Arsenic （As） pollutants generated by human activities in karst areas flow into subterranean streams and contaminate groundwater easily because of the unique hydrogeological characteristics of karst areas. To elucida...Arsenic （As） pollutants generated by human activities in karst areas flow into subterranean streams and contaminate groundwater easily because of the unique hydrogeological characteristics of karst areas. To elucidate the reaction mechanisms of arsenic in karst subterranean streams, physical-chemical analysis was conducted by an inductively coupled plasma mass spectrometer and an X-ray fluorescence spectrometer. The results show that inorganic species account for most of the total arsenic, whereas organic arsenic is not detected or occurs in infinitesimal amounts. As（III） accounts for 51.0% ± 9.9% of the total inorganic arsenic. Arsenic attenuation occurs and the attenuation rates of total As, As（III） and As（V） in the Lihu subterranean stream are 51%, 36% and 59%, respectively. To fully explain the main geochemical factors influencing arsenic attenuation, SPSS 13.0 and CANOCO 4.5 bundled with CanoDraw for Windows were used for simple statistical analysis and redundancy analysis （RDA）. Eight main factors, i.e., sediment iron （SFe）, sediment aluminum （SAI）, sediment calcium （SCa）, sediment organic matter （SOM）, sediment manganese （SMn）, water calcium （WCa^2＋）, water magnesium （WMg^2＋）, and water bicarbonate ion （WILCOX） were extracted from thirteen indicators. Their impacts on arsenic content rank as： SFe〉SCa〉WCa^2＋〉SAl〉wHCO3^-〉SMn〉SOM〉WMg^2＋. Of these factors, SFe, SAl, SCa, SOM, SMn, WMg^2＋ and WCa＆2＋ promote arsenic attenuation, whereas WHCO3^- inhibits it. Further investigation revealed that the redox potential （Eh） and pH are adverse to arsenic removal. The dramatic distinction between karst and non-karst terrain is that calcium and bicarbonate are the primary factors influencing arsenic migration in karst areas due to the high calcium concentration and alkalinity of karst water.展开更多
The karst process acts as carbon sequestration for atmospheric CO_2.The amount of karst carbon sequestration (KCS) depends on the discharge of karst catchment and inorganic carbon concentration of the water body.Based...The karst process acts as carbon sequestration for atmospheric CO_2.The amount of karst carbon sequestration (KCS) depends on the discharge of karst catchment and inorganic carbon concentration of the water body.Based on the data from the monitoring station on Banzhai subterranean stream located in Maolan National Nature Reserve of Guizhou province,the process and influence factors of KCS have been analyzed.It shows that the amount of KCS is about 353 t C per year in the catchment of Banzhai subterranean stream,and there is good linear relationship between the strength of KCS and discharge of the stream at various time scales.Therefore,how to monitor the discharge accurately is the key to the estimation of KCS.And stations with real-time monitoring function are very important for KCS calculation because of strong seasonal variability of the karst water cycle.展开更多
Eight spatial structure types are determined through morphology, hydrogeology, hydrology and impulse response in karst districts, with the well studied Houzhai subterranean stream in Puding, Guizhou Province as a samp...Eight spatial structure types are determined through morphology, hydrogeology, hydrology and impulse response in karst districts, with the well studied Houzhai subterranean stream in Puding, Guizhou Province as a sample research area. These types contain peak forest basin, peak forest laterite platform, resurrected peak forest basin, old peak forest funnel depression, peak forest funnel, peak forest funnel depression, peak cluster valley and peak forest doline. In the area, each of them has its respective surface and subterranean structural feature, and morphology, hydrogeology, hydrology and impulse response as well. The difference of responses of subsurface system in different spatial structure types are obtained by time series analysis, frequency spectrum research and decline curve calculation of material current. According to the analysis of the aquifer feature, the upper reaches of suburfall stream is dominated by pipeline flow, the lower reaches is characterized by braided fissure flow drainage system and mixed characteristic exists in the middle reaches. The result of the impulse test shows that the large ascending range of stage in the test on swash condition is in fissure system. However, in pipeline type, especially in the subterranean stream where there is waterfall or incomplete fill of underground water, the ascending range of stage is one quantity level less than the impulse range of stage at some fissure types, showing that change range of stage can indicate the spatial structure characteristics of certain area upper the station. The main direction of karst geomorphic evolution there is positive course except in the west area. It can be seen that karst geomorphological evolution direction can change when discharge datum plane influences some part of a relatively large drainage. In certain time unit, the upper reaches are controlled by old datum plane and the lower reaches by new datum plane. Two opposite geomorphological evolution directions can exist in one drainage.展开更多
基金supported by the Basic Scientific Research Fund of Karst Geological Institute (No. 2012012)the Natural Science Fund Project of Guangxi (Nos. 2013GXNSFBA019218, 2013GXNSFBAO19217)the Project of the China Geological Survey (Nos. 12120113052500, 12120113005200)
文摘Arsenic （As） pollutants generated by human activities in karst areas flow into subterranean streams and contaminate groundwater easily because of the unique hydrogeological characteristics of karst areas. To elucidate the reaction mechanisms of arsenic in karst subterranean streams, physical-chemical analysis was conducted by an inductively coupled plasma mass spectrometer and an X-ray fluorescence spectrometer. The results show that inorganic species account for most of the total arsenic, whereas organic arsenic is not detected or occurs in infinitesimal amounts. As（III） accounts for 51.0% ± 9.9% of the total inorganic arsenic. Arsenic attenuation occurs and the attenuation rates of total As, As（III） and As（V） in the Lihu subterranean stream are 51%, 36% and 59%, respectively. To fully explain the main geochemical factors influencing arsenic attenuation, SPSS 13.0 and CANOCO 4.5 bundled with CanoDraw for Windows were used for simple statistical analysis and redundancy analysis （RDA）. Eight main factors, i.e., sediment iron （SFe）, sediment aluminum （SAI）, sediment calcium （SCa）, sediment organic matter （SOM）, sediment manganese （SMn）, water calcium （WCa^2＋）, water magnesium （WMg^2＋）, and water bicarbonate ion （WILCOX） were extracted from thirteen indicators. Their impacts on arsenic content rank as： SFe〉SCa〉WCa^2＋〉SAl〉wHCO3^-〉SMn〉SOM〉WMg^2＋. Of these factors, SFe, SAl, SCa, SOM, SMn, WMg^2＋ and WCa＆2＋ promote arsenic attenuation, whereas WHCO3^- inhibits it. Further investigation revealed that the redox potential （Eh） and pH are adverse to arsenic removal. The dramatic distinction between karst and non-karst terrain is that calcium and bicarbonate are the primary factors influencing arsenic migration in karst areas due to the high calcium concentration and alkalinity of karst water.
基金funded by the project (No.41072192)from National Natural Science Foundation of Chinathe project(No.1212011087122)from China Geological Survey
文摘The karst process acts as carbon sequestration for atmospheric CO_2.The amount of karst carbon sequestration (KCS) depends on the discharge of karst catchment and inorganic carbon concentration of the water body.Based on the data from the monitoring station on Banzhai subterranean stream located in Maolan National Nature Reserve of Guizhou province,the process and influence factors of KCS have been analyzed.It shows that the amount of KCS is about 353 t C per year in the catchment of Banzhai subterranean stream,and there is good linear relationship between the strength of KCS and discharge of the stream at various time scales.Therefore,how to monitor the discharge accurately is the key to the estimation of KCS.And stations with real-time monitoring function are very important for KCS calculation because of strong seasonal variability of the karst water cycle.
文摘Eight spatial structure types are determined through morphology, hydrogeology, hydrology and impulse response in karst districts, with the well studied Houzhai subterranean stream in Puding, Guizhou Province as a sample research area. These types contain peak forest basin, peak forest laterite platform, resurrected peak forest basin, old peak forest funnel depression, peak forest funnel, peak forest funnel depression, peak cluster valley and peak forest doline. In the area, each of them has its respective surface and subterranean structural feature, and morphology, hydrogeology, hydrology and impulse response as well. The difference of responses of subsurface system in different spatial structure types are obtained by time series analysis, frequency spectrum research and decline curve calculation of material current. According to the analysis of the aquifer feature, the upper reaches of suburfall stream is dominated by pipeline flow, the lower reaches is characterized by braided fissure flow drainage system and mixed characteristic exists in the middle reaches. The result of the impulse test shows that the large ascending range of stage in the test on swash condition is in fissure system. However, in pipeline type, especially in the subterranean stream where there is waterfall or incomplete fill of underground water, the ascending range of stage is one quantity level less than the impulse range of stage at some fissure types, showing that change range of stage can indicate the spatial structure characteristics of certain area upper the station. The main direction of karst geomorphic evolution there is positive course except in the west area. It can be seen that karst geomorphological evolution direction can change when discharge datum plane influences some part of a relatively large drainage. In certain time unit, the upper reaches are controlled by old datum plane and the lower reaches by new datum plane. Two opposite geomorphological evolution directions can exist in one drainage.
