In this work, the exp(-φ (ξ )) -expansion method is used for the first time to investigate the exact traveling wave solutions involving parameters of nonlinear evolution equations. When these parameters are taken to...In this work, the exp(-φ (ξ )) -expansion method is used for the first time to investigate the exact traveling wave solutions involving parameters of nonlinear evolution equations. When these parameters are taken to be special values, the solitary wave solutions are derived from the exact traveling wave solutions. The validity and reliability of the method are tested by its applications to Nano-ionic solitons wave’s propagation along microtubules in living cells and Nano-ionic currents of MTs which play an important role in biology.展开更多
In this work, the extended Jacobian elliptic function expansion method is used as the first time to evaluate the exact traveling wave solutions of nonlinear evolution equations. The validity and reliability of the met...In this work, the extended Jacobian elliptic function expansion method is used as the first time to evaluate the exact traveling wave solutions of nonlinear evolution equations. The validity and reliability of the method are tested by its applications to nano-solitons of ionic waves propagation along microtubules in living cells and nano-ionic currents of MTs which play an important role in biology.展开更多
Capacitance for electrostatic adsorption forms primarily within a Debye length of the electrode surface. Capacitive carbon electrodes were derivatized with ionic groups by means of adsorbing a surfactant in order to t...Capacitance for electrostatic adsorption forms primarily within a Debye length of the electrode surface. Capacitive carbon electrodes were derivatized with ionic groups by means of adsorbing a surfactant in order to test the theory that attached ionic groups would exclude co-ions and increase coulombic efficiency without the need for an added charge barrier membrane. It has been discovered that capacitive electrodes surface derivatized with ionic groups become polarized and intrinsically more coulombically efficient.展开更多
Activity coefficients at infinite dilution, γ ∞ i, were calculated for 12 solutes, with organic solutes including linear alcohols (methanol, ethanol, propanol), linear alkanes (heptane, octane), benzene, toluene, cy...Activity coefficients at infinite dilution, γ ∞ i, were calculated for 12 solutes, with organic solutes including linear alcohols (methanol, ethanol, propanol), linear alkanes (heptane, octane), benzene, toluene, cyclohexane, 1, 2-dichloroethane, trichloroethylene, acetonitrile and carbon tetrachloride. The values of γ ∞ i were determined via either thermodynamic or artificial neural network modelling at different temperatures. A comparison between extracted results from these two methods confirmed that experimental and predicted results are roughly the same. The accuracy of predicted results proves this model is fully compatible with a wide range of solutes, and it can readily be used as an alternative to conventional gas-liquid chromatography for the measurements of activity coefficient at infinite dilution.展开更多
As the global textile industry has accelerated its transition to a circular economy,iterative innovation in regenerated cellulose fibers has become a key industry focus.With viscose fiber having been industrialized fo...As the global textile industry has accelerated its transition to a circular economy,iterative innovation in regenerated cellulose fibers has become a key industry focus.With viscose fiber having been industrialized for over a century and lyocell fiber gaining market recognition because of its environmentally friendly process,which is the next regenerated cellulose fiber.Herein,ionic liquids with low vapor pressure,nonflammability,relatively simple recovery,and high dissolution efficiency were used to fabricate regenerated cellulose fibers.The viscose and lyocell properties of the fibers were systematically compared,including microscopic morphology,dyeing behavior,fibrillation resistance,mechanical properties,yarn-forming capacity,and fabric performance.The ionic liquid(IL)fiber exhibited a smooth surface and circular cross-section,with the highest tensile strength,moderate dyeing and fibrillation properties,and similar spinning and weaving performance.This work can provide a reference for the commercial application of regenerated cellulose fibers fabricated from ionic liquid.展开更多
Based on the characteristics of laser-induced surface ignition,energetic photosensitive films show promising potential to meet the ignition requirements of various energetic materials(EMs).In this study,DATNBI/ferric ...Based on the characteristics of laser-induced surface ignition,energetic photosensitive films show promising potential to meet the ignition requirements of various energetic materials(EMs).In this study,DATNBI/ferric alginate(DI/FeA),DI/cobalt alginate(DI/CoA),and DI/nickel alginate(DI/Ni A)films are fabricated by employing sodium alginate(SA)with a three-dimensional network structure as the film matrix,via ionic cross-linking of SA with Fe^(3+),Co^(2+),and Ni^(2+)ions.The study demonstrates that the ionic cross-linking enhances the hydrophobic performance of the films,with the water contact angle increasing from 82.1° to 123.5°.Concurrently,the films'near-infrared(NIR)light absorption improved.Furthermore,transition metal ions facilitate accelerated electron transfer,thereby catalyzing the thermal decomposition of DATNBI.Under 1064 nm laser irradiation,the DI/Fe A film exhibits exceptional combustion performance,with an ignition delay time as low as 76 ms.It successfully acts as an NIR laser ignition medium to initiate the self-sustained combustion of CL-20.This study demonstrates the synergistic realization of enhanced hydrophobicity,improved photosensitivity,and promoted catalytic decomposition through microstructural design of the material,providing new insights for the design of additive-free EMs in laser ignition applications.展开更多
Achieving high-energy density remains a key objective for advanced energy storage systems.However,challenges,such as poor cathode conductivity,anode dendrite formation,polysulfide shuttling,and electrolyte degradation...Achieving high-energy density remains a key objective for advanced energy storage systems.However,challenges,such as poor cathode conductivity,anode dendrite formation,polysulfide shuttling,and electrolyte degradation,continue to limit performance and stability.Molecular and ionic dipole interactions have emerged as an effective strategy to address these issues by regulating ionic transport,modulating solvation structures,optimizing interfacial chemistry,and enhancing charge transfer kinetics.These interactions also stabilize electrode interfaces,suppress side reactions,and mitigate anode corrosion,collectively improving the durability of high-energy batteries.A deeper understanding of these mechanisms is essential to guide the design of next-generation battery materials.Herein,this review summarizes the development,classification,and advantages of dipole interactions in high-energy batteries.The roles of dipoles,including facilitating ion transport,controlling solvation dynamics,stabilizing the electric double layer,optimizing solid electrolyte interphase and cathode–electrolyte interface layers,and inhibiting parasitic reactions—are comprehensively discussed.Finally,perspectives on future research directions are proposed to advance dipole-enabled strategies for high-performance energy storage.This review aims to provide insights into the rational design of dipole-interactive systems and promote the progress of electrochemical energy storage technologies.展开更多
Silica-grafted N-propyl-imidazolium hydrogen sulfate ([Sipim]HSO4) is employed as a recyclable heterogeneous ionic liquid catalyst for the synthesis of 3,4-dihydropyrano[c]-chromenes by the reaction of aromatic aldehy...Silica-grafted N-propyl-imidazolium hydrogen sulfate ([Sipim]HSO4) is employed as a recyclable heterogeneous ionic liquid catalyst for the synthesis of 3,4-dihydropyrano[c]-chromenes by the reaction of aromatic aldehydes, malononitrile and 4-hydroxycoumarin at 100°C under solvent-free conditions. Also, heterogeneous ionic liquid catalyst was used for the synthesis of pyrano[2,3-c]-pyrazoles by the reaction of aromatic aldehydes, malononitrile and 3-methyl-l-phenyl-5-pyrazolone at 110°C under solvent-free conditions. The heterogeneous ionic liquid showed much the same efficiency when used in consecutive reaction runs.展开更多
In this paper, we studied the process of dissociation unimolecular of the evaporation of H+2n+1 hydrogen clusters according to size, using the Rice-Ramsperger-Kassel-Marcus (RRKM) theory. The rate constants k(E) were ...In this paper, we studied the process of dissociation unimolecular of the evaporation of H+2n+1 hydrogen clusters according to size, using the Rice-Ramsperger-Kassel-Marcus (RRKM) theory. The rate constants k(E) were determined with the use of statistical theory of unimolecular reactions using various approximations. In our work, we used the products frequencies instead of transitions frequencies in the calculation of unimolecular dissociation rates obtained by three models RRKM. The agreement between the experimental cross section ratio and calculated rate ratio with direct count approximation seems to be reasonable.展开更多
In this work,we proposed a strategy for the hydrolysis of native corn starch after the treatment of corn starch in an ionic liquid aqueous solution,and it is an awfully“green”and simple means to obtain starch with l...In this work,we proposed a strategy for the hydrolysis of native corn starch after the treatment of corn starch in an ionic liquid aqueous solution,and it is an awfully“green”and simple means to obtain starch with low molecular weight and amorphous state.X-ray diffraction results revealed that the natural starch crystalline region was largely disrupted by ionic liquid owing to the broken intermolecular and intramolecular hydrogen bonds.After hydrolysis,the morphology of starch changed from particles of native corn starch into little pieces,and their molecular weight could be effectively regulated during the hydrolysis process,and also the hydrolyzed starch samples exhibited decreased thermal stability with the extension of hydrolysis time.This work would counsel as a powerful tool for the development of native starch in realistic applications.展开更多
The 1-octyl-3-methylimidazolium chloride, [C8 mim][Cl] ionic liquid(IL) was used as a novel surfactant in n-heptane/water system. The interfacial tensions(IFT) were measured and corresponding variations were investiga...The 1-octyl-3-methylimidazolium chloride, [C8 mim][Cl] ionic liquid(IL) was used as a novel surfactant in n-heptane/water system. The interfacial tensions(IFT) were measured and corresponding variations were investigated. An IFT reduction of 80.8% was appropriate under the IL CMC of about 0.1 mol·L^-1 and stronger effects were achieved when magnetite nanoparticles and salts were present profoundly under alkaline p Hs.The equilibrium IFT data were accurately simulated with the Frumkin adsorption model. Hereafter, the saturated surface concentration, equilibrium constant and interaction parameter were obtained and their variations were demonstrated. Further, emulsion stability and contact angle of oil/water interface over quartz surface were studied. The oil/water emulsion stability was hardly changed with nanoparticles;however, the stability of oil/water + IL emulsions was significantly improved. It was also revealed that the presence of sodium and calcium chloride electrolytes fortifies the IL impact, whereas sodium sulfate weakens. From dynamic IFT data and fitting with kinetic models, it was found that the IL migration toward interface follows the mixed diffusion–kinetic control model. Consequently, the IL diffusion coefficient and the appropriate activation energy were determined.展开更多
Lou soil was modified by amphoteric surfactant in column experiment which was conducted. This study attempts to explore the transport of phenol to unmodified and modified soil and inquire into the effect of concentrat...Lou soil was modified by amphoteric surfactant in column experiment which was conducted. This study attempts to explore the transport of phenol to unmodified and modified soil and inquire into the effect of concentrations, pH, and ionic strength on phenol migration in the soil column. The parameters and breakthrough curves (BTCs) of transport were fitted by using the CXTFIT (version 2.1) model. The result of Cl?’s BTCs for non-reactive by determining the equilibrium model (EM) showed the retardation factor which was smaller than 1. The result of phenol’s BTCs by determining non-equilibrium model (NEM) was shown that the R-value increased while modification ratio increased, and the R was in order of CK (1.337) < 50BS-12 (4.085) < 100BS-12 (7.048). The lower to higher concentration of phenol didn’t affect to CK and 100BS-12 was able to block higher concentration. The effect of pH on transport to CK and 100BS-12 didn’t react and the average pore water velocity was decreased at pH = 4. The decreasing ionic strength of phenol migration on CK and 100BS-12 had effect and the average pore water velocity and retardation factor also decreased. The residual retention in soil was in order of CK < 50BS-12 < 100BS-12, and 100BS-12 could hold the amount of phenol than CK 7.21 times. Thus, amphoteric modified lou soil definitely blocks phenol migration and controls groundwater pollution.展开更多
文摘In this work, the exp(-φ (ξ )) -expansion method is used for the first time to investigate the exact traveling wave solutions involving parameters of nonlinear evolution equations. When these parameters are taken to be special values, the solitary wave solutions are derived from the exact traveling wave solutions. The validity and reliability of the method are tested by its applications to Nano-ionic solitons wave’s propagation along microtubules in living cells and Nano-ionic currents of MTs which play an important role in biology.
文摘In this work, the extended Jacobian elliptic function expansion method is used as the first time to evaluate the exact traveling wave solutions of nonlinear evolution equations. The validity and reliability of the method are tested by its applications to nano-solitons of ionic waves propagation along microtubules in living cells and nano-ionic currents of MTs which play an important role in biology.
文摘Capacitance for electrostatic adsorption forms primarily within a Debye length of the electrode surface. Capacitive carbon electrodes were derivatized with ionic groups by means of adsorbing a surfactant in order to test the theory that attached ionic groups would exclude co-ions and increase coulombic efficiency without the need for an added charge barrier membrane. It has been discovered that capacitive electrodes surface derivatized with ionic groups become polarized and intrinsically more coulombically efficient.
文摘Activity coefficients at infinite dilution, γ ∞ i, were calculated for 12 solutes, with organic solutes including linear alcohols (methanol, ethanol, propanol), linear alkanes (heptane, octane), benzene, toluene, cyclohexane, 1, 2-dichloroethane, trichloroethylene, acetonitrile and carbon tetrachloride. The values of γ ∞ i were determined via either thermodynamic or artificial neural network modelling at different temperatures. A comparison between extracted results from these two methods confirmed that experimental and predicted results are roughly the same. The accuracy of predicted results proves this model is fully compatible with a wide range of solutes, and it can readily be used as an alternative to conventional gas-liquid chromatography for the measurements of activity coefficient at infinite dilution.
基金financially supported by the National Natural Science Foundation of China(Nos.22005226 and 52203124)Center for Carbon Neutral Chemistry,Institute of Chemistry,Chinese Academy of Sciences(No.CCNC-202402)+1 种基金the Basic and Advanced Research Project from Wuhan Science and Technology Bureau(No.2022013988065201)Hubei Integrative Technology and Innovation Center for Advanced Fiberous Materials,project(No.XC2024G3013)。
文摘As the global textile industry has accelerated its transition to a circular economy,iterative innovation in regenerated cellulose fibers has become a key industry focus.With viscose fiber having been industrialized for over a century and lyocell fiber gaining market recognition because of its environmentally friendly process,which is the next regenerated cellulose fiber.Herein,ionic liquids with low vapor pressure,nonflammability,relatively simple recovery,and high dissolution efficiency were used to fabricate regenerated cellulose fibers.The viscose and lyocell properties of the fibers were systematically compared,including microscopic morphology,dyeing behavior,fibrillation resistance,mechanical properties,yarn-forming capacity,and fabric performance.The ionic liquid(IL)fiber exhibited a smooth surface and circular cross-section,with the highest tensile strength,moderate dyeing and fibrillation properties,and similar spinning and weaving performance.This work can provide a reference for the commercial application of regenerated cellulose fibers fabricated from ionic liquid.
基金supported by Research Fund of SWUST for PhD(Grant No.22zx7175)Sichuan Science and Technology Program(Grant No.2024NSFSC1097)。
文摘Based on the characteristics of laser-induced surface ignition,energetic photosensitive films show promising potential to meet the ignition requirements of various energetic materials(EMs).In this study,DATNBI/ferric alginate(DI/FeA),DI/cobalt alginate(DI/CoA),and DI/nickel alginate(DI/Ni A)films are fabricated by employing sodium alginate(SA)with a three-dimensional network structure as the film matrix,via ionic cross-linking of SA with Fe^(3+),Co^(2+),and Ni^(2+)ions.The study demonstrates that the ionic cross-linking enhances the hydrophobic performance of the films,with the water contact angle increasing from 82.1° to 123.5°.Concurrently,the films'near-infrared(NIR)light absorption improved.Furthermore,transition metal ions facilitate accelerated electron transfer,thereby catalyzing the thermal decomposition of DATNBI.Under 1064 nm laser irradiation,the DI/Fe A film exhibits exceptional combustion performance,with an ignition delay time as low as 76 ms.It successfully acts as an NIR laser ignition medium to initiate the self-sustained combustion of CL-20.This study demonstrates the synergistic realization of enhanced hydrophobicity,improved photosensitivity,and promoted catalytic decomposition through microstructural design of the material,providing new insights for the design of additive-free EMs in laser ignition applications.
基金supported by the introduction of Talent Research Fund in Nanjing Institute of Technology(YKJ202204)the National Natural Science Foundation of China(52401282 and 52300206)the Natural Science Foundation of Jiangsu Province(BK20230701 and BK20230705).
文摘Achieving high-energy density remains a key objective for advanced energy storage systems.However,challenges,such as poor cathode conductivity,anode dendrite formation,polysulfide shuttling,and electrolyte degradation,continue to limit performance and stability.Molecular and ionic dipole interactions have emerged as an effective strategy to address these issues by regulating ionic transport,modulating solvation structures,optimizing interfacial chemistry,and enhancing charge transfer kinetics.These interactions also stabilize electrode interfaces,suppress side reactions,and mitigate anode corrosion,collectively improving the durability of high-energy batteries.A deeper understanding of these mechanisms is essential to guide the design of next-generation battery materials.Herein,this review summarizes the development,classification,and advantages of dipole interactions in high-energy batteries.The roles of dipoles,including facilitating ion transport,controlling solvation dynamics,stabilizing the electric double layer,optimizing solid electrolyte interphase and cathode–electrolyte interface layers,and inhibiting parasitic reactions—are comprehensively discussed.Finally,perspectives on future research directions are proposed to advance dipole-enabled strategies for high-performance energy storage.This review aims to provide insights into the rational design of dipole-interactive systems and promote the progress of electrochemical energy storage technologies.
文摘Silica-grafted N-propyl-imidazolium hydrogen sulfate ([Sipim]HSO4) is employed as a recyclable heterogeneous ionic liquid catalyst for the synthesis of 3,4-dihydropyrano[c]-chromenes by the reaction of aromatic aldehydes, malononitrile and 4-hydroxycoumarin at 100°C under solvent-free conditions. Also, heterogeneous ionic liquid catalyst was used for the synthesis of pyrano[2,3-c]-pyrazoles by the reaction of aromatic aldehydes, malononitrile and 3-methyl-l-phenyl-5-pyrazolone at 110°C under solvent-free conditions. The heterogeneous ionic liquid showed much the same efficiency when used in consecutive reaction runs.
文摘In this paper, we studied the process of dissociation unimolecular of the evaporation of H+2n+1 hydrogen clusters according to size, using the Rice-Ramsperger-Kassel-Marcus (RRKM) theory. The rate constants k(E) were determined with the use of statistical theory of unimolecular reactions using various approximations. In our work, we used the products frequencies instead of transitions frequencies in the calculation of unimolecular dissociation rates obtained by three models RRKM. The agreement between the experimental cross section ratio and calculated rate ratio with direct count approximation seems to be reasonable.
文摘In this work,we proposed a strategy for the hydrolysis of native corn starch after the treatment of corn starch in an ionic liquid aqueous solution,and it is an awfully“green”and simple means to obtain starch with low molecular weight and amorphous state.X-ray diffraction results revealed that the natural starch crystalline region was largely disrupted by ionic liquid owing to the broken intermolecular and intramolecular hydrogen bonds.After hydrolysis,the morphology of starch changed from particles of native corn starch into little pieces,and their molecular weight could be effectively regulated during the hydrolysis process,and also the hydrolyzed starch samples exhibited decreased thermal stability with the extension of hydrolysis time.This work would counsel as a powerful tool for the development of native starch in realistic applications.
基金financial support by the Bu-Ali Sina University to carry out this research.
文摘The 1-octyl-3-methylimidazolium chloride, [C8 mim][Cl] ionic liquid(IL) was used as a novel surfactant in n-heptane/water system. The interfacial tensions(IFT) were measured and corresponding variations were investigated. An IFT reduction of 80.8% was appropriate under the IL CMC of about 0.1 mol·L^-1 and stronger effects were achieved when magnetite nanoparticles and salts were present profoundly under alkaline p Hs.The equilibrium IFT data were accurately simulated with the Frumkin adsorption model. Hereafter, the saturated surface concentration, equilibrium constant and interaction parameter were obtained and their variations were demonstrated. Further, emulsion stability and contact angle of oil/water interface over quartz surface were studied. The oil/water emulsion stability was hardly changed with nanoparticles;however, the stability of oil/water + IL emulsions was significantly improved. It was also revealed that the presence of sodium and calcium chloride electrolytes fortifies the IL impact, whereas sodium sulfate weakens. From dynamic IFT data and fitting with kinetic models, it was found that the IL migration toward interface follows the mixed diffusion–kinetic control model. Consequently, the IL diffusion coefficient and the appropriate activation energy were determined.
文摘Lou soil was modified by amphoteric surfactant in column experiment which was conducted. This study attempts to explore the transport of phenol to unmodified and modified soil and inquire into the effect of concentrations, pH, and ionic strength on phenol migration in the soil column. The parameters and breakthrough curves (BTCs) of transport were fitted by using the CXTFIT (version 2.1) model. The result of Cl?’s BTCs for non-reactive by determining the equilibrium model (EM) showed the retardation factor which was smaller than 1. The result of phenol’s BTCs by determining non-equilibrium model (NEM) was shown that the R-value increased while modification ratio increased, and the R was in order of CK (1.337) < 50BS-12 (4.085) < 100BS-12 (7.048). The lower to higher concentration of phenol didn’t affect to CK and 100BS-12 was able to block higher concentration. The effect of pH on transport to CK and 100BS-12 didn’t react and the average pore water velocity was decreased at pH = 4. The decreasing ionic strength of phenol migration on CK and 100BS-12 had effect and the average pore water velocity and retardation factor also decreased. The residual retention in soil was in order of CK < 50BS-12 < 100BS-12, and 100BS-12 could hold the amount of phenol than CK 7.21 times. Thus, amphoteric modified lou soil definitely blocks phenol migration and controls groundwater pollution.
