Wound dressing management is critical in healthcare,and frequent dressing changes for full-thickness skin wounds can hinder healing.Nanofiber dressings that resemble the extracellular matrix,have gained popularity in ...Wound dressing management is critical in healthcare,and frequent dressing changes for full-thickness skin wounds can hinder healing.Nanofiber dressings that resemble the extracellular matrix,have gained popularity in wound repair,however,it is challenging to explore how to frequently change it without affecting healing processing and avoiding secondary damage.Here,we developed a self-adhesive and detachable nanofiber dressing inspired by Andrias davidianus.Our asymmetric nanofiber dressing exhibits strong adhesion(26 kPa),to the wound at high temperature(approximately 25°C)to the wound surface and can be easily detached(4 kPa)at low temperature(below 8°C),enabling painless dressing changes that minimize secondary injuries.The dressing comprises an outer layer of polylactic acid which provides mechanical property,support,and pollution resistance,with an inner layer of nanofibrous membrane,composed of gelatin and Andrias davidianus skin secretions,which promotes cellular migration,enhances wound healing and possesses inherent antimicrobial properties.Furthermore,the all-natural nanofiber dressings can be prepared on a large scale and offer favorable biocompatibility to meet the basic requirements of wound dressings.These findings demonstrate the potential applicability of our multilayer nanofiber dressing for advancing wound healing practices.展开更多
Temperature-responsive polymers have garnered significant attention due to their ability to respond to external stimuli.In this work,dual temperature-responsive block copolymers are synthesized via reversible addition...Temperature-responsive polymers have garnered significant attention due to their ability to respond to external stimuli.In this work,dual temperature-responsive block copolymers are synthesized via reversible addition-fragmentation chain transfer polymerization(RAFT)polymerization utilizing zwitterionic monomer methacryloyl ethyl sulfobetaine(SBMA) and N-isopropyl acrylamide(NIPAAm) as monomers.The thermal responsive behaviors can be easily modulated by incorporating additional hydrophobic monomer benzyl acrylate(BN) or hydrophilic monomer acrylic acid(AA),adjusting concentration or pH,or varying the degree of polymerization of the block chain segments.The cloud points of the copolymers are determined by UV-Vis spectrophotometry,and these copolymers exhibit both controlled upper and lower critical solu bility temperatures(LCST and UCST) in aqueous solution.This study analyzes and summarizes the influencing factors of dual temperature responsive block copolymers by exploring the effects of various conditions on the phase transition temperature of temperature-sensitive polymers to explore the relationship between their properties and environment and structure to make them more selective in terms of temperature application range and regulation laws.It is very interesting that the introduction of poly-acrylic acid(PAA) segments in the middle of di-block copolymer PSBMA_(55)-b-PNIPAAm_(80) to form PSBMA_(55)-b-PAA_(x)-b-PNIPAAm_(80) results in a reversal of temperature-responsive behaviors from 'U'(LCST UCST) type,while the copolymer PSBMA_(55)-b-P(NIPAAm_(80)-co-AA_(x)) not.This work provides a clue for tuning the phase transition behavior of polymers for manufacture of extreme smart materials.展开更多
Nanofiber membranes(NFMs) have become attractive candidates for next-generation flexible transparent materials due to their exceptional flexibility and breathability. However, improving the transmittance of NFMs is a ...Nanofiber membranes(NFMs) have become attractive candidates for next-generation flexible transparent materials due to their exceptional flexibility and breathability. However, improving the transmittance of NFMs is a great challenge due to the enormous reflection and incredibly poor transmission generated by the nanofiber-air interface. In this research, we report a general strategy for the preparation of flexible temperature-responsive transparent(TRT) membranes,which achieves a rapid transformation of NFMs from opaque to highly transparent under a narrow temperature window. In this process, the phase change material eicosane is coated on the surface of the polyurethane nanofibers by electrospray technology. When the temperature rises to 37 ℃, eicosane rapidly completes the phase transition and establishes the light transmission path between the nanofibers, preventing light loss from reflection at the nanofiber-air interface. The resulting TRT membrane exhibits high transmittance(> 90%), and fast response(5 s). This study achieves the first TRT transition of NFMs, offering a general strategy for building highly transparent nanofiber materials, shaping the future of next-generation intelligent temperature monitoring, anti-counterfeiting measures, and other high-performance devices.展开更多
This work introduces special states for light in multimode fibers featuring strongly enhanced or reduced correlations be-tween output fields in the presence of environmental temperature fluctuations.Using experimental...This work introduces special states for light in multimode fibers featuring strongly enhanced or reduced correlations be-tween output fields in the presence of environmental temperature fluctuations.Using experimentally measured multi-tem-perature transmission matrix,a set of temperature principal modes that exhibit resilience to disturbances caused by tem-perature fluctuations can be generated.Reversing this concept also allows the construction of temperature anti-principal modes,with output profiles more susceptible to temperature influences than the unmodulated wavefront.Despite changes in the length of the multimode fiber within the temperature-fluctuating region,the proposed approach remains capable of robustly controlling the temperature response within the fiber.To illustrate the practicality of the proposed spe-cial state,a learning-empowered fiber specklegram temperature sensor based on temperature anti-principal mode sensi-tization is proposed.This sensor exhibits outstanding superiority over traditional approaches in terms of resolution and accuracy.These novel states are anticipated to have wide-ranging applications in fiber communication,sensing,imaging,and spectroscopy,and serve as a source of inspiration for the discovery of other novel states.展开更多
Control crosslink network and chain connectivity are essential to develop shape memory polymers(SMPs)with high shape memory capabilities,adjustable response temperature,and satisfying mechanistical properties.In this ...Control crosslink network and chain connectivity are essential to develop shape memory polymers(SMPs)with high shape memory capabilities,adjustable response temperature,and satisfying mechanistical properties.In this study,novel poly(ε-caprolactone)(PCL)-poly(2-vinyl)ethylene glycol(PVEG)copolymers bearing multi-pendant vinyl groups is synthesized by branched-selective allylic etherification polymerization of vinylethylene carbonate(VEC)with linear and tetra-arm PCLs under a synergistic catalysis of palladium complex and boron reagent.Facile thiol-ene photo-click reaction of PCL-PVEG copolymers with multifunctional thiols can rapidly access a serious crosslinked SMPs with high shape memory performance.The thermal properties,mechanical properties and response temperature of the obtained SMPs are tunable by the variation of PCL prepolymers,vinyl contents and functionality of thiols.Moreover,high elastic modulus in the rubbery plateau region can be maintained effectively owing to high-density topological networks of the PCL materials.In addition,the utility of the present SMPs is further demonstrated by the post-functionalization via thiol-ene photo-click chemistry.展开更多
Organic perovskites are promising semiconductor materials for advanced photoelectric applications.Their fluorescence typically shows a negative temperature coefficient due to bandgap change and structural instability....Organic perovskites are promising semiconductor materials for advanced photoelectric applications.Their fluorescence typically shows a negative temperature coefficient due to bandgap change and structural instability.In this study,a novel perovskite-based composite with positive sensitivity to temperature was designed and obtained based on its inverse temperature crystallization,demonstrating good flexibility and solution processability.The supercritical drying method was used to address the limitations of annealing drying in preparing high-performance perovskite.Optimizing the precursor composition proved to be an effective approach for achieving high fluorescence and structural integrity in the perovskite material.This perovskite-based composite exhibited a positive temperature sensitivity of 28.563%℃^(-1)for intensity change and excellent temperature cycling reversibility in the range of 25-40℃in an ambient environment.This made it suitable for use as a smart window with rapid response.Furthermore,the perovskite composite was found to offer temperature-sensing photoluminescence and flexible processability due to its components of perovskite-based compounds and polyethylene oxide.The organic precursor solvent could be a promising candidate for use as ink to print or write on various substrates for optoelectronic devices responding to temperature.展开更多
In the feeding process of aluminum electrolytic, feeding quantity of alumina affects eventually dissolved quantity at the end of a feeding cycle. Based on the OpenFOAM platform, dissolution model coupled with heat and...In the feeding process of aluminum electrolytic, feeding quantity of alumina affects eventually dissolved quantity at the end of a feeding cycle. Based on the OpenFOAM platform, dissolution model coupled with heat and mass transfer was established. Applying the Rosin-Rammler function, alumina particle size distribution under different feeding quantities was obtained. The temperature response of electrolyte after feeding was included and calculated, and the dissolution processes of alumina with different feeding quantities (0.6, 0.8, 1.0, 1.2, 1.4, 1.6 kg) after feeding were simulated in 300 kA aluminum reduction cell. The results show that with the increase of feeding quantity, accumulated mass fraction of dissolved alumina decreases, and the time required for the rapid dissolution stage extends. When the feeding quantity is 0.6 kg and 1.2 kg, it takes the shortest time for the electrolyte temperature dropping before rebounding back. With the increase of feeding quantity, the dissolution rate in the rapid dissolution stage increases at first and then decreases gradually. The most suitable feeding quantity is 1.2 kg. The fitting equation of alumina dissolution curve under different feeding quantities is obtained, which can be used to evaluate the alumina dissolution and guide the feeding quantity and feeding cycle.展开更多
A process-oriented methodology to conduct precise evaluation temporally and spatially on temperature suitability for potato growth was applied in China. Arable lands in China were gridded with 1 km×1 km geographi...A process-oriented methodology to conduct precise evaluation temporally and spatially on temperature suitability for potato growth was applied in China. Arable lands in China were gridded with 1 km×1 km geographic units, and potential potato phenology in each unit was automatically identified in terms of the potato planting initial temperature and effective accu- mulated temperature. A temperature thermal response coefficient model was used to compute a temperature suitability value for each day of potato phenology in each geographic unit. In addition, five temperature suitability ranking methods were applied to define suitable areas： （1） upper fourth quantile, （2） median, （3） expected value＋1/4 standard deviation, （4） expected value＋1/2 standard deviation, （5） expected value＋1 standard deviation. A validation indicator was innovated to test the effectiveness of the five ranking methods. The results showed that from a strict degree point of view, the five methods sequence was as follows： 1=3〉4〉2〉5, with a and c determined as the two best ranking methods. For methods 1 and 3, the suitable potato growing area was 1 of 57.76× 10^4 km2. In addition, the suitable, areas were spatially coincident with the main potato producing counties. The study output technically supports the proposal from China＇s government that there is a large potential area to grow winter-ploughed potato in South China because the potential suitable area for growing potato is approximately 2×10^7 ha. In southeast Heilongjiang and east Jilin, where it is hilly and mountainous, there are still some potentially suitable areas for potato growing accounting for nearly 2.32×10^6 ha. The authors suggest to optimize the agricultural regionalization and layout in China and to adjust the cropping pattern structure.展开更多
The influence of temperature-dependent properties on temperature response and optimum design of newly developed ceramic-metal functionally graded materials under cyclic thermal loading and high temperature gradient en...The influence of temperature-dependent properties on temperature response and optimum design of newly developed ceramic-metal functionally graded materials under cyclic thermal loading and high temperature gradient environment is studied. The thermal conductivity of the material is considered to be dependent on the temperature. In this paper, the temperature response of the material is calculated using a nonlinear finite element method. Emphasis is placed on the influence of temperatue-dependent properties on the thermal response and insulation property of the material render the different graded compositional distributions and different heat flux magnitudes. Through the analysis, it is suggested that the influence of temperature-dependent properties can not be neglected in the temperature response analysis and the optimum design process of the material must be based on the temperature-dependent temperature analysis theory.展开更多
Temperature response functions have been developed to investigate sensor design and divertor heat flux estimation in magnetically confined plasmas. The time-dependent heat flux can be derived by fitting the response f...Temperature response functions have been developed to investigate sensor design and divertor heat flux estimation in magnetically confined plasmas. The time-dependent heat flux can be derived by fitting the response function to experimental thermocouple(TC) data. Because the TC signals have a time delay to transit events such as discharge start or confinement transition, the time delay is taken into account in a temperature response function. Such a function accurately describes the signal from each TC channel with time delay in a sensor test using a neutral beam injection. Measurement for commercial TCs shows that the time delay is caused by the finite heat capacity of TC wire and contact heat resistance between TC and target surface.展开更多
A theoretical model for calculation of the sample temperature during straight-line nitrogen ion implantation was established based on the results of experiment in this paper. Taking the pure aluminum as the samples, a...A theoretical model for calculation of the sample temperature during straight-line nitrogen ion implantation was established based on the results of experiment in this paper. Taking the pure aluminum as the samples, and from the transformation of electric energy into thermal energy, the calculated values of the temperature were in good agreement with the measured values in the experiment. According to the simulation, this technology can be applied to the control of specimens temperature during the implantation.展开更多
[Objectives]This study was conducted to investigate the differences in the physiological responses of different grape cultivars to high temperature.[Methods]The 19 tested cultivars were selected from the grape germpla...[Objectives]This study was conducted to investigate the differences in the physiological responses of different grape cultivars to high temperature.[Methods]The 19 tested cultivars were selected from the grape germplasm resources pool of Turpan Research Institute of Xinjiang Academy of Agricultural Sciences.Twelve physiological indexes including gas exchange parameters,chlorophyll content,antioxidant enzyme activity and proline content were determined in grape leaves under field conditions during the middle period of local natural high temperature period(July,daily maximum air temperature>35℃).The heat tolerance of different cultivars was evaluated by fuzzy membership function analysis and optimum partitioning clustering of ordered samples.[Results](1)Under natural high temperature conditions in Turpan,the 19 tested grape cultivars responded differently to high temperature.‘Red Globe’,‘Fujiminori’,‘Beta’,‘Hetianhuang’had strong heat tolerance,while‘Thompson Seedless’,‘Hongqi Tezaomeigui’,‘Shuijing Wuhe’,‘Victoria’,‘Yatomi Rosa’and‘Crimson Seedless’had weak heat tolerance.(2)Among the 12 physiological indexes,malondialdehyde content and antioxidant enzyme activity were mostly different among various grape cultivars.The grape cultivars with strong heat tolerance,‘Red Globe’and‘Fujiminori’,had relatively lower malondialdehyde contents,while‘Beta’and‘Hetianhuang’had relatively higher malondialdehyde contents.But they had higher activity of antioxidant enzymes.(3)The results of fuzzy membership function analysis showed that the cumulative membership value(AR)of each physiological index was consistent with its apparent heat tolerance performance,suggesting that AR can be a potential index for the evaluation of heat tolerance of grape cultivars.Further cluster analysis classified the tested cultivars as strong,medium and weak.‘Red Globe’,‘Fujiminori’,‘Beta’and‘Hetianhuang’had strong heat tolerance.[Conclusions]This study provides a reference for grape cultivation under high temperature and stress and breeding of heat-tolerant varieties.展开更多
In this paper, instead of with the more expensive Fourier Transform Infrared Spectrometer(FTIR) a new technique of Temperature Programmed Transient Response(TP-TR) has been used with gas chromatography. Therefore, the...In this paper, instead of with the more expensive Fourier Transform Infrared Spectrometer(FTIR) a new technique of Temperature Programmed Transient Response(TP-TR) has been used with gas chromatography. Therefore, the TP-TR will be applied more widespreadly than ever before. With the technique of TP-TR and electric conductivity, the study is on the reaction mechanism and the adsorption behavior of the reactants and products to the present catalyst Mo-V-Nb/Al_2O_3 in the reaction from ethane through oxydehydrogenation to ethylene as the product. By Range-Kutta-Gill and Margarat methods, the kinetic parameters of the reaction elementary steps (i.e. rate constants, active energies and frequency factors) have been evaluated. The mathematical treatment coincides with the experimental results.展开更多
Forest loss impacts local climate through biophysical processes.However,our understanding of this impact remains limited due to the neglect of its temporal dynamics.Using a space-and-time scheme that incorporates a ch...Forest loss impacts local climate through biophysical processes.However,our understanding of this impact remains limited due to the neglect of its temporal dynamics.Using a space-and-time scheme that incorporates a change-detection method,we assess the dynamics of land surface temperature(LST)responses to various forest-loss types.Globally,LST increased by 0.12 K one year after forest loss,followed by a decreasing trend of0.14 K per decade.Deforestation driven by commodity production and urbanization results in persistent warming,while forest disturbances such as shifting agriculture,forestry,and fire trigger diverse response dynamics with significant spatial variation due to differences in subsequent vegetation recovery.These disturbances cause attenuated warming in low and mid-latitudes,while,in the boreal zone,contrasting dynamics are observed:shifting agriculture causes attenuated cooling,whereas forestry and fire result in enhanced cooling.In addition to amplifying the amplitude of the LST seasonal cycle,forest loss also shifts the seasonal phase,which has not been previously reported.These findings demonstrate that climate feedback from forest loss is climate specific,loss-type dependent,and time varying,providing new insights for the development of local climate policies.展开更多
Thermoresponsive luminescent organic materials have great potential for intelligent optical devices,but their applicability remains limited due to formidable challenges in achieving tunable response temperature and di...Thermoresponsive luminescent organic materials have great potential for intelligent optical devices,but their applicability remains limited due to formidable challenges in achieving tunable response temperature and different colors.In this study,we developed a thermoresponsive polymer/lanthanide ion(Ln^(3+))complex system,enabling precise regulation of luminescence color and response temperature.The polymer was synthesized via copolymerization of acrylamide(Am)with 6-(3-(2-(methacryloyloxy)ethyl)ureido)picolinate(MAUP).The MAUP unit incorporates ligands capable of coordinating with Ln^(3+)and functions as an“antenna”,absorbing incident light and efficiently transferring energy to Ln^(3+),leading to diverse luminescent emissions.The thermoresponsive property of the poly(Am-co-MAUP)/Ln^(3+)complexes,based on the synergy of ionic coordination and hydrogen bonding,imparts the precise regulation of luminescence with temperature.The response temperature of the poly(Amco-MAUP)/Ln^(3+)complexes can be finely tuned by various factors synergistically,including polymer composition and Ln^(3+)concentrations.Moreover,these thermoresponsive luminescent complexes enable potential applications in multi-level information encryption and visual temperature sensing.展开更多
Ultra‐small metal nanoclusters have high surface energy and abundant active sites,and thereforetheir catalytic activities are usually significantly higher than those of larger nanoparticles.A temperature‐responsive ...Ultra‐small metal nanoclusters have high surface energy and abundant active sites,and thereforetheir catalytic activities are usually significantly higher than those of larger nanoparticles.A temperature‐responsive copolymer,namely poly(ethylene glycol)‐co‐poly(N‐isopropylacrylamide)(PEG‐PNIPAM)was synthesized as the first step,and then ultra‐small Pd clusters stabilized withinPEG‐PNIPAM copolymer micelles were formed by direct reduction.Pd nanoclusters of size less than2nm showed outstanding catalytic activity in the Suzuki coupling reaction.The reaction betweeniodobenzene and phenylboronic acid was completed in as little as10s(turnover frequency=4.3×104h?1).A yield of64%was achieved in5min in the reaction between chlorobenzene and phenylboronicacid.The catalyst showed significant deactivation during three consecutive runs.However,this composite catalyst consisting of Pd/PEG‐PNIPAM can be easily recycled based on the reversiblephase transition of temperature‐responsive PEG‐PNIPAM.This catalyst therefore has good potentialfor practical applications.展开更多
To measure the contribution of root respiration (Rr) to total soil respiration (Rt) in arid cotton fields, eighteen plots, nine for girdling and nine control, were built in an arid cotton field in the Aksu National Ex...To measure the contribution of root respiration (Rr) to total soil respiration (Rt) in arid cotton fields, eighteen plots, nine for girdling and nine control, were built in an arid cotton field in the Aksu National Experimental Station of Oasis Farmland Ecosystem, Xinjiang of China. Given the difference of soil respiration between girdled plots and non-girdled control plots, the components of soil respiration, root respiration (Rr) and respiration originating from decomposition (Rd) were divided. The temperature sensitivities of R r and R d were analyzed, respectively. The results showed that the average contribution of R r to R t in arid cotton field was about 32% during the study period. The temperature-response curve of R r differed from that of Rd . The dynamic variation of R d was more related to the change of soil temperature as compared to Rr . Rr and Rd had different responses to the variation of environment, and thus new models capable of differentiating between Rr and Rd are needed for evaluating the different factors controlling these two components of soil respiration in arid cotton field.展开更多
Laser-assisted manufacturing(LAM)is a technique that performs machining of materials using a laser heating process.During the process,temperatures can rise above over 2000°C.As a result,it is crucial to explore t...Laser-assisted manufacturing(LAM)is a technique that performs machining of materials using a laser heating process.During the process,temperatures can rise above over 2000°C.As a result,it is crucial to explore the thermal behavior of materials under such high temperatures to understand the physics behind LAM and provide feedback for manufacturing optimization.Raman spectroscopy,which is widely used for structure characterization,can provide a novel way to measure temperature during LAM.In this review,we discuss the mechanism of Raman-based temperature probing,its calibration,and sources of uncertainty/error,and how to control them.We critically review the Raman-based temperature measurement considering the spatial resolution under near-field optical heating and surface structure-induced asymmetries.As another critical aspect of Raman-based temperature measurement,temporal resolution is also reviewed to cover various ways of realizing ultrafast thermal probing.We conclude with a detailed outlook on Raman-based temperature probing in LAM and issues that need special attention.展开更多
Soil CO_2efflux（SCE） is an important component of ecosystem CO_2 exchange and is largely temperature and moisture dependent, providing feedback between C cycling and the climate system. We used a precipitation manip...Soil CO_2efflux（SCE） is an important component of ecosystem CO_2 exchange and is largely temperature and moisture dependent, providing feedback between C cycling and the climate system. We used a precipitation manipulation experiment to examine the effects of precipitation treatment on SCE and its dependences on soil temperature and moisture in a semiarid grassland. Precipitation manipulation included ambient precipitation, decreased precipitation（- 43%）, or increased precipitation（＋ 17%）. The SCE was measured from July2013 to December 2014, and CO_2 emission during the experimental period was assessed.The response curves of SCE to soil temperature and moisture were analyzed to determine whether the dependence of SCE on soil temperature or moisture varied with precipitation manipulation. The SCE significantly varied seasonally but was not affected by precipitation treatments regardless of season. Increasing precipitation resulted in an upward shift of SCE–temperature response curves and rightward shift of SCE–moisture response curves,while decreasing precipitation resulted in opposite shifts of such response curves. These shifts in the SCE response curves suggested that increasing precipitation strengthened the dependence of SCE on temperature or moisture, and decreasing precipitation weakened such dependences. Such shifts affected the predictions in soil CO_2 emissions for different precipitation treatments. When considering such shifts, decreasing or increasing precipitation resulted in 43 or 75% less change, respectively, in CO_2 emission compared with changes in emissions predicted without considering such shifts. Furthermore, the effects of shifts in SCE response curves on CO_2 emission prediction were greater during the growing than the non-growing season.展开更多
We investigated the mixed alkali effect on the thermal properties and elastic response to temperature in the borosilicate glasses system with the composition of 70.65Si O_(2)·21.09B_(2)O_(3)·1.88Al_(2)O_(3)&...We investigated the mixed alkali effect on the thermal properties and elastic response to temperature in the borosilicate glasses system with the composition of 70.65Si O_(2)·21.09B_(2)O_(3)·1.88Al_(2)O_(3)·(6.38-x)Li_(2)O·x Na_(2)O glasses,where x=0.00,1.595,3.19,4.785,and 6.38.Except for the expected positive and negative deviations from linearity for the coefficients of thermal expansion,room temperature E and G,we observed a new mixed alkali efiect on the response of elastic moduli to temperature.Fourier transform infrared spectra were obtained to elucidate the possible structural origin of the mixed alkali efiects.This work provides a valuable insight into the structural and mechanical properties of mixed-alkali borosilicate glasses.展开更多
基金supported by the National Natural Science Foundation of China(52273120,21975019,T2222029,and U21A20396)CAS Project for Young Scientists in Basic Research(YSBR-012)+3 种基金Incubation Foundation of Beijing Institute for Stem Cell and Regenerative Medicine(2022FH125,2023FH122)and,the China Scholarship Council(No.202206465017)the Fundamental Research Funds for the Central Universities(FRFTP-20-019A2,FRF-BR-20-03B)the Project was supported by the Science Fund of Shandong Laboratory of Advanced Materials and Green Manufacturing(Yantai)(AMGM2023F04)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA16020802).
文摘Wound dressing management is critical in healthcare,and frequent dressing changes for full-thickness skin wounds can hinder healing.Nanofiber dressings that resemble the extracellular matrix,have gained popularity in wound repair,however,it is challenging to explore how to frequently change it without affecting healing processing and avoiding secondary damage.Here,we developed a self-adhesive and detachable nanofiber dressing inspired by Andrias davidianus.Our asymmetric nanofiber dressing exhibits strong adhesion(26 kPa),to the wound at high temperature(approximately 25°C)to the wound surface and can be easily detached(4 kPa)at low temperature(below 8°C),enabling painless dressing changes that minimize secondary injuries.The dressing comprises an outer layer of polylactic acid which provides mechanical property,support,and pollution resistance,with an inner layer of nanofibrous membrane,composed of gelatin and Andrias davidianus skin secretions,which promotes cellular migration,enhances wound healing and possesses inherent antimicrobial properties.Furthermore,the all-natural nanofiber dressings can be prepared on a large scale and offer favorable biocompatibility to meet the basic requirements of wound dressings.These findings demonstrate the potential applicability of our multilayer nanofiber dressing for advancing wound healing practices.
基金financially supported by the National Natural Science Foundation of China (No. 22271207)the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)。
文摘Temperature-responsive polymers have garnered significant attention due to their ability to respond to external stimuli.In this work,dual temperature-responsive block copolymers are synthesized via reversible addition-fragmentation chain transfer polymerization(RAFT)polymerization utilizing zwitterionic monomer methacryloyl ethyl sulfobetaine(SBMA) and N-isopropyl acrylamide(NIPAAm) as monomers.The thermal responsive behaviors can be easily modulated by incorporating additional hydrophobic monomer benzyl acrylate(BN) or hydrophilic monomer acrylic acid(AA),adjusting concentration or pH,or varying the degree of polymerization of the block chain segments.The cloud points of the copolymers are determined by UV-Vis spectrophotometry,and these copolymers exhibit both controlled upper and lower critical solu bility temperatures(LCST and UCST) in aqueous solution.This study analyzes and summarizes the influencing factors of dual temperature responsive block copolymers by exploring the effects of various conditions on the phase transition temperature of temperature-sensitive polymers to explore the relationship between their properties and environment and structure to make them more selective in terms of temperature application range and regulation laws.It is very interesting that the introduction of poly-acrylic acid(PAA) segments in the middle of di-block copolymer PSBMA_(55)-b-PNIPAAm_(80) to form PSBMA_(55)-b-PAA_(x)-b-PNIPAAm_(80) results in a reversal of temperature-responsive behaviors from 'U'(LCST UCST) type,while the copolymer PSBMA_(55)-b-P(NIPAAm_(80)-co-AA_(x)) not.This work provides a clue for tuning the phase transition behavior of polymers for manufacture of extreme smart materials.
基金financially supported by National Key Research and Development Program of China (2022YFB3804903, 2022YFB3804900)the National Natural Science Foundation of China (No. 52273052)+2 种基金the Fundamental Research Funds for the Central Universities (No. 2232023Y01)the Program of Shanghai Academic/Technology Research Leader (No. 21XD1420100)the International Cooperation Fund of Science and Technology Commission of Shanghai Municipality (No. 21130750100)。
文摘Nanofiber membranes(NFMs) have become attractive candidates for next-generation flexible transparent materials due to their exceptional flexibility and breathability. However, improving the transmittance of NFMs is a great challenge due to the enormous reflection and incredibly poor transmission generated by the nanofiber-air interface. In this research, we report a general strategy for the preparation of flexible temperature-responsive transparent(TRT) membranes,which achieves a rapid transformation of NFMs from opaque to highly transparent under a narrow temperature window. In this process, the phase change material eicosane is coated on the surface of the polyurethane nanofibers by electrospray technology. When the temperature rises to 37 ℃, eicosane rapidly completes the phase transition and establishes the light transmission path between the nanofibers, preventing light loss from reflection at the nanofiber-air interface. The resulting TRT membrane exhibits high transmittance(> 90%), and fast response(5 s). This study achieves the first TRT transition of NFMs, offering a general strategy for building highly transparent nanofiber materials, shaping the future of next-generation intelligent temperature monitoring, anti-counterfeiting measures, and other high-performance devices.
基金financial supports from the National Natural Science Foundation of China (62075132 and 92050202)Natural Science Foundation of Shanghai (22ZR1443100)
文摘This work introduces special states for light in multimode fibers featuring strongly enhanced or reduced correlations be-tween output fields in the presence of environmental temperature fluctuations.Using experimentally measured multi-tem-perature transmission matrix,a set of temperature principal modes that exhibit resilience to disturbances caused by tem-perature fluctuations can be generated.Reversing this concept also allows the construction of temperature anti-principal modes,with output profiles more susceptible to temperature influences than the unmodulated wavefront.Despite changes in the length of the multimode fiber within the temperature-fluctuating region,the proposed approach remains capable of robustly controlling the temperature response within the fiber.To illustrate the practicality of the proposed spe-cial state,a learning-empowered fiber specklegram temperature sensor based on temperature anti-principal mode sensi-tization is proposed.This sensor exhibits outstanding superiority over traditional approaches in terms of resolution and accuracy.These novel states are anticipated to have wide-ranging applications in fiber communication,sensing,imaging,and spectroscopy,and serve as a source of inspiration for the discovery of other novel states.
基金financially supported by the National Natural Science Foundation of China(No.22171182)Sichuan Tianfu Emei Plan.
文摘Control crosslink network and chain connectivity are essential to develop shape memory polymers(SMPs)with high shape memory capabilities,adjustable response temperature,and satisfying mechanistical properties.In this study,novel poly(ε-caprolactone)(PCL)-poly(2-vinyl)ethylene glycol(PVEG)copolymers bearing multi-pendant vinyl groups is synthesized by branched-selective allylic etherification polymerization of vinylethylene carbonate(VEC)with linear and tetra-arm PCLs under a synergistic catalysis of palladium complex and boron reagent.Facile thiol-ene photo-click reaction of PCL-PVEG copolymers with multifunctional thiols can rapidly access a serious crosslinked SMPs with high shape memory performance.The thermal properties,mechanical properties and response temperature of the obtained SMPs are tunable by the variation of PCL prepolymers,vinyl contents and functionality of thiols.Moreover,high elastic modulus in the rubbery plateau region can be maintained effectively owing to high-density topological networks of the PCL materials.In addition,the utility of the present SMPs is further demonstrated by the post-functionalization via thiol-ene photo-click chemistry.
基金the financial support from the National Natural Science Foundation of China(No.61904005,52103010 and 52003200)Guangdong Provincial Department of Education Featured Innovation Project(No.2021KTSCX138)+4 种基金Jiangmen Key Project of Research for Basic and Basic Application(No.2021030102800007443 and 2021030102790006114)the Science Foundation for Young Research Group of Wuyi University(No.2020AL021,2019AL019,and 2020AL016)Wuyi University-Hong Kong/Macao Joint Research Funds(No.2021WGALH05)Youth Innovation Talent Project for the Universities of Guangdong(No.2020KQNCX089)Guangdong Basic and Applied Basic Research Foundation(No.2020A1515110897)
文摘Organic perovskites are promising semiconductor materials for advanced photoelectric applications.Their fluorescence typically shows a negative temperature coefficient due to bandgap change and structural instability.In this study,a novel perovskite-based composite with positive sensitivity to temperature was designed and obtained based on its inverse temperature crystallization,demonstrating good flexibility and solution processability.The supercritical drying method was used to address the limitations of annealing drying in preparing high-performance perovskite.Optimizing the precursor composition proved to be an effective approach for achieving high fluorescence and structural integrity in the perovskite material.This perovskite-based composite exhibited a positive temperature sensitivity of 28.563%℃^(-1)for intensity change and excellent temperature cycling reversibility in the range of 25-40℃in an ambient environment.This made it suitable for use as a smart window with rapid response.Furthermore,the perovskite composite was found to offer temperature-sensing photoluminescence and flexible processability due to its components of perovskite-based compounds and polyethylene oxide.The organic precursor solvent could be a promising candidate for use as ink to print or write on various substrates for optoelectronic devices responding to temperature.
基金Project(2010AA065201) supported by the High-Tech Research and Development Program of ChinaProject(2018zzts157) supported by the Fundamental Research Funds for the Central Universities,China
文摘In the feeding process of aluminum electrolytic, feeding quantity of alumina affects eventually dissolved quantity at the end of a feeding cycle. Based on the OpenFOAM platform, dissolution model coupled with heat and mass transfer was established. Applying the Rosin-Rammler function, alumina particle size distribution under different feeding quantities was obtained. The temperature response of electrolyte after feeding was included and calculated, and the dissolution processes of alumina with different feeding quantities (0.6, 0.8, 1.0, 1.2, 1.4, 1.6 kg) after feeding were simulated in 300 kA aluminum reduction cell. The results show that with the increase of feeding quantity, accumulated mass fraction of dissolved alumina decreases, and the time required for the rapid dissolution stage extends. When the feeding quantity is 0.6 kg and 1.2 kg, it takes the shortest time for the electrolyte temperature dropping before rebounding back. With the increase of feeding quantity, the dissolution rate in the rapid dissolution stage increases at first and then decreases gradually. The most suitable feeding quantity is 1.2 kg. The fitting equation of alumina dissolution curve under different feeding quantities is obtained, which can be used to evaluate the alumina dissolution and guide the feeding quantity and feeding cycle.
基金funded by the Innovation Project Special Funding of the Chinese Academy of Agricultural Sciences(CAAS-IARRP,2017-727-1)the National Natural Science Foundation of China(41001049)
文摘A process-oriented methodology to conduct precise evaluation temporally and spatially on temperature suitability for potato growth was applied in China. Arable lands in China were gridded with 1 km×1 km geographic units, and potential potato phenology in each unit was automatically identified in terms of the potato planting initial temperature and effective accu- mulated temperature. A temperature thermal response coefficient model was used to compute a temperature suitability value for each day of potato phenology in each geographic unit. In addition, five temperature suitability ranking methods were applied to define suitable areas： （1） upper fourth quantile, （2） median, （3） expected value＋1/4 standard deviation, （4） expected value＋1/2 standard deviation, （5） expected value＋1 standard deviation. A validation indicator was innovated to test the effectiveness of the five ranking methods. The results showed that from a strict degree point of view, the five methods sequence was as follows： 1=3〉4〉2〉5, with a and c determined as the two best ranking methods. For methods 1 and 3, the suitable potato growing area was 1 of 57.76× 10^4 km2. In addition, the suitable, areas were spatially coincident with the main potato producing counties. The study output technically supports the proposal from China＇s government that there is a large potential area to grow winter-ploughed potato in South China because the potential suitable area for growing potato is approximately 2×10^7 ha. In southeast Heilongjiang and east Jilin, where it is hilly and mountainous, there are still some potentially suitable areas for potato growing accounting for nearly 2.32×10^6 ha. The authors suggest to optimize the agricultural regionalization and layout in China and to adjust the cropping pattern structure.
基金This work was supported by the National Science Foundation of China
文摘The influence of temperature-dependent properties on temperature response and optimum design of newly developed ceramic-metal functionally graded materials under cyclic thermal loading and high temperature gradient environment is studied. The thermal conductivity of the material is considered to be dependent on the temperature. In this paper, the temperature response of the material is calculated using a nonlinear finite element method. Emphasis is placed on the influence of temperatue-dependent properties on the thermal response and insulation property of the material render the different graded compositional distributions and different heat flux magnitudes. Through the analysis, it is suggested that the influence of temperature-dependent properties can not be neglected in the temperature response analysis and the optimum design process of the material must be based on the temperature-dependent temperature analysis theory.
基金partially performed with the support and under the auspices of the NIFS Collaborative Research Program(Nos.NIFS20KLPR051,NIFS20KUHL099 and NIFS20KUGM153)。
文摘Temperature response functions have been developed to investigate sensor design and divertor heat flux estimation in magnetically confined plasmas. The time-dependent heat flux can be derived by fitting the response function to experimental thermocouple(TC) data. Because the TC signals have a time delay to transit events such as discharge start or confinement transition, the time delay is taken into account in a temperature response function. Such a function accurately describes the signal from each TC channel with time delay in a sensor test using a neutral beam injection. Measurement for commercial TCs shows that the time delay is caused by the finite heat capacity of TC wire and contact heat resistance between TC and target surface.
文摘A theoretical model for calculation of the sample temperature during straight-line nitrogen ion implantation was established based on the results of experiment in this paper. Taking the pure aluminum as the samples, and from the transformation of electric energy into thermal energy, the calculated values of the temperature were in good agreement with the measured values in the experiment. According to the simulation, this technology can be applied to the control of specimens temperature during the implantation.
基金Supported by Youth Science and Technology Backbone Innovation Ability Cultivation Project of Xinjiang Academy of Agricultural Sciences(xjnkq-2021010)Tianshan Youth Project in Xinjiang Uygur Autonomous Region(2018Q093,2019Q091)+2 种基金Tianshan Innovation Team of Xinjiang Uygur Autonomous Region(2020D14033)Natural Science Foundation of Xinjiang Uygur Autonomous Region(2019D01B33)Tianchi Plan of the Autonomous Region for Introduction of High-level Talents(2018)。
文摘[Objectives]This study was conducted to investigate the differences in the physiological responses of different grape cultivars to high temperature.[Methods]The 19 tested cultivars were selected from the grape germplasm resources pool of Turpan Research Institute of Xinjiang Academy of Agricultural Sciences.Twelve physiological indexes including gas exchange parameters,chlorophyll content,antioxidant enzyme activity and proline content were determined in grape leaves under field conditions during the middle period of local natural high temperature period(July,daily maximum air temperature>35℃).The heat tolerance of different cultivars was evaluated by fuzzy membership function analysis and optimum partitioning clustering of ordered samples.[Results](1)Under natural high temperature conditions in Turpan,the 19 tested grape cultivars responded differently to high temperature.‘Red Globe’,‘Fujiminori’,‘Beta’,‘Hetianhuang’had strong heat tolerance,while‘Thompson Seedless’,‘Hongqi Tezaomeigui’,‘Shuijing Wuhe’,‘Victoria’,‘Yatomi Rosa’and‘Crimson Seedless’had weak heat tolerance.(2)Among the 12 physiological indexes,malondialdehyde content and antioxidant enzyme activity were mostly different among various grape cultivars.The grape cultivars with strong heat tolerance,‘Red Globe’and‘Fujiminori’,had relatively lower malondialdehyde contents,while‘Beta’and‘Hetianhuang’had relatively higher malondialdehyde contents.But they had higher activity of antioxidant enzymes.(3)The results of fuzzy membership function analysis showed that the cumulative membership value(AR)of each physiological index was consistent with its apparent heat tolerance performance,suggesting that AR can be a potential index for the evaluation of heat tolerance of grape cultivars.Further cluster analysis classified the tested cultivars as strong,medium and weak.‘Red Globe’,‘Fujiminori’,‘Beta’and‘Hetianhuang’had strong heat tolerance.[Conclusions]This study provides a reference for grape cultivation under high temperature and stress and breeding of heat-tolerant varieties.
文摘In this paper, instead of with the more expensive Fourier Transform Infrared Spectrometer(FTIR) a new technique of Temperature Programmed Transient Response(TP-TR) has been used with gas chromatography. Therefore, the TP-TR will be applied more widespreadly than ever before. With the technique of TP-TR and electric conductivity, the study is on the reaction mechanism and the adsorption behavior of the reactants and products to the present catalyst Mo-V-Nb/Al_2O_3 in the reaction from ethane through oxydehydrogenation to ethylene as the product. By Range-Kutta-Gill and Margarat methods, the kinetic parameters of the reaction elementary steps (i.e. rate constants, active energies and frequency factors) have been evaluated. The mathematical treatment coincides with the experimental results.
基金support from the National Natural Science Foundation of China(grant no.41921001)the China Postdoctoral Science Foundation(certificate number 2023M733812)。
文摘Forest loss impacts local climate through biophysical processes.However,our understanding of this impact remains limited due to the neglect of its temporal dynamics.Using a space-and-time scheme that incorporates a change-detection method,we assess the dynamics of land surface temperature(LST)responses to various forest-loss types.Globally,LST increased by 0.12 K one year after forest loss,followed by a decreasing trend of0.14 K per decade.Deforestation driven by commodity production and urbanization results in persistent warming,while forest disturbances such as shifting agriculture,forestry,and fire trigger diverse response dynamics with significant spatial variation due to differences in subsequent vegetation recovery.These disturbances cause attenuated warming in low and mid-latitudes,while,in the boreal zone,contrasting dynamics are observed:shifting agriculture causes attenuated cooling,whereas forestry and fire result in enhanced cooling.In addition to amplifying the amplitude of the LST seasonal cycle,forest loss also shifts the seasonal phase,which has not been previously reported.These findings demonstrate that climate feedback from forest loss is climate specific,loss-type dependent,and time varying,providing new insights for the development of local climate policies.
基金supported by the Ningbo Youth Leading Talent Project(2024QL020)the National Natural Science Foundation of China(52373118 and 22075154)+1 种基金the“Mechanics+”Interdisciplinary Top Innovative Youth Fund Project of Ningbo University(LJ2024006)the Ningbo Major Science and Technology Project(2024Z205)。
文摘Thermoresponsive luminescent organic materials have great potential for intelligent optical devices,but their applicability remains limited due to formidable challenges in achieving tunable response temperature and different colors.In this study,we developed a thermoresponsive polymer/lanthanide ion(Ln^(3+))complex system,enabling precise regulation of luminescence color and response temperature.The polymer was synthesized via copolymerization of acrylamide(Am)with 6-(3-(2-(methacryloyloxy)ethyl)ureido)picolinate(MAUP).The MAUP unit incorporates ligands capable of coordinating with Ln^(3+)and functions as an“antenna”,absorbing incident light and efficiently transferring energy to Ln^(3+),leading to diverse luminescent emissions.The thermoresponsive property of the poly(Am-co-MAUP)/Ln^(3+)complexes,based on the synergy of ionic coordination and hydrogen bonding,imparts the precise regulation of luminescence with temperature.The response temperature of the poly(Amco-MAUP)/Ln^(3+)complexes can be finely tuned by various factors synergistically,including polymer composition and Ln^(3+)concentrations.Moreover,these thermoresponsive luminescent complexes enable potential applications in multi-level information encryption and visual temperature sensing.
基金supported by the National Natural Science Foundation of China (51502089,51302008)the Fundamental Research Funds for the Central Universities (2016MS03)~~
文摘Ultra‐small metal nanoclusters have high surface energy and abundant active sites,and thereforetheir catalytic activities are usually significantly higher than those of larger nanoparticles.A temperature‐responsive copolymer,namely poly(ethylene glycol)‐co‐poly(N‐isopropylacrylamide)(PEG‐PNIPAM)was synthesized as the first step,and then ultra‐small Pd clusters stabilized withinPEG‐PNIPAM copolymer micelles were formed by direct reduction.Pd nanoclusters of size less than2nm showed outstanding catalytic activity in the Suzuki coupling reaction.The reaction betweeniodobenzene and phenylboronic acid was completed in as little as10s(turnover frequency=4.3×104h?1).A yield of64%was achieved in5min in the reaction between chlorobenzene and phenylboronicacid.The catalyst showed significant deactivation during three consecutive runs.However,this composite catalyst consisting of Pd/PEG‐PNIPAM can be easily recycled based on the reversiblephase transition of temperature‐responsive PEG‐PNIPAM.This catalyst therefore has good potentialfor practical applications.
基金Supported by the National Natural Science Foundation of China(Nos.31000208 and 40830640)the National Basic Research Program(973 Program) of China(No.2009CB421302)
文摘To measure the contribution of root respiration (Rr) to total soil respiration (Rt) in arid cotton fields, eighteen plots, nine for girdling and nine control, were built in an arid cotton field in the Aksu National Experimental Station of Oasis Farmland Ecosystem, Xinjiang of China. Given the difference of soil respiration between girdled plots and non-girdled control plots, the components of soil respiration, root respiration (Rr) and respiration originating from decomposition (Rd) were divided. The temperature sensitivities of R r and R d were analyzed, respectively. The results showed that the average contribution of R r to R t in arid cotton field was about 32% during the study period. The temperature-response curve of R r differed from that of Rd . The dynamic variation of R d was more related to the change of soil temperature as compared to Rr . Rr and Rd had different responses to the variation of environment, and thus new models capable of differentiating between Rr and Rd are needed for evaluating the different factors controlling these two components of soil respiration in arid cotton field.
基金We are grateful for the financial support of National Key R&D Program of China(Nos.2O18YFEO2O5OOO and 2O19YFAO9O58OO for R W)Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning and China Scholarship Council(S X),National Natural Science Foundation of China(No.5157614 for Y Y)and US National Science Foundation(CBET193O866 for X W).
文摘Laser-assisted manufacturing(LAM)is a technique that performs machining of materials using a laser heating process.During the process,temperatures can rise above over 2000°C.As a result,it is crucial to explore the thermal behavior of materials under such high temperatures to understand the physics behind LAM and provide feedback for manufacturing optimization.Raman spectroscopy,which is widely used for structure characterization,can provide a novel way to measure temperature during LAM.In this review,we discuss the mechanism of Raman-based temperature probing,its calibration,and sources of uncertainty/error,and how to control them.We critically review the Raman-based temperature measurement considering the spatial resolution under near-field optical heating and surface structure-induced asymmetries.As another critical aspect of Raman-based temperature measurement,temporal resolution is also reviewed to cover various ways of realizing ultrafast thermal probing.We conclude with a detailed outlook on Raman-based temperature probing in LAM and issues that need special attention.
基金supported by the National Natural Science Foundation of China (Nos. 41271315, 41571130082)the Program for New Century Excellent Talents in University (No. NCET-13-0487)the Program from Chinese Academy of Sciences (No. 2014371)
文摘Soil CO_2efflux（SCE） is an important component of ecosystem CO_2 exchange and is largely temperature and moisture dependent, providing feedback between C cycling and the climate system. We used a precipitation manipulation experiment to examine the effects of precipitation treatment on SCE and its dependences on soil temperature and moisture in a semiarid grassland. Precipitation manipulation included ambient precipitation, decreased precipitation（- 43%）, or increased precipitation（＋ 17%）. The SCE was measured from July2013 to December 2014, and CO_2 emission during the experimental period was assessed.The response curves of SCE to soil temperature and moisture were analyzed to determine whether the dependence of SCE on soil temperature or moisture varied with precipitation manipulation. The SCE significantly varied seasonally but was not affected by precipitation treatments regardless of season. Increasing precipitation resulted in an upward shift of SCE–temperature response curves and rightward shift of SCE–moisture response curves,while decreasing precipitation resulted in opposite shifts of such response curves. These shifts in the SCE response curves suggested that increasing precipitation strengthened the dependence of SCE on temperature or moisture, and decreasing precipitation weakened such dependences. Such shifts affected the predictions in soil CO_2 emissions for different precipitation treatments. When considering such shifts, decreasing or increasing precipitation resulted in 43 or 75% less change, respectively, in CO_2 emission compared with changes in emissions predicted without considering such shifts. Furthermore, the effects of shifts in SCE response curves on CO_2 emission prediction were greater during the growing than the non-growing season.
基金National Natural Science Foundation of China(No.52172007)the Ph D Program Fund of Non-Metallic Excellence and Innovation Center for Building Materials(No.2022SFP6-2)+1 种基金Guang Dong Basic and Applied Basic Research Foundation(No.2022A1515010312)Jiangsu Science and Technology Innovation Project for Carbon Peaking and Carbon Neutrality(No.BE2022035)。
文摘We investigated the mixed alkali effect on the thermal properties and elastic response to temperature in the borosilicate glasses system with the composition of 70.65Si O_(2)·21.09B_(2)O_(3)·1.88Al_(2)O_(3)·(6.38-x)Li_(2)O·x Na_(2)O glasses,where x=0.00,1.595,3.19,4.785,and 6.38.Except for the expected positive and negative deviations from linearity for the coefficients of thermal expansion,room temperature E and G,we observed a new mixed alkali efiect on the response of elastic moduli to temperature.Fourier transform infrared spectra were obtained to elucidate the possible structural origin of the mixed alkali efiects.This work provides a valuable insight into the structural and mechanical properties of mixed-alkali borosilicate glasses.
