Cross-band camouflage technology is a critical necessity,enabling personnel and equipment to evade detection across evolving surveillance systems,thereby enhancing survivability and mission success.Herein,this work de...Cross-band camouflage technology is a critical necessity,enabling personnel and equipment to evade detection across evolving surveillance systems,thereby enhancing survivability and mission success.Herein,this work develops a layer-structured composite system based on carbon nanotube(CNT)film comprising ionic liquid(IL)interlayer for infrared(IR)modulation and surface-engineered Cu_(2)O nanoparticles for visible camouflage.The CNT/IL/CNT architecture enables reversible IR emissivity switching(Δε≈0.55)through electrically driven ion intercalation/deintercalation within 2 s,while spray-coated Cu_(2)O nanoparticles(100~400 nm diameter)on the top CNT film layer generate rich structure colors with 90%IR transmittance.This spectral-decoupling design overcomes the traditional trade-off between color visibility and IR transmittance observed in pigment-based systems.Remarkably,due to physical interface coupling,the Cu_(2)O-coated layer-structured system maintains exceptional electrical conductivity,enabling simultaneous electromagnetic interference shielding and electrothermal energy conversion.The integrated system demonstrates long-term operational stability.By unifying visible-IR camouflage,electromagnetic protection,and energy management in a lightweight platform,this work provides an important paradigm for cross-band camouflage technologies.展开更多
The seismic data of the Laoshan Uplift in the South Yellow Sea Basin reveal a low signal-tonoise ratio and low refl ection signal energy in the deep Mesozoic–Paleozoic strata.The main reason is that the Mesozoic-Pale...The seismic data of the Laoshan Uplift in the South Yellow Sea Basin reveal a low signal-tonoise ratio and low refl ection signal energy in the deep Mesozoic–Paleozoic strata.The main reason is that the Mesozoic-Paleozoic marine carbonate rock strata are directly covered by the Cenozoic terrestrial clastic rock strata,which form a strong shielding layer.To obtain the reflection signals of the strata below the strong shielding layer,a one-way wave equation bidirectional illumination analysis of the main observation system parameters was conducted by analyzing the mechanism of the strong shielding layer.Low-frequency seismic sources are assumed to have a high illumination intensity on the reflection layer below the strong shielding layer.Accordingly,optimized acquisition parameter suggestions were proposed,and reacquisition was performed at the existing survey line locations in the Laoshan Uplift area.The imaging of the newly acquired data in the middle and deep layers was drastically improved.It revealed the unconformity between the Sinian and Cambrian under the strong shielding layer.The study yielded new insights into the tectonic and sedimentary evolution of the Lower Paleozoic in the South Yellow Sea.展开更多
The uplift resistance of the soil overlying shield tunnels significantly impacts their anti-floating stability.However,research on uplift resistance concerning special-shaped shield tunnels is limited.This study combi...The uplift resistance of the soil overlying shield tunnels significantly impacts their anti-floating stability.However,research on uplift resistance concerning special-shaped shield tunnels is limited.This study combines numerical simulation with machine learning techniques to explore this issue.It presents a summary of special-shaped tunnel geometries and introduces a shape coefficient.Through the finite element software,Plaxis3D,the study simulates six key parameters—shape coefficient,burial depth ratio,tunnel’s longest horizontal length,internal friction angle,cohesion,and soil submerged bulk density—that impact uplift resistance across different conditions.Employing XGBoost and ANN methods,the feature importance of each parameter was analyzed based on the numerical simulation results.The findings demonstrate that a tunnel shape more closely resembling a circle leads to reduced uplift resistance in the overlying soil,whereas other parameters exhibit the contrary effects.Furthermore,the study reveals a diminishing trend in the feature importance of buried depth ratio,internal friction angle,tunnel longest horizontal length,cohesion,soil submerged bulk density,and shape coefficient in influencing uplift resistance.展开更多
The investigation of absorption-led shielding mechanisms has now made practical progress as a result of the concept of green EM shielding.The extant studies primarily concentrate on the introduction of mag-netic parti...The investigation of absorption-led shielding mechanisms has now made practical progress as a result of the concept of green EM shielding.The extant studies primarily concentrate on the introduction of mag-netic particles into the system,with the objective of enhancing the absorption rate(A)through dielectric-magnetic modulation for absorption-led electromagnetic shielding.In contrast,this paper presents a novel approach whereby PVA,glycerol,and MXene are combined into an organohydrogel(PMG)with oriented pores.This results in the creation of a non-magnetic medium that exhibits high absorption loss in mul-tiple bands,thereby establishing a novel shielding system.The PMG20-3 organohydrogel(0.78 wt%MX-ene)has a shielding performance in the X-band of 42.34 dB(A/R=1).In the terahertz band,the organic hydrogel gel exhibits an absorption rate of 99.9%,a performance that exceeds that of the majority of previously reported systems.The PMG gel displays remarkable flexibility and strength,with a hysteresis return line that remains stable under 1000 compression cycles.Additionally,it offers versatile sensing capabilities and infrared stealth.The findings of this study offer novel insights that may facilitate the accelerated utilization of innovative multifunctional and environmentally conscious electromagnetic in-terference(EMI)shielding materials.展开更多
The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D i...The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D interconnected pore structure was prepared through the high pressure pyrolysis of mesophase coal tar pitch.It is found that the 3D interconnected cellular pores of MPCF facilitate multiple reflections of electromagnetic waves,which results in the minimum reflection loss(RLmin)value of MPCF reaches-37.84 dB with the effective absorption bandwidth(EAB)of 5.44 GHz at a thickness of 2.70 mm,and the total average electromagnetic shielding effectiveness(SE_(T))under 3.00 mm thickness achieves 26.52 dB in X-band.Subsequently,MPCF is activated by KOH to obtain activated carbon foam(A-MPCF).The average SE_(T)of A-MPCF achieves 103.00 dB for abundant nanopores on the pore cell walls,which leads to a transition from the multiple reflections of electromagnetic waves on the walls to diffuse reflection.Unfortunately,the reflection coefficient(R)of A-MPCF increases from 0.78 to 0.90.To reduce the R value,Fe_(3)O_(4)/A-MPCF was fabricated via the in situ growth of nano Fe_(3)O_(4)on A-MPCF.Consequently,the R value of Fe_(3)O_(4)/A-MPCF was reduced from 0.90 to 0.74,whereas the MWA performance was only slightly decreased.This work proposes a simple strategy for simultaneously adjusting MWA and EMI shielding performances of materials.展开更多
The advancement of next-generation high-frequency communication systems and stealth detection technologies necessitate the development of efficient,multi-spectrum compatible shielding materials.However,the achievement...The advancement of next-generation high-frequency communication systems and stealth detection technologies necessitate the development of efficient,multi-spectrum compatible shielding materials.However,the achievement of simultaneous high efficiency and low reflectivity across microwave,terahertz,and infrared spectra remains a formidable challenge.Herein,a carbonized MXene/polyimide(C-MXene/PI)aerogel material integrating a spatially coupled hierarchically anisotropic structure with stepwise conductivity gradients was constructed.Electromagnetic waves propagate through the top-down vertical disordered horizontal architecture and progressive conductivity gradient of C-MXene/PI aerogel,undergoing stepwise absorption-dissipation-re-dissipation processes.The C-MXene/PI aerogel exhibits an average electromagnetic interference(EMI)shielding effectiveness of91.0 dB in X-band and a reflection coefficient of 0.40.In the terahertz frequency band,the average EMI shielding performance reaches66.2 dB with a reflection coefficient of 0.33.Furthermore,the heterolayered porous architecture of C-MXene/PI aerogels exhibits low thermal conductivity and reduced infrared emissivity,enabling exceptional infrared stealth capability across the 2-16μm wavelength spectrum.This study provides an feasible strategy for constructing low-reflectivity multi-spectrum compatible shielding materials.展开更多
In this study,an architecture featuring a gradient conductive network structure and three-dimensional dual-continuous network structure is constructed in a carbon nanotubes/cellulose-boron nitride/poly(vinyl alcohol)(...In this study,an architecture featuring a gradient conductive network structure and three-dimensional dual-continuous network structure is constructed in a carbon nanotubes/cellulose-boron nitride/poly(vinyl alcohol)(CNT/cellulose-BN/PVA)composite.Using cellulose aerogel as a template,CNT were incorporated into the cellulose template by vertically impregnating the CNT suspension.Following the impregnation of BN/PVA and high-pressure compression,three-dimensional dual-continuous network structure was successfully constructed in the CNT/cellulose-BN/PVA composite.The comprehensive performance of the composite,including electromagnetic interference(EMI)shielding and Joule heating performance,was investigated.The results indicate that the total EMI shielding effectiveness(SE)for the CNT/cellulose-BN/PVA composite reveals similar values for electromagnetic waves incident from different directions,but totally different shielding mechanisms.For the CNT/cellulose-BN/PVA composite with three impregnation cycles of CNT,the EMI SE values exceeded 39 dB for electromagnetic waves incident from both the high-and low-CNT-content sides.93%of the microwaves were reflected when electromagnetic waves were incident from the high-CNT-content side,while the reflection coefficient decreased to 0.44 for the transverse direction.In addition,the construction of the dual-continuous network structure enabled the composite to exhibit both excellent electrical conductivity and good thermal conductivity simultaneously,endowing the material with good Joule heating performance.CNT/cellulose-BN/PVA composite films have significant potential for application as EMI shielding materials in extremely cold weather.展开更多
Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the...Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.展开更多
With the rapid development of intelligent electronic and military equipment,multifunctional flexible materials that integrat electromagnetic interference(EMI)shielding,temperature sensing,and information encryption ar...With the rapid development of intelligent electronic and military equipment,multifunctional flexible materials that integrat electromagnetic interference(EMI)shielding,temperature sensing,and information encryption are urgently required.This study presents a bio-inspired hierarchical composite foam fabricated using supercritical nitrogen foaming technology.This material exhibits a honeycomb structure,with pore cell sizes controllable within a range of 30–92μm by regulating the filler.The carbon fiber felt(CFf)provides efficient reflection of electromagnetic waves,while the chloroprene rubber/carbon fiber/carbon black foam facilitates both wave absorption and temperature monitoring through its optimized conductive network.This synergistic mechanism results in an EMI shielding effectiveness(SE)of 60.06 d B with excellent temperature sensing performance(The temperature coefficient of resistance(TCR)is-2.642%/℃)in the 24–70℃ range.Notably,the material has a thermal conductivity of up to 0.159 W/(m·K),and the bio-inspired layered design enables information encryption,demonstrating the material's potential for secure communication applications.The foam also has tensile properties of up to 5.13 MPa and a tear strength of 33.02 N/mm.This biomimetic design overcomes the traditional limitations of flexible materials and provides a transformative solution for next-generation applications such as flexible electronics,aerospace systems and military equipment,which urgently need integrated electromagnetic protection,thermal management and information security.展开更多
To shield electronics from complicated electromagnetic environments caused by wireless electromagnetic waves,achieving elaborately structural manufacturing while not sacrificing electromagnetic interference shielding ...To shield electronics from complicated electromagnetic environments caused by wireless electromagnetic waves,achieving elaborately structural manufacturing while not sacrificing electromagnetic interference shielding performances remains crucial challenges.Herein,we propose a hierarchical manufacturing method that combines the use of 3D printing shear flow field and layer-by-layer assembly for fabricating the structurally customizable and multifunctional polylactic acid@graphene nanoparticle(PLA@GNs)materials.The dynamic behavior of polymer fluids is firstly explored via computational fluid dynamic simulation,and a Weissenberg number is employed to quantitatively analyze the disordered-to-ordered structural evolution of molecular chains and nanoparticles,allowing to tailor the micro-scale ordered structures.Subsequently,the macro-scale 3D architectures of PLA@GNs modules are fabricated by layer-by-layer assembly.Owing to the aligned GNs,the shielding performance reaches 41.2 d B,simultaneously accompanied by a directional thermal conductivity of 3.2 W m^(-1)K^(-1).Moreover,the potential application of 3D-printed shielding modules in specific civilian frequency bands such as 4G(1800–2100 MHz),Bluetooth(2402–2480 MHz),and 5G(3300–3800 MHz)is fully demonstrated.Overall,this work not only establishes a universal methodology about 3D printing shear flow field-driven orientation of two-dimensional nanoparticles within polymer fluids,but also gives a scientific method for advanced manufacturing of the next-generation electromagnetic functional modules for smart electronics.展开更多
In a rapid cycling synchrotron(RCS),the magnetic field is synchronized with the beam energy,creating a highly dynamic magnetic environment.A ceramic chamber with a shielding layer(RF shield),composed of a series of co...In a rapid cycling synchrotron(RCS),the magnetic field is synchronized with the beam energy,creating a highly dynamic magnetic environment.A ceramic chamber with a shielding layer(RF shield),composed of a series of copper strips connected to a capacitor at either end,is typically employed as a vacuum chamber to mitigate eddy current effects and beam coupling impedance.Consequently,the ceramic chamber exhibits a thin-walled multilayered complex structure.Previous theoretical studies have suggested that the impedance of such a structure has a negligible impact on the beam.However,recent impedance measurements of the ceramic chamber in the China Spallation Neutron Source(CSNS)RCS revealed a resonance in the low-frequency range,which was confirmed by further theoretical analysis as a source of beam instability in the RCS.Currently,the magnitude of this impedance cannot be accurately assessed using theoretical calculations.In this study,we used the CST Microwave Studio to confirm the impedance of the ceramic chamber.Further simulations covering six different types of ceramic chambers were conducted to develop an impedance model in the RCS.Additionally,this study investigates the resonant characteristics of the ceramic chamber impedance,finding that the resonant frequency is closely related to the capacitance of the capacitors.This finding provides clear directions for further impedance optimization and is crucial for achieving a beam power of 500 kW for the CSNS Phase-Ⅱ project(CSNS-Ⅱ).However,careful attention must be paid to the voltage across the capacitors.展开更多
Developing advanced cathode modification strategies to address the inherent high charge density of Al^(3+) is essential for achieving high-energy-density and long-cycle-life rechargeable aluminum batteries(RABs).Herei...Developing advanced cathode modification strategies to address the inherent high charge density of Al^(3+) is essential for achieving high-energy-density and long-cycle-life rechargeable aluminum batteries(RABs).Herein,we engineer tetraethylammonium(TEA)cation intercalation as a dual-function strategy that concurrently enables interlayer distance enlargement and electrostatic shielding effects,resolving Al^(3+) polarization-induced sluggish kinetics and cathode degradation in RABs.TEA intercalation triggers exceptional V2O5 interlayer expansion from 4.37 to 13.10Å,while the modulated charge distribution generates an electrostatic shielding effect that significantly weakens the Coulombic interactions between Al^(3+) and V2O5 frameworks.This dual mechanism collectively enhances ion diffusion kinetics and suppresses lattice stress accumulation.Ex situ X-ray diffraction and transmission electron microscopy analyses confirm that the“molecular pillar effect”of TEA enables minimal and highly reversible structural deformation of the cathode(<2.0%volume change after 200 cycles),demonstrating zero-strain aluminum-storage behavior.The optimized cathode delivers a high reversible capacity of 258 mAh g^(−1) at 0.5 A g^(−1),maintains 99%capacity retention at 5.0 A g^(−1),and exhibits an ultralow capacity decay rate of 0.01%per cycle over 6000 cycles.This work opens new pathways for designing stable high-performance RAB cathodes through synergistic modulation of electronic and lattice structures.展开更多
Shield tunneling in saturated ground poses challenges due to the potential risk of ground collapse resulting from seepage force and inadequate support pressure.This study employed a laboratory model test and a theoret...Shield tunneling in saturated ground poses challenges due to the potential risk of ground collapse resulting from seepage force and inadequate support pressure.This study employed a laboratory model test and a theoretical validation to elucidate the mechanisms of face failure and subsequent ground collapse in saturated ground during slurry pressure-balanced shield(SPBS)tunneling operations.A slurry circulation system was developed to ensure steady shield tunneling and to replicate the phenomena of ground collapse.Investigations into shield tunneling parameters and ground responses,including soil pressure,pore water pressure,and surface subsidence,were conducted to understand the mechanisms of face failure and subsequent ground collapse.The theoretical solution for the critical collapse pressure of the tunnel face,based on the rotational failure mechanism,was validated through the comparison with the experimentally determined critical collapse pressure.The results indicate that:(1)appropriate adjustments of tunneling parameters are crucial for promoting filtercake formation,maintaining chamber pressure,and minimizing ground subsidence;(2)chamber pressure,soil pressure,pore water pressure,and ground subsidence are closely correlated with shield tunneling parameters and the formation of filter cake;(3)ground collapse follows a continuous failure mode due to the destruction of filtercake and the decrease in chamber pressure;(4)the soil pressure at the cutterhead is more sensitive to disturbances from shield tunneling than chamber pressure;and(5)experimentally determined critical collapse pressures is consistent with the theoretical solution of limit analysis.展开更多
Aqueous zinc-ion batteries(AZIBs)are facing challenges of severe parasitic side reactions and uncontrolled Zn dendrite growth in promoting commercial applications.Here,rare earth metal neodymium ions(Nd^(3+))have been...Aqueous zinc-ion batteries(AZIBs)are facing challenges of severe parasitic side reactions and uncontrolled Zn dendrite growth in promoting commercial applications.Here,rare earth metal neodymium ions(Nd^(3+))have been introduced into the conventional Zn SO_4 electrolyte as an electrolyte additive to improve the stability and reversibility of AZIBs.Combining experimental characterization and theoretical calculations,Nd^(3+)ions are adsorbed at the active sites of zinc crystal growth,forming a positively charged shielding layer on the Zn anode surface that effectively prevents lateral reactions and induces uniform Zn deposition.Meanwhile,Nd^(3+)ions preferentially adsorb on(100)and(101)planes of Zn,thus facilitating preferential deposition on the(002)plane and achieving a dendrite-free Zn anode.Consequently,a Zn//Zn symmetric cell with the Nd^(3+)-modified electrolyte exhibits an ultralong lifespan of 3000 h at0.5 m A cm^(-2),and a Zn//Cu asymmetric cell realizes an impressive Coulombic efficiency of 99.47%for Zn stripping and plating over 550 cycles at 1.0 mA cm^(-2).Impressively,Zn//CNT@MnO_(2) full cell reaches a considerably stable long cycle performance over 2500 cycles at 1.0 A g^(-1).This work offers an effective solution to the challenges faced by Zn anode and expands the application scope of metallic ions in metalbased energy storage devices.展开更多
Although machine learning models have achieved high enough accuracy in predicting shield position deviations,their“black box”nature makes the prediction mechanisms and decision-making processes opaque,leading to wea...Although machine learning models have achieved high enough accuracy in predicting shield position deviations,their“black box”nature makes the prediction mechanisms and decision-making processes opaque,leading to weaker explanations and practicability.This study introduces a novel explainable deep learning framework comprising the Informer model with enhanced attention mechanisms(EAMInfor)and deep learning important features(DeepLIFT),aimed at improving the prediction accuracy of shield position deviations and providing interpretability for predictive results.The EAMInfor model attempts to integrate channel attention,spatial attention,and simple attention modules to improve the Informer model's performance.The framework is tested with the four different geological conditions datasets generated from the Xiamen metro line 3,China.Results show that the EAMInfor model outperforms the traditional Informer and comparison models.The analysis with the DeepLIFT method indicates that the push thrust of push cylinder and the earth chamber pressure are the most significant features,while the stroke length of the push cylinder demonstrated lower importance.Furthermore,the variation trends in the significance of data points within input sequences exhibit substantial differences between single and composite strata.This framework not only improves predictive accuracy but also strengthens the credibility and reliability of the results.展开更多
Estimating the properties of foam-conditioned clay soils is important for both conditioning and recycling goals in earth pressure balance(EPB)shield tunneling.In this study,the vacuum dewatering behaviors of foam-cond...Estimating the properties of foam-conditioned clay soils is important for both conditioning and recycling goals in earth pressure balance(EPB)shield tunneling.In this study,the vacuum dewatering behaviors of foam-conditioned clay soils were investigated,with their potential use as an alternative means to assess foam optimization being examined.A series of laboratory and fieldtests was conducted,including vacuum dewatering tests that considered the effects of filtrationtime and pressure,vane shear tests,and improved cone pullout tests under different gravimetric water content(w)and foam injection ratio(FIR)conditions.It was found that the filtrate loss(FL),which characterizes dewaterability,was increased by extended vacuum filtrationtime and elevated pressure.While increases in w and FIR enhanced FL,reductions were observed in the undrained shear strength(cu),tangential adhesion stress(Fs),and normal adhesion stress(Fn).Furthermore,a linear decrease in FL with increasing mechanical indices(cu,Fs,and Fn)was demonstrated by both laboratory and fielddata fittingresults,regardless of w,FIR,and dewatering conditions.This study provides novel insights into the understanding of vacuum dewatering mechanisms in foam-conditioned clay soils,while a simple approach is proposed for evaluating foam conditioning effectiveness in EPB shield tunneling applications.展开更多
Bio-based 2,5-furandicarboxylic acid polyesters offer significant promise for reducing energy and environmental crises.However,their intrinsic flammability remains a critical limitation,and conventional flame-retardan...Bio-based 2,5-furandicarboxylic acid polyesters offer significant promise for reducing energy and environmental crises.However,their intrinsic flammability remains a critical limitation,and conventional flame-retardant strategies often compromise their mechanical properties,hindering their practical applications.Herein,a 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide(DOPO)-based comonomer(DDP)was used to synthesize flame-retardant poly(ethylene furandicarboxylate-co-phosphaphenanthrene)(PEFDn).The covalent integration of DDP confers intrinsic flame retardancy,avoiding the plasticization and migration issues associated with additive-type systems.Upon thermal decomposition,the DOPO-derived moieties release phosphoric acid and radical scavengers,promoting char formation and suppressing flame propagation.Furthermore,density functional theory(DFT)calculations combined with non-covalent interaction(NCI)analysis revealed that DOPO dimer molecules adopt a stable parallel-displaced π-π stacking configu ration,potentially facilitating microphase separation and enhancing the energy dissipation capability.PEFD_(10)achieves a UL-94 V-0 rating while simultaneously increasing impact toughness from 1.5 kJ/m^(2) to 14.7 kJ/m^(2).Im portantly,PEFDn maintained acceptable oxygen-barrier properties.PEFD10 also exhibited high transparency and UV-shielding performance.The combination of intrinsic flame safety,im pact-toughness resistance,UV shielding,and an oxygen barrier ensures reliable protection of electrical components and long-term operational stability.The integration of multiple critical properties within a single bio-based material represents a novel approach fo r enabling sustainable polymer solutions for high-pe rformance electrical applications.展开更多
The thrust hydraulic system of the prototype shield machine with pressure and flow compound control scheme was introduced. The experimental system integrated with proportional valves for study was designed. Dynamics m...The thrust hydraulic system of the prototype shield machine with pressure and flow compound control scheme was introduced. The experimental system integrated with proportional valves for study was designed. Dynamics modeling of multi-cylinder thrust system and synchronous control design were accomplished. The simulation of the synchronization motion control system was completed in AMESim and Matlab/Simulink software environments. The experiment was conducted by means of master/slave PID with dead band compensating flow and conventional PID regulating pressure. The experimental results show that the proposed thrust hydraulic system and its control strategy can meet the requirements of tunneling in motion and posture control for the shield machine, keeping the non-synchronous error within ±3 mm.展开更多
An estimation approach using least squares method was presented for identificationof model parameters of pressure control in shield tunneling.The state equation ofthe pressure control system for shield tunneling was a...An estimation approach using least squares method was presented for identificationof model parameters of pressure control in shield tunneling.The state equation ofthe pressure control system for shield tunneling was analytically derived based on themass equilibrium principle that the entry mass of the pressure chamber from cutting headwas equal to excluding mass from the screw conveyor.The randomly observed noise wasnumerically simulated and mixed to simulated observation values of system responses.The numerical simulation shows that the state equation of the pressure control system forshield tunneling is reasonable and the proposed estimation approach is effective even ifthe random observation noise exists.The robustness of the controlling procedure is validatedby numerical simulation results.展开更多
The development of the preparation strategy for high-quality and large-size graphene via eco-friendly routes is still a challenging issue.Herein,we have successfully developed a novel route to chemically exfoliate nat...The development of the preparation strategy for high-quality and large-size graphene via eco-friendly routes is still a challenging issue.Herein,we have successfully developed a novel route to chemically exfoliate natural graphite into high-quality and large-size graphene in a binary-peroxidant system.This system is composed of urea peroxide(CO(NH_(2))_(2)·H_(2)O_(2))and hydrogen peroxide(H_(2)O_(2)),where CO(NH_(2))_(2)·H_(2)O_(2)is used in preparing graphene for the first time.Benefiting from the complete decomposition of CO(NH_(2))_(2)·H_(2)O_(2)and H_(2)O_(2)into gaseous species under microwave(MW)irradiation,no water-washing and effluent-treatment are needed in this chemical exfoliation procedure,thus the preparation of graphene in an eco-friendly way is realized.The resultant graphene behaves a large-size,high-quality and few-layer feature with a yield of~100%.Then 4µm-thick ultrathin graphene paper fabricated from the as-exfoliated graphene is used as an electromagnetic interference(EMI)shielding material.And its absolute effectiveness of EMI shielding(SSE/t)is up to 34,176.9 dB cm^(2)/g,which is,to the best of our knowledge,among the highest values so far reported for typical EMI shielding materials.The EMI shielding performance demonstrates a great application potential of graphene paper in meeting the ever-increasingly EMI shielding demands in miniaturized electronic devices.展开更多
基金Financial support from the National Nature Science Foundation of China(No.:52373244)the Foundation of National Science and Technology Key Laboratory(No.:KZ571801)。
文摘Cross-band camouflage technology is a critical necessity,enabling personnel and equipment to evade detection across evolving surveillance systems,thereby enhancing survivability and mission success.Herein,this work develops a layer-structured composite system based on carbon nanotube(CNT)film comprising ionic liquid(IL)interlayer for infrared(IR)modulation and surface-engineered Cu_(2)O nanoparticles for visible camouflage.The CNT/IL/CNT architecture enables reversible IR emissivity switching(Δε≈0.55)through electrically driven ion intercalation/deintercalation within 2 s,while spray-coated Cu_(2)O nanoparticles(100~400 nm diameter)on the top CNT film layer generate rich structure colors with 90%IR transmittance.This spectral-decoupling design overcomes the traditional trade-off between color visibility and IR transmittance observed in pigment-based systems.Remarkably,due to physical interface coupling,the Cu_(2)O-coated layer-structured system maintains exceptional electrical conductivity,enabling simultaneous electromagnetic interference shielding and electrothermal energy conversion.The integrated system demonstrates long-term operational stability.By unifying visible-IR camouflage,electromagnetic protection,and energy management in a lightweight platform,this work provides an important paradigm for cross-band camouflage technologies.
基金“High precision prestack reverse time depth migration imaging of long array seismic data in the East China Sea Shelf Basin”of the National Natural Science Foundation of China(No.42106207)“Seismic acquisition technology for deep strata under strong shielding layers in the sea and rugged seabed”of Laoshan Laboratory Science and Technology Innovation Project(No.LSKJ202203404)“Research on the compensation methods of the middledeep weak seismic reflections in the South Yellow Sea based on multi-resolution HHT time-frequency analysis”of the National Natural Science Foundation of China(No.42106208).
文摘The seismic data of the Laoshan Uplift in the South Yellow Sea Basin reveal a low signal-tonoise ratio and low refl ection signal energy in the deep Mesozoic–Paleozoic strata.The main reason is that the Mesozoic-Paleozoic marine carbonate rock strata are directly covered by the Cenozoic terrestrial clastic rock strata,which form a strong shielding layer.To obtain the reflection signals of the strata below the strong shielding layer,a one-way wave equation bidirectional illumination analysis of the main observation system parameters was conducted by analyzing the mechanism of the strong shielding layer.Low-frequency seismic sources are assumed to have a high illumination intensity on the reflection layer below the strong shielding layer.Accordingly,optimized acquisition parameter suggestions were proposed,and reacquisition was performed at the existing survey line locations in the Laoshan Uplift area.The imaging of the newly acquired data in the middle and deep layers was drastically improved.It revealed the unconformity between the Sinian and Cambrian under the strong shielding layer.The study yielded new insights into the tectonic and sedimentary evolution of the Lower Paleozoic in the South Yellow Sea.
基金Guangzhou Metro Scientific Research Project(No.JT204-100111-23001)Chongqing Municipal Special Project for Technological Innovation and Application Development(No.CSTB2022TIAD-KPX0101)Science and Technology Research and Development Program of China State Railway Group Co.,Ltd.(No.N2023G045)。
文摘The uplift resistance of the soil overlying shield tunnels significantly impacts their anti-floating stability.However,research on uplift resistance concerning special-shaped shield tunnels is limited.This study combines numerical simulation with machine learning techniques to explore this issue.It presents a summary of special-shaped tunnel geometries and introduces a shape coefficient.Through the finite element software,Plaxis3D,the study simulates six key parameters—shape coefficient,burial depth ratio,tunnel’s longest horizontal length,internal friction angle,cohesion,and soil submerged bulk density—that impact uplift resistance across different conditions.Employing XGBoost and ANN methods,the feature importance of each parameter was analyzed based on the numerical simulation results.The findings demonstrate that a tunnel shape more closely resembling a circle leads to reduced uplift resistance in the overlying soil,whereas other parameters exhibit the contrary effects.Furthermore,the study reveals a diminishing trend in the feature importance of buried depth ratio,internal friction angle,tunnel longest horizontal length,cohesion,soil submerged bulk density,and shape coefficient in influencing uplift resistance.
基金the National Natural Science Foundation of China(Nos.52373073,52073091,52303083,22171086)the Shanghai Pujiang Program(No.22PJ1402500)the Fundamental Research Funds for the Central Universities(No.JKD01231701).
文摘The investigation of absorption-led shielding mechanisms has now made practical progress as a result of the concept of green EM shielding.The extant studies primarily concentrate on the introduction of mag-netic particles into the system,with the objective of enhancing the absorption rate(A)through dielectric-magnetic modulation for absorption-led electromagnetic shielding.In contrast,this paper presents a novel approach whereby PVA,glycerol,and MXene are combined into an organohydrogel(PMG)with oriented pores.This results in the creation of a non-magnetic medium that exhibits high absorption loss in mul-tiple bands,thereby establishing a novel shielding system.The PMG20-3 organohydrogel(0.78 wt%MX-ene)has a shielding performance in the X-band of 42.34 dB(A/R=1).In the terahertz band,the organic hydrogel gel exhibits an absorption rate of 99.9%,a performance that exceeds that of the majority of previously reported systems.The PMG gel displays remarkable flexibility and strength,with a hysteresis return line that remains stable under 1000 compression cycles.Additionally,it offers versatile sensing capabilities and infrared stealth.The findings of this study offer novel insights that may facilitate the accelerated utilization of innovative multifunctional and environmentally conscious electromagnetic in-terference(EMI)shielding materials.
基金Supported by the National Natural Science Foundation of China(22378181).
文摘The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D interconnected pore structure was prepared through the high pressure pyrolysis of mesophase coal tar pitch.It is found that the 3D interconnected cellular pores of MPCF facilitate multiple reflections of electromagnetic waves,which results in the minimum reflection loss(RLmin)value of MPCF reaches-37.84 dB with the effective absorption bandwidth(EAB)of 5.44 GHz at a thickness of 2.70 mm,and the total average electromagnetic shielding effectiveness(SE_(T))under 3.00 mm thickness achieves 26.52 dB in X-band.Subsequently,MPCF is activated by KOH to obtain activated carbon foam(A-MPCF).The average SE_(T)of A-MPCF achieves 103.00 dB for abundant nanopores on the pore cell walls,which leads to a transition from the multiple reflections of electromagnetic waves on the walls to diffuse reflection.Unfortunately,the reflection coefficient(R)of A-MPCF increases from 0.78 to 0.90.To reduce the R value,Fe_(3)O_(4)/A-MPCF was fabricated via the in situ growth of nano Fe_(3)O_(4)on A-MPCF.Consequently,the R value of Fe_(3)O_(4)/A-MPCF was reduced from 0.90 to 0.74,whereas the MWA performance was only slightly decreased.This work proposes a simple strategy for simultaneously adjusting MWA and EMI shielding performances of materials.
基金supported by the Fundamental Research Funds for the Central Universities under No.2024KQ130the National Natural Science Foundation of China(No.52373259)。
文摘The advancement of next-generation high-frequency communication systems and stealth detection technologies necessitate the development of efficient,multi-spectrum compatible shielding materials.However,the achievement of simultaneous high efficiency and low reflectivity across microwave,terahertz,and infrared spectra remains a formidable challenge.Herein,a carbonized MXene/polyimide(C-MXene/PI)aerogel material integrating a spatially coupled hierarchically anisotropic structure with stepwise conductivity gradients was constructed.Electromagnetic waves propagate through the top-down vertical disordered horizontal architecture and progressive conductivity gradient of C-MXene/PI aerogel,undergoing stepwise absorption-dissipation-re-dissipation processes.The C-MXene/PI aerogel exhibits an average electromagnetic interference(EMI)shielding effectiveness of91.0 dB in X-band and a reflection coefficient of 0.40.In the terahertz frequency band,the average EMI shielding performance reaches66.2 dB with a reflection coefficient of 0.33.Furthermore,the heterolayered porous architecture of C-MXene/PI aerogels exhibits low thermal conductivity and reduced infrared emissivity,enabling exceptional infrared stealth capability across the 2-16μm wavelength spectrum.This study provides an feasible strategy for constructing low-reflectivity multi-spectrum compatible shielding materials.
基金financially supported by the National Natural Science Foundation of China(No.52103127)the Opening Project of the State Key Laboratory of Polymer Materials Engineering(Sichuan University)(No.sklpme2022-4-10)Shaanxi Provincial Science and Technology Department(No.2025GH-YBXM-042).
文摘In this study,an architecture featuring a gradient conductive network structure and three-dimensional dual-continuous network structure is constructed in a carbon nanotubes/cellulose-boron nitride/poly(vinyl alcohol)(CNT/cellulose-BN/PVA)composite.Using cellulose aerogel as a template,CNT were incorporated into the cellulose template by vertically impregnating the CNT suspension.Following the impregnation of BN/PVA and high-pressure compression,three-dimensional dual-continuous network structure was successfully constructed in the CNT/cellulose-BN/PVA composite.The comprehensive performance of the composite,including electromagnetic interference(EMI)shielding and Joule heating performance,was investigated.The results indicate that the total EMI shielding effectiveness(SE)for the CNT/cellulose-BN/PVA composite reveals similar values for electromagnetic waves incident from different directions,but totally different shielding mechanisms.For the CNT/cellulose-BN/PVA composite with three impregnation cycles of CNT,the EMI SE values exceeded 39 dB for electromagnetic waves incident from both the high-and low-CNT-content sides.93%of the microwaves were reflected when electromagnetic waves were incident from the high-CNT-content side,while the reflection coefficient decreased to 0.44 for the transverse direction.In addition,the construction of the dual-continuous network structure enabled the composite to exhibit both excellent electrical conductivity and good thermal conductivity simultaneously,endowing the material with good Joule heating performance.CNT/cellulose-BN/PVA composite films have significant potential for application as EMI shielding materials in extremely cold weather.
基金support provided by the Center for Fabrication and Application of Electronic Materials at Dokuz Eylül University,Türkiye。
文摘Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.
基金financially supported by the Natural Science Foundation of Shandong Province(No.ZR2024QE446)。
文摘With the rapid development of intelligent electronic and military equipment,multifunctional flexible materials that integrat electromagnetic interference(EMI)shielding,temperature sensing,and information encryption are urgently required.This study presents a bio-inspired hierarchical composite foam fabricated using supercritical nitrogen foaming technology.This material exhibits a honeycomb structure,with pore cell sizes controllable within a range of 30–92μm by regulating the filler.The carbon fiber felt(CFf)provides efficient reflection of electromagnetic waves,while the chloroprene rubber/carbon fiber/carbon black foam facilitates both wave absorption and temperature monitoring through its optimized conductive network.This synergistic mechanism results in an EMI shielding effectiveness(SE)of 60.06 d B with excellent temperature sensing performance(The temperature coefficient of resistance(TCR)is-2.642%/℃)in the 24–70℃ range.Notably,the material has a thermal conductivity of up to 0.159 W/(m·K),and the bio-inspired layered design enables information encryption,demonstrating the material's potential for secure communication applications.The foam also has tensile properties of up to 5.13 MPa and a tear strength of 33.02 N/mm.This biomimetic design overcomes the traditional limitations of flexible materials and provides a transformative solution for next-generation applications such as flexible electronics,aerospace systems and military equipment,which urgently need integrated electromagnetic protection,thermal management and information security.
基金financially supported by the National Natural Science Foundation of China(52303036)the Natural Science Foundation of Guangxi(2024GXNSFBA010123)+2 种基金the International Science&Technology Innovation Cooperation Project of Sichuan Province(2024YFHZ0232)the International Science&Technology Cooperation Project of Chengdu(2021-GH03-00009-HZ)the Opening Project of State Key Laboratory of Polymer Materials Engineering(Sichuan University)(Sklpme2023-3-18)。
文摘To shield electronics from complicated electromagnetic environments caused by wireless electromagnetic waves,achieving elaborately structural manufacturing while not sacrificing electromagnetic interference shielding performances remains crucial challenges.Herein,we propose a hierarchical manufacturing method that combines the use of 3D printing shear flow field and layer-by-layer assembly for fabricating the structurally customizable and multifunctional polylactic acid@graphene nanoparticle(PLA@GNs)materials.The dynamic behavior of polymer fluids is firstly explored via computational fluid dynamic simulation,and a Weissenberg number is employed to quantitatively analyze the disordered-to-ordered structural evolution of molecular chains and nanoparticles,allowing to tailor the micro-scale ordered structures.Subsequently,the macro-scale 3D architectures of PLA@GNs modules are fabricated by layer-by-layer assembly.Owing to the aligned GNs,the shielding performance reaches 41.2 d B,simultaneously accompanied by a directional thermal conductivity of 3.2 W m^(-1)K^(-1).Moreover,the potential application of 3D-printed shielding modules in specific civilian frequency bands such as 4G(1800–2100 MHz),Bluetooth(2402–2480 MHz),and 5G(3300–3800 MHz)is fully demonstrated.Overall,this work not only establishes a universal methodology about 3D printing shear flow field-driven orientation of two-dimensional nanoparticles within polymer fluids,but also gives a scientific method for advanced manufacturing of the next-generation electromagnetic functional modules for smart electronics.
基金supported by the Guangdong Basic and Applied Basic Research Foundation,China(No.2021B1515140007).
文摘In a rapid cycling synchrotron(RCS),the magnetic field is synchronized with the beam energy,creating a highly dynamic magnetic environment.A ceramic chamber with a shielding layer(RF shield),composed of a series of copper strips connected to a capacitor at either end,is typically employed as a vacuum chamber to mitigate eddy current effects and beam coupling impedance.Consequently,the ceramic chamber exhibits a thin-walled multilayered complex structure.Previous theoretical studies have suggested that the impedance of such a structure has a negligible impact on the beam.However,recent impedance measurements of the ceramic chamber in the China Spallation Neutron Source(CSNS)RCS revealed a resonance in the low-frequency range,which was confirmed by further theoretical analysis as a source of beam instability in the RCS.Currently,the magnitude of this impedance cannot be accurately assessed using theoretical calculations.In this study,we used the CST Microwave Studio to confirm the impedance of the ceramic chamber.Further simulations covering six different types of ceramic chambers were conducted to develop an impedance model in the RCS.Additionally,this study investigates the resonant characteristics of the ceramic chamber impedance,finding that the resonant frequency is closely related to the capacitance of the capacitors.This finding provides clear directions for further impedance optimization and is crucial for achieving a beam power of 500 kW for the CSNS Phase-Ⅱ project(CSNS-Ⅱ).However,careful attention must be paid to the voltage across the capacitors.
基金supported by the Key R&D Program of Zaozhuang city,China(2024GH12)the Zaozhuang Gathering of Talents Program。
文摘Developing advanced cathode modification strategies to address the inherent high charge density of Al^(3+) is essential for achieving high-energy-density and long-cycle-life rechargeable aluminum batteries(RABs).Herein,we engineer tetraethylammonium(TEA)cation intercalation as a dual-function strategy that concurrently enables interlayer distance enlargement and electrostatic shielding effects,resolving Al^(3+) polarization-induced sluggish kinetics and cathode degradation in RABs.TEA intercalation triggers exceptional V2O5 interlayer expansion from 4.37 to 13.10Å,while the modulated charge distribution generates an electrostatic shielding effect that significantly weakens the Coulombic interactions between Al^(3+) and V2O5 frameworks.This dual mechanism collectively enhances ion diffusion kinetics and suppresses lattice stress accumulation.Ex situ X-ray diffraction and transmission electron microscopy analyses confirm that the“molecular pillar effect”of TEA enables minimal and highly reversible structural deformation of the cathode(<2.0%volume change after 200 cycles),demonstrating zero-strain aluminum-storage behavior.The optimized cathode delivers a high reversible capacity of 258 mAh g^(−1) at 0.5 A g^(−1),maintains 99%capacity retention at 5.0 A g^(−1),and exhibits an ultralow capacity decay rate of 0.01%per cycle over 6000 cycles.This work opens new pathways for designing stable high-performance RAB cathodes through synergistic modulation of electronic and lattice structures.
基金support of the National Natural Science Foundation of China(Grant Nos.52179116 and 51991392)the support of Key Deployment Projects of Chinese Academy of Sciences(Grant No.ZDRW-ZS-2021-3).
文摘Shield tunneling in saturated ground poses challenges due to the potential risk of ground collapse resulting from seepage force and inadequate support pressure.This study employed a laboratory model test and a theoretical validation to elucidate the mechanisms of face failure and subsequent ground collapse in saturated ground during slurry pressure-balanced shield(SPBS)tunneling operations.A slurry circulation system was developed to ensure steady shield tunneling and to replicate the phenomena of ground collapse.Investigations into shield tunneling parameters and ground responses,including soil pressure,pore water pressure,and surface subsidence,were conducted to understand the mechanisms of face failure and subsequent ground collapse.The theoretical solution for the critical collapse pressure of the tunnel face,based on the rotational failure mechanism,was validated through the comparison with the experimentally determined critical collapse pressure.The results indicate that:(1)appropriate adjustments of tunneling parameters are crucial for promoting filtercake formation,maintaining chamber pressure,and minimizing ground subsidence;(2)chamber pressure,soil pressure,pore water pressure,and ground subsidence are closely correlated with shield tunneling parameters and the formation of filter cake;(3)ground collapse follows a continuous failure mode due to the destruction of filtercake and the decrease in chamber pressure;(4)the soil pressure at the cutterhead is more sensitive to disturbances from shield tunneling than chamber pressure;and(5)experimentally determined critical collapse pressures is consistent with the theoretical solution of limit analysis.
基金supported by the National Natural Science Foundation of China(Grant No.51702081)。
文摘Aqueous zinc-ion batteries(AZIBs)are facing challenges of severe parasitic side reactions and uncontrolled Zn dendrite growth in promoting commercial applications.Here,rare earth metal neodymium ions(Nd^(3+))have been introduced into the conventional Zn SO_4 electrolyte as an electrolyte additive to improve the stability and reversibility of AZIBs.Combining experimental characterization and theoretical calculations,Nd^(3+)ions are adsorbed at the active sites of zinc crystal growth,forming a positively charged shielding layer on the Zn anode surface that effectively prevents lateral reactions and induces uniform Zn deposition.Meanwhile,Nd^(3+)ions preferentially adsorb on(100)and(101)planes of Zn,thus facilitating preferential deposition on the(002)plane and achieving a dendrite-free Zn anode.Consequently,a Zn//Zn symmetric cell with the Nd^(3+)-modified electrolyte exhibits an ultralong lifespan of 3000 h at0.5 m A cm^(-2),and a Zn//Cu asymmetric cell realizes an impressive Coulombic efficiency of 99.47%for Zn stripping and plating over 550 cycles at 1.0 mA cm^(-2).Impressively,Zn//CNT@MnO_(2) full cell reaches a considerably stable long cycle performance over 2500 cycles at 1.0 A g^(-1).This work offers an effective solution to the challenges faced by Zn anode and expands the application scope of metallic ions in metalbased energy storage devices.
基金supported by the National Natural Science Foundation of China(Grant Nos.52378392,52408356)the Foal Eagle Program Youth Top-notch Talent Project of Fujian Province,China(Grant No.00387088).
文摘Although machine learning models have achieved high enough accuracy in predicting shield position deviations,their“black box”nature makes the prediction mechanisms and decision-making processes opaque,leading to weaker explanations and practicability.This study introduces a novel explainable deep learning framework comprising the Informer model with enhanced attention mechanisms(EAMInfor)and deep learning important features(DeepLIFT),aimed at improving the prediction accuracy of shield position deviations and providing interpretability for predictive results.The EAMInfor model attempts to integrate channel attention,spatial attention,and simple attention modules to improve the Informer model's performance.The framework is tested with the four different geological conditions datasets generated from the Xiamen metro line 3,China.Results show that the EAMInfor model outperforms the traditional Informer and comparison models.The analysis with the DeepLIFT method indicates that the push thrust of push cylinder and the earth chamber pressure are the most significant features,while the stroke length of the push cylinder demonstrated lower importance.Furthermore,the variation trends in the significance of data points within input sequences exhibit substantial differences between single and composite strata.This framework not only improves predictive accuracy but also strengthens the credibility and reliability of the results.
基金supported by the National Youth Top-notch Talent Support Program of China(Grant No.00389335)the National Natural Science Foundation of China(Grant No.52378392)the“Foal Eagle Program”Youth Top-notch Talent Project of Fujian Province(Grant No.00387088).
文摘Estimating the properties of foam-conditioned clay soils is important for both conditioning and recycling goals in earth pressure balance(EPB)shield tunneling.In this study,the vacuum dewatering behaviors of foam-conditioned clay soils were investigated,with their potential use as an alternative means to assess foam optimization being examined.A series of laboratory and fieldtests was conducted,including vacuum dewatering tests that considered the effects of filtrationtime and pressure,vane shear tests,and improved cone pullout tests under different gravimetric water content(w)and foam injection ratio(FIR)conditions.It was found that the filtrate loss(FL),which characterizes dewaterability,was increased by extended vacuum filtrationtime and elevated pressure.While increases in w and FIR enhanced FL,reductions were observed in the undrained shear strength(cu),tangential adhesion stress(Fs),and normal adhesion stress(Fn).Furthermore,a linear decrease in FL with increasing mechanical indices(cu,Fs,and Fn)was demonstrated by both laboratory and fielddata fittingresults,regardless of w,FIR,and dewatering conditions.This study provides novel insights into the understanding of vacuum dewatering mechanisms in foam-conditioned clay soils,while a simple approach is proposed for evaluating foam conditioning effectiveness in EPB shield tunneling applications.
基金financially supported by the National Key Research and Development Program of China(No.2021YFB3700300)the National Natural Science Foundation of China(Nos.52573017 and U21B2093)+1 种基金Key Research and Development Program of Ningbo(No.2022Z200)the Zhejiang Provincial Natural Science Foundation(No.LY23E030005)。
文摘Bio-based 2,5-furandicarboxylic acid polyesters offer significant promise for reducing energy and environmental crises.However,their intrinsic flammability remains a critical limitation,and conventional flame-retardant strategies often compromise their mechanical properties,hindering their practical applications.Herein,a 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide(DOPO)-based comonomer(DDP)was used to synthesize flame-retardant poly(ethylene furandicarboxylate-co-phosphaphenanthrene)(PEFDn).The covalent integration of DDP confers intrinsic flame retardancy,avoiding the plasticization and migration issues associated with additive-type systems.Upon thermal decomposition,the DOPO-derived moieties release phosphoric acid and radical scavengers,promoting char formation and suppressing flame propagation.Furthermore,density functional theory(DFT)calculations combined with non-covalent interaction(NCI)analysis revealed that DOPO dimer molecules adopt a stable parallel-displaced π-π stacking configu ration,potentially facilitating microphase separation and enhancing the energy dissipation capability.PEFD_(10)achieves a UL-94 V-0 rating while simultaneously increasing impact toughness from 1.5 kJ/m^(2) to 14.7 kJ/m^(2).Im portantly,PEFDn maintained acceptable oxygen-barrier properties.PEFD10 also exhibited high transparency and UV-shielding performance.The combination of intrinsic flame safety,im pact-toughness resistance,UV shielding,and an oxygen barrier ensures reliable protection of electrical components and long-term operational stability.The integration of multiple critical properties within a single bio-based material represents a novel approach fo r enabling sustainable polymer solutions for high-pe rformance electrical applications.
基金Project(50425518) supported by National Outstanding Youth Foundation of China Project(2007CB714004) supported by National Basic Research Program of China
文摘The thrust hydraulic system of the prototype shield machine with pressure and flow compound control scheme was introduced. The experimental system integrated with proportional valves for study was designed. Dynamics modeling of multi-cylinder thrust system and synchronous control design were accomplished. The simulation of the synchronization motion control system was completed in AMESim and Matlab/Simulink software environments. The experiment was conducted by means of master/slave PID with dead band compensating flow and conventional PID regulating pressure. The experimental results show that the proposed thrust hydraulic system and its control strategy can meet the requirements of tunneling in motion and posture control for the shield machine, keeping the non-synchronous error within ±3 mm.
基金Supported by the National Basic Research Program of China(2007CB714006)the National Natural Science Foundation of China(90815023)
文摘An estimation approach using least squares method was presented for identificationof model parameters of pressure control in shield tunneling.The state equation ofthe pressure control system for shield tunneling was analytically derived based on themass equilibrium principle that the entry mass of the pressure chamber from cutting headwas equal to excluding mass from the screw conveyor.The randomly observed noise wasnumerically simulated and mixed to simulated observation values of system responses.The numerical simulation shows that the state equation of the pressure control system forshield tunneling is reasonable and the proposed estimation approach is effective even ifthe random observation noise exists.The robustness of the controlling procedure is validatedby numerical simulation results.
基金supported by National Natural Science Foundation of China(No.51872253)supported by Hebei Natural Science Foundation of China(No.E2019203480).
文摘The development of the preparation strategy for high-quality and large-size graphene via eco-friendly routes is still a challenging issue.Herein,we have successfully developed a novel route to chemically exfoliate natural graphite into high-quality and large-size graphene in a binary-peroxidant system.This system is composed of urea peroxide(CO(NH_(2))_(2)·H_(2)O_(2))and hydrogen peroxide(H_(2)O_(2)),where CO(NH_(2))_(2)·H_(2)O_(2)is used in preparing graphene for the first time.Benefiting from the complete decomposition of CO(NH_(2))_(2)·H_(2)O_(2)and H_(2)O_(2)into gaseous species under microwave(MW)irradiation,no water-washing and effluent-treatment are needed in this chemical exfoliation procedure,thus the preparation of graphene in an eco-friendly way is realized.The resultant graphene behaves a large-size,high-quality and few-layer feature with a yield of~100%.Then 4µm-thick ultrathin graphene paper fabricated from the as-exfoliated graphene is used as an electromagnetic interference(EMI)shielding material.And its absolute effectiveness of EMI shielding(SSE/t)is up to 34,176.9 dB cm^(2)/g,which is,to the best of our knowledge,among the highest values so far reported for typical EMI shielding materials.The EMI shielding performance demonstrates a great application potential of graphene paper in meeting the ever-increasingly EMI shielding demands in miniaturized electronic devices.
