Catalytic properties of the metal-organic framework Cr-MIL-101 in solvent-free cycloaddition of CO2 to epoxides to produce cyclic carbon- ates using tetrabutylammonium bromide as co-catalyst have been explored under m...Catalytic properties of the metal-organic framework Cr-MIL-101 in solvent-free cycloaddition of CO2 to epoxides to produce cyclic carbon- ates using tetrabutylammonium bromide as co-catalyst have been explored under mild reaction conditions （8 bar CO2, 25 ~C）. Styrene and propylene carbonates were formed with high yields （95% and 82%, respectively）. Catalytic performance of Cr-MIL-101 was compared with other MOFs： Fe-MIL-101, Zn-MOF-5 and HKUST-1, The catalytic properties of different quaternary ammonium bromides, Cr-MIL-101 as well as PW12/Cr-MIL-101 composite material have been assessed in oxidative carboxylation of styrene in the presence of both tert-butyl hydroperoxide and H202 as oxidants at 8-100bar CO2 and 25-80 ~C with selectivity to styrene carbonate up to 44% at 57% substrate conversion.展开更多
The carboxyl-functionalized graphene oxide(GO-COOH)is a kind of unique two-dimensional(2 D)material and possesses excellent nonlinear saturable absorption property and high water-solubility.In this paper,we prepare sa...The carboxyl-functionalized graphene oxide(GO-COOH)is a kind of unique two-dimensional(2 D)material and possesses excellent nonlinear saturable absorption property and high water-solubility.In this paper,we prepare saturable absorber(SA)device by depositing GO-COOH nanosheets aqueous solution on a D-shaped fiber.The modulation depth(MD)and saturable intensity of the SA are measured to be 9.6%and 19 MW/cm^(2),respectively.By inserting the SA into the erbium-doped fiber(EDF)laser,a passively mode-locked EDF laser has been achieved with the spectrum center wavelength of 1562.76 nm.The pulse duration,repetition rate,and the signal-to-noise ratio(SNR)are 500 fs,14.79 MHz,and 80 dB,respectively.The maximum average output power is measured to be 3.85 mW.These results indicate that the GO-COOH nanosheets SA can be used as a promising mode locker for the generation of ultrashort pulses.展开更多
A novel bromination of α,β-unsaturated carboxylic acids was developed via a decarboxylation by virtue of a direct anodic electro-oxidation.In this method,ammonium bromide was employed as a bromine source and the rea...A novel bromination of α,β-unsaturated carboxylic acids was developed via a decarboxylation by virtue of a direct anodic electro-oxidation.In this method,ammonium bromide was employed as a bromine source and the reaction features transition-metal-free,short time,and no additional supporting electrolyte.展开更多
基金the Russian Foundation for Basic Research(RFBR grant12-03-31537)
文摘Catalytic properties of the metal-organic framework Cr-MIL-101 in solvent-free cycloaddition of CO2 to epoxides to produce cyclic carbon- ates using tetrabutylammonium bromide as co-catalyst have been explored under mild reaction conditions （8 bar CO2, 25 ~C）. Styrene and propylene carbonates were formed with high yields （95% and 82%, respectively）. Catalytic performance of Cr-MIL-101 was compared with other MOFs： Fe-MIL-101, Zn-MOF-5 and HKUST-1, The catalytic properties of different quaternary ammonium bromides, Cr-MIL-101 as well as PW12/Cr-MIL-101 composite material have been assessed in oxidative carboxylation of styrene in the presence of both tert-butyl hydroperoxide and H202 as oxidants at 8-100bar CO2 and 25-80 ~C with selectivity to styrene carbonate up to 44% at 57% substrate conversion.
基金Project supported by the Central University Special Fund Basic Research and Operating Expenses,China(Grant No.GK201702005)the Natural Science Foundation of Shaanxi Province,China(Grant No.2017JM6091)+1 种基金the National Natural Science Foundation of China(Grant No.61705183)the Fundamental Research Funds for the Central Universities,China(Grant No.2017TS011)
文摘The carboxyl-functionalized graphene oxide(GO-COOH)is a kind of unique two-dimensional(2 D)material and possesses excellent nonlinear saturable absorption property and high water-solubility.In this paper,we prepare saturable absorber(SA)device by depositing GO-COOH nanosheets aqueous solution on a D-shaped fiber.The modulation depth(MD)and saturable intensity of the SA are measured to be 9.6%and 19 MW/cm^(2),respectively.By inserting the SA into the erbium-doped fiber(EDF)laser,a passively mode-locked EDF laser has been achieved with the spectrum center wavelength of 1562.76 nm.The pulse duration,repetition rate,and the signal-to-noise ratio(SNR)are 500 fs,14.79 MHz,and 80 dB,respectively.The maximum average output power is measured to be 3.85 mW.These results indicate that the GO-COOH nanosheets SA can be used as a promising mode locker for the generation of ultrashort pulses.
基金the National Nature Science Foundation of China(Nos.21472177,21672200,21432009,J1310010)the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000)
文摘A novel bromination of α,β-unsaturated carboxylic acids was developed via a decarboxylation by virtue of a direct anodic electro-oxidation.In this method,ammonium bromide was employed as a bromine source and the reaction features transition-metal-free,short time,and no additional supporting electrolyte.
