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Transition of Y_2BaCuO_5 Phase in Powder Melting Processed YBa_2Cu_3O_(7-x) Superconductors
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作者 冯建情 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2011年第4期620-623,共4页
The morphology and the formation of Y2BaCuO5 phase in powder melting processed YBa2Cu3O7-x superconductors were investigated. The experimental results show the heat treatment can not change the shape of Y2BaCuO5 parti... The morphology and the formation of Y2BaCuO5 phase in powder melting processed YBa2Cu3O7-x superconductors were investigated. The experimental results show the heat treatment can not change the shape of Y2BaCuO5 particles in powder melting processed samples. The formation of round Y2BaCuO5 phase is due to relative content of each constitution of precursor powders in powder melting process. For powder melting process, the excessive liquid phase is eliminated, which restrains the preferred growth of Y2BaCuO5 particles. 展开更多
关键词 MoRPHoLoGY powder melting process YBa2CU3o7-X scanning electron microscopy
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STUDY ON PREPARATION OF YBa_2Cu_3O_(7-x) ULTRAFINE POWDERS BY SOL-GEL PROCESS
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作者 袁启华 邬江新 +1 位作者 唐福龙 黄俊 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 1994年第4期47-54,共8页
The ultrafine powders of YBa2Cu3O7-x with the size of 100nm were synthesized by Sol-Gel process using cit-rate as complex and ammonium hydroxide to adjust pH of solu-tion. The process of Sol formation and Gel polymeri... The ultrafine powders of YBa2Cu3O7-x with the size of 100nm were synthesized by Sol-Gel process using cit-rate as complex and ammonium hydroxide to adjust pH of solu-tion. The process of Sol formation and Gel polymerization of YBa2Cu3O7-x in the Sol-Gel synthetic reaction has bee studied. The particle size ,pruity, sintering activity and superconducting properties of YBa2Cu3O7-x prepared by Sol-Gel method are better than by solid state reaction. 展开更多
关键词 Sol-Gel process YBa2CU3o7-X ultrafine powders.
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STUDY OF PREPARATION AND PROPERTY OF YBa_2Cu_3O_(7-δ)-Ag_x COMPOSITE SUPERCONDUCTORS PREPARED BY SOL-GEL PROCESS
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作者 袁启华 唐福龙 +1 位作者 佟钰 袁润章 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 1996年第1期47-51,共5页
YBa2Cu3O7-δ-Agx composite superconductors were prepared by hybrid sintering process using YBa2Cu3O7-δ-Agx ultrafine powder and Ag2O finepower, which were prepared by sol-gel process and precipitation process respect... YBa2Cu3O7-δ-Agx composite superconductors were prepared by hybrid sintering process using YBa2Cu3O7-δ-Agx ultrafine powder and Ag2O finepower, which were prepared by sol-gel process and precipitation process respectively. The effect of the Ag content on superconducting crictical transition temperature of YBa2Cu3O7-δ-Agx was not evident as long as YBa2Cu3O7-δ-Agx can form continuous network. But Ag can increase superconduction crictical current and density of the composite superconductors. The normal state (i.e. non-superconducting state at room temperature) resistivity shows a percolation threshold at 20%-30% Ag, whereas the superconducting net-work shows a percolationthreshold at 70% -80% Ag. 展开更多
关键词 YBa2Cu3o7-δ-Agx superconductors sol-gel process.
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IN-SITU HVEM STUDY ON PHASE TRANSITION OF YBa_2Cu_3O_(7-x) SUPERCONDUCTING COMPOUND IN PROCESS OF HEATING
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作者 王瑞坤 邸秀萱 +4 位作者 王振海 贺庆 俞定安 周和平 王英 《Journal of Rare Earths》 SCIE EI CAS CSCD 1990年第2期99-103,共5页
In-situ HVEM observation on phase transition of the YBa_2Cu_3O_(7-x) superconducting compound in pro- cess of heating was carried out,and high temperature X-ray diffraction analysis in air and X-ray diffraction phase ... In-situ HVEM observation on phase transition of the YBa_2Cu_3O_(7-x) superconducting compound in pro- cess of heating was carried out,and high temperature X-ray diffraction analysis in air and X-ray diffraction phase analysis for the sample treated in vacuum condition were made.The results showed that the temperature of phase transition is related to oxygen content in the sample and in general,is 100℃ to 120℃ lower in vacu- um condition than in air.At 320℃ to 350℃ twin bands begin to disappear,and some Cu_2O are formed on the surface of the sample and transit from orthorhombic YBa_2Cu_3O_(7-x) to arthorhombic Y_2BaCuO_5 compound. This transition was completed at about 500℃.Above 900℃,this compound consists of the Y_2BaCuO_5, BaCuO_2,Y_2O_3 and some other minor compounds.No phase transition was observed during cooling the sample. 展开更多
关键词 HVEM SUPERCoNDUCTING CoMPoUND IN process oF HEATING IN-SITU HVEM STUDY oN PHASE TRANSITIoN oF YBa2Cu3o Cu
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焦化废水中几种含氮杂环有机物在A_1-A_2-O系统中的降解特性研究 被引量:40
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作者 李咏梅 顾国雄 赵建夫 《环境科学学报》 CAS CSCD 北大核心 2002年第1期34-39,共6页
在对焦化废水中有机物在A1 A2 O生物膜系统中降解转化规律进行分析的基础上 ,选取焦化废水中 6种主要的含氮杂环化合物 :吡啶、吲哚、喹啉、异喹啉、2 甲基喹啉、8 羟基喹啉 ,与苯酚共同配制成溶液 ,在A1 A2 O生物膜系统中运行 ,结... 在对焦化废水中有机物在A1 A2 O生物膜系统中降解转化规律进行分析的基础上 ,选取焦化废水中 6种主要的含氮杂环化合物 :吡啶、吲哚、喹啉、异喹啉、2 甲基喹啉、8 羟基喹啉 ,与苯酚共同配制成溶液 ,在A1 A2 O生物膜系统中运行 ,结果表明上述几种含氮杂环有机物在A1 A2 O系统中都可得到较完全的去除 .它们在厌氧段的降解速率从大到小依次为 :吲哚>2 甲基喹啉 >8 羟基喹啉 >异喹啉 >喹啉 >吡啶 .在厌氧条件下 ,吲哚和喹啉存在拮抗作用 ,而吡啶对喹啉有协同作用 ; 展开更多
关键词 焦化废水 含氮杂环化合物 A1-a2-o生物膜系统 厌氧 废水处理 降解特性 有机物
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Hot deformation and processing maps of Al_2O_3/Al composites fabricated by flake powder metallurgy 被引量:1
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作者 栾佰峰 邱日盛 +4 位作者 李春红 杨晓芳 李志强 张荻 刘庆 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第4期1056-1063,共8页
The deformation behaviors of Al2O3/Al composites were investigated by compressive tests conducted at temperature of 300-450 °C and strain rates of 0.001-1.0 s-1 with Gleeble-1500 D thermal simulator system. The r... The deformation behaviors of Al2O3/Al composites were investigated by compressive tests conducted at temperature of 300-450 °C and strain rates of 0.001-1.0 s-1 with Gleeble-1500 D thermal simulator system. The results show that the flow stress increases with increasing strain rate and decreasing temperature. The hyperbolic sine constitutive equation can describe the flow stress behavior of Al2O3/Al composites, and the deformation activation energy and constitutive equations were calculated. The processing maps of Al2O3/Al-2 μm and Al2O3/Al-1 μm composites at strain of 0.6 were obtained and the optimum processing domains are in ranges of 300-330 °C, 0.007-0.03 s-1 and 335-360 °C, 0.015-0.06 s-1 for hot working, respectively. The instability zones of flow behavior can also be recognized by the maps. 展开更多
关键词 Al2o3/Al composites flake powder metallurgy flow stress processing map
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La_2O_3-Mo阴极碳化工艺研究 被引量:2
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作者 周文元 张久兴 +4 位作者 周美玲 王金淑 杜玮 左铁镛 李保真 《材料科学与工艺》 EI CAS CSCD 2002年第1期66-68,共3页
研究了碳化温度、碳化时间、碳化时苯的浓度对La2O3-Mo阴极碳化度大小和碳化层组织的影响.实验结果表明:在1683~1723K,苯的浓度为8.0~8.5Pa,碳化6~8min后La2O3-Mo阴极碳化度>5%,达到使用要求,碳化层是我们所希望的疏松多孔的Mo2C... 研究了碳化温度、碳化时间、碳化时苯的浓度对La2O3-Mo阴极碳化度大小和碳化层组织的影响.实验结果表明:在1683~1723K,苯的浓度为8.0~8.5Pa,碳化6~8min后La2O3-Mo阴极碳化度>5%,达到使用要求,碳化层是我们所希望的疏松多孔的Mo2C组织. 展开更多
关键词 La2o3-Mo阴极 碳化度 组织 阴极材料 氧化镧 碳化工艺 电子管 热阴极
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Influence of pretreatment process on structure, morphology and electrochemical properties of Li[Ni_(1/3)Co_(1/3)Mn_(1/3)]O_2 cathode material 被引量:1
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作者 杨顺毅 王先友 +3 位作者 刘子玲 陈权启 杨秀康 魏启亮 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2011年第9期1995-2001,共7页
The layered Li[Ni1/3Mn1/3Co1/3]O2 was separately synthesized by pretreatment process of ball mill method and solution phase route, using [Ni1/3Co1/3Mn1/3]3O4 and lithium hydroxide as raw materials. The physical and el... The layered Li[Ni1/3Mn1/3Co1/3]O2 was separately synthesized by pretreatment process of ball mill method and solution phase route, using [Ni1/3Co1/3Mn1/3]3O4 and lithium hydroxide as raw materials. The physical and electrochemical behaviors of Li[Ni1/3Mn1/3Co1/3]O2 were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), field emission scanning electron microscopy (FESEM) and electrochemical charge/discharge cycling tests. The results show that the difference in pretreatment process results in the difference in compound Li[Ni1/3Co1/3Mn1/3]O2 structure, morphology and the electrochemical characteristics. The Li[Ni1/3Mn1/3Co1/3]O2 prepared by solution phase route maintains the uniform spherical morphology of the [Ni1/3Co1/3Mn1/3]3O4, and it exhibits a higher capacity retention and better rate capability than that prepared by ball mill method. The initial discharge capacity of this sample reaches 178 mA-h/g and the capacity retention after 50 cycles is 98.7% at a current density of 20 mA/g. Moreover, it delivers high discharge capacity of 135 mA-h/g at a current density of 1 000 mA/g. 展开更多
关键词 lithium ion batteries Li[Ni1/3Co1/3Mn1/3]o2 carbonate co-precipitation method pretreatment process electrochemical characteristics
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基于BioWin6.0的A^(2)/O工艺模型构建与运行优化
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作者 邢传宏 王梦园 +3 位作者 西蒙克里斯蒂娜 胡富静 张艳 陈伟 《环境工程》 2025年第6期115-126,共12页
大型污水处理厂实时调控困难导致超标风险长期存在,迫切需要过程仿真软件指导达标运行。以北方某A^(2)/O工艺污水处理厂为研究对象,借助BioWin6.0构建适用模型,面向GB3838一2002《地表水环境质量标准》的准IV类标准深入开展仿真运行优化... 大型污水处理厂实时调控困难导致超标风险长期存在,迫切需要过程仿真软件指导达标运行。以北方某A^(2)/O工艺污水处理厂为研究对象,借助BioWin6.0构建适用模型,面向GB3838一2002《地表水环境质量标准》的准IV类标准深入开展仿真运行优化,分别以控TN优先和控TP优先模拟得到四季推荐运行参数。谨以冬季为例,对冬季控TN优先推荐运行参数进行验证,结果表明COD、NH_(4)^(+)-N和TP3个指标均稳定优于GB3838一2002准IV类标准。值得注意的是,模拟出水TN浓度相比优化前最高降低21.2%;模拟出水TP浓度相比优化前最高降低15.6%,甚至优于地表水准Ⅲ类标准。可见该厂运行升级改造仍有较大空间,所得四季推荐运行参数可为大型污水处理厂降本增效提供借鉴和指导。 展开更多
关键词 A^(2)/o工艺 BioWin6.0 模型构建 运行优化 模拟验证
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A_1-A_2/O工艺结合生物流化床降解焦化废水NH_3-N、COD中试研究 被引量:1
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作者 杨天旺 吴洪英 林齐枢 《煤化工》 CAS 2002年第3期52-58,62,共8页
本文介绍了用 A1 - A2 / O工艺结合流化床技术对攀钢高浓度焦化废水进行 NH3 - N、COD降解的中试试验。试验结果表明 :当进水 NH3 - N<5 0 0 mg/ L、COD<2 0 0 0 m g/ L 时 ,该工艺可以实现 NH3 - N去除率 97%以上 ,COD去除率 85 ... 本文介绍了用 A1 - A2 / O工艺结合流化床技术对攀钢高浓度焦化废水进行 NH3 - N、COD降解的中试试验。试验结果表明 :当进水 NH3 - N<5 0 0 mg/ L、COD<2 0 0 0 m g/ L 时 ,该工艺可以实现 NH3 - N去除率 97%以上 ,COD去除率 85 %以上 ,酚去除率 99.9%。药剂及动力费用为 6 .6元 / t水 ,停留时间 5 0 展开更多
关键词 焦化废水 A1-a2/o工艺 充化床 NH3-N CoD 降解 废水处理 生化处理
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回流对城镇污水处理厂A^(2)O-MBR工艺除磷效果影响及机制-工程化规模研究 被引量:1
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作者 董君兰 楼菊青 +1 位作者 王如意 刘春晓 《环境科学学报》 北大核心 2025年第2期31-44,共14页
本研究对两个同样采用A^(2)O-MBR工艺的城镇污水处理厂在不同回流条件下的运行监测数据进行了深入分析.检测分析了沿程水相和泥相中磷浓度、胞外聚合物(EPS)含量及微生物群落结构,并开展了非原位批次实验,深入分析了释磷/吸磷、挥发性... 本研究对两个同样采用A^(2)O-MBR工艺的城镇污水处理厂在不同回流条件下的运行监测数据进行了深入分析.检测分析了沿程水相和泥相中磷浓度、胞外聚合物(EPS)含量及微生物群落结构,并开展了非原位批次实验,深入分析了释磷/吸磷、挥发性脂肪酸(VFA)以及聚羟基烷酸酯(PHA)、糖原(Glyc)的变化情况,揭示了不同回流条件下不同形态磷浓度的变化及机制.结果发现,在较低内回流比(缺氧池回流至厌氧池R1=100%、好氧池回流至缺氧池R2=200%)和较高外回流比(MBR回流至好氧池R3=500%)时,系统中溶解性总磷(DTP)浓度先上升后下降,且出水磷浓度较低,各单元贡献率计算发现好氧吸磷量显著高于厌氧释磷量.同时,微生物群落的丰富度和多样性显著较高,典型聚磷菌(PAOs)Candidatus Accumulibacter、Dechloromonas相对丰度较高,除磷性能较好.然而,在较高内回流比(R_(1)=200%、R_(2)=300%)和较低外回流比(R_(3)=400%)时,DTP浓度持续下降,未观察到明显的释磷现象,主要的吸磷过程发生在缺氧阶段.厌氧、缺氧段硝态氮(NO_(3)^(-)-N)、溶解氧(DO)和氧化还原电位(ORP)较高,不利于生物除磷性能的发挥.此外,EPS含量及PN/PS比值较低,表明微生物活性受到抑制.非原位释磷/吸磷批次实验进一步验证了这一点,单位释磷速率低,且糖原分解量和PHA产生量均较小.微生物群落分析显示,Nitrospira、Ferruginibacter和IMCC26207为代表性分类菌群.研究结果可为A^(2)O-MBR工艺的污水处理厂的优化运行提供理论依据. 展开更多
关键词 回流比 生物除磷 a2o工艺 微生物群落
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AGS强化A^(2)O工艺处理生活污水的效能 被引量:1
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作者 孙秉毅 秦庆东 +1 位作者 孔宇 李建 《中国给水排水》 北大核心 2025年第17期113-119,共7页
为提高A^(2)O工艺处理效率,将好氧颗粒污泥(AGS)技术引入A^(2)O工艺,对A^(2)O工艺处理生活污水的效能进行研究。试验结果表明,经过90 d培养后粒径大于200μm的颗粒污泥占58.2%。培养末期COD去除率>78%、NH_(4)^(+)-N去除率>95%、T... 为提高A^(2)O工艺处理效率,将好氧颗粒污泥(AGS)技术引入A^(2)O工艺,对A^(2)O工艺处理生活污水的效能进行研究。试验结果表明,经过90 d培养后粒径大于200μm的颗粒污泥占58.2%。培养末期COD去除率>78%、NH_(4)^(+)-N去除率>95%、TN去除率>75%、TP去除率>80%。试验装置的脱氮除磷效果均优于对照污水厂,并且HRT降低近50%。脱氮过程分析和细菌16S rRNA高通量测序的结果表明,AGS通过强化好氧池的反硝化脱氮能力来提高A^(2)O工艺的脱氮效果。除磷过程分析表明,同步化学除磷不仅能够实现对磷的高效去除,也能够促进污泥颗粒化。 展开更多
关键词 好氧颗粒污泥 连续流 A^(2)o工艺 生活污水 脱氮除磷
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儿茶素对反硝化细菌反硝化过程及N_(2)O排放的影响
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作者 张新星 陈召亚 +2 位作者 廖文华 刘春敬 高志岭 《环境污染与防治》 北大核心 2025年第7期36-41,I0019,I0020,共8页
提高农田生态系统养分利用率,降低N_(2)O排放,以及促进农业废弃物资源化利用是绿色农业可持续发展的重要任务。探讨了酚类化合物儿茶素对4种土壤反硝化细菌反硝化过程及N_(2)O排放的影响。结果表明:儿茶素虽对反硝化细菌生长有一定的抑... 提高农田生态系统养分利用率,降低N_(2)O排放,以及促进农业废弃物资源化利用是绿色农业可持续发展的重要任务。探讨了酚类化合物儿茶素对4种土壤反硝化细菌反硝化过程及N_(2)O排放的影响。结果表明:儿茶素虽对反硝化细菌生长有一定的抑制作用,但对脱氮副球菌(Paracoccus denitrificans)和泛养副球菌(Paracoccus pantotrophus)N_(2)O向N_(2)转化的反硝化过程具有一定促进作用,从而减少反硝化过程中N_(2)O排放,但低浓度儿茶素对4种反硝化细菌的生长影响不显著,需添加0.500 mg/mL的儿茶素才能显现效果。研究结果对挖掘合适的生物氮素调理剂以及推动含酚类化合物的有机废弃物循环利用等都具有重要的指导意义。 展开更多
关键词 儿茶素 反硝化细菌 反硝化过程 N_(2)o排放
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Comparison of conventional and inverted A^2/O processes:Phosphorus release and uptake behaviors 被引量:11
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作者 Rong Qi Tao Yu +5 位作者 Zheng Li Dong Li Takashi Mino Tadashi Shoji Kochi Fujie Min Yang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2012年第4期571-578,共8页
Two full-scale systems operated in parallel, a conventional A2/O system consisting of anaerobic, anoxic and oxic compartments in succession and an inverted system consisting of anoxic, anaerobic and oxic compartments ... Two full-scale systems operated in parallel, a conventional A2/O system consisting of anaerobic, anoxic and oxic compartments in succession and an inverted system consisting of anoxic, anaerobic and oxic compartments without internal recycle, were compared in terms of their phosphorus removal performance, with an emphasis on phosphate (P) release behaviors, using both operational data and simulation results. The inverted system exhibited better long-term phosphorus removal performance (0.2 ± 0.3 vs. 0.7 ±0.7 mg/L), which should be attributed to the higher P release rate (0.79 vs. 0.60 kg P/(kg MLSS.day)) in the non-aerated compartments. The P release occurred in both the anoxic and anaerobic compartments of the inverted system, resulting in more efficient P release. Although the abundances of the 'Candidatus Accumulibacter phosphatis' population in the two systems were quite similar ((19.1 + 3.27)% and (18.4 + 4.15)% of the total microbe (DAPI stained particles) population in the inverted and conventional systems, respectively, by fluorescence in situ hybridization (FISH)), the high-concentration DAPI staining results show that the abundances of the whole polyphosphate accumulating organisms (PAOs) in the aerobic ends were quite different (the average ratios of the poly-P granules to total microbes (DAPI stained particles) were (45 ±4.18)% and (35 ± 5.39)%, respectively). Both the operational data and simulation results showed that the inverted system retained more abundant PAO populations due to its special configuration, which permitted efficient P release in the non-aerated compartment and better P removal, 展开更多
关键词 phosphate release and uptake a2/o process inverted a2/o process activated sludge model
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Formaldehyde degradation by UV/TiO_2/O_3 process using continuous flow mode 被引量:12
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作者 QI Hong SUN De-zhi CHI Guo-qing 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2007年第9期1136-1140,共5页
The degradation of formaldehyde gas was studied using UV/TiO2/O3 process under the condition of continuous flow mode. The effects of humidity, initial formaldehyde concentration, residence time and ozone adding amount... The degradation of formaldehyde gas was studied using UV/TiO2/O3 process under the condition of continuous flow mode. The effects of humidity, initial formaldehyde concentration, residence time and ozone adding amount on degradation of formaldehyde gas were investigated. The experimental results indicated that the combination of ozonation with photocatalytic oxidation on the degradation of formaldehyde showed a synergetic action, e.g,, it could considerably increase decomposing of formaldehyde. The degradation efficiency of formaldehyde was between 73.6% and 79.4% while the initial concentration in the range of 1.84--24 mg/m^3 by O3/TiO2flJV process. The optimal humidity was about 50% in UV/TiO2/O3 processs and degradation of formaldehyde increases from 39.0% to 94.1% when the ozone content increased from 0 to 141 mg/m^3. Furthermore, the kinetics of formaldehyde degradation reaction could be described by Langmuir-Hinshelwood model. The rate constant k of 46.72 mg/(m^3.min) and Langmuir adsorption coefficient K of 0.0268 m^3/mg were obtained. 展开更多
关键词 UV/Tio2/o3 process FoRMALDEHYDE continuous flow mode
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Anoxic Biological Phosphorus Uptake in A^2O Process 被引量:11
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作者 WANG Xiaolian(王晓莲) +3 位作者 WANG Shuying(王淑莹) PENG Yongzhen(彭永臻) 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2005年第4期516-521,共6页
A lab-scale anaerobic-anoxic-oxic (A2O) process used to treat a synthetic brewage wastewater was investigated. The objectives of the study were to identify the existence of denitrifying phosphorus removing bacteria (D... A lab-scale anaerobic-anoxic-oxic (A2O) process used to treat a synthetic brewage wastewater was investigated. The objectives of the study were to identify the existence of denitrifying phosphorus removing bacteria (DPB), evaluate the contribution of DPB to biological nutrient removal and enhance the denitrifying phosphorus removal in A2O bioreactors. Sludge analysis confirmed that the average anoxic P uptake accounted for approximately 70% the total amount of P uptake, and the ratio of anoxic P uptake rate to aerobic P uptake rate was 69%. In addition, nitrate concentration in the anoxic phase and different organic substrate introduced into the anaerobic phase had significant effect on the anoxic P uptake. Compared with conventional A2O processes, good removal efficiencies of COD, phosphorus, ammonia and total nitrogen (92.3%, 95.5%, 96% and 79.5%, respectively) could be achieved in the anoxic P uptake system, and aeration energy consumption was saved 25%. By controlling the nitrate recirculation flow in the anoxic zone, anoxic P uptake could be enhanced, which solved the competition for organic substrates among poly-P organisms and denitrifiers successfully under the COD limiting conditions. Therefore, in wastewater treatment plants the control system should be applied according to the practical situation to optimize the operation. 展开更多
关键词 A^2o process nitrogen and phosphorus removal denitrifying phosphorus removing bacteria nitrate recirculation flow
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Removal of benzotriazole by heterogeneous photoelectro-Fenton like process using ZnFe_2O_4 nanoparticles as catalyst 被引量:5
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作者 Junfeng Wu Wenhong Pu +2 位作者 Changzhu Yang Man Zhang Jingdong Zhang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2013年第4期801-807,共7页
ZnFe2O4 nanoparticles (ZFNPs) were developed as catalyst for the degradation of benzotriazole (BTA) by heterogeneous photoelectro- Fenton (PE-Fenton) like process. ZFNPs were prepared by a co-precipitation proce... ZnFe2O4 nanoparticles (ZFNPs) were developed as catalyst for the degradation of benzotriazole (BTA) by heterogeneous photoelectro- Fenton (PE-Fenton) like process. ZFNPs were prepared by a co-precipitation process and then characterized with transmission electron microscopy (TEM), X-ray fluorescence (XRF), X-ray diffraction (XRD) and BET surface area. Using such ZFNPs as catalyst, the degradation of BTA was investigated. Due to the high catalytic activity of ZFNPs, PE-Fenton like process showed efficient degradation of BTA. The influencing factors such as pH, dosage of ZFNPs, applied potential and initial concentration of BTA were systematically investigated. Under the optimum conditions, 91.2% of BTA was removed after 180 rain treatment. 展开更多
关键词 ZnFe2o4 nanoparticles photoelectro-Fenton like process BENZoTRIAZoLE heterogeneous catalytic degradation
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IN SITU PROCESSING OF Al_(2)O_(3) WHISKERS REINFORCED Ti-Al INTERMETALLIC COMPOSITES 被引量:6
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作者 F.Wang Z.K.Fan J.F.Zhu 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2006年第6期432-440,共9页
In situ Al2O3 whiskers reinforced Ti-Al intermetallic composites were fabricated at ~1200℃ by reaction sintering of cold-consolidated fillets consisting mainly of Ti, Al, and different additives. The phases and micro... In situ Al2O3 whiskers reinforced Ti-Al intermetallic composites were fabricated at ~1200℃ by reaction sintering of cold-consolidated fillets consisting mainly of Ti, Al, and different additives. The phases and microstructures of the sintered composites were characterized using X-ray diffraction (XRD) and scanning electron microscopy (SEM) coupled with energy dispersive spectroscopy (EDS). The process of synthesis was investigated using differential thermal analysis (DTA). The effects of processing parameters and additives on the microstructures of the composites and the development of whisker were examined. It is found that the morphology of the whisker is strongly influenced by the additives, the exothermal reaction process, and the processing parameters. 展开更多
关键词 in situ Al2o3 whisker Ti-Al intermetallic composite ADDITIVE reaction process
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Photolysis pathway of nitroaromatic compounds in aqueous solutions in the UV/H_2O_2 process 被引量:2
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作者 GOH Ngoh Khang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2006年第6期1061-1064,共4页
Nitroaromatic compounds such as nitrobenzene and nitrophenols are largely synthesised and particularly often occur in water bodies as toxic pollutants. The degradation of these compounds in the environment via direct ... Nitroaromatic compounds such as nitrobenzene and nitrophenols are largely synthesised and particularly often occur in water bodies as toxic pollutants. The degradation of these compounds in the environment via direct photolysis and by biological treatment is difficult and usually slow. In our two previous published papers, we have discussed the advanced oxidation of nitrobenzene and nitrophenols in aqueous solutions irradiated by direct photolysis using polychromatic light and by means of UV/H2O2 process. The experimental results suggested the UV/H2O2 process is an effective and efficient technology for complete mineralization of these organic compounds. Based on the results therein, comprehensive reaction mechanism for nitrobenzene photolysis was proposed with detailed discussions. 展开更多
关键词 PHoToLYSIS PATHWAY NITRoBENZENE NITRoPHENoLS UV/H2o2 process
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Nitrogen removal for low-carbon wastewater in reversed A^2/O process by regulation technology 被引量:1
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作者 张智 陈杰云 +3 位作者 谢丽华 范功端 尹晓静 李勇 《Journal of Central South University》 SCIE EI CAS 2009年第S1期304-308,共5页
Full scale experimental study on nitrogen removal for low-carbon wastewater was conducted in reversed A2/O process in Jiguanshi waste water treatment plant in Chongqing,in order to aid the operation and maintenance of... Full scale experimental study on nitrogen removal for low-carbon wastewater was conducted in reversed A2/O process in Jiguanshi waste water treatment plant in Chongqing,in order to aid the operation and maintenance of similar WWTP. When the proposed measures,such as using 0.1% (volume fraction of wastewater) landfill leachate,shortening HRT by 2/3 in the primary sedimentation tank and controlling DO at 0.5 mg/L in the 3rd section of aerobic zone,are applied,15% of the carbon source can be complemented,the favorable property of activated sludge is achieved,and the nitrogen removal effect is significantly improved. The effluent NH3-N is 2 mg/L and the removal rate is 90%. The effluent TN is 17 mg/L and the removal rate is 54%. The up-to-standard discharge of the effluent is achieved. And after the optimization,the unit electricity consumption also reaches 0.21 kW/h and saves 20%. 展开更多
关键词 reversed a2/o process low-carbon resource LANDFILL LEACHATE primary SEDIMENTATIoN TANK nitrogen removal
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