Through successive one-electron reduction processes,a coordinatively unsaturated thiolate-bridged CoIICoII complex[Cp*Co(μ-SEt)_(2)CoCp*](1)was facilely generated in high yield.In the presence of O_(2),complex 1 can ...Through successive one-electron reduction processes,a coordinatively unsaturated thiolate-bridged CoIICoII complex[Cp*Co(μ-SEt)_(2)CoCp*](1)was facilely generated in high yield.In the presence of O_(2),complex 1 can smoothly take up CO_(2),and then install it at the Co_(2)S_(2)scaffold in the form of a carbonate bridge to give complex[Cp*Co(μ-SEt)_(2)(μ–η^(1):η^(1)-CO_(3))CoCp*](2).展开更多
基金supported by the National Natural Science Foundation of China(No.21690064,21571026,and 21231003)the Program for Changjiang Scholars and Innovative Research Team in University(No.IRT13008)the“111”project of the Ministry of Education of China.
文摘Through successive one-electron reduction processes,a coordinatively unsaturated thiolate-bridged CoIICoII complex[Cp*Co(μ-SEt)_(2)CoCp*](1)was facilely generated in high yield.In the presence of O_(2),complex 1 can smoothly take up CO_(2),and then install it at the Co_(2)S_(2)scaffold in the form of a carbonate bridge to give complex[Cp*Co(μ-SEt)_(2)(μ–η^(1):η^(1)-CO_(3))CoCp*](2).
