-Lower Yangtze River metallogenic belt were measured using EMPA （electron microprobe）, LA-ICP-MS （laser ablation inductively coupled plasma mass spectrometer） and LA-MC （multicollector）-ICP-MS methods in order to reveal the petroge- netic and metallogenic significance of the skarn-type iron deposits. The results show that the apatite in Chengchao granite is fluorapatite, which displays slight variation in major elements. The REE distribution pattern of the apatite is similar to that of the whole rocks, with strong negative Eu anomaly and low Sr/Y ratio. The concentration of Mn in apatite is low （140 ppm-591 ppm） and the Sr isotopic composition shows a limited variation from 0.706 9 to 0.708 2. The high oxygen fugacity of the Chengchao granite, implied by the low Mn content in apatite, is possibly attributed to contamination of the gypsum from sedimentary rock strata, which has long been thought to be an important factor that controls the Fe mineralization in the Middle-Lower Yangtze River metallogenic bell This study also proves that the Eu/Eu＊ value and Sr/Y ra- tio in apatite can be effectively used to identify the adakitie affinity. The in situ Sr isotope analysis of apatite is in consistent with the bulk rock analysis, which indicates that the apatite Sr isotope can represent the ini- tial Sr isotopic compositions of the magma. The Sr isotope and negative Eu anomaly in apatite imply that the Chengchao granite is likely sourced from crust-mantle mixed materials.展开更多
The Nanling Range in South China is well known for its rich granite-related W–Sn deposits.To elucidate the controls of different granite-related W–Sn metallogenesis in the region,we chose five representative orerela...The Nanling Range in South China is well known for its rich granite-related W–Sn deposits.To elucidate the controls of different granite-related W–Sn metallogenesis in the region,we chose five representative orerelated granites(Yanbei,Mikengshan,Tieshanlong,Qianlishan,and Yaogangxian intrusions)in the Hunan–Jiangxi region,and studied their magmatic zircon ages and trace element geochemistry.Our new zircon data showed the differences in ages,temperatures and oxygen fugacity of the ore-forming magmas.Zircon U–Pb ages of the Yanbei and Mikengshan intrusions are characterized by 142.4±2.4 and 143.0±2.3 Ma,respectively,whereas the Tieshanlong and Qianlishan intrusions are 159.5±2.3and 153.2±3.3 Ma,respectively.The Sn-related intrusions were younger than the W-related intrusions.The Tiin-zircon thermometry showed that there was no systematic difference between the Sn-related Yanbei(680–744℃)and Mikengshan(697–763℃)intrusions and the W-related Tieshanlong(730–800℃),Qianlishan(690–755℃)and Yaogangxian(686–751℃)intrusions.However,the zircon Ce^4+/Ce^3+ratios of the Yanbei(averaged at 18.3)and Mikengshan(averaged at 18.8)intrusions are lower than those of the Tieshanlong(averaged at 36.9),Qianlishan(averaged at 38.4)and Yaogangxian(averaged at 37)intrusions,indicating that the Sn-related granitic magmas might have lower oxygen fugacities than those of the W-related.This can be explained by that,in more reduced magmas,Sn is more soluble than W and thus is more enriched in the residual melt to form Sn mineralization.The difference in source materials between the Sn-related and the W-related granites seems to have contributed to the different redox conditions of the melts.展开更多
Silica sinter developed on the northern shore of Lake Usoriyama in the Osorezan geothermal field was examined for the occurrence, texture, crystallinity of silica minerals, and the concentrations of trace elements and...Silica sinter developed on the northern shore of Lake Usoriyama in the Osorezan geothermal field was examined for the occurrence, texture, crystallinity of silica minerals, and the concentrations of trace elements and oxygen isotopes. The silica sinter consists of a thick eastern mound (layer A) and a thin western part (layer B). Most of the silica sinter is composed of alternating bands of thin layers of silica minerals with colors varying from white to yellow and reddish gray. There is a unique stromatolitic texture, an aggregate of stratified concentric layers that extends upward and is red to reddish gray in color in the middle of layer A. Silica minerals, mainly opal-A and opal-CT, dominate the mineralogical constituents of the sinter. The δ18O of the silica mineral in layer A varies between 13‰ and 26‰, while layer B has higher values, between 19‰ and 33‰. The hydrothermal fluid from which the silica sinter precipitated is dominated by meteoric water is similar to present-day hot spring water.展开更多
文摘Two kinds of high pure silver materials with 5.3 ppm oxygen and 32.7 ppm oxygen were prepared by various melting processes, both samples were subjected to accumulative rolling with 95% thickness reduction. Their mechanical properties were tested during long natural aging. Results showed that the Ag sheet with 5.3 ppm oxygen is at full annealed state when natural aging 58 days or kept at 150℃ for 30 minutes, and the Ag sheet with 32.7 ppm oxygen is a little of recovery when natural aging a year. It is suggested that appropriate oxygen interstitial solute in Ag solid solution and a few of Ag2O particles at Ag grain boundaries impede the recovery and recrystallization of Ag sheets.
文摘This study evaluated the Cretaceous(Campanian–Maastrichtian) kaolinitic sediments of the Ajali/Mamu and Enugu/Nkporo Formations from the Lower Benue Trough of Nigeria. A combined method of inductively coupled plasma–mass spectrometry and isotope ratio mass spectrometry was used to investigate trace and rareearth element geochemistry and hydrogen and oxygen isotopic compositions. These data were then used to infer the sediments' provenance and paleoclimatic conditions during their deposition. The sediments contained low concentrations of most trace elements, with the exceptions of Zr(651–1352 ppm), Ba(56–157 ppm), V(38–90 ppm),and Sr(15.1–59.6 ppm). Average values of Co and Ni were1.5 and 0.7 ppm, respectively. Trace and rare earth element values were lower than corresponding values for upper continental crust and Post-Archean Australian Shale, with the exception of Zr. The samples showed only slight light rare-earth enrichment and nearly flat heavy rare-earth depletion patterns, with negative Eu and Tm anomalies,typical of felsic sources. Geochemical parameters such as La/Sc, Th/Sc, and Th/Co ratios support that the kaolinitic sediments were derived from a felsic rock source, likely deposited in an oxic environment.^(18 )O values ranged from+ 15.4 to + 21.2% for the investigated samples, consistent with a residual material derived from chemicalweathering of felsic rock and redeposited in a sedimentary basin(typical values of + 19 to + 21.2%). While in the basin, the sediments experienced extended interactions with meteoric water enriched in d D and d16 O. However,the variation in d D and d16 O values for the investigated samples is attributed to the high temperature of formation(54–91 °C). The d D and d^(18 )O values suggest that the sediments, although obtained from different localities within the Lower Benue Trough, formed under similar hot,tropical climatic conditions.
基金supported by the National Key Research and Development Program of China(2024YFA1209600 to Li L)the National Natural Science Foundation of China(52225304 and 52073210 to Li L,52403243 to Huang Y)。
文摘Organic semiconductors(OSCs)are showing great promise in large-area wearable devices,optoelectronic displays,logic circuits,and next-generation optoelectronic applications[1-9].Examples include organic field-effect transistors(OFETs),organic light-emitting diodes(OLEDs),organic photovoltaic cells(OPVs),and sensing devices.However,OSCs encounter significant challenges in widespread commercialization[10-13].Compared with their inorganic counterparts connected by strong covalent bonds,the structural characteristics of OSCs films are predominantly governed by van der Waals interactions[14-19],rendering their optoelectronic properties typically dependent on the synergistic effects between intrinsic properties and extrinsic effects,such as impurities and defects[20-26].
基金supported by the National Key R & D Program of China (No. 2016YFC0600206)the China Geological Survey (No. 12120114051801)
文摘Major elements, trace elements and Sr isotopic compositions of apatite from the granite in the Chengchao skarn-type Fe deposit of Edong ore district of Middle-Lower Yangtze River metallogenic belt were measured using EMPA （electron microprobe）, LA-ICP-MS （laser ablation inductively coupled plasma mass spectrometer） and LA-MC （multicollector）-ICP-MS methods in order to reveal the petroge- netic and metallogenic significance of the skarn-type iron deposits. The results show that the apatite in Chengchao granite is fluorapatite, which displays slight variation in major elements. The REE distribution pattern of the apatite is similar to that of the whole rocks, with strong negative Eu anomaly and low Sr/Y ratio. The concentration of Mn in apatite is low （140 ppm-591 ppm） and the Sr isotopic composition shows a limited variation from 0.706 9 to 0.708 2. The high oxygen fugacity of the Chengchao granite, implied by the low Mn content in apatite, is possibly attributed to contamination of the gypsum from sedimentary rock strata, which has long been thought to be an important factor that controls the Fe mineralization in the Middle-Lower Yangtze River metallogenic bell This study also proves that the Eu/Eu＊ value and Sr/Y ra- tio in apatite can be effectively used to identify the adakitie affinity. The in situ Sr isotope analysis of apatite is in consistent with the bulk rock analysis, which indicates that the apatite Sr isotope can represent the ini- tial Sr isotopic compositions of the magma. The Sr isotope and negative Eu anomaly in apatite imply that the Chengchao granite is likely sourced from crust-mantle mixed materials.
基金supported by the National Basic Research Program of China (973 Program) (Grants No. 2014CB440906)Innovation Team Program of Chinese Academy of Sciences (Overseas Famous Scholars Program)‘‘Light of West China’’ Program of Chinese Academy of Sciences
文摘The Nanling Range in South China is well known for its rich granite-related W–Sn deposits.To elucidate the controls of different granite-related W–Sn metallogenesis in the region,we chose five representative orerelated granites(Yanbei,Mikengshan,Tieshanlong,Qianlishan,and Yaogangxian intrusions)in the Hunan–Jiangxi region,and studied their magmatic zircon ages and trace element geochemistry.Our new zircon data showed the differences in ages,temperatures and oxygen fugacity of the ore-forming magmas.Zircon U–Pb ages of the Yanbei and Mikengshan intrusions are characterized by 142.4±2.4 and 143.0±2.3 Ma,respectively,whereas the Tieshanlong and Qianlishan intrusions are 159.5±2.3and 153.2±3.3 Ma,respectively.The Sn-related intrusions were younger than the W-related intrusions.The Tiin-zircon thermometry showed that there was no systematic difference between the Sn-related Yanbei(680–744℃)and Mikengshan(697–763℃)intrusions and the W-related Tieshanlong(730–800℃),Qianlishan(690–755℃)and Yaogangxian(686–751℃)intrusions.However,the zircon Ce^4+/Ce^3+ratios of the Yanbei(averaged at 18.3)and Mikengshan(averaged at 18.8)intrusions are lower than those of the Tieshanlong(averaged at 36.9),Qianlishan(averaged at 38.4)and Yaogangxian(averaged at 37)intrusions,indicating that the Sn-related granitic magmas might have lower oxygen fugacities than those of the W-related.This can be explained by that,in more reduced magmas,Sn is more soluble than W and thus is more enriched in the residual melt to form Sn mineralization.The difference in source materials between the Sn-related and the W-related granites seems to have contributed to the different redox conditions of the melts.
文摘Silica sinter developed on the northern shore of Lake Usoriyama in the Osorezan geothermal field was examined for the occurrence, texture, crystallinity of silica minerals, and the concentrations of trace elements and oxygen isotopes. The silica sinter consists of a thick eastern mound (layer A) and a thin western part (layer B). Most of the silica sinter is composed of alternating bands of thin layers of silica minerals with colors varying from white to yellow and reddish gray. There is a unique stromatolitic texture, an aggregate of stratified concentric layers that extends upward and is red to reddish gray in color in the middle of layer A. Silica minerals, mainly opal-A and opal-CT, dominate the mineralogical constituents of the sinter. The δ18O of the silica mineral in layer A varies between 13‰ and 26‰, while layer B has higher values, between 19‰ and 33‰. The hydrothermal fluid from which the silica sinter precipitated is dominated by meteoric water is similar to present-day hot spring water.
