The aging process is an inexorable fact throughout our lives and is considered a major factor in develo ping neurological dysfunctions associated with cognitive,emotional,and motor impairments.Aging-associated neurode...The aging process is an inexorable fact throughout our lives and is considered a major factor in develo ping neurological dysfunctions associated with cognitive,emotional,and motor impairments.Aging-associated neurodegenerative diseases are characterized by the progressive loss of neuronal structure and function.展开更多
Based on monthly runoff and climate datasets spanning 2000–2024,this study employed the Theil–Sen’s slope estimation,Mann–Kendall(M–K)trend test,as well as Pearson correlation and Spearman rank correlation analys...Based on monthly runoff and climate datasets spanning 2000–2024,this study employed the Theil–Sen’s slope estimation,Mann–Kendall(M–K)trend test,as well as Pearson correlation and Spearman rank correlation analyses to systematically examine the spatiotemporal patterns of runoff and its climatic driving mechanisms across Tajikistan,providing a scientific basis for sustainable water resource utilization and management in the study area.Results indicated that during 2000–2024,the annual runoff in Tajikistan exhibited statistically non-significant long-term trend(P=0.76),while displaying pronounced seasonal variability and strong spatial heterogeneity.Spring and summer average runoff primarily exhibited slight declining tendencies,while winter average runoff exhibited pronounced reduction in localized regions,such as the Syr Darya Basin,the Vakhsh River Basin,and the lower reaches of the Zeravshan River Basin.Precipitation emerged as the dominant positive driver of runoff,exhibiting moderate to strong positive correlations across over 78.00%of the country,whereas potential evapotranspiration consistently functioned as a negative driver.Rising temperatures exerted a dual competitive effect on runoff:in high-elevation,glacier-covered regions,rising temperatures temporarily increased runoff by accelerating glacier melt;however,at the national scale,the negative impact of rising temperature on runoff has played a slightly dominant role to a certain extent by enhancing evapotranspiration.Collectively,these results indicated that the present stability of runoff in Tajikistan is strongly dependent on the short-term compensatory effects of glacier melt and the risk of future runoff decline is likely to intensify as glacier reserves continue to diminish.This study provides a critical scientific evidence to inform sustainable water resource management in Tajikistan and underscores the need for glacier conservation and integrated water resource management strategies.展开更多
In rock engineering,natural cracks in rock masses subjected to external loads tend to initiate and propagate,leading to potential safety hazards.To investigate the effect of cracking behavior on the mechanical propert...In rock engineering,natural cracks in rock masses subjected to external loads tend to initiate and propagate,leading to potential safety hazards.To investigate the effect of cracking behavior on the mechanical properties of rocks,the cracking processes of pre-cracked rocks have been extensively studied using numerical modeling methods.The peridynamics(PD)exhibits advantages over other numerical methods due to the absence of the requirements for remeshing and external crack growth criterion.However,for modeling pre-cracked rock cracking processes under impact,current PD implementations lack generally applicable rock constitutive models and impact contact models,which leads to difficulties in determining rock material parameters and efficiently calculating impact loads.This paper proposes a non-ordinary state-based peridynamics(NOSBPD)modeling method integrating the Drucker-Prager(DP)plasticity model and an efficient contact model to address the above problems.In the proposed method,the Drucker-Prager plasticity model is integrated into the NOSBPD,thereby equipping NOSBPD with the capability to accurately characterize the nonlinear stress-strain relationship inherent in rocks.An efficient contact model between particles and meshes is designed to calculate the impact loads,which is essentially a coupling method of PD with the finite element method(FEM).The effectiveness of the proposed NOSBPD modeling method is verified by comparison with other numerical methods and experiments.Experimental results indicate that the proposed method can effectively and accurately predict the 3D cracking processes of pre-cracked cracks under impact loading,and the maximum principal stress is the key driver behind wing crack formation in pre-cracked rocks.展开更多
Water is the important resource to guarantee the existence and development of oases in arid areas. To improve the utilization efficiency of water resources in Manas River Basin, this paper investigated the trends and ...Water is the important resource to guarantee the existence and development of oases in arid areas. To improve the utilization efficiency of water resources in Manas River Basin, this paper investigated the trends and periods of runoff based on the runoff and climate data for the past 50 years. Subsequently, with the socioeconomic and water resources data, we studied a comprehensive evaluation on the water security in this area. The results indicated that the stream flows in the three hydrological stations of Hongshanzui, Kensiwat and Bajiahu have sig- nificantly increased and undergone abrupt changes, with periods of 18 and 20 years. According to assessment, water security in the Manas River Basin was at an unsafe level in 2008. In criterion layer, the ecological security index and the index of supply-demand situation are both at the relatively secure level; the quantity index and so- cioeconomic index of water resources are at the unsafe level and basic security level, respectively. Therefore, in order to achieve sustainable economic and social development within the Manas River Basin, it is vital to take a series of effective measures to improve the status of water security.展开更多
Hydrological processes were compared, with and without the influence of precipita- tion on discharge, to identify the differences between glacierized and non-glacierized catchments in the Urumqi River source region, o...Hydrological processes were compared, with and without the influence of precipita- tion on discharge, to identify the differences between glacierized and non-glacierized catchments in the Urumqi River source region, on the northern slope of the eastern Tianshan Mountains, during the melting season （May-September） in 2011. The study was based on hydrological data observed at 10-min intervals, meteorological data observed at 15-min intervals, and glacier melting and snow observations from the Empty Cirque, Zongkong, and Urumqi Glacier No.1 gauging stations. The results indicated that the discharge differed markedly among the three gauging stations. The daily discharge was more than the nightly discharge at the Glacier No.1 gauging station, which contrasted with the patterns observed at the Zongkong and Empty Cirque gauging stations. There was a clear daily variation in the discharge at the three gauging stations, with differences in the magnitude and duration of the peak discharge. When precipitation was not considered, the time-lags between the maximum discharge and the highest temperature were 1-3 h, 10-16 h, and 5-11 h at the Glacier No.l, Empty Cirque, and Zongkong gauging stations, respectively. When precipitation was taken into consideration, the corresponding time-lags were 0-1 h, 13 h, and 6-7 h, respectively. Therefore, the duration from the generation of discharge to confluence was the shortest in the glacierized catchment and the longest in the catchment where was mainly covered by snow. It was also shown that the hydrological process from the generation of discharge to confluence shortened when precipitation was considered. The factors influencing changes in the discharge among the three gauging stations were different. For Glacier No.1 station, the discharge was mainly controlled by heat conditions in the glacierized region, and the discharge displayed an accelerated growth when the temperature exceeded 5℃ in the melt season. It was found that the englacial and subglacial drainage channel of Glacier No.1 had become simpler during the past 20 years. Its weaker retardance and storage of glacier melting water resulted in rapid discharge confluence. It was also shown that the discharge curve and the time-lag between the maximum discharge and the highest temperature could be used to reveal the evolution of the drainage system and the process of glacier and snow melting at different levels of glacier coverage.展开更多
This paper attempted to identify fractal and chaotic characteristics of the annual runoff processes in headwaters of the Tarim River.Methods of fractal analyses were used to explore several aspects of the temporal cha...This paper attempted to identify fractal and chaotic characteristics of the annual runoff processes in headwaters of the Tarim River.Methods of fractal analyses were used to explore several aspects of the temporal changes from 1957 to 2002.The main findings are as follows:(1) The annual runoff processes of the three headwaters of the Tarim River are com-plex nonlinear systems with fractal as well as chaotic dynamics.(2) The correlation dimensions of attractor derived from the time series of the annual runoff for the Hotan,Yarkand and Aksu rivers are all greater than 3.0 and non-integral,implying that all three rivers are chaotic dynamical systems that are sensitive to initial conditions,and the dynamic modeling of their annual runoff process requires at least four independent variables.(3) The time series of annual runoff in each river presents a long-term correlation characteristic.The Hurst exponent for the period of 1989 to 2002 suggests that we may expect to see an increasing trend in the annual runoff of the Aksu and Yarkand rivers in the years after 2002,but a decreasing tendency for the Hotan River in the same period.展开更多
This paper presents a dynamic glacier model that simulates the processes in response of Glacier No. 1 in headwaters of the Urumqi River to various future climatic scenarios The results indicate that the Glader No. 1 w...This paper presents a dynamic glacier model that simulates the processes in response of Glacier No. 1 in headwaters of the Urumqi River to various future climatic scenarios The results indicate that the Glader No. 1 will continue retreating if current climatic conditions prevail, until it reaches an equilibrium state of 1600 m in length after 700 to 800 years. If air temperature raise 1℃, the glacier would become a hanging glacier with a length of 300 m after 700 to 800 years. Due to its retreat, cooling function of the glacier would be weakened, resulting in the air temperature in glaciated area higher than that in ice-free areas. The results also indicate that the current glacier melt runoff is in higher value period in comparison with the runoff in the equilibrium state under the current climatic condition. If the air temperature continues increasing, however, the runoff would still increase to a new peak and then decrease rapidly.展开更多
The runoff and runoff process of Eucalyptus plantations natural watershed were studied to provide guidance for scientific evaluation of water conservation capacities of Eucalyptus plantations,compared with the Pinus m...The runoff and runoff process of Eucalyptus plantations natural watershed were studied to provide guidance for scientific evaluation of water conservation capacities of Eucalyptus plantations,compared with the Pinus massoniana forest natural watershed. The runoff volumes of Eucalyptus plantations and P. massoniana forest natural watersheds were continuously monitored using the small watershed runoff monitoring method and the automatic data collection devices from August,2013 to December,2016,and effects of heavy rainfall and continuous rainfall on the runoff process were studied. Results showed that the annual runoff coefficient of Eucalyptus plantations natural watershed was 0. 050,and 55. 4% lower than P. massoniana forest（ 0. 112）,with the difference being significant（ P 〈 0. 01）. Total runoff duration,time of maximum runoff lagging behind rainfall peak,and runoff duration caused by a heavy rainfall process（ amounting to 147. 5 mm） between the two kinds of forest watersheds were significant different,those of Eucalyptus plantations were 35. 6 mm,0. 2 h and 13. 8 h,respectively,while those of P. massoniana forest were28. 5 mm,0. 7 h and 35. 5 h,respectively. Eucalyptus plantations natural watershed produced only 4-days runoff,and runoff depth amounted to3. 8 mm with a 7-days continuous precipitation process of rainfall with 125. 0 mm,while P. massoniana forest natural watershed produced continuously 13-days runoff,and the runoff depth was 10. 1 mm. In conclusion,water conservation capacity of Eucalyptus plantations is obviously lower than P. massoniana forest.展开更多
Climate warming increases the variability in runoff of semiarid mountains where seasonally-frozen ground is widely distributed.However,what is not well understood are the processes of runoff,hydrological drivers,and f...Climate warming increases the variability in runoff of semiarid mountains where seasonally-frozen ground is widely distributed.However,what is not well understood are the processes of runoff,hydrological drivers,and freeze-thaw cycles in seasonally-frozen ground in semiarid mountains.To understand how freeze-thaw cycles affect runoff processes in seasonally-frozen ground,we monitored hydrological processes in a typical headwater catchment with seasonally-frozen ground in Qilian Mountain,China,from 2002 to 2017.We analyzed the responses of runoff to temperature,precipitation,and seasonally-frozen ground to quantify process characteristics and driving factors.The results show that annual runoff was 88.5 mm accounting for 25.6%of rainfall,mainly concentrated in May to October,with baseflow of 36.44 mm.Peak runoff occurred in June,August,and September,i.e.,accounting for spring and summer floods.Runoff during the spring flood was produced by a mix of rainfall,melting snow,and melting seasonally-frozen ground,and had a significant correlation with air temperature.Runoff was mainly due to precipitation accumulation during the summer flood.Air temperature,average soil temperature at 0−50 cm depth,and frozen soil depth variable explained 59.60%of the variation of runoff in the thawing period,while precipitation variable explained 21.9%.Thawing-period runoff and soil temperature had a>0.6 correlation coefficient(P<0.05).In the rainfall-period,runoff was also affected by temperature,soil moisture,and precipitation,which explained 33.6%,34.1%and 18.1%,respectively.Our results show that increasing temperature and precipitation will have an irreversible impact on the hydrological regime in mountainous basins where seasonally-frozen ground is widely distributed.展开更多
In this paper, a novel and efficient study on the hydrological processes of storm runoff from catchments of different land uses is conducted. The motivation is to precisely simulate the hydrological processes of storm...In this paper, a novel and efficient study on the hydrological processes of storm runoff from catchments of different land uses is conducted. The motivation is to precisely simulate the hydrological processes of storm runoff in the agricultural catchments with different patterns of land uses, i.e., forest, paddy, and upland, respectively. As it is discussed in this paper, different land use leads to different characteristics of storm runoff. In order to understand the changes in the hydrological processes of storm runoff from catchments of different land uses, the effects of rainfall intensity, initial soil moisture deficit, evapotranspiration rate, percolation rate, and retention capacity on hydrological processes of the catchments are taken into consideration. According to the principle of water balance, a general model to connect the separate hydrological processes is developed; then, the individual hydrological process is studied in detail： Firstly, the daily evaporation is calculated according to the relation between the actual evapotranspiration and the potential evapotranspiration rate; Secondly, the retention of storm runoff is plotted against the total rainfall, and the maximum storage is calculated; Thirdly, the percolation rate is calculated for each catchment.展开更多
The freezing-thawing variation of permafrost active layer increases the complexity of rainfall-runoff processes in alpine river basins,Northwest China.And alpine meadow is the prominent ecosystem in these basins.This ...The freezing-thawing variation of permafrost active layer increases the complexity of rainfall-runoff processes in alpine river basins,Northwest China.And alpine meadow is the prominent ecosystem in these basins.This study selected a small alpine meadow watershed in the upper reaches of the Shule River Basin,China.We investigated alpine rainfall-runoff processes,as well as impacts of summer thaw depth of active layer,soil temperature and moisture variation on streamflow based on in-situ observations from July 2015 to December 2020.Some hydrologic parameters or indices were calculated using statistical methods,and impacts of permafrost change on river runoff were assessed using the variable infiltration capacity model(VIC).In the alpine meadow,surface soil(0–10 cm depth)of the active layer starts to freeze in mid-October each year,and begins to thaw in early April.Also,the deeper soil(70–80 cm depth)of the active layer starts to freeze in late October,and begins to thaw in late June.Moisture content in shallow soils fluctuates regularly,whereas deeper soils are more stable,and their response to rainstorms is negligible.During active layer thawing,the moisture content increases with soil depth.In the alpine meadow,vertical infiltration only occurred in soils up to 40 cm deep,and lateral flow occurred in0–20 and 60–80 cm deep soils at current rainfall intensity.Summer runoff ratios were 0.06–0.31,and runoff floods show lags of 9.5–23.0 h following the rainfall event in the study area.The freeze–thaw process also significantly impacts runoff regression coefficients,which were 0.0088–0.0654 per hour.Recession coefficient decrease negatively correlates with active layer thawing depth in summer and autumn.Alpine river basin permafrost can effectively increase peak discharge and reduce low flow.These findings are highly significant for rainfall–runoff conversion research in alpine areas of inland rivers.展开更多
Rainfall simulations have been conducted to study the soil erosion process of purple soil in two cultiva-tion practices—contour cultivation and downslope cultivation. Results showed that under the two cultivation pra...Rainfall simulations have been conducted to study the soil erosion process of purple soil in two cultiva-tion practices—contour cultivation and downslope cultivation. Results showed that under the two cultivation prac-tices,the surface runoff can be described by the logarithmic function formula. In the initial period of rainfall,the amount of runoff increased with the rainfall duration and 20 minutes later it became relatively constant. The chang-ing process of soil erosion rate may be described by the logarithmic function formula. The erosion rate increased with the rainfall duration and 20 minutes later it also became constant. Under downslope cultivation condition,the soil erosion rate increased more significantly than that under contour cultivation condition in the case of gentle rain-fall intensity,and there is no obvious difference in erosion rate for downslope cultivation and contour cultivation practices. However,with increasing rainfall intensity the soil erosion rate under the downslope cultivation condition could be more than 30 times that under the contour cultivation condition. But this kind of difference would be re-duced to some extent in the case of heavy rain.展开更多
Microplastics(MPs),as a new category of environmental pollutant,have been the hotspot of eco-friendly issues nowadays.Studies based on the aging process,the migration pattern of MPs in runoff rainwater,and the use of ...Microplastics(MPs),as a new category of environmental pollutant,have been the hotspot of eco-friendly issues nowadays.Studies based on the aging process,the migration pattern of MPs in runoff rainwater,and the use of bioretention cells to remove MPs from runoff rainwater are beginning to attract widespread attention.This review analyses the migration patterns of MPs in rainwater runoff through their sources,structure and characteristics.The mechanism of removing MPs from runoff stormwater,the purification efficiency of different fillers and their influencing factors,and the accumulation,fate,and aging of MPs in bioretention cells are described.Furthermore,the hazards of MP accumulation on the performance of bioretention cells are summarised.Future directions for removing MPs in bioretention cells are proposed:(1)research on MPs smaller than 100μm;(2)influence of MPs aging process on bioretention cells;(3)exploration of more effective fillers to enhance their removal efficiency;(4)research on synergistic removal mechanism of MPs and other pollution.展开更多
The effect of hot band annealing processes—batch annealing and continuous annealing—on the texture evolution and ridging performance of ferritic stainless steel was investigated.The surface and central layers of the...The effect of hot band annealing processes—batch annealing and continuous annealing—on the texture evolution and ridging performance of ferritic stainless steel was investigated.The surface and central layers of the hot band exhibited strong shear and plane deformation textures,respectively.After batch annealing,the texture intensity of the hot-rolled sheet texture significantly decreased,and a weak recrystallization texture appeared,while fully recrystallized grains occurred after continuous annealing.A complete recrystallized{111}texture was obtained after recrystallization annealing.The sheet subjected to continuous annealing exhibited the highest intensity of{111}texture,which was accompanied by a dispersed grain orientation distribution,resulting in the lowest ridging height.展开更多
Current research on heterogeneous advanced oxidation processes(HAOPs)predominantly emphasizes catalyst iteration and innovation.Significant efforts have been made to regulate the electron structure and optimize the el...Current research on heterogeneous advanced oxidation processes(HAOPs)predominantly emphasizes catalyst iteration and innovation.Significant efforts have been made to regulate the electron structure and optimize the electron distribution,thereby increasing the catalytic activity.However,this focus often overshadows an equally essential aspect of HAOPs:the adsorption effect.Adsorption is a critical initiator for triggering the interaction of oxidants and contaminants with heterogeneous catalysts.The efficacy of these interactions is influenced by a variety of physicochemical properties,including surface chemistry and pore sizes,which determine the affinities between contaminants and material surfaces.This dispar ity in affinity is pivotal because it underpins the selective removal of contaminants,especially in complex waste streams containing diverse contaminants and competing matrices.Consequently,understanding and mastering these interfacial interactions is fundamentally indispensable not only for improving pro cess efficiency but also for enhancing the selectivity of contaminant removal.Herein,we highlight the importance of adsorption-driven interfacial interactions for fundamentally elucidating the catalytic mechanisms of HAOPs.Such interactions dictate the overall performance of the treatment processes by balancing the adsorption,reaction,and desorption rates on the catalyst surfaces.Elucidating the adsorption effect not only shifts the paradigm in understanding HAOPs but also improves their practical ity in water treatment and wastewater decontamination.Overall,we propose that revisiting adsorption driven interfacial interactions holds great promise for optimizing catalytic processes to develop effective HAOP strategies.展开更多
In oil and gas well cementing processes,accurately predicting the bottom hole circulating temperature(BHCT)is critical to ensuring effective zonal isolation.Overestimating the temperature can lead to excessive retarda...In oil and gas well cementing processes,accurately predicting the bottom hole circulating temperature(BHCT)is critical to ensuring effective zonal isolation.Overestimating the temperature can lead to excessive retardation issues,while underestimation can cause cementing accidents.Current methods for calculating the BHCT of cement slurry typically simplify the cementing processes to a single-fluid circulation and ignore the impact of pre-cementing processes on temperature,leading to significant discrepancies between calculated and actual results.In this study,the wellbore and formation are simplified into a two-dimensional axisymmetric structure,and a mathematical model of the temperature field under multi-fluid and multi-step conditions is established based on the law of energy conservation.The finite volume method was used to discretize the model,and a transient temperature field solver for the entire cementing process was developed,which can numerically calculate the temperature of any fluid at any time,any location.For an actual well example,the temperature distribution of the wellbore and formation after casing running is taken as the initial condition.Numerical calculations were performed sequentially to calculate the temperature fields of circulation flushing,wellbore preparation,and cementing,as well as the BHCT of the cement slurry.The study reveals that during the circulation flushing stage,the maximum temperature point in the wellbore is located at a distance of about 366 m above the bottom of the well.In the wellbore preparation stage,due to static heat exchange,the maximum temperature point gradually shifts to the bottom of the well.The BHCT of cement slurry changes continuously under cementing processes with multi-fluid and multi-step,making it a transient value.The BHCT of the lead slurry and tail slurry are not equal,with the maximum BHCT of the tail slurry being 2.46°C higher than that of the lead slurry.If circulation flushing and wellbore preparation are not considered,the calculated BHCT of the cement slurry will have errors of+6.8%and-1.9%.The study highlighted that considering thermal effects of all cementing stages,such as circulation flushing and wellbore preparation,in BHCT calculations can help improve prediction accuracy.展开更多
This paper focuses on the preparation of rare earth oxide products from rare earth chloride solutions during the rare earth extraction and separation processes,as well as the recycling of magnesium chloride solutions....This paper focuses on the preparation of rare earth oxide products from rare earth chloride solutions during the rare earth extraction and separation processes,as well as the recycling of magnesium chloride solutions.It proposes the idea of introducing spray pyrolysis technology into the rare earth extraction and separation processes.This paper briefly describes the development history of chloride spray pyrolysis technology,focusing on the research status and application progress of rare earth chloride solution and magnesium chloride solution spray pyrolysis technology,as well as spray pyrolysis equipment.The paper also analyzes the challenges and technical intricacies associated with applying spray pyrolysis technology to chloride solutions in the rare earth extraction and separation processes.Additionally,it explores future trends and proposes strategies to facilitate the full recycling of acids and bases,streamline the process flow,and enhance the prospects for green and low-carbon rare earth metallurgy.展开更多
Magnesium and magnesium alloys,serving as crucial lightweight structural materials and hydrogen storage elements,find extensive applications in space technology,aviation,automotive,and magnesium-based hydrogen industr...Magnesium and magnesium alloys,serving as crucial lightweight structural materials and hydrogen storage elements,find extensive applications in space technology,aviation,automotive,and magnesium-based hydrogen industries.The global production of primary magnesium has reached approximately 1.2 million tons per year,with anticipated diversification in future applications and significant market demand.Nevertheless,approximately 80%of the world’s primary magnesium is still manufactured through the Pidgeon process,grappling with formidable issues including high energy consumption,massive carbon emission,significant resource depletion,and environmental pollution.The implementation of the relative vacuum method shows potential in breaking through technological challenges in the Pidgeon process,facilitating clean,low-carbon continuous magnesium smelting.This paper begins by introducing the principles of the relative vacuum method.Subsequently,it elucidates various innovative process routes,including relative vacuum ferrosilicon reduction,aluminum thermal reduction co-production of spinel,and aluminum thermal reduction co-production of calcium aluminate.Finally,and thermodynamic foundations of the relative vacuum,a quantitative analysis of the material,energy flows,carbon emission,and production cost for several new processes is conducted,comparing and analyzing them against the Pidgeon process.The study findings reveal that,with identical raw materials,the relative vacuum silicon thermal reduction process significantly decreases raw material consumption,energy consumption,and carbon dioxide emissions by 15.86%,30.89%,and 26.27%,respectively,compared to the Pidgeon process.The relative vacuum process,using magnesite as the raw material and aluminum as the reducing agent,has the lowest magnesium-to-feed ratio,at only 3.385.Additionally,its energy consumption and carbon dioxide emissions are the lowest,at 1.817 tce/t Mg and 7.782 t CO_(2)/t Mg,respectively.The energy consumption and carbon emissions of the relative vacuum magnesium smelting process co-producing calcium aluminate(12CaO·7Al_(2)O_(3),3CaO·Al_(2)O_(3),and CaO·Al_(2)O_(3))are highly correlated with the consumption of dolomite in the raw materials.When the reduction temperature is around 1473.15 K,the critical volume fraction of magnesium vapor for different processes varies within the range of 5%–40%.Production cost analysis shows that the relative vacuum primary magnesium smelting process has significant economic benefits.This paper offers essential data support and theoretical guidance for achieving energy efficiency,carbon reduction in magnesium smelting,and the industrial adoption of innovative processes.展开更多
Previous works were mainly concentrated on long-term average runoff alterations,and extreme temperatures and watershed conditions are little analyzed.In this study,we collected gauged river flow and meteorological dat...Previous works were mainly concentrated on long-term average runoff alterations,and extreme temperatures and watershed conditions are little analyzed.In this study,we collected gauged river flow and meteorological data time series from 1916 to 2015 and 1941 to 2015 across the contiguous United States(CONUS)for 188 catchments to investigate the temporal trends and spatial features of runoff changes at multi-time scales.We also analyzed the relationships between runoff changes and climatic factors.Median descriptive statistics and Budyko coupled climate elasticity methods were used to calculate runoff elasticity in each time scale.The original Mann-Kendall trend test was used to test their trend significance in four time-scale(11,20,40,and 60 a),respectively.The results show that the trend of runoff changes is more significant in high time scales;total changes are heterogeneous over CONUS.After the 1970s,increases of up to 27%decade-1 were mainly concentrated in the mid-northern regions.Maximum temperature and catchment characteristics are vital factors for runoff alteration;runoff changes are independent of rainfall,and wet regions tend to have lower changes.These findings could help develop better regional water resource planning and management.展开更多
Land use and precipitation are two major factors affecting phosphorus(P)pollution of watershed runoff.However,molecular characterization of dissolved organic phosphorus(DOP)in runoff under the joint influences of land...Land use and precipitation are two major factors affecting phosphorus(P)pollution of watershed runoff.However,molecular characterization of dissolved organic phosphorus(DOP)in runoff under the joint influences of land use and precipitation remains limited.This study used Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR-MS)to study the molecular characteristics of DOP in a typical P-polluted watershed with spatially variable land use and precipitation.The results showed that low precipitation and intense human activity,including phosphate mining and associated industries,resulted in the accumulation of aliphatic DOP compounds in the upper reaches,characterized by low aromaticity and low biological stability.Higher precipitation and widespread agriculture in the middle and lower reaches resulted in highly unsaturated DOP compounds with high biological stability constituting a higher proportion,compared to in the upper reaches.While,under similar precipitation,more aliphatic DOP compounds characterized by lower aromaticity and higher saturation were enriched in the lower reaches due to more influence from urban runoff relative to the middle reaches.Photochemical and/or microbial processes did result in changes in the characteristics of DOP compounds during runoff processes due to the prevalence of low molecular weight and low O/C bioavailable aliphatic DOP molecules in the upper reaches,which were increasingly transformed into refractory compounds from the upper tomiddle reaches.The results of this study can increase the understanding of the joint impacts of land use and precipitation on DOP compounds in watershed runoff.展开更多
文摘The aging process is an inexorable fact throughout our lives and is considered a major factor in develo ping neurological dysfunctions associated with cognitive,emotional,and motor impairments.Aging-associated neurodegenerative diseases are characterized by the progressive loss of neuronal structure and function.
基金funded by the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0720203)the National Key Research and Development Program of China(2023YFF0805603).
文摘Based on monthly runoff and climate datasets spanning 2000–2024,this study employed the Theil–Sen’s slope estimation,Mann–Kendall(M–K)trend test,as well as Pearson correlation and Spearman rank correlation analyses to systematically examine the spatiotemporal patterns of runoff and its climatic driving mechanisms across Tajikistan,providing a scientific basis for sustainable water resource utilization and management in the study area.Results indicated that during 2000–2024,the annual runoff in Tajikistan exhibited statistically non-significant long-term trend(P=0.76),while displaying pronounced seasonal variability and strong spatial heterogeneity.Spring and summer average runoff primarily exhibited slight declining tendencies,while winter average runoff exhibited pronounced reduction in localized regions,such as the Syr Darya Basin,the Vakhsh River Basin,and the lower reaches of the Zeravshan River Basin.Precipitation emerged as the dominant positive driver of runoff,exhibiting moderate to strong positive correlations across over 78.00%of the country,whereas potential evapotranspiration consistently functioned as a negative driver.Rising temperatures exerted a dual competitive effect on runoff:in high-elevation,glacier-covered regions,rising temperatures temporarily increased runoff by accelerating glacier melt;however,at the national scale,the negative impact of rising temperature on runoff has played a slightly dominant role to a certain extent by enhancing evapotranspiration.Collectively,these results indicated that the present stability of runoff in Tajikistan is strongly dependent on the short-term compensatory effects of glacier melt and the risk of future runoff decline is likely to intensify as glacier reserves continue to diminish.This study provides a critical scientific evidence to inform sustainable water resource management in Tajikistan and underscores the need for glacier conservation and integrated water resource management strategies.
基金support from the National Natural Science Foundation of China(Grant Nos.42277161 and 42230709).
文摘In rock engineering,natural cracks in rock masses subjected to external loads tend to initiate and propagate,leading to potential safety hazards.To investigate the effect of cracking behavior on the mechanical properties of rocks,the cracking processes of pre-cracked rocks have been extensively studied using numerical modeling methods.The peridynamics(PD)exhibits advantages over other numerical methods due to the absence of the requirements for remeshing and external crack growth criterion.However,for modeling pre-cracked rock cracking processes under impact,current PD implementations lack generally applicable rock constitutive models and impact contact models,which leads to difficulties in determining rock material parameters and efficiently calculating impact loads.This paper proposes a non-ordinary state-based peridynamics(NOSBPD)modeling method integrating the Drucker-Prager(DP)plasticity model and an efficient contact model to address the above problems.In the proposed method,the Drucker-Prager plasticity model is integrated into the NOSBPD,thereby equipping NOSBPD with the capability to accurately characterize the nonlinear stress-strain relationship inherent in rocks.An efficient contact model between particles and meshes is designed to calculate the impact loads,which is essentially a coupling method of PD with the finite element method(FEM).The effectiveness of the proposed NOSBPD modeling method is verified by comparison with other numerical methods and experiments.Experimental results indicate that the proposed method can effectively and accurately predict the 3D cracking processes of pre-cracked cracks under impact loading,and the maximum principal stress is the key driver behind wing crack formation in pre-cracked rocks.
基金supported by the National Natural Science Foundation of China (41001066)the National Basic Research Program of China (Program 973) (2009CB421308)the Ministry of Water Resources’ Special Funds for Scientific Research on Public Causes (201101049)
文摘Water is the important resource to guarantee the existence and development of oases in arid areas. To improve the utilization efficiency of water resources in Manas River Basin, this paper investigated the trends and periods of runoff based on the runoff and climate data for the past 50 years. Subsequently, with the socioeconomic and water resources data, we studied a comprehensive evaluation on the water security in this area. The results indicated that the stream flows in the three hydrological stations of Hongshanzui, Kensiwat and Bajiahu have sig- nificantly increased and undergone abrupt changes, with periods of 18 and 20 years. According to assessment, water security in the Manas River Basin was at an unsafe level in 2008. In criterion layer, the ecological security index and the index of supply-demand situation are both at the relatively secure level; the quantity index and so- cioeconomic index of water resources are at the unsafe level and basic security level, respectively. Therefore, in order to achieve sustainable economic and social development within the Manas River Basin, it is vital to take a series of effective measures to improve the status of water security.
基金National Science and Technology Support Plan Projects,No.2012BAC19B07Scientific Research Project of Higher Learning Institution in Gansu Province,No.2013A-018Project of Scientific Ability Promoting of Young Teachers of Northwest Normal University,No.NWNU-LKQN-12-20
文摘Hydrological processes were compared, with and without the influence of precipita- tion on discharge, to identify the differences between glacierized and non-glacierized catchments in the Urumqi River source region, on the northern slope of the eastern Tianshan Mountains, during the melting season （May-September） in 2011. The study was based on hydrological data observed at 10-min intervals, meteorological data observed at 15-min intervals, and glacier melting and snow observations from the Empty Cirque, Zongkong, and Urumqi Glacier No.1 gauging stations. The results indicated that the discharge differed markedly among the three gauging stations. The daily discharge was more than the nightly discharge at the Glacier No.1 gauging station, which contrasted with the patterns observed at the Zongkong and Empty Cirque gauging stations. There was a clear daily variation in the discharge at the three gauging stations, with differences in the magnitude and duration of the peak discharge. When precipitation was not considered, the time-lags between the maximum discharge and the highest temperature were 1-3 h, 10-16 h, and 5-11 h at the Glacier No.l, Empty Cirque, and Zongkong gauging stations, respectively. When precipitation was taken into consideration, the corresponding time-lags were 0-1 h, 13 h, and 6-7 h, respectively. Therefore, the duration from the generation of discharge to confluence was the shortest in the glacierized catchment and the longest in the catchment where was mainly covered by snow. It was also shown that the hydrological process from the generation of discharge to confluence shortened when precipitation was considered. The factors influencing changes in the discharge among the three gauging stations were different. For Glacier No.1 station, the discharge was mainly controlled by heat conditions in the glacierized region, and the discharge displayed an accelerated growth when the temperature exceeded 5℃ in the melt season. It was found that the englacial and subglacial drainage channel of Glacier No.1 had become simpler during the past 20 years. Its weaker retardance and storage of glacier melting water resulted in rapid discharge confluence. It was also shown that the discharge curve and the time-lag between the maximum discharge and the highest temperature could be used to reveal the evolution of the drainage system and the process of glacier and snow melting at different levels of glacier coverage.
基金Knowledge Innovation Project of CAS, No.KZCX2-XB2-03Major Direction of Knowledge Innovation Project of CAS,No.KZCX2-YW-127Shanghai Academic Discipline Project (Human Geography),No.B410
文摘This paper attempted to identify fractal and chaotic characteristics of the annual runoff processes in headwaters of the Tarim River.Methods of fractal analyses were used to explore several aspects of the temporal changes from 1957 to 2002.The main findings are as follows:(1) The annual runoff processes of the three headwaters of the Tarim River are com-plex nonlinear systems with fractal as well as chaotic dynamics.(2) The correlation dimensions of attractor derived from the time series of the annual runoff for the Hotan,Yarkand and Aksu rivers are all greater than 3.0 and non-integral,implying that all three rivers are chaotic dynamical systems that are sensitive to initial conditions,and the dynamic modeling of their annual runoff process requires at least four independent variables.(3) The time series of annual runoff in each river presents a long-term correlation characteristic.The Hurst exponent for the period of 1989 to 2002 suggests that we may expect to see an increasing trend in the annual runoff of the Aksu and Yarkand rivers in the years after 2002,but a decreasing tendency for the Hotan River in the same period.
文摘This paper presents a dynamic glacier model that simulates the processes in response of Glacier No. 1 in headwaters of the Urumqi River to various future climatic scenarios The results indicate that the Glader No. 1 will continue retreating if current climatic conditions prevail, until it reaches an equilibrium state of 1600 m in length after 700 to 800 years. If air temperature raise 1℃, the glacier would become a hanging glacier with a length of 300 m after 700 to 800 years. Due to its retreat, cooling function of the glacier would be weakened, resulting in the air temperature in glaciated area higher than that in ice-free areas. The results also indicate that the current glacier melt runoff is in higher value period in comparison with the runoff in the equilibrium state under the current climatic condition. If the air temperature continues increasing, however, the runoff would still increase to a new peak and then decrease rapidly.
基金Supported by Special Project for Scientific Research of Public Welfare Industry of Ministry of Water Resources(201301044)
文摘The runoff and runoff process of Eucalyptus plantations natural watershed were studied to provide guidance for scientific evaluation of water conservation capacities of Eucalyptus plantations,compared with the Pinus massoniana forest natural watershed. The runoff volumes of Eucalyptus plantations and P. massoniana forest natural watersheds were continuously monitored using the small watershed runoff monitoring method and the automatic data collection devices from August,2013 to December,2016,and effects of heavy rainfall and continuous rainfall on the runoff process were studied. Results showed that the annual runoff coefficient of Eucalyptus plantations natural watershed was 0. 050,and 55. 4% lower than P. massoniana forest（ 0. 112）,with the difference being significant（ P 〈 0. 01）. Total runoff duration,time of maximum runoff lagging behind rainfall peak,and runoff duration caused by a heavy rainfall process（ amounting to 147. 5 mm） between the two kinds of forest watersheds were significant different,those of Eucalyptus plantations were 35. 6 mm,0. 2 h and 13. 8 h,respectively,while those of P. massoniana forest were28. 5 mm,0. 7 h and 35. 5 h,respectively. Eucalyptus plantations natural watershed produced only 4-days runoff,and runoff depth amounted to3. 8 mm with a 7-days continuous precipitation process of rainfall with 125. 0 mm,while P. massoniana forest natural watershed produced continuously 13-days runoff,and the runoff depth was 10. 1 mm. In conclusion,water conservation capacity of Eucalyptus plantations is obviously lower than P. massoniana forest.
基金the National Natural Science Foundation of China(Nos.41901044,41621001 and 41701296)the"CAS Light of West China"Program(29Y829861)Foundation for Excellent Youth Scholars of Northwest Institute of Eco‐Environment and Resources,Chinese Academy of Sciences(FEYS2019019).
文摘Climate warming increases the variability in runoff of semiarid mountains where seasonally-frozen ground is widely distributed.However,what is not well understood are the processes of runoff,hydrological drivers,and freeze-thaw cycles in seasonally-frozen ground in semiarid mountains.To understand how freeze-thaw cycles affect runoff processes in seasonally-frozen ground,we monitored hydrological processes in a typical headwater catchment with seasonally-frozen ground in Qilian Mountain,China,from 2002 to 2017.We analyzed the responses of runoff to temperature,precipitation,and seasonally-frozen ground to quantify process characteristics and driving factors.The results show that annual runoff was 88.5 mm accounting for 25.6%of rainfall,mainly concentrated in May to October,with baseflow of 36.44 mm.Peak runoff occurred in June,August,and September,i.e.,accounting for spring and summer floods.Runoff during the spring flood was produced by a mix of rainfall,melting snow,and melting seasonally-frozen ground,and had a significant correlation with air temperature.Runoff was mainly due to precipitation accumulation during the summer flood.Air temperature,average soil temperature at 0−50 cm depth,and frozen soil depth variable explained 59.60%of the variation of runoff in the thawing period,while precipitation variable explained 21.9%.Thawing-period runoff and soil temperature had a>0.6 correlation coefficient(P<0.05).In the rainfall-period,runoff was also affected by temperature,soil moisture,and precipitation,which explained 33.6%,34.1%and 18.1%,respectively.Our results show that increasing temperature and precipitation will have an irreversible impact on the hydrological regime in mountainous basins where seasonally-frozen ground is widely distributed.
基金Supported by the Natural Science Foundation of Hubei Province (2005ABA290)
文摘In this paper, a novel and efficient study on the hydrological processes of storm runoff from catchments of different land uses is conducted. The motivation is to precisely simulate the hydrological processes of storm runoff in the agricultural catchments with different patterns of land uses, i.e., forest, paddy, and upland, respectively. As it is discussed in this paper, different land use leads to different characteristics of storm runoff. In order to understand the changes in the hydrological processes of storm runoff from catchments of different land uses, the effects of rainfall intensity, initial soil moisture deficit, evapotranspiration rate, percolation rate, and retention capacity on hydrological processes of the catchments are taken into consideration. According to the principle of water balance, a general model to connect the separate hydrological processes is developed; then, the individual hydrological process is studied in detail： Firstly, the daily evaporation is calculated according to the relation between the actual evapotranspiration and the potential evapotranspiration rate; Secondly, the retention of storm runoff is plotted against the total rainfall, and the maximum storage is calculated; Thirdly, the percolation rate is calculated for each catchment.
基金supported by the National Key R&D Program of China(2021YFC3201102-02)the National Natural Science Foundation of China(Grant No.42171028,41877156,and 41730751)+1 种基金the State Key Laboratory of Frozen Soil Engineering Foundation(SKLFSE202110)the Science and Technology Program of Gansu Province,China(20JR5RA545)。
文摘The freezing-thawing variation of permafrost active layer increases the complexity of rainfall-runoff processes in alpine river basins,Northwest China.And alpine meadow is the prominent ecosystem in these basins.This study selected a small alpine meadow watershed in the upper reaches of the Shule River Basin,China.We investigated alpine rainfall-runoff processes,as well as impacts of summer thaw depth of active layer,soil temperature and moisture variation on streamflow based on in-situ observations from July 2015 to December 2020.Some hydrologic parameters or indices were calculated using statistical methods,and impacts of permafrost change on river runoff were assessed using the variable infiltration capacity model(VIC).In the alpine meadow,surface soil(0–10 cm depth)of the active layer starts to freeze in mid-October each year,and begins to thaw in early April.Also,the deeper soil(70–80 cm depth)of the active layer starts to freeze in late October,and begins to thaw in late June.Moisture content in shallow soils fluctuates regularly,whereas deeper soils are more stable,and their response to rainstorms is negligible.During active layer thawing,the moisture content increases with soil depth.In the alpine meadow,vertical infiltration only occurred in soils up to 40 cm deep,and lateral flow occurred in0–20 and 60–80 cm deep soils at current rainfall intensity.Summer runoff ratios were 0.06–0.31,and runoff floods show lags of 9.5–23.0 h following the rainfall event in the study area.The freeze–thaw process also significantly impacts runoff regression coefficients,which were 0.0088–0.0654 per hour.Recession coefficient decrease negatively correlates with active layer thawing depth in summer and autumn.Alpine river basin permafrost can effectively increase peak discharge and reduce low flow.These findings are highly significant for rainfall–runoff conversion research in alpine areas of inland rivers.
基金This research project was granted jointly by the National Program on Key Basic Research Projects "973" (2007CB407206)
文摘Rainfall simulations have been conducted to study the soil erosion process of purple soil in two cultiva-tion practices—contour cultivation and downslope cultivation. Results showed that under the two cultivation prac-tices,the surface runoff can be described by the logarithmic function formula. In the initial period of rainfall,the amount of runoff increased with the rainfall duration and 20 minutes later it became relatively constant. The chang-ing process of soil erosion rate may be described by the logarithmic function formula. The erosion rate increased with the rainfall duration and 20 minutes later it also became constant. Under downslope cultivation condition,the soil erosion rate increased more significantly than that under contour cultivation condition in the case of gentle rain-fall intensity,and there is no obvious difference in erosion rate for downslope cultivation and contour cultivation practices. However,with increasing rainfall intensity the soil erosion rate under the downslope cultivation condition could be more than 30 times that under the contour cultivation condition. But this kind of difference would be re-duced to some extent in the case of heavy rain.
基金supported by the National Natural Science Foundation of China(No.52070152).
文摘Microplastics(MPs),as a new category of environmental pollutant,have been the hotspot of eco-friendly issues nowadays.Studies based on the aging process,the migration pattern of MPs in runoff rainwater,and the use of bioretention cells to remove MPs from runoff rainwater are beginning to attract widespread attention.This review analyses the migration patterns of MPs in rainwater runoff through their sources,structure and characteristics.The mechanism of removing MPs from runoff stormwater,the purification efficiency of different fillers and their influencing factors,and the accumulation,fate,and aging of MPs in bioretention cells are described.Furthermore,the hazards of MP accumulation on the performance of bioretention cells are summarised.Future directions for removing MPs in bioretention cells are proposed:(1)research on MPs smaller than 100μm;(2)influence of MPs aging process on bioretention cells;(3)exploration of more effective fillers to enhance their removal efficiency;(4)research on synergistic removal mechanism of MPs and other pollution.
文摘The effect of hot band annealing processes—batch annealing and continuous annealing—on the texture evolution and ridging performance of ferritic stainless steel was investigated.The surface and central layers of the hot band exhibited strong shear and plane deformation textures,respectively.After batch annealing,the texture intensity of the hot-rolled sheet texture significantly decreased,and a weak recrystallization texture appeared,while fully recrystallized grains occurred after continuous annealing.A complete recrystallized{111}texture was obtained after recrystallization annealing.The sheet subjected to continuous annealing exhibited the highest intensity of{111}texture,which was accompanied by a dispersed grain orientation distribution,resulting in the lowest ridging height.
基金supported by the National Key Research and Development Program of China(2022YFC3205300)the National Natural Science Foundation of China(22176124).
文摘Current research on heterogeneous advanced oxidation processes(HAOPs)predominantly emphasizes catalyst iteration and innovation.Significant efforts have been made to regulate the electron structure and optimize the electron distribution,thereby increasing the catalytic activity.However,this focus often overshadows an equally essential aspect of HAOPs:the adsorption effect.Adsorption is a critical initiator for triggering the interaction of oxidants and contaminants with heterogeneous catalysts.The efficacy of these interactions is influenced by a variety of physicochemical properties,including surface chemistry and pore sizes,which determine the affinities between contaminants and material surfaces.This dispar ity in affinity is pivotal because it underpins the selective removal of contaminants,especially in complex waste streams containing diverse contaminants and competing matrices.Consequently,understanding and mastering these interfacial interactions is fundamentally indispensable not only for improving pro cess efficiency but also for enhancing the selectivity of contaminant removal.Herein,we highlight the importance of adsorption-driven interfacial interactions for fundamentally elucidating the catalytic mechanisms of HAOPs.Such interactions dictate the overall performance of the treatment processes by balancing the adsorption,reaction,and desorption rates on the catalyst surfaces.Elucidating the adsorption effect not only shifts the paradigm in understanding HAOPs but also improves their practical ity in water treatment and wastewater decontamination.Overall,we propose that revisiting adsorption driven interfacial interactions holds great promise for optimizing catalytic processes to develop effective HAOP strategies.
基金supported by the National Natural Science Foundation of China(No.U22B6003 and No.52274010)the China Scholarship Council(No.202008080235)。
文摘In oil and gas well cementing processes,accurately predicting the bottom hole circulating temperature(BHCT)is critical to ensuring effective zonal isolation.Overestimating the temperature can lead to excessive retardation issues,while underestimation can cause cementing accidents.Current methods for calculating the BHCT of cement slurry typically simplify the cementing processes to a single-fluid circulation and ignore the impact of pre-cementing processes on temperature,leading to significant discrepancies between calculated and actual results.In this study,the wellbore and formation are simplified into a two-dimensional axisymmetric structure,and a mathematical model of the temperature field under multi-fluid and multi-step conditions is established based on the law of energy conservation.The finite volume method was used to discretize the model,and a transient temperature field solver for the entire cementing process was developed,which can numerically calculate the temperature of any fluid at any time,any location.For an actual well example,the temperature distribution of the wellbore and formation after casing running is taken as the initial condition.Numerical calculations were performed sequentially to calculate the temperature fields of circulation flushing,wellbore preparation,and cementing,as well as the BHCT of the cement slurry.The study reveals that during the circulation flushing stage,the maximum temperature point in the wellbore is located at a distance of about 366 m above the bottom of the well.In the wellbore preparation stage,due to static heat exchange,the maximum temperature point gradually shifts to the bottom of the well.The BHCT of cement slurry changes continuously under cementing processes with multi-fluid and multi-step,making it a transient value.The BHCT of the lead slurry and tail slurry are not equal,with the maximum BHCT of the tail slurry being 2.46°C higher than that of the lead slurry.If circulation flushing and wellbore preparation are not considered,the calculated BHCT of the cement slurry will have errors of+6.8%and-1.9%.The study highlighted that considering thermal effects of all cementing stages,such as circulation flushing and wellbore preparation,in BHCT calculations can help improve prediction accuracy.
基金supported by the National Key Research and Development Program of China(2022YFB3504501)the National Natural Science Foundation of China(52274355)。
文摘This paper focuses on the preparation of rare earth oxide products from rare earth chloride solutions during the rare earth extraction and separation processes,as well as the recycling of magnesium chloride solutions.It proposes the idea of introducing spray pyrolysis technology into the rare earth extraction and separation processes.This paper briefly describes the development history of chloride spray pyrolysis technology,focusing on the research status and application progress of rare earth chloride solution and magnesium chloride solution spray pyrolysis technology,as well as spray pyrolysis equipment.The paper also analyzes the challenges and technical intricacies associated with applying spray pyrolysis technology to chloride solutions in the rare earth extraction and separation processes.Additionally,it explores future trends and proposes strategies to facilitate the full recycling of acids and bases,streamline the process flow,and enhance the prospects for green and low-carbon rare earth metallurgy.
基金supported by the China Postdoctoral Science Foundation(No.2023T160088)the Youth Fund of the National Natural Science Foundation of China(No.52304324).
文摘Magnesium and magnesium alloys,serving as crucial lightweight structural materials and hydrogen storage elements,find extensive applications in space technology,aviation,automotive,and magnesium-based hydrogen industries.The global production of primary magnesium has reached approximately 1.2 million tons per year,with anticipated diversification in future applications and significant market demand.Nevertheless,approximately 80%of the world’s primary magnesium is still manufactured through the Pidgeon process,grappling with formidable issues including high energy consumption,massive carbon emission,significant resource depletion,and environmental pollution.The implementation of the relative vacuum method shows potential in breaking through technological challenges in the Pidgeon process,facilitating clean,low-carbon continuous magnesium smelting.This paper begins by introducing the principles of the relative vacuum method.Subsequently,it elucidates various innovative process routes,including relative vacuum ferrosilicon reduction,aluminum thermal reduction co-production of spinel,and aluminum thermal reduction co-production of calcium aluminate.Finally,and thermodynamic foundations of the relative vacuum,a quantitative analysis of the material,energy flows,carbon emission,and production cost for several new processes is conducted,comparing and analyzing them against the Pidgeon process.The study findings reveal that,with identical raw materials,the relative vacuum silicon thermal reduction process significantly decreases raw material consumption,energy consumption,and carbon dioxide emissions by 15.86%,30.89%,and 26.27%,respectively,compared to the Pidgeon process.The relative vacuum process,using magnesite as the raw material and aluminum as the reducing agent,has the lowest magnesium-to-feed ratio,at only 3.385.Additionally,its energy consumption and carbon dioxide emissions are the lowest,at 1.817 tce/t Mg and 7.782 t CO_(2)/t Mg,respectively.The energy consumption and carbon emissions of the relative vacuum magnesium smelting process co-producing calcium aluminate(12CaO·7Al_(2)O_(3),3CaO·Al_(2)O_(3),and CaO·Al_(2)O_(3))are highly correlated with the consumption of dolomite in the raw materials.When the reduction temperature is around 1473.15 K,the critical volume fraction of magnesium vapor for different processes varies within the range of 5%–40%.Production cost analysis shows that the relative vacuum primary magnesium smelting process has significant economic benefits.This paper offers essential data support and theoretical guidance for achieving energy efficiency,carbon reduction in magnesium smelting,and the industrial adoption of innovative processes.
基金supported by National Key R&D Program of China(No.2018YFC0407303)“Young Talents”Project of Northeast Agricultural University(No.20QC13)the Natural Science Foundation of Heilongjiang Province of China(No.E2017009)。
文摘Previous works were mainly concentrated on long-term average runoff alterations,and extreme temperatures and watershed conditions are little analyzed.In this study,we collected gauged river flow and meteorological data time series from 1916 to 2015 and 1941 to 2015 across the contiguous United States(CONUS)for 188 catchments to investigate the temporal trends and spatial features of runoff changes at multi-time scales.We also analyzed the relationships between runoff changes and climatic factors.Median descriptive statistics and Budyko coupled climate elasticity methods were used to calculate runoff elasticity in each time scale.The original Mann-Kendall trend test was used to test their trend significance in four time-scale(11,20,40,and 60 a),respectively.The results show that the trend of runoff changes is more significant in high time scales;total changes are heterogeneous over CONUS.After the 1970s,increases of up to 27%decade-1 were mainly concentrated in the mid-northern regions.Maximum temperature and catchment characteristics are vital factors for runoff alteration;runoff changes are independent of rainfall,and wet regions tend to have lower changes.These findings could help develop better regional water resource planning and management.
基金supported by the Three Gorges Corporation (No.HBHB2023018)the Project of Hubei Provincial Key Research and Development (No.2022BCA074)the National Key Research and Development Program of China (No.2022YFC3705002).
文摘Land use and precipitation are two major factors affecting phosphorus(P)pollution of watershed runoff.However,molecular characterization of dissolved organic phosphorus(DOP)in runoff under the joint influences of land use and precipitation remains limited.This study used Fourier transform ion cyclotron resonance mass spectrometry(FT-ICR-MS)to study the molecular characteristics of DOP in a typical P-polluted watershed with spatially variable land use and precipitation.The results showed that low precipitation and intense human activity,including phosphate mining and associated industries,resulted in the accumulation of aliphatic DOP compounds in the upper reaches,characterized by low aromaticity and low biological stability.Higher precipitation and widespread agriculture in the middle and lower reaches resulted in highly unsaturated DOP compounds with high biological stability constituting a higher proportion,compared to in the upper reaches.While,under similar precipitation,more aliphatic DOP compounds characterized by lower aromaticity and higher saturation were enriched in the lower reaches due to more influence from urban runoff relative to the middle reaches.Photochemical and/or microbial processes did result in changes in the characteristics of DOP compounds during runoff processes due to the prevalence of low molecular weight and low O/C bioavailable aliphatic DOP molecules in the upper reaches,which were increasingly transformed into refractory compounds from the upper tomiddle reaches.The results of this study can increase the understanding of the joint impacts of land use and precipitation on DOP compounds in watershed runoff.
