Herein,anthracene-pyridinium derivative(A1)is synthesized to assemble with amphiphilic sulfonatocalix[4]arene(SC4AD)with a porous cavity through electrostatic interaction,exhibiting enhanced fluorescence emission and ...Herein,anthracene-pyridinium derivative(A1)is synthesized to assemble with amphiphilic sulfonatocalix[4]arene(SC4AD)with a porous cavity through electrostatic interaction,exhibiting enhanced fluorescence emission and multipath fluorescence resonance energy transfer(FRET)with organic dyes(EY,Ni R or Cy5.5).In this nanoassembly,A1/SC4AD first transfers the energy to dye EY(first acceptor),and then delivers it to Ni R(second acceptor),which further transfers the energy to Cy5.5(third acceptor),accompanying with an emission ranging from 535 nm to 570 nm,then to 638 nm,and finally to near-infrared emission at 717 nm.Compared to one-step FRET(43.0%),the three-step FRET system shows higher energy transfer efficiency(FRET Ⅰ:84.9%,FRET Ⅱ:81.4%,FRET Ⅲ:66.9%).The donor/acceptor ratio is 3000(A1):20(EY):8(Ni R):5(Cy5.5),together with an antenna effect of 2.3.Additionally,diverse two-step cascade light-harvesting systems are successfully fabricated via tuning combination of dye acceptors.We believe that this multipath light-harvesting assembly will provide a direction for designing multiple sequential FRET and artificial light-harvesting systems.展开更多
The low Earth orbit(LEO)satellite networks have outstanding advantages such as wide coverage area and not being limited by geographic environment,which can provide a broader range of communication services and has bec...The low Earth orbit(LEO)satellite networks have outstanding advantages such as wide coverage area and not being limited by geographic environment,which can provide a broader range of communication services and has become an essential supplement to the terrestrial network.However,the dynamic changes and uneven distribution of satellite network traffic inevitably bring challenges to multipath routing.Even worse,the harsh space environment often leads to incomplete collection of network state data for routing decision-making,which further complicates this challenge.To address this problem,this paper proposes a state-incomplete intelligent dynamic multipath routing algorithm(SIDMRA)to maximize network efficiency even with incomplete state data as input.Specifically,we model the multipath routing problem as a markov decision process(MDP)and then combine the deep deterministic policy gradient(DDPG)and the K shortest paths(KSP)algorithm to solve the optimal multipath routing policy.We use the temporal correlation of the satellite network state to fit the incomplete state data and then use the message passing neuron network(MPNN)for data enhancement.Simulation results show that the proposed algorithm outperforms baseline algorithms regarding average end-to-end delay and packet loss rate and performs stably under certain missing rates of state data.展开更多
Most GPS positioning errors can be eliminated or removed by the differential technique or the modeling method,but the multipath effect is a special kind of system or gross error,so it is difficult to be simulated or e...Most GPS positioning errors can be eliminated or removed by the differential technique or the modeling method,but the multipath effect is a special kind of system or gross error,so it is difficult to be simulated or eliminated.In order to improve the accuracy of GPS positioning,the single-epoch pseudorange multipath effects at GPS station were calculated,and firstly modeled based on the spherical cap harmonic（SCH）,which is the function of satellite longitude and latitude with the robust method.The accuracy of the kinematic point positioning technique was improved by correcting pseudorange observations with the multipath effect calculated by the SCH model,especially in the elevation direction.The spherical cap harmonic can be used to model the pseudorange multipath effect.展开更多
An altemative algorithm for mitigating GPS multipath was presented by integrating unscented Kalman filter （UKF） and wavelet transform with particle filter. Within consideration of particle degeneracy, UKF was taken ...An altemative algorithm for mitigating GPS multipath was presented by integrating unscented Kalman filter （UKF） and wavelet transform with particle filter. Within consideration of particle degeneracy, UKF was taken for drawing particle. To remove the noise from raw data and data processing error, adaptive wavelet filtering with threshold was adopted while data preprocessing and drawing particle. Three algorithms, named EKF-PF, UKF-PF and WM-UKF-PF, were performed for comparison. The proposed WM-UKF-PF algorithm gives better error minimization, and significantly improves performance of multipath mitigation in terms of SNR and coefficient even though it has computation complexity. It is of significance for high-accuracy positioning and non-stationary deformation analysis.展开更多
In order to improve the performance of multipath mitigation in tracking Galileo signals, a new multipath mitigation method named early-late strobe correlator （ELSC） is proposed. By applying the strobe correlator use...In order to improve the performance of multipath mitigation in tracking Galileo signals, a new multipath mitigation method named early-late strobe correlator （ELSC） is proposed. By applying the strobe correlator used widely in global positioning system （GPS） scenarios to Galileo E1 signals, it can be found that the strobe correlator has an undesirable level of performance when the delay of multipath signals is about 0. 5 chip. Combining several strobe correlators, the ELSC can effectively mitigate the multipath effect especially for the multipath signals with the 0. 5 chip delay. The multipath error envelopes between the strobe correlator and the ELSC are compared for Galileo E1 signals. The simulation results indicate that the ELSC performs excellently on multipath mitigation, and can be applied in both Galileo scenarios and GPS scenarios.展开更多
In order to eliminate the multipath errors existing in static short-baseline applications, a novel de-noising method based on a singular spectrum analysis （named as DSSA） is introduced to extract multipath signals. ...In order to eliminate the multipath errors existing in static short-baseline applications, a novel de-noising method based on a singular spectrum analysis （named as DSSA） is introduced to extract multipath signals. The multipath error is extracted from the double difference （DD） residuals by DSSA and then applied to the correct multipath error in subsequent measurements based on the correlation among adjacent epochs. Methods based on discrete wavelet transform （DWT） and stationary wavelet transform （SWT） are introduced as comparisons of DSSA based on analysis of a simulated signal. Real baseline residuals are tested to verify different extract methods. Results show that compared with the SWT, the DSSA improves the root mean square （RMS） of the residual by 48.6% and achieves a time reduction of 75.3%.展开更多
基金financially supported by the National Natural Science Foundation of China(No.22131008)。
文摘Herein,anthracene-pyridinium derivative(A1)is synthesized to assemble with amphiphilic sulfonatocalix[4]arene(SC4AD)with a porous cavity through electrostatic interaction,exhibiting enhanced fluorescence emission and multipath fluorescence resonance energy transfer(FRET)with organic dyes(EY,Ni R or Cy5.5).In this nanoassembly,A1/SC4AD first transfers the energy to dye EY(first acceptor),and then delivers it to Ni R(second acceptor),which further transfers the energy to Cy5.5(third acceptor),accompanying with an emission ranging from 535 nm to 570 nm,then to 638 nm,and finally to near-infrared emission at 717 nm.Compared to one-step FRET(43.0%),the three-step FRET system shows higher energy transfer efficiency(FRET Ⅰ:84.9%,FRET Ⅱ:81.4%,FRET Ⅲ:66.9%).The donor/acceptor ratio is 3000(A1):20(EY):8(Ni R):5(Cy5.5),together with an antenna effect of 2.3.Additionally,diverse two-step cascade light-harvesting systems are successfully fabricated via tuning combination of dye acceptors.We believe that this multipath light-harvesting assembly will provide a direction for designing multiple sequential FRET and artificial light-harvesting systems.
文摘The low Earth orbit(LEO)satellite networks have outstanding advantages such as wide coverage area and not being limited by geographic environment,which can provide a broader range of communication services and has become an essential supplement to the terrestrial network.However,the dynamic changes and uneven distribution of satellite network traffic inevitably bring challenges to multipath routing.Even worse,the harsh space environment often leads to incomplete collection of network state data for routing decision-making,which further complicates this challenge.To address this problem,this paper proposes a state-incomplete intelligent dynamic multipath routing algorithm(SIDMRA)to maximize network efficiency even with incomplete state data as input.Specifically,we model the multipath routing problem as a markov decision process(MDP)and then combine the deep deterministic policy gradient(DDPG)and the K shortest paths(KSP)algorithm to solve the optimal multipath routing policy.We use the temporal correlation of the satellite network state to fit the incomplete state data and then use the message passing neuron network(MPNN)for data enhancement.Simulation results show that the proposed algorithm outperforms baseline algorithms regarding average end-to-end delay and packet loss rate and performs stably under certain missing rates of state data.
基金Project (41374009) supported by the National Natural Science Foundation of ChinaProjects (TJES1101,TJES1203) supported by the Key Laboratory of Advanced Engineering Surveying of NASMG,China+1 种基金Project (ZR2013DM009) supported by the Shandong Natural Science Foundation of ChinaProject (201412001) supported by the Public Benefit Scientific Research Project of China
文摘Most GPS positioning errors can be eliminated or removed by the differential technique or the modeling method,but the multipath effect is a special kind of system or gross error,so it is difficult to be simulated or eliminated.In order to improve the accuracy of GPS positioning,the single-epoch pseudorange multipath effects at GPS station were calculated,and firstly modeled based on the spherical cap harmonic（SCH）,which is the function of satellite longitude and latitude with the robust method.The accuracy of the kinematic point positioning technique was improved by correcting pseudorange observations with the multipath effect calculated by the SCH model,especially in the elevation direction.The spherical cap harmonic can be used to model the pseudorange multipath effect.
基金Project(51174206)supported by the National Natural Science Foundation of ChinaProject(2013AA12A201)supported by the National Hi-tech Research and Development Program of China+1 种基金Project(2012ZDP08)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(SZBF2011-6-B35)supported by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD),China
文摘An altemative algorithm for mitigating GPS multipath was presented by integrating unscented Kalman filter （UKF） and wavelet transform with particle filter. Within consideration of particle degeneracy, UKF was taken for drawing particle. To remove the noise from raw data and data processing error, adaptive wavelet filtering with threshold was adopted while data preprocessing and drawing particle. Three algorithms, named EKF-PF, UKF-PF and WM-UKF-PF, were performed for comparison. The proposed WM-UKF-PF algorithm gives better error minimization, and significantly improves performance of multipath mitigation in terms of SNR and coefficient even though it has computation complexity. It is of significance for high-accuracy positioning and non-stationary deformation analysis.
基金The National Key Technology R&D Program of China during the 11th Five-Year Plan Period(No.2008BAJ11B05)
文摘In order to improve the performance of multipath mitigation in tracking Galileo signals, a new multipath mitigation method named early-late strobe correlator （ELSC） is proposed. By applying the strobe correlator used widely in global positioning system （GPS） scenarios to Galileo E1 signals, it can be found that the strobe correlator has an undesirable level of performance when the delay of multipath signals is about 0. 5 chip. Combining several strobe correlators, the ELSC can effectively mitigate the multipath effect especially for the multipath signals with the 0. 5 chip delay. The multipath error envelopes between the strobe correlator and the ELSC are compared for Galileo E1 signals. The simulation results indicate that the ELSC performs excellently on multipath mitigation, and can be applied in both Galileo scenarios and GPS scenarios.
基金The National Natural Science Foundation of China(No.51375087,50975049)the Ocean Special Funds for Scientific Research on Public Causes(No.201205035-09)
文摘In order to eliminate the multipath errors existing in static short-baseline applications, a novel de-noising method based on a singular spectrum analysis （named as DSSA） is introduced to extract multipath signals. The multipath error is extracted from the double difference （DD） residuals by DSSA and then applied to the correct multipath error in subsequent measurements based on the correlation among adjacent epochs. Methods based on discrete wavelet transform （DWT） and stationary wavelet transform （SWT） are introduced as comparisons of DSSA based on analysis of a simulated signal. Real baseline residuals are tested to verify different extract methods. Results show that compared with the SWT, the DSSA improves the root mean square （RMS） of the residual by 48.6% and achieves a time reduction of 75.3%.
