Cyclic polymers exhibit fascinating crystallization behaviors owing to the absence of chain ends and more compact conformations.In the current simulation,dynamic Monte Carlo simulations were performed to reveal the un...Cyclic polymers exhibit fascinating crystallization behaviors owing to the absence of chain ends and more compact conformations.In the current simulation,dynamic Monte Carlo simulations were performed to reveal the underlying mechanism of the effect of chain topology and chain length on crystallization of polymer in solutions containing one-dimensional nanofiller.Simulation results suggested that the filled cyclic polymers exhibit higher melting temperature,higher crystallization temperature,and faster crystallization rate than the analogous linear polymers of identical chain length,especially in the systems with relatively short chains.Based on the Thomson-Gibbs equation,we theoretically analyzed the difference in the melting point between the cyclic and linear polymers under different chain lengths,and derived the dependence of the ratio of the melting point of the linear polymers to that of its cyclic analogs on chain length.In addition,it was also observed that the nanofiller can induce the formation of nanohybrid shish-kebab structure during isothermal crystallization of all systems.展开更多
Here we use nor-seco-cucurbit[10]uril(ns-CB[10]) based ternary complexation to construct [5]rotaxane,linear supramolecular dynamic rotaxane polymers and cubic 3D supramolecular organic framework.A [5]rotaxane is const...Here we use nor-seco-cucurbit[10]uril(ns-CB[10]) based ternary complexation to construct [5]rotaxane,linear supramolecular dynamic rotaxane polymers and cubic 3D supramolecular organic framework.A [5]rotaxane is constructed by ns-CB[10], TMe CB[6] and short linear derivatives of 4,4'-bipyridinium(M2). ns-CB[10], CB[7] and long linear derivatives of 4,4'-bipyridinium(M3) self-assemble into a linear supramolecular dynamic rotaxane polymer. ns-CB[10] and tetracationic tetrahedral monomer selfassemble and form a three-dimensional supramolecular organic framework. The above results demonstrate that ns-CB[10]-based ternary complexation is a versatile platform to build various supramolecular systems.展开更多
Polydopamine-based melanin-like materials have been widely used in the fields of ultraviolet(UV)shielding,solar desalination and anti-inflammatory treatment owing to their unique physical properties.The well-establish...Polydopamine-based melanin-like materials have been widely used in the fields of ultraviolet(UV)shielding,solar desalination and anti-inflammatory treatment owing to their unique physical properties.The well-established synthesis of polydopamine nanoparticles involves the oxidative polymerization of dopamine-derived monomers,resulting in cross-linked nanostructures with high complexity and heterogeneity.Therefore,the controlled synthesis of polydopamine-based melanin-like materials with well-defined structures and predictable properties remains challenging.Herein,we propose a mechanochemical Suzuki polymerization approach for the synthesis of linear melanin-like polymers with tunable physical properties.Compared with polydopamine nanoparticles,the mechanochemical approach offers a more flexible chain-like structure,thereby enhancing its antioxidant performance.Furthermore,this approach also enables the preparation of a melanin-like alternating copolymer that exhibits green fluorescence owing to itsπ-conjugated structure.This study not only offers opportunities for exploring novel synthetic melanin materials,but also provides new insights into the structure-function relationships of polydopamine-based materials.展开更多
A new solvent polymeric membrane (SPM)pH2sensor based on 4,4'-bis (N, N-didecylamino)methyl)azobenzene as neutral carricr has been reported. It has excellent pH response characteristics with the linear response ra...A new solvent polymeric membrane (SPM)pH2sensor based on 4,4'-bis (N, N-didecylamino)methyl)azobenzene as neutral carricr has been reported. It has excellent pH response characteristics with the linear response range (1.7—13.2)much wider than that of similar SPM pH sensors reported so far. The sensor has a theoretical Nernstian response of 57.4+0.2V/pH(at 20℃)without super—Nernstian response phenomenon.展开更多
The title complex [NH4]n [WAgS4]n crystallizes in the tetragonalspace group I4 with crystallographic parameters: a = b = 7. 994 (2 ), c = 5. 855 (2 ):A,V = 373. g(2) A3, Z=2, Dc= 3. 89 g/cm3, F(000) = 392, μ= 19. 27 ...The title complex [NH4]n [WAgS4]n crystallizes in the tetragonalspace group I4 with crystallographic parameters: a = b = 7. 994 (2 ), c = 5. 855 (2 ):A,V = 373. g(2) A3, Z=2, Dc= 3. 89 g/cm3, F(000) = 392, μ= 19. 27 mm-l , A(MoKα) = 0. 71069, Mr = 438. 01, and the convergence factors R = 0. 045, Rw =0. 055 for 341 observed reflections (I>3σ(I)). The anion structure can be viewed as apolymeric single chain consisting of unlimited extended rhombic fragruents of -AgS2W-which are alternately perpendicular to each other. Additionally, influence of di- and tri-valent complex cations on the assembIy of WS2-4 and Ag+ is briefly discussed.展开更多
CONSPECTUS:The microfluidic biochemical/immunoassay systems typically consist of microfluidic chips,fluid driving devices,and detection components.The core of the system is the microfluidic chips based on microfluidic...CONSPECTUS:The microfluidic biochemical/immunoassay systems typically consist of microfluidic chips,fluid driving devices,and detection components.The core of the system is the microfluidic chips based on microfluidic technology,which are typically constructed with nonresponsive materials such as silicon,glass,and rigid plastics,thus requiring complex external air/liquid pumps to manipulate the samples.The external equipment renders the microfluidic systems cumbersome and increases the risk of biosample contamination.展开更多
用毛细管流变仪研究了冲击性能相对优良的共聚聚丙烯 (cPP)与茂金属低密度聚乙烯 (m PE LLD)共混物熔体的流变行为。讨论了共混物的组成、剪切应力和剪切速率对熔体流变行为、熔体粘度的影响。测定了不同cPP及m PE LLD配比的共混物熔体...用毛细管流变仪研究了冲击性能相对优良的共聚聚丙烯 (cPP)与茂金属低密度聚乙烯 (m PE LLD)共混物熔体的流变行为。讨论了共混物的组成、剪切应力和剪切速率对熔体流变行为、熔体粘度的影响。测定了不同cPP及m PE LLD配比的共混物熔体的非牛顿指数。结果表明 :共混物熔体属假塑性流体 ,但其粘度随m PE LLD加入量的增加变化不大。DSC分析及微观形态分析表明 ,m PE LLD的加入使cPP的结晶温度提高 ,具有异相成核作用。m PE LLD对cPP有明显的增韧作用 ,当m PE LLD含量为 15 %时 ,共混物的冲击强度明显提高 ,增幅在 75 %左右 ,而拉伸强度保持率为 85 %以上。展开更多
基金the National Natural Science Foundation of China(No.21404050)the Postgraduate Research&Practice Innovation Program of Jiangsu Province(No.KYCX19_1593).
文摘Cyclic polymers exhibit fascinating crystallization behaviors owing to the absence of chain ends and more compact conformations.In the current simulation,dynamic Monte Carlo simulations were performed to reveal the underlying mechanism of the effect of chain topology and chain length on crystallization of polymer in solutions containing one-dimensional nanofiller.Simulation results suggested that the filled cyclic polymers exhibit higher melting temperature,higher crystallization temperature,and faster crystallization rate than the analogous linear polymers of identical chain length,especially in the systems with relatively short chains.Based on the Thomson-Gibbs equation,we theoretically analyzed the difference in the melting point between the cyclic and linear polymers under different chain lengths,and derived the dependence of the ratio of the melting point of the linear polymers to that of its cyclic analogs on chain length.In addition,it was also observed that the nanofiller can induce the formation of nanohybrid shish-kebab structure during isothermal crystallization of all systems.
基金supports from the National Natural Science Foundation of China(Nos.21890732,21890730 and 21921003)。
文摘Here we use nor-seco-cucurbit[10]uril(ns-CB[10]) based ternary complexation to construct [5]rotaxane,linear supramolecular dynamic rotaxane polymers and cubic 3D supramolecular organic framework.A [5]rotaxane is constructed by ns-CB[10], TMe CB[6] and short linear derivatives of 4,4'-bipyridinium(M2). ns-CB[10], CB[7] and long linear derivatives of 4,4'-bipyridinium(M3) self-assemble into a linear supramolecular dynamic rotaxane polymer. ns-CB[10] and tetracationic tetrahedral monomer selfassemble and form a three-dimensional supramolecular organic framework. The above results demonstrate that ns-CB[10]-based ternary complexation is a versatile platform to build various supramolecular systems.
基金supported by the National Natural Science Foundation of China(Nos.22471185 and 52225311)Science and Technology Program of Suzhou(No.ZXL2022480)+1 种基金Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)Program of Innovative Research Team of Soochow University。
文摘Polydopamine-based melanin-like materials have been widely used in the fields of ultraviolet(UV)shielding,solar desalination and anti-inflammatory treatment owing to their unique physical properties.The well-established synthesis of polydopamine nanoparticles involves the oxidative polymerization of dopamine-derived monomers,resulting in cross-linked nanostructures with high complexity and heterogeneity.Therefore,the controlled synthesis of polydopamine-based melanin-like materials with well-defined structures and predictable properties remains challenging.Herein,we propose a mechanochemical Suzuki polymerization approach for the synthesis of linear melanin-like polymers with tunable physical properties.Compared with polydopamine nanoparticles,the mechanochemical approach offers a more flexible chain-like structure,thereby enhancing its antioxidant performance.Furthermore,this approach also enables the preparation of a melanin-like alternating copolymer that exhibits green fluorescence owing to itsπ-conjugated structure.This study not only offers opportunities for exploring novel synthetic melanin materials,but also provides new insights into the structure-function relationships of polydopamine-based materials.
基金Project supported by the National Natural Science Foundation of China partially by Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Academia Sinica.
文摘A new solvent polymeric membrane (SPM)pH2sensor based on 4,4'-bis (N, N-didecylamino)methyl)azobenzene as neutral carricr has been reported. It has excellent pH response characteristics with the linear response range (1.7—13.2)much wider than that of similar SPM pH sensors reported so far. The sensor has a theoretical Nernstian response of 57.4+0.2V/pH(at 20℃)without super—Nernstian response phenomenon.
文摘The title complex [NH4]n [WAgS4]n crystallizes in the tetragonalspace group I4 with crystallographic parameters: a = b = 7. 994 (2 ), c = 5. 855 (2 ):A,V = 373. g(2) A3, Z=2, Dc= 3. 89 g/cm3, F(000) = 392, μ= 19. 27 mm-l , A(MoKα) = 0. 71069, Mr = 438. 01, and the convergence factors R = 0. 045, Rw =0. 055 for 341 observed reflections (I>3σ(I)). The anion structure can be viewed as apolymeric single chain consisting of unlimited extended rhombic fragruents of -AgS2W-which are alternately perpendicular to each other. Additionally, influence of di- and tri-valent complex cations on the assembIy of WS2-4 and Ag+ is briefly discussed.
基金financially supported by the National Natural Science Foundation of China(51927805,52233001)the Innovation Program of Shanghai Municipal Education Commission(2023ZKZD07).
文摘CONSPECTUS:The microfluidic biochemical/immunoassay systems typically consist of microfluidic chips,fluid driving devices,and detection components.The core of the system is the microfluidic chips based on microfluidic technology,which are typically constructed with nonresponsive materials such as silicon,glass,and rigid plastics,thus requiring complex external air/liquid pumps to manipulate the samples.The external equipment renders the microfluidic systems cumbersome and increases the risk of biosample contamination.
文摘用毛细管流变仪研究了冲击性能相对优良的共聚聚丙烯 (cPP)与茂金属低密度聚乙烯 (m PE LLD)共混物熔体的流变行为。讨论了共混物的组成、剪切应力和剪切速率对熔体流变行为、熔体粘度的影响。测定了不同cPP及m PE LLD配比的共混物熔体的非牛顿指数。结果表明 :共混物熔体属假塑性流体 ,但其粘度随m PE LLD加入量的增加变化不大。DSC分析及微观形态分析表明 ,m PE LLD的加入使cPP的结晶温度提高 ,具有异相成核作用。m PE LLD对cPP有明显的增韧作用 ,当m PE LLD含量为 15 %时 ,共混物的冲击强度明显提高 ,增幅在 75 %左右 ,而拉伸强度保持率为 85 %以上。
