To improve separate effect of binary heterogeneous azeotrope in the magnetic field with different magnetic induction intensity, the influence of magnetic field on the rectification process of binary heterogeneous azeo...To improve separate effect of binary heterogeneous azeotrope in the magnetic field with different magnetic induction intensity, the influence of magnetic field on the rectification process of binary heterogeneous azeotrope was investigated with l-butanol-water system. The results show that the composition of liquid-liquid phase equilibrium of l-butanol-water system has definitely changed, the composition of l-butanol in light phase （l-butanol layer） increases by 1. 17%-1.63% and the composition of water in heavy phase （water layer） increases by 1.21%-1.58% under the influence of magnetic field. By separation of magnetization, the composition of l-butanol increases by 0.8%-1.2% and the recovery ratio of 1 -butanol increases by 1.6%-2.5%. Magnetic field has positive effect, however, the magnetized effect is not in proportion to magnetic induction intensity and has an optimum condition, in the range of 0.25 T-0. 3 T.展开更多
The three-dimensional particle electrode system exhibits significant potential for application in the treatment of wastewater.Nonetheless,the advancement of effective granular electrodes characterized by elevated cata...The three-dimensional particle electrode system exhibits significant potential for application in the treatment of wastewater.Nonetheless,the advancement of effective granular electrodes characterized by elevated catalytic activity and minimal energy consumption continues to pose a significant challenge.In this research,Fluorine-doped copper-carbon(F/Cu-GAC)particle electrodes were effectively synthesized through an impregnationcalcination technique,utilizing granular activated carbon as the carrier and fluorinedoped modified copper oxides as the catalytic agents.The particle electrodes were subsequently utilized to promote the degradation of 2,4,6-trichlorophenol(2,4,6-TCP)in a threedimensional electrocatalytic reactor(3DER).The F/Cu-GAC particle electrodes were polarized under the action of electric field,which promoted the heterogeneous Fenton-like reaction in which H2O2 generated by two-electron oxygen reduction reaction(2e-ORR)of O_(2) was catalytically decomposed to·OH.The 3DER equipped with F/Cu-GAC particle electrodes showed 100%removal of 2,4,6-TCP and 79.24%removal of TOC with a specific energy consumption(EC)of approximately 0.019 kWh/g·COD after 2 h of operation.The F/Cu-GAC particle electrodes exhibited an overpotential of 0.38 V and an electrochemically active surface area(ECSA)of 715 cm^(2),as determined through linear sweep voltammetry(LSV)and cyclic voltammetry(CV)assessments.These findings suggest a high level of electrocatalytic performance.Furthermore,the catalytic mechanism of the 3DER equipped with F/Cu-GAC particle electrodes was elucidated through the application of X-ray photoelectron spectroscopy(XPS),electron spin resonance(ESR),and active species capture experiments.This investigation offers a novel approach for the effective degradation of 2,4,6-TCP.展开更多
This paper proposes an asynchronous heterogeneous propagation approach of concurrent competitive waves for hyper-distributed hyper-parallel heuris tic problem-solving. This approach is much more powerful than the sync...This paper proposes an asynchronous heterogeneous propagation approach of concurrent competitive waves for hyper-distributed hyper-parallel heuris tic problem-solving. This approach is much more powerful than the synchronous homogeneous mechanisms and the asynchronous superimposition algorithms, and has universal validity and availability. The basic conception, concurrent algorithm and its properties are discussed. The theory and conclusions drawn in this paper are of essential importance for the hardware implementation of hyper-distributed hyper-parallel processing based on chaotic cellular networks.展开更多
Heterogeneous Fenton-like reaction shows great potential for eliminating organic substances (e.g. emerging organic contaminants (EOCs)) in water, which has been widely explored in recent decades. However, the catalyti...Heterogeneous Fenton-like reaction shows great potential for eliminating organic substances (e.g. emerging organic contaminants (EOCs)) in water, which has been widely explored in recent decades. However, the catalytic mechanisms reported in current studies are extremely complicated because multiple mechanisms coexist and contribute to the removal efficiencies. Most importantly, heterogeneous systems show selective oxidation properties, which are crucial for improving the efficiencies in the catalytic elimination of organic substances. Thus, this critical review summarizes and compares the diverse existing mechanisms (non-radical and radical pathways) in heterogeneous catalytic processes based on recent studies. The typical oxidation mechanisms during selective advanced oxidation of EOCs were systematically discussed based on the following sections, including the selective adsorption and generation of reactive oxygen species (ROS) in photo/electron-Fenton and Fenton-like systems. Moreover, the non-radical pathways are discussed in depth by the singlet oxygen, high-valent metal-oxo, electron transfer process, etc. Moreover, the direct oxidative transfer process for the removal of EOCs was introduced in recent studies. Finally, the cost, feasibility as well as the sustainability of heterogeneous Fenton-like catalysts are summarized. This review offers useful guidance for developing suitable strategies to develop materials for decomposing the organic substrates.展开更多
A space-ground integrated network(SGIN)will be a future network for the heterogeneous convergence of space-and ground-based networks.The SGIN envisions satellites with the capability to adapt to various communication ...A space-ground integrated network(SGIN)will be a future network for the heterogeneous convergence of space-and ground-based networks.The SGIN envisions satellites with the capability to adapt to various communication protocols,enabling the convergence of diverse network systems.A crucial aspect of satellite payload in the SGIN is the recognition of satellite signal types and their modulation modes,which substantially enhances the processing of heterogeneous wireless signals at the baseband processing.A multitask learning(MTL)model-based convolutional neural network(CNN)architecture is proposed,which addresses the recognition problem.An MTL model-based CNN architecture is proposed,which addresses the recognition problem.This model is composed of 3 key components:A multi-input part that processes in-phase/quadrature(IQ)complex signals and power spectral density data,a set of shared part that facilitates the model’s efficiency and mitigate overfitting,and a multitask output part capable of concurrently recognizing signal types and modulation modes.Furthermore,we have developed a dataset that encompasses 5 satellite signal protocols,i.e.,signal type,and 6 modulation modes,derived from the digital video broadcasting(DVB)protocols and the tracking,telemetry,and command(TT&C)standards of the consultative committee for space data systems(CCSDS).This dataset also takes into account the impact of the additive white Gaussian noise(AWGN)channel and land mobile satellite(LMS)channel models.Simulation experiments validate the effectiveness of the proposed MTL model in accurately identifying various satellite signal protocols and modulation techniques.展开更多
基金Supported by Natural Science Foundation of Tianjin (No.033603611).
文摘To improve separate effect of binary heterogeneous azeotrope in the magnetic field with different magnetic induction intensity, the influence of magnetic field on the rectification process of binary heterogeneous azeotrope was investigated with l-butanol-water system. The results show that the composition of liquid-liquid phase equilibrium of l-butanol-water system has definitely changed, the composition of l-butanol in light phase （l-butanol layer） increases by 1. 17%-1.63% and the composition of water in heavy phase （water layer） increases by 1.21%-1.58% under the influence of magnetic field. By separation of magnetization, the composition of l-butanol increases by 0.8%-1.2% and the recovery ratio of 1 -butanol increases by 1.6%-2.5%. Magnetic field has positive effect, however, the magnetized effect is not in proportion to magnetic induction intensity and has an optimum condition, in the range of 0.25 T-0. 3 T.
基金supported by Guangxi Science and Technology Major Program(No.AA23073008)Hubei Key Laboratory of Water System Science for Sponge City Construction(Wuhan University)(No.2023–05)Nanning Innovation and Entrepreneur Leading Talent Project(No.2021001).
文摘The three-dimensional particle electrode system exhibits significant potential for application in the treatment of wastewater.Nonetheless,the advancement of effective granular electrodes characterized by elevated catalytic activity and minimal energy consumption continues to pose a significant challenge.In this research,Fluorine-doped copper-carbon(F/Cu-GAC)particle electrodes were effectively synthesized through an impregnationcalcination technique,utilizing granular activated carbon as the carrier and fluorinedoped modified copper oxides as the catalytic agents.The particle electrodes were subsequently utilized to promote the degradation of 2,4,6-trichlorophenol(2,4,6-TCP)in a threedimensional electrocatalytic reactor(3DER).The F/Cu-GAC particle electrodes were polarized under the action of electric field,which promoted the heterogeneous Fenton-like reaction in which H2O2 generated by two-electron oxygen reduction reaction(2e-ORR)of O_(2) was catalytically decomposed to·OH.The 3DER equipped with F/Cu-GAC particle electrodes showed 100%removal of 2,4,6-TCP and 79.24%removal of TOC with a specific energy consumption(EC)of approximately 0.019 kWh/g·COD after 2 h of operation.The F/Cu-GAC particle electrodes exhibited an overpotential of 0.38 V and an electrochemically active surface area(ECSA)of 715 cm^(2),as determined through linear sweep voltammetry(LSV)and cyclic voltammetry(CV)assessments.These findings suggest a high level of electrocatalytic performance.Furthermore,the catalytic mechanism of the 3DER equipped with F/Cu-GAC particle electrodes was elucidated through the application of X-ray photoelectron spectroscopy(XPS),electron spin resonance(ESR),and active species capture experiments.This investigation offers a novel approach for the effective degradation of 2,4,6-TCP.
文摘This paper proposes an asynchronous heterogeneous propagation approach of concurrent competitive waves for hyper-distributed hyper-parallel heuris tic problem-solving. This approach is much more powerful than the synchronous homogeneous mechanisms and the asynchronous superimposition algorithms, and has universal validity and availability. The basic conception, concurrent algorithm and its properties are discussed. The theory and conclusions drawn in this paper are of essential importance for the hardware implementation of hyper-distributed hyper-parallel processing based on chaotic cellular networks.
基金financially supported by the National Natural Science Foundation of China(Nos.21625102,21971017,and 21906007)the National Key Research and Development Program of China(No.2020YFB1506300)the Beijing Institute of Technology Research Fund Program.
文摘Heterogeneous Fenton-like reaction shows great potential for eliminating organic substances (e.g. emerging organic contaminants (EOCs)) in water, which has been widely explored in recent decades. However, the catalytic mechanisms reported in current studies are extremely complicated because multiple mechanisms coexist and contribute to the removal efficiencies. Most importantly, heterogeneous systems show selective oxidation properties, which are crucial for improving the efficiencies in the catalytic elimination of organic substances. Thus, this critical review summarizes and compares the diverse existing mechanisms (non-radical and radical pathways) in heterogeneous catalytic processes based on recent studies. The typical oxidation mechanisms during selective advanced oxidation of EOCs were systematically discussed based on the following sections, including the selective adsorption and generation of reactive oxygen species (ROS) in photo/electron-Fenton and Fenton-like systems. Moreover, the non-radical pathways are discussed in depth by the singlet oxygen, high-valent metal-oxo, electron transfer process, etc. Moreover, the direct oxidative transfer process for the removal of EOCs was introduced in recent studies. Finally, the cost, feasibility as well as the sustainability of heterogeneous Fenton-like catalysts are summarized. This review offers useful guidance for developing suitable strategies to develop materials for decomposing the organic substrates.
基金supported by the National Key Research and Development Program(grant number 2021Y FB2900604)Young Elite Scientists Sponsorship Program by CAST(grant number 2022QNRC001).
文摘A space-ground integrated network(SGIN)will be a future network for the heterogeneous convergence of space-and ground-based networks.The SGIN envisions satellites with the capability to adapt to various communication protocols,enabling the convergence of diverse network systems.A crucial aspect of satellite payload in the SGIN is the recognition of satellite signal types and their modulation modes,which substantially enhances the processing of heterogeneous wireless signals at the baseband processing.A multitask learning(MTL)model-based convolutional neural network(CNN)architecture is proposed,which addresses the recognition problem.An MTL model-based CNN architecture is proposed,which addresses the recognition problem.This model is composed of 3 key components:A multi-input part that processes in-phase/quadrature(IQ)complex signals and power spectral density data,a set of shared part that facilitates the model’s efficiency and mitigate overfitting,and a multitask output part capable of concurrently recognizing signal types and modulation modes.Furthermore,we have developed a dataset that encompasses 5 satellite signal protocols,i.e.,signal type,and 6 modulation modes,derived from the digital video broadcasting(DVB)protocols and the tracking,telemetry,and command(TT&C)standards of the consultative committee for space data systems(CCSDS).This dataset also takes into account the impact of the additive white Gaussian noise(AWGN)channel and land mobile satellite(LMS)channel models.Simulation experiments validate the effectiveness of the proposed MTL model in accurately identifying various satellite signal protocols and modulation techniques.
