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SELECTIVE SULFUR DIOXIDE DETERMINATION BY GAS DIFFUSION FLOW INJECTION ANALYSIS WITH CHEMILUMINESCENT DETECTION
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作者 Yong He BAO Qi Jun SONG Department of Chemistry,XingJiang University,Urumchi,830046 《Chinese Chemical Letters》 SCIE CAS CSCD 1991年第4期313-314,共2页
Sulfur dioxide has been found to decrease the chemiluminescence of luminol-iodine system.A new determination method for sulfur dioxide in atmosphere is developed by applying this reaction to a flow injection gas diffu... Sulfur dioxide has been found to decrease the chemiluminescence of luminol-iodine system.A new determination method for sulfur dioxide in atmosphere is developed by applying this reaction to a flow injection gas diffusion separation system.This permits the determination of sulfur dioxide selectively and rapidly. 展开更多
关键词 FLOW SELECTIVE sulfur DIOXIDE DETERMINATION BY GAS diffusion FLOW INJECTION ANALYSIS WITH CHEMILUMINESCENT DETECTION GAS
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扩散捕获效应对LiAl负极材料极化行为的影响
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作者 黄方铎 孙婷婷 +3 位作者 刘俊良 丰雪帆 喻文瑞 张福勤 《矿冶工程》 北大核心 2025年第1期171-178,共8页
研究了Li的固态扩散对LiAl合金负极极化行为的影响,制备了具有不同比表面积的LiAl电极与不受Li固态扩散影响的Cu@Li电极。采用恒流充放电、循环伏安法、电化学阻抗与恒流间歇滴定测试对沉积容量为0.51mAh/cm^(2)的电沉积LiAl合金在半电... 研究了Li的固态扩散对LiAl合金负极极化行为的影响,制备了具有不同比表面积的LiAl电极与不受Li固态扩散影响的Cu@Li电极。采用恒流充放电、循环伏安法、电化学阻抗与恒流间歇滴定测试对沉积容量为0.51mAh/cm^(2)的电沉积LiAl合金在半电池和全电池中的极化行为进行探究。结果表明:Li在LiAl中的固态扩散是导致LiAl电极在半电池和全电池中极化的主要原因;扩散捕获效应将增加电池内阻,使极化现象增强,最终导致LiAl‖S全电池约1.84和1.55V的低放电电位;通过破坏导致扩散捕获效应的表面α-Al层,可提高电解液中的Li+浓度,促进Li_(2)S析出,从而减轻极化,提高LiAl‖S全电池的放电电压,使其接近热力学放电电位。 展开更多
关键词 锂硫电池 锂铝合金负极 扩散捕获效应 结构退化 负极材料 极化行为
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Possible influence of sulfur content on magnetic aging behaviors of non-oriented electrical steels
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作者 Wei-Min MAO Ping YANG Chang-Rong LI 《Frontiers of Materials Science》 SCIE CSCD 2013年第4期413-416,共4页
Six non-oriented steel sheets of similar grade produced by different steel companies were used to analyze the magnetic aging behaviors after aging at 200~C for 48 h. It was observed that tiny S atoms, besides C and N,... Six non-oriented steel sheets of similar grade produced by different steel companies were used to analyze the magnetic aging behaviors after aging at 200~C for 48 h. It was observed that tiny S atoms, besides C and N, could also induce certain increase of core loss during aging. Thermodynamic calculation indicated that the nucleation driving force of FeS is much higher than those of Fe3C and Fe4N at low temperature, while S atoms, which tend to segregated around dislocations and boundaries, would diffuse rapidly along the crystalline defects while FeS particles would form. Therefore, higher content of tiny S atoms could increase core loss during service time of non-oriented steel sheets. 展开更多
关键词 non-oriented electrical steel sulfur diffusion magnetic aging core loss
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