The difficulty in fabricating a multifaceted composite heterojunction system based on Cd_(x) Zn_(1-x) S limits the enhancement of photocatalytic performance.In the present scrutiny,novel ZnO/Cd_(x) Zn_(1-x) S/CdS com-...The difficulty in fabricating a multifaceted composite heterojunction system based on Cd_(x) Zn_(1-x) S limits the enhancement of photocatalytic performance.In the present scrutiny,novel ZnO/Cd_(x) Zn_(1-x) S/CdS com-posite heterojunctions are successfully prepared by the alkaline dissolution etching method.The internal electric field at the interface of I-type and Z-scheme heterojunction improved the effective charge sepa-ration.The ZC 8 sample exhibits excellent photocatalytic performance and the H2 production efficiency is 15.67 mmol g^(−1) h^(−1) with good stability up to 82.9%in 24-hour cycles.The performance of CH_(4) and CO capacity in the CO_(2) RR process is 3.47μmol g^(−1) h^(−1) and 23.5μmol g^(−1) h^(−1),respectively.The photogener-ated accelerated charge transport is then examined in detail by in situ X-ray photoelectron spectroscopy(ISXPS)and density functional theory(DFT)calculations.This work presents a new idea for the synthe-sis of Cd_(x) Zn_(1-x) S solid-solution-based materials and provides a solid reference for the detailed mechanism regarding the electric field at the heterojunction interface.展开更多
The paper develops and employs analytical-numerical solution method for the study of the time-harmonic dynamic stress field in the system consisting of the hollow cylinder and surrounding elastic medium under the non-...The paper develops and employs analytical-numerical solution method for the study of the time-harmonic dynamic stress field in the system consisting of the hollow cylinder and surrounding elastic medium under the non-axisymmetric forced vibration of this system.It is assumed that in the interior of the hollow cylinder the point-located with respect to the cylinder axis,non-axisymmetric with respect to the circumferential direction and uniformly distributed time-harmonic forces act.Corresponding boundary value problem is solved by employing of the exponential Fourier transformation with respect to the axial coordinate and by employing of the Fourier series expansion of these transformations.Numerical results on the frequency response of the interface normal stresses are presented and discussed.展开更多
When the size of an inclusion shrinks to nanometers, interface energy plays an important role in the deformation around it. In the present paper, we consider the effect of interface energy on the elastic fields near a...When the size of an inclusion shrinks to nanometers, interface energy plays an important role in the deformation around it. In the present paper, we consider the effect of interface energy on the elastic fields near a spheroidal nanoinclusion embedded in an elastic medium on the basis of surface elasticity theory. Using Boussinesq-Sadowsky potential function method, we obtain the deformation field near the inclusion subjected to a uniformly uniaxial loading at infinity. The results show that the elastic fields near the nano-inclusion depend strongly on the interface properties, the size and shape of inclusion. These new characteristics may be helpful to understand various relevant mechanical performances of nanosized inhomogeneities.展开更多
The oil-pressboard insulation is a typical composite insulation system widely used in the design and manufactory of large power apparatus. The implement of oil-pressboard insulation may lead to surface electrification...The oil-pressboard insulation is a typical composite insulation system widely used in the design and manufactory of large power apparatus. The implement of oil-pressboard insulation may lead to surface electrification and discharge at the interface under certain condition. It is of significant importance to take an insight into the phenomenon occurring at the interface. Through experiment, the pressboard is found as a porous material. The interface changes abruptly from bulk pressboard to the bulk oil as a result of the porous structure. A new model is proposed which divides the interface into bulk oil region, transition region, and bulk pressboard region. The width of the transition region is decided according to the microtome figure. The effective permittivity of the transition region is calculated using a new model based on fractal theory. The model is validated and compared with previous calculation model. The effect of the existence of transition region on the electric field distribution is discussed.展开更多
Z-scheme photocatalytic system has been regarded as a popular field of research in photoelectrochemical(PEC)water splitting.Among the many obstacles facing a Z-scheme photocatalytic system,the analysis methods of inte...Z-scheme photocatalytic system has been regarded as a popular field of research in photoelectrochemical(PEC)water splitting.Among the many obstacles facing a Z-scheme photocatalytic system,the analysis methods of interfacial Z-scheme charge transfer still remain a significant challenge.Hence,in this study,CdS/Ti-Fe_(2)O_(3)heterojunction photoanodes are elaborately designed to explore the charge-transfer behavior in PEC water splitting.In this study,photophysical measurements,including the Kelvin probe measurement,surface photovoltage spectroscopy(SPV),and transient photovoltage spectroscopy(TPV),are used to monitor the migration behavior of photogenerated charges at the interface electric field of CdS/Ti-Fe_(2)O_(3)Z-scheme heterojunction photoanodes.The Kelvin probe and SPV measurements demonstrate that CdS/Ti-Fe_(2)O_(3)interfacial driving force favors the rapid transfer of photoexcited electrons to CdS.The double-beam strategy based on TPV indicates that more electrons of Ti-Fe_(2)O_(3)are combined with the holes of CdS owing to the intensive interface electric field.The results of these measurements successfully prove the Z-scheme migration mechanism of CdS/Ti-Fe_(2)O_(3)photoanodes.Benefiting from the desirable charge transfer at the interface electric field,CdS/Ti-Fe_(2)O_(3)photoanodes exhibit superior photocatalytic oxygen evolution reaction performance compared with that of pure Ti-Fe_(2)O_(3).The photocurrent density of the 25CdS/Ti-Fe_(2)O_(3)photoanode reaches 1.94 mA/cm^(2) at 1.23 V versus reversible hydrogen electrode without excess cocatalyst,and it is two times higher than that of pure Ti-Fe_(2)O_(3)photoanode.Therefore,an outstanding strategy is provided in this study to prove the Z-scheme charge-transfer mechanism of photocatalytic systems in PEC water splitting.展开更多
In order to study the failure process of an anchorage structure and the evolution law of the body＇s defor- mation field, anchor push-out tests were carried out based on digital speckle correlation methods （DSCM）. T...In order to study the failure process of an anchorage structure and the evolution law of the body＇s defor- mation field, anchor push-out tests were carried out based on digital speckle correlation methods （DSCM）. The stress distribution of the anchorage interface was investigated using the particle flow numerical simulation method. The results indicate that there are three stages in the deformation and fail- ure process of an anchorage structure： elastic bonding stage, a de-bonding stage and a failure stage. The stress distribution in the interface controls the stability of the structure. In the elastic bonding stage, the shear stress peak point of the interface is close to the loading end, and the displacement field gradually develops into a ＂V＂ shape, in the de-bonding stage, there is a shear stress plateau in the center of the anchorage section, and shear strain localization begins to form in the deformation field. In the failure stage, the bonding of the interface fails rapidly and the shear stress peak point moves to the anchorage free end. The anchorage structure moves integrally along the macro-cracl~ The de-bonding stage is a research focus in the deformation and failure process of an anchorage structure, and plays an important guiding role in roadway support design and prediction of the stability of the surrounding rock.展开更多
In order to explore the spatial variability of soil moisture near the interface of high/low stands, an experiment was conducted at Luancheng Experimental Station, Chinese Academy of Sciences, Hebei, China from May to ...In order to explore the spatial variability of soil moisture near the interface of high/low stands, an experiment was conducted at Luancheng Experimental Station, Chinese Academy of Sciences, Hebei, China from May to June, 1996. By analyzing the observed soil moisture data, it shows that there exists an obvious turning point of soil moisture pattern from one side of the interface to another. The effect of drier soil closer to the interface in winter wheat field is obvious, which is mainly due to the better ventilation condition near the interface in winter wheat filed than in alfalfa field. The irrigation in large scale is one of the most important factors to control the spatial pattern of soil moisture while the small scale human disturbing activity, such as the stealing event occurred during our observation, does not change the spatial pattern of soil moisture obviously. Latent heat, calculated by Bowen ratio method based on our observed micrometeorological data, is shown larger in alfalfa than that in winter wheat both at earring stage from May 8 to 10 and mature stage from June 11 to 14. This fact, together with the larger ground temperature and a little bit larger wind velocity in lower layer, explains that the soil is drier in alfalfa than in winter wheat from May 8 to 10. While for the period from June 11 to 14, irrigation's effect changes the natural interrelationship of soil moisture with meteorology and ground temperature.展开更多
The differences in Zn crystal plane kinetics can lead to non-uniform deposition,promoting dendrite growth and side reactions,especially under high deposition capacities.Fast kinetics can also cause anion depletion on ...The differences in Zn crystal plane kinetics can lead to non-uniform deposition,promoting dendrite growth and side reactions,especially under high deposition capacities.Fast kinetics can also cause anion depletion on the zinc anode surface,leading to uneven electric field distribution and worsening these issues.Inducing preferred electrodeposition of the Zn(101)crystal plane can ensure dense epitaxial growth and achieve fast reaction kinetics.However,its highly reactive and wave-like arrangement will also lead to higher hydrogen evolution activity and cause uneven electric field distribution,accelerating side reactions and dendrite growth.This study utilizes the adsorption ability of 2-mercaptoethanesulfonate(MES)anion on the zinc anode surface to optimize the interfacial concentration and electric fields.It effectively reduces the presence of H_(2)O on the zinc anode surface,minimizing side reactions and inducing oriented growth of Zn(101)crystal plane.Furthermore,a high concentration of MES anions at the interface can effectively prevent the space charge effect caused by the depletion of SO_(4)^(2-)anions,thereby inhibiting dendrite growth caused by the local electric field.This strategy enables Zn//Zn symmetric cells to achieve 3000 h of cycle life and demonstrates excellent performance in high mass-loading,low N/P ratio Zn//VO_(2)full cells.展开更多
A two-dimensional analytical model of double-gate（DG） tunneling field-effect transistors（TFETs） with interface trapped charges is proposed in this paper. The influence of the channel mobile charges on the potentia...A two-dimensional analytical model of double-gate（DG） tunneling field-effect transistors（TFETs） with interface trapped charges is proposed in this paper. The influence of the channel mobile charges on the potential profile is also taken into account in order to improve the accuracy of the models. On the basis of potential profile,the electric field is derived and the expression for the drain current is obtained by integrating the BTBT generation rate. The model can be used to study the impact of interface trapped charges on the surface potential, the shortest tunneling length, the drain current and the threshold voltage for varying interface trapped charge densities, length of damaged region as well as the structural parameters of the DG TFET and can also be utilized to design the charge trapped memory devices based on TFET. The biggest advantage of this model is that it is more accurate,and in its expression there are no fitting parameters with small calculating amount. Very good agreements for both the potential, drain current and threshold voltage are observed between the model calculations and the simulated results.展开更多
基金financially supported by the National Key Re-search and Development Program of China[No.2022YFF1202500,2022YFF1202502]the National Natural Science Foundation of China[62071459]+1 种基金the Subject arrangement Foundation of Shen-zhen[No.JCYJ20180507182057026]the International Science and Technology Cooperation Project of Bingtuan[No.2022BC008]。
文摘The difficulty in fabricating a multifaceted composite heterojunction system based on Cd_(x) Zn_(1-x) S limits the enhancement of photocatalytic performance.In the present scrutiny,novel ZnO/Cd_(x) Zn_(1-x) S/CdS com-posite heterojunctions are successfully prepared by the alkaline dissolution etching method.The internal electric field at the interface of I-type and Z-scheme heterojunction improved the effective charge sepa-ration.The ZC 8 sample exhibits excellent photocatalytic performance and the H2 production efficiency is 15.67 mmol g^(−1) h^(−1) with good stability up to 82.9%in 24-hour cycles.The performance of CH_(4) and CO capacity in the CO_(2) RR process is 3.47μmol g^(−1) h^(−1) and 23.5μmol g^(−1) h^(−1),respectively.The photogener-ated accelerated charge transport is then examined in detail by in situ X-ray photoelectron spectroscopy(ISXPS)and density functional theory(DFT)calculations.This work presents a new idea for the synthe-sis of Cd_(x) Zn_(1-x) S solid-solution-based materials and provides a solid reference for the detailed mechanism regarding the electric field at the heterojunction interface.
文摘The paper develops and employs analytical-numerical solution method for the study of the time-harmonic dynamic stress field in the system consisting of the hollow cylinder and surrounding elastic medium under the non-axisymmetric forced vibration of this system.It is assumed that in the interior of the hollow cylinder the point-located with respect to the cylinder axis,non-axisymmetric with respect to the circumferential direction and uniformly distributed time-harmonic forces act.Corresponding boundary value problem is solved by employing of the exponential Fourier transformation with respect to the axial coordinate and by employing of the Fourier series expansion of these transformations.Numerical results on the frequency response of the interface normal stresses are presented and discussed.
基金supported by the National Natural Science Foundation of China (10672129 and 10602042)973 program (2007CB707702)NCET program of MOE.
文摘When the size of an inclusion shrinks to nanometers, interface energy plays an important role in the deformation around it. In the present paper, we consider the effect of interface energy on the elastic fields near a spheroidal nanoinclusion embedded in an elastic medium on the basis of surface elasticity theory. Using Boussinesq-Sadowsky potential function method, we obtain the deformation field near the inclusion subjected to a uniformly uniaxial loading at infinity. The results show that the elastic fields near the nano-inclusion depend strongly on the interface properties, the size and shape of inclusion. These new characteristics may be helpful to understand various relevant mechanical performances of nanosized inhomogeneities.
基金Project(2009CB724504)supported by the National Basic Research Program of China
文摘The oil-pressboard insulation is a typical composite insulation system widely used in the design and manufactory of large power apparatus. The implement of oil-pressboard insulation may lead to surface electrification and discharge at the interface under certain condition. It is of significant importance to take an insight into the phenomenon occurring at the interface. Through experiment, the pressboard is found as a porous material. The interface changes abruptly from bulk pressboard to the bulk oil as a result of the porous structure. A new model is proposed which divides the interface into bulk oil region, transition region, and bulk pressboard region. The width of the transition region is decided according to the microtome figure. The effective permittivity of the transition region is calculated using a new model based on fractal theory. The model is validated and compared with previous calculation model. The effect of the existence of transition region on the electric field distribution is discussed.
文摘Z-scheme photocatalytic system has been regarded as a popular field of research in photoelectrochemical(PEC)water splitting.Among the many obstacles facing a Z-scheme photocatalytic system,the analysis methods of interfacial Z-scheme charge transfer still remain a significant challenge.Hence,in this study,CdS/Ti-Fe_(2)O_(3)heterojunction photoanodes are elaborately designed to explore the charge-transfer behavior in PEC water splitting.In this study,photophysical measurements,including the Kelvin probe measurement,surface photovoltage spectroscopy(SPV),and transient photovoltage spectroscopy(TPV),are used to monitor the migration behavior of photogenerated charges at the interface electric field of CdS/Ti-Fe_(2)O_(3)Z-scheme heterojunction photoanodes.The Kelvin probe and SPV measurements demonstrate that CdS/Ti-Fe_(2)O_(3)interfacial driving force favors the rapid transfer of photoexcited electrons to CdS.The double-beam strategy based on TPV indicates that more electrons of Ti-Fe_(2)O_(3)are combined with the holes of CdS owing to the intensive interface electric field.The results of these measurements successfully prove the Z-scheme migration mechanism of CdS/Ti-Fe_(2)O_(3)photoanodes.Benefiting from the desirable charge transfer at the interface electric field,CdS/Ti-Fe_(2)O_(3)photoanodes exhibit superior photocatalytic oxygen evolution reaction performance compared with that of pure Ti-Fe_(2)O_(3).The photocurrent density of the 25CdS/Ti-Fe_(2)O_(3)photoanode reaches 1.94 mA/cm^(2) at 1.23 V versus reversible hydrogen electrode without excess cocatalyst,and it is two times higher than that of pure Ti-Fe_(2)O_(3)photoanode.Therefore,an outstanding strategy is provided in this study to prove the Z-scheme charge-transfer mechanism of photocatalytic systems in PEC water splitting.
基金financially supported by the National Key Basic Research Program of China (No.2010CB226805)the National Natural Science Foundation of China (Nos.51474136 and 51474013)+1 种基金the Opening Project Fund of State Key Laboratory of Mining Disaster Prevention and Control Co-founded by Shandong Province and the Ministry of Science and Technology (No.MDPC2013KF06)the Research Award Fund for the Excellent Youth of Shandong University of Science and Technology (No.2011KYJQ106)
文摘In order to study the failure process of an anchorage structure and the evolution law of the body＇s defor- mation field, anchor push-out tests were carried out based on digital speckle correlation methods （DSCM）. The stress distribution of the anchorage interface was investigated using the particle flow numerical simulation method. The results indicate that there are three stages in the deformation and fail- ure process of an anchorage structure： elastic bonding stage, a de-bonding stage and a failure stage. The stress distribution in the interface controls the stability of the structure. In the elastic bonding stage, the shear stress peak point of the interface is close to the loading end, and the displacement field gradually develops into a ＂V＂ shape, in the de-bonding stage, there is a shear stress plateau in the center of the anchorage section, and shear strain localization begins to form in the deformation field. In the failure stage, the bonding of the interface fails rapidly and the shear stress peak point moves to the anchorage free end. The anchorage structure moves integrally along the macro-cracl~ The de-bonding stage is a research focus in the deformation and failure process of an anchorage structure, and plays an important guiding role in roadway support design and prediction of the stability of the surrounding rock.
基金Projects supported by the National Natural Science Foundation of China (Nos. 49471016, 49771019 and 49890330)
文摘In order to explore the spatial variability of soil moisture near the interface of high/low stands, an experiment was conducted at Luancheng Experimental Station, Chinese Academy of Sciences, Hebei, China from May to June, 1996. By analyzing the observed soil moisture data, it shows that there exists an obvious turning point of soil moisture pattern from one side of the interface to another. The effect of drier soil closer to the interface in winter wheat field is obvious, which is mainly due to the better ventilation condition near the interface in winter wheat filed than in alfalfa field. The irrigation in large scale is one of the most important factors to control the spatial pattern of soil moisture while the small scale human disturbing activity, such as the stealing event occurred during our observation, does not change the spatial pattern of soil moisture obviously. Latent heat, calculated by Bowen ratio method based on our observed micrometeorological data, is shown larger in alfalfa than that in winter wheat both at earring stage from May 8 to 10 and mature stage from June 11 to 14. This fact, together with the larger ground temperature and a little bit larger wind velocity in lower layer, explains that the soil is drier in alfalfa than in winter wheat from May 8 to 10. While for the period from June 11 to 14, irrigation's effect changes the natural interrelationship of soil moisture with meteorology and ground temperature.
基金supported by the National Natural Science Foundation of China(Nos.22325802 and U22A20417)the Natural Science Foundation of Guangdong Province(No.2024A1515012535)+2 种基金the Science and Technology Program of Guangzhou(No.2023B03J1281)the Guangdong Basic and Applied Basic Research Foundation(No.2023B1515120005)the State Key Laboratory of Catalysis(No.2024SKL-A-009).
文摘The differences in Zn crystal plane kinetics can lead to non-uniform deposition,promoting dendrite growth and side reactions,especially under high deposition capacities.Fast kinetics can also cause anion depletion on the zinc anode surface,leading to uneven electric field distribution and worsening these issues.Inducing preferred electrodeposition of the Zn(101)crystal plane can ensure dense epitaxial growth and achieve fast reaction kinetics.However,its highly reactive and wave-like arrangement will also lead to higher hydrogen evolution activity and cause uneven electric field distribution,accelerating side reactions and dendrite growth.This study utilizes the adsorption ability of 2-mercaptoethanesulfonate(MES)anion on the zinc anode surface to optimize the interfacial concentration and electric fields.It effectively reduces the presence of H_(2)O on the zinc anode surface,minimizing side reactions and inducing oriented growth of Zn(101)crystal plane.Furthermore,a high concentration of MES anions at the interface can effectively prevent the space charge effect caused by the depletion of SO_(4)^(2-)anions,thereby inhibiting dendrite growth caused by the local electric field.This strategy enables Zn//Zn symmetric cells to achieve 3000 h of cycle life and demonstrates excellent performance in high mass-loading,low N/P ratio Zn//VO_(2)full cells.
基金Project supported by the National Natural Science Foundation of China(No.61376106)the University Natural Science Research Key Project of Anhui Province(No.KJ2016A169)the Introduced Talents Project of Anhui Science and Technology University
文摘A two-dimensional analytical model of double-gate（DG） tunneling field-effect transistors（TFETs） with interface trapped charges is proposed in this paper. The influence of the channel mobile charges on the potential profile is also taken into account in order to improve the accuracy of the models. On the basis of potential profile,the electric field is derived and the expression for the drain current is obtained by integrating the BTBT generation rate. The model can be used to study the impact of interface trapped charges on the surface potential, the shortest tunneling length, the drain current and the threshold voltage for varying interface trapped charge densities, length of damaged region as well as the structural parameters of the DG TFET and can also be utilized to design the charge trapped memory devices based on TFET. The biggest advantage of this model is that it is more accurate,and in its expression there are no fitting parameters with small calculating amount. Very good agreements for both the potential, drain current and threshold voltage are observed between the model calculations and the simulated results.
