Ball milling is an environmentally friendly technology for the remediation of petroleumcontaminated soil(PCS),but the cleanup of organic pollutants requires a long time,and the post-remediation soil needs an economica...Ball milling is an environmentally friendly technology for the remediation of petroleumcontaminated soil(PCS),but the cleanup of organic pollutants requires a long time,and the post-remediation soil needs an economically viable disposal/reuse strategy due to its vast volume.The present paper develops a ball milling process under oxygen atmosphere to enhance PCS remediation and reuse the obtained carbonized soil(BCS-O)as wastewater treatment materials.The total petroleum hydrocarbon removal rates by ball milling under vacuum,air,and oxygen atmospheres are 39.83%,55.21%,and 93.84%,respectively.The Langmuir and pseudo second-order models satisfactorily describe the adsorption capacity and behavior of BCS-O for transition metals.The Cu^(2+),Ni^(2+),and Mn^(2+)adsorbed onto BCS-O were mainly bound to metal carbonates and metal oxides.Furthermore,BCS-O can effectively activate persulfate(PDS)oxidation to degrade aniline,while BCS-O loaded with transition metal(BCS-O-Me)shows better activation efficiency and reusability.BCS-O and BCS-O-Me activated PDS oxidation systems are dominated by^(1)O_(2)oxidation and electron transfer.The main active sites are oxygen-containing functional groups,vacancy defects,and graphitized carbon.The oxygen-containing functional groups and vacancy defects primarily activate PDS to generate^(1)O_(2)and attack aniline.Graphitized carbon promotes aniline degradation by accelerating electron transfer.The paper develops an innovative strategy to simultaneously realize efficient remediation of PCS and sequential reuse of the postremediation soil.展开更多
Knowing the optimal operating parameters of Stirling engines is important for efficient combustion through adaptability to changed pressures and oxygen atmospheres. In this study, the optimum operating conditions for ...Knowing the optimal operating parameters of Stirling engines is important for efficient combustion through adaptability to changed pressures and oxygen atmospheres. In this study, the optimum operating conditions for efficient combustion in a singular Stirling engine combustor at different oxygen atmospheres were investigated and determined. Numerical simulations were performed to investigate the effects of ejection ratio and pressure on combustion performance. In an oxygen/carbon dioxide atmosphere, the results show that increasing the ejection ratio substantially alters the flame distribution in the Stirling engine combustor, increasing heat transfer and external combustion efficiency. In contrast, increasing the ejection ratio reduces the average and maximum temperatures of the Stirling engine combustor. Increased pressure affects the flame distribution in the Stirling engine combustor and impedes the flow and convective heat transfer in the combustor, reducing the overall external combustion efficiency at pressures above 6.5 MPa. In an air/carbon dioxide atmosphere, an increased ejection ratio reduces the average and maximum temperatures in the Stirling engine combustor. However, the overall flame distribution does not change substantially. The external combustion efficiency tends to increase and then decrease because of two opposing factors: the increase in the convective heat transfer coefficient and the decrease in the temperature difference. Increasing pressure inhibits forced convection heat transfer in the Stirling engine combustor, reducing external combustion efficiency, which drops from 78% to 65% when pressure increases from 0.2 MPa to 0.5 MPa.展开更多
Yttrium aluminum garnet （YAG） transparent ceramics were fabricated by sintering at oxygen atmosphere. Tetraethyl orthosilicate （TEOS） was added as the sintering additive to control the grain growth and densificati...Yttrium aluminum garnet （YAG） transparent ceramics were fabricated by sintering at oxygen atmosphere. Tetraethyl orthosilicate （TEOS） was added as the sintering additive to control the grain growth and densification. Pores were eliminated clearly at temperature lower than 1700oC, while grain size was around 3 μm. The in-line transmittance was 80% at 1064 nm when samples were sintered at 1710oC. The effect of TEOS was studied in oxygen atmosphere sintering for Nd：YAG transparent ceramics. At higher temperature like 1710oC, the grain growth mechanism was solute drag, while at 1630 and 1550 oC the grain growth was controlled by liquid phase sintering mechanism. And 0.5 wt.% TEOS was the best adding content for Nd：YAG sintered in oxygen atmosphere.展开更多
By means of scanning electron microscope(SEM)and high voltage electron microscope(HVEM)we have observed and analysed morphology and micro-structure of silicon oxide film with different thickness formed on(111)silicon ...By means of scanning electron microscope(SEM)and high voltage electron microscope(HVEM)we have observed and analysed morphology and micro-structure of silicon oxide film with different thickness formed on(111)silicon monocrystal under dry oxygen atmosphere at 1100℃.Compared with their oxidation kinetic curves consisted of three stages,we suggested a mechanism on forming silicon oxide film.According to electron and X-ray diffraction analyses the silicon oxide films consisted of silica with different crystal structure.We also have discussed a stacking fault and a dislocation formed in the Si-Sio_2 interface region simulaneously forming silicon oxide film.展开更多
A number of Precambrian sedimentary basins of the Indian subcontinent offer scope for tracking early oxygenation history of atmosphere and hydrosphere.Available studies,though certainly not exhaustive,record signature...A number of Precambrian sedimentary basins of the Indian subcontinent offer scope for tracking early oxygenation history of atmosphere and hydrosphere.Available studies,though certainly not exhaustive,record signatures of pre-great oxygenation event(GOE)whiffs of atmospheric oxygenation between 3.29 and 3.02 Ga.展开更多
To explore the reaction behavior of trace oxygen during the flash combustion process of falling FeSi75 powder in a nitrogen flow, a flash-combustion-synthesized Fe-Si;N;sample was heat-treated to remove SiO;. The samp...To explore the reaction behavior of trace oxygen during the flash combustion process of falling FeSi75 powder in a nitrogen flow, a flash-combustion-synthesized Fe-Si;N;sample was heat-treated to remove SiO;. The samples before and after the treatment were investigated by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy, and the formation mechanism of SiO;was investigated. The results show that SiO;in the Fe-Si;N;is mainly located on the surface or around the Si;N;particles in dense areas, existing in both crystalline and amorphous states; when the FeSi75 particles, which are less than 0.074 mm in size, fell in up-flowing hot N;stream, trace oxygen in the N;stream did not significantly hinder the nitridation of FeSi75 particles as it was consumed by the surface oxidation of the generated Si;N;particles to form SiO;. At the reaction zone, the oxidation of Si;N;particles decreased the oxygen partial pressure in the N;stream and greatly reduced the opportunity for FeSi75 particles to be oxidized into SiO;; by virtue of the SiO;film developed on the surface, the Si;N;particles adhered to each other and formed dense areas in the material.展开更多
The role of the oxygen in AlGaN/GaN high electron mobility transistors(HEMTs)before and after semi-on state stress was discussed.Comparing with the electrical characteristics of the devices in vacuum,air,and oxygen at...The role of the oxygen in AlGaN/GaN high electron mobility transistors(HEMTs)before and after semi-on state stress was discussed.Comparing with the electrical characteristics of the devices in vacuum,air,and oxygen atmosphere,it is revealed that the oxygen has significant influence on the electric characteristics and the hot-carrier-stress-induced degradation of the device.Comparing with the situation in vacuum,the gate leakage increased an order of magnitude in oxygen and air atmosphere.Double gate structure was used to separate the barrier leakage and surface leakage of AlGaN/GaN HEMT it is found that surface leakage is the major influencing factor in gate leakage of SiN-passivated devices before and after semi-on state stress.During semi-on state stress in the oxygen atmosphere,the electric-field-driven oxidation process promoted the oxidation of the nitride layer,and the oxidation layer in the SiN/AlGaN interface leads to the decreasing of the surface leakage.展开更多
The buildup of oxygen in the Earth＇s atmosphere and oceans has fundamentally reshaped the dynamics of nearly all major biogeochemical cycles and ultimately paved the way for the diversification of complex life on Ear...The buildup of oxygen in the Earth＇s atmosphere and oceans has fundamentally reshaped the dynamics of nearly all major biogeochemical cycles and ultimately paved the way for the diversification of complex life on Earth. Over the past decades there have been sustained efforts to develop a more comprehensive understanding of ocean-atmosphere redox evolution and its relationship to the evolution of early life （Fig. 1）. It is generally accepted that the development of oxygenic photosynthesis at ~2.7 Ga may have been responsible for the Great Oxidation Event （GOE） at the beginning of the Proterozoic Eon, whereas a second big O2 rise at the end of the Proterozoic Eon （the so-called Neoproterozoic Oxidation Event or NOE） was responsible for the diversification of metazoans （Lyons et al., 2014）.展开更多
The late Carboniferous to early Permian period is renowned for extensive coal formation and frequent paleowildfires.Nonetheless,the nature and distribution of these wildfires varied significantly over time.In an effor...The late Carboniferous to early Permian period is renowned for extensive coal formation and frequent paleowildfires.Nonetheless,the nature and distribution of these wildfires varied significantly over time.In an effort to elucidate the patterns of paleowildfires during the late Paleozoic Ice Age and to probe into the controlling mechanisms of paleowildfires under icehouse conditions,a comprehensive analysis was performed on coal samples from the Taiyuan and Shanxi formations within the Dacheng coalfield of Hebei Province,North China.The dataset was augmented with global inertinite data from the late Carboniferous to early Permian periods and was compared to paleowildfire patterns from the Pliocene to Holocene epochs.The results show that paleowildfires in the Dacheng coalfield of North China transitioned from moderate-scale,low-intensity surface fires to large-scale,relatively high-intensity ground fires.Globally,the distribution of paleowildfires shifted from Euramerica to Gondwana,Cathaysia,and Angara from 300 Ma to 290 Ma,accompanied by a corresponding increase in inertinite content.This spatial and temporal variation in wildfire activity appears to have been strongly influenced by paleoclimate and atmospheric conditions.At 300 Ma,cooler and wetter paleoclimate,coupled with relatively low atmospheric pO_(2) levels,likely contributed to a reduced incidence of paleowildfires.In contrast,at 290 Ma,warmer paleoclimate,higher atmospheric pO_(2) levels,and the flourishing mires in Gondwana,Cathaysia,and Angara were conducive to more intense paleowildfires.This pattern is further supported by the comparison to more recent icehouse periods.Similar to the late Carboniferous–early Permian period,wildfire activity increased from the Pliocene to the Holocene,highlighting the critical role of climatic conditions in driving wildfire proliferation under icehouse conditions.However,the Pleistocene to Holocene wildfires were less intense than those of the late Carboniferous–early Permian,suggesting that atmospheric oxygen concentrations played a key role in modulating the evolution of the fire systems over geological timescales.These findings underscore the complex interplay between climate,atmospheric composition,and vegetation in shaping wildfire dynamics across Earth’s history.展开更多
Atmospheric oxygen （02） is the most crucial element on earth for the aerobic organisms that depend on it to release energy from carbon-based macromolecules. This is the first study to systematically analyze the glob...Atmospheric oxygen （02） is the most crucial element on earth for the aerobic organisms that depend on it to release energy from carbon-based macromolecules. This is the first study to systematically analyze the global O2 budget and its changes over the past 100 years. It is found that anthropogenic fossil fuel combustion is the largest contributor to the current O2 deficit, which consumed 2.0 Gt/a in 1900 and has increased to 38.2 Gt/a by 2015. Under the Representative Concentration Pathways （RCPs） RCP8,5 scenario, approximately 100Gt （gigatonnes） of O2 would be removed from the atmosphere per year until 2100, and the O2 concentration will decrease from its current level of 20.946% to 20.825%. Human activities have caused irreversible decline of atmospheric O2. It is time to take actions to promote O2 production and reduce O2 consumption.展开更多
The Cretaceous was a significant greenhouse period in Earth's history with higher atmospheric CO_(2) levels and temperatures than today. Although evidence of combustion has been widely described from the Cretaceou...The Cretaceous was a significant greenhouse period in Earth's history with higher atmospheric CO_(2) levels and temperatures than today. Although evidence of combustion has been widely described from the Cretaceous deposits, our understanding of the spatiotemporal diversification pattern and process of the Cretaceous wildfires is still limited. In this study, we comprehensively synthesize a total of 271 published Cretaceous wildfire occurrences based on the by-products of burning, including fossil charcoal, pyrogenic inertinite(fossil charcoal in coal), and pyrogenic polycyclic aromatic hydrocarbons(PAHs). Spatially, the dataset shows a distinctive distribution of reported wildfire evidence characterized by high concentration in the middle latitudinal areas of the Northern Hemisphere(30°N-60°N) over the Cretaceous. Temporally, an overall increasing trend of the reported wildfire data from the Early Cretaceous to the Late Cretaceous is coincident with higher atmospheric O_(2) levels. However, the spatial and temporal patterns may result from many types of factors, such as taphonomy, preservation, and researcher biases, instead of a real picture of the Cretaceous wildfire evolution. To better understand the spatiotemporal diversification of the Cretaceous wildfire, more investigations on the record of wildfire occurrences during this period would be necessary in the future.展开更多
Secular changes in atmospheric CO_(2)and consequent global climate variations,are commonly attributed to global outgassing and the efficiency of silicate weathering,which may have been linked to mountain formation,lan...Secular changes in atmospheric CO_(2)and consequent global climate variations,are commonly attributed to global outgassing and the efficiency of silicate weathering,which may have been linked to mountain formation,land/arc distribution,and plant colonization through geological time.Although oxidative weathering has been shown to exert a significant role in the propagation of weathering fronts through the oxidation of Fe-bearing minerals,the influence of atmospheric O_(2)concentration(pO_(2))on silicate weathering,CO_(2)consumption,and global climate has not been thoroughly evaluated.This study presents a numerical model aimed at estimating the effects of pO_(2)on the climate,considering the influence of pO_(2)on the regolith thickness and thus weathering duration of granitic domains.Our model simulations reveal that an increase in weathering efficiency,through deeper penetration of the oxidative weathering front in the granitic regolith,would independently introduce a steady-state climate cooling of up to~8℃,in step with one-order of magnitude rise in pO_(2).This temperature change may have repeatedly initiated the runaway ice-albedo feedback,leading to global glacial events(e.g.,Neoproterozoic Snowball Earth).Increasing granitic weathering efficiency caused by a substantial pO_(2)increase may also have contributed to the development of icehouse climate during the Phanerozoic.展开更多
An atmospheric-oxygen-mediated four-component reaction was developed for the divergent synthesis of pyrazolo[1,5-a]pyrimidine and pyrazolo[3,4-b]pyridine derivatives from readily available alcohols and 3-aminopyrazole...An atmospheric-oxygen-mediated four-component reaction was developed for the divergent synthesis of pyrazolo[1,5-a]pyrimidine and pyrazolo[3,4-b]pyridine derivatives from readily available alcohols and 3-aminopyrazoles.In this transformation,atmospheric oxygen serves as the green oxidant,promoting alcohols as equivalent aldehydes for the synthesis of four types of N-containing heterocycles(>40 examples).Remarkably,the transformation features metal-free and molecular diversity.展开更多
The largest global carbon-cycle perturbation in Earth history was recorded in the Ediacaran—a persistent negative shift in the global marine dissolved inorganic carbon(DIC) reservoir that lasted for ~25–50 million y...The largest global carbon-cycle perturbation in Earth history was recorded in the Ediacaran—a persistent negative shift in the global marine dissolved inorganic carbon(DIC) reservoir that lasted for ~25–50 million years, with a nadir of –12‰(i.e.,the Shuram Excursion, or SE). This event is considered to have been a result of full or partial oxidation of a large dissolved organic carbon(DOC) reservoir, which, if correct, provides evidence for massive DOC storage in the Ediacaran ocean owing to an intensive microbial carbon pump(MCP). However, this scenario was recently challenged by new hypotheses that relate the SE to oxidization of recycled continentally derived organic carbon or hydrocarbons from marine seeps. In order to test these competing hypotheses,this paper numerically simulates changes in global carbon cycle fluxes and isotopic compositions during the SE, revealing that:(1) given oxygen levels in the Ediacaran atmosphere-ocean of ≤40% PAL, the recycled continental organic carbon hypothesis and the full oxidation of oceanic DOC reservoir hypothesis are challenged by the atmospheric oxygen availability which would have been depleted in 4 and 6 million years, respectively;(2) the marine-seep hydrocarbon oxidation hypothesis is challenged by the exceedingly large hydrocarbon fluxes required to sustain the SE for >25 Myr; and(3) the heterogeneous(partial) DOC oxidation hypothesis is quantitatively able to account for the SE because the total amount of oxidants needed for partial oxidation(<50%)of the global DOC reservoir could have been met.展开更多
Inertinite,as an important and abundant maceral group in coal,is critical for the study of palaeowildfires and their roles in the Earth’s ecosystems.Recently,there has been a significant amount of research on the rel...Inertinite,as an important and abundant maceral group in coal,is critical for the study of palaeowildfires and their roles in the Earth’s ecosystems.Recently,there has been a significant amount of research on the relationship between palaeowildfire,palaeoclimate change and palaeovegetation evolution based on inertinite data.The reflectance of fusinite and semifusinite has been used to estimate the combustion temperature and type of palaeowildfires,and then to evaluate the combustion characteristics of different types of palaeowildfires.The relative abundance of inertinite can be used to estimate the atmospheric oxygen contents.The rapid development of artificial intelligence(AI)and online tools to search scientific databases has presented an opportunity for us to find,collect,arrange,and analyse data from the earliest to latest publications on inertinite.The data extraction tool Deep Shovel is used to collect and analyse global inertinite data from the Silurian to the Neogene.The software programs such as Gplates,ArcGIS pro and Tableau are then applied to model the relative abundance of inertinite over geological time,which can be correlated with other parameters such as atmospheric oxygen contents,plant evolution and palaeoclimate changes.The distribution of inertinite in coals varied over different geological periods,being typified by the“high inertinite content-high atmospheric oxygen level”period in the Permian and the“low inertinite content-low atmospheric oxygen level”period in the Cenozoic.This study has proposed a possible model of the positive and negative feedbacks between inertinite characteristics and palaeoenvironmental factors,and has revealed the exceptional role of inertinite in palaeoenvironmental studies.Future research on inertinite will be focused on the integrated study of organic petrology and organic geochemistry of inertinite,the big data-driven research on the temporal and spatial distribution of the global inertinite,the exploration of the functions of palaeowildfires in the Earth systems in different climatic backgrounds,and the study of modern wildfires to better predict the future frequency and intensity of wildfires due to climate changes.展开更多
The Ediacaran-Cambrian transition witnessed some of the most important biological,tectonic,climatic and geochemical changes in Earth's history.Of utmost importance for early animal evolution is the likely shift in...The Ediacaran-Cambrian transition witnessed some of the most important biological,tectonic,climatic and geochemical changes in Earth's history.Of utmost importance for early animal evolution is the likely shift in redox conditions of bottom waters,which might have taken place in distinct pulses during the late Ediacaran and early Paleozoic.To track redox changes during this transition,we present new trace element,total organic carbon and both inorganic and organic carbon isotopes,and the first iron speciation data on the Tamengo and Guaicurus formations of the CorumbáGroup in western Brazil,which record important paleobiological changes between 555 Ma to<541 Ma.The stratigraphically older Tamengo Formation is composed mainly of limestone with interbedded marls and mudrocks,and bears fragments of upper Ediacaran biomineralized fossils such as Cloudina lucianoi and Corumbella werneri.The younger Guaicurus Formation represents a regional transgression of the shallow carbonate platform and is composed of a homogeneous fine-grained siliciclastic succession,bearing meiofaunal bilateral burrows.The new iron speciation data reveal predominantly anoxic and ferruginous(non-sulfidic)bottom water conditions during deposition of the Tamengo Formation,with FeHR/FeT around 0.8 and FePy/FeHR below 0.7.The transition from the Tamengo to the Guaicurus Formation is marked by a stratigraphically rapid drop in FeHR/FeT to below 0.2,recording a shift to likely oxic bottom waters,which persist upsection.Redox-sensitive element(RSE)concentrations are muted in both formations,but consistent with non-sulfidic bottom water conditions throughout.We interpret the collected data to reflect a transition between two distinct paleoenvironmental settings.The Tamengo Formation represents an environment with anoxic bottom waters,with fragments of biomineralized organisms that lived on shallower,proba-bly mildly oxygenated surficial waters,and that were then transported down-slope.Similar to coeval suc-cessions(e.g.,the Nama Group in Namibia),our data support the hypothesis that late Ediacaran biomineralized organisms lived in a thin oxygenated surface layer above a relatively shallow chemocline.The Guaicurus Formation,on the other hand,records the expansion of oxic conditions to deeper waters during a sea level rise.Although the relationship between global biogeochemical changes and the activities of early bioturbators remains complex,these results demonstrate an unequivocal synchronous relationship between oxygenation of the Corumbábasin and the local appearance of meiofaunal bioturbators.展开更多
基金supported by the National Natural Science Foundation of China(No.41772240)the Key Research and Development program of Jiangsu Province(No.BE2021637).
文摘Ball milling is an environmentally friendly technology for the remediation of petroleumcontaminated soil(PCS),but the cleanup of organic pollutants requires a long time,and the post-remediation soil needs an economically viable disposal/reuse strategy due to its vast volume.The present paper develops a ball milling process under oxygen atmosphere to enhance PCS remediation and reuse the obtained carbonized soil(BCS-O)as wastewater treatment materials.The total petroleum hydrocarbon removal rates by ball milling under vacuum,air,and oxygen atmospheres are 39.83%,55.21%,and 93.84%,respectively.The Langmuir and pseudo second-order models satisfactorily describe the adsorption capacity and behavior of BCS-O for transition metals.The Cu^(2+),Ni^(2+),and Mn^(2+)adsorbed onto BCS-O were mainly bound to metal carbonates and metal oxides.Furthermore,BCS-O can effectively activate persulfate(PDS)oxidation to degrade aniline,while BCS-O loaded with transition metal(BCS-O-Me)shows better activation efficiency and reusability.BCS-O and BCS-O-Me activated PDS oxidation systems are dominated by^(1)O_(2)oxidation and electron transfer.The main active sites are oxygen-containing functional groups,vacancy defects,and graphitized carbon.The oxygen-containing functional groups and vacancy defects primarily activate PDS to generate^(1)O_(2)and attack aniline.Graphitized carbon promotes aniline degradation by accelerating electron transfer.The paper develops an innovative strategy to simultaneously realize efficient remediation of PCS and sequential reuse of the postremediation soil.
基金Supported by the Shanghai Rising Star Program (Grant No. 21QB1403900)the Shanghai Municipal Commission of Science and Technology (Grant No. 22170712600)。
文摘Knowing the optimal operating parameters of Stirling engines is important for efficient combustion through adaptability to changed pressures and oxygen atmospheres. In this study, the optimum operating conditions for efficient combustion in a singular Stirling engine combustor at different oxygen atmospheres were investigated and determined. Numerical simulations were performed to investigate the effects of ejection ratio and pressure on combustion performance. In an oxygen/carbon dioxide atmosphere, the results show that increasing the ejection ratio substantially alters the flame distribution in the Stirling engine combustor, increasing heat transfer and external combustion efficiency. In contrast, increasing the ejection ratio reduces the average and maximum temperatures of the Stirling engine combustor. Increased pressure affects the flame distribution in the Stirling engine combustor and impedes the flow and convective heat transfer in the combustor, reducing the overall external combustion efficiency at pressures above 6.5 MPa. In an air/carbon dioxide atmosphere, an increased ejection ratio reduces the average and maximum temperatures in the Stirling engine combustor. However, the overall flame distribution does not change substantially. The external combustion efficiency tends to increase and then decrease because of two opposing factors: the increase in the convective heat transfer coefficient and the decrease in the temperature difference. Increasing pressure inhibits forced convection heat transfer in the Stirling engine combustor, reducing external combustion efficiency, which drops from 78% to 65% when pressure increases from 0.2 MPa to 0.5 MPa.
基金Project supported by National Natural Science Foundation of China(50990301,51172263,51072210)Science and Technology Commission of Shanghai Municipality(12ZR1451900)
文摘Yttrium aluminum garnet （YAG） transparent ceramics were fabricated by sintering at oxygen atmosphere. Tetraethyl orthosilicate （TEOS） was added as the sintering additive to control the grain growth and densification. Pores were eliminated clearly at temperature lower than 1700oC, while grain size was around 3 μm. The in-line transmittance was 80% at 1064 nm when samples were sintered at 1710oC. The effect of TEOS was studied in oxygen atmosphere sintering for Nd：YAG transparent ceramics. At higher temperature like 1710oC, the grain growth mechanism was solute drag, while at 1630 and 1550 oC the grain growth was controlled by liquid phase sintering mechanism. And 0.5 wt.% TEOS was the best adding content for Nd：YAG sintered in oxygen atmosphere.
文摘By means of scanning electron microscope(SEM)and high voltage electron microscope(HVEM)we have observed and analysed morphology and micro-structure of silicon oxide film with different thickness formed on(111)silicon monocrystal under dry oxygen atmosphere at 1100℃.Compared with their oxidation kinetic curves consisted of three stages,we suggested a mechanism on forming silicon oxide film.According to electron and X-ray diffraction analyses the silicon oxide films consisted of silica with different crystal structure.We also have discussed a stacking fault and a dislocation formed in the Si-Sio_2 interface region simulaneously forming silicon oxide film.
基金JM acknowledges FRPDF grant for his research from Presidency University,KolkataPPC and PP acknowledges UGC major project grant for carrying out work at the Gwalior basin.
文摘A number of Precambrian sedimentary basins of the Indian subcontinent offer scope for tracking early oxygenation history of atmosphere and hydrosphere.Available studies,though certainly not exhaustive,record signatures of pre-great oxygenation event(GOE)whiffs of atmospheric oxygenation between 3.29 and 3.02 Ga.
基金financially supported by the National Nature Science Foundation of China (No.51572019)
文摘To explore the reaction behavior of trace oxygen during the flash combustion process of falling FeSi75 powder in a nitrogen flow, a flash-combustion-synthesized Fe-Si;N;sample was heat-treated to remove SiO;. The samples before and after the treatment were investigated by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy, and the formation mechanism of SiO;was investigated. The results show that SiO;in the Fe-Si;N;is mainly located on the surface or around the Si;N;particles in dense areas, existing in both crystalline and amorphous states; when the FeSi75 particles, which are less than 0.074 mm in size, fell in up-flowing hot N;stream, trace oxygen in the N;stream did not significantly hinder the nitridation of FeSi75 particles as it was consumed by the surface oxidation of the generated Si;N;particles to form SiO;. At the reaction zone, the oxidation of Si;N;particles decreased the oxygen partial pressure in the N;stream and greatly reduced the opportunity for FeSi75 particles to be oxidized into SiO;; by virtue of the SiO;film developed on the surface, the Si;N;particles adhered to each other and formed dense areas in the material.
基金supported by the National Natural Science Foundation of China(Grant No.62104167)the Natural Science Foundation of Jiangsu Province,China(Grant Nos.BK20210863 and BK20180966)by Qing Lan Project of Jiangsu Province,China.
文摘The role of the oxygen in AlGaN/GaN high electron mobility transistors(HEMTs)before and after semi-on state stress was discussed.Comparing with the electrical characteristics of the devices in vacuum,air,and oxygen atmosphere,it is revealed that the oxygen has significant influence on the electric characteristics and the hot-carrier-stress-induced degradation of the device.Comparing with the situation in vacuum,the gate leakage increased an order of magnitude in oxygen and air atmosphere.Double gate structure was used to separate the barrier leakage and surface leakage of AlGaN/GaN HEMT it is found that surface leakage is the major influencing factor in gate leakage of SiN-passivated devices before and after semi-on state stress.During semi-on state stress in the oxygen atmosphere,the electric-field-driven oxidation process promoted the oxidation of the nitride layer,and the oxidation layer in the SiN/AlGaN interface leads to the decreasing of the surface leakage.
文摘The buildup of oxygen in the Earth＇s atmosphere and oceans has fundamentally reshaped the dynamics of nearly all major biogeochemical cycles and ultimately paved the way for the diversification of complex life on Earth. Over the past decades there have been sustained efforts to develop a more comprehensive understanding of ocean-atmosphere redox evolution and its relationship to the evolution of early life （Fig. 1）. It is generally accepted that the development of oxygenic photosynthesis at ~2.7 Ga may have been responsible for the Great Oxidation Event （GOE） at the beginning of the Proterozoic Eon, whereas a second big O2 rise at the end of the Proterozoic Eon （the so-called Neoproterozoic Oxidation Event or NOE） was responsible for the diversification of metazoans （Lyons et al., 2014）.
基金supported by the National Natural Science Foundation of China(Grant No.42302205 and No.42002128)the Fundamental Research Funding Project of Liaoning Education Department(Grant No.LJKMZ20220692)the Open Fund of State Key Laboratory of Coal Resources and Safe Mining(Grant No.SKLCRSM22KFA07 and No.SKLCRSM20KFA02).
文摘The late Carboniferous to early Permian period is renowned for extensive coal formation and frequent paleowildfires.Nonetheless,the nature and distribution of these wildfires varied significantly over time.In an effort to elucidate the patterns of paleowildfires during the late Paleozoic Ice Age and to probe into the controlling mechanisms of paleowildfires under icehouse conditions,a comprehensive analysis was performed on coal samples from the Taiyuan and Shanxi formations within the Dacheng coalfield of Hebei Province,North China.The dataset was augmented with global inertinite data from the late Carboniferous to early Permian periods and was compared to paleowildfire patterns from the Pliocene to Holocene epochs.The results show that paleowildfires in the Dacheng coalfield of North China transitioned from moderate-scale,low-intensity surface fires to large-scale,relatively high-intensity ground fires.Globally,the distribution of paleowildfires shifted from Euramerica to Gondwana,Cathaysia,and Angara from 300 Ma to 290 Ma,accompanied by a corresponding increase in inertinite content.This spatial and temporal variation in wildfire activity appears to have been strongly influenced by paleoclimate and atmospheric conditions.At 300 Ma,cooler and wetter paleoclimate,coupled with relatively low atmospheric pO_(2) levels,likely contributed to a reduced incidence of paleowildfires.In contrast,at 290 Ma,warmer paleoclimate,higher atmospheric pO_(2) levels,and the flourishing mires in Gondwana,Cathaysia,and Angara were conducive to more intense paleowildfires.This pattern is further supported by the comparison to more recent icehouse periods.Similar to the late Carboniferous–early Permian period,wildfire activity increased from the Pliocene to the Holocene,highlighting the critical role of climatic conditions in driving wildfire proliferation under icehouse conditions.However,the Pleistocene to Holocene wildfires were less intense than those of the late Carboniferous–early Permian,suggesting that atmospheric oxygen concentrations played a key role in modulating the evolution of the fire systems over geological timescales.These findings underscore the complex interplay between climate,atmospheric composition,and vegetation in shaping wildfire dynamics across Earth’s history.
基金supported by the National Natural Science Foundation of China (41521004)the China University Research Talents Recruitment Program (111 project, B13045)
文摘Atmospheric oxygen （02） is the most crucial element on earth for the aerobic organisms that depend on it to release energy from carbon-based macromolecules. This is the first study to systematically analyze the global O2 budget and its changes over the past 100 years. It is found that anthropogenic fossil fuel combustion is the largest contributor to the current O2 deficit, which consumed 2.0 Gt/a in 1900 and has increased to 38.2 Gt/a by 2015. Under the Representative Concentration Pathways （RCPs） RCP8,5 scenario, approximately 100Gt （gigatonnes） of O2 would be removed from the atmosphere per year until 2100, and the O2 concentration will decrease from its current level of 20.946% to 20.825%. Human activities have caused irreversible decline of atmospheric O2. It is time to take actions to promote O2 production and reduce O2 consumption.
基金financially supported by the National Natural Science Foundation of China (Grant Nos.42102127, 42172117)the Natural Science Foundation of Shandong Province (Grant No. ZR2021QD087)+1 种基金the Chinese Postdoctoral Science Foundation (Grant No.2021M702019)the SDUST Research Fund,Shandong University of Science and Technology (Grant No.2018TDJH101)。
文摘The Cretaceous was a significant greenhouse period in Earth's history with higher atmospheric CO_(2) levels and temperatures than today. Although evidence of combustion has been widely described from the Cretaceous deposits, our understanding of the spatiotemporal diversification pattern and process of the Cretaceous wildfires is still limited. In this study, we comprehensively synthesize a total of 271 published Cretaceous wildfire occurrences based on the by-products of burning, including fossil charcoal, pyrogenic inertinite(fossil charcoal in coal), and pyrogenic polycyclic aromatic hydrocarbons(PAHs). Spatially, the dataset shows a distinctive distribution of reported wildfire evidence characterized by high concentration in the middle latitudinal areas of the Northern Hemisphere(30°N-60°N) over the Cretaceous. Temporally, an overall increasing trend of the reported wildfire data from the Early Cretaceous to the Late Cretaceous is coincident with higher atmospheric O_(2) levels. However, the spatial and temporal patterns may result from many types of factors, such as taphonomy, preservation, and researcher biases, instead of a real picture of the Cretaceous wildfire evolution. To better understand the spatiotemporal diversification of the Cretaceous wildfire, more investigations on the record of wildfire occurrences during this period would be necessary in the future.
基金supported by the National Natural Science Foundation of China(42325302,42373056,41991321)。
文摘Secular changes in atmospheric CO_(2)and consequent global climate variations,are commonly attributed to global outgassing and the efficiency of silicate weathering,which may have been linked to mountain formation,land/arc distribution,and plant colonization through geological time.Although oxidative weathering has been shown to exert a significant role in the propagation of weathering fronts through the oxidation of Fe-bearing minerals,the influence of atmospheric O_(2)concentration(pO_(2))on silicate weathering,CO_(2)consumption,and global climate has not been thoroughly evaluated.This study presents a numerical model aimed at estimating the effects of pO_(2)on the climate,considering the influence of pO_(2)on the regolith thickness and thus weathering duration of granitic domains.Our model simulations reveal that an increase in weathering efficiency,through deeper penetration of the oxidative weathering front in the granitic regolith,would independently introduce a steady-state climate cooling of up to~8℃,in step with one-order of magnitude rise in pO_(2).This temperature change may have repeatedly initiated the runaway ice-albedo feedback,leading to global glacial events(e.g.,Neoproterozoic Snowball Earth).Increasing granitic weathering efficiency caused by a substantial pO_(2)increase may also have contributed to the development of icehouse climate during the Phanerozoic.
基金the National Natural Science Foundation of China(22201203).
文摘An atmospheric-oxygen-mediated four-component reaction was developed for the divergent synthesis of pyrazolo[1,5-a]pyrimidine and pyrazolo[3,4-b]pyridine derivatives from readily available alcohols and 3-aminopyrazoles.In this transformation,atmospheric oxygen serves as the green oxidant,promoting alcohols as equivalent aldehydes for the synthesis of four types of N-containing heterocycles(>40 examples).Remarkably,the transformation features metal-free and molecular diversity.
基金supported by the National Program on Key Basic Research Project(Grant No.2013CB955704)the National Key Research and Development Program of China(Grant No.2016YFA0601100)+2 种基金the NSFC-RCUK_NERC Program(Grant No.41661134048)the Fundamental Research Funds for Central Universities(Grant Nos.CUG-Wuhan,grants 1610491T01 and G1323531767)the NASA Exobiology Program(TJA)
文摘The largest global carbon-cycle perturbation in Earth history was recorded in the Ediacaran—a persistent negative shift in the global marine dissolved inorganic carbon(DIC) reservoir that lasted for ~25–50 million years, with a nadir of –12‰(i.e.,the Shuram Excursion, or SE). This event is considered to have been a result of full or partial oxidation of a large dissolved organic carbon(DOC) reservoir, which, if correct, provides evidence for massive DOC storage in the Ediacaran ocean owing to an intensive microbial carbon pump(MCP). However, this scenario was recently challenged by new hypotheses that relate the SE to oxidization of recycled continentally derived organic carbon or hydrocarbons from marine seeps. In order to test these competing hypotheses,this paper numerically simulates changes in global carbon cycle fluxes and isotopic compositions during the SE, revealing that:(1) given oxygen levels in the Ediacaran atmosphere-ocean of ≤40% PAL, the recycled continental organic carbon hypothesis and the full oxidation of oceanic DOC reservoir hypothesis are challenged by the atmospheric oxygen availability which would have been depleted in 4 and 6 million years, respectively;(2) the marine-seep hydrocarbon oxidation hypothesis is challenged by the exceedingly large hydrocarbon fluxes required to sustain the SE for >25 Myr; and(3) the heterogeneous(partial) DOC oxidation hypothesis is quantitatively able to account for the SE because the total amount of oxidants needed for partial oxidation(<50%)of the global DOC reservoir could have been met.
基金supported by the National Natural Science Foundation of China(Grant Nos.42321002,41572090)the Deep-time Digital Earth(DDE)Big Science Program。
文摘Inertinite,as an important and abundant maceral group in coal,is critical for the study of palaeowildfires and their roles in the Earth’s ecosystems.Recently,there has been a significant amount of research on the relationship between palaeowildfire,palaeoclimate change and palaeovegetation evolution based on inertinite data.The reflectance of fusinite and semifusinite has been used to estimate the combustion temperature and type of palaeowildfires,and then to evaluate the combustion characteristics of different types of palaeowildfires.The relative abundance of inertinite can be used to estimate the atmospheric oxygen contents.The rapid development of artificial intelligence(AI)and online tools to search scientific databases has presented an opportunity for us to find,collect,arrange,and analyse data from the earliest to latest publications on inertinite.The data extraction tool Deep Shovel is used to collect and analyse global inertinite data from the Silurian to the Neogene.The software programs such as Gplates,ArcGIS pro and Tableau are then applied to model the relative abundance of inertinite over geological time,which can be correlated with other parameters such as atmospheric oxygen contents,plant evolution and palaeoclimate changes.The distribution of inertinite in coals varied over different geological periods,being typified by the“high inertinite content-high atmospheric oxygen level”period in the Permian and the“low inertinite content-low atmospheric oxygen level”period in the Cenozoic.This study has proposed a possible model of the positive and negative feedbacks between inertinite characteristics and palaeoenvironmental factors,and has revealed the exceptional role of inertinite in palaeoenvironmental studies.Future research on inertinite will be focused on the integrated study of organic petrology and organic geochemistry of inertinite,the big data-driven research on the temporal and spatial distribution of the global inertinite,the exploration of the functions of palaeowildfires in the Earth systems in different climatic backgrounds,and the study of modern wildfires to better predict the future frequency and intensity of wildfires due to climate changes.
基金supported by CNPq-Brazil through grants nb.408815/2021-3 and 304509/2021-3by Instituto Serrapilheira through Project“MOBILE:Mountain Belts and the Inception of Complex Life on Earth(geolifemobile.com)”,grant no.Serra-1912-31510,and by the Worldwide Universities Network-WUN through their Research Development Fund(RDF 2022)+3 种基金The first author is part of Instituto GeoAtlântico,a National Institute of Science and Technology,CNPq-Brazil process nb.405653/2022-0Most of the data presented here was acquired during a sevenmonth visiting research appointment of FAC at the Stanford Doerr School of Sustainability supported by CAPES-Brazil through their PRINT program(88887.682318/2022-00)EAS and some geochemical analyses at Stanford were supported by U.S.National Science Foundation grant EAR-2143164MG was supported by the Research Foundation of the Federal District(FAPDF)-process no.0193.001609/2017。
文摘The Ediacaran-Cambrian transition witnessed some of the most important biological,tectonic,climatic and geochemical changes in Earth's history.Of utmost importance for early animal evolution is the likely shift in redox conditions of bottom waters,which might have taken place in distinct pulses during the late Ediacaran and early Paleozoic.To track redox changes during this transition,we present new trace element,total organic carbon and both inorganic and organic carbon isotopes,and the first iron speciation data on the Tamengo and Guaicurus formations of the CorumbáGroup in western Brazil,which record important paleobiological changes between 555 Ma to<541 Ma.The stratigraphically older Tamengo Formation is composed mainly of limestone with interbedded marls and mudrocks,and bears fragments of upper Ediacaran biomineralized fossils such as Cloudina lucianoi and Corumbella werneri.The younger Guaicurus Formation represents a regional transgression of the shallow carbonate platform and is composed of a homogeneous fine-grained siliciclastic succession,bearing meiofaunal bilateral burrows.The new iron speciation data reveal predominantly anoxic and ferruginous(non-sulfidic)bottom water conditions during deposition of the Tamengo Formation,with FeHR/FeT around 0.8 and FePy/FeHR below 0.7.The transition from the Tamengo to the Guaicurus Formation is marked by a stratigraphically rapid drop in FeHR/FeT to below 0.2,recording a shift to likely oxic bottom waters,which persist upsection.Redox-sensitive element(RSE)concentrations are muted in both formations,but consistent with non-sulfidic bottom water conditions throughout.We interpret the collected data to reflect a transition between two distinct paleoenvironmental settings.The Tamengo Formation represents an environment with anoxic bottom waters,with fragments of biomineralized organisms that lived on shallower,proba-bly mildly oxygenated surficial waters,and that were then transported down-slope.Similar to coeval suc-cessions(e.g.,the Nama Group in Namibia),our data support the hypothesis that late Ediacaran biomineralized organisms lived in a thin oxygenated surface layer above a relatively shallow chemocline.The Guaicurus Formation,on the other hand,records the expansion of oxic conditions to deeper waters during a sea level rise.Although the relationship between global biogeochemical changes and the activities of early bioturbators remains complex,these results demonstrate an unequivocal synchronous relationship between oxygenation of the Corumbábasin and the local appearance of meiofaunal bioturbators.
