As hundreds of millions of distributed devices appear in every corner of our lives for information collection and transmission in big data era,the biggest challenge is the energy supply for these devices and the signa...As hundreds of millions of distributed devices appear in every corner of our lives for information collection and transmission in big data era,the biggest challenge is the energy supply for these devices and the signal transmission of sensors.Triboelectric nanogenerator(TENG)as a new energy technology meets the increasing demand of today’s distributed energy supply due to its ability to convert the ambient mechanical energy into electric energy.Meanwhile,TENG can also be used as a sensing system.Direct current triboelectric nanogenerator(DC-TENG)can directly supply power to electronic devices without additional rectification.It has been one of the most important developments of TENG in recent years.Herein,we review recent progress in the novel structure designs,working mechanism and corresponding method to improve the output performance for DC-TENGs from the aspect of mechanical rectifier,tribovoltaic effect,phase control,mechanical delay switch and air-discharge.The basic theory of each mode,key merits and potential development are discussed in detail.At last,we provide a guideline for future challenges of DC-TENGs,and a strategy for improving the output performance for commercial applications.展开更多
Based on the discussion about working mechanism of horizontal reinforcement and that of vertical reinforcement,respectively,the working mechanism of two-direction reinforced composite foundation was studied.The enhanc...Based on the discussion about working mechanism of horizontal reinforcement and that of vertical reinforcement,respectively,the working mechanism of two-direction reinforced composite foundation was studied.The enhancing effect of horizontal reinforcement on vertical reinforced composite foundation was analyzed.A simplified calculation method for such two-direction reinforced working system was presented.A model experiment was carried out to validate the proposed method.In the experiment,geocell reinforcement worked as the horizontal reinforcement,while gravel pile composite foundation worked as the vertical reinforcement.The results show that the calculated curve is close to the measured one.The installation of geosynthetic reinforcement can increase the bearing capacity of composite foundation by nearly 68% at normal foundation settlement,which suggests that the enhancing effect by geosynthetic reinforcement should be taken into account in current design/analysis methods.展开更多
For Gu-Ag alloy, an important parameter called workability in the forming process of materials can be evaluated by processing maps yielded from the stress-strain data generated by hot compression tests at temperatures...For Gu-Ag alloy, an important parameter called workability in the forming process of materials can be evaluated by processing maps yielded from the stress-strain data generated by hot compression tests at temperatures of 700-850 °C and strain rates of 0.01-10 s-1. And at the true strain of 0.15, 0.35 and 0.55, respectively, the responses of strain-rate sensitivity, power dissipation efficiency and instability parameter to temperature and strain rate were studied. Instability maps and power dissipation maps were superimposed to form processing maps, which reveal the determinate regions where individual metallurgical processes occur and the limiting conditions of flow instability regions. Furthermore, the optimal processing parameters for bulk metal working are identified clearly by the processing maps.展开更多
In this work, the Mg–5Al–2Ca alloy was extruded at 573, 623 and 673 K, with a ratio of 16：1 and a constant speed of 3 mm/s. Results demonstrate that the Al2Ca particle is formed in Mg–5Al–2Ca alloy. The size, amo...In this work, the Mg–5Al–2Ca alloy was extruded at 573, 623 and 673 K, with a ratio of 16：1 and a constant speed of 3 mm/s. Results demonstrate that the Al2Ca particle is formed in Mg–5Al–2Ca alloy. The size, amount and distribution of Al2Ca particles are influenced evidently by extrusion temperature. Unlike previous reports, the intensity of basal texture increases with increasing extrusion temperature, and the reasons are analyzed and given. Even though the average grain size increases as the extrusion temperature increased from 573 to 623 K, the YS, UTS and elongation of asextruded Mg–5Al–2Ca alloy are almost kept the same at 573 and 623 K. The reason is speculated as the balance of grain size, Al2Ca phase and texture at the two temperatures. The work hardening rate depends on extrusion temperature, and the largest θ value of Mg–5Al–2Ca alloy is obtained when the extrusion was performed at 623 K.展开更多
The article introduced the key technology, mining process, and back-and-forth mining method for the caving working face of hard-thick coal seams in Datong mine, and researched this innovations process, optimized the s...The article introduced the key technology, mining process, and back-and-forth mining method for the caving working face of hard-thick coal seams in Datong mine, and researched this innovations process, optimized the systemic design and working face out-play, tried to perfect the caving mining technology of hard-thick coal seams further.展开更多
Working memory（WM）allows humans to hold necessary information in temporary storage and manipulate such information online for higher-order cognitive functions,such as language understanding,decision making,and probl...Working memory（WM）allows humans to hold necessary information in temporary storage and manipulate such information online for higher-order cognitive functions,such as language understanding,decision making,and problem solving.Since its first appearance in the science of psychology in the 1960s,many theories have sought to elucidate the nature of WM.The most accepted model is展开更多
On July 22, 2014, the second group of national human rights education and train- ing bases was announced,increasing the number of national bases from the previous three to a total of eight, which reflects the advancem...On July 22, 2014, the second group of national human rights education and train- ing bases was announced,increasing the number of national bases from the previous three to a total of eight, which reflects the advancement of human rights education and ~aining in China and has far-reaching significance.展开更多
I graduated from the National Peiyang University (now called Tianjin University) in 1950, majoring in hydraulic engineering. Starting from 1952, my teaching work was basically in mechanics.My first academic probe was ...I graduated from the National Peiyang University (now called Tianjin University) in 1950, majoring in hydraulic engineering. Starting from 1952, my teaching work was basically in mechanics.My first academic probe was in cybernetics, resulting in the publication of the first Chinese paper concerning optimal control. After 1963, I worked on the theory of hydrodynamic stability. My explorative thrust is at the eigenvalues of the Orr Sommerfeld Equation,a non-self adjoint problem in展开更多
The effects of He, Ar and N2, as the working gas, on the formation of Fullerenes were studied respectively. The experimental results indicated that the different inert gases greatly affect both the productivity and t...The effects of He, Ar and N2, as the working gas, on the formation of Fullerenes were studied respectively. The experimental results indicated that the different inert gases greatly affect both the productivity and the composition of Fullerenes and for the same gas the different pressures also affect the productivity. It was also found that no Fullerenes can be obtained without a working gas. It indicates that the gas of a difinite pressure may be necessary to the formation of Fullerenes. A new possible mechanism of the Fullerenes formation was suggested.展开更多
Multifunctional photodetectors boost the development of traditional optical communication technology and emerging artificial intelligence fields, such as robotics and autonomous driving. However, the current implement...Multifunctional photodetectors boost the development of traditional optical communication technology and emerging artificial intelligence fields, such as robotics and autonomous driving. However, the current implementation of multifunctional detectors is based on the physical combination of optical lenses, gratings, and multiple photodetectors, the large size and its complex structure hinder the miniaturization, lightweight, and integration of devices. In contrast, perovskite materials have achieved remarkable progress in the field of multifunctional photodetectors due to their diverse crystal structures, simple morphology manipulation, and excellent optoelectronic properties. In this review, we first overview the crystal structures and morphology manipulation techniques of perovskite materials and then summarize the working mechanism and performance parameters of multifunctional photodetectors. Furthermore, the fabrication strategies of multifunctional perovskite photodetectors and their advancements are highlighted, including polarized light detection, spectral detection, angle-sensing detection, and selfpowered detection. Finally, the existing problems of multifunctional detectors and the perspectives of their future development are presented.展开更多
Early-stage fire-warning systems(EFWSs)have attracted significant attention owing to their superiority in detecting fire situations occurring in the pre-combustion process.Substantial progress on EFWSs has been achiev...Early-stage fire-warning systems(EFWSs)have attracted significant attention owing to their superiority in detecting fire situations occurring in the pre-combustion process.Substantial progress on EFWSs has been achieved recently,and they have presented a considerable possibility for more evacuation time to control constant unintentional fire hazards in our daily life.This review mainly makes a comprehensive summary of the current EFWSs,including the working mechanisms and their performance.According to the different working mechanisms,fire alarms can be classified into graphene oxide-based fire alarms,semiconductor-based fire alarms,thermoelectric-based fire alarms,and fire alarms on other working mechanisms.Finally,the challenge and prospect for EFWSs are briefly provided by comparing the art of state of fire alarms.This work can propose a more comprehensive understanding of EFWSs and a guideline for the cutting-edge development direction of EFWSs for readers.展开更多
In the last five years, China has seen the technological development of intelligent mining and the application of the longwall automation technology developed by the Longwall Automation Steering Committee. This paper ...In the last five years, China has seen the technological development of intelligent mining and the application of the longwall automation technology developed by the Longwall Automation Steering Committee. This paper summarizes this great achievement, which occurred during the 12th Five-Year Plan （2011-2015）, and which included the development of a set of intelligent equipment for hydraulic-powered supports, information transfers, dynamic decision-making, performance coordination, and the achievement of a high level of reliability despite difficult conditions. Within China, the intelligent system of a set of hydraulic-powered supports was completed, with our own intellectual property rights. An intelligent mining model was developed that permitted unmanned operation and single-person inspection on the work face. With these technologies, the number of miners on the work face can now be significantly reduced. Miners are only required to monitor mining machines on the roadway or at the surface control center, since intelligent mining can be applied to extract middle-thick or thick coal seams. As a result, miners＇ safety has been improved. Finally, this Darter discusses theprospects and challenges of intelligent mining over the next ten years.展开更多
In advantages of their high capacity and high operating voltage,the nickel(Ni)-rich layered transition metal oxide cathode materials(LiNi_(x)Co_(y)Mn_(z)O_(2)(NCMxyz,x+y+z=1,x≥0.5)and LiNi_(0.8)Co_(0.15)Al_(0.05)O_(2...In advantages of their high capacity and high operating voltage,the nickel(Ni)-rich layered transition metal oxide cathode materials(LiNi_(x)Co_(y)Mn_(z)O_(2)(NCMxyz,x+y+z=1,x≥0.5)and LiNi_(0.8)Co_(0.15)Al_(0.05)O_(2)(NCA))have been arousing great interests to improve the energy density of LIBs.However,these Nirich cathodes always suffer from rapid capacity degradation induced by unstable cathode-electrolyte interphase(CEI)layer and destruction of bulk crystal structure.Therefore,varied electrode/electrolyte interface engineering strategies(such as electrolyte formulation,material coating or doping)have been developed for Ni-rich cathodes protection.Among them,developing electrolyte functional additives has been proven to be a simple,effective,and economic method to improve the cycling stability of Nirich cathodes.This is achieved by removing unfavorable species(such as HF,H_(2)O)or constructing a stable and protective CEI layer against unfavorable reactive species(such as HF,H_(2)O).Herein,this review mainly introduces the varied classes of electrolyte functional additives and their working mechanism for interfacial engineering of Ni-rich cathodes.Especially,key favorable species for stabilizing CEI layer are summarized.More importantly,we put forward perspectives for screening and customizing ideal functional additives for high performance Ni-rich cathodes based LIBs.展开更多
By combing the characteristics of drilling in Antarctic region, performance requirements on drilling fluid for Antarctic low temperature conditions, and research progress of low temperature drilling fluid, current pro...By combing the characteristics of drilling in Antarctic region, performance requirements on drilling fluid for Antarctic low temperature conditions, and research progress of low temperature drilling fluid, current problems of the drilling fluid have been sorted out, and the development direction of the drilling fluid has been pointed out. Drilling in the Antarctic region mainly includes drilling in snow, ice and subglacial rock formations, and drilling in Antarctic low temperature conditions will face problems in four aspects:(1) low temperature and large temperature changes in the drilling area;(2) likely well leakage and drillstring-sticking in the snow layer, creep in the ice layer, ice chip gathering jamming in the warm ice layer, well wall collapse in the subglacial rock formations;(3) lack of infrastructure and difficulty in logistical support;(4) fragile environment and low carrying capacity. After years of development, progresses have been made on low-temperature drilling fluids for the Antarctic region. Low-temperature petroleum-based drilling fluid, ethanol/ethylene glycol-based drilling fluid, ester-based drilling fluid and silicone oil-based drilling fluid have been developed. However, these drilling fluids have problems such as insufficient low-temperature tolerance, low environmental performance and weak wellbore stability, etc. In order to meet the performance requirements of drilling fluid under low-temperature conditions in Antarctic region, the working mechanisms of low-temperature drilling fluid must be examined in depth;environment-friendly low-temperature base fluid of drilling fluid and related additives must be developed to prepare environmentally friendly low temperature drilling fluid systems;multi-functional integrated adjustment method for drilling fluid must be worked out to ensure well wall stability and improve cutting-carry capacity when drilling ice formations and ice-rock interlayers;and on-site support operation codes must be established to provide technical support for Antarctic drilling.展开更多
North and west China has abundant coal resources, however, such resources make these regions prone to serious mine fire disasters. Although the copious sand and fly ash resources found in these areas can be used as fi...North and west China has abundant coal resources, however, such resources make these regions prone to serious mine fire disasters. Although the copious sand and fly ash resources found in these areas can be used as fire-fighting materials, conventional grouting is expensive because of water shortage and loess particles. A new compound material(i.e., a sand-suspended colloid), which comprises a mineral inorganic gel and an organic polymer, is developed in the current study to improve the quality of sand injection and reduce water wastage when grouting. The new material can steadily suspend the sand, through the addition of a small amount of colloid yielding steady sand-suspended slurry. The process of producing the slurry is convenient and quick, overcoming the shortage of sand-suspending thickeners which need heat and are difficult to produce. The space work model based on the theory of the double-electric layer is established to study the suspended mechanism of the solid particles in the sand-suspended colloid.The dispersion effect of the sand-suspended colloid is demonstrated by the incorporation of the electrostatic effect by the double-electric layer and the steric hindrance effect on the sand particles, ensuring the stability of the colloid system and the steady suspension of sand particles in the sand-suspended colloid.Mechanical analysis indicates that the sand is suspended steadily under the condition that the rock sand particles stress on the lower part of the fluid is less than the yield stress of the colloid. Finally, the fireprevention technology of sand suspension was applied and tested in the Daliuta Coal Mine, achieving successful results.展开更多
The effects of deforming temperatures on the tensile behaviors of quenching and partitioning treated steels were investigated. It was found that the ultimate tensile strength of the steel decreased with the increasing...The effects of deforming temperatures on the tensile behaviors of quenching and partitioning treated steels were investigated. It was found that the ultimate tensile strength of the steel decreased with the increasing temperature from 25 to 100 ℃, reached the maximum value at 300 ℃, and then declined by a significant extent when the temperature further reached 400 ℃. The total elongations at 100, 200 and 300 ℃are at about the same level. The steel achieved optimal mechanical properties at 300 ℃due to the proper transformation behavior of retained austenite since the stability of retained austenite is largely dependent on the deforming temperature. When tested at 100 and 200 ℃, the retained aus tenite was reluctant to transform, while at the other temperatures, about 10 vol. % of retained aus- tenite transformed during the tensile tests. The relationship between the stability of retained austenite and the work hardening behavior of quenching and partitioning treated steels at different deforming temperatures was also studied and discussed in detail. In order to obtain excellent mechanical properties, the stability of retained austenite should be carefully controlled so that the effect of transforma tion-induced plasticity could take place continuously during plastic deformation.展开更多
Rechargeable aqueous Zn/MnO_(2)batteries raise massive research activities in recent years. However, both the working principle and the degradation mechanism of this battery chemistry are still under debate. Herein, w...Rechargeable aqueous Zn/MnO_(2)batteries raise massive research activities in recent years. However, both the working principle and the degradation mechanism of this battery chemistry are still under debate. Herein, we provide an in-depth electrochemical and structural investigation on this controversial issue based on α-MnO_(2)crystalline nanowires. Mechanistic analysis substantiates a two-electron reaction pathway of Mn2+/Mn4+redox couple from part of MnO_(2)accompanying with a reversible precipitation/dissolution of flaky zinc sulfate hydroxide(ZSH) during the discharge/charge processes. The formation of the ZSH layer is double-edged, which passivates the deep dissolution of MnO_(2)upon discharging,but promotes the electrochemical deposition kinetics of active MnO_(2)upon charging. The cell degradation originates primarily from the corrosion failure of metallic zinc anode and the accumulation of irreversible ZnMn2O_(4)phases on the cathode. The addition of MnSO_(4)to the electrolyte could afford supplementary capacity contribution via electro-oxidation of Mn2+. However, a high MnSO_(4)concentration will expedite the cell failure by corroding the metallic zinc anodes. The present study will shed a fundamental insight on developing new strategies toward practically viable Zn/MnO_(2)batteries.展开更多
With the emergence of some solid electrolytes(SSEs)with high ionic conductivity being comparable to liquid electrolytes,solid-state lithium-sulfur batteries(SSLSBs)have been widely regarded as one of the most promisin...With the emergence of some solid electrolytes(SSEs)with high ionic conductivity being comparable to liquid electrolytes,solid-state lithium-sulfur batteries(SSLSBs)have been widely regarded as one of the most promising candidates for the next generation of power generation energy storage batteries,and have been extensively researched.Though many fundamental and technological issues still need to be resolved to develop commercially viable technologies,SSLSBs using SSEs are expected to address the present limitations and achieve high energy and power density while improving safety,which is very attractive to large-scale energy storage systems.SSLSBs have been developed for many years.However,there are few systematic discussions related to the working mechanism of action of various electrolytes in SSLSBs and the defects and the corresponding solutions of various electrolytes.To fill this gap,it is very meaningful to review the recent progress of SSEs in SSLSBs.In this review,we comprehensively investigate and summarize the application of SSEs in LSBs to determine the differences which still exist between current progresses and real-world requirements,and comprehensively describe the mechanism of action of SSLSBs,including lithium-ion transport,interfacial contact,and catalytic conversion mechanisms.More importantly,the selection of solid electrolyte materials and the novel design of structures are reviewed and the properties of various SSEs are elucidated.Finally,the prospects and possible future research directions of SSLSBs including designing high electronic/ionic conductivity for cathodes,optimizing electrolytes and developing novel electrolytes with excellent properties,improving electrode/-electrolyte interface stability and enhancing interfacial dynamics between electrolyte and anode,using more advanced test equipment and characterization techniques to analyze conduction mechanism of Li^(+)in SSEs are presented.It is hoped that this review can arouse people’s attention and enlighten the development of functional materials and novel structures of SSEs in the next step.展开更多
Psychological health education has been highly valued by the party and the state.During the fight against the COVID-19,colleges and universities have made a beneficial exploration in carrying out psychological health ...Psychological health education has been highly valued by the party and the state.During the fight against the COVID-19,colleges and universities have made a beneficial exploration in carrying out psychological health education.In older to further understand the impact of the epidemic on the psychological health of college students,a survey was carried out based on questionnaire survey,depth interview and expert consultation.The survey found that the epidemic increased the psychological pressure and posed new challenges to the psychological health education in colleges and universities.Based on the analysis of the causes from the four aspects of society,family,college and individual,this thesis put forwards some suggestions on how to effectively carry out the psychological health education of college students in the context of fighting against the epidemic.展开更多
In order to strengthen the production efficiency and quality of underground coal mine, the application of variable frequency drive control system of scraper conveyor is analyzed. Firstly, the performance of the equipm...In order to strengthen the production efficiency and quality of underground coal mine, the application of variable frequency drive control system of scraper conveyor is analyzed. Firstly, the performance of the equipment is introduced, and the necessity of the design and application of frequency conversion drive control system is clarified, which is beneficial to strengthen the informatization and digitization of underground coal mine production. Secondly, it describes the construction of variable frequency drive control system, grasps the system structure and the selection requirements of various components. Finally analyzes the application of variable frequency drive control system, and summarizes the suggestions on optimizing the application effect of scraper conveyor, which is conducive to improving the stability and efficiency of the equipment operation, and provides modern system support for future underground coal mine production.展开更多
基金supported by The National Key R&D Project from Minister of Science and Technology(2021YFA1201602)the National Natural Science Foundation of China(U21A20147,52073037).
文摘As hundreds of millions of distributed devices appear in every corner of our lives for information collection and transmission in big data era,the biggest challenge is the energy supply for these devices and the signal transmission of sensors.Triboelectric nanogenerator(TENG)as a new energy technology meets the increasing demand of today’s distributed energy supply due to its ability to convert the ambient mechanical energy into electric energy.Meanwhile,TENG can also be used as a sensing system.Direct current triboelectric nanogenerator(DC-TENG)can directly supply power to electronic devices without additional rectification.It has been one of the most important developments of TENG in recent years.Herein,we review recent progress in the novel structure designs,working mechanism and corresponding method to improve the output performance for DC-TENGs from the aspect of mechanical rectifier,tribovoltaic effect,phase control,mechanical delay switch and air-discharge.The basic theory of each mode,key merits and potential development are discussed in detail.At last,we provide a guideline for future challenges of DC-TENGs,and a strategy for improving the output performance for commercial applications.
基金Project (2006AA11Z104) supported by the National High-Tech Research and Development Program("863" Program)
文摘Based on the discussion about working mechanism of horizontal reinforcement and that of vertical reinforcement,respectively,the working mechanism of two-direction reinforced composite foundation was studied.The enhancing effect of horizontal reinforcement on vertical reinforced composite foundation was analyzed.A simplified calculation method for such two-direction reinforced working system was presented.A model experiment was carried out to validate the proposed method.In the experiment,geocell reinforcement worked as the horizontal reinforcement,while gravel pile composite foundation worked as the vertical reinforcement.The results show that the calculated curve is close to the measured one.The installation of geosynthetic reinforcement can increase the bearing capacity of composite foundation by nearly 68% at normal foundation settlement,which suggests that the enhancing effect by geosynthetic reinforcement should be taken into account in current design/analysis methods.
基金Project(CSTC2009BA4065) supported by the Chongqing Natural Science Foundation,China
文摘For Gu-Ag alloy, an important parameter called workability in the forming process of materials can be evaluated by processing maps yielded from the stress-strain data generated by hot compression tests at temperatures of 700-850 °C and strain rates of 0.01-10 s-1. And at the true strain of 0.15, 0.35 and 0.55, respectively, the responses of strain-rate sensitivity, power dissipation efficiency and instability parameter to temperature and strain rate were studied. Instability maps and power dissipation maps were superimposed to form processing maps, which reveal the determinate regions where individual metallurgical processes occur and the limiting conditions of flow instability regions. Furthermore, the optimal processing parameters for bulk metal working are identified clearly by the processing maps.
基金financially supported by the National Natural Science Foundation of China (Nos. 51201112, 51301120 and 51401144)the Natural Science Foundation of Shanxi (No. 2013021013-3)
文摘In this work, the Mg–5Al–2Ca alloy was extruded at 573, 623 and 673 K, with a ratio of 16：1 and a constant speed of 3 mm/s. Results demonstrate that the Al2Ca particle is formed in Mg–5Al–2Ca alloy. The size, amount and distribution of Al2Ca particles are influenced evidently by extrusion temperature. Unlike previous reports, the intensity of basal texture increases with increasing extrusion temperature, and the reasons are analyzed and given. Even though the average grain size increases as the extrusion temperature increased from 573 to 623 K, the YS, UTS and elongation of asextruded Mg–5Al–2Ca alloy are almost kept the same at 573 and 623 K. The reason is speculated as the balance of grain size, Al2Ca phase and texture at the two temperatures. The work hardening rate depends on extrusion temperature, and the largest θ value of Mg–5Al–2Ca alloy is obtained when the extrusion was performed at 623 K.
基金Supported by the Production Safety and Supervision of Management Bureau of China(04-116) the Returned Overseas Scholar Fund of Educational Department of China(2003406)+1 种基金 the Soft Science Planning Program of Shandong Province(A200423-6) the National Soft Science Planed Program (2004DGQ3D090)
文摘The article introduced the key technology, mining process, and back-and-forth mining method for the caving working face of hard-thick coal seams in Datong mine, and researched this innovations process, optimized the systemic design and working face out-play, tried to perfect the caving mining technology of hard-thick coal seams further.
文摘Working memory（WM）allows humans to hold necessary information in temporary storage and manipulate such information online for higher-order cognitive functions,such as language understanding,decision making,and problem solving.Since its first appearance in the science of psychology in the 1960s,many theories have sought to elucidate the nature of WM.The most accepted model is
文摘On July 22, 2014, the second group of national human rights education and train- ing bases was announced,increasing the number of national bases from the previous three to a total of eight, which reflects the advancement of human rights education and ~aining in China and has far-reaching significance.
文摘I graduated from the National Peiyang University (now called Tianjin University) in 1950, majoring in hydraulic engineering. Starting from 1952, my teaching work was basically in mechanics.My first academic probe was in cybernetics, resulting in the publication of the first Chinese paper concerning optimal control. After 1963, I worked on the theory of hydrodynamic stability. My explorative thrust is at the eigenvalues of the Orr Sommerfeld Equation,a non-self adjoint problem in
文摘The effects of He, Ar and N2, as the working gas, on the formation of Fullerenes were studied respectively. The experimental results indicated that the different inert gases greatly affect both the productivity and the composition of Fullerenes and for the same gas the different pressures also affect the productivity. It was also found that no Fullerenes can be obtained without a working gas. It indicates that the gas of a difinite pressure may be necessary to the formation of Fullerenes. A new possible mechanism of the Fullerenes formation was suggested.
基金supported financially by the National Key R&D Program of China (Nos. 2018YFA0208501 and 2018YFA0703200)the National Natural Science Foundation of China (NSFC, Nos. 52103236, 91963212, 21875260)Beijing National Laboratory for Molecular Sciences (No. BNLMSCXXM-202005)。
文摘Multifunctional photodetectors boost the development of traditional optical communication technology and emerging artificial intelligence fields, such as robotics and autonomous driving. However, the current implementation of multifunctional detectors is based on the physical combination of optical lenses, gratings, and multiple photodetectors, the large size and its complex structure hinder the miniaturization, lightweight, and integration of devices. In contrast, perovskite materials have achieved remarkable progress in the field of multifunctional photodetectors due to their diverse crystal structures, simple morphology manipulation, and excellent optoelectronic properties. In this review, we first overview the crystal structures and morphology manipulation techniques of perovskite materials and then summarize the working mechanism and performance parameters of multifunctional photodetectors. Furthermore, the fabrication strategies of multifunctional perovskite photodetectors and their advancements are highlighted, including polarized light detection, spectral detection, angle-sensing detection, and selfpowered detection. Finally, the existing problems of multifunctional detectors and the perspectives of their future development are presented.
基金This work was partially supported by the China Scholarship Council under the Grant CSC(201908110272)BIOFIRESAFE Project funded by Ministerio De Ciencia E Innovacion,Spain,with the project numbers:PID2020-117274RB-I00BIOFIRESAFE and PEJ-2018 MINECO.
文摘Early-stage fire-warning systems(EFWSs)have attracted significant attention owing to their superiority in detecting fire situations occurring in the pre-combustion process.Substantial progress on EFWSs has been achieved recently,and they have presented a considerable possibility for more evacuation time to control constant unintentional fire hazards in our daily life.This review mainly makes a comprehensive summary of the current EFWSs,including the working mechanisms and their performance.According to the different working mechanisms,fire alarms can be classified into graphene oxide-based fire alarms,semiconductor-based fire alarms,thermoelectric-based fire alarms,and fire alarms on other working mechanisms.Finally,the challenge and prospect for EFWSs are briefly provided by comparing the art of state of fire alarms.This work can propose a more comprehensive understanding of EFWSs and a guideline for the cutting-edge development direction of EFWSs for readers.
文摘In the last five years, China has seen the technological development of intelligent mining and the application of the longwall automation technology developed by the Longwall Automation Steering Committee. This paper summarizes this great achievement, which occurred during the 12th Five-Year Plan （2011-2015）, and which included the development of a set of intelligent equipment for hydraulic-powered supports, information transfers, dynamic decision-making, performance coordination, and the achievement of a high level of reliability despite difficult conditions. Within China, the intelligent system of a set of hydraulic-powered supports was completed, with our own intellectual property rights. An intelligent mining model was developed that permitted unmanned operation and single-person inspection on the work face. With these technologies, the number of miners on the work face can now be significantly reduced. Miners are only required to monitor mining machines on the roadway or at the surface control center, since intelligent mining can be applied to extract middle-thick or thick coal seams. As a result, miners＇ safety has been improved. Finally, this Darter discusses theprospects and challenges of intelligent mining over the next ten years.
基金supported by the National Key R&D Program of China(Grant No.2017YFE0127600)the National Natural Science Foundation of China(Grant No.U1706229、21901248)+2 种基金the Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDA22010600)the National Natural Science Foundation for Distinguished Young Scholars of China(No.51625204)the Taishan Scholars of Shandong Province(ts201511063)。
文摘In advantages of their high capacity and high operating voltage,the nickel(Ni)-rich layered transition metal oxide cathode materials(LiNi_(x)Co_(y)Mn_(z)O_(2)(NCMxyz,x+y+z=1,x≥0.5)and LiNi_(0.8)Co_(0.15)Al_(0.05)O_(2)(NCA))have been arousing great interests to improve the energy density of LIBs.However,these Nirich cathodes always suffer from rapid capacity degradation induced by unstable cathode-electrolyte interphase(CEI)layer and destruction of bulk crystal structure.Therefore,varied electrode/electrolyte interface engineering strategies(such as electrolyte formulation,material coating or doping)have been developed for Ni-rich cathodes protection.Among them,developing electrolyte functional additives has been proven to be a simple,effective,and economic method to improve the cycling stability of Nirich cathodes.This is achieved by removing unfavorable species(such as HF,H_(2)O)or constructing a stable and protective CEI layer against unfavorable reactive species(such as HF,H_(2)O).Herein,this review mainly introduces the varied classes of electrolyte functional additives and their working mechanism for interfacial engineering of Ni-rich cathodes.Especially,key favorable species for stabilizing CEI layer are summarized.More importantly,we put forward perspectives for screening and customizing ideal functional additives for high performance Ni-rich cathodes based LIBs.
文摘By combing the characteristics of drilling in Antarctic region, performance requirements on drilling fluid for Antarctic low temperature conditions, and research progress of low temperature drilling fluid, current problems of the drilling fluid have been sorted out, and the development direction of the drilling fluid has been pointed out. Drilling in the Antarctic region mainly includes drilling in snow, ice and subglacial rock formations, and drilling in Antarctic low temperature conditions will face problems in four aspects:(1) low temperature and large temperature changes in the drilling area;(2) likely well leakage and drillstring-sticking in the snow layer, creep in the ice layer, ice chip gathering jamming in the warm ice layer, well wall collapse in the subglacial rock formations;(3) lack of infrastructure and difficulty in logistical support;(4) fragile environment and low carrying capacity. After years of development, progresses have been made on low-temperature drilling fluids for the Antarctic region. Low-temperature petroleum-based drilling fluid, ethanol/ethylene glycol-based drilling fluid, ester-based drilling fluid and silicone oil-based drilling fluid have been developed. However, these drilling fluids have problems such as insufficient low-temperature tolerance, low environmental performance and weak wellbore stability, etc. In order to meet the performance requirements of drilling fluid under low-temperature conditions in Antarctic region, the working mechanisms of low-temperature drilling fluid must be examined in depth;environment-friendly low-temperature base fluid of drilling fluid and related additives must be developed to prepare environmentally friendly low temperature drilling fluid systems;multi-functional integrated adjustment method for drilling fluid must be worked out to ensure well wall stability and improve cutting-carry capacity when drilling ice formations and ice-rock interlayers;and on-site support operation codes must be established to provide technical support for Antarctic drilling.
基金support of the research funds provided by the National Natural Science Foundation of China (Nos. 51304071, 51304073)the Open Projects of State Key Laboratory of Coal Resources and Safe Mining, China University of Mining & Technology of China (No. 12KF02)
文摘North and west China has abundant coal resources, however, such resources make these regions prone to serious mine fire disasters. Although the copious sand and fly ash resources found in these areas can be used as fire-fighting materials, conventional grouting is expensive because of water shortage and loess particles. A new compound material(i.e., a sand-suspended colloid), which comprises a mineral inorganic gel and an organic polymer, is developed in the current study to improve the quality of sand injection and reduce water wastage when grouting. The new material can steadily suspend the sand, through the addition of a small amount of colloid yielding steady sand-suspended slurry. The process of producing the slurry is convenient and quick, overcoming the shortage of sand-suspending thickeners which need heat and are difficult to produce. The space work model based on the theory of the double-electric layer is established to study the suspended mechanism of the solid particles in the sand-suspended colloid.The dispersion effect of the sand-suspended colloid is demonstrated by the incorporation of the electrostatic effect by the double-electric layer and the steric hindrance effect on the sand particles, ensuring the stability of the colloid system and the steady suspension of sand particles in the sand-suspended colloid.Mechanical analysis indicates that the sand is suspended steadily under the condition that the rock sand particles stress on the lower part of the fluid is less than the yield stress of the colloid. Finally, the fireprevention technology of sand suspension was applied and tested in the Daliuta Coal Mine, achieving successful results.
基金financial support of the National Key Research and Development Program of China(No.2017YFB0304401)National Natural Science Foundation of China(Nos.U1564203,51571141 and 51201105)the support provided by Shanghai Key Laboratory of Materials Laser Processing and Modification,Shanghai Jiao Tong University
文摘The effects of deforming temperatures on the tensile behaviors of quenching and partitioning treated steels were investigated. It was found that the ultimate tensile strength of the steel decreased with the increasing temperature from 25 to 100 ℃, reached the maximum value at 300 ℃, and then declined by a significant extent when the temperature further reached 400 ℃. The total elongations at 100, 200 and 300 ℃are at about the same level. The steel achieved optimal mechanical properties at 300 ℃due to the proper transformation behavior of retained austenite since the stability of retained austenite is largely dependent on the deforming temperature. When tested at 100 and 200 ℃, the retained aus tenite was reluctant to transform, while at the other temperatures, about 10 vol. % of retained aus- tenite transformed during the tensile tests. The relationship between the stability of retained austenite and the work hardening behavior of quenching and partitioning treated steels at different deforming temperatures was also studied and discussed in detail. In order to obtain excellent mechanical properties, the stability of retained austenite should be carefully controlled so that the effect of transforma tion-induced plasticity could take place continuously during plastic deformation.
基金the research fund of National Natural Science Foundation of China (No. 51821091)Fundamental Research Funds for the Central Universities (Nos.D5000210894 and 3102019JC005)。
文摘Rechargeable aqueous Zn/MnO_(2)batteries raise massive research activities in recent years. However, both the working principle and the degradation mechanism of this battery chemistry are still under debate. Herein, we provide an in-depth electrochemical and structural investigation on this controversial issue based on α-MnO_(2)crystalline nanowires. Mechanistic analysis substantiates a two-electron reaction pathway of Mn2+/Mn4+redox couple from part of MnO_(2)accompanying with a reversible precipitation/dissolution of flaky zinc sulfate hydroxide(ZSH) during the discharge/charge processes. The formation of the ZSH layer is double-edged, which passivates the deep dissolution of MnO_(2)upon discharging,but promotes the electrochemical deposition kinetics of active MnO_(2)upon charging. The cell degradation originates primarily from the corrosion failure of metallic zinc anode and the accumulation of irreversible ZnMn2O_(4)phases on the cathode. The addition of MnSO_(4)to the electrolyte could afford supplementary capacity contribution via electro-oxidation of Mn2+. However, a high MnSO_(4)concentration will expedite the cell failure by corroding the metallic zinc anodes. The present study will shed a fundamental insight on developing new strategies toward practically viable Zn/MnO_(2)batteries.
基金supported by the National Natural Science Foundation of China(52203066,51973157,51673148,51678411)the Science and Technology Plans of Tianjin,China(19PTSYJC00010)+3 种基金the China Postdoctoral Science Foundation Grant(2019M651047)the Tianjin Research Innovation Project for Postgraduate Students,China(2020YJSB062)the Tianjin Municipal college student’innovation and entrepreneurship training program,China(202110058052)the National innovation and entrepreneurship training program for college students,China(202110058017)。
文摘With the emergence of some solid electrolytes(SSEs)with high ionic conductivity being comparable to liquid electrolytes,solid-state lithium-sulfur batteries(SSLSBs)have been widely regarded as one of the most promising candidates for the next generation of power generation energy storage batteries,and have been extensively researched.Though many fundamental and technological issues still need to be resolved to develop commercially viable technologies,SSLSBs using SSEs are expected to address the present limitations and achieve high energy and power density while improving safety,which is very attractive to large-scale energy storage systems.SSLSBs have been developed for many years.However,there are few systematic discussions related to the working mechanism of action of various electrolytes in SSLSBs and the defects and the corresponding solutions of various electrolytes.To fill this gap,it is very meaningful to review the recent progress of SSEs in SSLSBs.In this review,we comprehensively investigate and summarize the application of SSEs in LSBs to determine the differences which still exist between current progresses and real-world requirements,and comprehensively describe the mechanism of action of SSLSBs,including lithium-ion transport,interfacial contact,and catalytic conversion mechanisms.More importantly,the selection of solid electrolyte materials and the novel design of structures are reviewed and the properties of various SSEs are elucidated.Finally,the prospects and possible future research directions of SSLSBs including designing high electronic/ionic conductivity for cathodes,optimizing electrolytes and developing novel electrolytes with excellent properties,improving electrode/-electrolyte interface stability and enhancing interfacial dynamics between electrolyte and anode,using more advanced test equipment and characterization techniques to analyze conduction mechanism of Li^(+)in SSEs are presented.It is hoped that this review can arouse people’s attention and enlighten the development of functional materials and novel structures of SSEs in the next step.
基金Hubei Province university student work quality general support project"practice exploration of non structural group consultation to improve college students'interpersonal skills"(2018XGJPX3010)Wuhan Institute of Technology 2019 humanities and social science project"early warning and intervention mechanism of psychological health risk of college":The construction of"great health"education pattern(R201903).
文摘Psychological health education has been highly valued by the party and the state.During the fight against the COVID-19,colleges and universities have made a beneficial exploration in carrying out psychological health education.In older to further understand the impact of the epidemic on the psychological health of college students,a survey was carried out based on questionnaire survey,depth interview and expert consultation.The survey found that the epidemic increased the psychological pressure and posed new challenges to the psychological health education in colleges and universities.Based on the analysis of the causes from the four aspects of society,family,college and individual,this thesis put forwards some suggestions on how to effectively carry out the psychological health education of college students in the context of fighting against the epidemic.
文摘In order to strengthen the production efficiency and quality of underground coal mine, the application of variable frequency drive control system of scraper conveyor is analyzed. Firstly, the performance of the equipment is introduced, and the necessity of the design and application of frequency conversion drive control system is clarified, which is beneficial to strengthen the informatization and digitization of underground coal mine production. Secondly, it describes the construction of variable frequency drive control system, grasps the system structure and the selection requirements of various components. Finally analyzes the application of variable frequency drive control system, and summarizes the suggestions on optimizing the application effect of scraper conveyor, which is conducive to improving the stability and efficiency of the equipment operation, and provides modern system support for future underground coal mine production.
