Benthic habitat mapping is an emerging discipline in the international marine field in recent years,providing an effective tool for marine spatial planning,marine ecological management,and decision-making applications...Benthic habitat mapping is an emerging discipline in the international marine field in recent years,providing an effective tool for marine spatial planning,marine ecological management,and decision-making applications.Seabed sediment classification is one of the main contents of seabed habitat mapping.In response to the impact of remote sensing imaging quality and the limitations of acoustic measurement range,where a single data source does not fully reflect the substrate type,we proposed a high-precision seabed habitat sediment classification method that integrates data from multiple sources.Based on WorldView-2 multi-spectral remote sensing image data and multibeam bathymetry data,constructed a random forests(RF)classifier with optimal feature selection.A seabed sediment classification experiment integrating optical remote sensing and acoustic remote sensing data was carried out in the shallow water area of Wuzhizhou Island,Hainan,South China.Different seabed sediment types,such as sand,seagrass,and coral reefs were effectively identified,with an overall classification accuracy of 92%.Experimental results show that RF matrix optimized by fusing multi-source remote sensing data for feature selection were better than the classification results of simple combinations of data sources,which improved the accuracy of seabed sediment classification.Therefore,the method proposed in this paper can be effectively applied to high-precision seabed sediment classification and habitat mapping around islands and reefs.展开更多
The arsenic(As)release from sediments in great lakes is affected by various factors.In this study,the characteristics of As release fromsediments was investigated,and the As sources and sinks with the strengths in sed...The arsenic(As)release from sediments in great lakes is affected by various factors.In this study,the characteristics of As release fromsediments was investigated,and the As sources and sinks with the strengths in sediments from different areas(grass-type,algae-type,and grass-algae alternation areas)in great shallow lakes(Taihu Lake,China)were analyzed,and the influence of P competition in the process of As release was also studied.The results showed that changing trend of the values of equilibrium As concentration in sediments were consistent with the regional changes(0 to 28.12μg/L),and the sediments from algaetype areas had the higher values.The sediments from western lake and northwest lake bay were a strong As and a weak P source,and the north lake bay had the opposite trend of these two regions.Intense P source competition with As from the sediments occurred in algae-type areas.The grass-type areas had strong As and P retention capacities,indicating a sink role of sediment with high As and P sorption capacities.The degree of As and P saturation had similar trend in sediments,and the grass-type areas had the higher values,18.3%-21.4%and 15.31%-20.34%,respectively.Contribution analysis results showed that most of As release contribution was from the bottom(30-50 cm)sediments,and the surface(0-10 cm)sediments from algae-type areas contributed more to the overlying water than other region.展开更多
Microplastic(MP)contamination is becoming a major worldwide concern,affecting terrestrial and aquatic ecosystems.This study investigated the source,distribution,and abundance of MPs in sediments from Dongshan Bay,Fuji...Microplastic(MP)contamination is becoming a major worldwide concern,affecting terrestrial and aquatic ecosystems.This study investigated the source,distribution,and abundance of MPs in sediments from Dongshan Bay,Fujian,South China,emphasizing particularly the coastline region's susceptibility to tidal impacts in four study sites.The concentrations of MPs in the sediments in the four sites were high from 7.4 to 283.1 items/kg(dry weight).There were notable differences in abundance between the locations and tide levels.Tides influenced the distribution of MPs greatly;however,the estuary areas showed greater MPs abundance during high tide,due possibly to enhanced water turbulence and riverine inputs.Low tide indicated higher concentrations in coastal locations owing to accumulation.Popular varieties,including nylon,polypropylene,and polyethylene,were identified by polymer research,pointing to the origins from fishing,packaging,and mariculture industries.Potential sources were determined using the PCA-K-means statistical analysis,by linking the origins of MPs to domestic activities,fishing,mariculturing,shipping,and packing.Fishing and packing were shown in the Sankey diagram as the two main sources,but their effects varied with research locations and tidal regimes.This study clarified the intricate dynamics of MPs pollution,highlighting the impact of tides on its dispersal and the variety of sources that contribute to this widespread environmental problem in coastal areas.展开更多
This study investigates the distribution,geochemical behavior,and potential anthropogenic influences of rare earth elements(REEs)in the surface sediments of Qinghai Lake,the largest saline lake in China.A total of 36 ...This study investigates the distribution,geochemical behavior,and potential anthropogenic influences of rare earth elements(REEs)in the surface sediments of Qinghai Lake,the largest saline lake in China.A total of 36 surface sediment samples were analyzed for REE concentrations with a combination of self-organizing maps(SOM)and positive matrix factorization(PMF).Results indicate distinct enrichment patterns,with light REEs(LREEs)exhibiting higher concentrations than heavy REEs(HREEs),reflecting natural abundances and geochemical behaviors.The minimum value was found in Lu as low as 0.091 mg/kg,and the maximum concentration was exhibited in Ce at 78.877 mg/kg.Geoaccumulation index(I_(geo))analysis reveals minor to moderate enrichment of specific REEs of Sm and Nd,suggesting possible localized anthropogenic inputs,particularly near river mouths.Spatial analysis using inverse distance weighting(IDW)and self-organizing maps(SOM)highlights significant correlations between REE distributions and riverine inputs,underscoring fluvial transport's role in sedimentary REE dynamics.PMF identifies mixed natural and anthropogenic sources,with agricultural and industrial activities contributing to elevated REE levels in sediment.These findings provide critical insights into the geochemical behavior of REEs in saline lake systems and off er a foundation for pollution control and sustainable resource management in sensitive environments like Qinghai Lake.展开更多
Environmental problems from heavy metals(HMs)attract global attention.Accurately identifying sources and quantitatively evaluating ecological risks are keys for HMs pollution prevention.Dongting Lake in China was inve...Environmental problems from heavy metals(HMs)attract global attention.Accurately identifying sources and quantitatively evaluating ecological risks are keys for HMs pollution prevention.Dongting Lake in China was investigated through integrated methods like positive matrix factorization and Nemerow integrated risk index to examine spatial distribution,contamination characteristics,pollution sources,and the contribution of each source and pollutant to the ecological risk of 14 HMs in its surface sediments.Results showed that the mean concentrations of HMs were 0.82-9.44 times greater than the corresponding background values.The spatial distribution of HMs varied significantly,with high values of As,Cd,Mn,Pb,Sn,Tl and Zn concentrated in the sediments from Xiangjiang inlet and Yangtze outlet;Co,Cr,Cu,Ni and V in the Lishui sediments;Hg and Sb in the sediments from Yuanjiang and Zishui inlets,respectively.The accumulation of HMs was affected by five sources:mercury mining and atmospheric deposition(F1)(17.99%),urban domestic sewage and industrial sewage discharge(F2)(24.44%),antimony ore mining and smelting(F3)(6.50%),non-ferrous metal mining and extended processing industrial sources(F4)(15.72%),and mixed sources mainly from natural sources and agricultural sources(F5)(35.35%).F1 and F2 were identified as priority pollution sources;Cd,Hg,Tl,Sb and As,especially Cd and Hg,posed relatively high ecological risks and were prioritized HMs for control.展开更多
Mangrove forests are critical ecosystems for carbon sequestration,effectively capturing atmospheric carbon and permanently storing soil organic carbon(SOC)in coastal wetlands.Recent restoration and afforestation initi...Mangrove forests are critical ecosystems for carbon sequestration,effectively capturing atmospheric carbon and permanently storing soil organic carbon(SOC)in coastal wetlands.Recent restoration and afforestation initiatives have been undertaken to mitigate the rising atmospheric CO_(2) concentrations along tropical ocean coasts worldwide.The expansion of mangrove forests has garnered significant attention for elucidating their contributions to the permanent storage of carbon in both surface and subsoil layers.In this study,we investigated a recently expanding mangrove forest in the Beilun River Estuary of Guangxi Province,focusing on the abundance and sources of organic carbon(OC)in surface sediments.We also analyzed sediment grain size distribution,SOC,total nitrogen(TN)content,and stable carbon isotope composition(δ^(13)C).Additionally,we determined the molar ratio of SOC to nitrogen(C/N).The SOC content ranged from 0.25%to 6.58%,the C/N ratio varied from 9.85 to 17.73,δ^(13)C values spanned from-29.58‰to-24.93‰,andδ^(15)N values ranged from 3.10‰to 7.36‰.A strong correlation was observed between SOC and TN content.However,particle size did not significantly influence these relationships.In terms of SOC sources in the sediments,contributions from mangrove,terrestrial,and marine sources accounted for 37.1%to 99.5%,0.5%to 47.4%,and 0%to 17.6%,respectively.The findings of this study provide essential insights for evaluating and managing carbon sinks within the mangrove ecosystems of the Beibu Gulf region,contributing to more effective carbon management strategies in coastal areas.展开更多
The mound-making behavior of plateau zokors is one of the most important factors in remodeling meadow microtopography and causing soil erosion in the Yellow River source area of western China,but little is known about...The mound-making behavior of plateau zokors is one of the most important factors in remodeling meadow microtopography and causing soil erosion in the Yellow River source area of western China,but little is known about the effects of microtopography on particle size characteristics(PSC)of eroded sediments from the bare slopes of zokor mounds during different rainfall events.In this study,we analyzed the relationship of microtopographic features derived from laser point cloud data and PSC of eroded sediments at six simulated rainfall intensities(all lasting 60 min).The effects of microtopography on PSC of eroded sediments were studied via partial least squares regression(PLSR)and structural equation modeling(SEM).The results showed that:(1)15-20 minutes from the beginning of rainfall was the sensitive period of soil loss from the slopes,and the function relationship between the rate of sediment and runoff and rainfall intensity can better predict the development trend of soil erosion;(2)Intense erosion occurred mainly in the upper half of the zokor mound,while deposition was mainly limited to its lower half.It is suggested that diminished plateau zokor activity intensity can effectively prevent and control soil erosion;(3)The PSC of eroded sediment is dominated by silt,followed by sand,with clay being the least abundant,and the eroded sediments with a particle size of 10-20μm were sensitive and highly susceptible to rainfall erosion.This finding facilitates the understanding of the formation process of surface geomorphology and the mechanism of soil erosion;(4)The PLSR model indicates that microtopography has an extensive influence on eroded sediments during hydraulic erosion,and the SEM analysis results further confirm that the fractal dimension was the best parameter to represent the PSC of eroded sediments,whereas surface cutting degree was the dominant factor controlling the PSC of eroded sediments.These findings are crucial for predicting soil erosion in the Yellow River source area and provide a new perspective for understanding soil erosion mechanisms in alpine meadow ecosystems.展开更多
Fluoroquinolones(FQs)have the propensity to accumulate in sediments once introduction into aquatic envi-ronments,thereby posing potential threats to benthic organisms,yet the ecotoxicity of sediment-associated FQs rem...Fluoroquinolones(FQs)have the propensity to accumulate in sediments once introduction into aquatic envi-ronments,thereby posing potential threats to benthic organisms,yet the ecotoxicity of sediment-associated FQs remains unclear.In this study,the toxicokinetics and responses of multiple biomarkers in Bellamya aeruginosa,exposed to the three commonly used FQs(norfloxacin,NOR;ciprofloxacin,CIP;levofloxacin,LEVO)at envi-ronmentally relevant concentrations were investigated under sediment exposure scenario.The results revealed that FQs were effectively ingested by B.aeruginosa from sediments,CIP showing the highest bioaccumulation(180.59μg/kg),followed by NOR(74.49μg/kg)and LEVO(36.02μg/kg).CIP exhibiting a highest uptake rate constant(Ks)(4.64 g/(g·day))and the lowest elimination rate constant(K_(e))(0.05 g/(g·day)).The descending order of biological half-life is as follows:CIP(13.62 days),LEVO(8.14 days),and NOR(6.83 days).NOR induced the activity of superoxide dismutase,catalase,and glutathione-S-transferase while CIP and LEVO depressed their activities and increased malondialdehyde content,indicating a more pronounced oxidative damage to B.aerug-inosa caused by CIP and LEVO than NOR.Furthermore,all three FQs were found to induce DNA damage and elevate acetylcholinesterase activity,suggesting distinct genotoxic and neurotoxic effects.Interestingly,despite its low bioaccumulation potential,LEVO exhibited high toxicity towards B.aeruginosa.These findings enhance our understanding of the ecotoxicity of FQs in sediments,providing further evidence of their potential ecological risks.展开更多
Noncohesive particle clusters are identified and tracked in turbulent flows to determine the breakdown and time evolution of cluster statistics and their implications for interscale mass transfer,which has connections...Noncohesive particle clusters are identified and tracked in turbulent flows to determine the breakdown and time evolution of cluster statistics and their implications for interscale mass transfer,which has connections to the classical turbulent energy cascade and its mass cascade counterpart running in parallel.In particular,the formation and dynamics of sediment and larvae clusters are of interest to coral larvae settlement in coastal regions and particularly the resilience of green-gray coastal protection solutions.Analogous cluster behavior is relevant to cloud microphysics and precipitation initiation,radiation transport and light transmission through colloids and suspensions,heat and mass transfer in particle-laden flows,and viral and pollutant transmission.Following a comparison between various clustering techniques,we adopt a density-based cluster identification algorithm based on its simplicity and efficiency,where particles are clustered based on the number of neighboring particles in their individual spheres of influence.We establish parallels with lattice-based percolation theory,as evident in the power-law scaling of the cluster size distribution near the percolation threshold.The degree of discontinuity of the phase transition associated with this percolation threshold is observed to broaden with larger Stokes numbers and thereby large-scale clustering.The sensitivity of our findings to the employed clustering algorithm is discussed.A novel cluster tracking algorithm is deployed to determine the interscale transfer rate along the particle-number phase-space dimension via accounting of cluster breakup and merger events,extending previous work on the bubble breakup cascade beneath surface breaking waves.Our findings shed light on the interaction between particle clusters and their carrier turbulent flows,with an eye toward transport models incorporating cluster characteristics and dynamics.展开更多
Subducted sediments,as an integral part of subducted slab,can strongly influence the chemistry of volcanic arc lavas,and clarify the relationship between subduction input and arc output,which is the focus of the subdu...Subducted sediments,as an integral part of subducted slab,can strongly influence the chemistry of volcanic arc lavas,and clarify the relationship between subduction input and arc output,which is the focus of the subduction factory theory in the context of plate tectonics.In this study,we analyzed major and trace element compositions of the subducting sediments from two sites[Deep Sea Drilling Program(DSDP)Site 495 and Ocean Drilling Program(ODP)Site 1039]at the different locations along the Middle America Trench.The results showed that the sediments from these two sites are mainly composed of terrigenous material,carbonate components,and biogenic silicate in different proportions.In order to reduce the effects of the variations in subduction topography on the chemical composition of sediments,we recalculated the bulk subducted sediment composition at northern and southern Central America subduction zone,and identified the Nicaragua Fracture Zone as the dividing line for northern and southern subducting sediments at Middle America Trench.Compared to the global trench subducting sediment,both the subducting sediments from northern and southern Central America subduction zone exhibit lower contents of terrigenous material-controlled elements and are more enriched in the biogenic components-controlled elements.We suggested that the variations in both chemical compositions for sediments and subduction angles are responsible for the different contributions of subducting sediments to volcanic arc magmatism in the northern Central America.展开更多
Reliable thickness of sedimentary layers is essential for seismic hazard assessment in active fault zones, especially in regions prone to strong earthquakes. This study analyzed the seismic ambient noise data recorded...Reliable thickness of sedimentary layers is essential for seismic hazard assessment in active fault zones, especially in regions prone to strong earthquakes. This study analyzed the seismic ambient noise data recorded by 60 short-period seismic stations deployed at the Jishishan earthquake source and adjacent areas. The base-order resonance frequencies of sedimentary layers beneath the stations were determined using the horizontal-to-vertical spectral ratio method on ambient noise with diff erent frequencies. Then, a resonance-thickness formula was applied to estimate the sedimentary layer thickness at each station. Finally, the entire regional sediment thickness was obtained via interpolation. The thickness of the sedimentary layer beneath each station was estimated using the equation of the relationship between resonance frequency and sedimentary layer thickness, and fi nally, the distribution of sedimentary layer thickness in the whole region was obtained by interpolation. Results reveal notable spatial variations in sediment thickness in the source and adjacent areas. The shallow sedimentary layer in the source area is relatively thick at approximately 100 m, whereas that in Liugou Village, which is the most severely damaged area, is approximately 150-180 m. In the western region, specifically along the western edge of the Jishishan Mountain rupture and the Pourouliuhe-Cheunhua Nanshan rupture zone, the shallow sedimentary layer is approximately 30-60 m. A comparison between the distribution of seismic secondary hazards and sedimentary layer thickness highlights a strong correlation between these hazards and the amplifi cation eff ects of seismic waves. In regions with thicker sedimentary layers, ground shaking is signifi cantly amplifi ed, resulting in more serious seismic secondary hazards. In addition, the study confi rmed that secondary hazards, such as landslides and liquefaction, were more prevalent in regions with thicker sedimentary layers. These fi ndings provide an important reference for post-earthquake reconstruction, seismic risk assessment, and the development of regional disaster prevention and mitigation strategies..展开更多
This study investigated the hydrocarbon source rock potential of the Late Cretaceous Mamu and Nkporo formations in the Asaga-Ohafia Axis,Afikpo Basin,southeastern Nigeria,using integrated facies analysis,organic geoch...This study investigated the hydrocarbon source rock potential of the Late Cretaceous Mamu and Nkporo formations in the Asaga-Ohafia Axis,Afikpo Basin,southeastern Nigeria,using integrated facies analysis,organic geochemical and palynofacies data.Five lithofacies were identified:dark grey shale,oolitic limestone,heterolithic mudstone/sandstone,laminated bioturbated sandstone,and calcareous mudstone,indicating estuarine,deltaic,and shallow marine depositional environments.Total organic carbon(TOC) contents range from 1.47 to 2.40 wt%,which reflects moderate to good organic richness.For the Mamu Formation,kerogen composition is dominated by Type Ⅱ/Ⅲ,composed of 30 %-50 %amorphous organic matter(AOM),5 %-10 % liptinite,30 %-50 % vitrinite,and 10 %-20 % inertinite.Spore coloration and Thermal Alteration Index(TAI:3-3+) suggest thermal maturity within the oil window(Ro:0.80 %-1.50 %).In contrast,the Nkporo Formation shows comparable kerogen composition(20 %-45 % AOM,0-20 % liptinite,and 40 %-65 % vitrinite) but lower maturity(TAI:2-2+;Ro:0.45 %-0.80 %).Rock-Eval pyrolysis further supports these findings.The Mamu Formation displays higher Hydrogen Index,favorable Tmax,and Production Index values,confirming its maturity and oil and gas-prone potential.Palynological assemblages,including marine dinoflagellate cysts(Mamu Formation) and freshwater algae/fungal spores(Nkporo Formation),align with the inferred depositional settings.Thus,the Mamu Formation is the more prolific source rock,characterized by superior organic quality and thermal maturity.展开更多
39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.Ar...39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.ArcGIS inverse distance weight difference method was used to analyze the characteristics of pollution distribution,and single-factor pollution index,Nemerow comprehensive pollution index,ground accumulation index,and potential ecological risk index were selected to evaluate the characteristics of heavy metal pollution.Based on correlation analysis,the absolute principal component-multiple linear regression(APCS-MLR)and positive definite matrix factorization(PMF)models were used to analyze the sources of soil heavy metals.The results showed that the average concentrations of all eight heavy metals exceeded both national and Guangxi soil background values.Hg,Cd,and Zn exhibited high variation(greater than 0.5),indicating significant external disturbances,and their spatial distribution was closely related to mining activity locations.The single-factor pollution index evaluation indicated varying degrees of pollution risk for Cd,Zn,and As,with Cd and Zn being the most severe pollutants,as 69.23%and 30.77%of the samples fell into the moderate pollution or higher category.The geoaccumulation index analysis ranked the mean pollution levels of the eight elements as follows:Zn>Cd>Ni>Pb>Cu>Cr>Hg>As,with Cd and Zn showing the most severe contamination,and 51.28%of the samples exhibiting moderate or higher pollution levels.The Nemerow comprehensive pollution index evaluation showed that 74.35%of soil samples were classified as moderate to heavy pollution.The potential ecological risk index assessment indicated significant ecological risks posed by Cd and Zn,with 82.05%and 5.12%of the samples classified as causing strong to extreme ecological risks,respectively.The source apportionment analysis revealed minor differences between the two models.The APCS-MLR model identified three pollution sources and their contribution rates:anthropogenic mining sources(31.13%),parent material sources(40.38%),and unidentified sources(28.49%).The PMF model identified three pollution sources with contribution rates of anthropogenic mining sources(26.10%),parent material sources(46.96%),and a combined traffic and agricultural source(26.61%).Pb,Hg,Cd,and Zn mainly originated from mining activities;Cr,As,and Ni were primarily derived from the parent material,while Cu was predominantly attributed to traffic and agricultural sources.These findings provide a scientific basis for the prevention and control of heavy metal pollution in mining areas.展开更多
Pharmaceuticals and personal care products(PPCPs)are receiving attention as emerging pollutants due to their extensive applications and persistent emissions.The Qiantang River Basin,a representative region in eastern ...Pharmaceuticals and personal care products(PPCPs)are receiving attention as emerging pollutants due to their extensive applications and persistent emissions.The Qiantang River Basin,a representative region in eastern China that relies on surface water for drinking purposes,experiences the movement and accumulation of PPCPs in its water and sediment,which can directly affect the safety of drinking water in the basin.This study focuses on the Qiantang River Basin’s surface water,sediment,and drinking water to determine the occurrence and potential risks of 31 PPCPs.It aims to address whether PPCPs in the environment could migrate and accumulate,thereby affecting human health.The findings indicated that PPCPs are ubiquitous in various environmental media,with surface and pore water showing distinct spatial distribution characteristics,specifically,concentrations escalated with urban scale expansion,indicating that domestic sewage discharge is the primary source of PPCP input.Bisphenol A(BPA),ketoprofen(KTP),and diethyltoluamide(DEET)were the primary contaminants.The movement of PPCPs within the surface water-sediment-pore water system was affected by various circumstances.Substances like Sulfamethoxazole(SMX)(RQ>103)and KTP(RQ=22.3)present in surface water and sediment pose significant ecological concerns,and KTP and atrazine(ATZ)(0.6<RQ<2.1)also pose a high risk in drinking water.This study performed an extensive analysis of the distribution and risks associated with typical PPCPs in the Qiantang River Basin,offering a scientific foundation and theoretical support for research on the environmental behavior of PPCPs in this area and the development of targeted pollution control strategies.展开更多
Curcuma is a traditional Chinese medicine that has been utilized for centuries in the treatment of various diseases. Terpenoids, particularly monoterpenes and sesquiterpenes, constitute the primary bioactive component...Curcuma is a traditional Chinese medicine that has been utilized for centuries in the treatment of various diseases. Terpenoids, particularly monoterpenes and sesquiterpenes, constitute the primary bioactive components of the essential oil derived from Curcuma species.Among these, curdione—one of the key active constituents—has been identified in 25 Curcuma species, with the highest concentration reported in the rhizome essential oil of Curcuma trichosantha Gagnep. Curdione can also be synthesized through chemical methods,and its regio-and stereo-selectivity can be further optimized via chemo-bio transformations.This compound demonstrates significant therapeutic potential, including anticancer, antithrombotic, anti-inflammatory, anti-viral, anti-fungal, anti-diabetic, and multi-organ protective properties. Despite these promising biological activities, its clinical application is hindered by poor water solubility and potential toxicity. This review summarizes current knowledge on the natural sources, chemical synthesis, chemo-bio transformations, metabolism, pharmacokinetics, pharmacological effects, potential toxicities, and molecular mechanisms of curdione. Furthermore, perspectives on future drug development are discussed with the aim of promoting the clinical translation of this promising natural compound.展开更多
Soil erosion is a fundamental physical process driving land degradation across various spatial and temporal scales.The Soil and Water Assessment Tool(SWAT)model is a robust tool for predicting soil erosion and evaluat...Soil erosion is a fundamental physical process driving land degradation across various spatial and temporal scales.The Soil and Water Assessment Tool(SWAT)model is a robust tool for predicting soil erosion and evaluating water and soil quality within watersheds.The latest version,SWAT+,introduces advanced encoding capabilities and improved performance,making it better suited for addressing complex watershed modeling challenges.This study implemented the SWAT+model to quantify soil erosion rates within the Chehelchay watershed in northern Iran.The foundational dataset comprises a 30-meter resolution Digital Elevation Model(DEM),land use classification,soil,and weather data.Model performance was evaluated using Nash-Sutcliffe Efficiency(NSE),coefficient of determination(R^(2)),root mean square error(RMSE),and percent bias(PBIAS).The SWAT+simulation revealed substantial spatial variation in erosion patterns across the watershed,with annual sediment yields in critical HRUs,reflecting diverse erosion intensities driven by variations in land use,soil characteristics,and slope.Among the Hydrological Response Units(HRUs),50 critical units,representing approximately 9%of the total watershed area,generate sediment yields exceeding 5 tons per hectare per year.The most severe erosion occurs predominantly in the central zone of the watershed.Downstream regions exhibit minimal soil loss due to gentle topography while upstream areas maintain soil stability through protective forest cover,resulting in negligible erosion rates.Best Management Practices(BMPs)were designed to safeguard water and soil resources at a watershed level.The study evaluated three strategic conservation interventions:alfalfa cultivation,agroforestry implementation,and garden development.When applied in combination,these measures achieved approximately 30%reduction in sediment yield at the HRU level.This integrated approach demonstrates the potential of combining multiple land management strategies to combat erosion effectively.展开更多
With the legislative development,the organic and inorganic composition separation has become the primary requirement for sewer sediment disposal,however the relevant technology has been rarely reported and the driving...With the legislative development,the organic and inorganic composition separation has become the primary requirement for sewer sediment disposal,however the relevant technology has been rarely reported and the driving mechanism was still unclear.In this study,direct disintegration of biopolymers and indirect broken of connection point were investigated on the hydrolysis and component separation.Three typical sewer sediment treatment approaches,i.e.,alkaline,thermal and cation exchange treatments were proposed,which represented the hydrolysis-driving forces of chemical hydrolysis,physical hydrolysis and innovative cation bridging break-age.The results showed that the organic and inorganic separation rates of sewer sediment driven by alkaline,thermal and cation exchange treatments reached 21.26%,23.80%,and 19.56%-48.0%,respectively,compared to 4.43%in control.The secondary structure of proteins was disrupted,transitioning from𝛼α-helix to𝛽β-turn and random coil.Meanwhile,much biopolymers were released from solid to the liquid phase.From thermody-namic perspective,sewer sediment deposition was controlled by short-range interfacial interactions described by extended Derjaguin-Landau-Verwey-Overbeek theory.Additionally,the separation of organic and inorganic components was positively correlated with the thermodynamic parameters(Corr=0.87),highlighted the robust-ness of various driving forces.And the flocculation energy barriers were 2.40(alkaline),1.60 times(thermal),and 4.02–4.97 times(cation exchange)compared to control group.The findings revealed the contrition differ-ence of direct disintegration of gelatinous biopolymers and indirect breakage of composition connection sites in sediment composition separation,filling the critical gaps in understanding the specific mechanisms of sediment biopolymer disintegration and intermolecular connection breakage.展开更多
The present study investigated the effects of varying protein source combinations and feeding strategies on the growth,health and organoleptic quality of the large yellow croaker(Larimichthys crocea).Three iso-nitroge...The present study investigated the effects of varying protein source combinations and feeding strategies on the growth,health and organoleptic quality of the large yellow croaker(Larimichthys crocea).Three iso-nitrogenous and iso-lipidic diets were formulated.The control diet was made with 62%fish meal(FM).The other two experimental diets were formulated by replacing 45%FM with 22.5%mealworm(TM)and 22.5%cottonseed protein concentrate(CPC),or with 22.5%TM and 22.5%Clostridium autoethanogenum protein(CAP),respectively.The three kinds of diet were named as A1,A2 and A3,respectively.Five groups of large yellow croaker were fed with two different strategies:the first three groups were continuously fed with A1,A2 and A3 diets,respectively.The fourth group was alternately fed with A1 and A2 diet every 5 days.The fifth group was alternately fed with A1 and A3diet every 5 days.The five groups were named D1,D2,D3,D1-2 and D1-3,respectively.Results showed that D2 and D3 groups exhibited significantly lower weight gain rate(WGR)and higher feed conversion ratios(FCR)compared to the D1 group.The D1-2 and D1-3 groups exhibited improved WGR and significantly reduced FCR compared to the D2 and D3 groups.The A2 and A3 diets significantly suppressed digestive enzymes'activities compared to A1,whereas alternate-feeding groups significantly enhanced the enzyme activities.Compared to the D1 group,D2 and D3 groups significantly downregulated mRNA expression levels of intestinal antiinflammatory cytokines and upregulated the expression of pro-inflammatory mediators.The anti-inflammatory abilities in the D1-2and D1-3 groups were significantly higher than those in the D2 and D3 groups.Additionally,diets containing TM+CAP and TM+CPC protein sources enhanced ventral redness and yellowness indices.Considering the growth,digestion,immunity and organoleptic quality of large yellow croaker,it is recommended to replace up to 45%of FM with TM+CPC and use an alternate-feeding strategy.展开更多
Organic-rich sediments represent vital components of Earth's geochemical cycles, acting both as potential hydrocarbon and coal reservoirs and as unconventional archives for critical metals such as rare earth eleme...Organic-rich sediments represent vital components of Earth's geochemical cycles, acting both as potential hydrocarbon and coal reservoirs and as unconventional archives for critical metals such as rare earth elements(REEs). With the growing emphasis on clean energy technologies, the Cenozoic organic deposits of India have gained renewed significance;however, those from the southern state of Kerala remain understudied. This study investigates lignite and associated carbonaceous sediments from the Cheruvathur and Warkalli Formations using a multi-proxy approach integrating organic petrography,infrared spectroscopy, stable carbon isotopes, and REE geochemistry. The lignite exhibits huminite dominance with Type Ⅲ kerogen, deposited in a wet, mesotropic bog forest swamp under anoxic conditions. The mineral assemblage, dominated by kaolinite, quartz, illite, montmorillonite, feldspar,and pyrite/marcasite, reflects strong chemical alteration in a reducing environment. The δ^(13)C values(-25.1 to-27.3) indicate a C_(3) angiosperm source and deposition in tropical to subtropical swamp settings. REE patterns reveal LREE enrichment in carbonaceous shales and HREE enrichment in lignite,with distinct Ce, Eu, and Gd anomalies associated with provenance and redox conditions. The findings provide new insights into the paleoenvironmental evolution of Kerala's Cenozoic basins and highlight their potential as unconventional REE-bearing resources in the context of the global energy transition.展开更多
Presented in this study is a novel method for estimating the depth of single underwater source in shallow water,utilizing vector sensors.The approach leverages the depth distribution of the broadband Stokes parameters...Presented in this study is a novel method for estimating the depth of single underwater source in shallow water,utilizing vector sensors.The approach leverages the depth distribution of the broadband Stokes parameters to estimate source depth accurately.Unlike traditional matched field processing(MFP)and matched mode processing(MMP),the proposed approach can estimate source depth directly from the data received by sensors without requiring complete environmental information.Firstly,the broadband Stokes parameters(BSP)are established using the normal mode theory.Then the nonstationary phase approximation is used to simplify the theoretical derivation,which is necessary when dealing with broadband integrals.Additionally,range terms of the BSP are eliminated by normalization.By analyzing the depth distribution of the normalized broadband Stokes parameters(NBSP),it is found that the NBSP exhibit extreme values at the source depth,which can be used for source depth estimation.So the proposed depth estimation method is based on searching the peaks of the NBSP.Simulations show that this method is effective in relatively simple shallow water environments.Finally,the effect of source range,frequency bandwidth,sound speed profile(SSP),water depth,and signal-to-noise ratio(SNR)are studied.The findings indicate that the proposed method can accurately estimate the source depth when the SNR is greater than-5 d B and does not need to consider model mismatch issues.Additionally,variations in environmental parameters have minimal impact on estimation accuracy.Compared to MFP,the proposed method requires a higher SNR,but demonstrates superior robustness against fluctuations in environmental parameters.展开更多
基金Supported by the National Natural Science Foundation of China(Nos.42376185,41876111)the Shandong Provincial Natural Science Foundation(No.ZR2023MD073)。
文摘Benthic habitat mapping is an emerging discipline in the international marine field in recent years,providing an effective tool for marine spatial planning,marine ecological management,and decision-making applications.Seabed sediment classification is one of the main contents of seabed habitat mapping.In response to the impact of remote sensing imaging quality and the limitations of acoustic measurement range,where a single data source does not fully reflect the substrate type,we proposed a high-precision seabed habitat sediment classification method that integrates data from multiple sources.Based on WorldView-2 multi-spectral remote sensing image data and multibeam bathymetry data,constructed a random forests(RF)classifier with optimal feature selection.A seabed sediment classification experiment integrating optical remote sensing and acoustic remote sensing data was carried out in the shallow water area of Wuzhizhou Island,Hainan,South China.Different seabed sediment types,such as sand,seagrass,and coral reefs were effectively identified,with an overall classification accuracy of 92%.Experimental results show that RF matrix optimized by fusing multi-source remote sensing data for feature selection were better than the classification results of simple combinations of data sources,which improved the accuracy of seabed sediment classification.Therefore,the method proposed in this paper can be effectively applied to high-precision seabed sediment classification and habitat mapping around islands and reefs.
基金supported by the National Natural Science Foundation(Nos.52000024 and 41907335)the Natural Science Foundation of Shanghai(No.23ZR1400700).
文摘The arsenic(As)release from sediments in great lakes is affected by various factors.In this study,the characteristics of As release fromsediments was investigated,and the As sources and sinks with the strengths in sediments from different areas(grass-type,algae-type,and grass-algae alternation areas)in great shallow lakes(Taihu Lake,China)were analyzed,and the influence of P competition in the process of As release was also studied.The results showed that changing trend of the values of equilibrium As concentration in sediments were consistent with the regional changes(0 to 28.12μg/L),and the sediments from algaetype areas had the higher values.The sediments from western lake and northwest lake bay were a strong As and a weak P source,and the north lake bay had the opposite trend of these two regions.Intense P source competition with As from the sediments occurred in algae-type areas.The grass-type areas had strong As and P retention capacities,indicating a sink role of sediment with high As and P sorption capacities.The degree of As and P saturation had similar trend in sediments,and the grass-type areas had the higher values,18.3%-21.4%and 15.31%-20.34%,respectively.Contribution analysis results showed that most of As release contribution was from the bottom(30-50 cm)sediments,and the surface(0-10 cm)sediments from algae-type areas contributed more to the overlying water than other region.
基金the Natural Science Key Foundation of Fujian ProvinceChina(No.2020J02002)+4 种基金the Hainan Province Science and Technology Special Fund(No.ZDYF2022SHFZ317)the National Natural Science Foundation of China(Nos.U2005207,41976216,41776088,42106224)the Norwegian Institute of FoodFishery and AquacultureGovernance of Marine Plastic Litter in the Arctic。
文摘Microplastic(MP)contamination is becoming a major worldwide concern,affecting terrestrial and aquatic ecosystems.This study investigated the source,distribution,and abundance of MPs in sediments from Dongshan Bay,Fujian,South China,emphasizing particularly the coastline region's susceptibility to tidal impacts in four study sites.The concentrations of MPs in the sediments in the four sites were high from 7.4 to 283.1 items/kg(dry weight).There were notable differences in abundance between the locations and tide levels.Tides influenced the distribution of MPs greatly;however,the estuary areas showed greater MPs abundance during high tide,due possibly to enhanced water turbulence and riverine inputs.Low tide indicated higher concentrations in coastal locations owing to accumulation.Popular varieties,including nylon,polypropylene,and polyethylene,were identified by polymer research,pointing to the origins from fishing,packaging,and mariculture industries.Potential sources were determined using the PCA-K-means statistical analysis,by linking the origins of MPs to domestic activities,fishing,mariculturing,shipping,and packing.Fishing and packing were shown in the Sankey diagram as the two main sources,but their effects varied with research locations and tidal regimes.This study clarified the intricate dynamics of MPs pollution,highlighting the impact of tides on its dispersal and the variety of sources that contribute to this widespread environmental problem in coastal areas.
基金funded by the Basic Research Program of Qinghai Province(2023-ZJ-910M)。
文摘This study investigates the distribution,geochemical behavior,and potential anthropogenic influences of rare earth elements(REEs)in the surface sediments of Qinghai Lake,the largest saline lake in China.A total of 36 surface sediment samples were analyzed for REE concentrations with a combination of self-organizing maps(SOM)and positive matrix factorization(PMF).Results indicate distinct enrichment patterns,with light REEs(LREEs)exhibiting higher concentrations than heavy REEs(HREEs),reflecting natural abundances and geochemical behaviors.The minimum value was found in Lu as low as 0.091 mg/kg,and the maximum concentration was exhibited in Ce at 78.877 mg/kg.Geoaccumulation index(I_(geo))analysis reveals minor to moderate enrichment of specific REEs of Sm and Nd,suggesting possible localized anthropogenic inputs,particularly near river mouths.Spatial analysis using inverse distance weighting(IDW)and self-organizing maps(SOM)highlights significant correlations between REE distributions and riverine inputs,underscoring fluvial transport's role in sedimentary REE dynamics.PMF identifies mixed natural and anthropogenic sources,with agricultural and industrial activities contributing to elevated REE levels in sediment.These findings provide critical insights into the geochemical behavior of REEs in saline lake systems and off er a foundation for pollution control and sustainable resource management in sensitive environments like Qinghai Lake.
基金financially supported by the Key Research and Development Program of Hunan Province,China(No.2023SK2006)the Natural Science Foundation of Hunan Province,China(No.2023JJ50057)+2 种基金the Science and Technology Plan Project of Geological Bureau of Hunan Province,China(No.HNGSTP202411)the Open Project of Key Laboratory of the Ministry of Natural Resources,China(No.BL202105)the Natural Science Foundation of Changsha City,China(No.kq2202090)。
文摘Environmental problems from heavy metals(HMs)attract global attention.Accurately identifying sources and quantitatively evaluating ecological risks are keys for HMs pollution prevention.Dongting Lake in China was investigated through integrated methods like positive matrix factorization and Nemerow integrated risk index to examine spatial distribution,contamination characteristics,pollution sources,and the contribution of each source and pollutant to the ecological risk of 14 HMs in its surface sediments.Results showed that the mean concentrations of HMs were 0.82-9.44 times greater than the corresponding background values.The spatial distribution of HMs varied significantly,with high values of As,Cd,Mn,Pb,Sn,Tl and Zn concentrated in the sediments from Xiangjiang inlet and Yangtze outlet;Co,Cr,Cu,Ni and V in the Lishui sediments;Hg and Sb in the sediments from Yuanjiang and Zishui inlets,respectively.The accumulation of HMs was affected by five sources:mercury mining and atmospheric deposition(F1)(17.99%),urban domestic sewage and industrial sewage discharge(F2)(24.44%),antimony ore mining and smelting(F3)(6.50%),non-ferrous metal mining and extended processing industrial sources(F4)(15.72%),and mixed sources mainly from natural sources and agricultural sources(F5)(35.35%).F1 and F2 were identified as priority pollution sources;Cd,Hg,Tl,Sb and As,especially Cd and Hg,posed relatively high ecological risks and were prioritized HMs for control.
基金The National Natural Science Foundation of China under contract No.42476043the Guangxi Key Research and Development Project under contract No.AB21076016+2 种基金the Scientific Research and Technology Development Project of Qinzhou under contract No.202116623the Natural Science Foundation of Guangxi under contract No.2021GXNSFAA075013the China College Students’Innovation and Entrepreneurship Training Program Project under contract No.S202411607002。
文摘Mangrove forests are critical ecosystems for carbon sequestration,effectively capturing atmospheric carbon and permanently storing soil organic carbon(SOC)in coastal wetlands.Recent restoration and afforestation initiatives have been undertaken to mitigate the rising atmospheric CO_(2) concentrations along tropical ocean coasts worldwide.The expansion of mangrove forests has garnered significant attention for elucidating their contributions to the permanent storage of carbon in both surface and subsoil layers.In this study,we investigated a recently expanding mangrove forest in the Beilun River Estuary of Guangxi Province,focusing on the abundance and sources of organic carbon(OC)in surface sediments.We also analyzed sediment grain size distribution,SOC,total nitrogen(TN)content,and stable carbon isotope composition(δ^(13)C).Additionally,we determined the molar ratio of SOC to nitrogen(C/N).The SOC content ranged from 0.25%to 6.58%,the C/N ratio varied from 9.85 to 17.73,δ^(13)C values spanned from-29.58‰to-24.93‰,andδ^(15)N values ranged from 3.10‰to 7.36‰.A strong correlation was observed between SOC and TN content.However,particle size did not significantly influence these relationships.In terms of SOC sources in the sediments,contributions from mangrove,terrestrial,and marine sources accounted for 37.1%to 99.5%,0.5%to 47.4%,and 0%to 17.6%,respectively.The findings of this study provide essential insights for evaluating and managing carbon sinks within the mangrove ecosystems of the Beibu Gulf region,contributing to more effective carbon management strategies in coastal areas.
基金financially supported by the Qinghai University Graduate Student Research and Practice Innovation Project(2025-GPKY-12)Basic Research Project of Qinghai Provincial Science and Technology Department(2021-ZJ-701)+1 种基金National Natural Science Foundation of China(U23A20159,42161068)the 111 Project of China(D18013)。
文摘The mound-making behavior of plateau zokors is one of the most important factors in remodeling meadow microtopography and causing soil erosion in the Yellow River source area of western China,but little is known about the effects of microtopography on particle size characteristics(PSC)of eroded sediments from the bare slopes of zokor mounds during different rainfall events.In this study,we analyzed the relationship of microtopographic features derived from laser point cloud data and PSC of eroded sediments at six simulated rainfall intensities(all lasting 60 min).The effects of microtopography on PSC of eroded sediments were studied via partial least squares regression(PLSR)and structural equation modeling(SEM).The results showed that:(1)15-20 minutes from the beginning of rainfall was the sensitive period of soil loss from the slopes,and the function relationship between the rate of sediment and runoff and rainfall intensity can better predict the development trend of soil erosion;(2)Intense erosion occurred mainly in the upper half of the zokor mound,while deposition was mainly limited to its lower half.It is suggested that diminished plateau zokor activity intensity can effectively prevent and control soil erosion;(3)The PSC of eroded sediment is dominated by silt,followed by sand,with clay being the least abundant,and the eroded sediments with a particle size of 10-20μm were sensitive and highly susceptible to rainfall erosion.This finding facilitates the understanding of the formation process of surface geomorphology and the mechanism of soil erosion;(4)The PLSR model indicates that microtopography has an extensive influence on eroded sediments during hydraulic erosion,and the SEM analysis results further confirm that the fractal dimension was the best parameter to represent the PSC of eroded sediments,whereas surface cutting degree was the dominant factor controlling the PSC of eroded sediments.These findings are crucial for predicting soil erosion in the Yellow River source area and provide a new perspective for understanding soil erosion mechanisms in alpine meadow ecosystems.
基金supported by the Hunan Provincial Natural Science Foundation of China(Nos.2023JJ40518 and 2023JJ30490)the Scientific Research Foundation of Hunan Provincial Education Department(Nos.21B0511 and 22A0384)the Research Funding Project of Jishou University for talent introduction.
文摘Fluoroquinolones(FQs)have the propensity to accumulate in sediments once introduction into aquatic envi-ronments,thereby posing potential threats to benthic organisms,yet the ecotoxicity of sediment-associated FQs remains unclear.In this study,the toxicokinetics and responses of multiple biomarkers in Bellamya aeruginosa,exposed to the three commonly used FQs(norfloxacin,NOR;ciprofloxacin,CIP;levofloxacin,LEVO)at envi-ronmentally relevant concentrations were investigated under sediment exposure scenario.The results revealed that FQs were effectively ingested by B.aeruginosa from sediments,CIP showing the highest bioaccumulation(180.59μg/kg),followed by NOR(74.49μg/kg)and LEVO(36.02μg/kg).CIP exhibiting a highest uptake rate constant(Ks)(4.64 g/(g·day))and the lowest elimination rate constant(K_(e))(0.05 g/(g·day)).The descending order of biological half-life is as follows:CIP(13.62 days),LEVO(8.14 days),and NOR(6.83 days).NOR induced the activity of superoxide dismutase,catalase,and glutathione-S-transferase while CIP and LEVO depressed their activities and increased malondialdehyde content,indicating a more pronounced oxidative damage to B.aerug-inosa caused by CIP and LEVO than NOR.Furthermore,all three FQs were found to induce DNA damage and elevate acetylcholinesterase activity,suggesting distinct genotoxic and neurotoxic effects.Interestingly,despite its low bioaccumulation potential,LEVO exhibited high toxicity towards B.aeruginosa.These findings enhance our understanding of the ecotoxicity of FQs in sediments,providing further evidence of their potential ecological risks.
文摘Noncohesive particle clusters are identified and tracked in turbulent flows to determine the breakdown and time evolution of cluster statistics and their implications for interscale mass transfer,which has connections to the classical turbulent energy cascade and its mass cascade counterpart running in parallel.In particular,the formation and dynamics of sediment and larvae clusters are of interest to coral larvae settlement in coastal regions and particularly the resilience of green-gray coastal protection solutions.Analogous cluster behavior is relevant to cloud microphysics and precipitation initiation,radiation transport and light transmission through colloids and suspensions,heat and mass transfer in particle-laden flows,and viral and pollutant transmission.Following a comparison between various clustering techniques,we adopt a density-based cluster identification algorithm based on its simplicity and efficiency,where particles are clustered based on the number of neighboring particles in their individual spheres of influence.We establish parallels with lattice-based percolation theory,as evident in the power-law scaling of the cluster size distribution near the percolation threshold.The degree of discontinuity of the phase transition associated with this percolation threshold is observed to broaden with larger Stokes numbers and thereby large-scale clustering.The sensitivity of our findings to the employed clustering algorithm is discussed.A novel cluster tracking algorithm is deployed to determine the interscale transfer rate along the particle-number phase-space dimension via accounting of cluster breakup and merger events,extending previous work on the bubble breakup cascade beneath surface breaking waves.Our findings shed light on the interaction between particle clusters and their carrier turbulent flows,with an eye toward transport models incorporating cluster characteristics and dynamics.
基金The Laoshan Laboratory Project under contract No.LSKJ202204103the National Natural Science Foundation of China under contract Nos 41322036 and 41776070+1 种基金the Qingdao Postdoctoral Sustentation Foundation under contract No.QDBSH20220202147the Taishan Scholarship from Shandong Province under contract No.tstp20230643.
文摘Subducted sediments,as an integral part of subducted slab,can strongly influence the chemistry of volcanic arc lavas,and clarify the relationship between subduction input and arc output,which is the focus of the subduction factory theory in the context of plate tectonics.In this study,we analyzed major and trace element compositions of the subducting sediments from two sites[Deep Sea Drilling Program(DSDP)Site 495 and Ocean Drilling Program(ODP)Site 1039]at the different locations along the Middle America Trench.The results showed that the sediments from these two sites are mainly composed of terrigenous material,carbonate components,and biogenic silicate in different proportions.In order to reduce the effects of the variations in subduction topography on the chemical composition of sediments,we recalculated the bulk subducted sediment composition at northern and southern Central America subduction zone,and identified the Nicaragua Fracture Zone as the dividing line for northern and southern subducting sediments at Middle America Trench.Compared to the global trench subducting sediment,both the subducting sediments from northern and southern Central America subduction zone exhibit lower contents of terrigenous material-controlled elements and are more enriched in the biogenic components-controlled elements.We suggested that the variations in both chemical compositions for sediments and subduction angles are responsible for the different contributions of subducting sediments to volcanic arc magmatism in the northern Central America.
基金jointly supported by the National Natural Science Foundation of China (42204061)Special Fund for Basic Research Operations of the Institute of Geophysics,China Earthquake Administration (0419501)+1 种基金the Gansu Jishishan6.2 magnitude earthquake scientific investigation (DQJB23Y45) programthe Sichuan Provincial Natural Science Foundation (2023NSFSC0768,2023NSFSC0770)。
文摘Reliable thickness of sedimentary layers is essential for seismic hazard assessment in active fault zones, especially in regions prone to strong earthquakes. This study analyzed the seismic ambient noise data recorded by 60 short-period seismic stations deployed at the Jishishan earthquake source and adjacent areas. The base-order resonance frequencies of sedimentary layers beneath the stations were determined using the horizontal-to-vertical spectral ratio method on ambient noise with diff erent frequencies. Then, a resonance-thickness formula was applied to estimate the sedimentary layer thickness at each station. Finally, the entire regional sediment thickness was obtained via interpolation. The thickness of the sedimentary layer beneath each station was estimated using the equation of the relationship between resonance frequency and sedimentary layer thickness, and fi nally, the distribution of sedimentary layer thickness in the whole region was obtained by interpolation. Results reveal notable spatial variations in sediment thickness in the source and adjacent areas. The shallow sedimentary layer in the source area is relatively thick at approximately 100 m, whereas that in Liugou Village, which is the most severely damaged area, is approximately 150-180 m. In the western region, specifically along the western edge of the Jishishan Mountain rupture and the Pourouliuhe-Cheunhua Nanshan rupture zone, the shallow sedimentary layer is approximately 30-60 m. A comparison between the distribution of seismic secondary hazards and sedimentary layer thickness highlights a strong correlation between these hazards and the amplifi cation eff ects of seismic waves. In regions with thicker sedimentary layers, ground shaking is signifi cantly amplifi ed, resulting in more serious seismic secondary hazards. In addition, the study confi rmed that secondary hazards, such as landslides and liquefaction, were more prevalent in regions with thicker sedimentary layers. These fi ndings provide an important reference for post-earthquake reconstruction, seismic risk assessment, and the development of regional disaster prevention and mitigation strategies..
文摘This study investigated the hydrocarbon source rock potential of the Late Cretaceous Mamu and Nkporo formations in the Asaga-Ohafia Axis,Afikpo Basin,southeastern Nigeria,using integrated facies analysis,organic geochemical and palynofacies data.Five lithofacies were identified:dark grey shale,oolitic limestone,heterolithic mudstone/sandstone,laminated bioturbated sandstone,and calcareous mudstone,indicating estuarine,deltaic,and shallow marine depositional environments.Total organic carbon(TOC) contents range from 1.47 to 2.40 wt%,which reflects moderate to good organic richness.For the Mamu Formation,kerogen composition is dominated by Type Ⅱ/Ⅲ,composed of 30 %-50 %amorphous organic matter(AOM),5 %-10 % liptinite,30 %-50 % vitrinite,and 10 %-20 % inertinite.Spore coloration and Thermal Alteration Index(TAI:3-3+) suggest thermal maturity within the oil window(Ro:0.80 %-1.50 %).In contrast,the Nkporo Formation shows comparable kerogen composition(20 %-45 % AOM,0-20 % liptinite,and 40 %-65 % vitrinite) but lower maturity(TAI:2-2+;Ro:0.45 %-0.80 %).Rock-Eval pyrolysis further supports these findings.The Mamu Formation displays higher Hydrogen Index,favorable Tmax,and Production Index values,confirming its maturity and oil and gas-prone potential.Palynological assemblages,including marine dinoflagellate cysts(Mamu Formation) and freshwater algae/fungal spores(Nkporo Formation),align with the inferred depositional settings.Thus,the Mamu Formation is the more prolific source rock,characterized by superior organic quality and thermal maturity.
文摘39 soil samples surrounding a lead-zinc mining area in Guangxi were collected,and the contents of Pb,Hg,Cd,Cr,As,Cu,Zn,and Ni were determined to investigate the pollution characteristics and sources of heavy metals.ArcGIS inverse distance weight difference method was used to analyze the characteristics of pollution distribution,and single-factor pollution index,Nemerow comprehensive pollution index,ground accumulation index,and potential ecological risk index were selected to evaluate the characteristics of heavy metal pollution.Based on correlation analysis,the absolute principal component-multiple linear regression(APCS-MLR)and positive definite matrix factorization(PMF)models were used to analyze the sources of soil heavy metals.The results showed that the average concentrations of all eight heavy metals exceeded both national and Guangxi soil background values.Hg,Cd,and Zn exhibited high variation(greater than 0.5),indicating significant external disturbances,and their spatial distribution was closely related to mining activity locations.The single-factor pollution index evaluation indicated varying degrees of pollution risk for Cd,Zn,and As,with Cd and Zn being the most severe pollutants,as 69.23%and 30.77%of the samples fell into the moderate pollution or higher category.The geoaccumulation index analysis ranked the mean pollution levels of the eight elements as follows:Zn>Cd>Ni>Pb>Cu>Cr>Hg>As,with Cd and Zn showing the most severe contamination,and 51.28%of the samples exhibiting moderate or higher pollution levels.The Nemerow comprehensive pollution index evaluation showed that 74.35%of soil samples were classified as moderate to heavy pollution.The potential ecological risk index assessment indicated significant ecological risks posed by Cd and Zn,with 82.05%and 5.12%of the samples classified as causing strong to extreme ecological risks,respectively.The source apportionment analysis revealed minor differences between the two models.The APCS-MLR model identified three pollution sources and their contribution rates:anthropogenic mining sources(31.13%),parent material sources(40.38%),and unidentified sources(28.49%).The PMF model identified three pollution sources with contribution rates of anthropogenic mining sources(26.10%),parent material sources(46.96%),and a combined traffic and agricultural source(26.61%).Pb,Hg,Cd,and Zn mainly originated from mining activities;Cr,As,and Ni were primarily derived from the parent material,while Cu was predominantly attributed to traffic and agricultural sources.These findings provide a scientific basis for the prevention and control of heavy metal pollution in mining areas.
基金jointly supported by the Open Research Fund of State Environmental Protection Key Laboratory of Drinking Water Source Protection,Chinese Research Academy of Environmental Sciences(2022YYSYKFYB07)the Fundamental Research Funds for the Central Publicinterest Scientific Institution(2022YSKY-07)the China Geological Survey Project(DD20211414).
文摘Pharmaceuticals and personal care products(PPCPs)are receiving attention as emerging pollutants due to their extensive applications and persistent emissions.The Qiantang River Basin,a representative region in eastern China that relies on surface water for drinking purposes,experiences the movement and accumulation of PPCPs in its water and sediment,which can directly affect the safety of drinking water in the basin.This study focuses on the Qiantang River Basin’s surface water,sediment,and drinking water to determine the occurrence and potential risks of 31 PPCPs.It aims to address whether PPCPs in the environment could migrate and accumulate,thereby affecting human health.The findings indicated that PPCPs are ubiquitous in various environmental media,with surface and pore water showing distinct spatial distribution characteristics,specifically,concentrations escalated with urban scale expansion,indicating that domestic sewage discharge is the primary source of PPCP input.Bisphenol A(BPA),ketoprofen(KTP),and diethyltoluamide(DEET)were the primary contaminants.The movement of PPCPs within the surface water-sediment-pore water system was affected by various circumstances.Substances like Sulfamethoxazole(SMX)(RQ>103)and KTP(RQ=22.3)present in surface water and sediment pose significant ecological concerns,and KTP and atrazine(ATZ)(0.6<RQ<2.1)also pose a high risk in drinking water.This study performed an extensive analysis of the distribution and risks associated with typical PPCPs in the Qiantang River Basin,offering a scientific foundation and theoretical support for research on the environmental behavior of PPCPs in this area and the development of targeted pollution control strategies.
基金supported by the National Natural Science Foundation of China (Nos. 82192913 and 82304851)the Scientific and Technological Innovation Project of China Academy of Chinese Medical Sciences (Nos. CI2023E002, CI2021B016, and CI2021A04801)the Fundamental Research Funds for the Central Public Welfare Research Institutes (Nos. ZZ13-YQ-055 and ZXKT22044)。
文摘Curcuma is a traditional Chinese medicine that has been utilized for centuries in the treatment of various diseases. Terpenoids, particularly monoterpenes and sesquiterpenes, constitute the primary bioactive components of the essential oil derived from Curcuma species.Among these, curdione—one of the key active constituents—has been identified in 25 Curcuma species, with the highest concentration reported in the rhizome essential oil of Curcuma trichosantha Gagnep. Curdione can also be synthesized through chemical methods,and its regio-and stereo-selectivity can be further optimized via chemo-bio transformations.This compound demonstrates significant therapeutic potential, including anticancer, antithrombotic, anti-inflammatory, anti-viral, anti-fungal, anti-diabetic, and multi-organ protective properties. Despite these promising biological activities, its clinical application is hindered by poor water solubility and potential toxicity. This review summarizes current knowledge on the natural sources, chemical synthesis, chemo-bio transformations, metabolism, pharmacokinetics, pharmacological effects, potential toxicities, and molecular mechanisms of curdione. Furthermore, perspectives on future drug development are discussed with the aim of promoting the clinical translation of this promising natural compound.
文摘Soil erosion is a fundamental physical process driving land degradation across various spatial and temporal scales.The Soil and Water Assessment Tool(SWAT)model is a robust tool for predicting soil erosion and evaluating water and soil quality within watersheds.The latest version,SWAT+,introduces advanced encoding capabilities and improved performance,making it better suited for addressing complex watershed modeling challenges.This study implemented the SWAT+model to quantify soil erosion rates within the Chehelchay watershed in northern Iran.The foundational dataset comprises a 30-meter resolution Digital Elevation Model(DEM),land use classification,soil,and weather data.Model performance was evaluated using Nash-Sutcliffe Efficiency(NSE),coefficient of determination(R^(2)),root mean square error(RMSE),and percent bias(PBIAS).The SWAT+simulation revealed substantial spatial variation in erosion patterns across the watershed,with annual sediment yields in critical HRUs,reflecting diverse erosion intensities driven by variations in land use,soil characteristics,and slope.Among the Hydrological Response Units(HRUs),50 critical units,representing approximately 9%of the total watershed area,generate sediment yields exceeding 5 tons per hectare per year.The most severe erosion occurs predominantly in the central zone of the watershed.Downstream regions exhibit minimal soil loss due to gentle topography while upstream areas maintain soil stability through protective forest cover,resulting in negligible erosion rates.Best Management Practices(BMPs)were designed to safeguard water and soil resources at a watershed level.The study evaluated three strategic conservation interventions:alfalfa cultivation,agroforestry implementation,and garden development.When applied in combination,these measures achieved approximately 30%reduction in sediment yield at the HRU level.This integrated approach demonstrates the potential of combining multiple land management strategies to combat erosion effectively.
基金supported by Shaanxi Key Research and Development Program(No.2024SF-YBXM-546)the National Natural Science Foundation of China(No.52470161)the State Key Laboratory of Pollution Control and Resource Reuse Foundation(No.PCRRF21007).
文摘With the legislative development,the organic and inorganic composition separation has become the primary requirement for sewer sediment disposal,however the relevant technology has been rarely reported and the driving mechanism was still unclear.In this study,direct disintegration of biopolymers and indirect broken of connection point were investigated on the hydrolysis and component separation.Three typical sewer sediment treatment approaches,i.e.,alkaline,thermal and cation exchange treatments were proposed,which represented the hydrolysis-driving forces of chemical hydrolysis,physical hydrolysis and innovative cation bridging break-age.The results showed that the organic and inorganic separation rates of sewer sediment driven by alkaline,thermal and cation exchange treatments reached 21.26%,23.80%,and 19.56%-48.0%,respectively,compared to 4.43%in control.The secondary structure of proteins was disrupted,transitioning from𝛼α-helix to𝛽β-turn and random coil.Meanwhile,much biopolymers were released from solid to the liquid phase.From thermody-namic perspective,sewer sediment deposition was controlled by short-range interfacial interactions described by extended Derjaguin-Landau-Verwey-Overbeek theory.Additionally,the separation of organic and inorganic components was positively correlated with the thermodynamic parameters(Corr=0.87),highlighted the robust-ness of various driving forces.And the flocculation energy barriers were 2.40(alkaline),1.60 times(thermal),and 4.02–4.97 times(cation exchange)compared to control group.The findings revealed the contrition differ-ence of direct disintegration of gelatinous biopolymers and indirect breakage of composition connection sites in sediment composition separation,filling the critical gaps in understanding the specific mechanisms of sediment biopolymer disintegration and intermolecular connection breakage.
基金financially supported by the Key Research and Development Program of Shandong,China(No.2021SFGC0701)。
文摘The present study investigated the effects of varying protein source combinations and feeding strategies on the growth,health and organoleptic quality of the large yellow croaker(Larimichthys crocea).Three iso-nitrogenous and iso-lipidic diets were formulated.The control diet was made with 62%fish meal(FM).The other two experimental diets were formulated by replacing 45%FM with 22.5%mealworm(TM)and 22.5%cottonseed protein concentrate(CPC),or with 22.5%TM and 22.5%Clostridium autoethanogenum protein(CAP),respectively.The three kinds of diet were named as A1,A2 and A3,respectively.Five groups of large yellow croaker were fed with two different strategies:the first three groups were continuously fed with A1,A2 and A3 diets,respectively.The fourth group was alternately fed with A1 and A2 diet every 5 days.The fifth group was alternately fed with A1 and A3diet every 5 days.The five groups were named D1,D2,D3,D1-2 and D1-3,respectively.Results showed that D2 and D3 groups exhibited significantly lower weight gain rate(WGR)and higher feed conversion ratios(FCR)compared to the D1 group.The D1-2 and D1-3 groups exhibited improved WGR and significantly reduced FCR compared to the D2 and D3 groups.The A2 and A3 diets significantly suppressed digestive enzymes'activities compared to A1,whereas alternate-feeding groups significantly enhanced the enzyme activities.Compared to the D1 group,D2 and D3 groups significantly downregulated mRNA expression levels of intestinal antiinflammatory cytokines and upregulated the expression of pro-inflammatory mediators.The anti-inflammatory abilities in the D1-2and D1-3 groups were significantly higher than those in the D2 and D3 groups.Additionally,diets containing TM+CAP and TM+CPC protein sources enhanced ventral redness and yellowness indices.Considering the growth,digestion,immunity and organoleptic quality of large yellow croaker,it is recommended to replace up to 45%of FM with TM+CPC and use an alternate-feeding strategy.
文摘Organic-rich sediments represent vital components of Earth's geochemical cycles, acting both as potential hydrocarbon and coal reservoirs and as unconventional archives for critical metals such as rare earth elements(REEs). With the growing emphasis on clean energy technologies, the Cenozoic organic deposits of India have gained renewed significance;however, those from the southern state of Kerala remain understudied. This study investigates lignite and associated carbonaceous sediments from the Cheruvathur and Warkalli Formations using a multi-proxy approach integrating organic petrography,infrared spectroscopy, stable carbon isotopes, and REE geochemistry. The lignite exhibits huminite dominance with Type Ⅲ kerogen, deposited in a wet, mesotropic bog forest swamp under anoxic conditions. The mineral assemblage, dominated by kaolinite, quartz, illite, montmorillonite, feldspar,and pyrite/marcasite, reflects strong chemical alteration in a reducing environment. The δ^(13)C values(-25.1 to-27.3) indicate a C_(3) angiosperm source and deposition in tropical to subtropical swamp settings. REE patterns reveal LREE enrichment in carbonaceous shales and HREE enrichment in lignite,with distinct Ce, Eu, and Gd anomalies associated with provenance and redox conditions. The findings provide new insights into the paleoenvironmental evolution of Kerala's Cenozoic basins and highlight their potential as unconventional REE-bearing resources in the context of the global energy transition.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.12274348 and 12004335)the National Key Research and Development Program of China(Grant No.2024YFC2813800)。
文摘Presented in this study is a novel method for estimating the depth of single underwater source in shallow water,utilizing vector sensors.The approach leverages the depth distribution of the broadband Stokes parameters to estimate source depth accurately.Unlike traditional matched field processing(MFP)and matched mode processing(MMP),the proposed approach can estimate source depth directly from the data received by sensors without requiring complete environmental information.Firstly,the broadband Stokes parameters(BSP)are established using the normal mode theory.Then the nonstationary phase approximation is used to simplify the theoretical derivation,which is necessary when dealing with broadband integrals.Additionally,range terms of the BSP are eliminated by normalization.By analyzing the depth distribution of the normalized broadband Stokes parameters(NBSP),it is found that the NBSP exhibit extreme values at the source depth,which can be used for source depth estimation.So the proposed depth estimation method is based on searching the peaks of the NBSP.Simulations show that this method is effective in relatively simple shallow water environments.Finally,the effect of source range,frequency bandwidth,sound speed profile(SSP),water depth,and signal-to-noise ratio(SNR)are studied.The findings indicate that the proposed method can accurately estimate the source depth when the SNR is greater than-5 d B and does not need to consider model mismatch issues.Additionally,variations in environmental parameters have minimal impact on estimation accuracy.Compared to MFP,the proposed method requires a higher SNR,but demonstrates superior robustness against fluctuations in environmental parameters.
