This study leverages machine learning to perform high-throughput computational screening of n-hexane cracking initiators.Artificial neural networks are applied to predict the chemical performance of initiators,using s...This study leverages machine learning to perform high-throughput computational screening of n-hexane cracking initiators.Artificial neural networks are applied to predict the chemical performance of initiators,using simulated pyrolysis data as the training dataset.Various feature extraction methods are utilized,and five neural network architectures are developed to predict the co-cracking product distribution based on molecular structures.High-throughput screening of 12946 molecules outside the training dataset identifies the top 10 initiators for each target product—ethylene,propylene,and butadiene.The relative error between predicted and simulated values is less than 7%.Additionally,reaction pathway analysis elucidates the mechanisms by which initiators influence the distribution of cracking products.The proposed framework provides a practical and efficient approach for the rapid identification and evaluation of high-performance cracking initiators.展开更多
In recent years,(0001)twist grain boundaries(BTGBs)located in primary α grain clusters were identified as fatigue crack nucleation sites in different Ti alloys.In the present study,crack initiation was investigated i...In recent years,(0001)twist grain boundaries(BTGBs)located in primary α grain clusters were identified as fatigue crack nucleation sites in different Ti alloys.In the present study,crack initiation was investigated in a bimodal Ti-5Al-4 V alloy subjected to low-cycle fatigue and dwell-fatigue loadings at room temperature.The low fraction of primary α grains was not associated with a lack of sensitivity to BTGB cracking.Transmission electron microscopy and electron back-scattered diffraction were used to characterize BTGBs in the initial microstructure.The fatigue mechanisms were then analyzed with a focus on dislocation activity.α_(p) grains adjacent to cracked BTGBs contained a high dislocation density.It was primarily composed of planar slip bands of dislocations.In addition,<c+a>dislocations were noticed in the vicinity of cracked BTGBs.They supposedly pertain to crack tip plasticity during growth,and no evidence of a role of an incoming slip event in crack nucleation was obtained.Also,basal slip bands extending across adjacent grains were found to emerge from BTGBs.This feature provides an easier path for crack extension when growth along the grain boundary becomes difficult owing to a deviation from the basal plane.Atom probe tomography analyses evidenced V and Fe segregation at a grain boundary with a significant deviation from the BTGB configuration.This suggests a possible contribution of local solute segregation to the high cracking resistance of general α_(p)/α_(p) grain boundaries.This work provides new insights into the mechanisms involved in cracking of BTGB in Ti alloys subjected to cyclic loadings.展开更多
Mg-Li alloys hold significant potential for applications in aerospace,automotive manufacturing,military weaponry,and biomedical implants,due to their excellent recyclability,high specific strength,biocompatibility,and...Mg-Li alloys hold significant potential for applications in aerospace,automotive manufacturing,military weaponry,and biomedical implants,due to their excellent recyclability,high specific strength,biocompatibility,and superior electromagnetic shielding properties.However,their poor corrosion resistance and high susceptibility to environmentally assisted cracking(EAC)significantly limit broader application.In recent years,growing attention has been directed toward understanding the corrosion and EAC behavior of Mg-Li alloys,as localized corrosion areas and hydrogen generated during the corrosion process can serve as crack initiation points and promote crack propagation.A comprehensive understanding of these mechanisms is essential for enhancing the reliability and performance of Mg-Li alloys in practical environments.This paper presents a detailed review of corrosion and EAC in Mg-Li alloys,focusing on corrosion behavior,crack initiation and propagation mechanisms,and the key factors influencing these processes.It summarizes recent advances in alloying,heat treatment,mechanical processing,microstructural control,environmental influences,mechanical loading,and surface treatments.In addition,the paper explores future research directions,highlights emerging trends,and proposes strategies to improve the durability and service performance of Mg-Li alloys.展开更多
A laboratory study was undertaken to investigate drying shrinkage and cracking sensitivity subjected to restrained shrinkage of mortar containing fly ash (FA), granulated blast-furnace slag (GBFS) and silica fume (SF)...A laboratory study was undertaken to investigate drying shrinkage and cracking sensitivity subjected to restrained shrinkage of mortar containing fly ash (FA), granulated blast-furnace slag (GBFS) and silica fume (SF). Six mortar mixtures including control Portland cement (PC) and FA, GBFS and SF mortar mixtures were prepared. FA replaced the cement on mass basis at the replacement ratios of 20% and 35%, GBFS replaced the cement at the replacement ratios of 40%, SF replaced the cement at the replacement ratios of 8% and the blended mixtures with 20% FA, 20% GBFS and 8% SF. Water-cementitious materials ratio and sand-cementitious materials ratio were 0.4 and 2.0 for all mixtures, respectively. The mixtures were cured at 65% relative humidity and 20℃. The drying shrinkage value, initial cracking time and cracking width of the mortar samples were measured. The results show that all the mortar mixture containing FA exhibited the decrease of drying shrinkage. Moreover, initial cracking time was markedly delayed, and the crack width of the initial crack was reduced. However, the incorporations of various ratios of GBFS and SF led to an increase of drying shrinkage, initial cracking time and cracking width as compared to control mixture.展开更多
The interrupted fatigue test method was utilized to investigate the damage evolution mechanism of the notch high-cycle fatigue(NHCF)in Ti-55531 alloy with a multilevel lamellar microstructure.The results reveal that s...The interrupted fatigue test method was utilized to investigate the damage evolution mechanism of the notch high-cycle fatigue(NHCF)in Ti-55531 alloy with a multilevel lamellar microstructure.The results reveal that significant microvoids and microcracks predominantly initiate at α/β interfaces under various notch root radii(R).Notably,even under larger R(0.75 mm),mutual interactions of stacking faults(SFs)−deformation twins,twins−twins,and SFs−SFs are observed.Furthermore,with decreasing R(0.34 and 0.14 mm),the volume fraction of SFs escalates significantly and twins are almost absent.Moreover,activated prismatic slip system decreases with a decrease in Schmidt factor and with the further decrease in R.Finally,strain localization near α/β interfaces contributes to the initiation of fatigue microcracks.展开更多
The stability of rock slopes is frequently controlled by the initiation and propagation of inherent dominant cracks.This study systematically investigated these processes in valley slopes by combining fracture-mechani...The stability of rock slopes is frequently controlled by the initiation and propagation of inherent dominant cracks.This study systematically investigated these processes in valley slopes by combining fracture-mechanics analysis with transparent soil model tests.An analytical expression for the stress field at the dominant crack tip was derived from the slope stress distribution by superposing the corresponding stress intensity factors(SIFs).The theoretical predictions were then validated against observations from transparent soil model tests.The influences of slope angle(β),crack inclination angle(α),crack position parameter(b),and crack length parameter(h)on crack initiation and propagation were quantified.The results indicated that:(1)cracks at the slope crest tended to propagate in shear mode,and the shear crack initiation angle(θ_(s))was approximately 8°.Cracks at the slope toe might propagate in either tensile or shear mode.(2)θ_(s) at the slope crest increased withβ,b,and l,and decreased withα.The maximum change inθ_(s) induced by the considered parameters was approximately 30°.(3)The tensile crack initiation angle(θ_(t))at the slop toe decreased withβ,α,and l,while the influence of b was comparatively minor.The maximum change inθ_(t) caused by individual parameters ranged approximately from 25°to 60°.Predicted crack propagation modes and directions showed good agreement with experimental results.These findings provide theoretical guidance for stability assessments of valley slopes controlled by dominant crack propagation.展开更多
The influence of different solution and aging conditions on the microstructure,impact toughness,and crack initiation and propagation mechanisms of the novel α+β titanium alloy Ti6422 was systematically investigated....The influence of different solution and aging conditions on the microstructure,impact toughness,and crack initiation and propagation mechanisms of the novel α+β titanium alloy Ti6422 was systematically investigated.By adjusting the furnace cooling time after solution treatment and the aging temperature,Ti6422 alloy samples were developed with a multi-level lamellar microstructure,in-cluding microscaleαcolonies and α_(p) lamellae,as well as nanoscale α_(s) phases.Extending the furnace cooling time after solution treatment at 920℃ for 1 h from 240 to 540 min,followed by aging at 600℃ for 6 h,increased the α_(p) lamella content,reduced the α_(s) phase content,expanded theαcolonies and α_(p) lamellae size,and improved the impact toughness from 22.7 to 53.8 J/cm^(2).Additionally,under the same solution treatment,raising the aging temperature from 500 to 700℃ resulted in a decrease in the α_(s) phase content and a growth in the thickness of the α_(p) lamella and α_(s) phase.The impact toughness increased significantly with these changes.Samples with high α_(p) lamellae content or large α_(s) phase size exhibited high crack initiation and propagation energies.Impact deformation caused severe kinking of the α_(p) lamellae in crack initiation and propagation areas,leading to a uniform and high-density kernel average misorientation(KAM)distribu-tion,enhancing plastic deformation coordination and uniformity.Moreover,the multidirectional arrangement of coarserαcolonies and α_(p) lamellae continuously deflect the crack propagation direction,inhibiting crack propagation.展开更多
Fatigue cracking behavior from a notch was investigated at room temperature for Ti-6.SAI-3.5Mo-1.5Zr- 0.3Si （TClI） alloys with four different microstructures obtained at different cooling rates from the β transus t...Fatigue cracking behavior from a notch was investigated at room temperature for Ti-6.SAI-3.5Mo-1.5Zr- 0.3Si （TClI） alloys with four different microstructures obtained at different cooling rates from the β transus temperature. It was found that the alloy with lamellar structures consisting of α/β lamellae or acicular α＇ martensite laths had a higher fatigue crack initiation threshold from the notch, while the bimodal structure with coarse a grain had a lower fatigue cracking resistance. The alloy with α/β lamellar structure showed a higher fatigue crack growth resistance. The length scales of the microstructures were characterized to correlate with fatigue cracking behavior. Fatigue cracking mechanism related to microstructures was discussed.展开更多
The fatigue cracking behavior of ultra-high strength steels containing rectangular inclusions of small sizes were investigated based on in situ observations by scanning electron microscopy （SEM）. The size and shape ...The fatigue cracking behavior of ultra-high strength steels containing rectangular inclusions of small sizes were investigated based on in situ observations by scanning electron microscopy （SEM）. The size and shape of rectangular inclusions affect markedly the initiation site and propagation path of a fatigue crack. Especially, the initiation site of a fatigue crack depends strongly on the angle between the long-axis of a rectangle inclusion and the loading direction, and the length/width ratio of this rectangle inclusion because the residual stress distribution fields vary with these conditions. The results coincide very well with those of finite element analysis.展开更多
This paper deals with the mechanism of the formation of initial cracks in the yttria partially stabilized zirconia thermal barrier coatings prepared by EB-PVD method.The microcracks were only recognized inside the cer...This paper deals with the mechanism of the formation of initial cracks in the yttria partially stabilized zirconia thermal barrier coatings prepared by EB-PVD method.The microcracks were only recognized inside the ceramic top coat of the thermalcycled TBCs. SEM/EDS observations indicated that some special oxides exist in the area just below the cracks.It seems that the formation of the initial cracks can result from the oxidation stress as well as the thermal stress.展开更多
The mechanical characteristics and failure behavior of rocks containing flaws or discontinuities have received wide attention in the field of rock mechanics.When external loads are applied to rock materials,stress-ind...The mechanical characteristics and failure behavior of rocks containing flaws or discontinuities have received wide attention in the field of rock mechanics.When external loads are applied to rock materials,stress-induced cracks would initiate and propagate from the flaws,ultimately leading to the irreversible failure of rocks.To investigate the cracking behavior and the effect of flaw geometries on the mechanical properties of rock materials,a series of samples containing one,two and multiple flaws have been widely investigated in the laboratory.In this paper,the experimental results for pre-cracked rocks under quasistatic compression were systematically reviewed.The progressive failure process of intact rocks is briefly described to reveal the background for experiments on samples with flaws.Then,the nondestructive measurement techniques utilized in experiments,such as acoustic emission(AE),X-ray computed tomography(CT),and digital image correlation(DIC),are summarized.The mechanical characteristics of rocks with different flaw geometries and under different loading conditions,including the geometry of pre-existing flaws,flaw filling condition and confining pressure,are discussed.Furthermore,the cracking process is evaluated from the perspective of crack initiation,coalescence,and failure patterns.展开更多
An analytical model for predicting the corrosion-induced cracking of concrete cover of reinforced concrete(RC) structures was developed.The effects of influence factors such as practical initial defects,corrosion rate...An analytical model for predicting the corrosion-induced cracking of concrete cover of reinforced concrete(RC) structures was developed.The effects of influence factors such as practical initial defects,corrosion rate,strength and elastic modulus of concrete on the corrosion-induced cracking of concrete cover were investigated.It was found that the size of practical initial defects was the most effective factor.Therefore,improving the compactness of concrete is an effective way to improve the durability of RC structures.It was also demonstrated that the accelerated corrosion tests may be unfavorable in the study of the relationship between cracking time and crack width.展开更多
The fatigue behavior of 30 WGP1600 non-oriented electrical steel, which is generally used in the motors for electrical vehicles, was investigated. The detailed microstructure and dislocation configurations of the fati...The fatigue behavior of 30 WGP1600 non-oriented electrical steel, which is generally used in the motors for electrical vehicles, was investigated. The detailed microstructure and dislocation configurations of the fatigue specimens were examined by OM, SEM, and TEM. The test results showed that fatigue cracks were commonly initiated from the surface grain boundaries, crystals plane, and inclusions. The rapid fatigue crack propagation was characterized by transgranular cleavage fracture, while most transient fracture exhibited ductile tearing characteristics. After cyclic deformation of the non-oriented electrical steels, various dislocation structures, such as short and thick lines, veins, persistent slip bands, cells, and labyrinth, were observed.展开更多
In this study,Al–4Cu alloy specimens with spherical grains and liquid flms were obtained by isothermal reheating treatment.The hot cracking of the solidifcation process was determined using a modifed constrained rod ...In this study,Al–4Cu alloy specimens with spherical grains and liquid flms were obtained by isothermal reheating treatment.The hot cracking of the solidifcation process was determined using a modifed constrained rod casting experimental apparatus,and the efect of liquid flm characteristics at the end of solidifcation on hot cracking initiation of Al–4Cu alloys was systematically investigated by combining molecular dynamics simulations and other methods.With the extension of soaking time,the liquid fraction(liquid flm fraction at the end of solidifcation)and grain shape factor increased with higher isothermal reheating temperatures.Additionally,the widened flling channel decreased the hot cracking initiation temperature and the critical hot cracking shrinkage stress was found to increase,thus reducing the hot cracking severity in Al–4Cu alloys.Molecular dynamics simulations revealed that with the extension of soaking time,the composition of the liquid flm changed at diferent isothermal reheating temperatures,but the short-range structure and atomic ordering of the liquid flm remained the same.The activity of the liquid flm increased in equilibrium,leading to a decrease in viscosity and an increase in fuidity,which contributed to the flling behaviour.After isothermal reheating at 640℃for 60 min,the liquid fraction reached the maximum,and the viscosity of the liquid flm was the minimum.In addition,almost no hot cracks were found.展开更多
Hydrogen diffusion in the wall of hydrogenation reactor for three situations, i.e. operating, normal shutdown and abnormal shutdown, was numerically simulated based on the finite element program-ABAQUS. The formula of...Hydrogen diffusion in the wall of hydrogenation reactor for three situations, i.e. operating, normal shutdown and abnormal shutdown, was numerically simulated based on the finite element program-ABAQUS. The formula of diffusion-induced stress was deduced for model of the thin walled cylinder. Distribution of diffusion-induced stress in the wall of hydrogenation reactor was studied. The results showed that the maximum stress was at the fusion surface between welding overlay and base metal and which would increase with cooling rate. The crack will initiate and propagate from fusion surface to welding overlay when the diffusion-induced stress is higher than yield stress, but it will not propagate to the base metal. Diffusion-induced stress is one of the important factors for crack initiation and propagation of welding overlay of hydrogenation reactor.展开更多
Aiming at mitigating the high risks associated with conventional explosive blasting,this study developed a safe directional fracturing technique,i.e.instantaneous expansion with a single fracture(IESF),using a coal-ba...Aiming at mitigating the high risks associated with conventional explosive blasting,this study developed a safe directional fracturing technique,i.e.instantaneous expansion with a single fracture(IESF),using a coal-based solid waste expanding agent.First,the mechanism of directional fracturing blasting by the IESF was analyzed,and the criterion of directional crack initiation was established.On this basis,laboratory experiments and numerical simulations were conducted to systematically evaluate the directional fracturing blasting performance of the IESF.The results indicate that the IESF presents an excellent directional fracturing effect,with average surface undulation differences ranging from 8.1 mm to 22.7 mm on the fracture surfaces.Moreover,during concrete fracturing tests,the stresses and strains in the fracturing direction are measured to be 2.16-3.71 times and 8 times larger than those in the nonfracturing direction,respectively.Finally,the IESF technique was implemented for no-pillar mining with gob-side entry retaining through roof cutting and pressure relief in an underground coal mine.The IESF technique effectively created directional cracks in the roof without causing severe roadway deformation,achieving an average cutting rate and maximum roadway deformation of 94%and 197 mm,respectively.These on-site test results verified its excellent directional rock fracturing performance.The IESF technique,which is safe,efficient,and green,has considerable application prospects in the field of rock mechanics and engineering.展开更多
Crack initiation mechanism of dwell fatigue has always been a key problem in rationalizing the dwell effect,and it is not completely understood yet.This study conducted stress-controlled low-cycle fatigue and dwell fa...Crack initiation mechanism of dwell fatigue has always been a key problem in rationalizing the dwell effect,and it is not completely understood yet.This study conducted stress-controlled low-cycle fatigue and dwell fatigue tests on Ti-6Al-3Nb-2Zr-1Mo alloy with bimodal microstructure to reveal its microstructural characteristics and crack initiation mechanisms.The study demonstrated that the faceted primaryα nodules located near the specimen surface acted as crack initiation sites during both fatigue and dwell fatigue tests.Slip trace analysis revealed that faceted cracking occurred at(0001)basal plane with the maximum Schmid factor value through a special cracking mode referred to as(0001)twist boundary cracking.Innovative criteria of parameters C1 and C2 were proposed based on experimental observation and molecular dynamics simulations,which well identify candidates for(0001)twist boundary crack nucleation.It demonstrated that grain pairs combining a moderately high Schmid factor for basal slip and a well-orientated Burgers vector in the out-of-surface plane was the preferable location for surface(0001)twist-boundary crack initiation,and grain pairs combining a high Schmid factor for basal slip and a high normal stress on basal plane are perfect candidates for subsurface cracking.Based on this,phenomeno-logical models are proposed to explain the surface(0001)twist-boundary cracking mechanism from the perspective of surface extrusion-intrusion-induced micro-notches.展开更多
The loaded rock experiences multiple stages of deformation.It starts with the formation of microcracks at low stresses(crack initiation,CI)and then transitions into unstable crack propagation(crack damage,CD)near the ...The loaded rock experiences multiple stages of deformation.It starts with the formation of microcracks at low stresses(crack initiation,CI)and then transitions into unstable crack propagation(crack damage,CD)near the ultimate strength.In this study,both the acoustic emission method(AEM)and the ultrasonic testing method(UTM)were used to examine the characteristics of AE parameters(b-value,peak frequency,frequency-band energy ratio,and fractal dimension)and ultrasonic(ULT)properties(velocity,amplitude,energy attenuation,and scattering attenuation)of bedded shale at CI,CD,and ultimate strength.The comparison involved analyzing the strain-based method(SBM),AEM,and UTM to determine the thresholds for damage stress.A fuzzy comprehensive evaluation model(FCEM)was created to describe the damage thresholds and hazard assessment.The results indicate that the optimal AE and ULT parameters for identifying CI and CD stress are ringing count,ultrasonic amplitude,energy attenuation,and scattering attenuation of the S-wave.Besides,damage thresholds were detected earlier by AE monitoring,ranging from 3 MPa to 10 MPa.CI and CD identified by UTM occurred later than SBM and AEM,and were in the range of 12 MPa.The b-value,peak frequency,energy ratio in the low-frequency band(0e62.5 kHz),correlation dimension,and sandbox dimension showed low values at the peak stress,while the energy ratio in a moderate-frequency band(187.5e281.25 kHz)and amplitude showed high values.The successful application of FCEM to laboratory testing of shales has demonstrated its ability to quantitatively identify AE/ULT precursors of seismic hazards associated with rock failure.展开更多
Microcrack growth during progressive compressive failure in brittle rocks strongly influences the safety of deep underground engineering.The external shear stressτxy on brittle rocks greatly affects microcrack growth...Microcrack growth during progressive compressive failure in brittle rocks strongly influences the safety of deep underground engineering.The external shear stressτxy on brittle rocks greatly affects microcrack growth and progressive failure.However,the theoretical mechanism of the growth direction evolution of the newly generated wing crack during progressive failure has rarely been studied.A novel analytical method is proposed to evaluate the shear stress effect on the progressive compressive failure and microcrack growth direction in brittle rocks.This model consists of the wing crack growth model under the principal compressive stresses,the direction correlation of the general stress,the principal stress and the initial microcrack inclination,and the relationship between the wing crack length and strain.The shear stress effect on the relationship between y-direction stress and wing crack growth and the relationship between y-direction stress and y-direction strain are analyzed.The shear stress effect on the wing crack growth direction during the progressive compressive failure is determined.The initial crack angle effect on the y-direction peak stress and the wing crack growth direction during the progressive compressive failure considering shear stress is also discussed.A crucial conclusion is that the direction of wing crack growth has a U-shaped variation with the growth of the wing crack.The rationality of the analytical results is verified by an experiment and from numerical results.The study results provide theoretical support for the evaluation of the safety and stability of surrounding rocks in deep underground engineering.展开更多
The critical wear rate,surface damage,deformation layer,crack initiation and propagation of U76CrRE heavy rail steel samples of two different cooling conditions(rolled rail,and heat-treated rail)under intermittent loa...The critical wear rate,surface damage,deformation layer,crack initiation and propagation of U76CrRE heavy rail steel samples of two different cooling conditions(rolled rail,and heat-treated rail)under intermittent load were measured and observed by friction and wear tester,laser confocal microscope,scanning electron microscope and EBSD.The experimental results show that when the same kind of rail is matched with wheel steel with low hardness and high hardness successively,the critical wear rate of rail moves to the right.Moreover,when the rolled rail is matched with wheel steel with low hardness,the deformation layer and wear amount are larger than those of heat-treated rail are,while when it is matched with wheel steel with high hardness,the deformation layer and wear amount are smaller than those of heat-treated rail.When the rolled rail and heat-treated rail are matched with the same kind of wheel steel successively,the critical wear rate moves down,and the wear deformation layer of heat-treated rail is smaller than that of rolled rail.The failure life of the heat-treated rail is better than that of the rolled rail,which is due to the increase of the hardness of the heat-treated rail and the refinement of pearlite lamellae.With the increase of the distance from the surface layer,the proportion of large-angle grain boundaries of ferrite grains gradually increases of rolled rail and heat-treated rail,but the rolled rail presents the characteristics of large crack angle,deep depth and small length,mainly due to wear failure.While the heat-treated rail has the characteristics of small crack angle,shallow depth and long length,the crack propagation trend is obvious,and the failure form of the heat-treated rail is mainly fatigue failure.Moving the critical wear rate to the right and down is beneficial to inhibit the formation and propagation of fatigue cracks.展开更多
基金The financial support provided by the Project of the National Natural Science Foundation of China (22308314,U22A20415)the Natural Science Foundation of Zhejiang Province (LQ24B060001)+1 种基金the "Pioneer" and "Leading Goose" Research & Development Program of Zhejiang (2022C01SA442617)the SINOPEC Technology Development Project (224244)
文摘This study leverages machine learning to perform high-throughput computational screening of n-hexane cracking initiators.Artificial neural networks are applied to predict the chemical performance of initiators,using simulated pyrolysis data as the training dataset.Various feature extraction methods are utilized,and five neural network architectures are developed to predict the co-cracking product distribution based on molecular structures.High-throughput screening of 12946 molecules outside the training dataset identifies the top 10 initiators for each target product—ethylene,propylene,and butadiene.The relative error between predicted and simulated values is less than 7%.Additionally,reaction pathway analysis elucidates the mechanisms by which initiators influence the distribution of cracking products.The proposed framework provides a practical and efficient approach for the rapid identification and evaluation of high-performance cracking initiators.
基金financially supported by the National Natural Science Foundation of China(No.U21A2050)support of the Chinese Scholarship Council(No.202006290165).
文摘In recent years,(0001)twist grain boundaries(BTGBs)located in primary α grain clusters were identified as fatigue crack nucleation sites in different Ti alloys.In the present study,crack initiation was investigated in a bimodal Ti-5Al-4 V alloy subjected to low-cycle fatigue and dwell-fatigue loadings at room temperature.The low fraction of primary α grains was not associated with a lack of sensitivity to BTGB cracking.Transmission electron microscopy and electron back-scattered diffraction were used to characterize BTGBs in the initial microstructure.The fatigue mechanisms were then analyzed with a focus on dislocation activity.α_(p) grains adjacent to cracked BTGBs contained a high dislocation density.It was primarily composed of planar slip bands of dislocations.In addition,<c+a>dislocations were noticed in the vicinity of cracked BTGBs.They supposedly pertain to crack tip plasticity during growth,and no evidence of a role of an incoming slip event in crack nucleation was obtained.Also,basal slip bands extending across adjacent grains were found to emerge from BTGBs.This feature provides an easier path for crack extension when growth along the grain boundary becomes difficult owing to a deviation from the basal plane.Atom probe tomography analyses evidenced V and Fe segregation at a grain boundary with a significant deviation from the BTGB configuration.This suggests a possible contribution of local solute segregation to the high cracking resistance of general α_(p)/α_(p) grain boundaries.This work provides new insights into the mechanisms involved in cracking of BTGB in Ti alloys subjected to cyclic loadings.
基金supported by the National Natural Science Foundation of China Projects under Grant(nos.52301112,52331004,U21A2049,and 51871211)Guangdong Basic and Applied Basic Research Foundation(Grant no.2024A1515030065)+4 种基金Basic and Applied Basic Research Project of Guangzhou(Grant no.2024A04J6299)LiaoNing Revitalization Talents Program(XLYC1907062,and XLYC2403026)Shenyang Young and Middle-aged Science and Technology Innovation Talent Support Program(RC231178)the Fundamental Research Funds for the Central Universities(N25GFY002)the Innovation Fund of Institute of Metal Research(IMR),Chinese Academy of Sciences(CAS).
文摘Mg-Li alloys hold significant potential for applications in aerospace,automotive manufacturing,military weaponry,and biomedical implants,due to their excellent recyclability,high specific strength,biocompatibility,and superior electromagnetic shielding properties.However,their poor corrosion resistance and high susceptibility to environmentally assisted cracking(EAC)significantly limit broader application.In recent years,growing attention has been directed toward understanding the corrosion and EAC behavior of Mg-Li alloys,as localized corrosion areas and hydrogen generated during the corrosion process can serve as crack initiation points and promote crack propagation.A comprehensive understanding of these mechanisms is essential for enhancing the reliability and performance of Mg-Li alloys in practical environments.This paper presents a detailed review of corrosion and EAC in Mg-Li alloys,focusing on corrosion behavior,crack initiation and propagation mechanisms,and the key factors influencing these processes.It summarizes recent advances in alloying,heat treatment,mechanical processing,microstructural control,environmental influences,mechanical loading,and surface treatments.In addition,the paper explores future research directions,highlights emerging trends,and proposes strategies to improve the durability and service performance of Mg-Li alloys.
基金Funded by the 863 Program from Ministry of Science and Technology of China(2005AA332010) the Key Technologies R&D Program from Department of Science and Technology. Hubei Province (200410G0121)
文摘A laboratory study was undertaken to investigate drying shrinkage and cracking sensitivity subjected to restrained shrinkage of mortar containing fly ash (FA), granulated blast-furnace slag (GBFS) and silica fume (SF). Six mortar mixtures including control Portland cement (PC) and FA, GBFS and SF mortar mixtures were prepared. FA replaced the cement on mass basis at the replacement ratios of 20% and 35%, GBFS replaced the cement at the replacement ratios of 40%, SF replaced the cement at the replacement ratios of 8% and the blended mixtures with 20% FA, 20% GBFS and 8% SF. Water-cementitious materials ratio and sand-cementitious materials ratio were 0.4 and 2.0 for all mixtures, respectively. The mixtures were cured at 65% relative humidity and 20℃. The drying shrinkage value, initial cracking time and cracking width of the mortar samples were measured. The results show that all the mortar mixture containing FA exhibited the decrease of drying shrinkage. Moreover, initial cracking time was markedly delayed, and the crack width of the initial crack was reduced. However, the incorporations of various ratios of GBFS and SF led to an increase of drying shrinkage, initial cracking time and cracking width as compared to control mixture.
基金supported by the National Natural Science Foundation of China(Nos.52061005,52261025)the Science and Technology Programs of Guizhou Province,China(Nos.YQK[2023]009,CXTD[2023]009)the Technology Innovation Leading Program of Shaanxi Province,China(No.2024ZCYYDP92)。
文摘The interrupted fatigue test method was utilized to investigate the damage evolution mechanism of the notch high-cycle fatigue(NHCF)in Ti-55531 alloy with a multilevel lamellar microstructure.The results reveal that significant microvoids and microcracks predominantly initiate at α/β interfaces under various notch root radii(R).Notably,even under larger R(0.75 mm),mutual interactions of stacking faults(SFs)−deformation twins,twins−twins,and SFs−SFs are observed.Furthermore,with decreasing R(0.34 and 0.14 mm),the volume fraction of SFs escalates significantly and twins are almost absent.Moreover,activated prismatic slip system decreases with a decrease in Schmidt factor and with the further decrease in R.Finally,strain localization near α/β interfaces contributes to the initiation of fatigue microcracks.
基金financially supported by the National Nature Science Foundation of China(Nos.52379110 and 42207222)the Key Technologies for Accurate Diagnosis and Intelligent Prevention and Control of Slope Hazards in Open Pit Mines,181 Major R&D projects of Metallurgical Corporation of China Ltd。
文摘The stability of rock slopes is frequently controlled by the initiation and propagation of inherent dominant cracks.This study systematically investigated these processes in valley slopes by combining fracture-mechanics analysis with transparent soil model tests.An analytical expression for the stress field at the dominant crack tip was derived from the slope stress distribution by superposing the corresponding stress intensity factors(SIFs).The theoretical predictions were then validated against observations from transparent soil model tests.The influences of slope angle(β),crack inclination angle(α),crack position parameter(b),and crack length parameter(h)on crack initiation and propagation were quantified.The results indicated that:(1)cracks at the slope crest tended to propagate in shear mode,and the shear crack initiation angle(θ_(s))was approximately 8°.Cracks at the slope toe might propagate in either tensile or shear mode.(2)θ_(s) at the slope crest increased withβ,b,and l,and decreased withα.The maximum change inθ_(s) induced by the considered parameters was approximately 30°.(3)The tensile crack initiation angle(θ_(t))at the slop toe decreased withβ,α,and l,while the influence of b was comparatively minor.The maximum change inθ_(t) caused by individual parameters ranged approximately from 25°to 60°.Predicted crack propagation modes and directions showed good agreement with experimental results.These findings provide theoretical guidance for stability assessments of valley slopes controlled by dominant crack propagation.
基金supported by the National Natural Science Foundation of China(No.52090041).
文摘The influence of different solution and aging conditions on the microstructure,impact toughness,and crack initiation and propagation mechanisms of the novel α+β titanium alloy Ti6422 was systematically investigated.By adjusting the furnace cooling time after solution treatment and the aging temperature,Ti6422 alloy samples were developed with a multi-level lamellar microstructure,in-cluding microscaleαcolonies and α_(p) lamellae,as well as nanoscale α_(s) phases.Extending the furnace cooling time after solution treatment at 920℃ for 1 h from 240 to 540 min,followed by aging at 600℃ for 6 h,increased the α_(p) lamella content,reduced the α_(s) phase content,expanded theαcolonies and α_(p) lamellae size,and improved the impact toughness from 22.7 to 53.8 J/cm^(2).Additionally,under the same solution treatment,raising the aging temperature from 500 to 700℃ resulted in a decrease in the α_(s) phase content and a growth in the thickness of the α_(p) lamella and α_(s) phase.The impact toughness increased significantly with these changes.Samples with high α_(p) lamellae content or large α_(s) phase size exhibited high crack initiation and propagation energies.Impact deformation caused severe kinking of the α_(p) lamellae in crack initiation and propagation areas,leading to a uniform and high-density kernel average misorientation(KAM)distribu-tion,enhancing plastic deformation coordination and uniformity.Moreover,the multidirectional arrangement of coarserαcolonies and α_(p) lamellae continuously deflect the crack propagation direction,inhibiting crack propagation.
基金supported by the National Basic Research Program of China (No. 2007CB613803)the National Natural Science Foundation of China (No.51071158)the Fundamental Research Funds for the Central Universities (No. N100702001)
文摘Fatigue cracking behavior from a notch was investigated at room temperature for Ti-6.SAI-3.5Mo-1.5Zr- 0.3Si （TClI） alloys with four different microstructures obtained at different cooling rates from the β transus temperature. It was found that the alloy with lamellar structures consisting of α/β lamellae or acicular α＇ martensite laths had a higher fatigue crack initiation threshold from the notch, while the bimodal structure with coarse a grain had a lower fatigue cracking resistance. The alloy with α/β lamellar structure showed a higher fatigue crack growth resistance. The length scales of the microstructures were characterized to correlate with fatigue cracking behavior. Fatigue cracking mechanism related to microstructures was discussed.
文摘The fatigue cracking behavior of ultra-high strength steels containing rectangular inclusions of small sizes were investigated based on in situ observations by scanning electron microscopy （SEM）. The size and shape of rectangular inclusions affect markedly the initiation site and propagation path of a fatigue crack. Especially, the initiation site of a fatigue crack depends strongly on the angle between the long-axis of a rectangle inclusion and the loading direction, and the length/width ratio of this rectangle inclusion because the residual stress distribution fields vary with these conditions. The results coincide very well with those of finite element analysis.
文摘This paper deals with the mechanism of the formation of initial cracks in the yttria partially stabilized zirconia thermal barrier coatings prepared by EB-PVD method.The microcracks were only recognized inside the ceramic top coat of the thermalcycled TBCs. SEM/EDS observations indicated that some special oxides exist in the area just below the cracks.It seems that the formation of the initial cracks can result from the oxidation stress as well as the thermal stress.
基金financial support from the National Key R&D Program of China(Grant No.2020YFA0711802)。
文摘The mechanical characteristics and failure behavior of rocks containing flaws or discontinuities have received wide attention in the field of rock mechanics.When external loads are applied to rock materials,stress-induced cracks would initiate and propagate from the flaws,ultimately leading to the irreversible failure of rocks.To investigate the cracking behavior and the effect of flaw geometries on the mechanical properties of rock materials,a series of samples containing one,two and multiple flaws have been widely investigated in the laboratory.In this paper,the experimental results for pre-cracked rocks under quasistatic compression were systematically reviewed.The progressive failure process of intact rocks is briefly described to reveal the background for experiments on samples with flaws.Then,the nondestructive measurement techniques utilized in experiments,such as acoustic emission(AE),X-ray computed tomography(CT),and digital image correlation(DIC),are summarized.The mechanical characteristics of rocks with different flaw geometries and under different loading conditions,including the geometry of pre-existing flaws,flaw filling condition and confining pressure,are discussed.Furthermore,the cracking process is evaluated from the perspective of crack initiation,coalescence,and failure patterns.
基金Supported by National Natural Science Foundation of China (No. 50908148)Natural Science Foundation for Team Project of Guangdong Province(No. 9351806001000001)+1 种基金Scientific Research Foundation for Returned Overseas Chinese Scholars,Ministry of Education(41 Batch)Open Fund of State Key Laboratory of Coastal and Of fshore Engineering of Dalian University of Technology (No. LP1111)
文摘An analytical model for predicting the corrosion-induced cracking of concrete cover of reinforced concrete(RC) structures was developed.The effects of influence factors such as practical initial defects,corrosion rate,strength and elastic modulus of concrete on the corrosion-induced cracking of concrete cover were investigated.It was found that the size of practical initial defects was the most effective factor.Therefore,improving the compactness of concrete is an effective way to improve the durability of RC structures.It was also demonstrated that the accelerated corrosion tests may be unfavorable in the study of the relationship between cracking time and crack width.
基金Funded by the High Technology Research and Development Program of China(2011AA11A238)
文摘The fatigue behavior of 30 WGP1600 non-oriented electrical steel, which is generally used in the motors for electrical vehicles, was investigated. The detailed microstructure and dislocation configurations of the fatigue specimens were examined by OM, SEM, and TEM. The test results showed that fatigue cracks were commonly initiated from the surface grain boundaries, crystals plane, and inclusions. The rapid fatigue crack propagation was characterized by transgranular cleavage fracture, while most transient fracture exhibited ductile tearing characteristics. After cyclic deformation of the non-oriented electrical steels, various dislocation structures, such as short and thick lines, veins, persistent slip bands, cells, and labyrinth, were observed.
基金supported by the National Natural Science Foundation of China(No.51875365).
文摘In this study,Al–4Cu alloy specimens with spherical grains and liquid flms were obtained by isothermal reheating treatment.The hot cracking of the solidifcation process was determined using a modifed constrained rod casting experimental apparatus,and the efect of liquid flm characteristics at the end of solidifcation on hot cracking initiation of Al–4Cu alloys was systematically investigated by combining molecular dynamics simulations and other methods.With the extension of soaking time,the liquid fraction(liquid flm fraction at the end of solidifcation)and grain shape factor increased with higher isothermal reheating temperatures.Additionally,the widened flling channel decreased the hot cracking initiation temperature and the critical hot cracking shrinkage stress was found to increase,thus reducing the hot cracking severity in Al–4Cu alloys.Molecular dynamics simulations revealed that with the extension of soaking time,the composition of the liquid flm changed at diferent isothermal reheating temperatures,but the short-range structure and atomic ordering of the liquid flm remained the same.The activity of the liquid flm increased in equilibrium,leading to a decrease in viscosity and an increase in fuidity,which contributed to the flling behaviour.After isothermal reheating at 640℃for 60 min,the liquid fraction reached the maximum,and the viscosity of the liquid flm was the minimum.In addition,almost no hot cracks were found.
基金supported by Graduate Student Scientific Innovation Project of Jiangsu Province (No.CX09B 131Z)
文摘Hydrogen diffusion in the wall of hydrogenation reactor for three situations, i.e. operating, normal shutdown and abnormal shutdown, was numerically simulated based on the finite element program-ABAQUS. The formula of diffusion-induced stress was deduced for model of the thin walled cylinder. Distribution of diffusion-induced stress in the wall of hydrogenation reactor was studied. The results showed that the maximum stress was at the fusion surface between welding overlay and base metal and which would increase with cooling rate. The crack will initiate and propagate from fusion surface to welding overlay when the diffusion-induced stress is higher than yield stress, but it will not propagate to the base metal. Diffusion-induced stress is one of the important factors for crack initiation and propagation of welding overlay of hydrogenation reactor.
基金supported by the National Natural Science Foundation of China(Grant No.52404155)State Key Laboratory of Mining Disaster Prevention and Control(Shandong University of Science and Technology)+1 种基金Ministry of Education(Grant No.JMDPC202402)supported by the opening project of State Key Laboratory of Explosion Science and Safety Protection(Beijing Institute of Technology).The opening project number is KFJJ24-20M.
文摘Aiming at mitigating the high risks associated with conventional explosive blasting,this study developed a safe directional fracturing technique,i.e.instantaneous expansion with a single fracture(IESF),using a coal-based solid waste expanding agent.First,the mechanism of directional fracturing blasting by the IESF was analyzed,and the criterion of directional crack initiation was established.On this basis,laboratory experiments and numerical simulations were conducted to systematically evaluate the directional fracturing blasting performance of the IESF.The results indicate that the IESF presents an excellent directional fracturing effect,with average surface undulation differences ranging from 8.1 mm to 22.7 mm on the fracture surfaces.Moreover,during concrete fracturing tests,the stresses and strains in the fracturing direction are measured to be 2.16-3.71 times and 8 times larger than those in the nonfracturing direction,respectively.Finally,the IESF technique was implemented for no-pillar mining with gob-side entry retaining through roof cutting and pressure relief in an underground coal mine.The IESF technique effectively created directional cracks in the roof without causing severe roadway deformation,achieving an average cutting rate and maximum roadway deformation of 94%and 197 mm,respectively.These on-site test results verified its excellent directional rock fracturing performance.The IESF technique,which is safe,efficient,and green,has considerable application prospects in the field of rock mechanics and engineering.
基金supported by the National Natural Science Foundation of China(Nos.52074231,52274396 and 52001258)the Chongqing Natural Science Foundation(No.cstc2020jcyj-msxmX1056).
文摘Crack initiation mechanism of dwell fatigue has always been a key problem in rationalizing the dwell effect,and it is not completely understood yet.This study conducted stress-controlled low-cycle fatigue and dwell fatigue tests on Ti-6Al-3Nb-2Zr-1Mo alloy with bimodal microstructure to reveal its microstructural characteristics and crack initiation mechanisms.The study demonstrated that the faceted primaryα nodules located near the specimen surface acted as crack initiation sites during both fatigue and dwell fatigue tests.Slip trace analysis revealed that faceted cracking occurred at(0001)basal plane with the maximum Schmid factor value through a special cracking mode referred to as(0001)twist boundary cracking.Innovative criteria of parameters C1 and C2 were proposed based on experimental observation and molecular dynamics simulations,which well identify candidates for(0001)twist boundary crack nucleation.It demonstrated that grain pairs combining a moderately high Schmid factor for basal slip and a well-orientated Burgers vector in the out-of-surface plane was the preferable location for surface(0001)twist-boundary crack initiation,and grain pairs combining a high Schmid factor for basal slip and a high normal stress on basal plane are perfect candidates for subsurface cracking.Based on this,phenomeno-logical models are proposed to explain the surface(0001)twist-boundary cracking mechanism from the perspective of surface extrusion-intrusion-induced micro-notches.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.U20A20266 and 12302503)Scientific and technological research projects in Sichuan province(Grant No.2024NSFSC0973).
文摘The loaded rock experiences multiple stages of deformation.It starts with the formation of microcracks at low stresses(crack initiation,CI)and then transitions into unstable crack propagation(crack damage,CD)near the ultimate strength.In this study,both the acoustic emission method(AEM)and the ultrasonic testing method(UTM)were used to examine the characteristics of AE parameters(b-value,peak frequency,frequency-band energy ratio,and fractal dimension)and ultrasonic(ULT)properties(velocity,amplitude,energy attenuation,and scattering attenuation)of bedded shale at CI,CD,and ultimate strength.The comparison involved analyzing the strain-based method(SBM),AEM,and UTM to determine the thresholds for damage stress.A fuzzy comprehensive evaluation model(FCEM)was created to describe the damage thresholds and hazard assessment.The results indicate that the optimal AE and ULT parameters for identifying CI and CD stress are ringing count,ultrasonic amplitude,energy attenuation,and scattering attenuation of the S-wave.Besides,damage thresholds were detected earlier by AE monitoring,ranging from 3 MPa to 10 MPa.CI and CD identified by UTM occurred later than SBM and AEM,and were in the range of 12 MPa.The b-value,peak frequency,energy ratio in the low-frequency band(0e62.5 kHz),correlation dimension,and sandbox dimension showed low values at the peak stress,while the energy ratio in a moderate-frequency band(187.5e281.25 kHz)and amplitude showed high values.The successful application of FCEM to laboratory testing of shales has demonstrated its ability to quantitatively identify AE/ULT precursors of seismic hazards associated with rock failure.
基金National Natural Science Foundation of China,Grant/Award Numbers:51708016,12172036R&D Program of Beijing Municipal Education Commission,Grant/Award Number:KM202110016014+1 种基金Government of Perm Krai,Research Project,Grant/Award Numbers:СED-26-08-08-28,С-26/628Graduate Innovation Program of Beijing University of Civil Engineering and Architecture,Grant/Award Number:PG2024035。
文摘Microcrack growth during progressive compressive failure in brittle rocks strongly influences the safety of deep underground engineering.The external shear stressτxy on brittle rocks greatly affects microcrack growth and progressive failure.However,the theoretical mechanism of the growth direction evolution of the newly generated wing crack during progressive failure has rarely been studied.A novel analytical method is proposed to evaluate the shear stress effect on the progressive compressive failure and microcrack growth direction in brittle rocks.This model consists of the wing crack growth model under the principal compressive stresses,the direction correlation of the general stress,the principal stress and the initial microcrack inclination,and the relationship between the wing crack length and strain.The shear stress effect on the relationship between y-direction stress and wing crack growth and the relationship between y-direction stress and y-direction strain are analyzed.The shear stress effect on the wing crack growth direction during the progressive compressive failure is determined.The initial crack angle effect on the y-direction peak stress and the wing crack growth direction during the progressive compressive failure considering shear stress is also discussed.A crucial conclusion is that the direction of wing crack growth has a U-shaped variation with the growth of the wing crack.The rationality of the analytical results is verified by an experiment and from numerical results.The study results provide theoretical support for the evaluation of the safety and stability of surrounding rocks in deep underground engineering.
基金Funded by the Inner Mongolia Autonomous Region Science and Technology Program(No.2023YFHH0036)the Natural Science Foundation of Inner Mongolia(No.2024LHMS05033)the Basic Scientific Research Fees for Colleges and Universities Directly under the Inner Mongolia(Nos.2023QNJS002,2023YXXS007,and 2024YXXS039)。
文摘The critical wear rate,surface damage,deformation layer,crack initiation and propagation of U76CrRE heavy rail steel samples of two different cooling conditions(rolled rail,and heat-treated rail)under intermittent load were measured and observed by friction and wear tester,laser confocal microscope,scanning electron microscope and EBSD.The experimental results show that when the same kind of rail is matched with wheel steel with low hardness and high hardness successively,the critical wear rate of rail moves to the right.Moreover,when the rolled rail is matched with wheel steel with low hardness,the deformation layer and wear amount are larger than those of heat-treated rail are,while when it is matched with wheel steel with high hardness,the deformation layer and wear amount are smaller than those of heat-treated rail.When the rolled rail and heat-treated rail are matched with the same kind of wheel steel successively,the critical wear rate moves down,and the wear deformation layer of heat-treated rail is smaller than that of rolled rail.The failure life of the heat-treated rail is better than that of the rolled rail,which is due to the increase of the hardness of the heat-treated rail and the refinement of pearlite lamellae.With the increase of the distance from the surface layer,the proportion of large-angle grain boundaries of ferrite grains gradually increases of rolled rail and heat-treated rail,but the rolled rail presents the characteristics of large crack angle,deep depth and small length,mainly due to wear failure.While the heat-treated rail has the characteristics of small crack angle,shallow depth and long length,the crack propagation trend is obvious,and the failure form of the heat-treated rail is mainly fatigue failure.Moving the critical wear rate to the right and down is beneficial to inhibit the formation and propagation of fatigue cracks.
