This work aimed to prepare the nanospike surface-modified bionic porous titanium implants that feature favorableosteointegration performance and anti-bacterial functions.The implant was prepared using freeze casting,a...This work aimed to prepare the nanospike surface-modified bionic porous titanium implants that feature favorableosteointegration performance and anti-bacterial functions.The implant was prepared using freeze casting,and nanospikesurface-modification of the implant was performed using thermal oxidation.The pore morphology and size,mechanical properties,and osteogenic performance of the implants were analyzed and discussed.The results showed that when the volume ratio of titaniumpowder in slurry was set to be10%,the porosity,pore diameter,compressive strength,and elastic modulus of the porous sampleswere(58.32±1.08)%,(126.17±18.64)μm,(58.51±20.38)MPa and(1.70±0.52)GPa,respectively.When the porous sample wassintered at a temperature of1200°C for1h,these values were(58.24±1.50)%,(124.16±13.64)μm,(54.77±27.55)MPa and(1.63±0.30)GPa,respectively.The nanospike surface-modified bionic porous titanium implants had favorable pore morphology andsize,mechanical properties and osteointegration performance through technology optimization,and showed significant clinicalapplication prospect.展开更多
Metal hydroxides （MAH） consisting of magnesium hydroxide and aluminum hydroxide with a mass ratio of 1：2 were surface-modified by y-diethoxyphosphorous ester propyldiethoxymethylsilane, boric acid and diphenylsilan...Metal hydroxides （MAH） consisting of magnesium hydroxide and aluminum hydroxide with a mass ratio of 1：2 were surface-modified by y-diethoxyphosphorous ester propyldiethoxymethylsilane, boric acid and diphenylsilanediol in xylene under dibutyl tin dilaurate catalyst at 140 ℃. Phosphorus, silicon and boron elements covalently bonded to metal hydroxide particles were detected by X-ray photoelectron spectroscopy. The degradation behavior of the surface-modified MAH was characterized by thermogravimetric analysis. The results show that linear low density polyethylene （LLDPE） composite, filled with 50% （mass fraction） of MAH modified by 5.0% （mass fraction） of modifiers, passes the V-0 rating of UL-94 test and shows the limited oxygen index of 34%, and its heat release rate and average effective heat combustion in a cone calorimeter measurement decrease obviously; The mechanical properties of MAH can be improved by surface-modification. The uniform dispersion of particles and strong interfacial bonding between particles and matrix are obtained.展开更多
Silicon dioxide sol was synthesized by silicon in the presence of alkali catalyst. SiO_2 nanoparticles (size in 8-15 nm) aqueous dispersion was prepared by using dispersion and surface modification in situ. The effect...Silicon dioxide sol was synthesized by silicon in the presence of alkali catalyst. SiO_2 nanoparticles (size in 8-15 nm) aqueous dispersion was prepared by using dispersion and surface modification in situ. The effects of reaction time, temperature, medium pH value, dispersant and surface-modifier on their diameters, sizes distribution and dispersion stability were also studied.The experimental results show that the preparation method can effectively resolve the dispersion stability of SiO_2 nanoparticles in water.展开更多
A series of CdS nanoparticles with different surfaces were prepared by colloidal chemical method and reverse micelle method. Their second-order nonlinear optical (NLO) properties were experimentally studied in solutio...A series of CdS nanoparticles with different surfaces were prepared by colloidal chemical method and reverse micelle method. Their second-order nonlinear optical (NLO) properties were experimentally studied in solution by newly developed hyper-Rayleigh scattering (HRS) technique. The results show that 'per particle' first-order hyperpolarizability beta values are sensitive To the synthetic method and the surface chemical modification.展开更多
Atom transfer radical polymerization (ATRP) using cuprous chloride/2,2'-bipyridine (bipy) was applied to graft polymerization of styrene on the surface of silica nanoparticles to synthesize polymer-inorganic hybri...Atom transfer radical polymerization (ATRP) using cuprous chloride/2,2'-bipyridine (bipy) was applied to graft polymerization of styrene on the surface of silica nanoparticles to synthesize polymer-inorganic hybrid nanoparticles, 2-(4Chloromethylphenyl) ethyltriethoxysilane (CTES) was immobilized on the surface of silica nanoparticles through condensation reaction of the silanol groups on silica with triethoxysilane group of CTES. Then ATRP of St was initiated by this surface-modified silica nanoparticles bearing benzyl chloride groups, and formed PSt graft chains on the surface of silica nanoparticles. The thickness of the graft chains increased with reaction time. End group analysis confirmed the occurrence of ATRP. Thermal analysis indicated that thermal stabilization of these resulting hybrid nanoparticles also increases with polymerization conversion. The results above show that this 'grafting from' reaction could be used for the preparation of polymer-inorganic hybrid nanoparticles with controlled structure of the polymer's end groups.展开更多
Argyrodite-based solid-state lithium metal batteries exhibit significant potential as next-generation energy storage devices.However,their practical applications are constrained by the intrinsic poor stability of argy...Argyrodite-based solid-state lithium metal batteries exhibit significant potential as next-generation energy storage devices.However,their practical applications are constrained by the intrinsic poor stability of argyrodite towards Li metal and exposure to air/moisture.Therefore,an indium-involved modification strategy is employed to address these issues.The optimized doping yields a high Li-ion conductivity of 7.5 mS cm^(-1)for Li_(5.54)In_(0.02)PS_(4.47)O_(0.03)Cl_(1.5)electrolyte,accompanied by enhanced endurance against air/moisture and bare Li metal.It retains 92.0%of its original conductivity after exposure to air at a low dew point of-60℃in dry room.Additionally,a composite layer comprising Li-In alloy and Li F phases is generated on the surface of lithium metal anode via the reaction between InF_(3)and molten Li.This layer effectively mitigates Li dendrite growth by creating a physical barrier from the robust LiF phase,while the Li-In alloy induces uniform Li-ion deposition and accelerates Li transport dynamics across the interphase between the solid electrolyte/Li metal.Moreover,the In-doped electrolyte facilitates the in-situ generation of Li-In alloy within its voids,reducing local current density and further inhibiting lithium dendrite growth.Consequently,the combination of the Li_(5.54)In_(0.02)PS_(4.47)O_(0.03)Cl_(1.5)electrolyte and the InF_(3)@Li anode provides exceptional electrochemical performances in both symmetric cells and solid-state lithium metal batteries across different operating temperatures.Specifically,the LiNbO_(3)@LiNi_(0.7)Co_(0.2)Mn_(0.1)O_(2)/Li_(5.54)In_(0.02)PS_(4.47)O_(0.03)Cl_(1.5)/InF_(3)@Li cell delivers a high discharge capacity of 167.8 mAh g^(-1)at 0.5 C under 25℃and retains 80.0%of its initial value after 400 cycles.This work offers a viable strategy for designing functional interfaces with enhanced stability for sulfide-based solid-state lithium batteries.展开更多
Titanic acid nanotubes(H_(2)Ti_(2)O_(4)(OH)_(2))were surface-modified with cetyl alcohol through dehydration reaction because of existence of Ti–OH.The modified nanotubes were characterized by transmission electron m...Titanic acid nanotubes(H_(2)Ti_(2)O_(4)(OH)_(2))were surface-modified with cetyl alcohol through dehydration reaction because of existence of Ti–OH.The modified nanotubes were characterized by transmission electron microscopy(TEM),Fourier Transform Infrared(FT-IR)spectrometry and pho-toluminescence(PL)spectra.The results indicate that the modified nanotubes can be easily dis-persed into organic solvent such as chloroform and toluene in contrast with the unmodified nanotubes,which makes it easier to be assembled by LB technique.Moreover,the Ti-O-CH_(2)(CH_(2))_(14)CH_(3) on the surface of the nanotubes can hinder the adsorption of water and consequently the photoluminescence property of the nanotubes can be stabilized.Even though kept in humid condition or in air for a long time,the modified nanotubes also maintain the special photoluminescence property in the visible region.展开更多
基金Projects(51290295,51305464) supported by the National Natural Science Foundation of ChinaProject(2016JJ6156) supported by the Natural Science Foundation of Hunan Province,China+1 种基金Project(2016JC2064) supported by the Key Research and Development Program of Hunan Province,ChinaProject(20130162120094) supported by the Specialized Research Fund for the Doctoral Program of Higher Education,China
文摘This work aimed to prepare the nanospike surface-modified bionic porous titanium implants that feature favorableosteointegration performance and anti-bacterial functions.The implant was prepared using freeze casting,and nanospikesurface-modification of the implant was performed using thermal oxidation.The pore morphology and size,mechanical properties,and osteogenic performance of the implants were analyzed and discussed.The results showed that when the volume ratio of titaniumpowder in slurry was set to be10%,the porosity,pore diameter,compressive strength,and elastic modulus of the porous sampleswere(58.32±1.08)%,(126.17±18.64)μm,(58.51±20.38)MPa and(1.70±0.52)GPa,respectively.When the porous sample wassintered at a temperature of1200°C for1h,these values were(58.24±1.50)%,(124.16±13.64)μm,(54.77±27.55)MPa and(1.63±0.30)GPa,respectively.The nanospike surface-modified bionic porous titanium implants had favorable pore morphology andsize,mechanical properties and osteointegration performance through technology optimization,and showed significant clinicalapplication prospect.
基金Project(20574020) supported by the National Natural Science Foundation of ChinaProject(20061001) supported by the Opening Project of the Key Laboratory of Polymer Processing Engineering, Ministry of Education, ChinaProject (20060106-2) supported by Guangdong Key Projects
文摘Metal hydroxides （MAH） consisting of magnesium hydroxide and aluminum hydroxide with a mass ratio of 1：2 were surface-modified by y-diethoxyphosphorous ester propyldiethoxymethylsilane, boric acid and diphenylsilanediol in xylene under dibutyl tin dilaurate catalyst at 140 ℃. Phosphorus, silicon and boron elements covalently bonded to metal hydroxide particles were detected by X-ray photoelectron spectroscopy. The degradation behavior of the surface-modified MAH was characterized by thermogravimetric analysis. The results show that linear low density polyethylene （LLDPE） composite, filled with 50% （mass fraction） of MAH modified by 5.0% （mass fraction） of modifiers, passes the V-0 rating of UL-94 test and shows the limited oxygen index of 34%, and its heat release rate and average effective heat combustion in a cone calorimeter measurement decrease obviously; The mechanical properties of MAH can be improved by surface-modification. The uniform dispersion of particles and strong interfacial bonding between particles and matrix are obtained.
文摘Silicon dioxide sol was synthesized by silicon in the presence of alkali catalyst. SiO_2 nanoparticles (size in 8-15 nm) aqueous dispersion was prepared by using dispersion and surface modification in situ. The effects of reaction time, temperature, medium pH value, dispersant and surface-modifier on their diameters, sizes distribution and dispersion stability were also studied.The experimental results show that the preparation method can effectively resolve the dispersion stability of SiO_2 nanoparticles in water.
基金National Natural Science Foundation of China! (No.59582005)
文摘A series of CdS nanoparticles with different surfaces were prepared by colloidal chemical method and reverse micelle method. Their second-order nonlinear optical (NLO) properties were experimentally studied in solution by newly developed hyper-Rayleigh scattering (HRS) technique. The results show that 'per particle' first-order hyperpolarizability beta values are sensitive To the synthetic method and the surface chemical modification.
基金This project was supported by the National Natural Science Foundation of China to K.Y Qiu (Grant No. 29874002) and Outstanding Young Scientist Award to Y. Wei (Grant No. 29825504)
文摘Atom transfer radical polymerization (ATRP) using cuprous chloride/2,2'-bipyridine (bipy) was applied to graft polymerization of styrene on the surface of silica nanoparticles to synthesize polymer-inorganic hybrid nanoparticles, 2-(4Chloromethylphenyl) ethyltriethoxysilane (CTES) was immobilized on the surface of silica nanoparticles through condensation reaction of the silanol groups on silica with triethoxysilane group of CTES. Then ATRP of St was initiated by this surface-modified silica nanoparticles bearing benzyl chloride groups, and formed PSt graft chains on the surface of silica nanoparticles. The thickness of the graft chains increased with reaction time. End group analysis confirmed the occurrence of ATRP. Thermal analysis indicated that thermal stabilization of these resulting hybrid nanoparticles also increases with polymerization conversion. The results above show that this 'grafting from' reaction could be used for the preparation of polymer-inorganic hybrid nanoparticles with controlled structure of the polymer's end groups.
基金supported by the National Key Research and Development Program (2021YFB2500200)the National Natural Science Foundation of China (52177214,52222703)+1 种基金The Basic Science Research Fund in Xidian University (ZYTS24132)the Postdoctoral Science Research Program of Shaanxi (30102230001)。
文摘Argyrodite-based solid-state lithium metal batteries exhibit significant potential as next-generation energy storage devices.However,their practical applications are constrained by the intrinsic poor stability of argyrodite towards Li metal and exposure to air/moisture.Therefore,an indium-involved modification strategy is employed to address these issues.The optimized doping yields a high Li-ion conductivity of 7.5 mS cm^(-1)for Li_(5.54)In_(0.02)PS_(4.47)O_(0.03)Cl_(1.5)electrolyte,accompanied by enhanced endurance against air/moisture and bare Li metal.It retains 92.0%of its original conductivity after exposure to air at a low dew point of-60℃in dry room.Additionally,a composite layer comprising Li-In alloy and Li F phases is generated on the surface of lithium metal anode via the reaction between InF_(3)and molten Li.This layer effectively mitigates Li dendrite growth by creating a physical barrier from the robust LiF phase,while the Li-In alloy induces uniform Li-ion deposition and accelerates Li transport dynamics across the interphase between the solid electrolyte/Li metal.Moreover,the In-doped electrolyte facilitates the in-situ generation of Li-In alloy within its voids,reducing local current density and further inhibiting lithium dendrite growth.Consequently,the combination of the Li_(5.54)In_(0.02)PS_(4.47)O_(0.03)Cl_(1.5)electrolyte and the InF_(3)@Li anode provides exceptional electrochemical performances in both symmetric cells and solid-state lithium metal batteries across different operating temperatures.Specifically,the LiNbO_(3)@LiNi_(0.7)Co_(0.2)Mn_(0.1)O_(2)/Li_(5.54)In_(0.02)PS_(4.47)O_(0.03)Cl_(1.5)/InF_(3)@Li cell delivers a high discharge capacity of 167.8 mAh g^(-1)at 0.5 C under 25℃and retains 80.0%of its initial value after 400 cycles.This work offers a viable strategy for designing functional interfaces with enhanced stability for sulfide-based solid-state lithium batteries.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.90306010 and 20371015)State Key Basic Research'973'Plan of China(Grant No.2002CCC02700).
文摘Titanic acid nanotubes(H_(2)Ti_(2)O_(4)(OH)_(2))were surface-modified with cetyl alcohol through dehydration reaction because of existence of Ti–OH.The modified nanotubes were characterized by transmission electron microscopy(TEM),Fourier Transform Infrared(FT-IR)spectrometry and pho-toluminescence(PL)spectra.The results indicate that the modified nanotubes can be easily dis-persed into organic solvent such as chloroform and toluene in contrast with the unmodified nanotubes,which makes it easier to be assembled by LB technique.Moreover,the Ti-O-CH_(2)(CH_(2))_(14)CH_(3) on the surface of the nanotubes can hinder the adsorption of water and consequently the photoluminescence property of the nanotubes can be stabilized.Even though kept in humid condition or in air for a long time,the modified nanotubes also maintain the special photoluminescence property in the visible region.
