ZnO-based thick film varistors have been fabricated by Y203 doping and low-temperature sintering, of which the sample with the best electrical properties has a high potential gradient value of 3159.4 V/mm. The effects...ZnO-based thick film varistors have been fabricated by Y203 doping and low-temperature sintering, of which the sample with the best electrical properties has a high potential gradient value of 3159.4 V/mm. The effects of Y2O3 doping concentration and sintering temperature on the potential gradient of the samples were systematically investigated. The results show that the sample with the best electrical properties can be obtained by doping 0.08 mol% Y2O3 and sintering at 725℃. Under these optimum preparation conditions, the leakage current and the nonlinear coefficient are found to be 36.4 gA and 13.1. The sample with the best electrical properties has a grain size of 1.290um, a single grain boundary voltage of 4.08 V, a barrier height of 0.81 eV, and a depletion layer width of 10.2 nm, which are determined by thermionic emission. Small grain size with good grain boundary characteristics is beneficial to improve the electrical properties of varistors and promote the potential gradient.展开更多
From 17 November to 27 December 2022, extremely cold snowstorms frequently swept across North America and Eurasia. Diagnostic analysis reveals that these extreme cold events were closely related to the establishment o...From 17 November to 27 December 2022, extremely cold snowstorms frequently swept across North America and Eurasia. Diagnostic analysis reveals that these extreme cold events were closely related to the establishment of blocking circulations. Alaska Blocking(AB) and subsequent Ural Blocking(UB) episodes are linked to the phase transition of the North Atlantic Oscillation(NAO) and represent the main atmospheric regimes in the Northern Hemisphere. The downstream dispersion and propagation of Rossby wave packets from Alaska to East Asia provide a large-scale connection between AB and UB episodes. Based on the nonlinear multi-scale interaction(NMI) model, we found that the meridional potential vorticity gradient(PVy) in November and December of 2022 was anomalously weak in the mid-high latitudes from North America to Eurasia and provided a favorable background for the prolonged maintenance of UB and AB events and the generation of associated severe extreme snowstorms. However, the difference in the UB in terms of its persistence,location, and strength between November and December is related to the positive(negative) NAO in November(December). During the La Ni?a winter of 2022, the UB and AB events are related to the downward propagation of stratospheric anomalies, in addition to contributions by La Ni?a and low Arctic sea ice concentrations as they pertain to reducing PVyin mid-latitudes.展开更多
In this paper we consider the initial boundary value problem of Cahn-Hilliard equation with concentration dependent mobility and gradient dependent potential. By the L^P type estimates and the theory of Morrey spaces,...In this paper we consider the initial boundary value problem of Cahn-Hilliard equation with concentration dependent mobility and gradient dependent potential. By the L^P type estimates and the theory of Morrey spaces,we prove the Holder continuity of the solutions.Then we obtain the existence of global classical solutions.The present work can be viewed as an extension to the previous work on the Cahn-Hilliard equation with concentration dependent mobility and potential.展开更多
Motivated by the special theory of gradient elasticity (GradEla), a proposal is advanced for extending it to construct gradient models for interatomic potentials, commonly used in atomistic simulations. Our focus is o...Motivated by the special theory of gradient elasticity (GradEla), a proposal is advanced for extending it to construct gradient models for interatomic potentials, commonly used in atomistic simulations. Our focus is on London’s quantum mechanical potential which is an analytical expression valid until a certain characteristic distance where “attractive” molecular interactions change character and become “repulsive” and cannot be described by the classical form of London’s potential. It turns out that the suggested internal length gradient (ILG) generalization of London’s potential generates both an “attractive” and a “repulsive” branch, and by adjusting the corresponding gradient parameters, the behavior of the empirical Lennard-Jones potentials is theoretically captured.展开更多
A nonlinear multi-scale interaction(NMI)model was proposed and developed by the first author for nearly 30 years to represent the evolution of atmospheric blocking.In this review paper,we first review the creation and...A nonlinear multi-scale interaction(NMI)model was proposed and developed by the first author for nearly 30 years to represent the evolution of atmospheric blocking.In this review paper,we first review the creation and development of the NMI model and then emphasize that the NMI model represents a new tool for identifying the basic physics of how climate change influences mid-to-high latitude weather extremes.The building of the NMI model took place over three main periods.In the 1990s,a nonlinear Schr?dinger(NLS)equation model was presented to describe atmospheric blocking as a wave packet;however,it could not depict the lifetime(10-20 days)of atmospheric blocking.In the 2000s,we proposed an NMI model of atmospheric blocking in a uniform basic flow by making a scale-separation assumption and deriving an eddyforced NLS equation.This model succeeded in describing the life cycle of atmospheric blocking.In the 2020s,the NMI model was extended to include the impact of a changing climate mainly by altering the basic zonal winds and the magnitude of the meridional background potential vorticity gradient(PVy).Model results show that when PVy is smaller,blocking has a weaker dispersion and a stronger nonlinearity,so blocking can be more persistent and have a larger zonal scale and weaker eastward movement,thus favoring stronger weather extremes.However,when PVy is much smaller and below a critical threshold under much stronger winter Arctic warming of global warming,atmospheric blocking becomes locally less persistent and shows a much stronger westward movement,which acts to inhibit local cold extremes.Such a case does not happen in summer under global warming because PVy fails to fall below the critical threshold.Thus,our theory indicates that global warming can render summer-blocking anticyclones and mid-to-high latitude heatwaves more persistent,intense,and widespread.展开更多
As an advanced polymer composites electro-kinetic geosynthetics, the electro-osmotic vertical drainage(EVD) board could drain water quickly and accelerate consolidation process. However, the drainage rate was mainly i...As an advanced polymer composites electro-kinetic geosynthetics, the electro-osmotic vertical drainage(EVD) board could drain water quickly and accelerate consolidation process. However, the drainage rate was mainly impacted by the vertical drainage capability. Therefore, vertical drainage capability at the top of EVD board was theoretically analyzed. Basic requirements for drainage at the top of the board were summed up, as well as the formula of anode pore pressure when losing the vertical drainage capability. Meanwhile, a contrast test on the top and bottom drainage capacities was conducted. In use of the advanced EVD board, the voltage potential and pore pressure of anode were measured. Moreover, the derived formulas were verified. The result shows that the decrease of electric force gradient had an observable impact on the drainage capability. There was nearly no difference between the energy consumption for the two drainage methods. Although a little less water was discharged, the top drainage method had more advantages, such as high initial drainage velocity, few soil cracks, low anode water content and high soil strength. All of these show that the super soft soil ground could be consolidated quickly in use of the advanced EVD board through the top drainage. The top drainage method could efficiently improve the drainage effect, decrease the energy consumption and speed up the project proceeding.展开更多
Soil salt transformation plays an important role in the freeze-thawing process,which is also one of basic problems of cryopedology. The very special law is made up of the two time salt-moisture transfer under freeze-t...Soil salt transformation plays an important role in the freeze-thawing process,which is also one of basic problems of cryopedology. The very special law is made up of the two time salt-moisture transfer under freeze-thawing condition. Based on the latest research at home and abroad,through the investigation of soil moisture-salt change in the freeze-thawing process,the conclusion is made that the soil water potential gradient is the main driving force of soil salt movement and the factors are of quantities. The research shows that,when freezing,temperature drops,salt and moisture move towards frozen layer. All make the salinity content of the frozen layer increase significantly. In the thawing process,salinity and moisture in the soil move up again with evaporation and makes the salt second migration.展开更多
In this paper,we first review the research advancements in blocking dynamics and highlight the merits and drawbacks of the previous theories of atmospheric blocking.Then,the dynamical mechanisms of atmospheric blockin...In this paper,we first review the research advancements in blocking dynamics and highlight the merits and drawbacks of the previous theories of atmospheric blocking.Then,the dynamical mechanisms of atmospheric blocking are presented based on a nonlinear multi-scale interaction(NMI)model.Previous studies suggested that the eddy deformation(e.g.,eddy straining,wave breaking,and eddy merging)might lead to the formation and maintenance of atmospheric blocking.However,the results were speculative and problematic because the previous studies,based on the time-mean eddy-mean flow interaction model,cannot identify the causal relationship between the evolution of atmospheric blocking and the eddy deformation.Based on the NMI model,we indicate that the onset,growth,maintenance,and decay of atmospheric blocking is mainly produced by the spatiotemporal evolution of pre-existing upstream synoptic-scale eddies,whereas the eddy deformation is a concomitant phenomenon of the blocking formation.The lifetime of blocking is mainly determined by the meridional background potential vorticity gradient(PVy)because a small PVyfavors weak energy dispersion and strong nonlinearity to sustain the blocking.But the zonal movement of atmospheric blocking is associated with the background westerly wind,PVy,and the blocking amplitude.Using this NMI model,a bridge from the climate change to sub-seasonal atmospheric blocking and weather extremes might be established via examining the effect of climate change on PVy.Thus,it is expected that using the NMI model to explore the dynamics of atmospheric blocking and its change is a new direction in the future.展开更多
In this paper we investigate the initial boundary value problem of Cahn-Hilliard equation with concentration dependent mobility and gradient dependent potential.By the energy method and the theory of Campanato spaces,...In this paper we investigate the initial boundary value problem of Cahn-Hilliard equation with concentration dependent mobility and gradient dependent potential.By the energy method and the theory of Campanato spaces,we prove the existence and the uniqueness of classical solutions in 3-dimensional space.展开更多
The molecular dynamics simulations are performed to show that in aque- ous environments, a short single-walled carbon nanotube （SWCNT） guided by a long SWCNT, either inside or outside the longer tube, is capable of ...The molecular dynamics simulations are performed to show that in aque- ous environments, a short single-walled carbon nanotube （SWCNT） guided by a long SWCNT, either inside or outside the longer tube, is capable of moving along the nanotube axis unidirectionally in an electric field perpendicular to the carbon nanotube （CNT） axis with the linear gradient. The design suggests a new way of molecule transportation or mass delivery. To reveal the mechanism behind this phenomenon, the free energy profiles of the system are calculated by the method of the potential of mean force （PMF）.展开更多
A high strength chemical industry wastewater was assessed for its impact on anaerobic microbial com- munity dynamics and consequently mesophilic methane generation. Cumulative methane production was 251 mL/g total che...A high strength chemical industry wastewater was assessed for its impact on anaerobic microbial com- munity dynamics and consequently mesophilic methane generation. Cumulative methane production was 251 mL/g total chemical oxygen demand removed at standard temperature and pressure at the end of 30 days experimental period with a highest recorded methane percentage of 80.6% of total biogas volume. Volatile fatty acids （VFAs） analysis revealed that acetic acid was the major intermediate VFAs produced with propionic acid accumulating over the experimental period. Quantitative analysis of microbial communities in the test and control groups with quantitative real time polymerase chain reaction highlighted that in the test group, Eubacteria （96.3%） was dominant in comparison with methanogens （3.7%）. The latter were dominated by Methanomicrobiales and Methanobacteriales while in test groups increased over the experimental period, reaching a maximum on day 30. Denaturing gradient gel electrophoresis profile was performed, targeting the 16S rRNA gene of Eubacteria and Archaea, with the DNA samples extracted at 3 different time points from the test groups. A phylogenetic tree was constructed for the sequences using the neighborhood joining method. The analysis revealed that the presence of organisms resembling Syntrophomonadaceae could have contributed to increased production of acetic and propionic acid intermediates while decrease of organisms resembling Pelotomaculum sp. could have most likely contributed to accumulation of propionic acid. This study suggested that the degradation of organic components within the high strength industrial wastewater is closely linked with the activity of certain niche microbial communities within eubacteria and methanogens.展开更多
The zonal width of the Ural blocking(UB)is a potentially crucial characteristic related to cold events in Eurasia.While most studies focus on the intensity,duration,frequency,and mobility of blocking events,the import...The zonal width of the Ural blocking(UB)is a potentially crucial characteristic related to cold events in Eurasia.While most studies focus on the intensity,duration,frequency,and mobility of blocking events,the importance of UB zonal width has often been overlooked.Against the backdrop of the declining Arctic sea ice concentration(SIC),the changes in UB zonal width and their association with winter extreme cold events in China remain unclear and require further investigation.This study defines the UB zonal width as the longitude difference between the easternmost and westernmost points of the 120-gpm contour line in the 500-hPa geopotential height(Z500)anomaly field.Based on the NCEP/NCA Rreanalysis data and SIC observations during 1970–2020,the UB width and coldair events under varied SIC conditions are examined.It is found that as SIC decreases in the Barents–Kara Sea(BKS),the UB extends zonally,coinciding with the transition of the North Atlantic Oscillation(NAO)from its positive to negative phase.Additionally,linear baroclinic model(LBM)simulations indicate that as the BKS warms,the zonal width of the UB broadens.Concurrently,warming sea surface temperatures(SST)in the BKS lead to decreased 500-hPa zonal wind(U500)and meridional potential vorticity gradient(PVy)over mid–high latitudes in Eurasia.As a result,energy dispersion weakens and nonlinearity strengthens in the Ural region,resulting in a more zonal extension of the UB.Consequently,the frequency of winter cold events of varying intensities in China increases,such as high-tolow latitude(H–L)and middle-to-low latitude(M–L)cold events.For H–L cold events,both intensity and frequency are higher during low SIC years when the UB widens.Conversely,for M–L events,there is no significant difference in the relationship of UB and cold air intrusion between high and low SIC years.Overall,reduced BKS SIC leads to a more zonal extension of the UB,facilitating the southward movement of cold air and influencing southern China.展开更多
For a long time,the phase-field method has been considered a mesoscale phenomenological method that lacks physical accuracy and is unable to be closely linked to the mechanical or functional properties of materials.So...For a long time,the phase-field method has been considered a mesoscale phenomenological method that lacks physical accuracy and is unable to be closely linked to the mechanical or functional properties of materials.Some misunderstandings existing in these viewpoints need to be clarified.Therefore,it is necessary to propose or adopt the perspective of“unified phase-field modeling(UPFM)”to address these issues,which means that phase-field modeling has multiple unified characteristics.Specifically,the phase-field method is the perfect unity of thermodynamics and kinetics,the unity of multi-scale models from microto meso and then to macro,the unity of internal or/and external driving energy with order parameters as field variables,the unity of multiple physical fields,and thus the unity of material composition design,process optimization,microstructure control,and performance prediction.It is precisely because the phase-field approach has these unified characteristics that,after more than 40 years of development,it has been increasingly widely applied in materials science and engineering.展开更多
Sandwich-style memristor devices were synthesized by electrochemical deposition with a ZnO film serving as the active layer between Al-doped ZnO （AZO） and Au electrodes. The carrier concentration of the ZnO films is...Sandwich-style memristor devices were synthesized by electrochemical deposition with a ZnO film serving as the active layer between Al-doped ZnO （AZO） and Au electrodes. The carrier concentration of the ZnO films is controlled by adding HNO3 during the growth process. A resulting increase in carrier concentration from 10^17 to 10^19 cm^-3 was observed, along with a corresponding drop in the on--off ratio from 6,437% to 100%. The resistive switching characteristics completely disappeared when the carrier concentration was above 1029 cm-3, making it unsuitable for a memory device. The decreasing switching ratio is attributed to a reduction in the driving force for oxygen vacancy drift. Systematic analysis of the migration of oxygen vacancies is presented, including the concentration gradient and electrical potential gradient. Such oxygen vacancy migration dynamics provide insight into the mechanisms of the oxygen vacancy drift and provide valuable information for industrial production of memristor devices.展开更多
The carrier screening effect occurs commonly in dielectric materials. It reduces the electric potential gradient, thus negatively affecting the functionality of resistive random access memory （RRAM） devices. An Au/Z...The carrier screening effect occurs commonly in dielectric materials. It reduces the electric potential gradient, thus negatively affecting the functionality of resistive random access memory （RRAM） devices. An Au/ZnO film/Al-doped ZnO device fabricated in this work exhibited no resistive switching （RS）, which was attributed to the carrier screening effect. Therefore, annealing was used for alleviating the screening effect, significantly enhancing the RS property. In addition, different on/off ratios were obtained for various bias values, and the screening effect was accounted for by investigating electron transport mechanisms. Furthermore, different annealing temperatures were employed to modulate the free carrier concentration in ZnO films to alleviate the screening effect. The maximal on/off ratio reached 10s at an annealing temperature of 600 ℃, yielding the lowest number of free carriers and the weakest screening effect in ZnO films. This work investigates the screening effect in RS devices. The screening effect not only modulates the characteristics of memory devices but also provides insight into the mechanism of RS in these devices.展开更多
Recent studies have indicated that hypervelocity impacts by meteoroids and space debris can induce spacecraft anomalies. However, the basic physical process through which space debris impacts cause anomalies is not en...Recent studies have indicated that hypervelocity impacts by meteoroids and space debris can induce spacecraft anomalies. However, the basic physical process through which space debris impacts cause anomalies is not entirely clear. Currently, impact-generated plasma is thought to be the primary cause of electrical spacecraft anomalies, while the effects of impact-generated mechanical damage have rarely been researched. This paper presents new evidence showing that impact-generated mechanical damage strongly influences electrostatic discharge. Hypervelocity impact experiments were conducted in a plasma drag particle accelerator, using particles with diameters of 200–500 ?m and velocities of 2–7 km/s. The impact-generated mechanical damage on a specimen surface was measured by a stereoscopic microscope and 3D Profilometer and it indicated that microscopic irregularities around the impact crater could be responsible for local electric field enhancement. Furthermore, the influence of impact-generated mechanical damage on electrostatic discharge was simulated in an inverted potential gradient situation. The experimental results show that the electrostatic discharge voltage threshold was significantly reduced after the specimen was impacted by particles.展开更多
For the inverse designs of centrifugal and mixed-flow pump impellers,clarifying the generation process of secondary flows and putting forward corresponding suppression measures is an important approach to improve the ...For the inverse designs of centrifugal and mixed-flow pump impellers,clarifying the generation process of secondary flows and putting forward corresponding suppression measures is an important approach to improve the impeller performance.In this paper,to provide a better qualitative insight into the generation mechanism of secondary flows in the impeller,a simple kinematic equation is derived based on the ideal assumptions,which indicates that the potential rothalpy gradient(PRG)is the most important dynamic source that actively induces secondary vortical flows.Induced by the natural adverse PRG on the S1 and S2 stream surfaces,two typical secondary flows,H-S and P-S secondary flows,are clearly presented.To specially suppress these typical secondary flows,a general alternate loading technique(GALT)is proposed,aiming to adjust the real blade loadingδp to control the PRG features.At the blade fore part,theδp on the hub streamline should be slowly increased to avoid breakneck growth of the potential rothalpy to reduce adverse streamwise PRG on the S2 streamsurface.At the blade middle part,theδp should be moderately decreased to reduce adverse streamwise PRG on the S1 streamsurface.At the blade aft part,the difference in theδp between the shroud and hub streamlines should be decreased faster to control the exit uniformity.By applying the GALT to the impeller designs of three typical pump types in hydraulic engineering,the organizational effect of the PRG on fundamental flow structures is proven.The GALT can effectively control the PRG distributions and suppress the secondary flows,thereby widening the pump’s high-efficiency zone,improving flow uniformity and suppressing pressure fluctuations.Compared with the current Z-G method and the ALT,the GALT can meet the requirements of"de-experience"better,thereby enabling the designers to obtain good products explicitly and quickly.展开更多
In this study,we analyzed 1979–2019 daily ERA-Interim reanalysis data in winter and performed atmospheric circulation experiments to examine the modulation of Arctic sea ice in western Greenland(Baffin Bay,Davis Stra...In this study,we analyzed 1979–2019 daily ERA-Interim reanalysis data in winter and performed atmospheric circulation experiments to examine the modulation of Arctic sea ice in western Greenland(Baffin Bay,Davis Strait,and the Labrador Sea,BDL)on winter Greenland blockings.It is found that low BDL sea ice and high BDL surface temperature favor frequent,long-lived,westward-moving Greenland blockings in winter,which cause frequent and strengthening cold surges over the mid-eastern United States.In contrast,high BDL sea ice and low BDL surface temperature favor short-lived,less frequent and quasi-stationary Greenland blockings,mainly leading to cold anomalies in North Europe.Low wintertime BDL sea ice reduces the background potential vorticity meridional gradient(PVy)and zonal wind over the mid-high latitudes of the North Atlantic,which enhances the nonlinearity of Greenland blocking,accelerates the phase speed of its westward movement,and weakens its energy dispersion,thus favoring the occurrence and persistence of Greenland blocking.High BDL sea ice strengthens the background PVyand zonal wind in the mid-high latitudes of the North Atlantic,which weakens the nonlinearity and movement of Greenland blocking,enhances its energy dispersion,and thus suppresses the occurrence and persistence of Greenland blocking and its retrogression.A set of atmospheric circulation experiments supports the above results based on the reanalysis dataset.展开更多
基金supported by the Nano Special Plan from Shanghai Municipal Science and Technology Plan of Commission (No 0852nm06000)the Shanghai Municipal Natural Science Foundation (No 08ZR1406700)
文摘ZnO-based thick film varistors have been fabricated by Y203 doping and low-temperature sintering, of which the sample with the best electrical properties has a high potential gradient value of 3159.4 V/mm. The effects of Y2O3 doping concentration and sintering temperature on the potential gradient of the samples were systematically investigated. The results show that the sample with the best electrical properties can be obtained by doping 0.08 mol% Y2O3 and sintering at 725℃. Under these optimum preparation conditions, the leakage current and the nonlinear coefficient are found to be 36.4 gA and 13.1. The sample with the best electrical properties has a grain size of 1.290um, a single grain boundary voltage of 4.08 V, a barrier height of 0.81 eV, and a depletion layer width of 10.2 nm, which are determined by thermionic emission. Small grain size with good grain boundary characteristics is beneficial to improve the electrical properties of varistors and promote the potential gradient.
基金support from the National Natural Science Foundation of China (Grant Nos. 41975068, 42150204, 42288101, 42075024, and 41830969)。
文摘From 17 November to 27 December 2022, extremely cold snowstorms frequently swept across North America and Eurasia. Diagnostic analysis reveals that these extreme cold events were closely related to the establishment of blocking circulations. Alaska Blocking(AB) and subsequent Ural Blocking(UB) episodes are linked to the phase transition of the North Atlantic Oscillation(NAO) and represent the main atmospheric regimes in the Northern Hemisphere. The downstream dispersion and propagation of Rossby wave packets from Alaska to East Asia provide a large-scale connection between AB and UB episodes. Based on the nonlinear multi-scale interaction(NMI) model, we found that the meridional potential vorticity gradient(PVy) in November and December of 2022 was anomalously weak in the mid-high latitudes from North America to Eurasia and provided a favorable background for the prolonged maintenance of UB and AB events and the generation of associated severe extreme snowstorms. However, the difference in the UB in terms of its persistence,location, and strength between November and December is related to the positive(negative) NAO in November(December). During the La Ni?a winter of 2022, the UB and AB events are related to the downward propagation of stratospheric anomalies, in addition to contributions by La Ni?a and low Arctic sea ice concentrations as they pertain to reducing PVyin mid-latitudes.
基金The NSF(11001103)the SRFDP(200801831002) of China
文摘In this paper we consider the initial boundary value problem of Cahn-Hilliard equation with concentration dependent mobility and gradient dependent potential. By the L^P type estimates and the theory of Morrey spaces,we prove the Holder continuity of the solutions.Then we obtain the existence of global classical solutions.The present work can be viewed as an extension to the previous work on the Cahn-Hilliard equation with concentration dependent mobility and potential.
文摘Motivated by the special theory of gradient elasticity (GradEla), a proposal is advanced for extending it to construct gradient models for interatomic potentials, commonly used in atomistic simulations. Our focus is on London’s quantum mechanical potential which is an analytical expression valid until a certain characteristic distance where “attractive” molecular interactions change character and become “repulsive” and cannot be described by the classical form of London’s potential. It turns out that the suggested internal length gradient (ILG) generalization of London’s potential generates both an “attractive” and a “repulsive” branch, and by adjusting the corresponding gradient parameters, the behavior of the empirical Lennard-Jones potentials is theoretically captured.
基金supported by the National Natural Science Foundation of China(Grant Nos.42150204 and 2288101)supported by the China National Postdoctoral Program for Innovative Talents(BX20230045)the China Postdoctoral Science Foundation(2023M730279)。
文摘A nonlinear multi-scale interaction(NMI)model was proposed and developed by the first author for nearly 30 years to represent the evolution of atmospheric blocking.In this review paper,we first review the creation and development of the NMI model and then emphasize that the NMI model represents a new tool for identifying the basic physics of how climate change influences mid-to-high latitude weather extremes.The building of the NMI model took place over three main periods.In the 1990s,a nonlinear Schr?dinger(NLS)equation model was presented to describe atmospheric blocking as a wave packet;however,it could not depict the lifetime(10-20 days)of atmospheric blocking.In the 2000s,we proposed an NMI model of atmospheric blocking in a uniform basic flow by making a scale-separation assumption and deriving an eddyforced NLS equation.This model succeeded in describing the life cycle of atmospheric blocking.In the 2020s,the NMI model was extended to include the impact of a changing climate mainly by altering the basic zonal winds and the magnitude of the meridional background potential vorticity gradient(PVy).Model results show that when PVy is smaller,blocking has a weaker dispersion and a stronger nonlinearity,so blocking can be more persistent and have a larger zonal scale and weaker eastward movement,thus favoring stronger weather extremes.However,when PVy is much smaller and below a critical threshold under much stronger winter Arctic warming of global warming,atmospheric blocking becomes locally less persistent and shows a much stronger westward movement,which acts to inhibit local cold extremes.Such a case does not happen in summer under global warming because PVy fails to fall below the critical threshold.Thus,our theory indicates that global warming can render summer-blocking anticyclones and mid-to-high latitude heatwaves more persistent,intense,and widespread.
基金Project(B15020060)supported by Fundamental Research Funds for the Central Universities,China
文摘As an advanced polymer composites electro-kinetic geosynthetics, the electro-osmotic vertical drainage(EVD) board could drain water quickly and accelerate consolidation process. However, the drainage rate was mainly impacted by the vertical drainage capability. Therefore, vertical drainage capability at the top of EVD board was theoretically analyzed. Basic requirements for drainage at the top of the board were summed up, as well as the formula of anode pore pressure when losing the vertical drainage capability. Meanwhile, a contrast test on the top and bottom drainage capacities was conducted. In use of the advanced EVD board, the voltage potential and pore pressure of anode were measured. Moreover, the derived formulas were verified. The result shows that the decrease of electric force gradient had an observable impact on the drainage capability. There was nearly no difference between the energy consumption for the two drainage methods. Although a little less water was discharged, the top drainage method had more advantages, such as high initial drainage velocity, few soil cracks, low anode water content and high soil strength. All of these show that the super soft soil ground could be consolidated quickly in use of the advanced EVD board through the top drainage. The top drainage method could efficiently improve the drainage effect, decrease the energy consumption and speed up the project proceeding.
文摘Soil salt transformation plays an important role in the freeze-thawing process,which is also one of basic problems of cryopedology. The very special law is made up of the two time salt-moisture transfer under freeze-thawing condition. Based on the latest research at home and abroad,through the investigation of soil moisture-salt change in the freeze-thawing process,the conclusion is made that the soil water potential gradient is the main driving force of soil salt movement and the factors are of quantities. The research shows that,when freezing,temperature drops,salt and moisture move towards frozen layer. All make the salinity content of the frozen layer increase significantly. In the thawing process,salinity and moisture in the soil move up again with evaporation and makes the salt second migration.
基金supported by the National Natural Science Foundation of China(Grant Nos.42150204 and 42288101)the Chinese Academy of Sciences Strategic Priority Research Program(Grant No.XDA19070403)。
文摘In this paper,we first review the research advancements in blocking dynamics and highlight the merits and drawbacks of the previous theories of atmospheric blocking.Then,the dynamical mechanisms of atmospheric blocking are presented based on a nonlinear multi-scale interaction(NMI)model.Previous studies suggested that the eddy deformation(e.g.,eddy straining,wave breaking,and eddy merging)might lead to the formation and maintenance of atmospheric blocking.However,the results were speculative and problematic because the previous studies,based on the time-mean eddy-mean flow interaction model,cannot identify the causal relationship between the evolution of atmospheric blocking and the eddy deformation.Based on the NMI model,we indicate that the onset,growth,maintenance,and decay of atmospheric blocking is mainly produced by the spatiotemporal evolution of pre-existing upstream synoptic-scale eddies,whereas the eddy deformation is a concomitant phenomenon of the blocking formation.The lifetime of blocking is mainly determined by the meridional background potential vorticity gradient(PVy)because a small PVyfavors weak energy dispersion and strong nonlinearity to sustain the blocking.But the zonal movement of atmospheric blocking is associated with the background westerly wind,PVy,and the blocking amplitude.Using this NMI model,a bridge from the climate change to sub-seasonal atmospheric blocking and weather extremes might be established via examining the effect of climate change on PVy.Thus,it is expected that using the NMI model to explore the dynamics of atmospheric blocking and its change is a new direction in the future.
基金Supported by the National Natural Science Foundation of China (Grant No.11001103)the Specialized Research Fund for the Doctoral Program of Higher Education (Grant No.200801831002)+1 种基金the China Postdoctoral Science Foundation (Grant No.20100481229)the Fundamental Research Funds for the Central Universities
文摘In this paper we investigate the initial boundary value problem of Cahn-Hilliard equation with concentration dependent mobility and gradient dependent potential.By the energy method and the theory of Campanato spaces,we prove the existence and the uniqueness of classical solutions in 3-dimensional space.
基金Project supported by the National Natural Science Foundation of China(Nos.11372175 and 11272197)the Research Fund for the Doctoral Program of Higher Education of China(No.20103108110004)the Innovation Program of Shanghai Municipality Education Commission(No.14ZZ095)
文摘The molecular dynamics simulations are performed to show that in aque- ous environments, a short single-walled carbon nanotube （SWCNT） guided by a long SWCNT, either inside or outside the longer tube, is capable of moving along the nanotube axis unidirectionally in an electric field perpendicular to the carbon nanotube （CNT） axis with the linear gradient. The design suggests a new way of molecule transportation or mass delivery. To reveal the mechanism behind this phenomenon, the free energy profiles of the system are calculated by the method of the potential of mean force （PMF）.
基金supported by the Energy Market Authority,Singapore through Smart Energy Challenge research funding
文摘A high strength chemical industry wastewater was assessed for its impact on anaerobic microbial com- munity dynamics and consequently mesophilic methane generation. Cumulative methane production was 251 mL/g total chemical oxygen demand removed at standard temperature and pressure at the end of 30 days experimental period with a highest recorded methane percentage of 80.6% of total biogas volume. Volatile fatty acids （VFAs） analysis revealed that acetic acid was the major intermediate VFAs produced with propionic acid accumulating over the experimental period. Quantitative analysis of microbial communities in the test and control groups with quantitative real time polymerase chain reaction highlighted that in the test group, Eubacteria （96.3%） was dominant in comparison with methanogens （3.7%）. The latter were dominated by Methanomicrobiales and Methanobacteriales while in test groups increased over the experimental period, reaching a maximum on day 30. Denaturing gradient gel electrophoresis profile was performed, targeting the 16S rRNA gene of Eubacteria and Archaea, with the DNA samples extracted at 3 different time points from the test groups. A phylogenetic tree was constructed for the sequences using the neighborhood joining method. The analysis revealed that the presence of organisms resembling Syntrophomonadaceae could have contributed to increased production of acetic and propionic acid intermediates while decrease of organisms resembling Pelotomaculum sp. could have most likely contributed to accumulation of propionic acid. This study suggested that the degradation of organic components within the high strength industrial wastewater is closely linked with the activity of certain niche microbial communities within eubacteria and methanogens.
基金Supported by the National Natural Science Foundation of China(42375061)National Key Research and Development Program of China(2023YFF0805101).
文摘The zonal width of the Ural blocking(UB)is a potentially crucial characteristic related to cold events in Eurasia.While most studies focus on the intensity,duration,frequency,and mobility of blocking events,the importance of UB zonal width has often been overlooked.Against the backdrop of the declining Arctic sea ice concentration(SIC),the changes in UB zonal width and their association with winter extreme cold events in China remain unclear and require further investigation.This study defines the UB zonal width as the longitude difference between the easternmost and westernmost points of the 120-gpm contour line in the 500-hPa geopotential height(Z500)anomaly field.Based on the NCEP/NCA Rreanalysis data and SIC observations during 1970–2020,the UB width and coldair events under varied SIC conditions are examined.It is found that as SIC decreases in the Barents–Kara Sea(BKS),the UB extends zonally,coinciding with the transition of the North Atlantic Oscillation(NAO)from its positive to negative phase.Additionally,linear baroclinic model(LBM)simulations indicate that as the BKS warms,the zonal width of the UB broadens.Concurrently,warming sea surface temperatures(SST)in the BKS lead to decreased 500-hPa zonal wind(U500)and meridional potential vorticity gradient(PVy)over mid–high latitudes in Eurasia.As a result,energy dispersion weakens and nonlinearity strengthens in the Ural region,resulting in a more zonal extension of the UB.Consequently,the frequency of winter cold events of varying intensities in China increases,such as high-tolow latitude(H–L)and middle-to-low latitude(M–L)cold events.For H–L cold events,both intensity and frequency are higher during low SIC years when the UB widens.Conversely,for M–L events,there is no significant difference in the relationship of UB and cold air intrusion between high and low SIC years.Overall,reduced BKS SIC leads to a more zonal extension of the UB,facilitating the southward movement of cold air and influencing southern China.
基金supported by the National Natural Science Foundation of China(grant number 52074246).
文摘For a long time,the phase-field method has been considered a mesoscale phenomenological method that lacks physical accuracy and is unable to be closely linked to the mechanical or functional properties of materials.Some misunderstandings existing in these viewpoints need to be clarified.Therefore,it is necessary to propose or adopt the perspective of“unified phase-field modeling(UPFM)”to address these issues,which means that phase-field modeling has multiple unified characteristics.Specifically,the phase-field method is the perfect unity of thermodynamics and kinetics,the unity of multi-scale models from microto meso and then to macro,the unity of internal or/and external driving energy with order parameters as field variables,the unity of multiple physical fields,and thus the unity of material composition design,process optimization,microstructure control,and performance prediction.It is precisely because the phase-field approach has these unified characteristics that,after more than 40 years of development,it has been increasingly widely applied in materials science and engineering.
基金This work was supported by the National Basic Research Program of China （No. 2013CB932602）, the Program of Introducing Talents of Discipline to Universities （No. B14003）, National Natural Science Foundation of China （Nos. 51527802, 51372023 and 51232001）, Beijing Municipal Science ＆ Technology Commission, the Fundamental Research Funds for Central Universities.
文摘Sandwich-style memristor devices were synthesized by electrochemical deposition with a ZnO film serving as the active layer between Al-doped ZnO （AZO） and Au electrodes. The carrier concentration of the ZnO films is controlled by adding HNO3 during the growth process. A resulting increase in carrier concentration from 10^17 to 10^19 cm^-3 was observed, along with a corresponding drop in the on--off ratio from 6,437% to 100%. The resistive switching characteristics completely disappeared when the carrier concentration was above 1029 cm-3, making it unsuitable for a memory device. The decreasing switching ratio is attributed to a reduction in the driving force for oxygen vacancy drift. Systematic analysis of the migration of oxygen vacancies is presented, including the concentration gradient and electrical potential gradient. Such oxygen vacancy migration dynamics provide insight into the mechanisms of the oxygen vacancy drift and provide valuable information for industrial production of memristor devices.
基金Acknowledgements This work was supported by the National Basic Research Program of China （No. 2013CB932602）, the Program of Introducing Talents of Discipline to Universities （No. B14003）, National Natural Science Foundation of China （Nos. 51527802, 51372023, and 51232001）, Beijing Municipal Science ＆ Technology Commission, the Fundamental Research Funds for Central Universities.
文摘The carrier screening effect occurs commonly in dielectric materials. It reduces the electric potential gradient, thus negatively affecting the functionality of resistive random access memory （RRAM） devices. An Au/ZnO film/Al-doped ZnO device fabricated in this work exhibited no resistive switching （RS）, which was attributed to the carrier screening effect. Therefore, annealing was used for alleviating the screening effect, significantly enhancing the RS property. In addition, different on/off ratios were obtained for various bias values, and the screening effect was accounted for by investigating electron transport mechanisms. Furthermore, different annealing temperatures were employed to modulate the free carrier concentration in ZnO films to alleviate the screening effect. The maximal on/off ratio reached 10s at an annealing temperature of 600 ℃, yielding the lowest number of free carriers and the weakest screening effect in ZnO films. This work investigates the screening effect in RS devices. The screening effect not only modulates the characteristics of memory devices but also provides insight into the mechanism of RS in these devices.
文摘Recent studies have indicated that hypervelocity impacts by meteoroids and space debris can induce spacecraft anomalies. However, the basic physical process through which space debris impacts cause anomalies is not entirely clear. Currently, impact-generated plasma is thought to be the primary cause of electrical spacecraft anomalies, while the effects of impact-generated mechanical damage have rarely been researched. This paper presents new evidence showing that impact-generated mechanical damage strongly influences electrostatic discharge. Hypervelocity impact experiments were conducted in a plasma drag particle accelerator, using particles with diameters of 200–500 ?m and velocities of 2–7 km/s. The impact-generated mechanical damage on a specimen surface was measured by a stereoscopic microscope and 3D Profilometer and it indicated that microscopic irregularities around the impact crater could be responsible for local electric field enhancement. Furthermore, the influence of impact-generated mechanical damage on electrostatic discharge was simulated in an inverted potential gradient situation. The experimental results show that the electrostatic discharge voltage threshold was significantly reduced after the specimen was impacted by particles.
基金supported by the National Natural Science Foundation of China(Grant Nos.51836010,51779258,51839001)the National Key Research and Development Program of China(Grant No.2018YFB0606103)the Beijing Natural Science Foundation of China(Grant No.3182018)。
文摘For the inverse designs of centrifugal and mixed-flow pump impellers,clarifying the generation process of secondary flows and putting forward corresponding suppression measures is an important approach to improve the impeller performance.In this paper,to provide a better qualitative insight into the generation mechanism of secondary flows in the impeller,a simple kinematic equation is derived based on the ideal assumptions,which indicates that the potential rothalpy gradient(PRG)is the most important dynamic source that actively induces secondary vortical flows.Induced by the natural adverse PRG on the S1 and S2 stream surfaces,two typical secondary flows,H-S and P-S secondary flows,are clearly presented.To specially suppress these typical secondary flows,a general alternate loading technique(GALT)is proposed,aiming to adjust the real blade loadingδp to control the PRG features.At the blade fore part,theδp on the hub streamline should be slowly increased to avoid breakneck growth of the potential rothalpy to reduce adverse streamwise PRG on the S2 streamsurface.At the blade middle part,theδp should be moderately decreased to reduce adverse streamwise PRG on the S1 streamsurface.At the blade aft part,the difference in theδp between the shroud and hub streamlines should be decreased faster to control the exit uniformity.By applying the GALT to the impeller designs of three typical pump types in hydraulic engineering,the organizational effect of the PRG on fundamental flow structures is proven.The GALT can effectively control the PRG distributions and suppress the secondary flows,thereby widening the pump’s high-efficiency zone,improving flow uniformity and suppressing pressure fluctuations.Compared with the current Z-G method and the ALT,the GALT can meet the requirements of"de-experience"better,thereby enabling the designers to obtain good products explicitly and quickly.
基金supported by the National Natural Science Foundation of China(Grant No.41790473)the China Postdoctoral Science Foundation(Grant No.BX20200087)。
文摘In this study,we analyzed 1979–2019 daily ERA-Interim reanalysis data in winter and performed atmospheric circulation experiments to examine the modulation of Arctic sea ice in western Greenland(Baffin Bay,Davis Strait,and the Labrador Sea,BDL)on winter Greenland blockings.It is found that low BDL sea ice and high BDL surface temperature favor frequent,long-lived,westward-moving Greenland blockings in winter,which cause frequent and strengthening cold surges over the mid-eastern United States.In contrast,high BDL sea ice and low BDL surface temperature favor short-lived,less frequent and quasi-stationary Greenland blockings,mainly leading to cold anomalies in North Europe.Low wintertime BDL sea ice reduces the background potential vorticity meridional gradient(PVy)and zonal wind over the mid-high latitudes of the North Atlantic,which enhances the nonlinearity of Greenland blocking,accelerates the phase speed of its westward movement,and weakens its energy dispersion,thus favoring the occurrence and persistence of Greenland blocking.High BDL sea ice strengthens the background PVyand zonal wind in the mid-high latitudes of the North Atlantic,which weakens the nonlinearity and movement of Greenland blocking,enhances its energy dispersion,and thus suppresses the occurrence and persistence of Greenland blocking and its retrogression.A set of atmospheric circulation experiments supports the above results based on the reanalysis dataset.
