Rechargeable lithium–sulfur(Li–S)batteries are considered promising next-generation energy storage systems owing to their high theoretical energy density,but their application is hindered by the shuttle effect arisi...Rechargeable lithium–sulfur(Li–S)batteries are considered promising next-generation energy storage systems owing to their high theoretical energy density,but their application is hindered by the shuttle effect arising from dissolved lithium polysulfides(LiPSs).Herein,we design an optimized electrolyte to achieve long-term stability by employing an appropriate low-polarity solvent.A combination of diethyl ether(DEE)and 1,2-dimethoxyethane(DME)was selected to improve Li metal stability even in the presence of LiPSs.The DEE/DME electrolyte not only suppresses parasitic reactions between Li and LiPSs but also promotes uniform Li deposition.Moreover,operando optical microscopy was employed to directly visualize electrolyte stability and dendrite evolution in real time,while quantitative analysis was conducted via normalized hue index and contour image mapping.The enhanced anode stability of the DEE/DME electrolyte enabled excellent cycling performance,retaining 80.14%of its initial capacity after300 cycles at 3 C,while maintaining superior performance under practical conditions with high sulfur loading and a low E/S ratio.These findings highlight that solvent properties critically influence Li metal stabilization in Li–S batteries and underscore the significance of solvent engineering in electrolyte design.展开更多
A simple method is applied to calculating the optical path difference （OPD） of a plane parallel uniaxial plate with an arbitrary optical axis direction. Then, the theoretical expressions of the OPD and lateral displ...A simple method is applied to calculating the optical path difference （OPD） of a plane parallel uniaxial plate with an arbitrary optical axis direction. Then, the theoretical expressions of the OPD and lateral displacement （LD） of Savart polariscope under non-ideal conditions are obtained exactly. The variations of OPD and LD are simulated, and some important conclusions are obtained when the optical axis directions have an identical tolerance of ／pm 1^{{／circ}}. An application example is given that the tolerances of optical axis directions are gained according to the spectral resolution tolerances of the stationary polarization interference imaging spectrometer （SPIIS）. Several approximate formulae are obtained for explaining some conclusions above. The work provides a theoretical guidance for the optic design, crystal processing, installation and debugging, data analysis and spectral reconstruction of the SPIIS.展开更多
To improve the time and frequency reference standards used for radio astronomy and high precision atomic physics applications, we describe a novel stable frequency transmission technique. The approach uses a vertical-...To improve the time and frequency reference standards used for radio astronomy and high precision atomic physics applications, we describe a novel stable frequency transmission technique. The approach uses a vertical-cavity surface-emitting laser(VCSEL) based phase correction actuator. Using a frequency mixing process for feedback control, the phase noise induced along the 26 km G.655 optical fibre link was actively reduced. This was achieved by using a 1 310 nm dither controlled VCSEL phase error correction actuator together with the inherent chromatic dispersion properties of the fibre. The technique corrects phase noise and optical signal drift along the fibre at the transmission end. Fractional frequency instabilities across the G.655 fibre link of 4.44×10-12 at 1 s and 4.86×10-14 at 104 s are successfully reported.展开更多
A method is presented to improve the laser frequency stabilization for the optical pumping cesium clock. By comparing the laser frequency stabilization of different schemes, we verify that the light angle is an import...A method is presented to improve the laser frequency stabilization for the optical pumping cesium clock. By comparing the laser frequency stabilization of different schemes, we verify that the light angle is an important factor that limits the long-term frequency stability. We minimize the drift of the light angle by using a fiber- coupled output, and lock the frequency of a distributed-feedback diode laser to the fluorescence spectrum of the atomic beam. The measured frequency stability is about 3.5 ×10^-11 at i s and reaches 1.5 × 10^-12 at 2000s. The Allan variance keeps going down for up to thousands of seconds, indicating that the medium- and long-term stability of the laser frequency is significantly improved and perfectly fulfills the requirement for the optical pumping cesium clock.展开更多
Environmental vibration causes mechanical deformation in optical fibers, which induces excess frequency noise in fiber-stabilized lasers. In order to solve such a problem, we propose an ultralow acceleration sensitivi...Environmental vibration causes mechanical deformation in optical fibers, which induces excess frequency noise in fiber-stabilized lasers. In order to solve such a problem, we propose an ultralow acceleration sensitivity fiber spool with symmetrically mounted structure. By numerical analysis with the finite element method, we obtain the optimal geometry parameters of the spool with which the horizontal and vertical acceleration sensitivity can be reduced to 3.25 × 10^-12/g and 5.38 × 10^-12/g respectively. Moreover, the structure features the insensitivity to the variation of geometry parameters,which will minimize the influence from numerical simulation error and manufacture tolerance.展开更多
Angular velocity stabilization control and attitude stabilization control for an underactuated spacecraft using only two single gimbal control moment gyros （SGCMGs） as actuators is investigated. First of all, the dy...Angular velocity stabilization control and attitude stabilization control for an underactuated spacecraft using only two single gimbal control moment gyros （SGCMGs） as actuators is investigated. First of all, the dynamic model of the underactuated spacecraft is established and the singularity of different configurations with the two SGCMGs is analyzed. Under the assumption that the gimbal axes of the two SGCMGs are installed in any direction, and that the total system angular momentum is not zero, a state feedback control law via Lyapunov method is designed to globally asymptotically stabilize the angular velocity of spacecraft. Under the assumption that the gimbal axes of the two SGCMGs are coaxially installed along anyone of the three principal axes of spacecraft inertia, and that the total system angular momentum is zero, a discontinuous state feedback control law is designed to stabilize three-axis attitude of spacecraft with respect to the inertial frame. Furthermore, the singularity escape of SGCMGs for the above two control problems is also studied. Simulation results demonstrate the validity of the control laws.展开更多
A novel liquid dye 2-((2E,5E)-2,5-bis(4-(methyl(2,5, 8,11-tetraoxatridecan-13-yl)amino)benzylidene)cyclopentylidene) malononitrile (TO-BDCM) was synthesized by incorporating two oligo(ethenyl glycol) groups into the b...A novel liquid dye 2-((2E,5E)-2,5-bis(4-(methyl(2,5, 8,11-tetraoxatridecan-13-yl)amino)benzylidene)cyclopentylidene) malononitrile (TO-BDCM) was synthesized by incorporating two oligo(ethenyl glycol) groups into the backbone of a prototype malononitrile derivative (BDCM) for the purpose of increasing its solubility in organic solvents. The nonlinear absorption properties of this liquid dye on 1064 nm ns pulsed laser were investigated in DMF with remarkably high concentration up to ~1M, showing a superior large nonlinear absorption coefficient of 55.6 cm3/GW2. Fairly good optical limiting and stabilization effects were achieved. Meanwhile, the liquid dye exhibited equivalent stability under laser irradiation compared to its prototype dye BDCM.展开更多
Future applications of portable40Ca^(+)optical clocks require reliable magnetic field stabilization to improve frequency stability, which can be achieved by implementing an active and passive magnetic field noise supp...Future applications of portable40Ca^(+)optical clocks require reliable magnetic field stabilization to improve frequency stability, which can be achieved by implementing an active and passive magnetic field noise suppression system. On the one hand, we have optimized the magnetic shielding performance of the portable optical clock by reducing its apertures and optimizing its geometry;on the other hand, we have introduced an active magnetic field noise suppression system to further suppress the magnetic field noise experienced by the ions. These efforts reduced the ambient magnetic field noise by about 10000 times, significantly reduced the linewidth of the clock transition spectrum, improved the stability of the portable40Ca+optical clock, and created the conditions for using portable optical clocks in non-laboratory magnetic field environments. This active magnetic field suppression scheme has the advantages of simple installation and wide applicability.展开更多
Reflective optics with wide field of view has been applied more and more widely in EUVL or space optics, and also plays an important role in promoting scientific and technological research. Among the reflective optics...Reflective optics with wide field of view has been applied more and more widely in EUVL or space optics, and also plays an important role in promoting scientific and technological research. Among the reflective optics, the off-axis reflective optics is the most hopeful solution to the ever-highest demands of these applications. This paper gives the requirements of both the above mentioned applications and the similarities and differences between these two kinds of optical systems. Finally, a design example of off-axis reflective optics with wide field of view is presented and described.展开更多
An airborne multi-axis differential optical absorption spectroscopic （AMAX-DOAS） instrument was developed and applied to measure tropospheric NO2 in the Pearl River Delta region in the south of China. By combining t...An airborne multi-axis differential optical absorption spectroscopic （AMAX-DOAS） instrument was developed and applied to measure tropospheric NO2 in the Pearl River Delta region in the south of China. By combining the measurements in nadir and zenith directions and analyzing the UV and visible spectral region using the DOAS method, information about tropospheric NO2 vertical columns was obtained. Strong tropospheric NO2 signals were detected when flying over heavilly polluted regions and point sources like plants. The AMAX-DOAS results were compared with ground-based MAX-DOAS observations in the southwest of Zhuhai city using the same parameters for radiative transport calculations. The difference in vertical column data between the two instruments is about 8%. Our data were also compared with those from OMI and fair agreement was obtained with a correlation coefficient R of 0.61. The difference between the two instruments can be attributed to the different spatial resolution and the temporal mismatch during the measurements.展开更多
In recent years,all inorganic CsPbX_(3)(X=F,Cl,Br,and I)perovskite quantum dots(QDs)have garnered increasing attention for their exceptional optical properties.However,the comme rcialization of CsPbX_(3)is hampered by...In recent years,all inorganic CsPbX_(3)(X=F,Cl,Br,and I)perovskite quantum dots(QDs)have garnered increasing attention for their exceptional optical properties.However,the comme rcialization of CsPbX_(3)is hampered by poor environmental stability and lead toxicity.Fortunately,the strategy of incorporating CsPbX_(3)into microcrystalline glass effectively addresses this issue.Notably,CsPbF_(3)demonstrates improved phase stability and a unique electronic structure,making its exploration crucial for various applications.In this study,we synthesized CsPbF_(3)QDs-in-glass(QiG)and Tb^(3+)-doped CsPbF_(3)QDs-inglasses(QiGs)using melt quenching and in-situ growth methods.The CsPbF_(3)QiG exhibits intrinsic photoluminescence with the main peak in the ultraviolet range,while Tb^(3+)-doped glasses show coemission of CsPbF_(3)QDs and Tb^(3+),allowing tunable colors by adjusting Tb^(3+)content.We systematically studied and evaluated the application of Tb^(3+)-doped CsPbF_(3)QiG as an optical temperature sensor.Importantly,the glass sample demonstrates high stability,including good thermal stability,superior high-temperature resistance,and moisture stability.This work significantly contributes to the exploration of the optical properties of CsPbF_(3)QiG,providing new insights into its future applications in diverse optical-related fields.展开更多
Optimization and simplification of optical systems represent a milestone in advancing the development of handheld and portable laser-induced breakdown spectroscopy(LIBS)systems towards smaller,more integrated forms.Th...Optimization and simplification of optical systems represent a milestone in advancing the development of handheld and portable laser-induced breakdown spectroscopy(LIBS)systems towards smaller,more integrated forms.This research,for the first time,conducted a comprehensive optimization design and comparative analysis of three compact LIBS system optical paths:the paraxial optical path(OP),the off-axis OP,and the reflective OP.The differences in spectral intensity and stability among these paths were revealed,providing a scientific basis for selecting the optimal OP for LIBS systems.The research found that the paraxial OP excels in spectral performance and quantitative analysis accuracy,making it the preferred choice for compact LIBS systems.Specifically,the paraxial OP significantly enhances spectral intensity,achieving a 6 times improvement over the off-axis OP and an even more remarkable 150 times increase compared to the reflective OP,greatly enhancing detection sensitivity.Additionally,the relative standard deviation,spectral stability index,maintains a consistently low level,ranging from 10.9%to 13.4%,significantly outperforming the other two OPs and ensuring the reliability of analytical results.In the field of quantitative analysis,the paraxial OP also demonstrates higher accuracy,precision,and sensitivity,comparing to other OPs.The quantitative analysis models for Si,Cu,and Ti elements exhibit excellent fitting,providing users with high-quality quantitative analysis results that are of great significance for applications in material science,environmental monitoring,industrial inspection,and other fields.In summary,this study not only confirms the enormous application potential of the paraxial OP in compact LIBS systems but also provides valuable practical experience and theoretical support for the miniaturization and integration of LIBS systems.Looking ahead,with continuous technological advancements,the design of the paraxial OP is expected to further propel the widespread adoption of LIBS technology in portable,on-site detection applications.展开更多
基金supported by the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIT)(RS-2024-00455177)the National Research Foundation of Korea(NRF)grant funded by the Korea government(MSIT)(RS-2025-00518953)+2 种基金the National Research Council of Science&Technology(NST)grant by the Korea government(MSIT)(GTL24012-000)the support by the National Natural Science Foundation of China(T2322015)the support by The Ministry of Science and ICT in Korea via KBSI(C524100)。
文摘Rechargeable lithium–sulfur(Li–S)batteries are considered promising next-generation energy storage systems owing to their high theoretical energy density,but their application is hindered by the shuttle effect arising from dissolved lithium polysulfides(LiPSs).Herein,we design an optimized electrolyte to achieve long-term stability by employing an appropriate low-polarity solvent.A combination of diethyl ether(DEE)and 1,2-dimethoxyethane(DME)was selected to improve Li metal stability even in the presence of LiPSs.The DEE/DME electrolyte not only suppresses parasitic reactions between Li and LiPSs but also promotes uniform Li deposition.Moreover,operando optical microscopy was employed to directly visualize electrolyte stability and dendrite evolution in real time,while quantitative analysis was conducted via normalized hue index and contour image mapping.The enhanced anode stability of the DEE/DME electrolyte enabled excellent cycling performance,retaining 80.14%of its initial capacity after300 cycles at 3 C,while maintaining superior performance under practical conditions with high sulfur loading and a low E/S ratio.These findings highlight that solvent properties critically influence Li metal stabilization in Li–S batteries and underscore the significance of solvent engineering in electrolyte design.
基金supported by the State Key Program of National Natural Science Foundation of China (Grant No. 40537031)the National Natural Science Foundation of China (Grant No. 40875013)+1 种基金the National Defense Basic Scientific Research Project, China (Grant No. A1420080187)the National High Technology Research and Development Program of China (Grant No. 2006AA12Z152)
文摘A simple method is applied to calculating the optical path difference （OPD） of a plane parallel uniaxial plate with an arbitrary optical axis direction. Then, the theoretical expressions of the OPD and lateral displacement （LD） of Savart polariscope under non-ideal conditions are obtained exactly. The variations of OPD and LD are simulated, and some important conclusions are obtained when the optical axis directions have an identical tolerance of ／pm 1^{{／circ}}. An application example is given that the tolerances of optical axis directions are gained according to the spectral resolution tolerances of the stationary polarization interference imaging spectrometer （SPIIS）. Several approximate formulae are obtained for explaining some conclusions above. The work provides a theoretical guidance for the optic design, crystal processing, installation and debugging, data analysis and spectral reconstruction of the SPIIS.
基金supported by the National Research Foundation of South Africa,Department of Science and Technology South Africa,Square Kilometre Array South Africa,Telkom,Cisco
文摘To improve the time and frequency reference standards used for radio astronomy and high precision atomic physics applications, we describe a novel stable frequency transmission technique. The approach uses a vertical-cavity surface-emitting laser(VCSEL) based phase correction actuator. Using a frequency mixing process for feedback control, the phase noise induced along the 26 km G.655 optical fibre link was actively reduced. This was achieved by using a 1 310 nm dither controlled VCSEL phase error correction actuator together with the inherent chromatic dispersion properties of the fibre. The technique corrects phase noise and optical signal drift along the fibre at the transmission end. Fractional frequency instabilities across the G.655 fibre link of 4.44×10-12 at 1 s and 4.86×10-14 at 104 s are successfully reported.
基金Supported by the National Fundamental Research Program of China under Grant No 2011CB921501the National Natural Science Foundation of China under Grant Nos 91336103,10934010 and 61078026
文摘A method is presented to improve the laser frequency stabilization for the optical pumping cesium clock. By comparing the laser frequency stabilization of different schemes, we verify that the light angle is an important factor that limits the long-term frequency stability. We minimize the drift of the light angle by using a fiber- coupled output, and lock the frequency of a distributed-feedback diode laser to the fluorescence spectrum of the atomic beam. The measured frequency stability is about 3.5 ×10^-11 at i s and reaches 1.5 × 10^-12 at 2000s. The Allan variance keeps going down for up to thousands of seconds, indicating that the medium- and long-term stability of the laser frequency is significantly improved and perfectly fulfills the requirement for the optical pumping cesium clock.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11034008 and 11274324)the Key Research Program of the Chinese Academy of Sciences(Grant No.KJZD-EW-W02)
文摘Environmental vibration causes mechanical deformation in optical fibers, which induces excess frequency noise in fiber-stabilized lasers. In order to solve such a problem, we propose an ultralow acceleration sensitivity fiber spool with symmetrically mounted structure. By numerical analysis with the finite element method, we obtain the optimal geometry parameters of the spool with which the horizontal and vertical acceleration sensitivity can be reduced to 3.25 × 10^-12/g and 5.38 × 10^-12/g respectively. Moreover, the structure features the insensitivity to the variation of geometry parameters,which will minimize the influence from numerical simulation error and manufacture tolerance.
文摘Angular velocity stabilization control and attitude stabilization control for an underactuated spacecraft using only two single gimbal control moment gyros （SGCMGs） as actuators is investigated. First of all, the dynamic model of the underactuated spacecraft is established and the singularity of different configurations with the two SGCMGs is analyzed. Under the assumption that the gimbal axes of the two SGCMGs are installed in any direction, and that the total system angular momentum is not zero, a state feedback control law via Lyapunov method is designed to globally asymptotically stabilize the angular velocity of spacecraft. Under the assumption that the gimbal axes of the two SGCMGs are coaxially installed along anyone of the three principal axes of spacecraft inertia, and that the total system angular momentum is zero, a discontinuous state feedback control law is designed to stabilize three-axis attitude of spacecraft with respect to the inertial frame. Furthermore, the singularity escape of SGCMGs for the above two control problems is also studied. Simulation results demonstrate the validity of the control laws.
文摘A novel liquid dye 2-((2E,5E)-2,5-bis(4-(methyl(2,5, 8,11-tetraoxatridecan-13-yl)amino)benzylidene)cyclopentylidene) malononitrile (TO-BDCM) was synthesized by incorporating two oligo(ethenyl glycol) groups into the backbone of a prototype malononitrile derivative (BDCM) for the purpose of increasing its solubility in organic solvents. The nonlinear absorption properties of this liquid dye on 1064 nm ns pulsed laser were investigated in DMF with remarkably high concentration up to ~1M, showing a superior large nonlinear absorption coefficient of 55.6 cm3/GW2. Fairly good optical limiting and stabilization effects were achieved. Meanwhile, the liquid dye exhibited equivalent stability under laser irradiation compared to its prototype dye BDCM.
基金supported by the National Key R&D Program of China (Grant Nos.2022YFB3904001, 2022YFB3904004, and 2018YFA0307500)the National Natural Science Foundation of China (Grant Nos. 12022414 and 12121004)+3 种基金the CAS Youth Innovation Promotion Association (Grant Nos. Y201963 and Y2022099)the Natural Science Foundation of Hubei Province (Grant No. 2022CFA013)the CAS Project for Young Scientists in Basic Research (Grant No. YSBR-055)the Interdisciplinary Cultivation Project of the Innovation Academy for Precision Measurement of Science and Technology (Grant No. S21S2201)。
文摘Future applications of portable40Ca^(+)optical clocks require reliable magnetic field stabilization to improve frequency stability, which can be achieved by implementing an active and passive magnetic field noise suppression system. On the one hand, we have optimized the magnetic shielding performance of the portable optical clock by reducing its apertures and optimizing its geometry;on the other hand, we have introduced an active magnetic field noise suppression system to further suppress the magnetic field noise experienced by the ions. These efforts reduced the ambient magnetic field noise by about 10000 times, significantly reduced the linewidth of the clock transition spectrum, improved the stability of the portable40Ca+optical clock, and created the conditions for using portable optical clocks in non-laboratory magnetic field environments. This active magnetic field suppression scheme has the advantages of simple installation and wide applicability.
文摘Reflective optics with wide field of view has been applied more and more widely in EUVL or space optics, and also plays an important role in promoting scientific and technological research. Among the reflective optics, the off-axis reflective optics is the most hopeful solution to the ever-highest demands of these applications. This paper gives the requirements of both the above mentioned applications and the similarities and differences between these two kinds of optical systems. Finally, a design example of off-axis reflective optics with wide field of view is presented and described.
基金supported by the National Natural Science Foundation of China(Grant Nos.41275037,41275038,and 41275027)
文摘An airborne multi-axis differential optical absorption spectroscopic （AMAX-DOAS） instrument was developed and applied to measure tropospheric NO2 in the Pearl River Delta region in the south of China. By combining the measurements in nadir and zenith directions and analyzing the UV and visible spectral region using the DOAS method, information about tropospheric NO2 vertical columns was obtained. Strong tropospheric NO2 signals were detected when flying over heavilly polluted regions and point sources like plants. The AMAX-DOAS results were compared with ground-based MAX-DOAS observations in the southwest of Zhuhai city using the same parameters for radiative transport calculations. The difference in vertical column data between the two instruments is about 8%. Our data were also compared with those from OMI and fair agreement was obtained with a correlation coefficient R of 0.61. The difference between the two instruments can be attributed to the different spatial resolution and the temporal mismatch during the measurements.
基金Project supported by the National Natural Science Foundation of China(51772330)。
文摘In recent years,all inorganic CsPbX_(3)(X=F,Cl,Br,and I)perovskite quantum dots(QDs)have garnered increasing attention for their exceptional optical properties.However,the comme rcialization of CsPbX_(3)is hampered by poor environmental stability and lead toxicity.Fortunately,the strategy of incorporating CsPbX_(3)into microcrystalline glass effectively addresses this issue.Notably,CsPbF_(3)demonstrates improved phase stability and a unique electronic structure,making its exploration crucial for various applications.In this study,we synthesized CsPbF_(3)QDs-in-glass(QiG)and Tb^(3+)-doped CsPbF_(3)QDs-inglasses(QiGs)using melt quenching and in-situ growth methods.The CsPbF_(3)QiG exhibits intrinsic photoluminescence with the main peak in the ultraviolet range,while Tb^(3+)-doped glasses show coemission of CsPbF_(3)QDs and Tb^(3+),allowing tunable colors by adjusting Tb^(3+)content.We systematically studied and evaluated the application of Tb^(3+)-doped CsPbF_(3)QiG as an optical temperature sensor.Importantly,the glass sample demonstrates high stability,including good thermal stability,superior high-temperature resistance,and moisture stability.This work significantly contributes to the exploration of the optical properties of CsPbF_(3)QiG,providing new insights into its future applications in diverse optical-related fields.
基金financially supported by National Natural Science Foundation of China (Nos.62305392 and 62305123)Independent Research and Development Project of Naval Engineering University (No.2023504050)the Nursery Plan Project of Navel University of Engineering (2022)。
文摘Optimization and simplification of optical systems represent a milestone in advancing the development of handheld and portable laser-induced breakdown spectroscopy(LIBS)systems towards smaller,more integrated forms.This research,for the first time,conducted a comprehensive optimization design and comparative analysis of three compact LIBS system optical paths:the paraxial optical path(OP),the off-axis OP,and the reflective OP.The differences in spectral intensity and stability among these paths were revealed,providing a scientific basis for selecting the optimal OP for LIBS systems.The research found that the paraxial OP excels in spectral performance and quantitative analysis accuracy,making it the preferred choice for compact LIBS systems.Specifically,the paraxial OP significantly enhances spectral intensity,achieving a 6 times improvement over the off-axis OP and an even more remarkable 150 times increase compared to the reflective OP,greatly enhancing detection sensitivity.Additionally,the relative standard deviation,spectral stability index,maintains a consistently low level,ranging from 10.9%to 13.4%,significantly outperforming the other two OPs and ensuring the reliability of analytical results.In the field of quantitative analysis,the paraxial OP also demonstrates higher accuracy,precision,and sensitivity,comparing to other OPs.The quantitative analysis models for Si,Cu,and Ti elements exhibit excellent fitting,providing users with high-quality quantitative analysis results that are of great significance for applications in material science,environmental monitoring,industrial inspection,and other fields.In summary,this study not only confirms the enormous application potential of the paraxial OP in compact LIBS systems but also provides valuable practical experience and theoretical support for the miniaturization and integration of LIBS systems.Looking ahead,with continuous technological advancements,the design of the paraxial OP is expected to further propel the widespread adoption of LIBS technology in portable,on-site detection applications.
