This paper introduces the usage of these functions. It presents the technique of how to program with them to perform the serial communications between a computer and other digital devices by the serial porst in Window...This paper introduces the usage of these functions. It presents the technique of how to program with them to perform the serial communications between a computer and other digital devices by the serial porst in Windows95. The related sample codes of the applications of this technique written in C++ programming language are also given. This technique is applied successfully to receive the data of the radio noise from a frequency monitor.展开更多
Isomorphism of the two-state system is heuristic in understanding the dynamical or statistical behavior of the simplest yet most quantum system that has no classical counterpart.We use the constraint phase space devel...Isomorphism of the two-state system is heuristic in understanding the dynamical or statistical behavior of the simplest yet most quantum system that has no classical counterpart.We use the constraint phase space developed in J.Chem.Phys.145,204105(2016);151,024105(2019);J.Phys.Chem.Lett.12,2496(2021),non-covariant phase space functions,time-dependent weight functions,and time-dependent normalization factors to construct a novel class of phase space representations of the exact population dynamics of the two-state quantum system.The equations of motion of the trajectory on constraint phase space are isomorphic to the time-dependent Schrödinger equation.The contribution of each trajectory to the integral expression for the population dynamics is always positive semi-definite.We also prove that the triangle window function approach,albeit proposed as a heuristic empirical model in J.Chem.Phys.145,144108(2016),is related to a special case of the novel class and leads to an isomorphic representation of the exact population dynamics of the two-state quantum system.展开更多
SnS has emerged as an attractive catalyst for the electrochemical CO_(2)reduction reaction(CO_(2)RR)to formate,while its long-term operational stability is hindered by the self-reduction of Sn^(2+) and sulfur dissolut...SnS has emerged as an attractive catalyst for the electrochemical CO_(2)reduction reaction(CO_(2)RR)to formate,while its long-term operational stability is hindered by the self-reduction of Sn^(2+) and sulfur dissolution.Thus,maintaining high current efficiency across a wide negative potential range to achieve high production rates of formate remains a significant challenge.In this study,we present a heterostructure constructed with SnS and CuS for efficient CO_(2)RR to formate.The SnS-CuS(30)exhibits a remarkable formate Faradaic efficiency(FE_(f))of 93.94%at−1 V vs.reversible hydrogen electrode(RHE)and demonstrates long-term stability for 7.5 h,maintaining high activity(with an average FE_(f)of 85.6%)across a wide negative potential range(from-0.8 to-1.2 V(vs.RHE)).The results reveal that the heterogeneous interface between SnS and CuS mitigates the self-reduction issue of SnS by sacrificing Cu^(2+),highlighting that the true active species is SnS,which effectively resists structural changes during the electrolysis process under the protection of CuS.The synergistic interaction within the CuS and SnS heterostructure,combined with the tendency for electron self-conduction,enables the catalyst to maintain high formate activity and selectivity across a wide potential range.Furthermore,theoretical results further indicate that the incorporation of CuS enhances CO_(2)adsorption and lowers the energy barrier for the formation of formate intermediates.This study inspires the concept of applying protective layers to active species,promoting high selectivity in Sn-based electrocatalysts.展开更多
The numerical dispersion and computational cost are high for conventional Taylor series expansion staggered-grid finite-difference forward modeling owing to the high frequency of the wavelets and the large grid interv...The numerical dispersion and computational cost are high for conventional Taylor series expansion staggered-grid finite-difference forward modeling owing to the high frequency of the wavelets and the large grid intervals. In this study, the cosine-modulated binomial window function （CMBWF）-based staggered-grid finite-difference method is proposed. Two new parameters, the modulated time and modulated range are used in the new window function and by adjusting these two parameters we obtain different characteristics of the main and side lobes of the amplitude response. Numerical dispersion analysis and elastic wavefield forward modeling suggests that the CMBWF method is more precise and less computationally costly than the conventional Taylor series expansion staggered-grid finite-difference method.展开更多
基金Supported by the 86 3 High Technology Project of China (86 3-818-0 1-0 2 )
文摘This paper introduces the usage of these functions. It presents the technique of how to program with them to perform the serial communications between a computer and other digital devices by the serial porst in Windows95. The related sample codes of the applications of this technique written in C++ programming language are also given. This technique is applied successfully to receive the data of the radio noise from a frequency monitor.
文摘Isomorphism of the two-state system is heuristic in understanding the dynamical or statistical behavior of the simplest yet most quantum system that has no classical counterpart.We use the constraint phase space developed in J.Chem.Phys.145,204105(2016);151,024105(2019);J.Phys.Chem.Lett.12,2496(2021),non-covariant phase space functions,time-dependent weight functions,and time-dependent normalization factors to construct a novel class of phase space representations of the exact population dynamics of the two-state quantum system.The equations of motion of the trajectory on constraint phase space are isomorphic to the time-dependent Schrödinger equation.The contribution of each trajectory to the integral expression for the population dynamics is always positive semi-definite.We also prove that the triangle window function approach,albeit proposed as a heuristic empirical model in J.Chem.Phys.145,144108(2016),is related to a special case of the novel class and leads to an isomorphic representation of the exact population dynamics of the two-state quantum system.
基金supported by the National Key Research and Development Program of China(No.2018YFB1501405)the National Natural Science Foundation of China(No.52476185).
文摘SnS has emerged as an attractive catalyst for the electrochemical CO_(2)reduction reaction(CO_(2)RR)to formate,while its long-term operational stability is hindered by the self-reduction of Sn^(2+) and sulfur dissolution.Thus,maintaining high current efficiency across a wide negative potential range to achieve high production rates of formate remains a significant challenge.In this study,we present a heterostructure constructed with SnS and CuS for efficient CO_(2)RR to formate.The SnS-CuS(30)exhibits a remarkable formate Faradaic efficiency(FE_(f))of 93.94%at−1 V vs.reversible hydrogen electrode(RHE)and demonstrates long-term stability for 7.5 h,maintaining high activity(with an average FE_(f)of 85.6%)across a wide negative potential range(from-0.8 to-1.2 V(vs.RHE)).The results reveal that the heterogeneous interface between SnS and CuS mitigates the self-reduction issue of SnS by sacrificing Cu^(2+),highlighting that the true active species is SnS,which effectively resists structural changes during the electrolysis process under the protection of CuS.The synergistic interaction within the CuS and SnS heterostructure,combined with the tendency for electron self-conduction,enables the catalyst to maintain high formate activity and selectivity across a wide potential range.Furthermore,theoretical results further indicate that the incorporation of CuS enhances CO_(2)adsorption and lowers the energy barrier for the formation of formate intermediates.This study inspires the concept of applying protective layers to active species,promoting high selectivity in Sn-based electrocatalysts.
基金supported by the National Major Research Equipment Development Projects(No.ZDYZ2012-1-02-04)the National Natural Science Foundation of China(No.41474106)
文摘The numerical dispersion and computational cost are high for conventional Taylor series expansion staggered-grid finite-difference forward modeling owing to the high frequency of the wavelets and the large grid intervals. In this study, the cosine-modulated binomial window function （CMBWF）-based staggered-grid finite-difference method is proposed. Two new parameters, the modulated time and modulated range are used in the new window function and by adjusting these two parameters we obtain different characteristics of the main and side lobes of the amplitude response. Numerical dispersion analysis and elastic wavefield forward modeling suggests that the CMBWF method is more precise and less computationally costly than the conventional Taylor series expansion staggered-grid finite-difference method.
