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Advances in Schottky parameter extraction and applications
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作者 Peihua Wangyang Xiaolin Huang +11 位作者 Xiao-Lei Shi Niuniu Zhang Yu Ye Shuangzhi Zhao Jiamin Zhang Yingbo Liu Fabi Zhang Xingpeng Liu Haiou Li Tangyou Sun Ying Peng Zhi-Gang Chen 《Journal of Materials Science & Technology》 2025年第15期317-335,共19页
Schottky contacts have attracted widespread attention from both the electronic device industry and researchers since their discovery.The Schottky characteristics make these contacts highly suitable for use in field-ef... Schottky contacts have attracted widespread attention from both the electronic device industry and researchers since their discovery.The Schottky characteristics make these contacts highly suitable for use in field-effect transistors(FETs),photodetectors(PDs),solar cells(SCs),resistive-switching memories(RSMs),thin-film transistors(TFTs),etc.However,how do Schottky contacts affect the device performance?The answer lies simply in the Schottky parameters.This review focuses on the extraction of Schottky parameters,i.e.,the Schottky barrier height(SBH),ideality factor(IF),and series resistance(SR),from the current-voltage(I−V)curve to understand and analyze the characteristics of Schottky devices.First,the current research progress in this field and the principles of Schottky contacts are presented.Second,this article delves into some classic and widely used extraction methods as well as the latest extraction methods,providing an objective evaluation based on their practical effectiveness.Then,several research applications,including studies that require extraction,simple extraction,and delicate extraction,are enumerated to demonstrate the necessity and importance of Schottky parameter analysis.Finally,an outlook and future research prospects are discussed based on recent progress,and a comprehensive summary is given. 展开更多
关键词 Schottky parameter extraction PHOTODETECTORS Solar cells Resistive-switching memory Thin-film transistors
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Experimental extraction of neutron resonance parameters at 20–300 eV for^(147,149)Sm
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作者 Xin-Xiang Li Long-Xiang Liu +29 位作者 Wei Jiang Ya-Ju Chen Jie Ren Hong-Wei Wang Gong-Tao Fan Wen Luo Song Feng Wen Xie Zi-Ang Lin Ting Jiang Gao-Le Yang Zhen-Dong An Xian-Kai Li Zhou-Ji Liao Jie-Ming Xue Xin-Yu Li Ning-Xin Peng De-Xin Wang Su-Ya-La-Tu Zhang Yue Zhang Xin-Rong Hu Zi-Rui Hao Bing Jiang Xiao-He Wang Ji-Feng Hu Ying-Du Liu Chun-Wang Ma Yu-Ting Wang Jian-Jun He Li-Yong Zhang 《Nuclear Science and Techniques》 2025年第10期98-107,共10页
^(147,149)Sm are slow neutron capture(s-process)nuclides in nuclear astrophysics,whose(n,γ)cross sections are important input parameters in nucleosynthesis network calculations in the samarium(Sm)region.In addition,^... ^(147,149)Sm are slow neutron capture(s-process)nuclides in nuclear astrophysics,whose(n,γ)cross sections are important input parameters in nucleosynthesis network calculations in the samarium(Sm)region.In addition,^(149)Sm is a fission product of ^(235)U with a 1%yield,and its neutron resonance parameters play a critical role in reactor neutronics.According to the available nuclear evaluation databases,a significant disagreement has been observed in the resonance peaks of the ^(147,149)Sm(n,γ)crosssectional data within the energy range of 20-300 eV.In this study,tutron capture cross section of a natural samarium target was measured at the back-streaming white neutron beamline of the China Spallation Neutron Source.The neutron capture yield was obtained,and the neutron resonance parameters for ^(147)Sm at 107.0,139.4,241.7,and 257.3 eV and ^(149)Sm at 23.2,24.6,26.1,28.0,51.5,75.2,90.9,125.3,and 248.4 eV were extracted using the SAMMY code based on R-matrix theory.For the parameters Γ_(n) and Γ_(γ) in these energies of ^(147,149)Sm,the percentages consistent with the results of the CENDL-3.2,ENDF/B-Ⅷ.0,JEFF-3.3,JENDL-4.0,and BROND-3.1 database are 27%,65%,65%,42%,and 58%,respectively.However,27% of the results were inconsistent with those of the major libraries.This work enriches experimental data of the ^(147,149)Sm neutron capture resonance and helps clarify the differences between different evaluation databases at the above energies. 展开更多
关键词 Neutron capture cross section Neutron resonance parameters Back-n facility
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Artificial intelligence-enabled high-precision colony extraction and isolation system
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作者 ZHAO Xu-feng JIA Zhi-qiang +5 位作者 CHEN Wei-xue HU Peng-tao SU Xin-ran LI Jun-lin GE Ming-feng DONG Wen-fei 《中国光学(中英文)》 北大核心 2026年第1期190-204,共15页
Standard bacterial suspensions play a crucial role in microbiological diagnosis.Traditional prepar-ation methods,which rely heavily on manual operations,face challenges such as poor reproducibility,low ef-ficiency,and... Standard bacterial suspensions play a crucial role in microbiological diagnosis.Traditional prepar-ation methods,which rely heavily on manual operations,face challenges such as poor reproducibility,low ef-ficiency,and biosafety concerns.In this study,we propose a high-precision automated colony extraction and separation system that combines large-field imaging and artificial intelligence(AI)to facilitate intelligent screening and localization of colonies.Firstly,a large-field imaging system was developed to capture high-resolution images of 90 mm Petri dishes,achieving a physical resolution of 13.2μm and an imaging speed of 13 frames per second.Subsequently,AI technology was employed for the automatic recognition and localiza-tion of colonies,enabling the selection of target colonies with diameters ranging from 1.9 to 2.3 mm.Next,a three-axis motion control platform was designed,accompanied by a path planning algorithm for the efficient extraction of colonies.An electronic pipette was employed for accurate colony collection.Additionally,a bacterial suspension concentration measurement module was developed,incorporating a 650 nm laser diode as the light source,achieving a measurement accuracy of 0.01 McFarland concentration(MCF).Finally,the system’s performance was validated through the preparation of an Esckerichia coli(E.coli)suspension.After 17 hours of cultivation,E.coli was extracted four times,achieving the target concentration set by the system.This work is expected to enable rapid and accurate microbial sample preparation,significantly reducing de-tection cycles and alleviating the workload of healthcare personnel. 展开更多
关键词 artificial intelligence colony extraction and isolation large-field imaging AUTOMATION
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Impact of preoperative anterior topographic parameters on effective optical zone after keratorefractive lenticule extraction and wavefront-guided LASIK
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作者 Tsung-Hsien Tsai Jui-Hung Hsu +1 位作者 Erh-Tsan Lin Chi-Chin Sun 《International Journal of Ophthalmology(English edition)》 2025年第12期2331-2338,共8页
AIM:To investigate the impact of preoperative anterior corneal topographic parameters on the morphology of the postoperative effective optical zone(EOZ)in patients undergoing keratorefractive lenticule extraction(KLEx... AIM:To investigate the impact of preoperative anterior corneal topographic parameters on the morphology of the postoperative effective optical zone(EOZ)in patients undergoing keratorefractive lenticule extraction(KLEx)and wavefront-guided LASIK(WG-LASIK).METHODS:This retrospective study included 310 eyes from patients who underwent either KLEx(via small incision lenticule extraction,171 eyes)or WG-LASIK(139 eyes).Patients were stratified into subgroups based on the median values of spherical equivalent(SE)and anterior corneal topographic parameters.Postoperative EOZ parameters were measured 1mo after surgery and compared across subgroups.Correlation analysis and multivariable linear regression analysis were performed to explore the associations between preoperative anterior corneal topographic parameters and EOZ parameters.RESULTS:A total of 310 eyes were included(KLEx:171 eyes from 88 patients;WG-LASIK:139 eyes from 82 patients).The mean age was 30.65±5.67y in the KLEx cohort and 29.06±5.94y in the WG-LASIK cohort.In the KLEx cohort,SE,preoperative mean keratometry(Km),steep keratometry(K2),and anterior corneal astigmatism(K2-K1)were positively correlated with the postoperative optical zone reduction ratio(RR=EOZ/planned optical zone×100%;all P<0.01).Multivariable regression identified SE[β=0.027,95%confidence interval(CI):0.022-0.032,P<0.001],Km(β=0.009,95%CI:0.002-0.016,P=0.014),and anterior corneal astigmatism(β=0.031,95%CI:0.013-0.049,P<0.001)as significant predictors of RR(R²=0.456,P<0.001).In the WG-LASIK cohort,SE was positively correlated with RR(P<0.01);K2 and anterior corneal astigmatism were positively correlated with both RR(P<0.05)and EOZ eccentricity(P<0.01).Multivariable regression showed SE(β=0.015,95%CI:0.007-0.023,P<0.001)and anterior corneal astigmatism(β=0.029,95%CI:0.012-0.047,P=0.001)were significant predictors of RR(R²=0.121,P<0.001).CONCLUSION:Preoperative anterior corneal topographic parameters,particularly anterior corneal astigmatism,significantly affect postoperative EOZ morphology in both KLEx and WG-LASIK.Additionally,Km is a predictor of EOZ reduction specifically in KLEx. 展开更多
关键词 keratorefractive lenticule extraction wavefront-guided LASIK anterior corneal topography effective optical zone optical zone reduction ratio
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Coordination-driven in-situ reduction and extraction of neptunium
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作者 Huaixin Hao Shuyun Zhang +7 位作者 Xue Dong Qilong Tang Yuxiao Guo Yaoyang Liu Jing Chen Jing Su Zhipeng Wang Chao Xu 《Science China Chemistry》 2026年第2期777-783,共7页
The recycling of neptunium(Np)from nuclear wastes is crucial for the sustainable development of nuclear energy,yet it is still a challenging task owing to the complexity of Np chemistry.Precise control of oxidation st... The recycling of neptunium(Np)from nuclear wastes is crucial for the sustainable development of nuclear energy,yet it is still a challenging task owing to the complexity of Np chemistry.Precise control of oxidation state is highly desirable for the effective recovery of Np.In this study,we report an innovative strategy for Np recovery through in-situ coordination and reduction of Np(Ⅴ)in a biphasic extraction system.By leveraging the synergistic effects of coordination by a P=O donating ligand(trialkyl phosphine oxide,TRPO)and reduction by hydroquinone(HQ)in the organic phase,efficient Np(Ⅴ)-to-Np(Ⅳ)conversion and high distribution ratio(D)of Np were achieved in a single extraction contact.The reduction mechanism of Np was elucidated through spectroscopic and theoretical analyses.This work enriches the redox chemistry of Np and provides a novel pathway for Np recovery in advanced nuclear fuel cycles. 展开更多
关键词 NEPTUNIUM COORDINATION REDUCTION extraction
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Flexible High-Aspect-Ratio COF Nanofibers:Defect-Engineered Synthesis,Superelastic Aerogels,and Uranium Extraction Applications
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作者 Binbin Fan Jianyong Yu +2 位作者 Xueli Wang Yang Si Peixin Tang 《Nano-Micro Letters》 2026年第5期15-30,共16页
The lack of macro-continuity and mechanical strength of covalent organic frameworks(COFs)has significantly limited their practical applications.Here,we propose an“alcohol-triggered defect cleavage”strategy to precis... The lack of macro-continuity and mechanical strength of covalent organic frameworks(COFs)has significantly limited their practical applications.Here,we propose an“alcohol-triggered defect cleavage”strategy to precisely regulate the growth and stacking of COF grains through a moderate reversed Schiff base reaction,realizing the direct synthesis of COF nanofibers(CNFs)with high aspect ratio(L/D=103.05)and long length(>20μm).An individual CNF exhibits a biomimetic scale-like architecture,achieving superior flexibility and fatigue resistance under dynamic bending via a multiscale stress dissipation mechanism.Taking advantages of these structural features,we engineer CNF aerogels(CNF-As)with programmable porous structures(e.g.,honeycomb,lamellar,isotropic)via directional ice-template methodology.CNF-As demonstrate 100%COF content,high specific surface area(396.15 m^(2)g^(-1))and superelasticity(~0%elastic deformation after 500 compression cycles at 50%strain),outperforming most COF-based counterparts.Compared with the conventional COF aerogels,the unique structural features of CNF-A enable it to perform outstandingly in uranium extraction,with an 11.72-fold increment in adsorption capacity(920.12 mg g^(-1))and adsorption rate(89.9%),and a 2.48-fold improvement in selectivity(U/V=2.31).This study provides a direct strategy for the development of next-generation COF materials with outstanding functionality and structural robustness. 展开更多
关键词 Defect cleavage COF nanofibers Flexibility AEROGELS Uranium extraction
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Multimodal clinical parameters-based immune status associated with the prognosis in patients with hepatocellular carcinoma
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作者 Yu-Zhou Zhang Yuan-Ze Tang +4 位作者 Yun-Xuan He Shu-Tong Pan Hao-Cheng Dai Yu Liu Hai-Feng Zhou 《World Journal of Gastrointestinal Oncology》 2026年第1期75-91,共17页
Hepatocellular carcinoma presents with three distinct immune phenotypes,including immune-desert,immune-excluded,and immune-inflamed,indicating various treatment responses and prognostic outcomes.The clinical applicati... Hepatocellular carcinoma presents with three distinct immune phenotypes,including immune-desert,immune-excluded,and immune-inflamed,indicating various treatment responses and prognostic outcomes.The clinical application of multi-omics parameters is still restricted by the expensive and less accessible assays,although they accurately reflect immune status.A comprehensive evaluation framework based on“easy-to-obtain”multi-model clinical parameters is urgently required,incorporating clinical features to establish baseline patient profiles and disease staging;routine blood tests assessing systemic metabolic and functional status;immune cell subsets quantifying subcluster dynamics;imaging features delineating tumor morphology,spatial configuration,and perilesional anatomical relationships;immunohistochemical markers positioning qualitative and quantitative detection of tumor antigens from the cellular and molecular level.This integrated phenomic approach aims to improve prognostic stratification and clinical decision-making in hepatocellular carcinoma management conveniently and practically. 展开更多
关键词 Hepatocellular carcinoma Immune status PHENOTYPE Multimodal parameters PROGNOSIS
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Straightforward and versatile construction of phenanthroline-derived diamide ligands for f-block element extraction
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作者 Dong Fang Xiaofan Yang +1 位作者 Fengxin Gao Chengliang Xiao 《Chinese Chemical Letters》 2026年第1期602-605,共4页
As an important class of phenanthroline derivatives containing soft N and hard O donor atoms,the laborious syntheses of unsymmetrical 1,10-phenanthroline-derived diamide ligands(DAPhen) have hindered its extensive stu... As an important class of phenanthroline derivatives containing soft N and hard O donor atoms,the laborious syntheses of unsymmetrical 1,10-phenanthroline-derived diamide ligands(DAPhen) have hindered its extensive study.In this work,we first report a convenient synthetic method for the construction of DAPhen using Friedländer reaction by two facile steps(vs.previous 12 steps).A variety of DAPhen ligands are readily available,especially unsymmetrical ones,which give us a platform to systematically study the substituent effect on f-block elements extraction performance.The performance of unsymmetrical extractants is experimentally confirmed to falls between that of their corresponding symmetrical extractants by extracting UO_(2)^(2+) as the representative f-block element.This work provides a direct and versatile method to synthesize symmetrical and unsymmetrical DAPhen,which paves way for the investigations on their coordination properties with metal ions and other applications. 展开更多
关键词 Phenanthroline diamide ligand Friedlander reaction UNSYMMETRICAL SYMMETRICAL Solvent extraction
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Cutting-edge aminated conjugated microporous poly(aniline)s enabled high-performance membrane for seawater uranium extraction
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作者 Xiaoxia Ye Bingqing Huang +7 位作者 Xueying Chen Yaping Wang Zhihong Zheng Yifan Liu Yuancai Lv Chunxiang Lin Jian Huang Jie Chen 《Green Energy & Environment》 2026年第1期181-194,共14页
The extraction of uranium from seawater via membrane adsorption is a promising strategy for ensuring a long-term supply of uranium and the sustainability of nuclear energy.However,this approach has been hindered by th... The extraction of uranium from seawater via membrane adsorption is a promising strategy for ensuring a long-term supply of uranium and the sustainability of nuclear energy.However,this approach has been hindered by the longstanding challenge of identifying sustainable membrane materials.In response,we propose a prototypal hybridization strategy to design a novel series of aminated conjugated microporous polymer(CMPN)@collagen fiber membrane(COLM).These sustainable and low-cost membrane materials allow a rapid and high-affinity kinetic to capture 90%of the uranium in just 30 min from 50 ppm with a high selectivity of Kd>105 mL·g^(−1).They also afford a robustly reusable adsorption capacity as high as 345 mg·g^(−1)that could harvest 1.61 mg·g^(−1)of uranium in a short 7-day real marine engineering in Fujian Province,even though suffered from very low uranium concentration of 3.29μg·L^(−1)and tough influence of salts such as 10.77 g·L^(−1)of Na^(+),1.75μg·L^(−1)of VO_(3)^(−)etc.in the rough seas.The structural evidence from both experimental and theoretical studies confirmed the formation of favorable chelating motifs from the amino group on CMPN-COLM,and the intensification by the synergistic effect from the size-sieving action of CMPN and the capillary inflow effect of COLM. 展开更多
关键词 Conjugated microporous polymer Collagen fiber MEMBRANE Seawater Uranium extraction
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Enhanced Multi-Scale Feature Extraction Lightweight Network for Remote Sensing Object Detection
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作者 Xiang Luo Yuxuan Peng +2 位作者 Renghong Xie Peng Li Yuwen Qian 《Computers, Materials & Continua》 2026年第3期2097-2118,共22页
Deep learning has made significant progress in the field of oriented object detection for remote sensing images.However,existing methods still face challenges when dealing with difficult tasks such as multi-scale targ... Deep learning has made significant progress in the field of oriented object detection for remote sensing images.However,existing methods still face challenges when dealing with difficult tasks such as multi-scale targets,complex backgrounds,and small objects in remote sensing.Maintaining model lightweight to address resource constraints in remote sensing scenarios while improving task completion for remote sensing tasks remains a research hotspot.Therefore,we propose an enhanced multi-scale feature extraction lightweight network EM-YOLO based on the YOLOv8s architecture,specifically optimized for the characteristics of large target scale variations,diverse orientations,and numerous small objects in remote sensing images.Our innovations lie in two main aspects:First,a dynamic snake convolution(DSC)is introduced into the backbone network to enhance the model’s feature extraction capability for oriented targets.Second,an innovative focusing-diffusion module is designed in the feature fusion neck to effectively integrate multi-scale feature information.Finally,we introduce Layer-Adaptive Sparsity for magnitude-based Pruning(LASP)method to perform lightweight network pruning to better complete tasks in resource-constrained scenarios.Experimental results on the lightweight platform Orin demonstrate that the proposed method significantly outperforms the original YOLOv8s model in oriented remote sensing object detection tasks,and achieves comparable or superior performance to state-of-the-art methods on three authoritative remote sensing datasets(DOTA v1.0,DOTA v1.5,and HRSC2016). 展开更多
关键词 Deep learning object detection feature extraction feature fusion remote sensing
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Single broadband source depth estimation using Stokes parameters in shallow water
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作者 Yizheng Wei Chao Sun +1 位作者 Lei Xie Mingyang Li 《Chinese Physics B》 2026年第2期451-460,共10页
Presented in this study is a novel method for estimating the depth of single underwater source in shallow water,utilizing vector sensors.The approach leverages the depth distribution of the broadband Stokes parameters... Presented in this study is a novel method for estimating the depth of single underwater source in shallow water,utilizing vector sensors.The approach leverages the depth distribution of the broadband Stokes parameters to estimate source depth accurately.Unlike traditional matched field processing(MFP)and matched mode processing(MMP),the proposed approach can estimate source depth directly from the data received by sensors without requiring complete environmental information.Firstly,the broadband Stokes parameters(BSP)are established using the normal mode theory.Then the nonstationary phase approximation is used to simplify the theoretical derivation,which is necessary when dealing with broadband integrals.Additionally,range terms of the BSP are eliminated by normalization.By analyzing the depth distribution of the normalized broadband Stokes parameters(NBSP),it is found that the NBSP exhibit extreme values at the source depth,which can be used for source depth estimation.So the proposed depth estimation method is based on searching the peaks of the NBSP.Simulations show that this method is effective in relatively simple shallow water environments.Finally,the effect of source range,frequency bandwidth,sound speed profile(SSP),water depth,and signal-to-noise ratio(SNR)are studied.The findings indicate that the proposed method can accurately estimate the source depth when the SNR is greater than-5 d B and does not need to consider model mismatch issues.Additionally,variations in environmental parameters have minimal impact on estimation accuracy.Compared to MFP,the proposed method requires a higher SNR,but demonstrates superior robustness against fluctuations in environmental parameters. 展开更多
关键词 broadband source depth estimation shallow water POLARIZATION Stokes parameters
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Investigation of equivalent strength parameters of soil-rock mixture using numerical manifold method
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作者 Junfeng Li Yongtao Yang +2 位作者 Yang Xia Hong Zheng Shuilin Wang 《Journal of Rock Mechanics and Geotechnical Engineering》 2026年第1期637-650,共14页
As binary geological media,soil-rock mixtures(SRMs)exhibit a distinct gradational composition,leading to their unique mechanical behaviors.To appraise the stability of SRM slopes,it is essential to determine equivalen... As binary geological media,soil-rock mixtures(SRMs)exhibit a distinct gradational composition,leading to their unique mechanical behaviors.To appraise the stability of SRM slopes,it is essential to determine equivalent parameters of SRMs,which are typically obtained through experimental and numerical methods.In contrasted to other numerical methods,the numerical manifold method(NMM)is more effective in addressing SRM problems.This is because the high-precision regular mathematical meshes in NMM can be used without aligning with the soil-rock interfaces and boundaries of SRMs.In the current research,the equivalent strength parameters of SRMs,i.e.the equivalent cohesion ce and internal friction angleϕ_(e),are determined using NMM.Initially,an NMM triaxial numerical model is established and validated based on triaxial experiments.Subsequently,the soil and rock parameters are derived through parameter inversion.Moreover,the impacts of rock content,size,shape and rock blocks'major-axis orientation on ce andϕ_(e) of SRMs are thoroughly examined using the NMM triaxial numerical model.Additionally,a fitting function is proposed to linkϕ_(e) to the rock content and size of SRMs.When other influencing factors are fixed,the above fitting model leads to the following conclusions:(1)the predictedϕ_(e) of SRMs increase with the increase of rock content;and(2)SRM samples with smaller rocks display a higher predictedϕ_(e). 展开更多
关键词 Soil-rock mixtures Equivalent strength parameters Numerical manifold method
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LLM-KE: An Ontology-Aware LLM Methodology for Military Domain Knowledge Extraction
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作者 Yu Tao Ruopeng Yang +3 位作者 Yongqi Wen Yihao Zhong Kaige Jiao Xiaolei Gu 《Computers, Materials & Continua》 2026年第1期2045-2061,共17页
Since Google introduced the concept of Knowledge Graphs(KGs)in 2012,their construction technologies have evolved into a comprehensive methodological framework encompassing knowledge acquisition,extraction,representati... Since Google introduced the concept of Knowledge Graphs(KGs)in 2012,their construction technologies have evolved into a comprehensive methodological framework encompassing knowledge acquisition,extraction,representation,modeling,fusion,computation,and storage.Within this framework,knowledge extraction,as the core component,directly determines KG quality.In military domains,traditional manual curation models face efficiency constraints due to data fragmentation,complex knowledge architectures,and confidentiality protocols.Meanwhile,crowdsourced ontology construction approaches from general domains prove non-transferable,while human-crafted ontologies struggle with generalization deficiencies.To address these challenges,this study proposes an OntologyAware LLM Methodology for Military Domain Knowledge Extraction(LLM-KE).This approach leverages the deep semantic comprehension capabilities of Large Language Models(LLMs)to simulate human experts’cognitive processes in crowdsourced ontology construction,enabling automated extraction of military textual knowledge.It concurrently enhances knowledge processing efficiency and improves KG completeness.Empirical analysis demonstrates that this method effectively resolves scalability and dynamic adaptation challenges in military KG construction,establishing a novel technological pathway for advancing military intelligence development. 展开更多
关键词 Knowledge extraction natural language processing knowledge graph large language model
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Recycling of High-Purity Lithium Metal from Waste Battery by Photoelectrochemical Extraction at Ultralow Overall Potential
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作者 Longfei Yang Chao Huang +3 位作者 Yanhong Lyu Dawei Chen Aibin Huang Jianyun Zheng 《Nano-Micro Letters》 2026年第4期371-388,共18页
To ease the scarcity of lithium(Li)resource and cut down on environmental pollution,an efficient,selective,inexpensive and sustainable Li recycling process from waste batteries is needed,which is yet to be achieved.He... To ease the scarcity of lithium(Li)resource and cut down on environmental pollution,an efficient,selective,inexpensive and sustainable Li recycling process from waste batteries is needed,which is yet to be achieved.Here,we report a low-potential photoelectrochemical(PEC)system that selectively and efficiently extracts Li metals from multi-cation electrolytes under 1 sun illumination.Based on the difference of redox potential,we can get rid of the disturbance of other cations(i.e.,Fe,Co and Ni ions)by a bias-free PEC device to realize the extraction of high-purity Li metals on a coplanar Si-based photocathode-TiO_(2) photoanode tandem device at 2 V of applied bias(far less than the redox potentials of Li^(+)/Li).In such system,the extraction rate of Li metals(purity>99.5%)exceeds 1.35 g h^(-1)m^(-2)with 90%of Faradaic efficiency.Long-term experiments,different electrode/electrolyte tests,and various price assessments further demonstrate the stability,compatibility and economy of PEC extraction system,enabling a solar-driven pathway for the recycling of critical metal resources. 展开更多
关键词 Photoelectrochemical method Lithium metals Waste batteries Ultralow-potential device Selective and efficient extraction
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Synergistic lock-anchor engineered diketopyrrolopyrrole-COFs for efficient photocatalytic uranium extraction
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作者 Fengtao Yu Xiaolong Zhang +5 位作者 Jie Xu Guihong Wu Huiying Lei Zhiwu Yu Jianding Qiu Jianli Hua 《Journal of Energy Chemistry》 2026年第1期284-293,I0007,共11页
As a key low-carbon energy source,nuclear power plays a vital role in the global transition toward sustainable energy.Photocatalytic uranium extraction from seawater(UES)offers a promising solution to ensure long-term... As a key low-carbon energy source,nuclear power plays a vital role in the global transition toward sustainable energy.Photocatalytic uranium extraction from seawater(UES)offers a promising solution to ensure long-term uranium supply but is challenged by ultra-low uranium concentrations and ion interference.To overcome these issues,we design three diketopyrrolopyrrole-based covalent organic frameworks(COFs)via a synergisticπ-extended lock and carboxyl-functionalized anchor molecular engineering strategy.Among them,TPy-DPP-COF features a covalently lockedπ-conjugated structure that enhances planarity,optimizes energy alignment,and minimizes exciton binding energy,thereby promoting charge transfer and suppressing recombination.Concurrently,carboxyl groups enable uranyl-specific coordination and create local electric fields to facilitate charge separation.These features contribute to the outstanding performance of TPy-DPP-COF,which achieves a high uranium adsorption capacity of 16.33 mg g−1 in natural seawater under irradiation,with only 29.3%capacity loss after 10 cycles,surpassing industrial benchmarks.Density functional theory(DFT)calculations and experimental studies reveal a synergistic photocatalysis-adsorption pathway,with DPP units acting as active sites for uranium reduction.This work highlights a molecular design strategy for developing efficient COF-based photocatalysts for practical marine uranium recovery. 展开更多
关键词 DIKETOPYRROLOPYRROLE Covalent organic frameworks Exciton binding energy Photocatalytic uranium extraction Synergistic effect
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UAV-to-Ground Channel Modeling:(Quasi-)Closed-Form Channel Statistics and Manual Parameter Estimation
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作者 Zeng Linzhou Liao Xuewen +3 位作者 Xie Wenwu Ma Zhangfeng Xiong Baiping Jiang Hao 《China Communications》 2026年第1期47-66,共20页
(Quasi-)closed-form results for the statistical properties of unmanned aerial vehicle(UAV)airto-ground channels are derived for the first time using a novel spatial-vector-based method from a threedimensional(3-D)arbi... (Quasi-)closed-form results for the statistical properties of unmanned aerial vehicle(UAV)airto-ground channels are derived for the first time using a novel spatial-vector-based method from a threedimensional(3-D)arbitrary-elevation one-cylinder model.The derived results include a closed-form expression for the space-time correlation function and some quasi-closed-form ones for the space-Doppler power spectrum density,the level crossing rate,and the average fading duration,which are shown to be the generalizations of those previously obtained from the two-dimensional(2-D)one-ring model and the 3-D low-elevation one-cylinder model for terrestrial mobile-to-mobile channels.The close agreements between the theoretical results and the simulations as well as the measurements validate the utility of the derived channel statistics.Based on the derived expressions,the impacts of some parameters on the channel characteristics are investigated in an effective,efficient,and explicable way,which leads to a general guideline on the manual parameter estimation from the measurement description. 展开更多
关键词 channel characteristics geometry-based stochastic model manual parameter estimation UAV channel modeling
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Physics-informed machine learning for identifying gradient-distributed plastic parameters of the S38C axle by nano-indentation
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作者 Siyu Li Lvfeng Jiang +4 位作者 Yanan Hu Jian Li Xu Zhang Qianhua Kan Guozheng Kang 《Acta Mechanica Sinica》 2026年第1期105-121,共17页
The S38C railway axle undergoes induction hardening,resulting in a gradient-distributed microstructure and mechanical properties.The accurate identification of gradient-distributed plastic parameters for the S38C axle... The S38C railway axle undergoes induction hardening,resulting in a gradient-distributed microstructure and mechanical properties.The accurate identification of gradient-distributed plastic parameters for the S38C axle remains a challenging task.To tackle this challenge,the present study proposes a novel approach for identifying the gradient-distributed plastic parameters for the S38C axle by integrating nano-indentation techniques with the machine learning method.Firstly,nano-indentation tests are conducted along the radial direction of the S38C axle to obtain the gradient-distributed load-displacement curves,nano-hardness,and elastic modulus.Subsequently,the dimensionless analysis is performed to obtain the representative stress,strain,and yield stress from load-displacement curves.These parameters are then incorporated into the machine learning method as physical information to identify the gradient-distributed plastic parameters of the S38C axle.The results indicate that the proposed method based on the physics-informed neural network and multi-fidelity neural network successfully identifies the gradient-distributed plastic parameters of the S38C axles and demonstrates superior prediction accuracy and generalization compared with the purely data-driven machine learning method. 展开更多
关键词 S38C axle Nanoindentation Physics-informed machine learning Gradient structure Plastic parameters
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Long-term outcomes following lens extraction surgery in acute primary angle closure
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作者 Yi-Ning Guo Jing Ding +3 位作者 Hao-Ran Ai Xin-Zuo Zhou Xue-Min Li Chun Zhang 《International Journal of Ophthalmology(English edition)》 2026年第2期281-290,共10页
AIM:To investigate the long-term outcomes in acute primary angle closure(APAC)patients treated with lens extraction(LE)surgery and to identify risk factors for glaucomatous optic neuropathy(GON).METHODS:In this longit... AIM:To investigate the long-term outcomes in acute primary angle closure(APAC)patients treated with lens extraction(LE)surgery and to identify risk factors for glaucomatous optic neuropathy(GON).METHODS:In this longitudinal observational study,detailed medical histories of APAC patients and comprehensive ophthalmic examinations at final followup were collected.Logistic regression analysis was performed to identify predictors of blindness.Univariate and multivariate linear regression analyses were conducted to determine risk factors associated with visual outcomes.RESULTS:This study included 39 affected eyes of 31 subjects(26 females)with an average age of 74.1±8.0y.At 6.7±4.2y after APAC attack,2(5.7%)eyes had bestcorrected visual acuity(VA)worse than 3/60.Advanced glaucomatous visual field loss was observed in 15(39.5%)affected eyes and 5(25.0%)fellow eyes.Nine affected eyes(23.7%)had GON,and 11(28.9%)were blind.Six(15.4%)affected eyes and 2(9.1%)fellow eyes had suspicious progression.A significantly higher blindness rate in factory workers compared to office workers.Logistic regression identified that worse VA at attack(OR 10.568,95%CI 1.288-86.695;P=0.028)and worse early postoperative VA(OR 13.214,95%CI 1.157-150.881;P=0.038)were risk factors for blindness.Multivariate regression showed that longer duration of elevated intraocular pressure(P=0.004)and worse early postoperative VA(P=0.009)were associated with worse visual outcomes.CONCLUSION:Despite LE surgery,some APAC patients experience continued visual function deterioration.Lifelong monitoring is necessary.Target pressure and progression rates should be re-evaluated during follow-up. 展开更多
关键词 acute primary angle closure lens extraction surgery long-term follow-up visual impairment glaucomatous optic neuropathy
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Photovoltaic Parameter Estimation Using a Parallelized Triangulation Topology Aggregation Optimization with Real-World Dataset Validation
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作者 Jun Zhe Tan Rodney H.G.Tan +4 位作者 Nor Ashidi Mat Isa Sew Sun Tiang Chun Kit Ang Kuo-Ping Lin Wei Hong Lim 《Computer Modeling in Engineering & Sciences》 2026年第2期691-736,共46页
Accurate estimation of photovoltaic(PV)parameters is essential for optimizing solar module perfor-mance and enhancing resource efficiency in renewable energy systems.This study presents a process innovation by introdu... Accurate estimation of photovoltaic(PV)parameters is essential for optimizing solar module perfor-mance and enhancing resource efficiency in renewable energy systems.This study presents a process innovation by introducing,for the first time,the Triangulation Topology Aggregation Optimizer(TTAO)integrated with parallel computing to address PV parameter estimation challenges.The effectiveness and robustness of TTAO are rigorously evaluated using two standard benchmark datasets(KC200GT and R.T.C.France solar cells)and a real-world dataset(Poly70W solar module)under single-,double-,and triple-diode configurations.Results show that TTAO consistently achieves superior accuracy by producing the lowest RMSE values and faster convergence compared to state-of-the-art metaheuristic algorithms.In addition,the integration of parallel computing significantly enhances computational efficiency,reducing execution time by up to 85%without compromising accuracy.Validation using real-world data further demonstrates TTAO’s adaptability and practical relevance in renewable energy systems,effectively bridging the gap between theoretical modeling and real-world implementation for PV system monitoring and optimization,contributing to climate mitigation through improved solar energy performance. 展开更多
关键词 Photovoltaic(PV) parameters estimation triangulation topology aggregation optimizer(TTAO) parallel computing OPTIMIZATION
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Laser-assisted full-size PDC bit:Drilling performance and parameter optimization
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作者 Bin Liu Bin Xu +3 位作者 Biao Li Bo Zhang Xinjie Huang Tongyuan Liu 《Journal of Rock Mechanics and Geotechnical Engineering》 2026年第2期971-985,共15页
Laser-assisted drilling combined with full-size polycrystalline diamond compact(PDC)bit is considered a feasible solution to enhance the drilling performance of engineering machinery.In this method,determining the opt... Laser-assisted drilling combined with full-size polycrystalline diamond compact(PDC)bit is considered a feasible solution to enhance the drilling performance of engineering machinery.In this method,determining the optimal collaborative control parameters that support rapid drilling is crucial for improving the combined performance.This study used average drilling speed,average torque,and total specificenergy for quantitative analysis to characterize the efficiencyand economy of combined rock breaking.Given the advantage of the response surface methodology in providing high-precision predictions with limited experimental data,regression models of the average drilling speed,average torque,and total specificenergy were established.The results showed that as the laser power and irradiation time increased,the average drilling speed firstincreased rapidly and then leveled off,while the average torque decreased sharply before decelerating.The total specificenergy initially decreased and then increased,with the combined drilling outperforming conventional mechanical drilling within specific parameter ranges.As the weight on bit increased,both the average torque and total specificenergy first decreased and then increased.With rising rotating speed,the average torque exhibited a trend of initial increase,then decrease,and finalincrease,whereas the total specificenergy increased slowly at firstand then sharply.Both parameters exhibited optimal values at which the average torque and total specific energy remained at minimal levels.For granite combined drilling,the optimal performance was achieved at a laser power of 3000 W,irradiation time of 31 s,the weight on bit of 2.4 kN,and the rotating speed of 97 r/min. 展开更多
关键词 Laser rock breaking Polycrystalline diamond compact(PDC) CUTTER Combined rock breaking Response surface methodology parameter optimization
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