In this study, to meet the development and application requirements for high-strength and hightoughness energetic structural materials, a representative volume element of a TA15 matrix embedded with a TaZrNb sphere wa...In this study, to meet the development and application requirements for high-strength and hightoughness energetic structural materials, a representative volume element of a TA15 matrix embedded with a TaZrNb sphere was designed and fabricated via diffusion bonding. The mechanisms of the microstructural evolution of the TaZrNb/TA15 interface were investigated via SEM, EBSD, EDS, and XRD.Interface mechanical property tests and in-situ tensile tests were conducted on the sphere-containing structure, and an equivalent tensile-strength model was established for the structure. The results revealed that the TA15 titanium alloy and joint had high density and no pores or cracks. The thickness of the planar joint was approximately 50-60 μm. The average tensile and shear strengths were 767 MPa and 608 MPa, respectively. The thickness of the spherical joint was approximately 60 μm. The Zr and Nb elements in the joint diffused uniformly and formed strong bonds with Ti without forming intermetallic compounds. The interface exhibited submicron grain refinement and a concave-convex interlocking structure. The tensile fracture surface primarily exhibited intergranular fracture combined with some transgranular fracture, which constituted a quasi-brittle fracture mode. The shear fracture surface exhibited brittle fracture with regular arrangements of furrows. Internal fracture occurred along the spherical interface, as revealed by advanced in-situ X-ray microcomputed tomography. The experimental results agreed well with the theoretical predictions, indicating that the high-strength interface contributes to the overall strength and toughness of the sphere-containing structure.展开更多
For a complex flow about multi-element airfoils a mixed grid method is set up. C-type grids are produced on each element′s body and in their wakes at first, O-type grids are given in the outmost area, and H-type grid...For a complex flow about multi-element airfoils a mixed grid method is set up. C-type grids are produced on each element′s body and in their wakes at first, O-type grids are given in the outmost area, and H-type grids are used in middle additional areas. An algebra method is used to produce the initial grids in each area. And the girds are optimized by elliptical differential equation method. Then C-O-H zonal patched grids around multi-element airfoils are produced automatically and efficiently. A time accurate finite-volume integration method is used to solve the compressible laminar and turbulent Navier-Stokes (N-S) equations on the grids. Computational results prove the method to be effective.展开更多
Almost half of all flight accidents caused by inflight icing occur at the approach and landing phases when high-lift devices are deployed.The present study focuses on the optimization of an ice-tolerant multi-element ...Almost half of all flight accidents caused by inflight icing occur at the approach and landing phases when high-lift devices are deployed.The present study focuses on the optimization of an ice-tolerant multi-element airfoil.Dual-objective optimization is carried out with critical hornshaped ice accumulated during the holding phase.The optimization results show that the present optimization method significantly enhances the iced-state and clean-state performance.The optimal multi-element airfoil has a larger deflection angle and wider gap at the slat and the flap compared with the baseline configuration.The sensitivity of each design parameter is analyzed,which verifies the robustness of the design.The design is further assessed when ice is accreted during the approach and landing phases,which also shows performance improvement.展开更多
To study the effects of the gamma reflection of multi-element materials,gamma ray transport models of single-element materials,such as iron and lead,and multielement materials,such as polyethylene and ordinary concret...To study the effects of the gamma reflection of multi-element materials,gamma ray transport models of single-element materials,such as iron and lead,and multielement materials,such as polyethylene and ordinary concrete,were established in this study.Relationships among the albedo factors of the gamma photons and energies and average energy of the reflected gamma rays by material type,material thickness,incident gamma energy,and incidence angle of gamma rays were obtained by Monte Carlo simulation.The results show that the albedo factors of single-element and multi-element materials increase rapidly with an increase in the material thickness.When the thickness of the material increases to a certain value,the albedo factors do not increase further but rather tend to the saturation value.The saturation values for the albedo factors of the gamma photons,and energies and the reflection thickness are related not only to the type of material but also to the incident gamma energy and incidence angle of the gamma rays.At a given incident gamma energy,which is between 0.2 and 2.5 MeV,the smaller the effective atomic number of the multi-element material is,the higher the saturation values of the albedo factors are.The larger the incidence angle of the gamma ray is,the greater the saturation value of the gamma albedo factor,saturation reflection thickness,and average saturation energy of the reflected gamma photons are.展开更多
The paper is to integrate aerodynamic and aero-acoustic optimizatiom design of high lift devices,especially for two-element airfoils with slat.Aerodynamic analysis on flow field utilizes a high-order,high-resolution s...The paper is to integrate aerodynamic and aero-acoustic optimizatiom design of high lift devices,especially for two-element airfoils with slat.Aerodynamic analysis on flow field utilizes a high-order,high-resolution spatial differential method for large eddy simulation(LES),which can guarantee accuracy and efficiency.The aeroacoustic analysis for noise level is calculated with Ffowcs Williams-Hawkings(FW-H)integration formula.Fidelity of calculation is verified by standard models.Method of streamline-based Euler simulation(MSES)is used to obtain the aerodynamic characters.Based on the confirmation of numerical methods,detailed research has been conducted for the leading edge slat on multi-element airfoils.Various slot parameter influences on noise are analyzed.The results of the slot optimization parameters can be used in multi-element airfoil design.展开更多
The effects of Al and Sc on mechanical properties of FeCoNi multi-element alloys(MEAs) were investigated by compressive tests. The microstructures of FeCoNi MEAs with different contents of Al and Sc were characterized...The effects of Al and Sc on mechanical properties of FeCoNi multi-element alloys(MEAs) were investigated by compressive tests. The microstructures of FeCoNi MEAs with different contents of Al and Sc were characterized and the strengthening mechanisms were discussed. The results show that FeCoNi MEA with a low content of Al has a face-centered cubic(FCC) structure. The yield strength increases linearly with the increase of Al content, which is largely caused by solid solution hardening. Further addition of Sc can promote the formation of a new phase in(FeCoNi)1-xAlx MEAs. A minor addition of Sc can significantly increase the yield strengths of(FeCoNi)1-xAlx MEAs with a low Al content and improve the compressive plasticity of(FeCoNi)1-xAlx MEAs with a high Al content.展开更多
Traditional distributed denial of service(DDoS)detection methods need a lot of computing resource,and many of them which are based on single element have high missing rate and false alarm rate.In order to solve the pr...Traditional distributed denial of service(DDoS)detection methods need a lot of computing resource,and many of them which are based on single element have high missing rate and false alarm rate.In order to solve the problems,this paper proposes a DDoS attack information fusion method based on CNN for multi-element data.Firstly,according to the distribution,concentration and high traffic abruptness of DDoS attacks,this paper defines six features which are respectively obtained from the elements of source IP address,destination IP address,source port,destination port,packet size and the number of IP packets.Then,we propose feature weight calculation algorithm based on principal component analysis to measure the importance of different features in different network environment.The algorithm of weighted multi-element feature fusion proposed in this paper is used to fuse different features,and obtain multi-element fusion feature(MEFF)value.Finally,the DDoS attack information fusion classification model is established by using convolutional neural network and support vector machine respectively based on the MEFF time series.Experimental results show that the information fusion method proposed can effectively fuse multi-element data,reduce the missing rate and total error rate,memory resource consumption,running time,and improve the detection rate.展开更多
A multivariate statistical analysis was performed on multi-element soil geochemical data from the Koda Hill-Bulenga gold prospects in the Wa-Lawra gold belt, northwest Ghana. The objectives of the study were to define...A multivariate statistical analysis was performed on multi-element soil geochemical data from the Koda Hill-Bulenga gold prospects in the Wa-Lawra gold belt, northwest Ghana. The objectives of the study were to define gold relationships with other trace elements to determine possible pathfinder elements for gold from the soil geochemical data. The study focused on seven elements, namely, Au, Fe, Pb, Mn, Ag, As and Cu. Factor analysis and hierarchical cluster analysis were performed on the analyzed samples. Factor analysis explained 79.093% of the total variance of the data through three factors. This had the gold factor being factor 3, having associations of copper, iron, lead and manganese and accounting for 20.903% of the total variance. From hierarchical clustering, gold was also observed to be clustering with lead, copper, arsenic and silver. There was further indication that, gold concentrations were lower than that of its associations. It can be inferred from the results that, the occurrence of gold and its associated elements can be linked to both primary dispersion from underlying rocks and secondary processes such as lateritization. This data shows that Fe and Mn strongly associated with gold, and alongside Pb, Ag, As and Cu, these elements can be used as pathfinders for gold in the area, with ferruginous zones as targets.展开更多
A factor analysis was applied to soil geochemical data to define anomalies related to buried Pb-Zn mineralization.A favorable main factor with a strong association of the elements Zn,Cu and Pb,related to mineralizatio...A factor analysis was applied to soil geochemical data to define anomalies related to buried Pb-Zn mineralization.A favorable main factor with a strong association of the elements Zn,Cu and Pb,related to mineralization,was selected for interpretation.The median+2 MAD(median absolute deviation)method of exploratory data analysis(EDA)and C-A(concentration-area)fractal modeling were then applied to the Mahalanobis distance,as defined by Zn,Cu and Pb from the factor analysis to set the thresholds for defining multi-element anomalies.As a result,the median+2 MAD method more successfully identified the Pb-Zn mineralization than the C-A fractal model.The soil anomaly identified by the median+2 MAD method on the Mahalanobis distances defined by three principal elements(Zn,Cu and Pb)rather than thirteen elements(Co,Zn,Cu,V,Mo,Ni,Cr,Mn,Pb,Ba,Sr,Zr and Ti)was the more favorable reflection of the ore body.The identified soil geochemical anomalies were compared with the in situ economic Pb-Zn ore bodies for validation.The results showed that the median+2 MAD approach is capable of mapping both strong and weak geochemical anomalies related to buried Pb-Zn mineralization,which is therefore useful at the reconnaissance drilling stage.展开更多
Multi-element analysis in historical sites is a major issue in archaeological studies;however,this approach is almost unknown among Iranian scholars.Geochemical multi-element analysis of soil is very important to eval...Multi-element analysis in historical sites is a major issue in archaeological studies;however,this approach is almost unknown among Iranian scholars.Geochemical multi-element analysis of soil is very important to evaluate anthropogenic activities.The aim of this study consists of assessing the potential usefulness of multi-elemental soil analysis,obtained by Analytical Jena atomic absorption spectrophotometer(AAS) and ICP-MS,to recognize ancient anthropogenic features on the territory of Tappe Rivi(North Khorasan,Iran).For that purpose,a total of 80 ancient soil samples were sampled from each soil horizon and cultural layer.The research involved Fe,Al,Cd,Cu,Ni,Co,Cr,Pb,and P which trace element samples were extracted according to the International Standard ISO 11466 and phosphorus samples by Olsen method.Besides,the contamination of the soils was assessed based on enrichment factors(EFs) by using Fe as a reference element.This geochemical/archaeological approach highlights that the content of most elements in the Parthian and Sassanid ages were significantly higher than the contents of the elements in other zones,which shows that by the development of the eras,the content of the elements has also increased.Also,the accumulation of metals in the Rivi site was significantly higher than in the control area.Among the sampled zones,enrichment factor(EF) indicated that the enrichment of Cu and phosphate at the Parthian and Sassanid had the highest content.This result is important because it shows that the amount of metals and human activities are directly related to each other during different ages.展开更多
Winter jujube(Ziziphus jujuba'Dongzao')is greatly appreciated by consumers for its excellent quality,but brand infringement frequently occurs in the market.Here,we first determined a total of 38 elements in 16...Winter jujube(Ziziphus jujuba'Dongzao')is greatly appreciated by consumers for its excellent quality,but brand infringement frequently occurs in the market.Here,we first determined a total of 38 elements in 167 winter jujube samples from the main winter jujube producing areas of China by inductively coupled plasma mass spectrometer(ICP-MS).As a result,16 elements(Mg,K,Mn,Cu,Zn,Mo,Ba,Be,As,Se,Cd,Sb,Ce,Er,Tl,and Pb)exhibited significant differences in samples from different producing areas.Supervised linear discriminant analysis(LDA)and orthogonal projection to latent structures discriminant analysis(OPLS-DA)showed better performance in identifying the origin of samples than unsupervised principal component analysis(PCA).LDA and OPLS-DA had a mean identification accuracy of 87.84 and 94.64%in the testing set,respectively.By using the multilayer perceptron(MLP)and C5.0,the prediction accuracy of the models could reach 96.36 and 91.06%,respectively.Based on the above four chemometric methods,Cd,Tl,Mo and Se were selected as the main variables and principal markers for the origin identification of winter jujube.Overall,this study demonstrates that it is practical and precise to identify the origin of winter jujube through multi-element fingerprint analysis with chemometrics,and may also provide reference for establishing the origin traceability system of other fruits.展开更多
A hybrid Cartesian grid/gridless method is developed for calculating viscous flows over multi-element airfoils.The method adopts an unstructured Cartesian grid to cover most areas of the computational domain and leave...A hybrid Cartesian grid/gridless method is developed for calculating viscous flows over multi-element airfoils.The method adopts an unstructured Cartesian grid to cover most areas of the computational domain and leaves only small region adjacent to the aerodynamic bodies to be filled with the cloud of points used in the gridless methods,which results in a better combination of the computational efficiency of the Cartesian grid and the flexibility of the gridless method in handling complex geometries.The clouds of points in the local gridless region are implemented in an anisotropic way according to the features of the thin boundary layer of the viscous flows over the airfoils,and the clouds of points at the vicinity of the interface between the grid and the gridless regions are also controlled by using an adaptive refinement technique during the generation of the unstructured Cartesian grid.An implementation of the resulting hybrid method is presented for solving two-dimensional compressible Navier-Stokes(NS)equations.The simulations of the viscous flows over a RAE2822airfoil or a two-element airfoil are successfully carried out,and the obtained results agree well with the available experimental data.展开更多
A set of serf-developed apparatus for foundation physical model were utilized to conduct model tests of the multi-element composite foundation with a steel pipe pile and several gravel piles. Some load-bearing charact...A set of serf-developed apparatus for foundation physical model were utilized to conduct model tests of the multi-element composite foundation with a steel pipe pile and several gravel piles. Some load-bearing characteristics of the multi-element Composite foundation, including the curves of foundation settlement, stresses of piles, pile-soil stress ratio, and load-sharing ratio of piles and soil, were obtained to study its working performances in silty sand soil. The experimental results revealed that the multi-element composite foundation with steel pipe pile and gravel pile contributed more than the gravel pile composite foundation in improving the bearing capacity of the silty fine sand.展开更多
High-entropy alloys(HEAs)have emerged as promising catalysts for the hydrogen evolution reaction(HER)due to their compositional diversity and synergistic effects.In this study,machine learning-accelerated density func...High-entropy alloys(HEAs)have emerged as promising catalysts for the hydrogen evolution reaction(HER)due to their compositional diversity and synergistic effects.In this study,machine learning-accelerated density functional theory(DFT)calculations were employed to assess the catalytic performance of PtPd-based HEAs with the formula PtPdXYZ(X,Y,Z=Fe,Co,Ni,Cu,Ru,Rh,Ag,Au;X≠Y≠Z).Among 56 screened HEA(111)surfaces,PtPdRuCoNi(111)was identified as the most promising,with adsorption energies(E_(ads))between−0.50 and−0.60 eV and high d-band center of−1.85 eV,indicating enhanced activity.This surface showed the hydrogen adsorption free energy(ΔG_(H^(*)))of−0.03 eV for hydrogen adsorption,outperforming Pt(111)by achieving a better balance between adsorption and desorption.Machine learning models,particularly extreme gradient boosting regression(XGBR),significantly reduced computational costs while maintaining high accuracy(root-mean-square error,RMSE=0.128 eV).These results demonstrate the potential of HEAs for efficient and sustainable hydrogen production.展开更多
Electrochemical CO_(2) reduction(CO_(2)RR)to value-added fuels and chemicals offers a promising route toward carbon neutrality.However,developing efficient and selective catalysts for the generation of multi-carbon(C_...Electrochemical CO_(2) reduction(CO_(2)RR)to value-added fuels and chemicals offers a promising route toward carbon neutrality.However,developing efficient and selective catalysts for the generation of multi-carbon(C_(2+))products remains a significant challenge.In this work,we propose a combined density functional theory(DFT)and machine learning(ML)approach to systematically screen CuSb-based catalysts with varying surface Sb atomic fractions and non-metal dopants(O,N,S,Se,and P)on the Cu_(2)Sb(100)surface for CO_(2)RR.Approximately 200 representative adsorption configurations were randomly selected for DFT calculations,which were then used to train a predictive ML model.This model enables high-accuracy predictions of the adsorption energies of key intermediates(*CO and*H)for the remaining uncalculated configurations.By integrating the K-means clustering analysis and the optimal adsorption energy selection criteria based on the Sabatier principle,the candidate configuration with the best potential for C_(2+)product formation was identified:O-doped CuSb with a surface Sb atomic fraction of 3/12.Mechanistic studies further reveal that O doping significantly strengthens *CO adsorption while suppressing *H adsorption by modulating the electronic structure,thereby lowering the CO_(2)RR energy barrier and improving the thermodynamic selectivity toward C_(2+)products.This work not only elucidates the synergistic effect of surface Sb atomic fraction and non-metal dopants on CO_(2)RR activity,but also establishes a scalable ML prediction and screening framework,providing theoretical support and methodological pathways for the design of high-performance CuSb-based catalysts.展开更多
Recently, as the oceanic activities are more and more frequently carried out, marine oil spill accidents bring to enormous harm to the economy and society in China, especially in the Offshore China. Marine oil spill i...Recently, as the oceanic activities are more and more frequently carried out, marine oil spill accidents bring to enormous harm to the economy and society in China, especially in the Offshore China. Marine oil spill is one kind of serious disasters which severely damages the marine environment. Aiming at the improvement of the emergency response system and response ability for the oil spill, the relative technologies on oil spill response are developed. This paper briefly introduces the developments and achievements of the oil spill numerical models, including the oil spill spreading model, the oil spill transport model, the oil particle model as well as the oil spill weathering model, which provide the theoretic criterions for the future work on the oil spill predicting and response.展开更多
A method was developed for content determination of Na, Mg, A1, Si, P,S, C1, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Nb, Zr, Y, Sr, Rb, Ba, La and Ce etc. covering 26 major, minor, and trace elements in marine sedim...A method was developed for content determination of Na, Mg, A1, Si, P,S, C1, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Nb, Zr, Y, Sr, Rb, Ba, La and Ce etc. covering 26 major, minor, and trace elements in marine sediment samples using fused glass disc by X-ray Fluorescence spectrometry. Calibration was made using marine sediment certified reference materials and the synthetic standard samples prepared by mixing several marine sediments with stream sediment and carbonate standard samples in different proportions. The matrix effect was corrected using theoretical alpha coefficients, experience coefficients and the scattered radiation as the internal standard （for the trace elements）. The accuracy of the method was evaluated by analysis of certified reference materials GBW07314, GBW07334 and GSMS6. The results are in good agreement with the certified values of the standards with RSD less than 2.60%, except for Y, Cr, Ga, Ce, La, Nb, Rb, and V with RSD less than 9.0% （n=12）.展开更多
Discrete element model was developed to simulate the ellipsoidal particles moving in the moving bed. Multi-element model was used to describe a ellipsoidal particle, the contact detection algorithm of ellipsoidal part...Discrete element model was developed to simulate the ellipsoidal particles moving in the moving bed. Multi-element model was used to describe a ellipsoidal particle, the contact detection algorithm of ellipsoidal particle was developed, and both contact force and gravity force were considered in the models. The simulation results were validated by our experiment. Three algorithms for representing an ellipsoidal particle were compared in macro and micro aspects. The results show that there exists big difference in the microscopic parameters such as kinetic energy, rotational kinetic energy, deformation, contact force and collision number which leads to the difference of macroscopic parameters. The relative error in the discharge rate and tracer particle position is the largest between 3-tangent-element representation and experimental results. The flow pattern is similar for the 5-element and 3-intersection representations. The only difference is the discharge rate of 5-element representation is larger than the experimental value and that of the 3-intersection representation has the contrary result. Finally the 3-intersection- element reoresentation is chosen in the simulation due to less comouting time than that of the 5-element renresentation.展开更多
McDonnell Douglas Aerospace(MDA)high-lift model is widely used in the study of multi-element airfoil,while there is still short knowledge of ice accretion and water impingement on it.In this paper,based on two-phase f...McDonnell Douglas Aerospace(MDA)high-lift model is widely used in the study of multi-element airfoil,while there is still short knowledge of ice accretion and water impingement on it.In this paper,based on two-phase flow theory,two numerical models were presented by using both Eulerian approach and Lagrangian approach,respectively,in order to predict the water impingement efficiency on a two-dimensional(2D)multi-element high-lift airfoil.Both computational results were validated with the experiment data,which shown good agreements in the impingement limitations and tendency.The trend that how the attack angle and droplet diameter affect the feather of local water impingement characteristics on the different elements of MDA were further investigated.As shown in this research,the trends that the local impingement intensity and extent on flap of MDA varied differently as in general understanding due to the complex structures of flow field,which should be careful cognized in design of the ice protection system.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.12372351).
文摘In this study, to meet the development and application requirements for high-strength and hightoughness energetic structural materials, a representative volume element of a TA15 matrix embedded with a TaZrNb sphere was designed and fabricated via diffusion bonding. The mechanisms of the microstructural evolution of the TaZrNb/TA15 interface were investigated via SEM, EBSD, EDS, and XRD.Interface mechanical property tests and in-situ tensile tests were conducted on the sphere-containing structure, and an equivalent tensile-strength model was established for the structure. The results revealed that the TA15 titanium alloy and joint had high density and no pores or cracks. The thickness of the planar joint was approximately 50-60 μm. The average tensile and shear strengths were 767 MPa and 608 MPa, respectively. The thickness of the spherical joint was approximately 60 μm. The Zr and Nb elements in the joint diffused uniformly and formed strong bonds with Ti without forming intermetallic compounds. The interface exhibited submicron grain refinement and a concave-convex interlocking structure. The tensile fracture surface primarily exhibited intergranular fracture combined with some transgranular fracture, which constituted a quasi-brittle fracture mode. The shear fracture surface exhibited brittle fracture with regular arrangements of furrows. Internal fracture occurred along the spherical interface, as revealed by advanced in-situ X-ray microcomputed tomography. The experimental results agreed well with the theoretical predictions, indicating that the high-strength interface contributes to the overall strength and toughness of the sphere-containing structure.
文摘For a complex flow about multi-element airfoils a mixed grid method is set up. C-type grids are produced on each element′s body and in their wakes at first, O-type grids are given in the outmost area, and H-type grids are used in middle additional areas. An algebra method is used to produce the initial grids in each area. And the girds are optimized by elliptical differential equation method. Then C-O-H zonal patched grids around multi-element airfoils are produced automatically and efficiently. A time accurate finite-volume integration method is used to solve the compressible laminar and turbulent Navier-Stokes (N-S) equations on the grids. Computational results prove the method to be effective.
基金supported by the National Key Project of China(No.GJXM92579)National Natural Science Foundation of China(Nos.92052203,11872230 and 91852108)。
文摘Almost half of all flight accidents caused by inflight icing occur at the approach and landing phases when high-lift devices are deployed.The present study focuses on the optimization of an ice-tolerant multi-element airfoil.Dual-objective optimization is carried out with critical hornshaped ice accumulated during the holding phase.The optimization results show that the present optimization method significantly enhances the iced-state and clean-state performance.The optimal multi-element airfoil has a larger deflection angle and wider gap at the slat and the flap compared with the baseline configuration.The sensitivity of each design parameter is analyzed,which verifies the robustness of the design.The design is further assessed when ice is accreted during the approach and landing phases,which also shows performance improvement.
基金This work was supported by the State Key Lab of Intense Pulsed Radiation Simulation and Effect Basic Research Foundation(No.SKLIPR1504).
文摘To study the effects of the gamma reflection of multi-element materials,gamma ray transport models of single-element materials,such as iron and lead,and multielement materials,such as polyethylene and ordinary concrete,were established in this study.Relationships among the albedo factors of the gamma photons and energies and average energy of the reflected gamma rays by material type,material thickness,incident gamma energy,and incidence angle of gamma rays were obtained by Monte Carlo simulation.The results show that the albedo factors of single-element and multi-element materials increase rapidly with an increase in the material thickness.When the thickness of the material increases to a certain value,the albedo factors do not increase further but rather tend to the saturation value.The saturation values for the albedo factors of the gamma photons,and energies and the reflection thickness are related not only to the type of material but also to the incident gamma energy and incidence angle of the gamma rays.At a given incident gamma energy,which is between 0.2 and 2.5 MeV,the smaller the effective atomic number of the multi-element material is,the higher the saturation values of the albedo factors are.The larger the incidence angle of the gamma ray is,the greater the saturation value of the gamma albedo factor,saturation reflection thickness,and average saturation energy of the reflected gamma photons are.
文摘The paper is to integrate aerodynamic and aero-acoustic optimizatiom design of high lift devices,especially for two-element airfoils with slat.Aerodynamic analysis on flow field utilizes a high-order,high-resolution spatial differential method for large eddy simulation(LES),which can guarantee accuracy and efficiency.The aeroacoustic analysis for noise level is calculated with Ffowcs Williams-Hawkings(FW-H)integration formula.Fidelity of calculation is verified by standard models.Method of streamline-based Euler simulation(MSES)is used to obtain the aerodynamic characters.Based on the confirmation of numerical methods,detailed research has been conducted for the leading edge slat on multi-element airfoils.Various slot parameter influences on noise are analyzed.The results of the slot optimization parameters can be used in multi-element airfoil design.
基金Projects(51671217,51604112) supported by the National Natural Science Foundation of ChinaProject(2017JJ3089) supported by the Natural Science Foundation of Hunan Province,China
文摘The effects of Al and Sc on mechanical properties of FeCoNi multi-element alloys(MEAs) were investigated by compressive tests. The microstructures of FeCoNi MEAs with different contents of Al and Sc were characterized and the strengthening mechanisms were discussed. The results show that FeCoNi MEA with a low content of Al has a face-centered cubic(FCC) structure. The yield strength increases linearly with the increase of Al content, which is largely caused by solid solution hardening. Further addition of Sc can promote the formation of a new phase in(FeCoNi)1-xAlx MEAs. A minor addition of Sc can significantly increase the yield strengths of(FeCoNi)1-xAlx MEAs with a low Al content and improve the compressive plasticity of(FeCoNi)1-xAlx MEAs with a high Al content.
基金This work was supported by the Hainan Provincial Natural Science Foundation of China[2018CXTD333,617048]National Natural Science Foundation of China[61762033,61702539]+1 种基金Hainan University Doctor Start Fund Project[kyqd1328]Hainan University Youth Fund Project[qnjj1444].
文摘Traditional distributed denial of service(DDoS)detection methods need a lot of computing resource,and many of them which are based on single element have high missing rate and false alarm rate.In order to solve the problems,this paper proposes a DDoS attack information fusion method based on CNN for multi-element data.Firstly,according to the distribution,concentration and high traffic abruptness of DDoS attacks,this paper defines six features which are respectively obtained from the elements of source IP address,destination IP address,source port,destination port,packet size and the number of IP packets.Then,we propose feature weight calculation algorithm based on principal component analysis to measure the importance of different features in different network environment.The algorithm of weighted multi-element feature fusion proposed in this paper is used to fuse different features,and obtain multi-element fusion feature(MEFF)value.Finally,the DDoS attack information fusion classification model is established by using convolutional neural network and support vector machine respectively based on the MEFF time series.Experimental results show that the information fusion method proposed can effectively fuse multi-element data,reduce the missing rate and total error rate,memory resource consumption,running time,and improve the detection rate.
文摘A multivariate statistical analysis was performed on multi-element soil geochemical data from the Koda Hill-Bulenga gold prospects in the Wa-Lawra gold belt, northwest Ghana. The objectives of the study were to define gold relationships with other trace elements to determine possible pathfinder elements for gold from the soil geochemical data. The study focused on seven elements, namely, Au, Fe, Pb, Mn, Ag, As and Cu. Factor analysis and hierarchical cluster analysis were performed on the analyzed samples. Factor analysis explained 79.093% of the total variance of the data through three factors. This had the gold factor being factor 3, having associations of copper, iron, lead and manganese and accounting for 20.903% of the total variance. From hierarchical clustering, gold was also observed to be clustering with lead, copper, arsenic and silver. There was further indication that, gold concentrations were lower than that of its associations. It can be inferred from the results that, the occurrence of gold and its associated elements can be linked to both primary dispersion from underlying rocks and secondary processes such as lateritization. This data shows that Fe and Mn strongly associated with gold, and alongside Pb, Ag, As and Cu, these elements can be used as pathfinders for gold in the area, with ferruginous zones as targets.
文摘A factor analysis was applied to soil geochemical data to define anomalies related to buried Pb-Zn mineralization.A favorable main factor with a strong association of the elements Zn,Cu and Pb,related to mineralization,was selected for interpretation.The median+2 MAD(median absolute deviation)method of exploratory data analysis(EDA)and C-A(concentration-area)fractal modeling were then applied to the Mahalanobis distance,as defined by Zn,Cu and Pb from the factor analysis to set the thresholds for defining multi-element anomalies.As a result,the median+2 MAD method more successfully identified the Pb-Zn mineralization than the C-A fractal model.The soil anomaly identified by the median+2 MAD method on the Mahalanobis distances defined by three principal elements(Zn,Cu and Pb)rather than thirteen elements(Co,Zn,Cu,V,Mo,Ni,Cr,Mn,Pb,Ba,Sr,Zr and Ti)was the more favorable reflection of the ore body.The identified soil geochemical anomalies were compared with the in situ economic Pb-Zn ore bodies for validation.The results showed that the median+2 MAD approach is capable of mapping both strong and weak geochemical anomalies related to buried Pb-Zn mineralization,which is therefore useful at the reconnaissance drilling stage.
文摘Multi-element analysis in historical sites is a major issue in archaeological studies;however,this approach is almost unknown among Iranian scholars.Geochemical multi-element analysis of soil is very important to evaluate anthropogenic activities.The aim of this study consists of assessing the potential usefulness of multi-elemental soil analysis,obtained by Analytical Jena atomic absorption spectrophotometer(AAS) and ICP-MS,to recognize ancient anthropogenic features on the territory of Tappe Rivi(North Khorasan,Iran).For that purpose,a total of 80 ancient soil samples were sampled from each soil horizon and cultural layer.The research involved Fe,Al,Cd,Cu,Ni,Co,Cr,Pb,and P which trace element samples were extracted according to the International Standard ISO 11466 and phosphorus samples by Olsen method.Besides,the contamination of the soils was assessed based on enrichment factors(EFs) by using Fe as a reference element.This geochemical/archaeological approach highlights that the content of most elements in the Parthian and Sassanid ages were significantly higher than the contents of the elements in other zones,which shows that by the development of the eras,the content of the elements has also increased.Also,the accumulation of metals in the Rivi site was significantly higher than in the control area.Among the sampled zones,enrichment factor(EF) indicated that the enrichment of Cu and phosphate at the Parthian and Sassanid had the highest content.This result is important because it shows that the amount of metals and human activities are directly related to each other during different ages.
基金This work was supported by the Scientific Research Foundation for High Level Talents of Qingdao Agricultural University,China(665-1120015)the National Program for Quality and Safety Risk Assessment of Agricultural Products of China(GJFP2019011)the National Natural Science Foundation of China(42207017).
文摘Winter jujube(Ziziphus jujuba'Dongzao')is greatly appreciated by consumers for its excellent quality,but brand infringement frequently occurs in the market.Here,we first determined a total of 38 elements in 167 winter jujube samples from the main winter jujube producing areas of China by inductively coupled plasma mass spectrometer(ICP-MS).As a result,16 elements(Mg,K,Mn,Cu,Zn,Mo,Ba,Be,As,Se,Cd,Sb,Ce,Er,Tl,and Pb)exhibited significant differences in samples from different producing areas.Supervised linear discriminant analysis(LDA)and orthogonal projection to latent structures discriminant analysis(OPLS-DA)showed better performance in identifying the origin of samples than unsupervised principal component analysis(PCA).LDA and OPLS-DA had a mean identification accuracy of 87.84 and 94.64%in the testing set,respectively.By using the multilayer perceptron(MLP)and C5.0,the prediction accuracy of the models could reach 96.36 and 91.06%,respectively.Based on the above four chemometric methods,Cd,Tl,Mo and Se were selected as the main variables and principal markers for the origin identification of winter jujube.Overall,this study demonstrates that it is practical and precise to identify the origin of winter jujube through multi-element fingerprint analysis with chemometrics,and may also provide reference for establishing the origin traceability system of other fruits.
基金Supported by the National Natural Science Foundation of China(11172134)the Funding of Jiangsu Innovation Program for Graduate Education(CXZZ110192)the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘A hybrid Cartesian grid/gridless method is developed for calculating viscous flows over multi-element airfoils.The method adopts an unstructured Cartesian grid to cover most areas of the computational domain and leaves only small region adjacent to the aerodynamic bodies to be filled with the cloud of points used in the gridless methods,which results in a better combination of the computational efficiency of the Cartesian grid and the flexibility of the gridless method in handling complex geometries.The clouds of points in the local gridless region are implemented in an anisotropic way according to the features of the thin boundary layer of the viscous flows over the airfoils,and the clouds of points at the vicinity of the interface between the grid and the gridless regions are also controlled by using an adaptive refinement technique during the generation of the unstructured Cartesian grid.An implementation of the resulting hybrid method is presented for solving two-dimensional compressible Navier-Stokes(NS)equations.The simulations of the viscous flows over a RAE2822airfoil or a two-element airfoil are successfully carried out,and the obtained results agree well with the available experimental data.
基金The National Natural Science Foundation of China (No.50478090)
文摘A set of serf-developed apparatus for foundation physical model were utilized to conduct model tests of the multi-element composite foundation with a steel pipe pile and several gravel piles. Some load-bearing characteristics of the multi-element Composite foundation, including the curves of foundation settlement, stresses of piles, pile-soil stress ratio, and load-sharing ratio of piles and soil, were obtained to study its working performances in silty sand soil. The experimental results revealed that the multi-element composite foundation with steel pipe pile and gravel pile contributed more than the gravel pile composite foundation in improving the bearing capacity of the silty fine sand.
基金the Second Century Fund(C2F),Chulalongkorn UniversityThailand Science Research and Innovation Fund Chulalongkorn University(No.IND_FF_68_054_2100_009)National Science and Technology Development Agency,Thailand,Hub of Knowledge funding,and the Mid-Career Research Grant 2024,National Research Council of Thailand(No.N42A670295).
文摘High-entropy alloys(HEAs)have emerged as promising catalysts for the hydrogen evolution reaction(HER)due to their compositional diversity and synergistic effects.In this study,machine learning-accelerated density functional theory(DFT)calculations were employed to assess the catalytic performance of PtPd-based HEAs with the formula PtPdXYZ(X,Y,Z=Fe,Co,Ni,Cu,Ru,Rh,Ag,Au;X≠Y≠Z).Among 56 screened HEA(111)surfaces,PtPdRuCoNi(111)was identified as the most promising,with adsorption energies(E_(ads))between−0.50 and−0.60 eV and high d-band center of−1.85 eV,indicating enhanced activity.This surface showed the hydrogen adsorption free energy(ΔG_(H^(*)))of−0.03 eV for hydrogen adsorption,outperforming Pt(111)by achieving a better balance between adsorption and desorption.Machine learning models,particularly extreme gradient boosting regression(XGBR),significantly reduced computational costs while maintaining high accuracy(root-mean-square error,RMSE=0.128 eV).These results demonstrate the potential of HEAs for efficient and sustainable hydrogen production.
基金supported by the National Natural Science Foundation of China(No.No.52394202,No.52476056)State Key Laboratory of Engines,Tianjin University(K2025-10)+2 种基金the Natural Science Foundation of Chongqing(CSTB2024NSCQ-MSX0915)the China Postdoctoral Science Foundation(No.BX20240449)the Innovative Research Group Project of the National Natural Science Foundation of China(No.52021004).
文摘Electrochemical CO_(2) reduction(CO_(2)RR)to value-added fuels and chemicals offers a promising route toward carbon neutrality.However,developing efficient and selective catalysts for the generation of multi-carbon(C_(2+))products remains a significant challenge.In this work,we propose a combined density functional theory(DFT)and machine learning(ML)approach to systematically screen CuSb-based catalysts with varying surface Sb atomic fractions and non-metal dopants(O,N,S,Se,and P)on the Cu_(2)Sb(100)surface for CO_(2)RR.Approximately 200 representative adsorption configurations were randomly selected for DFT calculations,which were then used to train a predictive ML model.This model enables high-accuracy predictions of the adsorption energies of key intermediates(*CO and*H)for the remaining uncalculated configurations.By integrating the K-means clustering analysis and the optimal adsorption energy selection criteria based on the Sabatier principle,the candidate configuration with the best potential for C_(2+)product formation was identified:O-doped CuSb with a surface Sb atomic fraction of 3/12.Mechanistic studies further reveal that O doping significantly strengthens *CO adsorption while suppressing *H adsorption by modulating the electronic structure,thereby lowering the CO_(2)RR energy barrier and improving the thermodynamic selectivity toward C_(2+)products.This work not only elucidates the synergistic effect of surface Sb atomic fraction and non-metal dopants on CO_(2)RR activity,but also establishes a scalable ML prediction and screening framework,providing theoretical support and methodological pathways for the design of high-performance CuSb-based catalysts.
文摘Recently, as the oceanic activities are more and more frequently carried out, marine oil spill accidents bring to enormous harm to the economy and society in China, especially in the Offshore China. Marine oil spill is one kind of serious disasters which severely damages the marine environment. Aiming at the improvement of the emergency response system and response ability for the oil spill, the relative technologies on oil spill response are developed. This paper briefly introduces the developments and achievements of the oil spill numerical models, including the oil spill spreading model, the oil spill transport model, the oil particle model as well as the oil spill weathering model, which provide the theoretic criterions for the future work on the oil spill predicting and response.
基金Supported by China Ministry of Science and Technology (2000DEB20081)China Ocean Mineral Resources R&D Association (COMRA) (No.DY105-05-01-05)+1 种基金China Ministry of Education(No.205089)China National Natural Science Foundation (No.40076015)
文摘A method was developed for content determination of Na, Mg, A1, Si, P,S, C1, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Nb, Zr, Y, Sr, Rb, Ba, La and Ce etc. covering 26 major, minor, and trace elements in marine sediment samples using fused glass disc by X-ray Fluorescence spectrometry. Calibration was made using marine sediment certified reference materials and the synthetic standard samples prepared by mixing several marine sediments with stream sediment and carbonate standard samples in different proportions. The matrix effect was corrected using theoretical alpha coefficients, experience coefficients and the scattered radiation as the internal standard （for the trace elements）. The accuracy of the method was evaluated by analysis of certified reference materials GBW07314, GBW07334 and GSMS6. The results are in good agreement with the certified values of the standards with RSD less than 2.60%, except for Y, Cr, Ga, Ce, La, Nb, Rb, and V with RSD less than 9.0% （n=12）.
基金Supported by the Major State Basic Research Development Program of China （2011CB201505）, the National Natural Science Foundation of China （50976025） and the Key Proj ect.of Science and Technology of Henan Province （12B610012）.
文摘Discrete element model was developed to simulate the ellipsoidal particles moving in the moving bed. Multi-element model was used to describe a ellipsoidal particle, the contact detection algorithm of ellipsoidal particle was developed, and both contact force and gravity force were considered in the models. The simulation results were validated by our experiment. Three algorithms for representing an ellipsoidal particle were compared in macro and micro aspects. The results show that there exists big difference in the microscopic parameters such as kinetic energy, rotational kinetic energy, deformation, contact force and collision number which leads to the difference of macroscopic parameters. The relative error in the discharge rate and tracer particle position is the largest between 3-tangent-element representation and experimental results. The flow pattern is similar for the 5-element and 3-intersection representations. The only difference is the discharge rate of 5-element representation is larger than the experimental value and that of the 3-intersection representation has the contrary result. Finally the 3-intersection- element reoresentation is chosen in the simulation due to less comouting time than that of the 5-element renresentation.
基金Many thanks to Prof.Tom Shih at Purdue University for providing guidance in grid generation and flow field simulation and the financial support from The Fundamental Research Funds for the Central Universities at Beihang University,number:YWF-14-JTXY-009.
文摘McDonnell Douglas Aerospace(MDA)high-lift model is widely used in the study of multi-element airfoil,while there is still short knowledge of ice accretion and water impingement on it.In this paper,based on two-phase flow theory,two numerical models were presented by using both Eulerian approach and Lagrangian approach,respectively,in order to predict the water impingement efficiency on a two-dimensional(2D)multi-element high-lift airfoil.Both computational results were validated with the experiment data,which shown good agreements in the impingement limitations and tendency.The trend that how the attack angle and droplet diameter affect the feather of local water impingement characteristics on the different elements of MDA were further investigated.As shown in this research,the trends that the local impingement intensity and extent on flap of MDA varied differently as in general understanding due to the complex structures of flow field,which should be careful cognized in design of the ice protection system.
