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Seismic Vibration Control of Wind Turbine Towers with Bidirectional Tuned Bellow Liquid Column Damper
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作者 Xiwei Wang Wanrun Li +2 位作者 Wenhai Zhao Yining Wang Yongfeng Du 《Structural Durability & Health Monitoring》 2025年第5期1241-1263,共23页
To address the vibration issues of wind turbine towers,this paper proposes a bidirectional tuned bellow liquid column damper(BTBLCD).The configuration of the proposed BTBLCD is first described in detail,and its energy... To address the vibration issues of wind turbine towers,this paper proposes a bidirectional tuned bellow liquid column damper(BTBLCD).The configuration of the proposed BTBLCD is first described in detail,and its energy dissipation mechanism is derived through theoretical analysis.A refined dynamic model of the wind turbine tower equipped with the BTBLCD is then developed.The vibration energy dissipation performance of the BTBLCD in multiple directions is evaluated through two-way fluid-structure coupling numerical simulations.Finally,a 1/10 scaled model of the wind turbine tower is constructed,and the energy dissipation performance of the BTBLCD is validated using a shaking table test.The results show that the vibration energy dissipation performance of the BTBLCD outperforms that of the bidirectional tuned liquid column damper(BTLCD)in multiple directions.The shaking table test and dynamic response analysis demonstrate a maximum reduction of 61.0%in acceleration and 47.9%in displacement response.Furthermore,the vibration control and energy dissipation performance of the BTBLCD are influenced by the direction and amplitude of vibrations.This study contributes to the development of more effective and versatile vibration mitigation strategies for wind turbine tower structures in various engineering scenarios. 展开更多
关键词 Structural durability vibration control bidirectional tuned bellow liquid column damper energy dissipation dynamic response
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Seismic response mitigation of offshore jacket platforms using a novel bidirectional tuned liquid column gas damper
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作者 Mohamadhosein Mohasel Mohammad Reza Chenaghlou Ahmad Reza Mostafa Gharabaghi 《Theoretical & Applied Mechanics Letters》 2025年第5期508-521,共14页
This study investigates the seismic response mitigation of an offshore jacket platform via a novel damping system,the bidirectional tuned liquid column gas damper(BTLCGD).To efficiently model the complex platform stru... This study investigates the seismic response mitigation of an offshore jacket platform via a novel damping system,the bidirectional tuned liquid column gas damper(BTLCGD).To efficiently model the complex platform structure,an equivalent single degree of freedom approach was employed.Since the mass contribution of the first mode of the platform is more than 90%,this simplification significantly reduces the computational burden while maintaining accuracy.Therefore,this structure was modeled and analyzed on a scale of 1 to 36 using the Froudian law.To address the limitations of conventional tuned liquid column gas dampers(TLCGDs),which are susceptible to the directionality of seismic excitations,BTLCGD was proposed.This innovative damper is designed to operate effectively in two orthogonal directions,thereby improving seismic performance.Through numerical simulations,the performance of both TLCGD and BTLCGD was evaluated under seismic loading.The results demonstrated that BTLCGD significantly outperforms TLCGD in terms of reducing structural responses,particularly in the direction where TLCGD is ineffective.Furthermore,BTLCGD offers advantages in terms of installation and space requirements.The results of this research offer valuable perspectives into the design and implementation of effective damping systems for offshore structures,contributing to enhanced structural integrity and safety. 展开更多
关键词 Offshore jacket platform Structural control Bidirectional tuned liquid column gas damper Response time history
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Contribution of tuned liquid column gas dampers to the performance of offshore wind turbines under wind, wave, and seismic excitations 被引量:8
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作者 Khosrow Bargi Reza Dezvareh Seyed Amin Mousavi 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2016年第3期551-561,共11页
The main intention of the present study is to reduce wind, wave, and seismic induced vibrations of jacket- type offshore wind turbines (JOWTs) through a newly developed vibration absorber, called tuned liquid column... The main intention of the present study is to reduce wind, wave, and seismic induced vibrations of jacket- type offshore wind turbines (JOWTs) through a newly developed vibration absorber, called tuned liquid column gas damper (TLCGD). Using a Simulink-based model, an analytical model is developed to simulate global behavior of JOWTs under different dynamic excitations. The study is followed by a parametric study to explore efficiency of the TLCGD in terms of nacelle acceleration reduction under wind, wave, and earthquake loads. Study results indicate that optimum frequency of the TLCGD is rather insensitive to excitation type. In addition, while the gain in vibration control from TLCGDs with higher mass ratios is generally more pronounced, heavy TLCGDs are more sensitive to their tuned frequency such that ill-regulated TLCGD with high mass ratio can lead to destructive results. It is revealed that a well regulated TLCGD has noticeable contribution to the dynamic response of the JOWT under any excitation. 展开更多
关键词 offshore wind turbine wind load wave load seismic load tuned liquid column gas damper
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Optimum geometry of tuned liquid column-gas damper for control of offshore jacket platform vibrations under seismic excitation 被引量:4
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作者 Seyed Amin Mousavi Seyed Mehdi Zahrai Khosrow Bargi 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2012年第4期579-592,共14页
In this study, the effectiveness of a tuned liquid column-gas damper, TLCGD, on the.suppression of seismic-induced vibrations of steel jacket platforms is evaluated. TLCGD is an interesting choice in the case of jacke... In this study, the effectiveness of a tuned liquid column-gas damper, TLCGD, on the.suppression of seismic-induced vibrations of steel jacket platforms is evaluated. TLCGD is an interesting choice in the case of jacket platforms because it is possible to use the structural elements as the horizontal column of the TLCGD. The objective here is to find the optimum geometric parameters, namely orientation and configuration of vertical columns, length ratio, and area ratio of the TLCGD, considering nonlinear damping of the TLCGD and water-structure interaction between the jacket platform and sea water. The effects of different characteristics of ground motion such as PGA and frequency content on the optimum geometry are also investigated and it is observed that these features have some influence on the optimum area ratio. Finally it is observed that pulse arrangement of ground acceleration is one of the most important parameters affecting the efficiency of a TLCGD. In other words, it is found that the TLCGD's capability to reduce the RMS responses depends only on the frequency content of the ground acceleration, but its capability to reduce the maximum responses depends on both the frequency content and the pulse arrangement of the ground acceleration. 展开更多
关键词 passive control tuned liquid column damper TLCGD offshore platform optimum geometry
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Wind-induced vibration control of bridges using liquid column damper 被引量:3
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作者 薛素铎 高赞明 徐幼麟 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2002年第2期271-280,共10页
The potential application of tuned liquid column damper (TLCD) for suppressing wind-induced vibration of long span bridges is explored in this paper.By installing the TLCD in the bridge deck,a mathematical model for t... The potential application of tuned liquid column damper (TLCD) for suppressing wind-induced vibration of long span bridges is explored in this paper.By installing the TLCD in the bridge deck,a mathematical model for the bridge-TLCD system is established.The governing equations of the system are developed by considering all three displacement components of the deck in vertical,lateral,and torsional vibrations,in which the interactions between the bridge deck,the TLCD,the aeroelastic forces,and the aerodynamic forces are fully reflected.Both buffeting and flutter analyses are carried out.The buffeting analysis is performed through random vibration approach,and a critical flutter condition is identified from flutter analysis.A numerical example is presented to demonstrate the control effectiveness of the damper and it is shown that the TLCD can be an effective device for suppressing wind-induced vibration of long span bridges,either for reducing the buffeting response or increasing the critical flutter wind velocity of the bridge. 展开更多
关键词 long span bridge bridge deck wind-induced vibration vibration control FLUTTER BUFFETING tuned liquid column damper TLCD-bridge interaction mathematical model
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Torsionally Coupled Response Control of Offshore Platform Structures Using Circular Tuned Liquid Column Dampers 被引量:2
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作者 霍林生 李宏男 《海洋工程:英文版》 EI 2004年第2期173-183,共11页
In this paper, the control performance is investigated of Circular Tuned Liquid Column Dampers (CTLCD) over torsional response of offshore platform structures excited by ground motions. Based on the equation of motion... In this paper, the control performance is investigated of Circular Tuned Liquid Column Dampers (CTLCD) over torsional response of offshore platform structures excited by ground motions. Based on the equation of motion for the CTLCD-structure system, the optimal control parameters of CTLCD are given through some derivations on the supposition that the ground motion is a stochastic process. The influence of systematic parameters on the equivalent damping ratio of the structures is analyzed with purely torsional vibration and translational-torsional coupled vibration, respectively. The results show that the Circular Tuned Liquid Column Damper (CTLCD) is an effective torsional response control device. 展开更多
关键词 circular tuned liquid column dampers offshore platform vibration control seismic response eccentric structures
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Impact of seismic excitation characteristics on the efficiency of tuned liquid column dampers
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作者 Ali Kavand S. Mehdi Zahrai 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2006年第2期235-243,共9页
Various types of passive control systems have been used to suppress the seismic response of structures in recent years. Among these systems, Tuned Liquid Column Dampers (TLCDs) dissipate the input earthquake energy ... Various types of passive control systems have been used to suppress the seismic response of structures in recent years. Among these systems, Tuned Liquid Column Dampers (TLCDs) dissipate the input earthquake energy by combining the effects of the movement of the liquid mass in the container, the restoring force on the liquid due to the gravity loads and the damping due to the liquid movement through orifices. In this study, the effects of seismic excitation characteristics such as frequency content and soil condition on the seismic performance of TLCDs are investigated using nonlinear time-history analyses. In this regard, among the past earthquake ground motion records of Iran, 16 records with different parameters were selected. In the structural model developed, the attached TLCD is simulated as a Tuned Mass Damper (TMD) having the same vibration period and damping ratio as the original TLCD. The numerical results show that the seismic excitation characteristics have a substantial role on the displacement reduction capability of TLCDs and they should be considered accordingly in the design of TLCDs. 展开更多
关键词 passive control tuned liquid column dampers seismic excitation characteristics frequency content subsoilconditions seismic performance
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Control performance comparison between tuned liquid damper and tuned liquid column damper using real-time hybrid simulation 被引量:4
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作者 Zhu Fei Wang Jinting +1 位作者 Jin Feng Lu Liqiao 《Earthquake Engineering and Engineering Vibration》 SCIE EI CSCD 2019年第3期695-701,共7页
Tuned liquid damper (TLD) and tuned liquid column damper (TLCD) are two types of passive control devices that are widely used in structural control. In this study, a real-time hybrid simulation (RTHS) technique is emp... Tuned liquid damper (TLD) and tuned liquid column damper (TLCD) are two types of passive control devices that are widely used in structural control. In this study, a real-time hybrid simulation (RTHS) technique is employed to investigate the diff erence in control performance between TLD and TLCD. A series of RTHSs is presented with the premise of the same liquid length, mass ratio, and structural parameters. Herein, TLD and TLCD are physically experimented, and controlled structures are numerically simulated. Then, parametric studies are performed to further evaluate the diff erent performance between TLD and TLCD. Experimental results demonstrate that TLD is more eff ective than TLCD under diff erent amplitude excitations. 展开更多
关键词 tuned liquid DAMPER tuned liquid column DAMPER real-time hybrid simulation CONTROL effi ciency STRUCTURAL CONTROL PARAMETRIC study
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Liquid Column Deformation and Particle Size Distribution in Gas Atomization 被引量:2
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作者 Georgios S. E. Antipas 《Materials Sciences and Applications》 2011年第2期87-96,共10页
A water-gas flow injected by a close coupled atomizer was studied via High Speed Photography and Phase Doppler Anemometry. The formation of a wave disturbance on the surface of the water column was confirmed. The flow... A water-gas flow injected by a close coupled atomizer was studied via High Speed Photography and Phase Doppler Anemometry. The formation of a wave disturbance on the surface of the water column was confirmed. The flow converged within an area approximately 3 mm in diameter, independent of atomization conditions. The particle size distribution across the spray suggested a trend of decreasing particle sizes and particle velocities with increasing distance from the spray axis of symmetry. 展开更多
关键词 liquid column DEFORMATION Two Phase Flow ATOMIZATION High Speed PHOTOGRAPHY Laser DOPPLER ANEMOMETRY
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Control of liquid column height in electromagnetic casting with fuzzy neural network model
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作者 李朝霞 郑贤淑 《中国有色金属学会会刊:英文版》 CSCD 2002年第5期922-925,共4页
The control of suitable and stable height of liquid column is the crucial point to operate the electromagnetic casting(EMC) process and to obtain ingots with desirable shape and dimensional accuracy. But due to the co... The control of suitable and stable height of liquid column is the crucial point to operate the electromagnetic casting(EMC) process and to obtain ingots with desirable shape and dimensional accuracy. But due to the complicated interact parameters and special circumstances, the measure and control of liquid column are quite difficult. A fuzzy neural network was used to help control the liquid column by predicting its height on line. The results show that the stabilization of the height of liquid column and surface quality of the ingot are remarkably improved by using the neural network based control system. 展开更多
关键词 电磁铸造 模糊神经网络 模式识别 液柱形状
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Desalination of Seawater by Liquid Columns and Decompression Boiling (Recovery of Condensation Latent Heat)
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作者 Toshihiko Shakouchi 《Journal of Water Resource and Protection》 2018年第8期809-816,共8页
In this study, the concept of a new seawater desalination method and equipment using liquid columns of seawater and desalinated fresh water, decompression boiling and evaporation, condensation, and recovery of condens... In this study, the concept of a new seawater desalination method and equipment using liquid columns of seawater and desalinated fresh water, decompression boiling and evaporation, condensation, and recovery of condensation latent heat are proposed. The equipment consists of seawater and freshwater columns approximately 10 m high with top spaces. The pressure of the top space, the evaporation and condensation area, of the seawater column, for example, is reduced approximately 30 mmHg (abs.) using the seawater column, after which it is heated from the general seawater temperature of 25°C to 30°C to boil and evaporate the seawater. The vapor is cooled by the seawater at approximately 25°C in a heat exchanger, and then, it is condensed and sent to the fresh water column. At this time, the condensation latent heat is recovered to preheat the newly flowing seawater. The evaporation or condensation rate, namely, the production rate of freshwater, by the new desalination equipment is also estimated by the results of the existing quadruplex effect vacuum evaporator used in the salt production industry. This new desalination method and its associated equipment also can be used to purify polluted water and waste water. 展开更多
关键词 New DESALINATION Method of Seawater liquid column DECOMPRESSION BOILING Evaporation and CONDENSATION RECOVERY of CONDENSATION LATENT Heat
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Study on Image- denoising of Liquid Column in Investment Casting Auto- pouring System
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作者 YANG Huiying DU Wenbin 《沈阳理工大学学报》 CAS 2015年第2期91-94,共4页
The application of investment casting auto-pouring system can improve the efficiency of manual-pouring system to a certain extent.The judgment of start-stop time depends on the preprocessing of original image collecte... The application of investment casting auto-pouring system can improve the efficiency of manual-pouring system to a certain extent.The judgment of start-stop time depends on the preprocessing of original image collected by the CCD camera.Several methods are presented to denoise the liquid column image.The method of morphological image processing is feasible in theory,and it is important whether to choose the structural element or not.The method of pouring image projection is less affected the image of spure cup.The complexity of image window algorithm is minimal. 展开更多
关键词 POURING PREPROCESSING projection camera manual JUDGMENT morphological STRUCTURING COORDINATES replace
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CONTROL OF FORMABILITY OF EMC LIQUID METAL COLUMN 被引量:4
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作者 Zhang Xingguo Jin Junze Cao Zhiqiang (Research Center of Foundry Engineering ,Dalian University of Technology, Dalian 116024) 《中国有色金属学会会刊:英文版》 CSCD 1996年第2期117-122,共6页
CONTROLOFFORMABILITYOFEMCLIQUIDMETALCOLUMNZhangXingguo;JinJunze;CaoZhiqiang(ResearchCenterofFoundryEngineeri... CONTROLOFFORMABILITYOFEMCLIQUIDMETALCOLUMNZhangXingguo;JinJunze;CaoZhiqiang(ResearchCenterofFoundryEngineering,DalianUniversi... 展开更多
关键词 electro-magnetic CASTING liquid column HEIGHT electro-magnetic FORMING
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Rapid and simultaneous determination of imidazolium and pyridinium ionic liquid cations by ion-pair chromatography using a monolithic column 被引量:8
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作者 Xu Huang Hong Yu Ying Jie Dong 《Chinese Chemical Letters》 SCIE CAS CSCD 2012年第7期843-846,共4页
A method for rapid and simultaneous determination of imidazolium and pyridinium ionic liquid cations by ion-pair chromatography with ultraviolet detection was developed. Chromatographic separations were performed on a... A method for rapid and simultaneous determination of imidazolium and pyridinium ionic liquid cations by ion-pair chromatography with ultraviolet detection was developed. Chromatographic separations were performed on a reversed-phase silica-based monolithic column using 1-heptanesulfonic acid sodium-acetonitrile as mobile phase. The effects of ion-pair reagent and acetonitrile concentration on retention of the cations were investigated. The retention times of the cations accord with carbon number rule. The method has been successfully applied to the determination of four ionic liquids synthesized by organic chemistry laboratory. 展开更多
关键词 Ionic liquids Ion-pair chromatography Monolithic column Ultraviolet detection
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Simulation of Liquid Velocity Field in a Gas-Liquid Bubble Column
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作者 张敏卿 范敏英 +1 位作者 余国琮 王树立 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1998年第4期28-36,共9页
A simplified turbulent model and a modified k-Σ two equation model are proposed todescribe the liquid velocity profiles in a bubble column taking into consideration of the effect of gasdrag force and gas hold-up.In t... A simplified turbulent model and a modified k-Σ two equation model are proposed todescribe the liquid velocity profiles in a bubble column taking into consideration of the effect of gasdrag force and gas hold-up.In the simplified mode1 the Reynolds equation of motion was adoptedand the turbulent viscosity was calculated from an empirical correlation which was deduced fromour experimental data.The calculated liquid velocity profiles were compared between the proposedmodel and the standard k-Σ two equation model as well as experimental data.The result shows thatthe proposed model simulates and predicts the liquid velocity field most satisfactorily and in goodagreement with the experimental measurement. 展开更多
关键词 BUBBLE column liquid VELOCITY field TURBULENT model
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柱后衍生液相色谱法测定茶酒中的果糖、葡萄糖和蔗糖
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作者 李丽霞 成洲 +2 位作者 李丹 钟晓雪 罗学平 《中国酿造》 北大核心 2026年第1期288-294,共7页
该研究建立了一种柱后衍生液相色谱法测定茶酒中果糖、葡萄糖和蔗糖含量的方法。采用Asahipak NH2P-50 4E色谱柱(250 mm×4.6 mm,5μm),以含0.5%H3PO4的乙腈-水(75∶25,V/V)为流动相进行等度洗脱,流速0.8 m L/min,柱温40℃,柱后120... 该研究建立了一种柱后衍生液相色谱法测定茶酒中果糖、葡萄糖和蔗糖含量的方法。采用Asahipak NH2P-50 4E色谱柱(250 mm×4.6 mm,5μm),以含0.5%H3PO4的乙腈-水(75∶25,V/V)为流动相进行等度洗脱,流速0.8 m L/min,柱温40℃,柱后120℃下采用2.0 g/L高碘酸氧化、1.0 g/L酚试剂进行衍生显色,于波长670 nm处检测。结果表明,果糖在25.0~500.0 mg/L、葡萄糖和蔗糖在50.0~1 000.0 mg/L质量浓度范围内具有良好的线性关系,相关系数(R^(2))>0.999,方法 检出限为2.58~9.64 mg/L,定量限为7.82~29.21 mg/L,加标回收率为96.55%~98.73%,精密度、稳定性试验结果相对标准偏差均<2.00%。利用本方法对市售的4类共11款茶酒中3种糖含量进行检测,结果表明在所有茶酒中均检测出葡萄糖,含量为0.038~111.36 g/L,10款茶酒中检测出果糖,含量为0.023~115.90 g/L,其中配制型茶酒中的葡萄糖、果糖含量最高;蔗糖仅在3款露酒型茶酒中检出,含量为0.012~0.380 g/L。该方法操作简便、试剂成本低、回收率高,可为茶酒的工艺研究、产品开发及标准制定等提供新的检测技术支持。 展开更多
关键词 液相色谱 柱后衍生 紫外检测 茶酒 糖类物质
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多液柱调谐阻尼器对浮式风机基础运动的抑制效果
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作者 陈淑玲 韩长志 +2 位作者 李国明 崔福音 YAN Shiqiang 《船舶工程》 北大核心 2026年第1期23-30,共8页
[目的]为研究半潜浮式风机平台俯仰运动对平台的疲劳载荷和气动性能的影响,并探讨多液柱调谐阻尼器(TLMCD)对平台运动的抑制效果,[方法]以OC4 DeepCWind半潜浮式平台为例,开展TLMCD对浮式风机平台运动的抑制作用研究。基于该平台的结构... [目的]为研究半潜浮式风机平台俯仰运动对平台的疲劳载荷和气动性能的影响,并探讨多液柱调谐阻尼器(TLMCD)对平台运动的抑制效果,[方法]以OC4 DeepCWind半潜浮式平台为例,开展TLMCD对浮式风机平台运动的抑制作用研究。基于该平台的结构和系泊特点设计3种不同规格的TLMCD,并利用聚焦波模型模拟真实海况中的波浪载荷,在保持原缆索系泊方式不变的情况下,分析TLMCD的调谐频率及其对平台运动响应的影响。[结果]结果表明:TLMCD对平台纵摇运动有显著的抑制效果,尤其是在平台固有频率、波浪谱峰频率和TLMCD调谐频率三者吻合条件下,调谐效率最佳。[结论]研究成果可为半潜浮式平台的运动控制设计和优化提供一定参考。 展开更多
关键词 多液柱调谐阻尼器(TLMCD) 运动抑制 浮式风机
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公英青蓝合剂HPLC特征图谱研究
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作者 魏秀丽 张志民 +5 位作者 刘华阳 梁萌 冯涛 于振洋 张传津 李有志 《饲料工业》 北大核心 2026年第2期136-144,共9页
研究旨在建立公英青蓝合剂液相色谱特征图谱,为制定兽药国家标准提供依据。通过配制参照物溶液,供试品中的药物经20%乙醇提取后,采用C_(18)色谱柱(4.6 mm×150 mm,3.5μm),以乙腈-0.4%磷酸溶液进行梯度洗脱;用二极管阵列检测器进行... 研究旨在建立公英青蓝合剂液相色谱特征图谱,为制定兽药国家标准提供依据。通过配制参照物溶液,供试品中的药物经20%乙醇提取后,采用C_(18)色谱柱(4.6 mm×150 mm,3.5μm),以乙腈-0.4%磷酸溶液进行梯度洗脱;用二极管阵列检测器进行分析,检测波长为240 nm,流速为0.6 mL/min,柱温为35℃。结果显示:供试品色谱图中呈现7个特征峰,并与对应的参照物色谱峰保留时间一致。研究表明,该液相色谱特征图谱法可操作性强、专属性强、稳定性好,可以有效控制公英青蓝合剂内在质量。 展开更多
关键词 公英青蓝合剂 特征图谱 高效液相色谱法 二极管阵列检测器 色谱柱
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在线固相萃取-超高效液相色谱-串联质谱法测定血清中3种类固醇雌激素的含量
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作者 裴海燕 杨继伟 +2 位作者 周衍霄 陈钰灵 俞晓峰 《理化检验(化学分册)》 北大核心 2026年第1期13-18,共6页
为测定血清中3种类固醇雌激素(雌酮、雌二醇、雌三醇)的含量,同时简化前处理流程、减少溶剂消耗及人为操作误差,提出了题示方法。取200μL血清样品置于1.5 mL离心管中,加入600μL 2μg·L^(-1)混合内标使用液,涡旋60 s,离心10 min,... 为测定血清中3种类固醇雌激素(雌酮、雌二醇、雌三醇)的含量,同时简化前处理流程、减少溶剂消耗及人为操作误差,提出了题示方法。取200μL血清样品置于1.5 mL离心管中,加入600μL 2μg·L^(-1)混合内标使用液,涡旋60 s,离心10 min,取200μL上清液置于800μL水中,涡旋60 s,所得溶液进入在线固相萃取系统,在两根Oasis HLB Direct Connect HP固相萃取柱上交替上样和净化,然后萃取液进入超高效液相色谱-串联质谱系统,3种目标物在Kinetex Polar C_(18)色谱柱上以0.5 mmol·L^(-1)氟化铵溶液-乙腈体系进行梯度洗脱分离,在电喷雾离子源负离子和多反应监测模式下进行内标法定量。结果显示,3种目标物的质量浓度在0.01~50μg·L^(-1)内和对应的峰面积与内标峰面积的比值呈线性关系,检出限(3S/N)为0.50~0.73 ng·L^(-1)。按照标准加入法进行回收试验,回收率为97.6%~106%,测定值的相对标准偏差(n=6)为1.2%~6.6%。方法用于分析30份血清样品,雌酮、雌二醇、雌三醇均被检出,检出量分别为15.31~95.78 ng·L^(-1),2.14~123.32 ng·L^(-1),3.06~29.08 ng·L^(-1)。 展开更多
关键词 在线固相萃取 双柱交替 超高效液相色谱-串联质谱法 血清 类固醇雌激素
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Construction of on-line supercritical fluid extraction with reverse phase liquid chromatography–tandem mass spectrometry for the determination of capsaicin 被引量:3
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作者 Naoki Hamada Yuki Hashi +4 位作者 Satoshi Yamaki Yanli Guo Lin Zhang Haifang Li Jin-Ming Lin 《Chinese Chemical Letters》 SCIE CAS CSCD 2019年第1期99-102,共4页
A novel on-line system composed of supercritical fluid extraction(SFE), dilution line and reverse phase liquid chromatography/mass spectrometry(RPLC/MS) was constructed for on-line extraction and reverse phase separat... A novel on-line system composed of supercritical fluid extraction(SFE), dilution line and reverse phase liquid chromatography/mass spectrometry(RPLC/MS) was constructed for on-line extraction and reverse phase separation of some fat-soluble components in foods. Three columns including a trap column,concentration column and analytical column were used for trapping the fat-soluble components, on-line enrichment and reverse phase separation, respectively. Capsaicinoids were on-line extracted by a CO_2 supercritical fluid, then concentrated and separated by using the C_(18) columns, finally detected by mass spectrometry(MS). Capsaicin eluted at 10.1 min and limit of detection(LOD, S/N=3) for the standard solution is 0.55pg. The linearity was calculated with a value of coefficient of determination(R^2)≥0.998 in the range of 1.1–8.5 ng. Concentrations of capsaicin in the green, yellow, and red bell peppers were determined to be 60.33 ng/g, 31.79 ng/g, 35.38ng/g, respectively. 展开更多
关键词 SUPERCRITICAL fluid extraction liquid chromatography-mass SPECTROMETRY column-SWITCHING system CAPSAICIN
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