The interaction between charge and spin degrees of freedom has always been the central issue of condensed matter physics,and transition metal dichalcogenides(TMDs)provide an ideal platform to study it benefiting from ...The interaction between charge and spin degrees of freedom has always been the central issue of condensed matter physics,and transition metal dichalcogenides(TMDs)provide an ideal platform to study it benefiting from their highly tunable properties.In this article,the influence of Fe intercalation in NbSe_(2)was elaborately investigated using a combination of techniques.Magnetic studies have shown that the insertion of Fe atoms induces an antiferromagnetic state in which the easy axis aligns out of the plane.The sign reversal of the magnetoresistance across the Neel temperature can be satisfactorily explained by the moderate interaction between electrons and local spins.The Hall and Seebeck measurements reveal a multi-band nature,and the contribution of various phonon scattering processes is discussed based on the thermal conductivity and specific heat data.展开更多
钙钛矿氧化物异质界面中二维电子气(two-dimensional electron gas,2DEG)与界面超导性的发现使其成为研究热点之一.近年来,氧化物界面研究取得突破性进展,除了传统的LaAlO_(3)/SrTiO_(3)(LAO/STO)界面,2021年在KTaO_(3)(KTO)界面也发现...钙钛矿氧化物异质界面中二维电子气(two-dimensional electron gas,2DEG)与界面超导性的发现使其成为研究热点之一.近年来,氧化物界面研究取得突破性进展,除了传统的LaAlO_(3)/SrTiO_(3)(LAO/STO)界面,2021年在KTaO_(3)(KTO)界面也发现超导性,其超导转变温度(Tc)较LAO/STO高出一个数量级,约为2 K,引起广泛关注.与STO界面体系相比,KTO氧化物界面显现出高载流子迁移率、强自旋轨道耦合(spin-orbit coupling,SOC)等特点,为理解非常规超导机制和构建新物理特性的研究提供了新途径,使KTO异质界面成为未来电子和自旋电子应用的有力候选者.本文旨在总结近5年KTO界面的最新进展,概述多种氧化物与KTO界面超导的新奇物理现象,并讨论目前研究中尚未解决的问题,为未来研究提供参考.展开更多
The microemulsion method for preparing ZnO nanocrystallites was reported.Through measuring ZnO microcrystllite ESR spectra, we found that at room temperature it has a significant ESR signal and its intensity descends ...The microemulsion method for preparing ZnO nanocrystallites was reported.Through measuring ZnO microcrystllite ESR spectra, we found that at room temperature it has a significant ESR signal and its intensity descends with the increase of annealed temperature. This result is in contrast with that of bulk ZnO which is a diamagnetic material and no ESR signal. Finally it was found and verified that on the surfaces of ZnO nanocrystallites there are a lot of oxygen vacancies and defects which trap electrons and form paramagnetic centers to provide the observed ESR signal.展开更多
Synthesis of a novel α phosphorus containing spin trap, DEPPEPO[5 (diethoxyphosphoryl) 5 phenylethyl 1 pyrroline] N oxide and evaluation of its ability to spin trap the hydroxyl and the superoxide anion radicals were...Synthesis of a novel α phosphorus containing spin trap, DEPPEPO[5 (diethoxyphosphoryl) 5 phenylethyl 1 pyrroline] N oxide and evaluation of its ability to spin trap the hydroxyl and the superoxide anion radicals were described in the present article. The ability for trapping an active superoxide anion radicals generated in the HX/XO system and the stability of their spin adduct of DEPPEPO were analyzed. In addition, the effects of 5 phenylethyl and 5 phenyl substituted analogues of DMPO on the stereochemistry of the corresponding spin adducts were systematically illustrated.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant No.12274440)the National Key R&D Program of China(Grant No.2022YFA1403903)+1 种基金the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(Grant No.XDB33010100)the Fund of the Synergetic Extreme Condition User Facility(SECUF)。
文摘The interaction between charge and spin degrees of freedom has always been the central issue of condensed matter physics,and transition metal dichalcogenides(TMDs)provide an ideal platform to study it benefiting from their highly tunable properties.In this article,the influence of Fe intercalation in NbSe_(2)was elaborately investigated using a combination of techniques.Magnetic studies have shown that the insertion of Fe atoms induces an antiferromagnetic state in which the easy axis aligns out of the plane.The sign reversal of the magnetoresistance across the Neel temperature can be satisfactorily explained by the moderate interaction between electrons and local spins.The Hall and Seebeck measurements reveal a multi-band nature,and the contribution of various phonon scattering processes is discussed based on the thermal conductivity and specific heat data.
文摘钙钛矿氧化物异质界面中二维电子气(two-dimensional electron gas,2DEG)与界面超导性的发现使其成为研究热点之一.近年来,氧化物界面研究取得突破性进展,除了传统的LaAlO_(3)/SrTiO_(3)(LAO/STO)界面,2021年在KTaO_(3)(KTO)界面也发现超导性,其超导转变温度(Tc)较LAO/STO高出一个数量级,约为2 K,引起广泛关注.与STO界面体系相比,KTO氧化物界面显现出高载流子迁移率、强自旋轨道耦合(spin-orbit coupling,SOC)等特点,为理解非常规超导机制和构建新物理特性的研究提供了新途径,使KTO异质界面成为未来电子和自旋电子应用的有力候选者.本文旨在总结近5年KTO界面的最新进展,概述多种氧化物与KTO界面超导的新奇物理现象,并讨论目前研究中尚未解决的问题,为未来研究提供参考.
文摘The microemulsion method for preparing ZnO nanocrystallites was reported.Through measuring ZnO microcrystllite ESR spectra, we found that at room temperature it has a significant ESR signal and its intensity descends with the increase of annealed temperature. This result is in contrast with that of bulk ZnO which is a diamagnetic material and no ESR signal. Finally it was found and verified that on the surfaces of ZnO nanocrystallites there are a lot of oxygen vacancies and defects which trap electrons and form paramagnetic centers to provide the observed ESR signal.
文摘Synthesis of a novel α phosphorus containing spin trap, DEPPEPO[5 (diethoxyphosphoryl) 5 phenylethyl 1 pyrroline] N oxide and evaluation of its ability to spin trap the hydroxyl and the superoxide anion radicals were described in the present article. The ability for trapping an active superoxide anion radicals generated in the HX/XO system and the stability of their spin adduct of DEPPEPO were analyzed. In addition, the effects of 5 phenylethyl and 5 phenyl substituted analogues of DMPO on the stereochemistry of the corresponding spin adducts were systematically illustrated.
