Improving the volumetric energy density of supercapacitors is essential for practical applications,which highly relies on the dense storage of ions in carbon-based electrodes.The functional units of carbon-based elect...Improving the volumetric energy density of supercapacitors is essential for practical applications,which highly relies on the dense storage of ions in carbon-based electrodes.The functional units of carbon-based electrode exhibit multi-scale structural characteristics including macroscopic electrode morphologies,mesoscopic microcrystals and pores,and microscopic defects and dopants in the carbon basal plane.Therefore,the ordered combination of multi-scale structures of carbon electrode is crucial for achieving dense energy storage and high volumetric performance by leveraging the functions of various scale structu re.Considering that previous reviews have focused more on the discussion of specific scale structu re of carbon electrodes,this review takes a multi-scale perspective in which recent progresses regarding the structureperformance relationship,underlying mechanism and directional design of carbon-based multi-scale structures including carbon morphology,pore structure,carbon basal plane micro-environment and electrode technology on dense energy storage and volumetric property of supercapacitors are systematically discussed.We analyzed in detail the effects of the morphology,pore,and micro-environment of carbon electrode materials on ion dense storage,summarized the specific effects of different scale structures on volumetric property and recent research progress,and proposed the mutual influence and trade-off relationship between various scale structures.In addition,the challenges and outlooks for improving the dense storage and volumetric performance of carbon-based supercapacitors are analyzed,which can provide feasible technical reference and guidance for the design and manufacture of dense carbon-based electrode materials.展开更多
Advanced chemical engineering for simultaneous modulation of nanomaterial morphology, defects, interfaces, and structure to enhance electromagnetic and microwave absorption (MA) performance. However, accurately distin...Advanced chemical engineering for simultaneous modulation of nanomaterial morphology, defects, interfaces, and structure to enhance electromagnetic and microwave absorption (MA) performance. However, accurately distinguishing the MA contributions of different scale factors and tuning the optimal combined effects remains a formidable challenge. This study employs a synergistic approach combining template protection etching and vacuum annealing to construct a controlled system of micrometer-sized cavities and amorphous carbon matrices in metal-organic framework (MOF) derivatives. The results demonstrate that the spatial effects introduced by the hollow structure enhance dielectric loss but significantly weaken impedance matching. By increasing the proportion of amorphous carbon, the balance between electromagnetic loss and impedance matching can be effectively maintained. Importantly, in a suitable graphitization environment, the presence of oxygen vacancies in amorphous carbon can induce significant polarization to compensate for the reduced conductivity loss due to the absence of sp2 carbon. Through the synergistic effects of morphology and composition, the samples exhibit a broader absorption bandwidth (6.28 GHz) and stronger reflection loss (−61.64 dB) compared to the original MOF. In conclusion, this study aims to elucidate the multiscale impacts of macroscopic micro-nano structure and microscopic defect engineering, providing valuable insights for future research in this field.展开更多
Rare earth elements(REEs) are associated with phosphorite,which is an important strategic reserve resource.During sorting process of phosphorite,REEs may move with specific host minerals,however,occurrence state and m...Rare earth elements(REEs) are associated with phosphorite,which is an important strategic reserve resource.During sorting process of phosphorite,REEs may move with specific host minerals,however,occurrence state and moving pattern of REEs from rock to products are still unclear,which limits separation and enrichment of REEs from phosphorite.Mappings of scanning electron microscope(SEM) and electron probe X-ray micro-analyzer(EPMA) of REEs are highly consistent with those of calcium and phosphorus,and complementary with that of magnesium,which indicates that fluorapatite(Fap) is the main host mineral of REEs.The results of flotation and leaching experiments further indicate that REEs are enriched along with Fap from phosphorite to products.Occupied sites and occupation number of REEs were obtained by X-ray diffraction(XRD) refinement based on the Rietveld method.La,Ce,Nd,and Y can occupy both Ca1 and Ca2 sites.The ratios of La,Ce,Nd,and Y at Ca2 and Cal sites are 4.20,3.70,3.00,and 1.33,showing a decreasing trend,indicating that La,Ce,and Nd tend to occupy Ca2 sites,while Y tends to occupy Ca1 sites.X-ray absorption fine structure(XAFS) shows that REEs mainly form coordinate structures with oxygen and fluorine,which is a direct evidence that REEs replace calcium(Ⅱ) in phosphorite in an isomorphism form.Coordination structure and polyhedral configuration analysis indicate that substitution degree of La,Ce,Nd,and Y is Y> La> Ce≈Nd from easy to difficult at Cal and Ca2 sites.The research enriches the mineralization theory of REEs-bearing phosphorite and provides certain theoretical guidance for selective enrichment of REEs from phosphorite.展开更多
Working conditions of rolling bearings of wind turbine generators are complicated, and their vibration signals often show non-linear and non-stationary characteristics. In order to improve the efficiency of feature ex...Working conditions of rolling bearings of wind turbine generators are complicated, and their vibration signals often show non-linear and non-stationary characteristics. In order to improve the efficiency of feature extraction of wind turbine rolling bearings and to strengthen the feature information, a new structural element and an adaptive algorithm based on the peak energy are proposed,which are combined with spectral correlation analysis to form a fault diagnosis algorithm for wind turbine rolling bearings. The proposed method firstly addresses the problem of impulsive signal omissions that are prone to occur in the process of fault feature extraction of traditional structural elements and proposes a "W" structural element to capture more characteristic information. Then, the proposed method selects the scale of multi-scale mathematical morphology, aiming at the problem of multi-scale mathematical morphology scale selection and structural element expansion law. An adaptive algorithm based on peak energy is proposed to carry out morphological scale selection and structural element expansion by improving the computing efficiency and enhancing the feature extraction effect.Finally, the proposed method performs spectral correlation analysis in the frequency domain for an unknown signal of the extracted feature and identifies the fault based on the correlation coefficient. The method is verified by numerical examples using experimental rig bearing data and actual wind field acquisition data and compared with traditional triangular and flat structural elements. The experimental results show that the new structural elements can more effectively extract the pulses in the signal and reduce noise interference,and the fault-diagnosis algorithm can accurately identify the fault category and improve the reliability of the results.展开更多
The searching method of failure surface which consists of complex geological structures in high and steep rock slopes was studied. Based on computer simulation technology and Monte-Carlo method, three dimensional mult...The searching method of failure surface which consists of complex geological structures in high and steep rock slopes was studied. Based on computer simulation technology and Monte-Carlo method, three dimensional multi-scale geological structures such as engineering scale and statistical scale structures of the slope were simulated. The searching method of failure route which consists of joints and rock bridges was determined via simulation annealing method by considering the shear strength of joints or rock bridges in one supposed route. When shear strengths of all the supposed routes were computed, the least shear strength route was considered failure route. Then, the inclined slice of joint slices and rock bridge slices were separated according to the position of joints and rock bridges. For the rock bridge slices, by distinguishing the failure model, the force direction to the next slice was defined. Finally, the limit equilibrium equations for every slice were established, and the slope stability factor was obtained. One practical example indicates that the discussed method is more closely to the real condition.展开更多
Smart material and structure (SMS) is a challenging novel technique for the 21 century especially in fields of aviation and aerospace. Vibration and noise suppression smart structure is an important branch of SMS. T...Smart material and structure (SMS) is a challenging novel technique for the 21 century especially in fields of aviation and aerospace. Vibration and noise suppression smart structure is an important branch of SMS. There are several typical structures such as the cabin of an airplane, space station, the solar board of satellite and the rotor blade of a helicopter, of which the vibrations and radiation noises have bad influences on precise equipments and aiming systems. In order to suppress vibrations and noises of these structures, several algorithms are applied to the models which simulate the structures. Experiments are performed to suppress vibrations and noises by bonding sensors and actuators to the structures at the optimized locations and using computer based measurement and control systems. For the blade vibration control of a helicopter, a non contact method of signal transmission by magneto electric coupling is discussed. The experimental results demonstrate that the methods used for active control are effective.展开更多
By integrating topology optimization and lattice-based optimization,a novel multi-scale design method is proposed to create solid-lattice hybrid structures and thus to improve the mechanical performance as well as red...By integrating topology optimization and lattice-based optimization,a novel multi-scale design method is proposed to create solid-lattice hybrid structures and thus to improve the mechanical performance as well as reduce the structural weight.To achieve this purpose,a two-step procedure is developed to design and optimize the innovative structures.Initially,the classical topology optimization is utilized to find the optimal material layout and primary load carrying paths.Afterwards,the solid-lattice hybrid structures are reconstructed using the finite element mesh based modeling method.And lattice-based optimization is performed to obtain the optimal crosssection area of the lattice structures.Finally,two typical aerospace structures are optimized to demonstrate the effectiveness of the proposed optimization framework.The numerical results are quite encouraging since the solid-lattice hybrid structures obtained by the presented approach show remarkably improved performance when compared with traditional designs.展开更多
Avian genomes exhibit compact organization and remarkable chromosomal stability.However,the extent and mechanisms by which structural variation in avian genomes differ from those in other vertebrate lineages are poorl...Avian genomes exhibit compact organization and remarkable chromosomal stability.However,the extent and mechanisms by which structural variation in avian genomes differ from those in other vertebrate lineages are poorly explored.This study generated a diploid genome assembly for the golden pheasant(Chrysolophus pictus),a species distinguished by the vibrant plumage of males.Each haploid genome assembly included complete chromosomalmodels,incorporatingall microchromosomes.Analysis revealed extensive tandem amplification of immune-related genes across the smallest microchromosomes(dot chromosomes),with an average copy number of 54.Structural variation between the haploid genomes was primarily shaped by large insertions and deletions(indels),with minimal contributions from inversions or duplications.Approximately 28%of these large indels were associated with recent insertions of transposable elements,despite their typically low activity in bird genomes.Evidence for significant effects of transposable elements on gene expression was minimal.Evolutionary strata on the sex chromosomes were identified,along with a drastic rearrangement of the W chromosome.These analyses of the high-quality diploid genome of the golden pheasant provide valuable insights into the evolutionary patterns of structural variation in avian genomes.展开更多
Design of a miniaturized lumped-element bandpass filter in multilayer liquid crystal polymer technology is proposed.Fractional bandwidth of the bandpass filter is 20%,operating at a center frequency of 500 MHz.In orde...Design of a miniaturized lumped-element bandpass filter in multilayer liquid crystal polymer technology is proposed.Fractional bandwidth of the bandpass filter is 20%,operating at a center frequency of 500 MHz.In order to further reduce the size and improve the performance of the proposed filter,defected ground structure(DGS)has been implemented in the filter.Based on this structure,the volume of the inductor is reduced by 60%eficiently compared with the inductor without DGS,and the Q-factor is increased up to 257%compared with the traditional multilayer spiral inductor.The measured results indicate that the designed filter has a very sharp stopband,an insertion loss of 2.3dB,and a return loss of 18.6dB in the passband.The whole volume of the fabricated filter is 0.032入_(g)×0.05入_(g)×0.00075入_(g),where Ag is the guided wavelength of the center frequency.The proposed filter is easily integrated into radio-frequency/microwave circuitry at a low manufacturing cost,especially wireless communication.展开更多
Achieving high yield strength and ductility in alloys remains a significant challenge in structural materials.In this study,combined nanoprecipitation and gradient grain structure were introduced into a Co-Cr-Ni-based...Achieving high yield strength and ductility in alloys remains a significant challenge in structural materials.In this study,combined nanoprecipitation and gradient grain structure were introduced into a Co-Cr-Ni-based multi-principal element alloy(MPEA)using surface mechanical attrition treatment(SMAT).The multi-scale composite structure,featuring grain sizes refined from∼43.6μm to∼24.3 nm at the topmost surface and high-density L1_(2)nanoprecipitates within the grains,results in a substantial tensile strength of 1733 MPa and a well-maintained ductility of∼23%.The alloy with low local stacking fault energy provides sufficient flow stress to reach the critical value for twinning,a phenomenon rarely observed in MPEAs with high-density L1_(2)nanoprecipitates under quasi-static tensile conditions.The formation of nanotwins further facilitates additional strain hardening,enhancing mechanical performance at ultrahigh strength levels.This work offers significant insights into the deformation behavior of gradient-structured materials with high-density nanoprecipitates.展开更多
Previous studies have demonstrated that increasing Fe doping content can enhance the saturation magnetization and maximum energy product of 2:17-type Sm-Co rare-earth permanent magnets.Howeve r,syste matic theo retica...Previous studies have demonstrated that increasing Fe doping content can enhance the saturation magnetization and maximum energy product of 2:17-type Sm-Co rare-earth permanent magnets.Howeve r,syste matic theo retical calculations and the effects of other transition metal dopants have yet to be explored.This study employed first-principles computational methods to investigate the effects of doping with 3d and Zr transition metal elements on the structural stability,magnetic properties,and electronic structure of Sm_(2)Co_(17)permanent magnets.The results indicate that Sc and Zr tend to occupy the Sm-6c site,while Ni,Cu and Zn preferentially occupy the 18h site,and Ti,V,Cr,Mn and Fe primarily occupy the Co-6c site.Except for V and Cu,all other elements effectively improve the structural stability of the doped systems.Additionally,Mn and Fe doping can significantly enhance the total magnetic moment and magnetocrystalline anisotropy energies of the Sm_(2)Co_(17)system,while Cr only increases the total magnetic moment.More importantly,doping with Cr,Mn and Fe within the doping co ntent range of9.8 at%<x<35.29 at% can simultaneously improve the structural stability,total magnetic moment and magnetocrystalline anisotropy energy of the Sm_(2)Co_(17) system.Our study provides valuable theoretical guidance for experimental exploration and is expected to promote the development and application of novel rare-earth permanent magnetic materials.展开更多
Creep experiments have been conducted on five powder metallurgy TiAl alloys with fine grains (65～80 μm), fine lamellar spacings (0.1～0.16 μm), and different compositions [Ti 47Al(+Cr, Nb, Ta, W, Si)] at temperatur...Creep experiments have been conducted on five powder metallurgy TiAl alloys with fine grains (65～80 μm), fine lamellar spacings (0.1～0.16 μm), and different compositions [Ti 47Al(+Cr, Nb, Ta, W, Si)] at temperatures of 760 ℃ and 815 ℃ and stresses from 35 to 723 MPa. Results show that at a given lamellar spacing 1% Nb(mole fraction) with 1% Ta and replacing 0.2% Ta with 0.2% W induced little effect, but addition of 0.3% Si decreased the creep resistance by a factor of 3～4 under otherwise identical conditions. These different effects of different alloying elements are interpreted in terms of the interaction of alloy segregants with misfit and/or misorientaion dislocations at the lamellar interface. That is, the interaction retards or facilitates the climb of interfacial dislocations, which is rate controlling during creep, depending on the size of the segregants relative to the host atoms.展开更多
A dynamic compression test was performed on α+β dual-phase titanium alloy Ti20C using a split Hopkinson pressure bar.The formation of adiabatic shear bands generated during the compression process was studied by com...A dynamic compression test was performed on α+β dual-phase titanium alloy Ti20C using a split Hopkinson pressure bar.The formation of adiabatic shear bands generated during the compression process was studied by combining the proposed multi-scale crystal plasticity finite element method with experimental measurements.The complex local micro region load was progressively extracted from the simulation results of a macro model and applied to an established three-dimensional multi-grain microstructure model.Subsequently,the evolution histories of the grain shape,size,and orientation inside the adiabatic shear band were quantitatively simulated.The results corresponded closely to the experimental results obtained via transmission electron microscopy and precession electron diffraction.Furthermore,by calculating the grain rotation and temperature rise inside the adiabatic shear band,the microstructural softening and thermal softening effects of typical heavily-deformed α grains were successfully decoupled.The results revealed that the microstructural softening stress was triggered and then stabilized(in general)at a relatively high value.This indicated that the mechanical strength was lowered mainly by the grain orientation evolution or dynamic recrystallization occurring during early plastic deformation.Subsequently,thermal softening increased linearly and became the main softening mechanism.Noticeably,in the final stage,the thermal softening stress accounted for 78.4% of the total softening stress due to the sharp temperature increase,which inevitably leads to the stress collapse and potential failure of the alloy.展开更多
This paper deals with the concurrent multi-scale optimization design of frame structure composed of glass or carbon fiber reinforced polymer laminates. In the composite frame structure, the fiber winding angle at the ...This paper deals with the concurrent multi-scale optimization design of frame structure composed of glass or carbon fiber reinforced polymer laminates. In the composite frame structure, the fiber winding angle at the micro-material scale and the geometrical parameter of components of the frame in the macro-structural scale are introduced as the independent variables on the two geometrical scales. Considering manufacturing requirements, discrete fiber winding angles are specified for the micro design variable. The improved Heaviside penalization discrete material optimization interpolation scheme has been applied to achieve the discrete optimization design of the fiber winding angle. An optimization model based on the minimum structural compliance and the specified fiber material volume constraint has been established. The sensitivity information about the two geometrical scales design variables are also deduced considering the characteristics of discrete fiber winding angles. The optimization results of the fiber winding angle or the macro structural topology on the two single geometrical scales, together with the concurrent two-scale optimization, is separately studied and compared in the paper. Numerical examples in the paper show that the concurrent multi-scale optimization can further explore the coupling effect between the macro-structure and micro-material of the composite to achieve an ultralight design of the composite frame structure. The novel two geometrical scales optimization model provides a new opportunity for the design of composite structure in aerospace and other industries.展开更多
In order to better understand the fatigue mechanisms of steel structures working under high temperature, a multi-scale fatigue damage model at high temperature is developed. In the developed model, the macroscopic fat...In order to better understand the fatigue mechanisms of steel structures working under high temperature, a multi-scale fatigue damage model at high temperature is developed. In the developed model, the macroscopic fatigue damage of metallic materials due to the collective behavior of micro-cracks is quantified by using the generalized self-consistent method. The influence of temperature on fatigue damage of steel structures is quantified by using the previous creep damage model. In addition, the fatigue damage at room temperature and creep damage is coupled in the multi-scale fatigue damage model. The validity of the developed multi-scale damage model is verified by comparing the predicted damage evolution curve with the experimental data. It shows that the developed model is effectiveness. Finally, the fatigue analysis on steel crane runway girders (CRGs) of industrial steel melt shop is performed based on the developed model.展开更多
It was shown by TEM and X-ray analysis that there are four types of grains of the main Ni3Al phase in the structure of the intermetallic obtained by the self-propagation high temperature method (SHS). Every type of gr...It was shown by TEM and X-ray analysis that there are four types of grains of the main Ni3Al phase in the structure of the intermetallic obtained by the self-propagation high temperature method (SHS). Every type of grains has its own domain and dislocation structure. There are mono- and polydomains with and without dislocations. The grains of the main phase of monoand polydomains without dislocations and polydomains with dislocations were formed by diffusion in the solid phase. In these conditions NiAl3 phase is located on the grain boundary of the main phase. The Ni2Al3 phase is located at the triple joints of the main phase.展开更多
Unique rapid solidified structure and nanocrystallization mechanism enable the Fe-based nanocrystalline alloys with high Cu content excellent soft magnetic properties and good manufacturability,and also results in unu...Unique rapid solidified structure and nanocrystallization mechanism enable the Fe-based nanocrystalline alloys with high Cu content excellent soft magnetic properties and good manufacturability,and also results in unusual phenomena in terms of alloying effects.In the present work,we systematically studied the influence rules of early transition elements on the rapid solidified structure and nanocrystallization behaviors of Fe-Si-B-Cu soft magnetic alloys with high Cu content and explored the related mechanisms.In terms of rapid solidified structure,the additions of early transition elements always inhibit the for-mation of pre-existingα-Fe crystals even eliminate them,and the additions that could produce larger atomic mismatch parameter(δ)and negative mixing enthalpy(△H_(mix))show stronger effects.In terms of nanocrystallization behaviors,the increases inδand negative△H_(mix) weaken the competitive growth between the pre-existing nanocrystals during annealing and then coarsen the nanostructure of the an-nealed alloys and deteriorate their magnetic softness,while the excessive increases inδand negativeHmix could significantly suppress the growth ofα-Fe crystals by diffusion inhibition during annealing and thus remarkable refine the nanostructure of the annealed alloys and improve their magnetic softness.展开更多
The Ni_3B phase was formed when boron (0.5 at. pct B) was added to the intermetallic of sto- ichiometric and off-stoichiometric (Ni-24 at. pct Al) compounds. In the alloy of stoichiometric composition the particles o...The Ni_3B phase was formed when boron (0.5 at. pct B) was added to the intermetallic of sto- ichiometric and off-stoichiometric (Ni-24 at. pct Al) compounds. In the alloy of stoichiometric composition the particles of Ni_3B phase has the size around 0.1μm and is located on the grain boundary of the main phase. The decreasing of concentrations of Al in the ofF-stoichiometric alloy leads to increase in the degree of the long-range order parameter, increasing the concen- trations of boron in the solid solution and decreasing its localization on the grain boundary. Microalloying of boron leads to increasing in the fraction of grain monodomains with disloca- tions up to 0.7 in the alloy of the off-stoichiometric composition and up to 1 in the alloy of the stoichiometric composition. It was established the correlation between the degree of the concentration inhomogeneity, average density of the dislocations and the average long range-order parameter.展开更多
1.IntroductionThe influence of substitution of variouselements for Fe on the magnetic propertiesof the NdFeBalloy has been investi-gated by several authors,among which theAl substitution can increase the coercivity[1]...1.IntroductionThe influence of substitution of variouselements for Fe on the magnetic propertiesof the NdFeBalloy has been investi-gated by several authors,among which theAl substitution can increase the coercivity[1]and the addition of both Co and Al has beenproved to have a positive effect on im-proving both the coercivity and other per-展开更多
By calculating the electron structures of the phases that phosphor, sulfur and alloying elements dissolving inγ-Fe, the reason why alloying elements can bring centerline segregation in continuous casting slab (CCS) w...By calculating the electron structures of the phases that phosphor, sulfur and alloying elements dissolving inγ-Fe, the reason why alloying elements can bring centerline segregation in continuous casting slab (CCS) with nA, the number of electrons on the strongest covalent bonds, and the structure formation factor S were investigated, and an electron structural criterion to control and to eliminate the centerline segregation was advanced. Basing on this, the electron structures of a part of rare earth phosphides and sulfides are calculated, the physical mechanism that rare earth elements can control the segregation of phosphor and sulfur is analyzed, and the criterion is well verified.展开更多
基金funded by the Joint Fund for Regional Innovation and Development of National Natural Science Foundation of China(U21A20143)the National Science Fund for Excellent Young Scholars(52322607)the Excellent Youth Foundation of Heilongjiang Scientific Committee(YQ2022E028)。
文摘Improving the volumetric energy density of supercapacitors is essential for practical applications,which highly relies on the dense storage of ions in carbon-based electrodes.The functional units of carbon-based electrode exhibit multi-scale structural characteristics including macroscopic electrode morphologies,mesoscopic microcrystals and pores,and microscopic defects and dopants in the carbon basal plane.Therefore,the ordered combination of multi-scale structures of carbon electrode is crucial for achieving dense energy storage and high volumetric performance by leveraging the functions of various scale structu re.Considering that previous reviews have focused more on the discussion of specific scale structu re of carbon electrodes,this review takes a multi-scale perspective in which recent progresses regarding the structureperformance relationship,underlying mechanism and directional design of carbon-based multi-scale structures including carbon morphology,pore structure,carbon basal plane micro-environment and electrode technology on dense energy storage and volumetric property of supercapacitors are systematically discussed.We analyzed in detail the effects of the morphology,pore,and micro-environment of carbon electrode materials on ion dense storage,summarized the specific effects of different scale structures on volumetric property and recent research progress,and proposed the mutual influence and trade-off relationship between various scale structures.In addition,the challenges and outlooks for improving the dense storage and volumetric performance of carbon-based supercapacitors are analyzed,which can provide feasible technical reference and guidance for the design and manufacture of dense carbon-based electrode materials.
基金supported by the National Natural Science Foundation of China(52172091,52172295)Defense Industrial Technology Development Program(JCKY2023605C002)+4 种基金Frontier Leading Technology Basic Research Major Project of Jiangsu Province(SBK2023050110)the National Key Laboratory on Electromagnetic Environmental Effects and Electro-optical Engineering(NO.61422062301)the Opening Project of Science and Technology on Reliability Physics and Application Technology of Electronic Component Laboratory(ZHD202305)the Opening Project of Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology(ASMA202303)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX23_0371).
文摘Advanced chemical engineering for simultaneous modulation of nanomaterial morphology, defects, interfaces, and structure to enhance electromagnetic and microwave absorption (MA) performance. However, accurately distinguishing the MA contributions of different scale factors and tuning the optimal combined effects remains a formidable challenge. This study employs a synergistic approach combining template protection etching and vacuum annealing to construct a controlled system of micrometer-sized cavities and amorphous carbon matrices in metal-organic framework (MOF) derivatives. The results demonstrate that the spatial effects introduced by the hollow structure enhance dielectric loss but significantly weaken impedance matching. By increasing the proportion of amorphous carbon, the balance between electromagnetic loss and impedance matching can be effectively maintained. Importantly, in a suitable graphitization environment, the presence of oxygen vacancies in amorphous carbon can induce significant polarization to compensate for the reduced conductivity loss due to the absence of sp2 carbon. Through the synergistic effects of morphology and composition, the samples exhibit a broader absorption bandwidth (6.28 GHz) and stronger reflection loss (−61.64 dB) compared to the original MOF. In conclusion, this study aims to elucidate the multiscale impacts of macroscopic micro-nano structure and microscopic defect engineering, providing valuable insights for future research in this field.
基金Project supported by Guizhou Provincial Basic Research Program (Natural Science)(Qian Ke He Basic-ZK 2024 General 626)National Natural Science Foundation of China (52164018)Scientific Research Foundation for High-level Talents of Anhui University of Science and Technology (13210025)。
文摘Rare earth elements(REEs) are associated with phosphorite,which is an important strategic reserve resource.During sorting process of phosphorite,REEs may move with specific host minerals,however,occurrence state and moving pattern of REEs from rock to products are still unclear,which limits separation and enrichment of REEs from phosphorite.Mappings of scanning electron microscope(SEM) and electron probe X-ray micro-analyzer(EPMA) of REEs are highly consistent with those of calcium and phosphorus,and complementary with that of magnesium,which indicates that fluorapatite(Fap) is the main host mineral of REEs.The results of flotation and leaching experiments further indicate that REEs are enriched along with Fap from phosphorite to products.Occupied sites and occupation number of REEs were obtained by X-ray diffraction(XRD) refinement based on the Rietveld method.La,Ce,Nd,and Y can occupy both Ca1 and Ca2 sites.The ratios of La,Ce,Nd,and Y at Ca2 and Cal sites are 4.20,3.70,3.00,and 1.33,showing a decreasing trend,indicating that La,Ce,and Nd tend to occupy Ca2 sites,while Y tends to occupy Ca1 sites.X-ray absorption fine structure(XAFS) shows that REEs mainly form coordinate structures with oxygen and fluorine,which is a direct evidence that REEs replace calcium(Ⅱ) in phosphorite in an isomorphism form.Coordination structure and polyhedral configuration analysis indicate that substitution degree of La,Ce,Nd,and Y is Y> La> Ce≈Nd from easy to difficult at Cal and Ca2 sites.The research enriches the mineralization theory of REEs-bearing phosphorite and provides certain theoretical guidance for selective enrichment of REEs from phosphorite.
基金supported by National Natural Science Foundation of China (No. 61763037)Inner Mongolia Autonomous Region Natural Science Foundation of China(No. 2019LH06007)Science and Technology Plan Project of Inner Mongolia (No. 2019,2020GG028)。
文摘Working conditions of rolling bearings of wind turbine generators are complicated, and their vibration signals often show non-linear and non-stationary characteristics. In order to improve the efficiency of feature extraction of wind turbine rolling bearings and to strengthen the feature information, a new structural element and an adaptive algorithm based on the peak energy are proposed,which are combined with spectral correlation analysis to form a fault diagnosis algorithm for wind turbine rolling bearings. The proposed method firstly addresses the problem of impulsive signal omissions that are prone to occur in the process of fault feature extraction of traditional structural elements and proposes a "W" structural element to capture more characteristic information. Then, the proposed method selects the scale of multi-scale mathematical morphology, aiming at the problem of multi-scale mathematical morphology scale selection and structural element expansion law. An adaptive algorithm based on peak energy is proposed to carry out morphological scale selection and structural element expansion by improving the computing efficiency and enhancing the feature extraction effect.Finally, the proposed method performs spectral correlation analysis in the frequency domain for an unknown signal of the extracted feature and identifies the fault based on the correlation coefficient. The method is verified by numerical examples using experimental rig bearing data and actual wind field acquisition data and compared with traditional triangular and flat structural elements. The experimental results show that the new structural elements can more effectively extract the pulses in the signal and reduce noise interference,and the fault-diagnosis algorithm can accurately identify the fault category and improve the reliability of the results.
基金Project(50539100) supported by the National Natural Science Foundation of ChinaProject(BK2006171) supported by the Jiangsu Natural Science Foundation
文摘The searching method of failure surface which consists of complex geological structures in high and steep rock slopes was studied. Based on computer simulation technology and Monte-Carlo method, three dimensional multi-scale geological structures such as engineering scale and statistical scale structures of the slope were simulated. The searching method of failure route which consists of joints and rock bridges was determined via simulation annealing method by considering the shear strength of joints or rock bridges in one supposed route. When shear strengths of all the supposed routes were computed, the least shear strength route was considered failure route. Then, the inclined slice of joint slices and rock bridge slices were separated according to the position of joints and rock bridges. For the rock bridge slices, by distinguishing the failure model, the force direction to the next slice was defined. Finally, the limit equilibrium equations for every slice were established, and the slope stability factor was obtained. One practical example indicates that the discussed method is more closely to the real condition.
文摘Smart material and structure (SMS) is a challenging novel technique for the 21 century especially in fields of aviation and aerospace. Vibration and noise suppression smart structure is an important branch of SMS. There are several typical structures such as the cabin of an airplane, space station, the solar board of satellite and the rotor blade of a helicopter, of which the vibrations and radiation noises have bad influences on precise equipments and aiming systems. In order to suppress vibrations and noises of these structures, several algorithms are applied to the models which simulate the structures. Experiments are performed to suppress vibrations and noises by bonding sensors and actuators to the structures at the optimized locations and using computer based measurement and control systems. For the blade vibration control of a helicopter, a non contact method of signal transmission by magneto electric coupling is discussed. The experimental results demonstrate that the methods used for active control are effective.
基金supported by National Key Research and Development Program(No.2017YFB1102800)Key Project of NSFC(Nos.51790171 and 51761145111)NSFC for Excellent Young Scholars(No.11722219)。
文摘By integrating topology optimization and lattice-based optimization,a novel multi-scale design method is proposed to create solid-lattice hybrid structures and thus to improve the mechanical performance as well as reduce the structural weight.To achieve this purpose,a two-step procedure is developed to design and optimize the innovative structures.Initially,the classical topology optimization is utilized to find the optimal material layout and primary load carrying paths.Afterwards,the solid-lattice hybrid structures are reconstructed using the finite element mesh based modeling method.And lattice-based optimization is performed to obtain the optimal crosssection area of the lattice structures.Finally,two typical aerospace structures are optimized to demonstrate the effectiveness of the proposed optimization framework.The numerical results are quite encouraging since the solid-lattice hybrid structures obtained by the presented approach show remarkably improved performance when compared with traditional designs.
基金supported by the Foundation of Gansu Key Laboratory of Protection and Utilization for Biological Resources and Ecological Restoration in Longdong (LDSWZY202103)Natural Science Foundation of Gansu Province (22JR5RM210)to B.P.L.Gansu Ziwuling Ecosystem Observation and Research Station (20JR10RA658)。
文摘Avian genomes exhibit compact organization and remarkable chromosomal stability.However,the extent and mechanisms by which structural variation in avian genomes differ from those in other vertebrate lineages are poorly explored.This study generated a diploid genome assembly for the golden pheasant(Chrysolophus pictus),a species distinguished by the vibrant plumage of males.Each haploid genome assembly included complete chromosomalmodels,incorporatingall microchromosomes.Analysis revealed extensive tandem amplification of immune-related genes across the smallest microchromosomes(dot chromosomes),with an average copy number of 54.Structural variation between the haploid genomes was primarily shaped by large insertions and deletions(indels),with minimal contributions from inversions or duplications.Approximately 28%of these large indels were associated with recent insertions of transposable elements,despite their typically low activity in bird genomes.Evidence for significant effects of transposable elements on gene expression was minimal.Evolutionary strata on the sex chromosomes were identified,along with a drastic rearrangement of the W chromosome.These analyses of the high-quality diploid genome of the golden pheasant provide valuable insights into the evolutionary patterns of structural variation in avian genomes.
基金the Shaanxi Provincial Key Research and Development Program(No.2020GY-040)。
文摘Design of a miniaturized lumped-element bandpass filter in multilayer liquid crystal polymer technology is proposed.Fractional bandwidth of the bandpass filter is 20%,operating at a center frequency of 500 MHz.In order to further reduce the size and improve the performance of the proposed filter,defected ground structure(DGS)has been implemented in the filter.Based on this structure,the volume of the inductor is reduced by 60%eficiently compared with the inductor without DGS,and the Q-factor is increased up to 257%compared with the traditional multilayer spiral inductor.The measured results indicate that the designed filter has a very sharp stopband,an insertion loss of 2.3dB,and a return loss of 18.6dB in the passband.The whole volume of the fabricated filter is 0.032入_(g)×0.05入_(g)×0.00075入_(g),where Ag is the guided wavelength of the center frequency.The proposed filter is easily integrated into radio-frequency/microwave circuitry at a low manufacturing cost,especially wireless communication.
基金financially supported by the National Natural Science Foundation of China(Nos.52122102 and 523B2003).
文摘Achieving high yield strength and ductility in alloys remains a significant challenge in structural materials.In this study,combined nanoprecipitation and gradient grain structure were introduced into a Co-Cr-Ni-based multi-principal element alloy(MPEA)using surface mechanical attrition treatment(SMAT).The multi-scale composite structure,featuring grain sizes refined from∼43.6μm to∼24.3 nm at the topmost surface and high-density L1_(2)nanoprecipitates within the grains,results in a substantial tensile strength of 1733 MPa and a well-maintained ductility of∼23%.The alloy with low local stacking fault energy provides sufficient flow stress to reach the critical value for twinning,a phenomenon rarely observed in MPEAs with high-density L1_(2)nanoprecipitates under quasi-static tensile conditions.The formation of nanotwins further facilitates additional strain hardening,enhancing mechanical performance at ultrahigh strength levels.This work offers significant insights into the deformation behavior of gradient-structured materials with high-density nanoprecipitates.
基金Project supported by the National Key R&D Program of China(2022YFB3505301)the National Key R&D Program of Shanxi Province(202302050201014)+2 种基金the National Natural Science Foundation of China(12304148)the Natural Science Basic Research Program of Shanxi Province(202203021222219)the China Postdoctoral Science Foundation(2023M731452)。
文摘Previous studies have demonstrated that increasing Fe doping content can enhance the saturation magnetization and maximum energy product of 2:17-type Sm-Co rare-earth permanent magnets.Howeve r,syste matic theo retical calculations and the effects of other transition metal dopants have yet to be explored.This study employed first-principles computational methods to investigate the effects of doping with 3d and Zr transition metal elements on the structural stability,magnetic properties,and electronic structure of Sm_(2)Co_(17)permanent magnets.The results indicate that Sc and Zr tend to occupy the Sm-6c site,while Ni,Cu and Zn preferentially occupy the 18h site,and Ti,V,Cr,Mn and Fe primarily occupy the Co-6c site.Except for V and Cu,all other elements effectively improve the structural stability of the doped systems.Additionally,Mn and Fe doping can significantly enhance the total magnetic moment and magnetocrystalline anisotropy energies of the Sm_(2)Co_(17)system,while Cr only increases the total magnetic moment.More importantly,doping with Cr,Mn and Fe within the doping co ntent range of9.8 at%<x<35.29 at% can simultaneously improve the structural stability,total magnetic moment and magnetocrystalline anisotropy energy of the Sm_(2)Co_(17) system.Our study provides valuable theoretical guidance for experimental exploration and is expected to promote the development and application of novel rare-earth permanent magnetic materials.
文摘Creep experiments have been conducted on five powder metallurgy TiAl alloys with fine grains (65～80 μm), fine lamellar spacings (0.1～0.16 μm), and different compositions [Ti 47Al(+Cr, Nb, Ta, W, Si)] at temperatures of 760 ℃ and 815 ℃ and stresses from 35 to 723 MPa. Results show that at a given lamellar spacing 1% Nb(mole fraction) with 1% Ta and replacing 0.2% Ta with 0.2% W induced little effect, but addition of 0.3% Si decreased the creep resistance by a factor of 3～4 under otherwise identical conditions. These different effects of different alloying elements are interpreted in terms of the interaction of alloy segregants with misfit and/or misorientaion dislocations at the lamellar interface. That is, the interaction retards or facilitates the climb of interfacial dislocations, which is rate controlling during creep, depending on the size of the segregants relative to the host atoms.
基金financially supported by the National Natural Science Foundation of China(No.51571031)。
文摘A dynamic compression test was performed on α+β dual-phase titanium alloy Ti20C using a split Hopkinson pressure bar.The formation of adiabatic shear bands generated during the compression process was studied by combining the proposed multi-scale crystal plasticity finite element method with experimental measurements.The complex local micro region load was progressively extracted from the simulation results of a macro model and applied to an established three-dimensional multi-grain microstructure model.Subsequently,the evolution histories of the grain shape,size,and orientation inside the adiabatic shear band were quantitatively simulated.The results corresponded closely to the experimental results obtained via transmission electron microscopy and precession electron diffraction.Furthermore,by calculating the grain rotation and temperature rise inside the adiabatic shear band,the microstructural softening and thermal softening effects of typical heavily-deformed α grains were successfully decoupled.The results revealed that the microstructural softening stress was triggered and then stabilized(in general)at a relatively high value.This indicated that the mechanical strength was lowered mainly by the grain orientation evolution or dynamic recrystallization occurring during early plastic deformation.Subsequently,thermal softening increased linearly and became the main softening mechanism.Noticeably,in the final stage,the thermal softening stress accounted for 78.4% of the total softening stress due to the sharp temperature increase,which inevitably leads to the stress collapse and potential failure of the alloy.
基金financial support for this research was provided by the Program (Grants 11372060, 91216201) of the National Natural Science Foundation of ChinaProgram (LJQ2015026 ) for Excellent Talents at Colleges and Universities in Liaoning Province+3 种基金the Major National Science and Technology Project (2011ZX02403-002)111 project (B14013)Fundamental Research Funds for the Central Universities (DUT14LK30)the China Scholarship Fund
文摘This paper deals with the concurrent multi-scale optimization design of frame structure composed of glass or carbon fiber reinforced polymer laminates. In the composite frame structure, the fiber winding angle at the micro-material scale and the geometrical parameter of components of the frame in the macro-structural scale are introduced as the independent variables on the two geometrical scales. Considering manufacturing requirements, discrete fiber winding angles are specified for the micro design variable. The improved Heaviside penalization discrete material optimization interpolation scheme has been applied to achieve the discrete optimization design of the fiber winding angle. An optimization model based on the minimum structural compliance and the specified fiber material volume constraint has been established. The sensitivity information about the two geometrical scales design variables are also deduced considering the characteristics of discrete fiber winding angles. The optimization results of the fiber winding angle or the macro structural topology on the two single geometrical scales, together with the concurrent two-scale optimization, is separately studied and compared in the paper. Numerical examples in the paper show that the concurrent multi-scale optimization can further explore the coupling effect between the macro-structure and micro-material of the composite to achieve an ultralight design of the composite frame structure. The novel two geometrical scales optimization model provides a new opportunity for the design of composite structure in aerospace and other industries.
文摘In order to better understand the fatigue mechanisms of steel structures working under high temperature, a multi-scale fatigue damage model at high temperature is developed. In the developed model, the macroscopic fatigue damage of metallic materials due to the collective behavior of micro-cracks is quantified by using the generalized self-consistent method. The influence of temperature on fatigue damage of steel structures is quantified by using the previous creep damage model. In addition, the fatigue damage at room temperature and creep damage is coupled in the multi-scale fatigue damage model. The validity of the developed multi-scale damage model is verified by comparing the predicted damage evolution curve with the experimental data. It shows that the developed model is effectiveness. Finally, the fatigue analysis on steel crane runway girders (CRGs) of industrial steel melt shop is performed based on the developed model.
文摘It was shown by TEM and X-ray analysis that there are four types of grains of the main Ni3Al phase in the structure of the intermetallic obtained by the self-propagation high temperature method (SHS). Every type of grains has its own domain and dislocation structure. There are mono- and polydomains with and without dislocations. The grains of the main phase of monoand polydomains without dislocations and polydomains with dislocations were formed by diffusion in the solid phase. In these conditions NiAl3 phase is located on the grain boundary of the main phase. The Ni2Al3 phase is located at the triple joints of the main phase.
基金supported by the National Key R&D Program of China(No.2021YFB3803004)the National Natural Science Foundation of China(Nos.52101239 and 52171153)+4 种基金Ningbo Natural Science Foundation(No.2021J222)the“Pioneer”R&D Program of Zhejiang Province(No.2023C01075)Youth Innovation Promotion Association CAS(No.2021294)Zhejiang Provincial Key Research and Development Projects(No.2021C01033)CITIC Group Major Science and Technology Innovation Project(HT-FZB-2022190).
文摘Unique rapid solidified structure and nanocrystallization mechanism enable the Fe-based nanocrystalline alloys with high Cu content excellent soft magnetic properties and good manufacturability,and also results in unusual phenomena in terms of alloying effects.In the present work,we systematically studied the influence rules of early transition elements on the rapid solidified structure and nanocrystallization behaviors of Fe-Si-B-Cu soft magnetic alloys with high Cu content and explored the related mechanisms.In terms of rapid solidified structure,the additions of early transition elements always inhibit the for-mation of pre-existingα-Fe crystals even eliminate them,and the additions that could produce larger atomic mismatch parameter(δ)and negative mixing enthalpy(△H_(mix))show stronger effects.In terms of nanocrystallization behaviors,the increases inδand negative△H_(mix) weaken the competitive growth between the pre-existing nanocrystals during annealing and then coarsen the nanostructure of the an-nealed alloys and deteriorate their magnetic softness,while the excessive increases inδand negativeHmix could significantly suppress the growth ofα-Fe crystals by diffusion inhibition during annealing and thus remarkable refine the nanostructure of the annealed alloys and improve their magnetic softness.
文摘The Ni_3B phase was formed when boron (0.5 at. pct B) was added to the intermetallic of sto- ichiometric and off-stoichiometric (Ni-24 at. pct Al) compounds. In the alloy of stoichiometric composition the particles of Ni_3B phase has the size around 0.1μm and is located on the grain boundary of the main phase. The decreasing of concentrations of Al in the ofF-stoichiometric alloy leads to increase in the degree of the long-range order parameter, increasing the concen- trations of boron in the solid solution and decreasing its localization on the grain boundary. Microalloying of boron leads to increasing in the fraction of grain monodomains with disloca- tions up to 0.7 in the alloy of the off-stoichiometric composition and up to 1 in the alloy of the stoichiometric composition. It was established the correlation between the degree of the concentration inhomogeneity, average density of the dislocations and the average long range-order parameter.
文摘1.IntroductionThe influence of substitution of variouselements for Fe on the magnetic propertiesof the NdFeBalloy has been investi-gated by several authors,among which theAl substitution can increase the coercivity[1]and the addition of both Co and Al has beenproved to have a positive effect on im-proving both the coercivity and other per-
基金the Natural Science Foundation of Liaoning under grant No.20022150 the National Natural Science Foundation of China under grant No.50271030.
文摘By calculating the electron structures of the phases that phosphor, sulfur and alloying elements dissolving inγ-Fe, the reason why alloying elements can bring centerline segregation in continuous casting slab (CCS) with nA, the number of electrons on the strongest covalent bonds, and the structure formation factor S were investigated, and an electron structural criterion to control and to eliminate the centerline segregation was advanced. Basing on this, the electron structures of a part of rare earth phosphides and sulfides are calculated, the physical mechanism that rare earth elements can control the segregation of phosphor and sulfur is analyzed, and the criterion is well verified.
