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Isomorphous substitution in CaAl-hydrotalcite to construct high density single-atom catalysts for selective N-Heteroarene hydrogenation
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作者 Jieting He Yu Liang +4 位作者 Binbin Zhao Lei Liu Qian He Dingsheng Wang Jinxiang Dong 《Chinese Journal of Catalysis》 2025年第3期353-362,共10页
Metal oxides as support for constructing precious metal single-atom catalysts hold great promise for a wide range of industrial applications,but achieving a high-loading of thermally stable metal single atoms on such ... Metal oxides as support for constructing precious metal single-atom catalysts hold great promise for a wide range of industrial applications,but achieving a high-loading of thermally stable metal single atoms on such supports has been challenging.Herein,we report an innovative strategy for the fabrication of high-density single-atoms(Rh,Ru,Pd)catalysts on CaAl-layered double hydroxides(CaAl-LDH)via isomorphous substitution.The Rh species have occupied Ca^(2+)vacancies within CaAl-LDH laminate by ion-exchange,facilitating a substantial loading of isolated Rh single-atoms.Such catalysts displayed superior performance in the selective hydrogenation to quinoline,pivotal for liquid organic hydrogen storage,and the universality for the hydrogenation of N-heterocyclic aromatic hydrocarbons was also verified.Combining the experimental results and density functional theory calculations,the pathway of quinoline hydrogenation over Rh1CaAl-LDH was proposed.This synthetic strategy marks a significant advancement in the field of single-atom catalysts,expanding their horizons in green chemical processes. 展开更多
关键词 isomorphous substitution High-loading Single-atom catalyst Selective hydrogenation
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FUNCTIONAL INEQUALITIES, ISOMORPHISMS AND DERIVATIONS ON BANACH ALGEBRAS
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作者 Hamid KHODAEI 《Acta Mathematica Scientia》 2025年第3期855-866,共12页
We analyze existence and uniqueness of solutions for perturbations of a Jensen functional inequality in several variables.Applications in connection with asymptotic behaviors of isomorphisms,derivations and n-Jordan d... We analyze existence and uniqueness of solutions for perturbations of a Jensen functional inequality in several variables.Applications in connection with asymptotic behaviors of isomorphisms,derivations and n-Jordan derivations on Banach algebras are also provided.The results of this paper correct and improve the main results of[12,16,22,23]and improve the corresponding results in[2,9,27],but under weaker assumptions. 展开更多
关键词 functional inequality isomorphISM DERIVATION n-Jordan derivation
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ISOMORPHISMS AND DERIVATIONS IN C*-ALGEBRAS 被引量:4
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作者 Lee Jung-Rye Shin Dong-Yun 《Acta Mathematica Scientia》 SCIE CSCD 2011年第1期309-320,共12页
In this article, we prove the Hyers-Ulam-Rassias stability of the following Cauchy-Jensen functional inequality:‖f (x) + f (y) + 2f (z) + 2f (w)‖ ≤‖ 2f x + y2 + z + w ‖(0.1)This is applied to inv... In this article, we prove the Hyers-Ulam-Rassias stability of the following Cauchy-Jensen functional inequality:‖f (x) + f (y) + 2f (z) + 2f (w)‖ ≤‖ 2f x + y2 + z + w ‖(0.1)This is applied to investigate isomorphisms between C*-algebras, Lie C*-algebras and JC*-algebras, and derivations on C*-algebras, Lie C*-algebras and JC*-algebras, associated with the Cauchy-Jensen functional equation 2f (x + y/2 + z + w) = f(x) + f(y) + 2f(z) + 2f(w). 展开更多
关键词 Jordan-von Neumann type Cauchy-Jensen functional equation C*-algebra isomorphism Lie C*-algebra isomorphism JC*-algebra isomorphism Hyers-Ulam-Rassias stability Cauchy-Jensen functional inequality derivation
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Simulated annealing algorithm for detecting graph isomorphism 被引量:4
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作者 Geng Xiutang Zhang Kai 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2008年第5期1047-1052,共6页
Evolutionary computation techniques have mostly been used to solve various optimization problems, and it is well known that graph isomorphism problem (GIP) is a nondeterministic polynomial problem. A simulated annea... Evolutionary computation techniques have mostly been used to solve various optimization problems, and it is well known that graph isomorphism problem (GIP) is a nondeterministic polynomial problem. A simulated annealing (SA) algorithm for detecting graph isomorphism is proposed, and the proposed SA algorithm is well suited to deal with random graphs with large size. To verify the validity of the proposed SA algorithm, simulations are performed on three pairs of small graphs and four pairs of large random graphs with edge densities 0.5, 0.1, and 0.01, respectively. The simulation results show that the proposed SA algorithm can detect graph isomorphism with a high probability. 展开更多
关键词 graph isomorphism problem simulated annealing algorithm nondeterministic polynomial problem local search.
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Leaching isomorphism rare earths from phosphorite ore by sulfuric acid and phosphoric acid 被引量:2
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作者 Hui-Xin Jin Fu-Zhong Wu +2 位作者 Xiao-Hao Mao Mei-Long Wang Hong-Yan Xie 《Rare Metals》 SCIE EI CAS CSCD 2017年第10期840-850,共11页
Most of the phosphorite deposits in the world contain isomorphism rare earths (RE) which are considerably difficult to be leached into solution in the wet phos- phoric acid process. In this work, a systematic study ... Most of the phosphorite deposits in the world contain isomorphism rare earths (RE) which are considerably difficult to be leached into solution in the wet phos- phoric acid process. In this work, a systematic study of leaching RE using sulfuric acid, phosphoric acid, mixed acid and two-step leaching of phosphoric acid and sulfuric acid was performed. The aims are to illuminate the main factors that inhibit RE leaching and to provide insights into the further enrichment of RE in the wet phosphoric acid solution. The results indicate that H2SO4 is not an effective acid for leaching isomorphism RE from phosphorite ore. The low RE leaching efficiency attributes to the RE cocrystallized and encapsulated by phosphogypsum (PG) as well as the precipitation of RE by RE sulfates or phosphates. High concentration of H3PO4 can enhance the dissolution and diffusion of RE ions. Hence, the optimized leaching mode of improving RE leaching efficiency is to adequately dissolve phosphorite ores in high concentration of H3PO4 solution and then add H2SO4 to crystallize PG. The effect of corystallization or encapsulation of PG on RE can be decreased due to the crystallizing mode of PG in the bulk solution instead of on the interface of solid reactants. RE leaching efficiency can be high up to 65% by the optimized leaching mode. 展开更多
关键词 PHOSPHORITE isomorphISM Rare earths LEACHING Sulfuric acid Phosphoric acid
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The Homomorphism and Isomorphism on Hypergroup 被引量:4
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作者 钟育彬 《Chinese Quarterly Journal of Mathematics》 CSCD 1997年第3期7-14, ,共8页
Basing on the papers from [1] to [4], this paper gives some further research,mainly solves the following problems:(1) It proved that several theorems of subgroup which have been raised to the hypergroup are still true... Basing on the papers from [1] to [4], this paper gives some further research,mainly solves the following problems:(1) It proved that several theorems of subgroup which have been raised to the hypergroup are still true.(2) It proved that the isomorphous relationship of the bottomgroups which guid to the hypergroup can still keep such relationship.(3) It proved that the basic isomorphous Theorem and the homogenous Theorem of the bottomgroup which raise to the hypergroup are still true.(4) It point out that when the isomorphous bottomgroups have been raised to the hypergroup,the conditions which form the isomorphism should be lessened. 展开更多
关键词 HYPERGROUP HOMOMORPHISM isomorphISM regular hypergroup uniform hypergroup
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Characteristics of industrial structure evolution and isomorphism in Central Asia 被引量:1
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作者 KANG Lei LIU Yi 《Journal of Geographical Sciences》 SCIE CSCD 2020年第11期1781-1801,共21页
This study undertakes a systematic examination of characteristics of the spatio-temporal evolution of industrial economies in Central Asia from the perspectives of industrial scale,structural rationality,industrial co... This study undertakes a systematic examination of characteristics of the spatio-temporal evolution of industrial economies in Central Asia from the perspectives of industrial scale,structural rationality,industrial competitiveness,and industrial isomorphism.The results show that industrial structures in Central Asian countries are becoming increasingly advanced,with certain differences among them in the characteristics of this evolution.Kazakhstan has long had a tertiary-secondary-primary industrial pattern,and productive services have played an increasingly prominent role in the development of its tertiary industry.The transformation of the industrial structure in Uzbekistan,from a secondary-tertiary-primary pattern at its independence from the Soviet Union to a tertiary-secondary-primary pattern,is apparent.Tajikistan's industrial structure has also changed significantly in recent times.Its secondary industries shrunk while tertiary industries developed rapidly.In Kyrgyzstan,the ratios of secondary and tertiary industries to total industrial output have fluctuated significantly while considerable progress has been made in the service sector.The industrial structure of Turkmenistan is significantly lower than the other countries,and Turkmenistan is the only country in the Central Asian region which still shows a tertiary-secondary-primary industrial pattern.The feasibility and competitiveness of the industrial structures of these five Central Asian countries have different characteristics.Kazakhstan has structural advantages but lags in competitiveness,Uzbekistan is driven by both structural and competitive advantages,Tajikistan enjoys structural advantages while Kyrgyzstan lags behind in competitiveness,and Turkmenistan has a competitiveness-driven economy.Furthermore,values of the similar coefficient index of the three industrial structures in these countries were mostly above 0.95,the coefficients of the secondary industrial subdivisions in some countries were below 0.85,and those of tertiary industrial subdivisions among most countries were above 0.89,indicating considerable similarities in industrial structure among them.These findings are important in the context of establishing an effective industrial development strategy for the Silk Road Economic Belt,improving international cooperation,and upgrading industrial structures to achieve economic prosperity. 展开更多
关键词 industrial structure EVOLUTION industrial isomorphism shift-share analysis similar coefficient index Central Asian countries
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SMALL INTO ISOMORPHISM FROM(c_0)INTO C(Ω)TYPE 被引量:1
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作者 定光桂 《Acta Mathematica Scientia》 SCIE CSCD 2008年第2期307-314,共8页
If T is an isomorphism of (c0) into C(Ω) (where Ω is a sequentially compact and paracompact space, or a compact metric space in particular), which satisfies the condition ||T||·||T^-1|| ≤ 1 +ε ... If T is an isomorphism of (c0) into C(Ω) (where Ω is a sequentially compact and paracompact space, or a compact metric space in particular), which satisfies the condition ||T||·||T^-1|| ≤ 1 +ε for some ε ∈ (0,1/5), then T/||T|| is close to an isometry with an error less than 9ε. The proof of this article is simple without using the dual space or adjoint operator. 展开更多
关键词 Small into isomorphism ISOMETRY almost isometry
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Similar Vertices and Isomorphism Detection for Planar Kinematic Chains Based on Ameliorated Multi-Order Adjacent Vertex Assignment Sequence 被引量:1
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作者 Liang Sun Zhizheng Ye +2 位作者 Fuwei Lu Rongjiang Cui Chuanyu Wu 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2021年第1期251-265,共15页
Isomorphism detection is fundamental to the synthesis and innovative design of kinematic chains(KCs).The detection can be performed accurately by using the similarity of KCs.However,there are very few works on isomorp... Isomorphism detection is fundamental to the synthesis and innovative design of kinematic chains(KCs).The detection can be performed accurately by using the similarity of KCs.However,there are very few works on isomorphism detection based on the properties of similar vertices.In this paper,an ameliorated multi-order adjacent vertex assignment sequence(AMAVS)method is proposed to seek out similar vertices and identify the isomorphism of the planar KCs.First,the specific definition of AMAVS is described.Through the calculation of the AMAVS,the adjacent vertex value sequence reflecting the uniqueness of the topology features is established.Based on the value sequence,all possible similar vertices,corresponding relations,and isomorphism discrimination can be realized.By checking the topological graph of KCs with a different number of links,the effectiveness and efficiency of the proposed method are verified.Finally,the method is employed to implement the similar vertices and isomorphism detection of all the 9-link 2-D0F(degree of freedom)planar KCs. 展开更多
关键词 Similar vertices isomorphism detection Kinematic chains Topology features AMAVS
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The Isomorphism Theorem of *-Bisimple Type A ω2-Semigroups 被引量:1
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作者 Yu SHANG Limin WANG 《Journal of Mathematical Research with Applications》 CSCD 2013年第2期231-240,共10页
In this paper we study the isomorphisms of two *-bisimple type A ω2-semigroups such that D^* = ^~D) and obtain a criterion for isomorphisms of two such semigroups.
关键词 Type A semigroup *-bisimple ω2-semigroup generalized Bruck-Reilly *-extension isomorphism.
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GPU acceleration of subgraph isomorphism search in large scale graph 被引量:1
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作者 杨博 卢凯 +2 位作者 高颖慧 王小平 徐凯 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第6期2238-2249,共12页
A novel framework for parallel subgraph isomorphism on GPUs is proposed, named GPUSI, which consists of GPU region exploration and GPU subgraph matching. The GPUSI iteratively enumerates subgraph instances and solves ... A novel framework for parallel subgraph isomorphism on GPUs is proposed, named GPUSI, which consists of GPU region exploration and GPU subgraph matching. The GPUSI iteratively enumerates subgraph instances and solves the subgraph isomorphism in a divide-and-conquer fashion. The framework completely relies on the graph traversal, and avoids the explicit join operation. Moreover, in order to improve its performance, a task-queue based method and the virtual-CSR graph structure are used to balance the workload among warps, and warp-centric programming model is used to balance the workload among threads in a warp. The prototype of GPUSI is implemented, and comprehensive experiments of various graph isomorphism operations are carried on diverse large graphs. The experiments clearly demonstrate that GPUSI has good scalability and can achieve speed-up of 1.4–2.6 compared to the state-of-the-art solutions. 展开更多
关键词 parallel graph isomorphism GPU backtrack paradigm
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ADJACENT MARTIX METHOD OF IDENTIFYING ISOMORPHISM TO PLANAR KINEMATIC CHAIN WITH MULTIPLE JOINTS AND HIGHER PAIRS 被引量:2
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作者 SONG Li HUANG Yong CHENG Ling 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2006年第4期605-609,共5页
The adjacent matrix method for identifying isomorphism to planar kinematic chain with multiple joints and higher pairs is presented. The topological invariants of the planar kinematic chain can be calculated and compa... The adjacent matrix method for identifying isomorphism to planar kinematic chain with multiple joints and higher pairs is presented. The topological invariants of the planar kinematic chain can be calculated and compared by adjacent matrix. The quantity of calculation can be reduced effectively using the several divisions of bars and the reconfiguration of the adjacent matrix. As two structural characteristics of adjacent matrix, the number of division and division code are presented. It can be identified that two kinematic chains are isomorphic or not by comparing the structural characteristics of their adjacent matrixes using a method called matching row-to-row. This method may be applied to the planar linkage chain too. So, the methods of identifying isomorphism are unified in the planar kinematic chain that has or hasn't higher pairs with or without multiple joints. And it has some characters such as visual, simple and convenient for processing by computer, and so on. 展开更多
关键词 Planar kinematic chain Higher pair Multiple joint Adjacent matrix Identifying isomorphism
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Ring Isomorphisms and Complete Preservers of Fixed Points for Multipliers
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作者 Ting ZHANG Jinchuan HOU 《Journal of Mathematical Research with Applications》 CSCD 2019年第1期89-100,共12页
Let R_1 and R_2 be two rings with unit I. We give some characterizations of ring homomorphisms and ring isomorphisms between R_1 and R_2 in term of complete preservers of fixed points of multipliers, under some mild a... Let R_1 and R_2 be two rings with unit I. We give some characterizations of ring homomorphisms and ring isomorphisms between R_1 and R_2 in term of complete preservers of fixed points of multipliers, under some mild assumption on R_1. Applications to several kinds of operator algebras such as Banach algebras, nest algebras, matrix algebras and standard operator algebras are presented. 展开更多
关键词 COMPLETE PRESERVER problem BANACH algebra RING isomorphism operator on BANACH space
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Isomorphous Substitution of Metallic Elements for Zeolite Y in the Aqueous Solution
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作者 Tang Yi, Xu Jinsuo and Gao Zi (Department of Chemistry, Fudan University, Shanghai) 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1990年第4期332-340,共9页
The substitutions of Ti, Fe and Zr into zeolite Y in the aqueous solutions of (NH4)2TiF6, (NH4)3ZrF7 and (NH4)3FeF6 were systematically Investigated. It was found that Ai atoms in the framework can be replaced by some... The substitutions of Ti, Fe and Zr into zeolite Y in the aqueous solutions of (NH4)2TiF6, (NH4)3ZrF7 and (NH4)3FeF6 were systematically Investigated. It was found that Ai atoms in the framework can be replaced by some metallic elements and the extent of substitution depends on the M/A1 ratio of the solution. The maximum allowable M/A1 ratio of the aqueous solution Is related with the radius of the M atom and the stability constant of the MFnm- complex. The substituted zeolite samples with crystallinity greater than 80% were characterized by means of XRD, IR, DTA, TPR and NH3-TPD measurements. The incorporation of Ti, Fe and Zr into the zeolite leads to an increase in the unit cell parameter, a lowering of thermal stability and a red shift of the asymmetric stretching frequency. The extent of these changes is apparently related with the ionic radius of the metallic element and the degree of substitution. The results of various characterization methods show that the het-eroatoms are readily Introduced into the zeolite framework by this preparation method. It was also observed that the substitution of heteroatoms may strengthen or weaken the surface acidity of zeolite Y. 展开更多
关键词 isomorphous substitution Zeolite Y CRYSTALLINITY Unit cell parameter
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Constraint of Isomorphous Substitution in Magnetite on Its Catalytic Activity in Heterogeneous Fenton Reaction
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作者 LIANG Xiaoliang ZHONG Yuanhong +4 位作者 HE Zisen TAN Wei HE Hongping YUAN Peng ZHU Jianxi 《矿物学报》 CAS CSCD 北大核心 2013年第S1期51-51,共1页
In nature, iron cations in magnetite are usually isomorphically substituted by divalent (Co, Ni, Zn, Cu, Mn, etc.), trivalent (Al, V, Cr, etc.) and tetravalent (Ti) cations while maintaining the spinel structure. Some... In nature, iron cations in magnetite are usually isomorphically substituted by divalent (Co, Ni, Zn, Cu, Mn, etc.), trivalent (Al, V, Cr, etc.) and tetravalent (Ti) cations while maintaining the spinel structure. Some of the substituting cations, e.g. Cr3+, V3+ and Mn2+, improve the catalytic activity of magnetite in heterogeneous Fenton reaction through the enhancement of hydroxyl radical OH production and the pollutant adsorption. 展开更多
关键词 MAGNETITE isomorphous SUBSTITUTION CATALYSE degradation
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Isomorphous Substitution of Aluminium for Gallium in a Framework Gallophosphate
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作者 CHEN Jie-sheng arid XU Ru-ren (Department of Chemistry, Jilin University, Changchun, 130023) 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1992年第2期65-70,共6页
An aluminium-substituted framework gallophosphate with occluded triethylamine was synthesized hydrothermally. 27Al MAS NMR spectroscopy indicates that only the tetrahedral coordinated gallium atoms in the gallophospha... An aluminium-substituted framework gallophosphate with occluded triethylamine was synthesized hydrothermally. 27Al MAS NMR spectroscopy indicates that only the tetrahedral coordinated gallium atoms in the gallophosphate are substituted by aluminium atoms. The substitution leads to an evident decrease in cell volume of the crystal. The differences between the original gallophosphate and the aluminium-substituted one are also found for the IR spectrum and the thermal property. 展开更多
关键词 isomorphous substitution Aluminogallophosphate FRAMEWORK
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ISOMORPHISMS OF CIRCULANT DIGRAPHS OF DEGREE 3
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作者 HUANG QIONGXIANG DU ZHIHUA Department of Mathematics, Xinjiang University, Urumuqi 830046. Department of Mathematics, Xinjiang Nprmal University Urumuqi 830054 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 1996年第1期115-123,共9页
In this paper, we introduce a new approach to characterize the isomor-phisms of circulant digraphs. In terms of this method, we completely determine theisomorphic classes of circulant digraphs of degree 3. In particul... In this paper, we introduce a new approach to characterize the isomor-phisms of circulant digraphs. In terms of this method, we completely determine theisomorphic classes of circulant digraphs of degree 3. In particular, we characterizethose circulant digraphs of degree 3 which don't satisfy Adam's conjecture. 展开更多
关键词 circulant digraph isomorphISM Adam's conjecture.
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ON THE ISOMETRIC ISOMORPHISM OF PROBABILISTIC METRIC SPACES
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作者 LIU Ming-xue(刘明学) 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 2002年第5期614-617,共4页
There are two kinds of isometric isomorphism in probabilistic metric space theory. The first is that a PM space (E, F) is isometrically isomorphic to another PM space (E', F'), and the second is that a PM spac... There are two kinds of isometric isomorphism in probabilistic metric space theory. The first is that a PM space (E, F) is isometrically isomorphic to another PM space (E', F'), and the second is that a PM space (E, F) is isometrically isomorphic to a generating space of quasi-metric family (E', d(r), r is an element of (0, 1)). This paper establishes the connection between the two kinds of isometric isomorphism. 展开更多
关键词 probabilistic metric space generating space of quasi-metric family isometric isomorphism
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ONSOMELINEARISOMORPHICTHEOREMSFORCERTAINNONSYMMETRICDIFFERENTIALOPERATORSOFSIXTHORDERWITHPARAMETER
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作者 Zhang Xingtai Liu Yingfan Science of College, NUAA29 Yudao Street, Nanjing 210016, P. R. China 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 1996年第1期112-117,共6页
This paper provides several linear isomorphism theorems for certain nonsymmetric differential operators of sixth order under proper topologies about some complex parameters. From these results, one can, to a large ext... This paper provides several linear isomorphism theorems for certain nonsymmetric differential operators of sixth order under proper topologies about some complex parameters. From these results, one can, to a large extent, explain and control the stability of some objects in their moving processes. 展开更多
关键词 differential operator REGULARITY STABILITY linear isomorphism Opial inequality interpolating inequality
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ISOMORPHISMS OF VARIABLE HARDY SPACES ASSOCIATED WITH SCHRÖDINGER OPERATORS
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作者 Junqiang ZHANG Dachun YANG 《Acta Mathematica Scientia》 SCIE CSCD 2021年第1期39-66,共28页
Let L:=-△+V be the Schrodinger operator on R^(n)with n≥3,where V is a non-negative potential satisfying△^(-1)(V)∈L^(∞)(R^(n)).Let w be an L-harmonic function,determined by V,satisfying that there exists a positiv... Let L:=-△+V be the Schrodinger operator on R^(n)with n≥3,where V is a non-negative potential satisfying△^(-1)(V)∈L^(∞)(R^(n)).Let w be an L-harmonic function,determined by V,satisfying that there exists a positive constantδsuch that,for any x∈Rn,0<δ≤w(x)≤1.Assume that p(·):R^(n)→(0,1]is a variable exponent satisfying the globally log-Hölder continuous condition.In this article,the authors show that the mappings HL^(p)(·))(R^(n))■f■wf∈H^(p)(·)(R^(n))and HL^(p(·))(R^(n))■f■(-△)^(1/2)L^(-1/2)(f)∈H^(p(·))(R^(n))are isomorphisms between the variable Hardy spaces HL^(p(·))(R^(n)),associated with L,and the variable Hardy spaces H^(p(·))(R^(n)). 展开更多
关键词 variable Hardy space Schrödinger operator L-harmonic function isomorphISM ATOM
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