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简谈Buffer区域漫延机制对CBTC列车运行影响
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作者 施宇锋 《铁路通信信号工程技术》 2026年第2期103-108,共6页
基于列车定位与安全防护包络计算原理,重点分析基于通信的列车控制(CBTC)系统中列车安全防护缓冲(Buffer)区域的生成与漫延机制。通过构建不同运营场景,系统研究前车丢失定位或车载ATP故障时,Buffer区域漫延对后续CBTC列车运行的影响规... 基于列车定位与安全防护包络计算原理,重点分析基于通信的列车控制(CBTC)系统中列车安全防护缓冲(Buffer)区域的生成与漫延机制。通过构建不同运营场景,系统研究前车丢失定位或车载ATP故障时,Buffer区域漫延对后续CBTC列车运行的影响规律。结果表明,Buffer区域漫延会导致后车移动授权受限甚至触发紧急制动,进而降低线路通过能力。为此,提出合理增加计轴点布局、优化列车追踪间隔等应对措施,可为实际运营中故障情况下的行车组织与效率提升提供参考。 展开更多
关键词 安全防护包络 CBTC buffer 漫延机制
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Development of a Twin-Accumulator Hydro-Pneumatic Suspension 被引量:1
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作者 杨波 陈思忠 +2 位作者 吴志成 杨林 张斌 《Journal of Shanghai Jiaotong university(Science)》 EI 2010年第2期183-187,共5页
A twin-accumulator hydro-pneumatic suspension has been developed based on the off-road vehicle in order to meet the requirements of ride comfort. The working principle and elements construct of the developed suspensio... A twin-accumulator hydro-pneumatic suspension has been developed based on the off-road vehicle in order to meet the requirements of ride comfort. The working principle and elements construct of the developed suspension are studied. And then,a mathematical model of the developed suspension is built. The influence of twin-accumulator hydro-pneumatic suspension parameters on the vehicle body vertical acceleration,suspension travel and dynamic tyre load is studied by simulation based on a quarter off-road vehicle model. The ride comfort of the vehicle with the developed suspension is studied by a theoretical evaluation; also the ride comfort of the vehicle with twin-accumulator hydro-pneumatic suspension is compared with the one with single accumulator hydro-pneumatic suspension in both time domain and frequency domain. The result shows that the twin-accumulator hydro-pneumatic suspension system gives worthwhile improvements in ride comfort compared with the single accumulator hydro-pneumatic suspension,and it is more suitable for off-road vehicle. 展开更多
关键词 off-road vehicle twin-accumulator hydro-pneumatic suspension ride comfort
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Investigation of Semi-Active Hydro-Pneumatic Suspension for a Heavy Vehicle Based on Electro-Hydraulic Proportional Valve 被引量:2
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作者 Wenchao Yue Shoucheng Li Xiaojun Zou 《World Journal of Engineering and Technology》 2017年第4期696-706,共11页
Hydro-pneumatic suspension is widely used in heavy vehicles due to its nonlinear characteristics of stiffness and damping. However, the conventional passive hydro-pneumatic suspension can’t adjust parameters accordin... Hydro-pneumatic suspension is widely used in heavy vehicles due to its nonlinear characteristics of stiffness and damping. However, the conventional passive hydro-pneumatic suspension can’t adjust parameters according to the complicated road environment of heavy vehicles to fulfill the requirements of the vehicle ride comfort. In this paper, a semi-active hydro-pneumatic suspension system based on the electro-hydraulic proportional valve control is proposed, and fuzzy control is used as the control strategy to adjust the?damping force of the semi-active hydro-pneumatic suspension. A 1/4?semi-active hydro-pneumatic suspension model is established, which is co-simulated with AMESim and MATLAB/Simulink. The co-simulation results show that the semi-active hydro-pneumatic suspension system can significantly reduce vibration of the vehicle body, and improve the suspension performance comparing with passive hydro-pneumatic suspension. 展开更多
关键词 hydro-pneumatic SUSPENSION SEMI-ACTIVE Control CO-SIMULATION ELECTRO-HYDRAULIC Proportional VALVE
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Development of a Composite Suspension with a Coil and Hydro-Pneumatic Spring 被引量:1
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作者 杨波 陈思忠 +1 位作者 吴志成 杨林 《Journal of Beijing Institute of Technology》 EI CAS 2008年第3期280-284,共5页
A new composite suspension is developed, where a coil spring and a hydro-pneumatic spring are used in order to improve the poor reliability of off-road vehicle with pure hydro-pneumatic suspension. According to road c... A new composite suspension is developed, where a coil spring and a hydro-pneumatic spring are used in order to improve the poor reliability of off-road vehicle with pure hydro-pneumatic suspension. According to road conditions, the two springs play different roles. The method for matching the composite suspension stiffness and distributing the load is proposed. The working pressure of hydro-pneumatic spring as well as the load and stiffness characteristics of composite suspension is compared with a pure hydro-pneumatic suspension. In addition, the ISO weighted vehicle body acceleration, suspension travel and relative dynamic load of the wheels between two kinds of suspension are analyzed with a quarter vehicle mode. The simulation result shows that the developed composite suspension is more suitable for off-road vehicle than the one hydro-pneumatic suspension, because the composite suspension can reduce the working pressure, improve the reliability and keep a similar ride comfort with hydro-pneumatic suspension. 展开更多
关键词 composite suspension hydro-pneumatic spring coil spring matching stiffness
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Control Research of Dual Chamber Hydro-Pneumatic Suspension 被引量:2
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作者 Jinwei Sun Mingming Dong +2 位作者 Zhiguo Wang Baoyu Li Liang Gu 《Journal of Beijing Institute of Technology》 EI CAS 2018年第4期510-517,共8页
Vehicle riding comfort and handling stability are directly affected by suspension performance.A novel dual chamber hydro-pneumatic(DCHP)suspension system is developed in this paper.Based on the structural analysis of ... Vehicle riding comfort and handling stability are directly affected by suspension performance.A novel dual chamber hydro-pneumatic(DCHP)suspension system is developed in this paper.Based on the structural analysis of the DCHP suspension,an equivalent suspension model is proposed for the control purpose.A cuckoo search(CS)based fuzzy PID controller is proposed for the control of the DCHP suspension system.The proposed controller combines the advantage of fuzzy logic and PID controller,and CS algorithm is used to regulate the membership functions and PID parameters.Compared with tradition LQR controller and passive suspension system,the CSFPID controller can reduce the sprung mass acceleration,and at the same time with no deterioration of tire deflection. 展开更多
关键词 vehicle dynamics dual chamber hydro-pneumatic(DCHP)suspension cuckoo search(CS) fuzzy PID
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Control algorithm for vehicle height adjustable system of hydro-pneumatic suspension based on LuGre model 被引量:2
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作者 赵丰 管继富 +3 位作者 顾亮 李毅 刘锐 张华 《Journal of Beijing Institute of Technology》 EI CAS 2016年第1期49-55,共7页
In order to control the vehicle body position precisely,1/4 nonlinear mathematical model of hydro-pneumatic suspension is established,and the influence of the frictional force in a hydraulic cylinder is analyzed.The f... In order to control the vehicle body position precisely,1/4 nonlinear mathematical model of hydro-pneumatic suspension is established,and the influence of the frictional force in a hydraulic cylinder is analyzed.The friction characteristics are described based on the LuGre model when the piston of a hydraulic actuator is operated at a low speed.Due to the fact parameters of the friction model are effected by the system condition,an adaptive friction compensation(AFC)controller is designed through the Backstepping method,and a dual-observer has been implemented to estimate the friction state.The global asymptotic convergence of a closed-loop system is proven by the Lyapunov theorem.The simulation results show that the positional accuracy of the adaptive friction compensation yiedls a significant improvement in the vehicle height adjustment as compared to the PID control,demonstrating the effectiveness of the adaptive fiction compensation method in the vehicle height adjustable system of the hydro-pneumatic suspension. 展开更多
关键词 LuGre model friction compensation dual-observer hydro-pneumatic suspension
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Experimental study on wheeled vehicle hydro-pneumatic suspension fault detection
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作者 赵丰 管继富 +1 位作者 顾亮 雷雪媛 《Journal of Beijing Institute of Technology》 EI CAS 2016年第2期181-186,共6页
A four-channel MTS road simulation system,which is used to regenerate the acceleration signal at the axle head is presented. A new fault detection method is proposed,which is based on the remote parameter control( RP... A four-channel MTS road simulation system,which is used to regenerate the acceleration signal at the axle head is presented. A new fault detection method is proposed,which is based on the remote parameter control( RPC) technology for vehicle hydro-pneumatic suspension system. The transfer function between the drive signals and the axle head acceleration should be identified before the RPC iterative calculation on a computer. By contrasting with the desired frequency response functions( FRF),excited through the sample spectrum of road,the iterative convergence speed of the drive function and weighted error are used to detect faults existing in the vehicle's suspension. Experimental results show that during the process of regeneration of the acceleration signal at the axle head,the characteristics of failure of the hydro-pneumatic spring are changed randomly resulting in a dramatic increase in calculation of the RPC iterative,which enables relatively large iterative convergence errors. This method can quickly detect and locate a suspension fault and is a simple bench test way in suspension fault detection. 展开更多
关键词 hydro-pneumatic suspension fault detection iterative calculation
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Low-frequency ride comfort of vibratory rollers equipped with cab hydro-pneumatic mounts
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作者 Nguyen Van Liem Zhang Jianrun +1 位作者 Lu Xi Huang Dacheng 《Journal of Southeast University(English Edition)》 EI CAS 2020年第3期278-284,共7页
Based on the advantages of hydraulic and pneumatic mounts,a new hydro-pneumatic mount(HPM)is proposed to improve the low-frequency ride comfort of vibration rollers.Through the experiment of the vibratory roller,a non... Based on the advantages of hydraulic and pneumatic mounts,a new hydro-pneumatic mount(HPM)is proposed to improve the low-frequency ride comfort of vibration rollers.Through the experiment of the vibratory roller,a nonlinear vehicle dynamic model working on off-road soil grounds is then established to assess the HPM's ride comfort in the low-frequency region.Two indices,the power spectral density(PSD)acceleration and root mean square(RMS)acceleration of the operator vibration and cab shaking,are chosen as objective functions in both the frequency and time regions.The research results show that when the cab isolations are equipped with the HPM,the RMS values of the operator's seat,cab's pitch and roll angles are reduced by 35%,42%and 53%;and the maximum PSD of the operator's seat,cab's pitch and roll angles are decreased by 39%,59%and 65%,respectively.Consequently,the characteristics of the nonlinear damper and high-static stiffness of HPM can greatly reduce the operator vibration and cab shaking in the low-frequency region when compared to the vibratory roller's cab using the rubber mounts. 展开更多
关键词 vibratory roller quality ride hydro-pneumatic mount low-frequency vibrations
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Study on Outboard Inductive Damping Valve in Hydro-pneumatic Suspension
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作者 王勋 陈思忠 《Defence Technology(防务技术)》 SCIE EI CAS 2011年第1期1-8,共8页
A new outboard inductive damping valve without any electronic control system is developed. Its working principle,structure and external characteristic are studied. Its mathematical model is presented and its damping c... A new outboard inductive damping valve without any electronic control system is developed. Its working principle,structure and external characteristic are studied. Its mathematical model is presented and its damping characteristic is investigated on the basis of fluid continuity equation,differential equations of motion and Bernoulli equation. The influence of the valve parameters on the damping characteristic is studied numerically. The effects of outboard inductive damping valve and common damping valve on ride and tire load are compared also. The external characteristic of the valve is verified in bench test. The results show that the valve’s mathematical model is quite accurate and the developed valve can be adjust in two stages,which can also meet the requirements of the dynamic characteristic of the vehicle suspension system. 展开更多
关键词 turn and control of fluid hydro-pneumatic suspension outboard inductive damping valve external characteristic
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Testing Research of Accumulator Performance in the Hydro-pneumatic Suspension of a Vehicle
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作者 FENG Shi cai, XU Yong, LU Hong yu Industrial College of Xuzhou Normal University, Jiangsu 221011, P.R.China 《International Journal of Plant Engineering and Management》 2001年第3期118-123,共6页
Taking a 2.5 liter accumulator with hydro-pneumatic suspension in a CXP1032 crane made in Germany as the research object and taking both the overall-road simulative test-bed and the control equipment made by the Schen... Taking a 2.5 liter accumulator with hydro-pneumatic suspension in a CXP1032 crane made in Germany as the research object and taking both the overall-road simulative test-bed and the control equipment made by the Schenck Company of Germany as the testing instrument, the structure performance and mechanism are theoretically clarified and the variation of gas states are obtained. This illustrates the accumulating and releasing process of a 2.5 liter accumulator in a 32t crane in the real condition. The preliminary volume and pressure of accumulator would directly affect the stiffness performance of the hydro-pneumatic suspension in a vehicle. 展开更多
关键词 hydro-pneumatic suspension ACCUMULATOR performance testing changing expo-nent
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Aluminum foam as buffer layer used in soft rock tunnel with large deformation 被引量:1
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作者 WU Faquan MIAO Binxin +2 位作者 TIAN Yun ZHANG Fang ZHANG Chaoxuan 《Journal of Mountain Science》 2025年第1期324-336,共13页
The squeezing deformation of surrounding rock is an important factor restricting the safe construction and long-term operation of tunnels when a tunnel passes through soft strata with high ground stress.Under such sof... The squeezing deformation of surrounding rock is an important factor restricting the safe construction and long-term operation of tunnels when a tunnel passes through soft strata with high ground stress.Under such soft rock geological conditions,the large deformation of the surrounding rock can easily lead to the failure of supporting structures,including shotcrete cracks,spalling,and steel arch distortion.To improve the lining support performance during the large deformation of squeezed surrounding rock,this work selects aluminum foam with densities of 0.25 g/cm3,0.42 g/cm3 and 0.61 g/cm3 as the buffer layer material and carries out uniaxial confined compression tests.Through the evaluation and analysis of energy absorption and the comparison of the yield pressure of aluminum foam with those of other cushioning materials and yield pressure support systems,the strength,deformation and energy absorption of aluminum foam with a density of 0.25 g/cm3 meet the yield pressure performance requirements.The numerical model of the buffer layer yielding support system is then established via the finite element analysis software ABAQUS,and the influence of the buffer layer setting on the lining support is analyzed.Compared with the conventional support scheme,the addition of an aluminum foam buffer layer can reduce the stress and deformation of the primary support and secondary lining.The maximum and minimum principal stresses of the primary support are reduced by 13%and 15%,respectively.The maximum and minimum principal stresses of the secondary lining are reduced by 15%and 12%,respectively,and the displacement deformation of the secondary lining position is reduced by 15%.In summary,the application of aluminum foam buffer layer can reduce the stress and deformation of the primary support and secondary lining,improve the stress safety of the support and reduce the deformation of the support. 展开更多
关键词 Soft rock tunnel Uniaxial confined compression Aluminum foam buffer layer Yielding support
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Effects of the buffer layer on the Casimir pressure of peptide films deposited on a substrate
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作者 Dingding Lv Shuai Zhou +2 位作者 Kaipeng Liu Shiwei Dai Lixin Ge 《Chinese Physics B》 2025年第10期385-390,共6页
The Casimir pressure plays an important role in the adhesion stability of nanofilms at submicro scales.In this work,the Casimir pressure of peptide films deposited on a layered substrate is investigated.Three types of... The Casimir pressure plays an important role in the adhesion stability of nanofilms at submicro scales.In this work,the Casimir pressure of peptide films deposited on a layered substrate is investigated.Three types of semi-infinite substrates,i.e.,silica,silicon and gold,are considered.The buffer layer between the peptide film and substrate consists of silicon or silica.The switching sign of the Casimir pressure can be controlled in a region ranging from about 130 nm to 1000 nm,depending on the thickness of the buffer layer and the substrate.The results suggest that the critical thickness of peptide films for Casimir equilibrium increases(or decreases)by increasing the thickness of the silicon(or silica)buffer film.The influences of wetting and electrolyte screening on the Casimir pressure are also investigated.Our finding provides a theoretical guide for the adhesion stability of peptide films in organic electronics. 展开更多
关键词 Casimir pressure buffer layer peptide films electrolyte screening
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Review of imaging buffers used in stochastic optical reconstruction microscopy
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作者 Can Wang Zhe Sun Donghan Ma 《Chinese Chemical Letters》 2025年第9期56-63,共8页
Stochastic optical reconstruction microscopy(STORM),as a typical technique of single-molecule localization microscopy(SMLM),has overcome the diffraction limit by randomly switching fluorophores between fluorescent and... Stochastic optical reconstruction microscopy(STORM),as a typical technique of single-molecule localization microscopy(SMLM),has overcome the diffraction limit by randomly switching fluorophores between fluorescent and dark states,allowing for the precise localization of isolated emission patterns and the super-resolution reconstruction from millions of localized positions of single fluorophores.A critical factor influencing localization precision is the photo-switching behavior of fluorophores,which is affected by the imaging buffer.The imaging buffer typically comprises oxygen scavengers,photo-switching reagents,and refractive index regulators.Oxygen scavengers help prevent photobleaching,photo-switching reagents assist in facilitating the conversion of fluorophores,and refractive index regulators are used to adjust the refractive index of the solution.The synergistic interaction of these components promotes stable blinking of fluorophores,reduces irreversible photobleaching,and thereby ensures high-quality super-resolution imaging.This review provides a comprehensive overview of the essential compositions and functionalities of imaging buffers used in STORM,serving as a valuable resource for researchers seeking to select appropriate imaging buffers for their experiments. 展开更多
关键词 Single-molecule localization microscopy Stochastic optical reconstruction microscopy Photo-switching Photobleaching Imaging buffer
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A moving model test of a maglev train passing through tunnels:Effect of train speed and buffer structure on aerodynamic environment
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作者 GUO Zi-jian CHEN Zheng-wei +2 位作者 GUO Zhan-hao ZENG Guang-zhi PENG Cheng 《Journal of Central South University》 2025年第12期4868-4884,共17页
Maglev trains experience significant aerodynamic effects when passing through tunnels.A moving model test was conducted to explore the practical effects of speed reduction and entrance buffer structures on mitigating ... Maglev trains experience significant aerodynamic effects when passing through tunnels.A moving model test was conducted to explore the practical effects of speed reduction and entrance buffer structures on mitigating tunnel/maglev aerodynamic effects.It is found that both have an overall positive effect on mitigating the aerodynamic environment inside and outside the tunnel.Trains operating at 200 km/h show a 49.8%decrease in peak-to-peak pressure and a 50.7%decrease in transient pressure instability on inner walls compared to those at 280 km/h.Lower speeds resulted in a 65.6%decrease in amplitude and a 24.5%decrease in decay rate,both of which are parameters for exponential fittings of pressure peaks that decay naturally after the train leaves.The buffer structures result in a reduction of up to 25.7%in the maximum positive pressure and a 29.0%decrease in transient pressure instability.Additionally,a reduction in amplitude of up to 21.2%and a 32.2%increase in decay rate were observed with the use of buffer structures.Nevertheless,it is difficult to conclude direct correlations between the maximum pressure,peak-to-peak values,etc.,and the speeds or buffer structures due to the complex wave propagation in tunnels.However,speed reduction and buffer structures are proven to be effective in reducing the micro-pressure wave levels with a simpler monotonic relationship. 展开更多
关键词 maglev train TUNNEL moving model test buffer structure micro-pressure wave
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Atmospheric‑pressure ion transfer in a gas flow device connected to the UniCell buffer gas cell for superheavy elements chemistry:simulation studies
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作者 Yeqiang Wei Alexander Yakushev +2 位作者 Jochen Ballof Jörg Krier Christoph E.Düllmann 《Nuclear Science and Techniques》 2025年第10期87-97,共11页
Man-made superheavy elements(SHE)are produced as energetic recoils in complete-fusion reactions and need to be thermalized in a gas-filled chamber for chemical studies.The ever-shorter half-lives and decreasing produc... Man-made superheavy elements(SHE)are produced as energetic recoils in complete-fusion reactions and need to be thermalized in a gas-filled chamber for chemical studies.The ever-shorter half-lives and decreasing production rates of the elements beyond Fl(atomic number Z=114)-the heaviest element chemically studied today-require the development of novel techniques for quantitative thermalization and fast extraction efficiency.The Universal high-density gas stopping Cell(UniCell),currently under construction,was proposed to achieve this.Within this work,we propose an Ion Transfer by Gas Flow(ITGF)device,which serves as a UniCell ejector to interface with a gas chromatography detector array for chemical studies.Detailed parameter optimizations,using gas dynamics and Monte Carlo ion-trajectory simulations,promise fast(within a few ms)and highly efficient(up to 100%)ion extraction across a wide mass range.These ions can then be transmitted quantitatively through the ITGF into the high-pressure environment needed for further chemical studies. 展开更多
关键词 Superheavy elements buffer gas cell Ion funnel Fast extraction ATMOSPHERIC-PRESSURE Chemical studies
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Unveiling the buffering impacts of temperate forests on enhancing grain yields through regional biogeophysical climate modification
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作者 Lingxue Yu Zhuoran Yan +4 位作者 Tingxiang Liu Xuan Li Jiaxuan Li Kun Bu Wen J.Wang 《Geography and Sustainability》 2025年第5期127-139,共13页
Temperate forests exert significant biogeophysical influences on local and regional climates through modulating the energy and moisture exchanges between the land surface and the atmosphere,thereby serving as crucial ... Temperate forests exert significant biogeophysical influences on local and regional climates through modulating the energy and moisture exchanges between the land surface and the atmosphere,thereby serving as crucial barriers with significant buffering impacts on the productivity of adjacent agricultural ecosystems.However,the extent and underlying mechanisms of these biogeophysical and buffering effects of temperate forest barriers remains insufficiently understood.In this study,we integrated the dynamic crop model Noah-MP-Crop with the Weather Research and Forecasting(WRF)model to investigate the biogeophysical climate regulation of temperate forests and its buffering effects on crop yields in adjacent agricultural lands across Northeast China.Our findings revealed that temperate forest barriers induced significant local climate effects by cooling air and surface temperatures and reducing wind speeds within forested areas during the growing season,while also regulating non-local climate,particularly by altering regional precipitation patterns,2 m water vapor mixing ratio(Q2),and soil moisture,predominantly in adjacent cropland areas.Furthermore,these forest barriers were found to modulate climate extremes,through affecting maximum temperature and wind speed on a local scale,as well as both maximum and minimum Q2 in non-local croplands.Our study also observed that temperate forest barriers,through biogeophysical climate regulation,enhanced GPP,NPP,and grain yields across most cropland areas.This productivity boost was especially pronounced,with yield increases up to 20%in certain regions during the extreme drought conditions of 2017,underscoring the critical role of temperate forest barriers in sustaining and enhancing crop yields under severe climatic stress.Our findings underscore the significant buffering effects of temperate forest barriers on regional agricultural production,having important implications for climate adaptation strategies aimed at bolstering agricultural resilience in the face of increasing climate variability and extremes. 展开更多
关键词 Temperate forests Regional climate buffering impact Grain yields WRF model Extreme drought
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Multi-Level Subpopulation-Based Particle Swarm Optimization Algorithm for Hybrid Flow Shop Scheduling Problem with Limited Buffers
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作者 Yuan Zou Chao Lu +1 位作者 Lvjiang Yin Xiaoyu Wen 《Computers, Materials & Continua》 2025年第8期2305-2330,共26页
The shop scheduling problem with limited buffers has broad applications in real-world production scenarios,so this research direction is of great practical significance.However,there is currently little research on th... The shop scheduling problem with limited buffers has broad applications in real-world production scenarios,so this research direction is of great practical significance.However,there is currently little research on the hybrid flow shop scheduling problem with limited buffers(LBHFSP).This paper deeply investigates the LBHFSP to optimize the goal of the total completion time.To better solve the LBHFSP,a multi-level subpopulation-based particle swarm optimization algorithm(MLPSO)is proposed,which is founded on the attributes of the LBHFSP and the shortcomings of the basic PSO(particle swarm optimization)algorithm.In MLPSO,firstly,considering the impact of the limited buffers on the process of subsequent operations,a specific circular decoding strategy is developed to accommodate the characteristics of limited buffers.Secondly,an initialization strategy based on blocking time is designed to enhance the quality and diversity of the initial population.Afterward,a multi-level subpopulation collaborative search is developed to prevent being trapped in a local optimum and improve the global exploration capability.Additionally,a local search strategy based on the first blocked job is designed to enhance the MLPSO algorithm’s exploitation capability.Lastly,numerous experiments are carried out to test the performance of the proposed MLPSO by comparing it with classical intelligent optimization and popular algorithms in recent years.The results confirm that the proposed MLPSO has an outstanding performance when compared to other algorithms when solving LBHFSP. 展开更多
关键词 Hybrid flow shop scheduling problem limited buffers PSO algorithm collaborative search blocking phenomenon
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Tris-buffered efficacy:enhancing stability and reversibility of Zn anode by efficient modulation at Zn/electrolyte interface
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作者 Yong-Jian Wang Su-Hong Li +3 位作者 Lin Li Jian-Yong Ren Ling-Di Shen Chao Lai 《Rare Metals》 2025年第2期925-937,共13页
Aqueous zinc-ion batteries(AZIBs)have developed rapidly in recent years but still face several challenges,including zinc dendrites growth,hydrogen evolution reaction,passivation and corrosion.The pH of the electrolyte... Aqueous zinc-ion batteries(AZIBs)have developed rapidly in recent years but still face several challenges,including zinc dendrites growth,hydrogen evolution reaction,passivation and corrosion.The pH of the electrolyte plays a crucial role in these processes,significantly impacting the stability and reversibility of Zn^(2+)deposition.Therefore,pH-buffer tris(hydroxymethyl)amino methane(tris)is chosen as a versatile electrolyte additive to address these issues.Tris can buffer electrolyte pH at Zn/electrolyte interface by protonated/deprotonated nature of amino group,optimize the coordination environment of zinc solvate ions by its strong interaction with zinc ions,and simultaneously create an in-situ stable solid electrolyte interface membrane on the zinc anode surface.These synergistic effects effectively restrain dendrite formation and side reactions,resulting in a highly stable and reversible Zn anode,thereby enhancing the electrochemical performance of AZIBs.The Zn||Zn battery with 0.15 wt%tris additives maintains stable cycling for 1500 h at 4 mA·cm^(−2) and 1120 h at 10 mA·cm^(−2).Furthermore,the Coulombic efficiency reaches~99.2%at 4 mA·cm^(−2)@1 mAh·cm^(−2).The Zn||NVO full batteries also demonstrated a stable specific capacity and exceptional capacity retention. 展开更多
关键词 Zn metal anode Hydrogen evolution reaction TRIS pH buffer Zn/electrolyte interface
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Long-term photocatalytic hydrogen peroxide production by hydroquinone-buffered covalent organic frameworks
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作者 Chang Shu Xiaoju Yang +3 位作者 Peixuan Xie Xuan Yang Bien Tan Xiaoyan Wang 《Chinese Journal of Catalysis》 2025年第6期300-310,共11页
Photocatalytic hydrogen peroxide(H_(2)O_(2))production offers a sustainable route to convert water and oxygen into H_(2)O_(2)using solar energy.However,achieving long-term stability in photocatalysts remains a critica... Photocatalytic hydrogen peroxide(H_(2)O_(2))production offers a sustainable route to convert water and oxygen into H_(2)O_(2)using solar energy.However,achieving long-term stability in photocatalysts remains a critical challenge due to mismatched kinetics between oxygen reduction(ORR)and water oxidation(WOR),which leads to hole accumulation and oxidative degradation.Here,we report a redox-mediated strategy to address this bottleneck by designing a hydroquinone-embedded covalent organic framework(Tz-QH-COF)that enables reversible hole buffering and kinetic balance.The hydroquinone(QH)units act as dynamic hole reservoirs,capturing excess holes during ORR and converting to benzoquinone(Q),which is regenerated to QH via WOR,thereby preventing oxidative decomposition.This reversible QH/Q cycle,directly visualized through in situ attenuated total reflection surface-enhanced infrared absorption spectroscopy,ensures unmatched stability,achieving continuous H_(2)O_(2) production for 528 h(22 d)with an accumulated yield of 18.6 mmol L^(–1)—the highest reported duration for organic photocatalysts.Density functional theory calculations reveal that the QH units exhibit a strong oxygen adsorption energy and favorable two-electron ORR/WOR pathways with low energy barriers.The synergy between experimental and theoretical insights elucidates a redox-mediated charge-balance mechanism,advancing the design of robust photocatalysts for solar-driven H_(2)O_(2) synthesis. 展开更多
关键词 Covalent organic frameworks Hole buffer Reversible redox chemistry Hydroquinone-quinone transformation Long-term photocatalytic hydrogen peroxide production
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Construction of a Linear Engineering Visual Landscape Interference Model for the Buffer Zone of the Libo Heritage Site Based on the AHP-Fuzzy Comprehensive Evaluation Method:A Case Study of the Guiyang-Nanning High-Speed Railway
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作者 WEI Wei MA Zhenrui XIAO Shizhen 《Journal of Landscape Research》 2025年第5期12-19,共8页
The buffer zone of a World Natural Heritage Site constitutes a critical element of the heritage site protection system.It not only functions as an ecological security barrier,but also significantly influences the visu... The buffer zone of a World Natural Heritage Site constitutes a critical element of the heritage site protection system.It not only functions as an ecological security barrier,but also significantly influences the visual integrity and aesthetic value of the core area’s landscape.Given the rapid development of transportation infrastructure,particularly the growing number of high-speed railways traversing ecologically sensitive regions,the scientific assessment of their impact on the landscape environment of heritage sites has emerged as a pivotal concern in heritage conservation and regional development.This study focused on the section of the Guiyang-Nanning High-Speed Railway that traverses the buffer zone of the Libo World Natural Heritage Site in Guizhou Province.Beginning with five primary indicators,including natural landscape and aesthetic value,geological geomorphology and Earth history value,biodiversity value,integrity and protection management,and impact on ecological environment,a visual landscape impact assessment system for high-speed railways was developed based on the analytic hierarchy process(AHP)and the fuzzy comprehensive evaluation method(FCE).Through expert scoring,hierarchical weight calculation,and fuzzy membership degree analysis,a comprehensive assessment was conducted on the landscape ecological quality,visual coordination,and aesthetic perception within the buffer zone following the construction of high-speed railways.The findings indicate that the construction of the Guiyang-Nanning High-Speed Railway generally harmonizes well with the landscape environment of the heritage site.The level of visual disturbance remains within an acceptable range and has not significantly damaged the overall aesthetic value or authenticity of the heritage site.Although the integrity of the landscape in certain local areas has experienced a slight decline due to the exposure of bridge and slope structures,the adverse effects have been effectively mitigated through engineering interventions such as vegetation restoration and color coordination.This study innovatively integrates the AHP with fuzzy mathematics methods to achieve a comprehensive evaluation that combines both qualitative and quantitative approaches.This integration provides a scientifically grounded analytical path and a practical technical framework for assessing the visual impact of linear infrastructure projects,such as high-speed railways,within the buffer zones of World Heritage Sites.The findings offer valuable insights for the protection of landscapes and the sustainable development of infrastructure in heritage sites. 展开更多
关键词 Heritage site buffer zone Analytic hierarchy process(AHP) Fuzzy comprehensive evaluation method(FCE)
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