Additives are chemical compounds that are added to concrete during its manufacture to modify one or more of its properties. The first additive used in modern concrete was the accelerator, intended to shorten the time ...Additives are chemical compounds that are added to concrete during its manufacture to modify one or more of its properties. The first additive used in modern concrete was the accelerator, intended to shorten the time during which the material is not capable of supporting stress. Traditionally, accelerators have been made from calcium chloride, but today the trend is to use chloride-free additives to prevent reinforcing steel from corroding and thereby make constructions durable. The objective of this study was to evaluate the effects on the concrete of two types of accelerating admixture, using limestone aggregates, under warm sub-humid climate conditions. The applied methodology consisted of the measurement in the laboratory of some of the main properties of concrete in fresh and hardened states, in samples manufactured both with and without accelerators. The results showed that the accelerator without chloride was less effective than the one based on calcium chloride and that without doses of the accelerator, the effectiveness documented by the manufacturers was achieved.展开更多
Three different types and sizes of coarse aggregate were chosen,and the alternating current（AC） impedance of cement paste samples with and without aggregate was measured at different curing ages.Based on Song’s equ...Three different types and sizes of coarse aggregate were chosen,and the alternating current（AC） impedance of cement paste samples with and without aggregate was measured at different curing ages.Based on Song’s equivalent circuit model,the electrical properties from the AC impedance results were obtained,and the resistance of connected pores RCCP was used to characterize the microstructure of the interfacial transition zone（ITZ）.The results show that the RCCP of concrete sample with aggregate is lower than that of cement paste sample,which indicates that the introduction of aggregate in cement paste makes the ITZ porous.Furthermore,for the same type of aggregate,an increase in particle size leads to a more porous ITZ,which accounts for the “water effect” and a larger aggregate would accumulate a thicker water film around it.In addition,for the same size of aggregate,the physical interaction between aggregate and cement paste is dominant in early age,and the microstructure of the ITZ around limestone aggregate is denser,which mainly depends on its rough surface and high water absorption.However,the microstructures of the ITZ around granite and basalt aggregates are denser in later age,which may be due to their higher chemical activity,and the chemical interaction between them and cement paste resulting in the generation of more hydrates.AC impedance spectroscopy thus proves to be powerful for evaluation of the microstructure of the ITZ.展开更多
文摘Additives are chemical compounds that are added to concrete during its manufacture to modify one or more of its properties. The first additive used in modern concrete was the accelerator, intended to shorten the time during which the material is not capable of supporting stress. Traditionally, accelerators have been made from calcium chloride, but today the trend is to use chloride-free additives to prevent reinforcing steel from corroding and thereby make constructions durable. The objective of this study was to evaluate the effects on the concrete of two types of accelerating admixture, using limestone aggregates, under warm sub-humid climate conditions. The applied methodology consisted of the measurement in the laboratory of some of the main properties of concrete in fresh and hardened states, in samples manufactured both with and without accelerators. The results showed that the accelerator without chloride was less effective than the one based on calcium chloride and that without doses of the accelerator, the effectiveness documented by the manufacturers was achieved.
基金Funded by the National Natural Science Foundations of China(Nos.51108282 and 51478278)the Excellent Youth Scholars of University Science and Technology Research of Hebei Province(No.Y2011111)
文摘Three different types and sizes of coarse aggregate were chosen,and the alternating current（AC） impedance of cement paste samples with and without aggregate was measured at different curing ages.Based on Song’s equivalent circuit model,the electrical properties from the AC impedance results were obtained,and the resistance of connected pores RCCP was used to characterize the microstructure of the interfacial transition zone（ITZ）.The results show that the RCCP of concrete sample with aggregate is lower than that of cement paste sample,which indicates that the introduction of aggregate in cement paste makes the ITZ porous.Furthermore,for the same type of aggregate,an increase in particle size leads to a more porous ITZ,which accounts for the “water effect” and a larger aggregate would accumulate a thicker water film around it.In addition,for the same size of aggregate,the physical interaction between aggregate and cement paste is dominant in early age,and the microstructure of the ITZ around limestone aggregate is denser,which mainly depends on its rough surface and high water absorption.However,the microstructures of the ITZ around granite and basalt aggregates are denser in later age,which may be due to their higher chemical activity,and the chemical interaction between them and cement paste resulting in the generation of more hydrates.AC impedance spectroscopy thus proves to be powerful for evaluation of the microstructure of the ITZ.
