We investigated the decolorization of Orange Ⅱ with and without the addition of co-substrates and nutrients under an anaerobic sequencing batch reactor(ASBR).The increase in COD concentrations from 900 to 1750 to 3...We investigated the decolorization of Orange Ⅱ with and without the addition of co-substrates and nutrients under an anaerobic sequencing batch reactor(ASBR).The increase in COD concentrations from 900 to 1750 to 3730 mg/L in the system treating 100 mg/L of Orange Ⅱ-containing wastewater enhanced color removal from 27% to 81% to 89%,respectively.In the absence of co-substrates and nutrients,more than 95% of decolorization was achieved by the acclimatized anaerobic microbes in the bioreactor treating 600 mg/L of Orange Ⅱ.The decrease in mixed liquor suspended solids concentration by endogenous lysis of biomass preserved a high reducing environment in the ASBR,which was important for the reduction of the Orange Ⅱ azo bond that caused decolorization.The maximum decolorization rate in the ASBR was approximately 0.17 g/hr in the absence of co-substrates and nutrients.展开更多
Some problems including low treatment capacity,agglomeration and clogging phenomena,and short working life,limit the application of pre-treatment methods involving zero-valent iron (ZVI).In this article,ZVI was froz...Some problems including low treatment capacity,agglomeration and clogging phenomena,and short working life,limit the application of pre-treatment methods involving zero-valent iron (ZVI).In this article,ZVI was frozen in an amorphous state through a melt-spinning technique,and the decolorization effect of amorphous ZVI on Acid Orange II solution was investigated under varied conditions of experimental variables such as reaction temperature,ribbon dosage,and initial pH.Batch experiments suggested that the decolorization rate was enhanced with the increase of reaction temperature and ribbon dosage,but decreased with increasing initial solution pH.Kinetic analyses indicated that the decolorization process followed a first order exponential kinetic model,and the surface-normalized decolorization rate could reach 2.09 L/(m^2 ·min) at room temperature,which was about ten times larger than any previously reported under similar conditions.Recycling experiments also proved that the ribbons could be reused at least four times without obvious decay of decolorization rate and efficiency.This study suggests a tremendous application potential for amorphous ZVI in remediation of groundwater or wastewater contaminated with azo dyes.展开更多
In this paper,prepared are three kinds of SiO 2 TiO 2 photocatalyst containig zirconium.At pH=7,treated with commonlight source,decoloration rates of acid scarlet red 3R,direct fast black G and active scarlet red K 2G...In this paper,prepared are three kinds of SiO 2 TiO 2 photocatalyst containig zirconium.At pH=7,treated with commonlight source,decoloration rates of acid scarlet red 3R,direct fast black G and active scarlet red K 2G are more than 95%.展开更多
文摘We investigated the decolorization of Orange Ⅱ with and without the addition of co-substrates and nutrients under an anaerobic sequencing batch reactor(ASBR).The increase in COD concentrations from 900 to 1750 to 3730 mg/L in the system treating 100 mg/L of Orange Ⅱ-containing wastewater enhanced color removal from 27% to 81% to 89%,respectively.In the absence of co-substrates and nutrients,more than 95% of decolorization was achieved by the acclimatized anaerobic microbes in the bioreactor treating 600 mg/L of Orange Ⅱ.The decrease in mixed liquor suspended solids concentration by endogenous lysis of biomass preserved a high reducing environment in the ASBR,which was important for the reduction of the Orange Ⅱ azo bond that caused decolorization.The maximum decolorization rate in the ASBR was approximately 0.17 g/hr in the absence of co-substrates and nutrients.
基金the financial support from the Ministry of Science and Technology of China(No. 2011CB606301)the National Natural Science Foundation of China (No. 50825402,51101156)
文摘Some problems including low treatment capacity,agglomeration and clogging phenomena,and short working life,limit the application of pre-treatment methods involving zero-valent iron (ZVI).In this article,ZVI was frozen in an amorphous state through a melt-spinning technique,and the decolorization effect of amorphous ZVI on Acid Orange II solution was investigated under varied conditions of experimental variables such as reaction temperature,ribbon dosage,and initial pH.Batch experiments suggested that the decolorization rate was enhanced with the increase of reaction temperature and ribbon dosage,but decreased with increasing initial solution pH.Kinetic analyses indicated that the decolorization process followed a first order exponential kinetic model,and the surface-normalized decolorization rate could reach 2.09 L/(m^2 ·min) at room temperature,which was about ten times larger than any previously reported under similar conditions.Recycling experiments also proved that the ribbons could be reused at least four times without obvious decay of decolorization rate and efficiency.This study suggests a tremendous application potential for amorphous ZVI in remediation of groundwater or wastewater contaminated with azo dyes.
文摘In this paper,prepared are three kinds of SiO 2 TiO 2 photocatalyst containig zirconium.At pH=7,treated with commonlight source,decoloration rates of acid scarlet red 3R,direct fast black G and active scarlet red K 2G are more than 95%.