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Green pathway to 14.51%efficiency in all-small-molecule organic solar cells:Apigenin-mediated morphology control with halogen-free processing
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作者 Lingya Sun Wentao Zou +11 位作者 Xu Zhang Shizhao Liu Meiyuan Zu Xunchang Wang Renqiang Yang Xianshao Zou Longlong Geng Hua Xie Huajun Xu Yuanyuan Kan Yanna Sun Ke Gao 《Journal of Energy Chemistry》 2025年第9期819-826,I0021,共9页
All-small-molecule organic solar cells(ASM OSCs)have emerged as promising photovoltaic technologies due to their excellent batch-to-batch reproducibility and potential for scalable manufacturing.However,the developmen... All-small-molecule organic solar cells(ASM OSCs)have emerged as promising photovoltaic technologies due to their excellent batch-to-batch reproducibility and potential for scalable manufacturing.However,the development of eco-friendly processing protocols using halogen-free solvents combined with sustainable solid additives remains unexplored,despite being crucial for realizing green and efficient ASM OSC production.Herein,we demonstrate the first successful integration of plant-extracted apigenin(AP)as a green solid additive with tetrahydrofuran(THF),a non-halogenated processing solvent,in ASM OSC fabrication.Systematic investigations reveal that AP establishes hydrogen-bonding interactions with the acceptor molecules,thereby promoting tighter molecular packing and enhancing crystallinity.Simultaneously,the additive modulates donor-acceptor miscibility to optimize phase-separated domain sizes.These synergistic effects generate a well-interconnected nanomorphology with balanced charge transport pathways,effectively facilitating exciton dissociation while suppressing charge recombination.The resultant devices obtain a remarkable power conversion efficiency(PCE)of 14.51%,representing one of the highest performances among halogen-free processed binary ASM OSCs reported to date.This pioneering work establishes a viable pathway toward sustainable OSC manufacturing by demonstrating that eco-friendly additives can synergistically cooperate with non-ha logenated solvents to simultaneously enhance device performance and process sustainability. 展开更多
关键词 Green solid additives Non-halogenated solvents Optimal phase separation Hydrogen bonding All-small-molecule organic solar cells
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Novel computer-assisted approach to quick prediction and optimization of gradient separation for online enrichment-reversed phase liquid chromatography tandem system 被引量:1
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作者 Shuying Han Yilin Song +6 位作者 Xinyi Jiang Junqin Qiao An Kang Haishan Deng Dong Zhu Rui Liu Hongzhen Lian 《Chinese Chemical Letters》 SCIE CAS CSCD 2023年第9期280-283,共4页
An algorithm capable of predicting and optimizing the gradient separation of LC×LC system was developed in this paper.Two groups of structural analogues,five ginsenosides as well as eight bisphenols,which were di... An algorithm capable of predicting and optimizing the gradient separation of LC×LC system was developed in this paper.Two groups of structural analogues,five ginsenosides as well as eight bisphenols,which were difficult to discriminate in routine analysis,were used to verify the effectiveness of the proposed algorithm in fast separation optimization.Average errors of retention times below 1%were found in the retention prediction for all types of gradient programs,implying that the theory could lead to high quality in prediction of the retention times under gradients elution.Meanwhile,84%of relative average deviations(RADs)between the predicted peak width and the measured ones were less than 20%.The larger deviation occurred at the time when the peak appeared while the gradient of the mobile phase changed,which led the deviations increased to 20%–42%.In all,method development and optimization for LC×LC tandem system was realized by the homemade user-friendly software.The present protocol may turn on great opportunities for the convenient method development in analysis of trace structural analogues in environmental,food and biological samples. 展开更多
关键词 LC×LC tandem system Separation prediction Gradient elution Peak shape Separation optimization algorithm
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Aircraft Optimal Separation Allocation Based on Global Optimization Algorithm
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作者 REN Xuanming TANG Xinmin 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2022年第6期707-720,共14页
A dynamic programming-sequential quadratic programming(DP-SQP)combined algorithm is proposed to address the problem that the traditional continuous control method has high computational complexity and is easy to fall ... A dynamic programming-sequential quadratic programming(DP-SQP)combined algorithm is proposed to address the problem that the traditional continuous control method has high computational complexity and is easy to fall into local optimal solution.To solve the globally optimal control law sequence,we use the dynamic programming algorithm to discretize the separation control decision-making process into a series of sub-stages based on the time characteristics of the separation allocation model,and recursion from the end stage to the initial stage.The sequential quadratic programming algorithm is then used to solve the optimal return function and the optimal control law for each sub-stage.Comparative simulations of the combined algorithm and the traditional algorithm are designed to validate the superiority of the combined algorithm.Aircraft-following and cross-conflict simulation examples are created to demonstrate the combined algorithm’s adaptability to various conflict scenarios.The simulation results demonstrate the separation deploy strategy’s effectiveness,efficiency,and adaptability. 展开更多
关键词 optimal separation allocation sequential quadratic programming dynamic programming globally optimal control optimal control law
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Adaptive Particle Swarm Optimization Data Hiding for High Security Secret Image Sharing
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作者 S.Lakshmi Narayanan 《Computer Systems Science & Engineering》 SCIE EI 2022年第12期931-946,共16页
The main aim of this work is to improve the security of data hiding forsecret image sharing. The privacy and security of digital information have becomea primary concern nowadays due to the enormous usage of digital t... The main aim of this work is to improve the security of data hiding forsecret image sharing. The privacy and security of digital information have becomea primary concern nowadays due to the enormous usage of digital technology.The security and the privacy of users’ images are ensured through reversible datahiding techniques. The efficiency of the existing data hiding techniques did notprovide optimum performance with multiple end nodes. These issues are solvedby using Separable Data Hiding and Adaptive Particle Swarm Optimization(SDHAPSO) algorithm to attain optimal performance. Image encryption, dataembedding, data extraction/image recovery are the main phases of the proposedapproach. DFT is generally used to extract the transform coefficient matrix fromthe original image. DFT coefficients are in float format, which assists in transforming the image to integral format using the round function. After obtainingthe encrypted image by data-hider, additional data embedding is formulated intohigh-frequency coefficients. The proposed SDHAPSO is mainly utilized for performance improvement through optimal pixel location selection within the imagefor secret bits concealment. In addition, the secret data embedding capacityenhancement is focused on image visual quality maintenance. Hence, it isobserved from the simulation results that the proposed SDHAPSO techniqueoffers high-level security outcomes with respect to higher PSNR, security level,lesser MSE and higher correlation than existing techniques. Hence, enhancedsensitive information protection is attained, which improves the overall systemperformance. 展开更多
关键词 Image sharing separable data hiding using adaptive particle swarm optimization(SDHAPSO) SECURITY access control
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A Half-Proximal Symmetric Splitting Method for Non-Convex Separable Optimization
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作者 Pengjie Liu Jinbao Jian +2 位作者 Hu Shao Xiaoquan Wang Xiangfeng Wang 《Acta Mathematica Sinica,English Series》 2025年第8期2160-2194,共35页
In this paper,we explore the convergence and convergence rate results for a new methodology termed the half-proximal symmetric splitting method(HPSSM).This method is designed to address linearly constrained two-block ... In this paper,we explore the convergence and convergence rate results for a new methodology termed the half-proximal symmetric splitting method(HPSSM).This method is designed to address linearly constrained two-block non-convex separable optimization problem.It integrates a half-proximal term within its first subproblem to cancel out complicated terms in applications where the subproblem is not easy to solve or lacks a simple closed-form solution.To further enhance adaptability in selecting relaxation factor thresholds during the two Lagrange multiplier update steps,we strategically incorporate a relaxation factor as a disturbance parameter within the iterative process of the second subproblem.Building on several foundational assumptions,we establish the subsequential convergence,global convergence,and iteration complexity of HPSSM.Assuming the presence of the Kurdyka-Łojasiewicz inequality of Łojasiewicz-type within the augmented Lagrangian function(ALF),we derive the convergence rates for both the ALF sequence and the iterative sequence.To substantiate the effectiveness of HPSSM,sufficient numerical experiments are conducted.Moreover,expanding upon the two-block iterative scheme,we present the theoretical results for the symmetric splitting method when applied to a three-block case. 展开更多
关键词 Nonconvex separable optimization half-proximal splitting method Kurdyka-Łojasiewicz property convergence and rate analyses
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Accuracy analysis of the optimal separable approximation method of one-way wave migration
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作者 杜淑媛 陈景波 刘洪 《Applied Geophysics》 SCIE CSCD 2011年第4期328-336,371,372,共11页
An approximation for the one-way wave operator takes the form of separated space and wave-number variables and makes it possible to use the FFT, which results in a great improvement in the computational efficiency. Fr... An approximation for the one-way wave operator takes the form of separated space and wave-number variables and makes it possible to use the FFT, which results in a great improvement in the computational efficiency. From the function approximation perspective, the OSA method shares the same separable approximation format to the one-way wave operator as other separable approximation methods but it is the only global function approximation among these methods. This leads to a difference in the phase error curve, impulse response, and migration result from other separable approximation methods. The difference is that the OSA method has higher accuracy, and the sensitivity to the velocity variation declines with increasing order. 展开更多
关键词 one-way wave operator MIGRATION separable approximation optimal separable approximation
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Optimal mode of capillary electrophoresis for the impurity analysis of β-lactam antibiotics
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作者 朱建平 张慧文 胡昌勤 《Journal of Chinese Pharmaceutical Sciences》 CAS 2010年第4期285-292,共8页
In order to determine the optimal mode of capillary electrophoresis for the impurity control of β-lactam antibiotics, different modes and various electrophoresis conditions for the separation of impurities were compa... In order to determine the optimal mode of capillary electrophoresis for the impurity control of β-lactam antibiotics, different modes and various electrophoresis conditions for the separation of impurities were compared.The results showed that micellar electrokinetic capillary chromatography(MEKC) was the optimal separation mode for the impurity profiling of β-lactam antibiotics.In MEKC,not only the common R and S isomers,Δ-2 andΔ-3 isomers,and Z and E isomers,but also the impurities of β-lactam antibiotics could be well separated compared with the capillary zone electrophoresis.Therefore,MECK is the first choice for the separation of impurities of β-lactam antibiotics with capillary electrophoresis(CE).The optimal separation could be achieved in MEKC by optimizing the pH and the concentrations of buffered saline,micelles and organic solvent(methanol) in running buffer. 展开更多
关键词 β-Lactam antibiotics IMPURITY CZE MEKC Optimal separation mode
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Investigation on a vertical radial flow adsorber designed by a novel parallel connection method 被引量:10
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作者 Zhengshu Dai Meng Yu +2 位作者 Daozhe Rui Xuejun Zhang Yang Zhao 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第3期484-493,共10页
Due to the increasing global demand for industrial gas, the development of large-scale cryogenic air separation systems has attracted considerable attention in recent years. Increasing the height of the adsorption bed... Due to the increasing global demand for industrial gas, the development of large-scale cryogenic air separation systems has attracted considerable attention in recent years. Increasing the height of the adsorption bed in a vertical radial flow adsorber used in cryogenic air separation systems may efficiently increase the treatment capacity of the air in the adsorber. However, uniformity of the flow distribution of the air inside the adsorber would be deteriorated using the height-increasing method. In order to reduce the non-uniformity of the flow distribution caused by the excessive height of adsorption bed in a vertical radial flow adsorber, a novel parallel connection method is proposed in the present work. The experimental apparatus is designed and constructed; the Computational Fluid Dynamics(CFD) technique is used to develop a CFD-based model, which is used to analyze the flow distribution, the static pressure drop and the radial velocity in the newly designed adsorber. In addition, the geometric parameters of annular flow channels and the adsorption bed thickness of the upper unit in the parallelconnected vertical radial flow adsorber are optimized, so that the upper and lower adsorption units could be penetrated by air simultaneously. Comparisons are made between the height-increasing method and the parallel connection method with the same adsorber height. It is shown that using the parallel connection method could reduce the difference between the maximum and minimum radial static pressure drop by 86.2% and improve the uniformity by 80% compared with those of using the height-increasing method. The optimal thickness ratio of the upper and lower adsorption units is obtained as 0.966, in which case the upper and lower adsorption units could be penetrated by air simultaneously, so that the adsorbents in adsorption space could be used more efficiently. 展开更多
关键词 Air separation Purification Vertical radial flow adsorber Flow distribution optimization
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3D wavefield extrapolation with optimal separable approximation
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作者 Zhang Zhifu Meng Xiaohong +2 位作者 Liu Hong Chen Jingbo Li YouMing 《Applied Geophysics》 SCIE CSCD 2006年第4期218-225,共8页
An accurate and wide-angle one-way propagator for wavefield extrapolation is an important topic for research on wave-equation prestack depth migration in the presence of large and rapid velocity variations. Based on t... An accurate and wide-angle one-way propagator for wavefield extrapolation is an important topic for research on wave-equation prestack depth migration in the presence of large and rapid velocity variations. Based on the optimal separable approximation presented in this paper, the mixed domain algorithm with forward and inverse Fourier transforms is used to construct the 3D one-way wavefield extrapolation operator. This operator separates variables in the wavenumber and spatial domains. The phase shift operation is implemented in the wavenumber domain while the time delay for lateral velocity variation is corrected in the spatial domain. The impulse responses of the one-way wave operator show that the numeric computation is consistent with the theoretical value for each velocity, revealing that the operator constructed with the optimal separable approximation can be applied to lateral velocity variations for the case of small steps. Imaging results of the SEG/EAGE model and field data indicate that the new method can be used to image complex structure. 展开更多
关键词 WAVE-EQUATION optimal separable approximation one-way wavefield extrapolation operator SYMBOL prestack depth migration.
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The Offset-Domain Prestack Depth Migration with Optimal Separable Approximation
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作者 张致付 刘春园 +1 位作者 张春涛 孟小红 《Journal of China University of Geosciences》 SCIE CSCD 2007年第4期350-356,共7页
The offset-domain prestack depth migration with optimal separable approximation, based on the double square root equation, is used to image complex media with large and rapid velocity variations. The method downward c... The offset-domain prestack depth migration with optimal separable approximation, based on the double square root equation, is used to image complex media with large and rapid velocity variations. The method downward continues the source and the receiver wavefields simultaneously. The mixed domain algorithm with forward Fourier and inverse Fourier transform is used to construct the double square root equation wavefield extrapolation operator. This operator separates variables in the wave number domain and variables in the space domain. The phase operation is implemented in the wave number domain, whereas the time delay for lateral velocity variation is corrected in the space domain. The migration algorithm is efficient since the seismic data are not computed shot by shot. The data set test of the Marmousi model indicates that the offset-domain migration provides a satisfied seismic migration section on which complex geologic structures are imaged in media with large and rapid lateral velocity variations. 展开更多
关键词 double square root equation optimal separable approximation prestack depth migration.
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A Homotopy Alternating Direction Method of Multipliers for Linearly Constrained Separable Convex Optimization 被引量:1
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作者 Jiao Yang Yi-Qing Dai +2 位作者 Zheng Peng Jie-Peng Zhuang Wen-Xing Zhu 《Journal of the Operations Research Society of China》 EI CSCD 2017年第2期271-290,共20页
Linearly constrained separable convex minimization problems have been raised widely in many real-world applications.In this paper,we propose a homotopy-based alternating direction method of multipliers for solving thi... Linearly constrained separable convex minimization problems have been raised widely in many real-world applications.In this paper,we propose a homotopy-based alternating direction method of multipliers for solving this kind of problems.The proposed method owns some advantages of the classical proximal alternating direction method of multipliers and homotopy method.Under some suitable condi-tions,we prove global convergence and the worst-case O(k/1)convergence rate in a nonergodic sense.Preliminary numerical results indicate effectiveness and efficiency of the proposed method compared with some state-of-the-art methods. 展开更多
关键词 Separable convex optimization Alternating direction method of multipliers Proximal point algorithm Homotopy method
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Inertial Proximal ADMM for Separable Multi-Block Convex Optimizations and Compressive Affine Phase Retrieval
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作者 Peng LI Wen Gu CHEN Qi Yu SUN 《Acta Mathematica Sinica,English Series》 SCIE CSCD 2023年第8期1459-1496,共38页
Separable multi-block convex optimization problem appears in many mathematical and engineering fields.In the first part of this paper,we propose an inertial proximal ADMM to solve a linearly constrained separable mult... Separable multi-block convex optimization problem appears in many mathematical and engineering fields.In the first part of this paper,we propose an inertial proximal ADMM to solve a linearly constrained separable multi-block convex optimization problem,and we show that the proposed inertial proximal ADMM has global convergence under mild assumptions on the regularization matrices.Affine phase retrieval arises in holography,data separation and phaseless sampling,and it is also considered as a nonhomogeneous version of phase retrieval,which has received considerable attention in recent years.Inspired by convex relaxation of vector sparsity and matrix rank in compressive sensing and by phase lifting in phase retrieval,in the second part of this paper,we introduce a compressive affine phase retrieval via lifting approach to connect affine phase retrieval with multi-block convex optimization,and then based on the proposed inertial proximal ADMM for 3-block convex optimization,we propose an algorithm to recover sparse real signals from their(noisy)affine quadratic measurements.Our numerical simulations show that the proposed algorithm has satisfactory performance for affine phase retrieval of sparse real signals. 展开更多
关键词 Inertial proximal ADMM separable multi-block convex optimization affine phase retrieval
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A HOMOTOPY-BASED ALTERNATING DIRECTION METHOD OF MULTIPLIERS FOR STRUCTURED CONVEX OPTIMIZATION
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作者 Yiqing Dai Zheng Peng 《Annals of Applied Mathematics》 2015年第3期262-273,共12页
The alternating direction method of multipliers (ADMM for short) is efficient for linearly constrained convex optimization problem. The practicM computationM cost of ADMM depends on the sub-problem solvers. The prox... The alternating direction method of multipliers (ADMM for short) is efficient for linearly constrained convex optimization problem. The practicM computationM cost of ADMM depends on the sub-problem solvers. The proximal point algorithm is a common sub-problem-solver. However, the proximal parameter is sensitive in the proximM ADMM. In this paper, we propose a homotopy-based proximal linearized ADMM, in which a homotopy method is used to soNe the sub-problems at each iteration. Under some suitable conditions, the global convergence and the convergence rate of O(1/k) in the worst case of the proposed method are proven. Some preliminary numerical results indicate the validity of the proposed method. 展开更多
关键词 separable convex optimization alternating direction method of mul-tipliers proximal point method homotopy method
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Optimization of the separation of a mixture of unknown composition by reversed-phase HPLC
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作者 WANG,Qin-Sun GAO,Ru-Yu ZHAN,Zhuang-Ping National Laboratory of Elemento-Organic Chemistry,Nankai University,Tianjin 300071 《Chinese Journal of Chemistry》 SCIE CAS CSCD 1993年第4期329-334,共8页
A method is presented for the computer-assisted optimization of mobile phase selection for the separation of a synthetic intermediate of unknown composition by reversed- phase HPLC.The method is based on recognition o... A method is presented for the computer-assisted optimization of mobile phase selection for the separation of a synthetic intermediate of unknown composition by reversed- phase HPLC.The method is based on recognition of the order of the peaks by comparison of peak area ratio and followed by the BSOS-L(Binary Solvent Optimization System for HPLC)method.Excellent agreement was obtained between predicted data and experimental results. 展开更多
关键词 optimization of the separation of a mixture of unknown composition by reversed-phase HPLC
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