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Asymmetric Side‑Group Engineering of Nonfused Ring Electron Acceptors for High‑Efficiency Thick‑Film Organic Solar Cells
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作者 Dawei Li Nan Wei +11 位作者 Ya‑Nan Chen Xiaodong Wang Xu Han Ziqing Bian Xinyuan Zhang Zhe Zhang Wenkai Zhang Xinjun Xu Cuihong Li Yahui Liu Hao Lu Zhishan Bo 《Nano-Micro Letters》 2026年第3期227-239,共13页
A nonfused ring electron acceptor(NFREA),designated as TT-Ph-C6,has been synthesized with the aim of enhancing the power conversion efficiency(PCE)of organic solar cells(OSCs).By integrating asymmetric phenylalkylamin... A nonfused ring electron acceptor(NFREA),designated as TT-Ph-C6,has been synthesized with the aim of enhancing the power conversion efficiency(PCE)of organic solar cells(OSCs).By integrating asymmetric phenylalkylamino side groups,TT-Ph-C6 demonstrates excellent solubility and its crystal structure exhibits compact packing structures with a three-dimensional molecular stacking network.These structural attributes markedly promote exciton diffusion and charge carrier mobility,particularly advantageous for the fabrication of thick-film devices.TT-Ph-C6-based devices have attained a PCE of 18.01%at a film thickness of 100 nm,and even at a film thickness of 300 nm,the PCE remains at 14.64%,surpassing that of devices based on 2BTh-2F.These remarkable properties position TT-Ph-C6 as a highly promising NFREA material for boosting the efficiency of OSCs. 展开更多
关键词 Organic solar cells Nonfused ring electron acceptors ASYMMETRIC Power conversion efficiency
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A deep-junction single-photon detector with field polysilicon gate structure for increased photon detection efficiency and reduced dark count noise
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作者 Zhentao Ni Dajing Bian +2 位作者 Haoxiang Jiang Xiaoming Huang Yue Xu 《Journal of Semiconductors》 2026年第1期65-71,共7页
A high-sensitivity,low-noise single photon avalanche diode(SPAD)detector was presented based on a 180 nm BCD process.The proposed device utilizes a p-implant layer/high-voltage n-well(HVNW)junction to form a deep aval... A high-sensitivity,low-noise single photon avalanche diode(SPAD)detector was presented based on a 180 nm BCD process.The proposed device utilizes a p-implant layer/high-voltage n-well(HVNW)junction to form a deep avalanche multiplication region for near-infrared(NIR)sensitivity enhancement.By optimizing the device size and electric field of the guard ring,the fill factor(FF)is significantly improved,further increasing photon detection efficiency(PDE).To solve the dark noise caused by the increasing active diameter,a field polysilicon gate structure connected to the p+anode was investigated,effectively suppressing dark count noise by 76.6%.It is experimentally shown that when the active diameter increases from 5 to 10μm,the FF is significantly improved from 20.7%to 39.1%,and thus the peak PDE also rises from 13.3%to 25.8%.At an excess bias voltage of 5 V,a NIR photon detection probability(PDP)of 6.8%at 905 nm,a dark count rate(DCR)of 2.12 cps/μm^(2),an afterpulsing probability(AP)of 1.2%,and a timing jitter of 216 ps are achieved,demonstrating excellent single photon detection performance. 展开更多
关键词 single-photon avalanche diode(SPAD) fill factor(FF) photon detection efficiency(PDE) dark count rate(DCR)
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Enhancing Solar Photovoltaic Efficiency:A Computational Fluid Dynamics Analysis 被引量:1
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作者 Rahool Rai Fareed Hussain Mangi +1 位作者 Kashif Ahmed Sudhakar Kumaramsay 《Energy Engineering》 EI 2025年第1期153-166,共14页
The growing need for sustainable energy solutions,driven by rising energy shortages,environmental concerns,and the depletion of conventional energy sources,has led to a significant focus on renewable energy.Solar ener... The growing need for sustainable energy solutions,driven by rising energy shortages,environmental concerns,and the depletion of conventional energy sources,has led to a significant focus on renewable energy.Solar energy,among the various renewable sources,is particularly appealing due to its abundant availability.However,the efficiency of commercial solar photovoltaic(PV)modules is hindered by several factors,notably their conversion efficiency,which averages around 19%.This efficiency can further decline to 10%–16%due to temperature increases during peak sunlight hours.This study investigates the cooling of PV modules by applying water to their front surface through Computational fluid dynamics(CFD).The study aimed to determine the optimal conditions for cooling the PV module by analyzing the interplay between water film thickness,Reynolds number,and their effects on temperature reduction and heat transfer.The CFD analysis revealed that the most effective cooling condition occurred with a 5 mm thick water film and a Reynolds number of 10.These specific parameters were found to maximize the heat transfer and temperature reduction efficiency.This finding is crucial for the development of practical and efficient cooling systems for PV modules,potentially leading to improved performance and longevity of solar panels.Alternative cooling fluids or advanced cooling techniques that might offer even better efficiency or practical benefits. 展开更多
关键词 PV module efficiency water film thickness reynolds number CFD analysis PV/T renewable energy
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Spatiotemporal characteristics and influencing factors of vegetation water use efficiency on the Tibetan Plateau in 2001-2020 被引量:2
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作者 HE Chenyang WANG Yanjiao +1 位作者 YAN Feng LU Qi 《Journal of Geographical Sciences》 2025年第1期39-64,共26页
Water use efficiency(WUE),as a pivotal indicator of the coupling degree within the carbon–water cycle of ecosystems,holds considerable importance in assessment of the carbon–water balance within terrestrial ecosyste... Water use efficiency(WUE),as a pivotal indicator of the coupling degree within the carbon–water cycle of ecosystems,holds considerable importance in assessment of the carbon–water balance within terrestrial ecosystems.However,in the context of global warming,WUE evolution and its primary drivers on the Tibetan Plateau remain unclear.This study employed the ensemble empirical mode decomposition method and the random forest algorithm to decipher the nonlinear trends and drivers of WUE on the Tibetan Plateau in 2001–2020.Results indicated an annual mean WUE of 0.8088 gC/mm·m^(2)across the plateau,with a spatial gradient reflecting decrease from the southeast toward the northwest.Areas manifesting monotonous trends of increase or decrease in WUE accounted for 23.64%and 9.69%of the total,respectively.Remarkably,66.67%of the region exhibited trend reversals,i.e.,39.94%of the area of the Tibetan Plateau showed transition from a trend of increase to a trend of decrease,and 26.73%of the area demonstrated a shift from a trend of decrease to a trend of increase.Environmental factors accounted for 70.79%of the variability in WUE.The leaf area index and temperature served as the major driving forces of WUE variation. 展开更多
关键词 water use efficiency spatiotemporal characteristic influencing factor Tibetan Plateau
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Study on the desalination efficiency of hydrate phase by a pressure-driven filtration method 被引量:1
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作者 Yiwei Wu Zhenbin Xu +5 位作者 Xiaohui Wang Jin Cai Tenghua Zhang Peng Xiao Changyu Sun Guangjin Chen 《Chinese Journal of Chemical Engineering》 2025年第9期66-75,共10页
The mechanism of hydrate-based desalination is that water molecules would transfer to the hydrate phase during gas hydrate formation process,while the salt ions would be conversely concentrated in the unreacted saltwa... The mechanism of hydrate-based desalination is that water molecules would transfer to the hydrate phase during gas hydrate formation process,while the salt ions would be conversely concentrated in the unreacted saltwater.However,the salt concentration of hydrate decomposed water and the desalination degree of hydrate phase are still unclear.The biggest challenge is how to effectively separate the hydrate phase and the remaining unreacted salt water,and then decompose the hydrate phase to measure the salt concentration of hydrate melt water.This work developed an apparatus and pressure-driven filtration method to efficiently separate the hydrate phase and the remaining unreacted saltwater.On this basis,the single hydrate phase was obtained,then it was dissociated and the salt concentration of hydrate melt water was measured.The experimental results demonstrate that when the initial salt mass concentration is 0.3% to 8.0%,the salt removal efficiency for NaCl solution is 15.9% to 29.8%by forming CO_(2) hydrate,while for CaCl_(2) solution is 28.9%to 45.5%.The solute CaCl_(2) is easier to be removed than solute NaCl.In addition,the salt removal efficiency for forming CO_(2) hydrate is higher than that for forming methane hydrate.The multi-stage desalination can continuously decrease the salt concentration of hydrate dissociated water,and the salt removal efficiency per stage is around 20%. 展开更多
关键词 DESALINATION Gas hydrate Pressure-driven filtration Salt removal efficiency MULTI-STAGE
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Micro-ridge-furrow planting increases rapeseed yield and resource utilization efficiency through optimizing field microenvironment and light-nitrogen matching 被引量:1
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作者 Xianling Wang Lin Li +15 位作者 Chunyun Wang Zongkai Wang Mengliang Li Xiaoqiang Tan Lei Zhang Tianyao Wang Yuanwei Zhou Xiongze Xie Sen Qiu Yitao Liao Jie Kuai Bo Wang Jing Wang Zhenghua Xu Jie Zhao Guangsheng Zhou 《The Crop Journal》 2025年第2期587-596,共10页
The effects of micro-ridge-furrow planting(MR)on yield and the efficiency of light,water,and thermal resource use in rapeseed were tested in a three-year field experiment comparing MR to conventional flat planting.MR ... The effects of micro-ridge-furrow planting(MR)on yield and the efficiency of light,water,and thermal resource use in rapeseed were tested in a three-year field experiment comparing MR to conventional flat planting.MR enhanced canopy heterogeneity by altering the leaf angle between plants on ridges and furrows.The heterogeneous canopy environment increased intercepted photosynthetic active radiation,alleviated canopy temperature stress,and optimized canopy humidity,leading to improvements in light-nitrogen matching and net photosynthetic rate.Consequently,dry matter and yield increased by 13.0%and 11.0%,respectively,while radiation,thermal,and precipitation utilization efficiency increased by 12.3%-16.2%.The corresponding improvements in yield and resource use efficiency were attributed to a heterogeneous canopy environment that improved microclimatic conditions. 展开更多
关键词 Direct-seeded rapeseed Micro-ridge-furrow Canopy heterogeneity Resources utilization efficiency Light-nitrogen matching
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Reduced Salinity Interacts with Enriched Nitrogen to Enhance the Photosynthetic Efficiency of Chlorophyta Ulva fasciata 被引量:1
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作者 WAN Mingyue BAI Lingling +3 位作者 NI Guangyan LI Li TAN Yehui LI Gang 《Journal of Ocean University of China》 2025年第1期130-138,共9页
Macroalgae dominate nutrient dynamics and function as high-value foods for microbial,meio-and macrofaunal communities in coastal ecosystems.Because of this vital role,it is important to clarify the physiological infor... Macroalgae dominate nutrient dynamics and function as high-value foods for microbial,meio-and macrofaunal communities in coastal ecosystems.Because of this vital role,it is important to clarify the physiological information associated with environmental changes as it reflects their growth potential.To evaluate the effects of the changes in salinity and nutrients,the photosynthetic efficiency of a green macroalga Ulva fasciata from the Daya Bay was tested at a range of salinity(i.e.,31 to 10 psu)and nitrogen content(i.e.,5 to 60μmol L^(-1)).The results showed that cellular chlorophyll a(Chl a),carbohydrate and protein contents of U.fasciata were increased due to reduced salinity,and were decreased by interactive nitrogen enrichment.Within a short culture period(i.e.,18 h),the reduced salinity decreased the maximum photosynthetic efficiency(rETRmax and Pmax)derived from the rapid light response curve and photosynthetic oxygen evolution rate versus irradiance curve,respectively,as well as the saturation irradiance(E_(K)).This reducing effect diminished with enlonged cultivation time and reversed to a stimulating effect after 24 h of cultivation.The nitrogen enrichment stimulated the rETRmax and Pmax,as well as the E_(K),regardless of salinity,especially within short-term cultivation period(i.e.,<24 h).In addition,our results indicate that seawater freshening lowers the photosynthetic efficiency of U.fasciata in the short term,which is mitigated by nitrogen enrichment,but stimulates it in the long term,providing insight into how macroalgae thrive in coastal or estuarine waters where salinity and nutrients normally covary strongly. 展开更多
关键词 reduced salinity nitrogen enrichment photosynthetic efficiency Ulva fasciata Daya Bay
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Drone-based superconducting nanowire single-photon detection system with a detection efficiency of more than 90% 被引量:2
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作者 Ruoyan Ma Zhimin Guo +11 位作者 Dai Chen Xiaojun Dai You Xiao Chengjun Zhang Jiamin Xiong Jia Huang Xingyu Zhang Xiaoyu Liu Liangliang Rong Hao Li Xiaofu Zhang Lixing You 《Advanced Photonics Nexus》 2025年第2期25-30,共6页
Conventional superconducting nanowire single-photon detectors(SNSPDs)have been typically limited in their applications due to their size,weight,and power consumption,which confine their use to laboratory settings.Howe... Conventional superconducting nanowire single-photon detectors(SNSPDs)have been typically limited in their applications due to their size,weight,and power consumption,which confine their use to laboratory settings.However,with the rapid development of remote imaging,sensing technologies,and long-range quantum communication with fewer topographical constraints,the demand for high-efficiency single-photon detectors integrated with avionic platforms is rapidly growing.We herein designed and manufactured the first drone-based SNSPD system with a system detection efficiency(SDE)as high as 91.8%.This drone-based system incorporates high-performance NbTiN SNSPDs,a self-developed miniature liquid helium dewar,and custom-built integrated electrical setups,making it capable of being launched in complex topographical conditions.Such a drone-based SNSPD system may open the use of SNSPDs for applications that demand high SDE in complex environments. 展开更多
关键词 superconducting nanowire single-photon detector drone-based single-photon detection system high system detection efficiency dark count rate
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A parameter-variant trochoidal-like tool path planning method for chatter-free and high-efficiency milling 被引量:1
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作者 Zhaoliang LI Jinbo NIU +1 位作者 Shuoxue SUN Yuwen SUN 《Chinese Journal of Aeronautics》 2025年第2期559-576,共18页
Trochoidal milling is known for its advantages in machining difficult-to-machine materials as it facilitates chip removal and tool cooling.However,the conventional trochoidal tool path presents challenges such as lowe... Trochoidal milling is known for its advantages in machining difficult-to-machine materials as it facilitates chip removal and tool cooling.However,the conventional trochoidal tool path presents challenges such as lower machining efficiency and longer machining time due to its time-varying cutter-workpiece engagement angle and a high percentage of non-cutting tool paths.To address these issues,this paper introduces a parameter-variant trochoidal-like(PVTR)tool path planning method for chatter-free and high-efficiency milling.This method ensures a constant engagement angle for each tool path period by adjusting the trochoidal radius and step.Initially,the nonlinear equation for the PVTR toolpath is established.Then,a segmented recurrence method is proposed to plan tool paths based on the desired engagement angle.The impact of trochoidal tool path parameters on the engagement angle is analyzed and coupled this information with the milling stability model based on spindle speed and engagement angle to determine the desired engagement angle throughout the machining process.Finally,several experimental tests are carried out using the bull-nose end mill to validate the feasibility and effectiveness of the proposed method. 展开更多
关键词 Trochoidal milling Milling stability Tool path planning Machining efficiency Bull-nose end mill
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Optimizing tillage and fertilization practices to improve the carbon footprint and energy efficiency of wheat-maize cropping systems 被引量:1
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作者 Kun Han Xinzhu Li +5 位作者 Liang Jia Dazhao Yu Wenhua Xu Hongkun Chen Tao Song Peng Liu 《Journal of Integrative Agriculture》 2025年第10期3789-3802,共14页
To make agricultural systems sustainable in terms of their greenness and efficiency,optimizing the tillage and fertilization practices is essential.To assess the effects of tilling and fertilization practices in wheat... To make agricultural systems sustainable in terms of their greenness and efficiency,optimizing the tillage and fertilization practices is essential.To assess the effects of tilling and fertilization practices in wheat-maize cropping systems,a three-year field experiment was designed to quantify the carbon footprint(CF)and energy efficiency of the cropping systems in the North China Plain.The study parameters included four tillage practices(no tillage(NT),conventional tillage(CT),rotary tillage(RT),and subsoiling rotary tillage(SRT))and two fertilizer regimes(inorganic fertilizer(IF)and hybrid fertilizer with organic and inorganic components(HF)).The results indicated that the most prominent energy inputs and greenhouse gas(GHG)emissions could be ascribed to the use of fertilizers and fuel consumption.Under the same fertilization regime,ranking the tillage patterns with respect to the value of the crop yield,profit,CF,energy use efficiency(EUE)or energy productivity(EP)for either wheat or maize always gave the same sequence of SRT>RT>CT>NT.For the same tillage,the energy consumption associated with HF was higher than IF,but its GHG emissions and CF were lower while the yield and profit were higher.In terms of overall performance,tilling is more beneficial than NT,and reduced tillage practices(RT and SRT)are more beneficial than CT.The fertilization regime with the best overall performance was HF.Combining SRT with HF has significant potential for reducing CF and increasing EUE,thereby improving sustainability.Adopting measures that promote these optimizations can help to overcome the challenges posed by a lack of food security,energy crises and ecological stress. 展开更多
关键词 reduced tillage organic fertilizer greenhouse gases C footprint energy use efficiency
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Phase-change heterostructure with HfTe_(2)confinement sublayers for enhanced thermal efficiency and low-power operation through Joule heating localization 被引量:1
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作者 S.W.Park H.J.Lee +6 位作者 K.A.Nirmal T.H.Kim D.H.Kim J.Y.Choi J.S.Oh J.M.Joo T.G.Kim 《Journal of Materials Science & Technology》 2025年第1期104-114,共11页
Although phase-change random-access memory(PCRAM)is a promising next-generation nonvolatile memory technology,challenges remain in terms of reducing energy consumption.This is primarily be-cause the high thermal condu... Although phase-change random-access memory(PCRAM)is a promising next-generation nonvolatile memory technology,challenges remain in terms of reducing energy consumption.This is primarily be-cause the high thermal conductivities of phase-change materials(PCMs)promote Joule heating dissi-pation.Repeated phase transitions also induce long-range atomic diffusion,limiting the durability.To address these challenges,phase-change heterostructure(PCH)devices that incorporate confinement sub-layers based on transition-metal dichalcogenide materials have been developed.In this study,we engi-neered a PCH device by integrating HfTe_(2),which has low thermal conductivity and excellent stability,into the PCM to realize PCRAM with enhanced thermal efficiency and structural stability.HEAT sim-ulations were conducted to validate the superior heat confinement in the programming region of the HfTe_(2)-based PCH device.Moreover,electrical measurements of the device demonstrated its outstanding performance,which was characterized by a low RESET current(∼1.6 mA),stable two-order ON/OFF ratio,and exceptional cycling endurance(∼2×10^(7)).The structural integrity of the HfTe_(2)confinement sub-layer was confirmed using X-ray photoelectron spectroscopy and transmission electron microscopy.The material properties,including electrical conductivity,cohesive energy,and electronegativity,substantiated these findings.Collectively,these results revealed that the HfTe_(2)-based PCH device can achieve significant improvements in performance and reliability compared with conventional PCRAM devices. 展开更多
关键词 Phase-change random-access memory Phase-change heterostructure Thermal efficiency Thermal stability Low-power operation
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Application of a low-cost and high-efficiency polymer non-catalytic reduction technology for NO_(x) removal in waste-to-energy plant 被引量:1
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作者 Shuai Xiao Congbo Li +4 位作者 Xueyan Zheng Liya Li Jingzhong Si Xiuqi Shu Xianqiong Zeng 《Journal of Environmental Sciences》 2025年第12期112-125,共14页
Ultra-low emission of nitrogen oxide(NO_(x))is an irreversible trend for the development of waste-to-energy industry.But traditional approaches to remove NO_(x) face significant challenge s,such as low denitration eff... Ultra-low emission of nitrogen oxide(NO_(x))is an irreversible trend for the development of waste-to-energy industry.But traditional approaches to remove NO_(x) face significant challenge s,such as low denitration efficiency,complex denitration system,and high investment and operating cost.Here we put forward a novel polymer non-catalytic reduction(PNCR)technology that utilized a new type of polymer agent to remove NO_(x),and the proposed PNCR technology was applied to the existing waste-to-energy plant to test the denitration performance.The PNCR technology demonstrated excellent denitration performance with a NO_(x) emission concentration of<100 mg/Nm^(3) and high denitration efficiency of>75%at the temperature range of 800-900℃,which showed the application feasibility even on the complex and unstable industrial operating conditions.In addition,PNCR and hybrid polymer/selective non-catalytic reduction(PNCR/SNCR)technology possessed remarkable economic advantages including low investment fee and low operating cost of<10 CNY per ton of municipal solid waste(MSW)compared with selective catalytic reduction(SCR)technology.The excellent denitration performance of PNCR technology forebodes a broad industrial application prospect in the field of flue gas cleaning for waste-to-energy plants. 展开更多
关键词 Polymer non-catalytic reduction High denitration efficiency Low operating cost Waste-to-energy plant
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Dual‑Donor‑Induced Crystallinity Modulation Enables 19.23% Efficiency Organic Solar Cells
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作者 Anhai Liang Yuqing Sun +9 位作者 Sein Chung Jiyeong Shin Kangbo Sun Chaofeng Zhu Jingjing Zhao Zhenmin Zhao Yufei Zhong Guangye Zhang Kilwon Cho Zhipeng Kan 《Nano-Micro Letters》 SCIE EI CAS 2025年第3期376-388,共13页
Trap-assisted charge recombination is one of the primary limitationsof restricting the performance of organic solar cells. However, effectivelyreducing the presence of traps in the photoactive layer remains challengin... Trap-assisted charge recombination is one of the primary limitationsof restricting the performance of organic solar cells. However, effectivelyreducing the presence of traps in the photoactive layer remains challenging.Herein, wide bandgap polymer donor PTzBI-dF is demonstrated as an effectivemodulator for enhancing the crystallinity of the bulk heterojunction active layerscomposed of D18 derivatives blended with Y6, leading to dense and orderedmolecular packings, and thus, improves photoluminescence quenching properties.As a result, the photovoltaic devices exhibit reduced trap-assisted charge recombinationlosses, achieving an optimized power conversion efficiency of over 19%.Besides the efficiency enhancement, the devices comprised of PTzBI-dF as athird component simultaneously attain decreased current leakage, improved chargecarrier mobilities, and suppressed bimolecular charge recombination, leading toreduced energy losses. The advanced crystalline structures induced by PTzBI-dFand its characteristics, such as well-aligned energy level, and complementaryabsorption spectra, are ascribed to the promising performance improvements.Our findings suggest that donor phase engineering is a feasible approach to tuning the molecular packings in the active layer, providingguidelines for designing effective morphology modulators for high-performance organic solar cells. 展开更多
关键词 Trap-assisted charge recombination PHOTOLUMINESCENCE MISCIBILITY Current leakage Power conversion efficiency
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Split nitrogen application increases maize root growth,yield,and nitrogen use efficiency under soil warming conditions 被引量:2
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作者 Zhenqing Xia Yuxiang Gong +3 位作者 Xiangyue Lyu Junchen Lin Yi Yang Haidong Lu 《The Crop Journal》 2025年第2期565-575,共11页
The increase in soil temperature associated with climate change has introduced considerable challenges to crop production.Split nitrogen application(SN)represents a potential strategy for improving crop nitrogen use e... The increase in soil temperature associated with climate change has introduced considerable challenges to crop production.Split nitrogen application(SN)represents a potential strategy for improving crop nitrogen use efficiency and enhancing crop stress resistance.Nevertheless,the precise interaction between soil warming(SW)and SN remains unclear.In order to ascertain the impact of SW on maize growth and whether SN can improve the tolerance of maize to SW,a two-year field experiment was conducted(2022-2023).The aim was to examine the influence of two SW ranges(MT,warming 1.40℃;HT,warming 2.75℃)and two nitrogen application methods(N1,one-time basal application of nitrogen fertilizer;N2,one third of base nitrogen fertilizer+two thirds of jointing stage supplemental nitrogen fertilizer)on maize root growth,photosynthetic characteristics,nitrogen use efficiency,and yield.The results demonstrated that SW impeded root growth and precipitated the premature aging of maize leaves following anthesis,particularly in the HT,which led to a notable reduction in maize yield.In comparison to N1,SN has been shown to increase root length density by 8.54%,root bleeding rate by 8.57%,and enhance root distribution ratio in the middle soil layers(20-60 cm).The interaction between SW and SN had a notable impact on maize growth and yield.The SN improved the absorption and utilization efficiency of nitrogen by promoting root development and downward canopy growth,thus improving the tolerance of maize to SW at the later stage of growth.In particular,the N2HT resulted in a 14.51%increase in the photosynthetic rate,a 18.58%increase in nitrogen absorption efficiency,and a 18.32%increase in maize yield compared with N1HT.It can be posited that the SN represents a viable nitrogen management measure with the potential to enhance maize tolerance to soil high-temperature stress. 展开更多
关键词 Maize(Zea mays L.) Soil warming Split nitrogen application Root growth Nitrogen use efficiency Grain yield
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Enhancing efficiency and stability of inverted perovskite solar cells through synergistic suppression of multiple defects via poly(ionic liquid)-buried interface modification 被引量:1
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作者 Yijun Bai Tong Wang +9 位作者 Jiabao Yang Xingyu Pu Bingxiu Xue Hui Chen Xilai He Guangpeng Feng Shiyao Jia Jianbo Yin Qi Cao Xuanhua Li 《Journal of Materials Science & Technology》 2025年第9期281-288,共8页
The stability of perovskite solar cells(PSCs)is adversely affected by nonradiative recombination resulting from buried interface defects.Herein,we synthesize a polyionic liquid,poly(p-vinylbenzyl trimethylam-monium he... The stability of perovskite solar cells(PSCs)is adversely affected by nonradiative recombination resulting from buried interface defects.Herein,we synthesize a polyionic liquid,poly(p-vinylbenzyl trimethylam-monium hexafluorophosphate)(PTA),and introduce it into the buried interface of PSCs.The quaternary ammonium cation(N(-CH_(3))^(3+))in PTA can fill the vacancies of organic cations within the perovskite structure and reduce shallow energy level defects.Additionally,the hexafluorophosphate(PF6−)in PTA forms a Lewis acid-base interaction with Pb^(2+)in the perovskite layer,effectively passivating deep en-ergy level defects.Furthermore,hydrogen bonding can be established between organic cations and the PF6−anion,preventing the formation of shallow energy level defects.Through this synergistic mecha-nism,the deep and shallow energy level defects are effectively mitigated,resulting in improved device performance.As a result,the resulting treated inverted PSC exhibits an impressive power conversion ef-ficiency(PCE)of 24.72%.Notably,the PTA-treated PSCs exhibit remarkable stability,with 88.5%of the original PCE retained after undergoing heat aging at 85℃ for 1078 h,and 89.1%of the initial PCE main-tained following continuous exposure to light for 1100 h at the maximum power point.Synergistically suppressing multiple defects at the buried interface through the use of polyionic liquids is a promising way to improve the commercial viability of PSCs. 展开更多
关键词 Polyionic liquid Inverted perovskite solar cells Defect passivation High efficiency Operational stability
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Advances in iron-based Fischer-Tropsch synthesis with high carbon efficiency 被引量:1
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作者 Xueqing Zhang Wusha Jiye +2 位作者 Yuhua Zhang Jinlin Li Li Wang 《Chinese Journal of Catalysis》 2025年第7期4-21,共18页
Fischer-Tropsch synthesis offers a promising route to convert carbon-rich resources such as coal,natural gas,and biomass into clean fuels and high-value chemicals via syngas.Catalyst development is crucial for optimiz... Fischer-Tropsch synthesis offers a promising route to convert carbon-rich resources such as coal,natural gas,and biomass into clean fuels and high-value chemicals via syngas.Catalyst development is crucial for optimizing the process,with cobalt-and iron-based catalysts being widely used in industrial applications.Iron-based catalysts,in particular,are favored due to their low cost,broad temperature range,and high water-gas shift reaction activity,making them ideal for syngas derived from coal and biomass with a low H_(2)/CO ratio.However,despite their long history of industrial use,iron-based catalysts face two significant challenges.First,the presence of multiple iron phases-metallic iron,iron oxides,and iron carbides-complicates the understanding of the reaction mechanism due to dynamic phase transformations.Second,the high water-gas shift activity of these catalysts leads to increased CO_(2) selectivity,thereby reducing overall carbon efficiency.In Fischer-Tropsch synthesis,CO_(2) can arise as primary CO_(2) from CO disproportionation(the Boudouard reaction)and as secondary CO_(2) from the water-gas shift reaction.The accumulation of CO_(2) formation further compromises overall carbon efficiency,which is particularly undesirable given the current focus on minimizing carbon emissions and achieving carbon neutrality.This review focus on the ongoing advancements of iron-based catalysts for Fischer-Tropsch synthesis,with particular emphasis on overcoming these two critical challenges for iron-based catalysts:regulating the active phases and minimizing CO_(2) selectivity.Addressing these challenges is essential for enhancing the overall catalytic efficiency and selectivity of iron-based catalysts.In this review,recent efforts to suppress CO_(2) selectivity of iron-based catalysts,including catalyst hydrophobic modification and graphene confinement,are explored for their potential to stabilize active phases and prevent unwanted side reactions.This innovative approach offers new opportunities for developing catalysts with high activity,low CO_(2) selectivity,and enhanced stability,which are key factors for enhancing both the efficiency and sustainability for Fischer-Tropsch synthesis.Such advancements are crucial for advancing more efficient and sustainable Fischer-Tropsch synthesis technologies,supporting the global push for net-zero emissions goals,and contributing to carbon reduction efforts worldwide. 展开更多
关键词 Fischer-Tropsch synthesis Syngas conversion Carbon dioxide Carbon efficiency Iron carbide Graphene layer confinement
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An improved high efficiency low error substrate integrated waveguide wideband delay line
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作者 ZHANG Hongxi WANG Pei 《中国科学院大学学报(中英文)》 北大核心 2025年第5期677-685,共9页
In this paper,a wideband true time delay line for X-band is designed to overcome the beam dispersion problem in a high-resolution spaceborne synthetic aperture radar phased array antenna system.The delay line loads th... In this paper,a wideband true time delay line for X-band is designed to overcome the beam dispersion problem in a high-resolution spaceborne synthetic aperture radar phased array antenna system.The delay line loads the electromagnetic bandgap structure on the upper surface of the substrate integrated waveguide.This is equivalent to including an additional inductance-capacitance for energy storage,which realizes the slow-wave effect.A microstrip line-SIW tapered transition structure is introduced to achieve a low loss and a large bandwidth.In the frequency band between 8-12 GHz,the measured results show that the delay multiplier of the delay line reaches 4 times,i.e.,delay line’s delay time is 4 times larger than 50Ωmicrostrip line with same length.Furthermore,the delay fluctuation,i.e.,the difference between the maximum and minimum delay as a percentage of the standard delay is only 2.5%,the insertion loss is less than-2.5 dB,and the return loss is less than-15 dB.Compared with the existing delay lines,the proposed delay line has the advantages of high delay efficiency,low delay error,wide bandwidth and low loss,which has good practical value and application prospects. 展开更多
关键词 SIW EBG low error high efficiency WIDEBAND
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Energy Efficiency Operating Indicator Forecasting and Speed Design Optimization for Polar Ice Class Merchant Vessels
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作者 LU Yu LI Chen−ran +3 位作者 ZHU Xiang−hang LI Shi−an GU Zhu−hao LIU She−wen 《船舶力学》 北大核心 2025年第6期901-911,共11页
In order to accurately forecast the main engine fuel consumption and reduce the Energy Efficiency Operational Indicator(EEOI)of merchant ships in polar ice areas,the energy transfer relationship between ship-machine-p... In order to accurately forecast the main engine fuel consumption and reduce the Energy Efficiency Operational Indicator(EEOI)of merchant ships in polar ice areas,the energy transfer relationship between ship-machine-propeller is studied by analyzing the complex force situation during ship navigation and building a MATLAB/Simulink simulation platform based on multi-environmental resistance,propeller efficiency,main engine power,fuel consumption,fuel consumption rate and EEOI calculation module.Considering the environmental factors of wind,wave and ice,the route is divided into sections,the calculation of main engine power,main engine fuel consumption and EEOI for each section is completed,and the speed design is optimized based on the simulation model for each section.Under the requirements of the voyage plan,the optimization results show that the energy efficiency operation index of the whole route is reduced by 3.114%and the fuel consumption is reduced by 9.17 t. 展开更多
关键词 Energy efficiency Operational Indicator ice-class ships segment division design optimization
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Global Ports Efficiency and Productivity Using DEA-MPI Approach
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作者 Calvin Elorm Atsunyo Bernard Kwei Tetteh 《Open Journal of Applied Sciences》 2025年第2期433-449,共17页
Ports are crucial to the economy of many nations;thus, numerous studies have been conducted on port efficiency and productivity. This study analyses the efficiency and productivity of some major global ports namely, P... Ports are crucial to the economy of many nations;thus, numerous studies have been conducted on port efficiency and productivity. This study analyses the efficiency and productivity of some major global ports namely, Port of Singapore, Rotterdam, Antwerp and Durban. The main objectives of this study are to determine the level of operational efficiency of the mentioned ports, measure and evaluate the ports’ productivity changes and lastly to investigate the factors influencing the productivity changes of the ports studied. To achieve these objectives, Data Envelopment Analysis (DEA-BCC) model was used to determine the technical and operational efficiencies of the ports and Malmquist productivity index was employed to calculate the various productivity levels. The results of the study can guide stakeholders to formulate their operational strategies for port efficiency and productivity. The study also has policy suggestions that are uniquely targeted to Africa’s issues and potential. 展开更多
关键词 efficiency PRODUCTIVITY Data Envelopment Analysis Malmquist Productivity Index
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Improving Provider Efficiency at the Local Level
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作者 Ronald Lagoe Shelly Littau 《Case Reports in Clinical Medicine》 2025年第1期1-9,共9页
This study reviewed developments in provider utilization related to health care in the metropolitan area of the Syracuse hospitals between the twentieth century and the twenty first century with respect to major hospi... This study reviewed developments in provider utilization related to health care in the metropolitan area of the Syracuse hospitals between the twentieth century and the twenty first century with respect to major hospital services. In this study, a decline in the utilization of inpatient hospitals developed between 2020 and 2022. During this period, use of additional outpatient services such as ambulatory surgery, individual practitioners, outside hospitals, and the use of hospital emergency departments developed in the community. The study data demonstrated that between 2020 and 2022, the numbers of discharges from the combined hospitals declined for both adult medicine and adult surgery. Inpatient discharges declined by 2730 patients for adult medicine and 1961 patients for adult surgery. The data also demonstrated that between 2022 and 2024, the numbers of discharges increased by 1998 discharges for adult medicine and by 229 for adult surgery. As followup to this study, health care providers and payors should review approaches to efficiency in their communities and evaluate their impact on health care efficiency. 展开更多
关键词 Health Care efficiency Hospitals Ambulatory Care
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