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Electronic Absorption Spectroscopy of H2X (X=O, Te, Po): Theoretical Treatment of Spin-Orbit Effects
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作者 Chérif A. A. Ndoye Chantal Daniel 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2009年第2期171-177,共7页
The electronic spectroscopy of H2X (X=O, Te, Po) was investigated by means of spinorbit configuration interaction (EPCISO) and restricted active space state interaction (SORASSI). The transition energies to the ... The electronic spectroscopy of H2X (X=O, Te, Po) was investigated by means of spinorbit configuration interaction (EPCISO) and restricted active space state interaction (SORASSI). The transition energies to the low-lying singlet and triplet states of H2O, in which the SO interaction is zero, compare rather well with the experimental data as well as to other theoretical values. The theoretical electronic absorption spectrum is characterized by three allowed transitions A^1B1 (2px(O)→σ^*g/3s(O)), B^1A1(σg→σ^*g/3s(O)) and A^1S2(σg→σ^*u) calculated at 7.68, 9.94, and 11.72 eV, respectively. The theoretical absorption spectra of H2X (X=Te, Po) are shifted to the red with the A^1B1 (npx(X)→σ^*g) states calculated at 5.06 eV (H2Te) and 4.40 eV (H2Po) and the A^1B2 (σg→σ^*u) states calculated at 7.89 eV (H2Te) and 7.77 eV (H2Po). The largest SO splitting amounts to 0.34 eV and is found for the lowest a^3A1 of H2Po. In H2Te the SO effects are still negligible with a maximum splitting of 0.04 eV for the lowest a^3B2. The two methods lead to comparable results but the EPCISO approach depends strongly on the reference wavefunction. 展开更多
关键词 spin-orbit Excited state Group dihydride
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Anomalous Hall effect in Bernal tetralayer graphene enhanced by spin-orbit interaction
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作者 Zhuangzhuang Qu Zhihao Chen +9 位作者 Xiangyan Han Zhiyu Wang Zhuoxian Li Qianling Liu Wenjun Zhao Kenji Watanabe Takashi Taniguchi Zhi-Gang Cheng Zizhao Gan Jianming Lu 《Chinese Physics B》 2025年第3期177-181,共5页
Spin-orbit interaction(SOI)can be introduced by the proximity effect to modulate the electronic properties of graphene-based heterostructures.In this work,we stack trilayer WSe_(2) on Bernal tetralayer graphene to inv... Spin-orbit interaction(SOI)can be introduced by the proximity effect to modulate the electronic properties of graphene-based heterostructures.In this work,we stack trilayer WSe_(2) on Bernal tetralayer graphene to investigate the influence of SOI on the anomalous Hall effect(AHE).In this structurally asymmetric device,by comparing the magnitude of AHE at positive and negative displacement fields,we find that AHE is strongly enhanced by bringing electrons in proximity to the WSe_(2) layer.Meanwhile,the enhanced AHE signal persists up to 80 K,providing important routes for topological device applications at high temperatures. 展开更多
关键词 anomalous Hall effect proximity effect Bernal tetralayer graphene spin-orbit interaction
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Effective spin dynamics of spin-orbit coupled matter-wave solitons in optical lattices
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作者 Kajal Krishna Dey Golam Ali Sekh 《Communications in Theoretical Physics》 2025年第1期172-178,共7页
We consider matter-wave solitons in spin-orbit coupled Bose-Einstein condensates embedded in an optical lattice and study the dynamics of the soliton within the framework of Gross-Pitaevskii equations.We express spin ... We consider matter-wave solitons in spin-orbit coupled Bose-Einstein condensates embedded in an optical lattice and study the dynamics of the soliton within the framework of Gross-Pitaevskii equations.We express spin components of the soliton pair in terms of nonlinear Bloch equations and investigate the effective spin dynamics.It is seen that the effective magnetic field that appears in the Bloch equation is affected by optical lattices,and thus the optical lattice influences the precessional frequency of the spin components.We make use of numerical approaches to investigate the dynamical behavior of density profiles and center-of-mass of the soliton pair in the presence of the optical lattice.It is shown that the spin density is periodically varying due to flipping of spinors between the two states.The amplitude of spin-flipping oscillation increases with lattice strength.We find that the system can also exhibit interesting nonlinear behavior for chosen values of parameters.We present a fixed point analysis to study the effects of optical lattices on the nonlinear dynamics of the spin components.It is seen that the optical lattice can act as a control parameter to change the dynamical behavior of the spin components from periodic to chaotic. 展开更多
关键词 spin-orbit coupled Bose-Einstein condensates effective spin dynamics regular and chaotic dynamics
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Interlayer exchange coupling effects on the spin-orbit torque in synthetic magnets
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作者 Haodong Fan Zhongshu Feng +11 位作者 Tingwei Chen Xiaofeng Han Xinyu Shu Mingzhang Wei Shiqi Liu Mengxi Wang Shengru Chen Xuejian Tang Menghao Jin Yungui Ma Bo Liu Tiejun Zhou 《Chinese Physics B》 2025年第9期654-661,共8页
Interlayer exchange coupling(IEC)plays a critical role in spin-orbit torque(SOT)switching in synthetic magnets.This work establishes a fundamental correlation between IEC and SOT dynamics within Co/Pt-based synthetic ... Interlayer exchange coupling(IEC)plays a critical role in spin-orbit torque(SOT)switching in synthetic magnets.This work establishes a fundamental correlation between IEC and SOT dynamics within Co/Pt-based synthetic antiferromagnets and synthetic ferromagnets.The antiferromagnetic and ferromagnetic coupling states are precisely engineered through Ruderman-Kittel-Kasuya-Yosida(RKKY)interactions by modulating the Ir spacer thickness.Experimental results reveal that the critical switching current density exhibits a strong positive correlation with the IEC strength,regardless of the coupling type.A comprehensive theoretical framework based on the Landau-Lifshitz-Gilbert equation elucidates how IEC contributes to the effective energy barrier that must be overcome during SOT-induced magnetization switching.Significantly,the antiferromagnetically coupled samples demonstrate enhanced SOT efficiency,with the spin Hall angle being directly proportional to the antiferromagnetic exchange coupling field.These insights establish a coherent physical paradigm for understanding IEC-dependent SOT dynamics and provide strategic design principles for the development of energy-efficient next-generation spintronic devices. 展开更多
关键词 interlayer exchange coupling spin-orbit torque synthetic antiferromagnet
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Surface plasmon polariton-enhanced exciton-mediated magnetic proximity effect in twisted CrOCl/CrOCl/WSe_(2) heterostructures
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作者 Xing Xie Junying Chen +7 位作者 Shaofei Li Siyu Zhang Shikun Hou Xian Zhang Jun He Zongwen Liu Jian-Tao Wang Yanping Liu 《Nano Research》 2026年第1期1329-1338,共10页
The magnetic proximity effect enables interfacial modulation of excitonic and spin-valley properties in transition metal dichalcogenides(TMDs),offering a versatile route toward next-generation spintronic and valleytro... The magnetic proximity effect enables interfacial modulation of excitonic and spin-valley properties in transition metal dichalcogenides(TMDs),offering a versatile route toward next-generation spintronic and valleytronic devices.However,the inherently weak photoluminescence(PL)of bright excitons—suppressed by proximity-induced darkening mechanisms—hinders the optical detection of magnetic interactions.Here,we demonstrate substantial exciton emission enhancement in CrOCl/WSe_(2)(HS)and twisted 90°-CrOCl/CrOCl/WSe_(2)(THS)heterostructures by employing plasmonic Au nanopillar arrays to activate surface plasmon polariton(SPP)coupling.The neutral exciton emission intensity is enhanced by factors of 5 and 18 for HS/Au and THS/Au,respectively,with enhancements persisting under high magnetic fields and elevated temperatures(~10-fold in THS/Au).Enabled by this amplification,we observe pronounced Zeeman splitting and modified intervalley relaxation pathways,indicating significant magnetic proximity interactions.Finite-element simulations and first-principles calculations reveal that the enhancement arises from local electromagnetic field concentration and layer-dependent interfacial coupling.Our results establish SPP-assisted PL enhancement as an effective strategy for probing weak magneto-optical signatures,paving the way for detailed exploration of exciton-magnon coupling and interface-driven quantum phenomena in twodimensional(2D)magnetic heterostructures. 展开更多
关键词 magnetic proximity effect HETEROSTRUCTURES surface plasmon polariton photoluminescence enhancement Zeeman effect intervalley scattering
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Electronically Conductive Metal−Organic Framework With Photoelectric and Photothermal Effect as a Stable Cathode for High-Temperature Photo-Assisted Zn/Sn-Air Battery
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作者 Jiangchang Chen Chuntao Yang +2 位作者 Yao Dong Ya Han Yingjian 《Carbon Energy》 2026年第1期105-114,共10页
Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electro... Rechargeable Zn/Sn-air batteries have received considerable attention as promising energy storage devices.However,the electrochemical performance of these batteries is significantly constrained by the sluggish electrocatalytic reaction kinetics at the cathode.The integration of light energy into Zn/Sn-air batteries is a promising strategy for enhancing their performance.However,the photothermal and photoelectric effects generate heat in the battery under prolonged solar irradiation,leading to air cathode instability.This paper presents the first design and synthesis of Ni_(2)-1,5-diamino-4,8-dihydroxyanthraquinone(Ni_(2)DDA),an electronically conductiveπ-d conjugated metal-organic framework(MOF).Ni_(2)DDA exhibits both photoelectric and photothermal effects,with an optical band gap of~1.14 eV.Under illumination,Ni_(2)DDA achieves excellent oxygen evolution reaction performance(with an overpotential of 245 mV vs.reversible hydrogen electrode at 10 mA cm^(−2))and photothermal stability.These properties result from the synergy between the photoelectric and photothermal effects of Ni_(2)DDA.Upon integration into Zn/Sn-air batteries,Ni_(2)DDA ensures excellent cycling stability under light and exhibits remarkable performance in high-temperature environments up to 80℃.This study experimentally confirms the stable operation of photo-assisted Zn/Sn-air batteries under high-temperature conditions for the first time and provides novel insights into the application of electronically conductive MOFs in photoelectrocatalysis and photothermal catalysis. 展开更多
关键词 electronically conductive MOFs high temperatures photo-assisted Zn/Sn-air batteries photoelectric effects photothermal effects
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CUDA‑based GPU‑only computation for efficient tracking simulation of single and multi‑bunch collective effects
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作者 Keon Hee Kim Eun‑San Kim 《Nuclear Science and Techniques》 2026年第1期61-79,共19页
Beam-tracking simulations have been extensively utilized in the study of collective beam instabilities in circular accelerators.Traditionally,many simulation codes have relied on central processing unit(CPU)-based met... Beam-tracking simulations have been extensively utilized in the study of collective beam instabilities in circular accelerators.Traditionally,many simulation codes have relied on central processing unit(CPU)-based methods,tracking on a single CPU core,or parallelizing the computation across multiple cores via the message passing interface(MPI).Although these approaches work well for single-bunch tracking,scaling them to multiple bunches significantly increases the computational load,which often necessitates the use of a dedicated multi-CPU cluster.To address this challenge,alternative methods leveraging General-Purpose computing on Graphics Processing Units(GPGPU)have been proposed,enabling tracking studies on a standalone desktop personal computer(PC).However,frequent CPU-GPU interactions,including data transfers and synchronization operations during tracking,can introduce communication overheads,potentially reducing the overall effectiveness of GPU-based computations.In this study,we propose a novel approach that eliminates this overhead by performing the entire tracking simulation process exclusively on the GPU,thereby enabling the simultaneous processing of all bunches and their macro-particles.Specifically,we introduce MBTRACK2-CUDA,a Compute Unified Device Architecture(CUDA)ported version of MBTRACK2,which facilitates efficient tracking of single-and multi-bunch collective effects by leveraging the full GPU-resident computation. 展开更多
关键词 Code development GPU computing Collective effects
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Synergistic antibacterial effect and mechanism of benzalkonium chloride and polymyxin B against Pseudomonas aeruginosa
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作者 Caihong Wang Jiaxin Zhang +3 位作者 Tong Li Jingwei Wang Dan Xu Qiao Ma 《Journal of Environmental Sciences》 2026年第1期555-564,共10页
Benzalkonium chloride(BAC)is widely employed as a broad-spectrum biocide and has emerged as a significant environmental pollutant.Polymyxin B(PB)serves as the last-line defense for the treatment of Gram-negative patho... Benzalkonium chloride(BAC)is widely employed as a broad-spectrum biocide and has emerged as a significant environmental pollutant.Polymyxin B(PB)serves as the last-line defense for the treatment of Gram-negative pathogens.Previous studies reported that BAC-adapted Pseudomonas aeruginosa increased the tolerance to PB.Herein,we present the novel finding that the combination of BAC and PB exhibited synergistic antibacterial effects against P.aeruginosa.Time-killing assay demonstrated a significant reduction in bacterial cell viability.Scanning electron microscopy,zeta potential analysis,hydrophobicity measurements,and fluorescence probe analyses collectively revealed severe disruption of the cell envelope and membrane potential induced by the combination of BAC and PB.Transcriptomic analysis revealed that the BAC-PB combination notably downreg-ulated the expression of genes involved in lipid A modification and cell envelope production,including phoPQ,pmrAB,bamABCDE,lptABCDEG,lolB,yidC,and murJ.Additionally,the combination group exhibited augmented production of reactive oxygen species and diminished ATP synthesis.The expression of the genes associated with substance metabolism and energy generation was significantly impeded.This study provides significant implica-tions for the interactions of biocides and antibiotics on Gram-negative pathogens,while also addressing antibiotic resistance and developing the external treatment strategy for Pseudomonas-infected wounds and burns. 展开更多
关键词 Pseudomonas aeruginosa Benzalkonium chloride Polymyxin B Synergistic effect Membrane disruption
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Postoperative effective lens position and refraction changes with three different types of intraocular lens
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作者 Xi-Xia Ding Lin-Feng Xiang +5 位作者 Wen-Tao Tong Dan-Dan Wang Hong-FangZhang Ping-Jun Chang Fu-Man Yang Yun-E Zhao 《International Journal of Ophthalmology(English edition)》 2026年第2期260-265,共6页
AIM:To evaluate and compare alterations in the effective lens position(ELP)and refractive outcomes among three distinct intraocular lens(IOL)types.METHODS:Patients with cataracts were enrolled and allocated to 3 group... AIM:To evaluate and compare alterations in the effective lens position(ELP)and refractive outcomes among three distinct intraocular lens(IOL)types.METHODS:Patients with cataracts were enrolled and allocated to 3 groups:Group A(implanted with the SN6CWS),Group B(implanted with the MI60),and Group C(implanted with the Aspira-aA).ELP measurements were obtained with swept-source optical coherence tomography(SS-OCT)at 1d,1wk,1mo,and 3mo postoperatively.Subjective refraction assessments were conducted at 1wk,1mo,and 3mo following surgery.RESULTS:The study included 189 eyes of 150 cataract patients(66 males).There were 77 eyes in Group A,55 eyes in Group B,and 57 eyes in Group C.The root mean square of the ELP(ELPRMS)within the initial 3mo was significantly lower for Group A than for Groups B and C.Refractive changes within Group A were not significant across the time points of 1wk,1mo,and 3mo.Conversely,both Group B and Group C demonstrated statistically significant shifts toward hyperopia from 1wk to 3mo postsurgery.CONCLUSION:Among the three IOLs examined,the SN6CWS IOL showes the greatest stability during the first 3mo postoperatively.Between 1wk and 3mo after surgery,notable hyperopic shifts are evident in eyes implanted with the MI60 and Aspira-aA IOLs,whereas refractive outcomes remain relatively constant in eyes implanted with SN6CWS IOLs. 展开更多
关键词 effective lens position REFRACTION intraocular lens swept-source optical coherence tomography
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Effect of Thermoelectric Cooler Arrangements on Thermal Performance and Energy Saving in Electronic Applications:An Experimental Study
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作者 M.N.Abd-Al Ameer Iman S.Kareem Ali A.Ismaeel 《Energy Engineering》 2026年第1期511-526,共16页
Electrical and electronic devices face significant challenges in heatmanagement due to their compact size and high heat flux,which negatively impact performance and reliability.Conventional coolingmethods,such as forc... Electrical and electronic devices face significant challenges in heatmanagement due to their compact size and high heat flux,which negatively impact performance and reliability.Conventional coolingmethods,such as forced air cooling,often struggle to transfer heat efficiently.In contrast,thermoelectric coolers(TECs)provide an innovative active cooling solution to meet growing thermal management demands.In this research,a refrigerant based on mono ethylene glycol and distilled water was used instead of using gases,in addition to using thermoelectric cooling units instead of using a compressor in traditional refrigeration systems.This study evaluates the performance of a Peltierbased thermalmanagement systemby analyzing the effects of using two,three,and four Peltiermodules on cooling rates,power consumption,temperature reduction,and system efficiency.Experimental results indicate that increasing the number of Peltier modules significantly enhances cooling performance.The four-module system achieved an optimal balance between cooling speed and energy efficiency,reducing the temperature of a liquidmixture(30% mono ethylene glycol+70% distilled water plus laser dyes)to 8℃ in just 17 min.It demonstrated a cooling rate of 0.794℃/min and a high coefficient of performance(COP)of 1.2 while consuming less energy than the two-and three-module systems.Furthermore,the study revealed that increasing the number of modules led to faster air cooling and improved temperature reduction.These findings highlight the importance of selecting the optimal number of Peltier modules to enhance efficiency and cooling speed whileminimizing energy consumption.This makes TEC technology a sustainable and effective solution for applications requiring rapid and reliable thermal management. 展开更多
关键词 Energy consumption mono ethylene glycol Peltier effect performance factor(COP)
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Magnetic Properties and Kondo Effect in Ce_(3)TiBi_(5) under High Pressure
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作者 L.C.Fu W.J.Cheng +11 位作者 L.C.Shi B.S.Min Y.Peng J.Zhang J.Song Z.Deng J.F.Zhao Y.Liu J.L.Zhu J.F.Zhang X.C.Wang C.Q.Jin 《Chinese Physics Letters》 2026年第1期184-197,共14页
The magnetic properties and Kondo effect in Ce3TiBi5 with a quasi-one-dimensional structure were investigated using in situ high-pressure resistivity measurements up to 48 GPa.At ambient pressure,Ce_(3)TiBi_(5) underg... The magnetic properties and Kondo effect in Ce3TiBi5 with a quasi-one-dimensional structure were investigated using in situ high-pressure resistivity measurements up to 48 GPa.At ambient pressure,Ce_(3)TiBi_(5) undergoes an antiferromagnetic(AFM)transition at T_(N)∼5 K.Under high pressures within 8.9 GPa,we find that Kondo scattering contributes differently to the high-temperature resistance,R(T),depending on the applied current direction,demonstrating a significantly anisotropic Kondo effect.The complete P–T phase diagram has been constructed,in which the pressure dependence of T_(N) exhibits a dome-like shape.The AFM order remains robust under pressure,even when the coherence temperature T^(*) far exceeds 300 K.We attribute the observed anisotropic Kondo effect and the robust AFM to the underlying anisotropy in electronic hybridization under high pressure. 展开更多
关键词 magnetic properties resistivity measurements high pressure kondo effect kondo effectthe kondo scattering Ce TbI
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Investigation of natural and anthropogenic effects on aerosols optical properties over the Western Pacific ocean by the research vessel KEXUE
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作者 Jinyuan Xin Yining Ma +6 位作者 Xiangguang Zhang Yongjing Ma Xiaoyan Wu Fangkun Wu Quan Liu Yilong Lyu Jiawei Jiang 《Journal of Environmental Sciences》 2026年第1期596-605,共10页
In winter 2018,an aerosol physicochemical experiment was conducted in the Western Pacific Ocean(WPO)aboard the Research Vessel KEXUE of Chinese Academy of Sciences.This study systematically investigated both natural a... In winter 2018,an aerosol physicochemical experiment was conducted in the Western Pacific Ocean(WPO)aboard the Research Vessel KEXUE of Chinese Academy of Sciences.This study systematically investigated both natural and anthropogenic effects on marine aerosols optical properties,as well as the applicability of multi-satellite products and IMPROVE equation.The averaged aerosol optical depth(AOD500 nm)was 0.31±0.16 andÅngström exponent440–675 nm was 0.29±0.30.In offshore China,significant anthropogenic emissions affected the marine environment.In remote WPO,dust aerosols transported from northern China,Siberia,Central Asia,and those settling from the upper troposphere originating from north Africa,Arabian peninsula,and western India,were dominant.The spatial trends of AOD were opposite in the mid-latitude and southern seas of WPO.The highest AOD,0.32±0.23,appeared along the coast of South Asia at mid-latitude,decreasing from offshore seas to remote oceans.In low-latitude and equatorial seas,AOD significantly increased from coast to remote oceans.Ångström exponent dropped significantly from the coast to remote oceans as anthropogenic influence diminished across the entire WPO.Correlation analysis showed that both MODIS-C6 and Himawari AOD prod-ucts showed similar applicability in coastal urban areas,while Himawari AOD is highly recommended for coastal background and marine environment due to its finer resolution.The extinction coefficient derived from PM_(2.5) chemical compositions using IMPROVE algorithm exhibited a significant correlation(R^(2)=0.58)with the con-currently measured AOD in the absence of long-distance transport,suggesting that the IMPROVE is a reasonable proxy of the columnar average of marine aerosol extinctions free from transport influences. 展开更多
关键词 Aerosol optical properties Natural and anthropogenic effects Improve algorithm Ship-borne experiment Western Pacific Ocean
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Dynamic fracture behavior and coupled impact effect of as-cast W-Zr-Ti energetic structural material
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作者 Yuxuan Qi Liang Mao +3 位作者 Chunlan Jiang Guitao Liu Kongxun Zhao Mengchen Zhang 《Defence Technology(防务技术)》 2026年第1期422-435,共14页
This paper prepared a novel as-cast W-Zr-Ti metallic ESM using high-frequency vacuum induction melting technique.The above ESM performs a typical elastic-brittle material feature and strain rate strengthening behavior... This paper prepared a novel as-cast W-Zr-Ti metallic ESM using high-frequency vacuum induction melting technique.The above ESM performs a typical elastic-brittle material feature and strain rate strengthening behavior.The specimens exhibit violent chemical reaction during the fracture process under the impact loading,and the size distribution of their residual debris follows Rosin-Rammler model.The dynamic fracture toughness is obtained by the fitting of debris length scale,approximately 1.87 MPa·m~(1/2).Microstructure observation on residual debris indicates that the failure process is determined by primary crack propagation under quasi-static compression,while it is affected by multiple cracks propagation in both particle and matrix in the case of dynamic impact.Impact test demonstrates that the novel energetic fragment performs brilliant penetration and combustion effect behind the front target,leading to the effective ignition of fuel tank.For the brittleness of as-cast W-ZrTi ESM,further study conducted bond-based peridynamic(BB-PD)C++computational code to simulate its fracture behavior during penetration.The BB-PD method successfully captured the fracture process and debris cloud formation of the energetic fragment.This paper explores a novel as-cast metallic ESM,and provides an available numerical avenue to the simulation of brittle energetic fragment. 展开更多
关键词 Energetic structural material Dynamic fracture behavior Coupled impact effect Mechanical property Peridynamics As-cast W-Zr-Ti alloy
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Effectiveness and Safety of Lenvatinib and Everolimus after Immune Checkpoint Inhibitors in Metastatic Renal Cell Cancer:A Systematic Review
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作者 Giacomo Iovane Luca Traman +5 位作者 Michele Maffezzoli Giuseppe Fornarini Domenico Corradi Debora Guareschi Matteo Santoni Sebastiano Buti 《Oncology Research》 2026年第1期57-70,共14页
Background:While the treatment of metastatic renal cell carcinoma(mRCC)is evolving due to immune checkpoint inhibitors(ICIs),optimal strategies for later lines of therapy have yet to be defined.The combination of lenv... Background:While the treatment of metastatic renal cell carcinoma(mRCC)is evolving due to immune checkpoint inhibitors(ICIs),optimal strategies for later lines of therapy have yet to be defined.The combination of lenvatinib and everolimus represents a viable option,and the present review aimed to summarize its activity,effectiveness,and safety.Methods:A systematic review of the literature was conducted using PubMed,targeting studies published between 2018 and 2025.Eligible studies included English-language prospective and retrospective trials reporting survival outcomes in mRCC patients treated with lenvatinib and everolimus after at least one ICI-containing regimen.Results:Nine studies met the inclusion criteria,encompassing a total of 441 patients.The lenvatinib and everolimus combination was primarily used in the third and subsequent lines of therapy.Median overall survival ranged from 7.5 to 24.5 months,while median progression-free survival was more consistent,between 6.1 and 6.7 months,except for one study reporting 12.9 months.Objective response rates varied widely(14.0%–55.7%).Adverse events of grade≥3 did not exceed the expected rate,with diarrhoea and proteinuria as the most reported events.Dose reductions and treatment discontinuations due to toxicity occurred but were generally lower than in prior pivotal trials.Conclusions:Real-world evidence suggests that lenvatinib and everolimus represent an effective and safe option after ICI failure in mRCC patients.Nevertheless,the lack of randomized phase III trials and the heterogeneity of existing studies highlight the need for more robust prospective research to guide post-ICI therapeutic strategies. 展开更多
关键词 Metastatic renal cell carcinoma(mRCC) immune checkpoint inhibitors(ICIs) lenvatinib EVEROLIMUS effectIVENESS SAFETY systematic review
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Lithium Nitrate Effects for Lithium-Based Chemical Batteries:A Review
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作者 Xianshu Wang Junru Wu +6 位作者 Huirong Wang Xiangshao Yin Zhuo Zhou Yuanyuan Huang Yelong Zhang Weishan Li Baohua Li 《Carbon Energy》 2026年第1期197-222,共26页
Lithium metal batteries(LMBs)have been regarded as one of the most promising alternatives in the post-lithium battery era due to their high energy density,which meets the needs of light-weight electronic devices and l... Lithium metal batteries(LMBs)have been regarded as one of the most promising alternatives in the post-lithium battery era due to their high energy density,which meets the needs of light-weight electronic devices and long-range electric vehicles.However,technical barriers such as dendrite growth and poor Li plating/stripping reversibility severely hinder the practical application of LMBs.However,lithium nitrate(LiNO_(3))is found to be able to stabilize the Li/electrolyte interface and has been used to address the above challenges.To date,considerable research efforts have been devoted toward understanding the roles of LiNO_(3) in regulating the surface properties of Li anodes and toward the development of many effective strategies.These research efforts are partially mentioned in some articles on LMBs and yet have not been reviewed systematically.To fill this gap,we discuss the recent advances in fundamental and technological research on LiNO_(3) and its derivatives for improving the performances of LMBs,particularly for Li-sulfur(S),Li-oxygen(O),and Li-Li-containing transition-metal oxide(LTMO)batteries,as well as LiNO_(3)-containing recipes for precursors in battery materials and interphase fabrication.This review pays attention to the effects of LiNO_(3) in lithium-based batteries,aiming to provide scientific guidance for the optimization of electrode/electrolyte interfaces and enrich the design of advanced LMBs. 展开更多
关键词 effects and mechanisms LiNO_(3)derivatives LiNO_(3)-containing recipes lithium metal anode Lithium nitrate basis lithium-based chemical batteries
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Electron Momentum Spectroscopy of Valence Orbitals of n-Propyl Iodide: Spin-Orbit Coupling Effect and Intramolecular Orbital Interaction
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作者 王恩亮 史钰峰 +3 位作者 单旭 阳弘江 张卫 陈向军 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2014年第5期503-511,I0003,共10页
The binding energy spectrum and electron momentum distributions for the outer valence orbitals of n-propyl iodide molecule have been measured using the electron momentum spectrometer employing non-coplanar asymmetric ... The binding energy spectrum and electron momentum distributions for the outer valence orbitals of n-propyl iodide molecule have been measured using the electron momentum spectrometer employing non-coplanar asymmetric geometry at impact energy of 2.5 keV plus binding energy. The ionization bands have been assigned in detail via the high accuracy SACCI general-R method calculation and the experimental momentum profiles are compared with the theoretical ones calculated by Hartree-Fock and B3LYP/aug-cc-pVTZ(C,H)6-311G??(I). The spin-orbit coupling effect and intramolecular orbital interaction have been analyzed for the outermost two bands, which are assigned to the iodine 5p lone pairs, using NBO method and non-relativistic as well as relativistic calculations. It is found that both of the interactions will lead to the observed differences in electron momentum distributions. The experimental results agree with the relativistic theoretical momentum profiles, indicating that the spin-orbit coupling effect dominates in n-propyl iodide molecule. 展开更多
关键词 n-Propyl iodide Electron momentum spectroscopy spin-orbit coupling effect Intramolecular orbital interaction
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Spin-Orbit State-Resolved Differential Cross Sections of S(^(1)D)+HD Reaction
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作者 Yu Li Heilong Wang +3 位作者 Zhirun Jiao Hongtao Zhang Chunlei Xiao Xueming Yang 《Chinese Journal of Chemical Physics》 2025年第5期582-586,I0147,共6页
Here,we report the spin-orbit state-resolved differential cross sections(DCSs)for the prototype barrierless reaction S(^(1)D)+HD.Both product channels,namely H+SD(^(2)Π_(3/2,1/2))and D+SH(^(2)Π_(3/2,1/2)),were measu... Here,we report the spin-orbit state-resolved differential cross sections(DCSs)for the prototype barrierless reaction S(^(1)D)+HD.Both product channels,namely H+SD(^(2)Π_(3/2,1/2))and D+SH(^(2)Π_(3/2,1/2)),were measured by high-resolution crossed molecular beam experiments.The DCSs of the two product channels show an overall forward-backward symmetry,in accordance with statistical model predictions.However,the DCSs for different spin-orbit manifolds show different preferences in forward or backward scattering directions at the same collision energies.This study reveals that,even though the title reaction proceeds via the long-lived complex mechanism,the spin-orbit coupling effects in the product channels play an important role in the reaction process. 展开更多
关键词 Barrierless reaction spin-orbit effects Crossed molecular beam Differential cross sections
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Vectorial spin-orbital Hall effect of light upon tight focusing and its experimental observation in azopolymer films 被引量:2
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作者 Alexey Porfirev Svetlana Khonina +2 位作者 Andrey Ustinov Nikolay Ivliev Ilya Golub 《Opto-Electronic Science》 2023年第7期12-30,共19页
Hall effect of light is a result of symmetry breaking in spin and/or orbital angular momentum(OAM)possessing optical system and is caused by e.g.refractive index gradient/interface between media or focusing of a spati... Hall effect of light is a result of symmetry breaking in spin and/or orbital angular momentum(OAM)possessing optical system and is caused by e.g.refractive index gradient/interface between media or focusing of a spatially asymmetrical beam,similar to the electric field breaking the symmetry in spin Hall effect for electrons.The angular momentum(AM)conservation law in the ensuing asymmetric system dictates redistribution of spin and orbital angular momentum,and is manifested in spin-orbit,orbit-orbit,and orbit-spin conversions and reorganization,i.e.spin-orbit and orbit-orbit interaction.This AM restructuring in turn requires shifts of the barycenter of the electric field of light.In the present study we show,both analytically and by numerical simulation,how different electric field components are displaced upon tight focusing of an asymmetric light beam having OAM and spin.The relation between field components shifts and the AM components shifts/redistribution is presented too.Moreover,we experimentally demonstrate,for the first time,to the best of our knowledge,the spin-orbit Hall effect of light upon tight focusing in free space.This is achieved using azopolymers as a media detecting longitudinal or z component of the electrical field of light.These findings elucidate the Hall effect of light and may broaden the spectrum of its applications. 展开更多
关键词 spin-orbital Hall effect of light symmetry breaking spin-orbit interaction AZOPOLYMERS optical vortex polarization
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Characteristics of anomalous Hall effect in spin-polarized two-dimensional electron gases in the presence of both intrinsic,extrinsic,and external electric-field induced spin-orbit couplings 被引量:1
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作者 Liu Song Yan Yu-Zhen Hu Liang-Bin 《Chinese Physics B》 SCIE EI CAS CSCD 2012年第2期469-476,共8页
The various competing contributions to the anomalous Hall effect in spin-polarized two-dimensional electron gases in the presence of both intrinsic, extrinsic and external electric-field induced spin-orbit coupling we... The various competing contributions to the anomalous Hall effect in spin-polarized two-dimensional electron gases in the presence of both intrinsic, extrinsic and external electric-field induced spin-orbit coupling were investigated theoretically. Based on a unified semiclassical theoretical approach, it is shown that the total anomalous Hall conductivity can be expressed as the sum of three distinct contributions in the presence of these competing spin-orbit interactions, namely an intrinsic contribution determined by the Berry curvature in the momentum space, an extrinsic contribution determined by the modified Bloch band group velocity and an extrinsic contribution determined by spin-orbit-dependent impurity scattering. The characteristics of these competing contributions are discussed in detail in the paper. 展开更多
关键词 anomalous Hall effect intrinsic spin orbit coupling extrinsic spin orbit coupling exter- nal electric-field induced spin-orbit coupling
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Spin-Orbit Scattering Effects on Hall Conductivity in a Layered Disordered Electron System
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作者 王勇刚 杨永宏 《Journal of Southeast University(English Edition)》 EI CAS 2002年第2期191-196,共6页
Spin-orbit scattering effects in a layered quasi-2D disordered electron system have been investigated by the diagrammatic techniques in perturbation theory. The expression of Cooperon (propagator in particle-particle ... Spin-orbit scattering effects in a layered quasi-2D disordered electron system have been investigated by the diagrammatic techniques in perturbation theory. The expression of Cooperon (propagator in particle-particle channel) is obtained as the function of interlayer coupling. The analytical result for the quantum correction to Hall conductivity has been obtained as functions of elastic, inelastic and spin-orbit scattering times. It is shown that the strong and weak couplings correspond, respectively, to the 3D and 2D situations. The Hall coefficient is shown to vanish. The relevant dimensional crossover behavior from 3D to 2D with decreasing the interlayer coupling has been discussed, and the condition for the crossover has been obtained. The present theory is expected to apply for the electronic transport in tunneling superlattices. 展开更多
关键词 layered system WEAK-LOCALIZATION Hall conductivity spin-orbit scattering
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