A nickel-catalyzed C(sp^(2))–H alkynylation of unprotected α-substituted benzylamines is achieved by utilizing a transient directing group. The combination of a TDG with a nickel catalyst significantly improves the ...A nickel-catalyzed C(sp^(2))–H alkynylation of unprotected α-substituted benzylamines is achieved by utilizing a transient directing group. The combination of a TDG with a nickel catalyst significantly improves the reaction step and atom economy. It has been investigated that the 2,4,6-trimethylpyridine ligand was critical to achieve the optimized reactivity. This protocol provides a straightforward route for synthesizing the alkynylated free benzylamines, featuring good substrate compatibility and monoselectivity.展开更多
The transition metal-catalyzed C–H activation have been considered as increasingly useful approach for installing new functional groups onto organic small molecules due to their high step-and atom-economy,the abundan...The transition metal-catalyzed C–H activation have been considered as increasingly useful approach for installing new functional groups onto organic small molecules due to their high step-and atom-economy,the abundance of hydrocarbon compounds,and the potential for late-stage functionalization of complex organic molecules.The ortho-and meta-C-H activation and functionalization of aromatic compounds have been widely explored in recent years,however the distal para-C-H activation and functionalization has remained a significant challenge because of the difficulty in forming energetically favorable metallacyclic transition states.The utilization of appropriate directing groups or templates as well as the meticulous design of catalysts and ligands has proven to be effective in transition-metal-catalyzed remote para-C-H bonds activation and functionalization of aromatic compounds.This review aims to summarize the strategies for controlling para-selective C–H functionalization using the directing group,template engineering,and catalyst/ligand design under transition metals catalysis in recent years.展开更多
Remote ether groups could be used as directing groups to prepare fully substituted 5-ether-1,2,3-triazoles with exclusive 1,5-regioselectivities and excellent chemoselectivities. Ether group could coordinate with irid...Remote ether groups could be used as directing groups to prepare fully substituted 5-ether-1,2,3-triazoles with exclusive 1,5-regioselectivities and excellent chemoselectivities. Ether group could coordinate with iridium catalyst by lone-pair electron at a distance(up to four σ bonds) away from alkyne to control the regioselectivity by weak coordination effect. The cycloaddition reaction chemoselectively occurred at the propargyl ether moiety of diyne to give unique fully substituted 4-alkynyl-triazole.展开更多
A rhodium-catalyzed directing group promoted selective C-H olefination reaction of indolizines at the 8-position is re ported.Di-olefination at 2,8-positions also achieved with silver hexafluoroantimonate as an additi...A rhodium-catalyzed directing group promoted selective C-H olefination reaction of indolizines at the 8-position is re ported.Di-olefination at 2,8-positions also achieved with silver hexafluoroantimonate as an additive under similar reaction conditions.Weakly coordinating groups,such as ketone,alde hyde,amide and ester,were used as directing groups.The ester group can be removed under acid conditions and therefore is used as a traceless directing group.展开更多
To investigate the effect of solidification parameters on the solidification path and microstructure evolution of Ti-45Al-5Nb(at.%) alloy, Bridgman-type directional solidification and thermodynamics calculations were ...To investigate the effect of solidification parameters on the solidification path and microstructure evolution of Ti-45Al-5Nb(at.%) alloy, Bridgman-type directional solidification and thermodynamics calculations were performed on the alloy. The microstructures, micro-segregation and solidification path were investigated.The results show that the β phase is the primary phase of the alloy at growth rates of 5-20 μm·s^(-1) under the temperature gradients of 15-20 K·mm^(-1), and the primary phase is transformed into an α phase at relatively higher growth rates(V >20 μm·s^(-1)). The mainly S-segregation and β-segregation can be observed in Ti-45Al-5Nb alloy at a growth rate of 10 μm·s^(-1) under a temperature gradient of 15 K·mm^(-1). The increase of temperature gradient to 20 K·mm^(-1) can eliminate β-segregation, but has no obvious effect on S-segregation. The results also show that 5 at.% Nb addition can expand the β phase region, increase the melting point of the alloy and induce the solidification path to become complicated. The equilibrium solidification path of Ti-45Al-5Nb alloy can be described as L L→β L+β L+β→αα+β_R β→ααα→γα+γα→α_2+γγ_R+(α_2+γ), in which β_R and γ_R mean the residual β and展开更多
The Central Qilian Block is a Precambrian block in the Qilian Orogen,which has long drawn international attention for the study of orogeny and continental dynamics.The Huangyuan Group in the Datong area is one of the ...The Central Qilian Block is a Precambrian block in the Qilian Orogen,which has long drawn international attention for the study of orogeny and continental dynamics.The Huangyuan Group in the Datong area is one of the Precambrian metamorphic basement units in the Central Qilian Block and reflects metamorphism in the Barrovian garnet zone and sillimanite zone from south to north.Based on detailed fieldwork,this study presents a systematic study of petrography,mineral chemistry and phase equilibria of schists and gneisses from the two metamorphic zones.The garnet metamorphic zone is composed of micaschist,garnet-bearing micaschist and felsic leptynite,with interlayered plagioclase amphibolite.The sillimanite metamorphic zone consists of garnet-bearing biotite micaschist,sillimanite-bearing biotite-plagioclase gneiss and felsic leptynite.Garnet from the garnet metamorphic zone shows growth zoning with increasing almandine and pyrope and decreasing spessartine from core to rim.Garnet from the sillimanite metamorphic zone is almost homogeneous.Towards the outer rim,the contents of almandine and pyrope slightly decrease and grossular slightly increase.Biotite in both metamorphic zones is ferro-biotite.Plagioclase is oligoclase in garnet metamorphic zone and andesine in sillimanite metamorphic zone.Phase equilibrium modeling of a sample from garnet metamorphic zone resulted in a clockwise P-T path with a prograde stage(4.5–5.0 kbar,520–530℃),a peak P stage(9.8–10.2 kbar,560–570℃),a stage of thermal relaxation(8.0–8.5 kbar,580–590℃)and finally a retrograde stage(6.8–7.0 kbar,560–580℃).Thermodynamic modeling of a sample from the sillimanite metamorphic zone indicates a prograde stage(5.5–6.0 kbar,540–550℃)and a peak stage(7.8–8.5 kbar,660–690℃).The results indicate that the Huangyuan Group experienced medium-pressure amphibolite-facies metamorphism,which resulted from continental-continental collision between the Qaidam Block and the Central Qilian Block.展开更多
Using the (2+1)-dimensional Broer-Kaup equation as an simple example, a new direct method is developed to find symmetry groups and symmetry algebras and then exact solutions of nonlinear mathematical physical equations.
In the paper [1] the upgrade of the structure of groups has been considered, in which the concept of HX group has been raised. In this paper we will discuss the direct product of HX groups and AX groups on direct prod...In the paper [1] the upgrade of the structure of groups has been considered, in which the concept of HX group has been raised. In this paper we will discuss the direct product of HX groups and AX groups on direct product group.展开更多
Stable adsorption and direct electrochemistry of glucose oxidase （COx） occurred on nitric acid （HNO3）-treated multi-walled carbon nanotubcs （MWNTs） instead of as-received MWNTs, demonstrating the critical roles ...Stable adsorption and direct electrochemistry of glucose oxidase （COx） occurred on nitric acid （HNO3）-treated multi-walled carbon nanotubcs （MWNTs） instead of as-received MWNTs, demonstrating the critical roles of oxygen-containing groups in stable adsorption and direct electrochemistry of GOx on carbon nanotubcs （CNTs）.展开更多
A search algorithm for the detection of a direct path signal in the presence of dense multipath in indoor environment using UWB is Woposed. This algorithm is based on signal correlation and differential coefficient. S...A search algorithm for the detection of a direct path signal in the presence of dense multipath in indoor environment using UWB is Woposed. This algorithm is based on signal correlation and differential coefficient. Statistical analysis of the algorithm is given out and computer simulation results are presented to validate the effectiveness of the algorithm. The results based on the algorithm pml3osed are compared with those based on Maximum Likelihood Estimator（MLE） and Peak Tracking（PT） in the simulation which shows that this algorithm achieves the highest accuracy in most cases and gives out relatively stable results in different Signal Noise Ratio（SNR）.展开更多
A series of directional shear tests on remolded frozen soil was carried out at 10°C by using a hollow cylinder apparatus to study failure criterion under a directional shear-stress path.Directional shear tests we...A series of directional shear tests on remolded frozen soil was carried out at 10°C by using a hollow cylinder apparatus to study failure criterion under a directional shear-stress path.Directional shear tests were conducted at five shear rates(10,20,30,40,and 50 kPa/min)and five intermediate principal stress coefficients(b=0,0.25,0.5,0.75,and 1),with the mean principal stress(p=4.5 MPa)kept constant.The results show that the torsional strength and the generalized strength both increase with the increase of the shear rates.According to the failure modes of frozen soil under different shear rates,the specimens present obvious plastic failure and shear band;and the torsional shear component dominates the failure modes of hollow cylindrical specimens.A shear rate of 30 kPa/min is chosen as the loading rate in the directional shear tests of frozen soil.The shape of the failure curve in theπplane is dependent on the directional anglesαof the major prin cipal stress.It is reasonable to use the strain-hardening curves to define the deviatoric stress value atγg=15%(generalized shear strain)as the failure criterion of frozen soil under a directional shear-stress path.展开更多
The local scour around a new pile-group foundation of offshore wind turbine subjected to a bi-directional current was physically modeled with a bi-directional flow flume. In a series of experiments, the flow velocity ...The local scour around a new pile-group foundation of offshore wind turbine subjected to a bi-directional current was physically modeled with a bi-directional flow flume. In a series of experiments, the flow velocity and topography of the seabed were measured based on a system composed of plane positioning equipment and an ADV.Experimental results indicate that the development of the scour hole was fast at the beginning, but then the scour rate decreased until reaching equilibrium. Erosion would occur around each pile of the foundation. In most cases, the scour pits were connected in pairs and the outside widths of the scour holes were larger than the inner widths. The maximum scour depth occurred at the side pile of the foundation for each test. In addition, a preliminary investigation shows that the larger the flow velocity, the larger the scour hole dimensions but the shorter equilibrium time. The field maximum scour depth around the foundation was obtained based on the physical experiments with the geometric length scales of 1:27.0, 1:42.5 and 1:68.0, and it agrees with the scour depth estimated by the HEC-18 equation.展开更多
The organizational structure change of enterprises should be subject to the change of strategy,and strategy change is the reaction to the environment change.This paper studied the expansion strategies and evolution pa...The organizational structure change of enterprises should be subject to the change of strategy,and strategy change is the reaction to the environment change.This paper studied the expansion strategies and evolution paths of hotel groups in China by a survey in 2007,in which the research objects were 91 hotel groups listed by China Tourist Hotels Association.The conclusions are drawn:based on the two dimensions of unification management function scope and the unification management degree,hotel groups can be divided into four strategic types,including strategically concentrated group,close function group,widespread alliance group and loose union group.Simultaneously there are three different expansion paths:stability path,growth path and undulation path.About 72.5% of Chinese hotel groups have a stability or growth expansion path.展开更多
In this paper,based on the symbolic computing system Maple,the direct method for Lie symmetry groupspresented by Sen-Yue Lou [J.Phys.A:Math.Gen.38 (2005) L129] is extended from the continuous differential equationsto ...In this paper,based on the symbolic computing system Maple,the direct method for Lie symmetry groupspresented by Sen-Yue Lou [J.Phys.A:Math.Gen.38 (2005) L129] is extended from the continuous differential equationsto the differential-difference equations.With the extended method,we study the well-known differential-difference KPequation,KZ equation and (2+1)-dimensional ANNV system,and both the Lie point symmetry groups and the non-Liesymmetry groups are obtained.展开更多
Let ARDkCS（v） denote an almost resolvable directed k-cycle system of order v. It is clear that a necessary condition for the existence of an ARDkCS（v） is v=1（mod k）. For k：3,4,5 and 6, the existence of an ARDk...Let ARDkCS（v） denote an almost resolvable directed k-cycle system of order v. It is clear that a necessary condition for the existence of an ARDkCS（v） is v=1（mod k）. For k：3,4,5 and 6, the existence of an ARDkCS （v） had been completely solved. This paper shows that there exists an ARD7CS（v） if and only if v≡1 （rood 7） and v≥8.展开更多
CO_(2) conversion into value-added products by electro-, photoand plasma catalysis under mild operating conditions(ambient temperature and pressure) is an emerging area to achieve carbon circularity by producing chemi...CO_(2) conversion into value-added products by electro-, photoand plasma catalysis under mild operating conditions(ambient temperature and pressure) is an emerging area to achieve carbon circularity by producing chemicals and fuels using directly renewable energy. Among all CO_(2) conversion approaches, the electrocatalytic reduction of CO_(2) is the most mature technology, capable of achieving high productivity(i.e. high current densities) at large scale, especially for producing carbon monoxide(CO), but with many examples showing selectivity to C_(2) carbon products.展开更多
The direct Pd-catalyzed β-C（sp3）--H activation and cyclization of aliphatic amides bearing a removable 2-pyridylmethyl directing group with gem-dibromoolefins is described for the first time to construct a variety ...The direct Pd-catalyzed β-C（sp3）--H activation and cyclization of aliphatic amides bearing a removable 2-pyridylmethyl directing group with gem-dibromoolefins is described for the first time to construct a variety of γ-lactams, The resulting products with Z- and E-configurations can be easily separated and purified after the reaction, demonstrating the effectiveness and applicability of the method herein developed.展开更多
The garnet (Grt) and biotite (Bt) from gneisses of the Ji’ an Group are characterized by diffusion zoning at the rim, but equilibrium composition of metamorphic peak is usually remained in extensive interior area. Ga...The garnet (Grt) and biotite (Bt) from gneisses of the Ji’ an Group are characterized by diffusion zoning at the rim, but equilibrium composition of metamorphic peak is usually remained in extensive interior area. Garnet with growth zoning is also found in the kyanite zone.In the light of microarea compositional variation of Grt and Bt, the temperatuIe and pressuIe at the progressive, peak and post peak metamorphic stages are determined by correctly using GrtBt thermometer and GASP barometer. On this basis, a counterclockwise P-T-t path can be constructed, which reflects the closing process of an ensialic rift belt in this region during the Early Proterozoic.展开更多
Stimulated Raman scattering(SRS)under a new ignition path that combines the advantages of direct-drive(DD)and indirect-drive(ID)schemes is investigated experimentally at the Shenguang-100 kJ facility.The results show ...Stimulated Raman scattering(SRS)under a new ignition path that combines the advantages of direct-drive(DD)and indirect-drive(ID)schemes is investigated experimentally at the Shenguang-100 kJ facility.The results show that collective SRS in the plasma produced by ablating a polyimide film is detected for the ID beams,but is suppressed by adding a toe before the main pulse of the ID beams.The toe also strongly influences SRS of both the ID and DD beams excited in the plasma generated in the hohlraum.When a toe is used,the SRS spectra of the DD beams show that SRS tends to be excited in lower plasma density,which will result in a lower risk of super-hot electrons.Measurements of hot electrons support this conclusion.This research will help us produce a better pulse design for this new ignition path.展开更多
基金supported financially by the Excellent Going Abroad Expert's Training Program in Hebei Province (No. 201940)the Hebei Natural Science Foundation of China (No. H2020208030)the S & T Program of Hebei (No. 22567607H) for financial support。
文摘A nickel-catalyzed C(sp^(2))–H alkynylation of unprotected α-substituted benzylamines is achieved by utilizing a transient directing group. The combination of a TDG with a nickel catalyst significantly improves the reaction step and atom economy. It has been investigated that the 2,4,6-trimethylpyridine ligand was critical to achieve the optimized reactivity. This protocol provides a straightforward route for synthesizing the alkynylated free benzylamines, featuring good substrate compatibility and monoselectivity.
基金support from the National Natural Science Foundation of China(No.21901206)Postdoctoral Science Foundation of China(No.2022M712589)+2 种基金General Key R&D Projects in Shaanxi Province(No.2023-YBGY-321)Natural Science Foundation of Chongqing(No.CSTB2022NSCQ-MSX0826)National&Local Joint Engineering Research Center for mineral Salt Deep Utilization,Huaiyin Institute of Technology(No.SF202407)for financial support。
文摘The transition metal-catalyzed C–H activation have been considered as increasingly useful approach for installing new functional groups onto organic small molecules due to their high step-and atom-economy,the abundance of hydrocarbon compounds,and the potential for late-stage functionalization of complex organic molecules.The ortho-and meta-C-H activation and functionalization of aromatic compounds have been widely explored in recent years,however the distal para-C-H activation and functionalization has remained a significant challenge because of the difficulty in forming energetically favorable metallacyclic transition states.The utilization of appropriate directing groups or templates as well as the meticulous design of catalysts and ligands has proven to be effective in transition-metal-catalyzed remote para-C-H bonds activation and functionalization of aromatic compounds.This review aims to summarize the strategies for controlling para-selective C–H functionalization using the directing group,template engineering,and catalyst/ligand design under transition metals catalysis in recent years.
基金supported by grants from the National Natural Science Foundation of China (No. 21978039)Special Funds of the Central Government Leading Local Government for the Technology Development (Nos. 2021JH6/10500146, 2021JH6/10500148)the Fundamental Research Funds for the Central Universities (Nos. DUT20YG120, DUT19LK60)。
文摘Remote ether groups could be used as directing groups to prepare fully substituted 5-ether-1,2,3-triazoles with exclusive 1,5-regioselectivities and excellent chemoselectivities. Ether group could coordinate with iridium catalyst by lone-pair electron at a distance(up to four σ bonds) away from alkyne to control the regioselectivity by weak coordination effect. The cycloaddition reaction chemoselectively occurred at the propargyl ether moiety of diyne to give unique fully substituted 4-alkynyl-triazole.
基金Jiangsu Province(No.BK20161307 and“333”Talents Project for H.Hu)Huaiyin Normal University(No.JSKC18014)for their financial support。
文摘A rhodium-catalyzed directing group promoted selective C-H olefination reaction of indolizines at the 8-position is re ported.Di-olefination at 2,8-positions also achieved with silver hexafluoroantimonate as an additive under similar reaction conditions.Weakly coordinating groups,such as ketone,alde hyde,amide and ester,were used as directing groups.The ester group can be removed under acid conditions and therefore is used as a traceless directing group.
基金financially supported by the National Natural Science Foundation of China(Nos.51331005 and 51425402)
文摘To investigate the effect of solidification parameters on the solidification path and microstructure evolution of Ti-45Al-5Nb(at.%) alloy, Bridgman-type directional solidification and thermodynamics calculations were performed on the alloy. The microstructures, micro-segregation and solidification path were investigated.The results show that the β phase is the primary phase of the alloy at growth rates of 5-20 μm·s^(-1) under the temperature gradients of 15-20 K·mm^(-1), and the primary phase is transformed into an α phase at relatively higher growth rates(V >20 μm·s^(-1)). The mainly S-segregation and β-segregation can be observed in Ti-45Al-5Nb alloy at a growth rate of 10 μm·s^(-1) under a temperature gradient of 15 K·mm^(-1). The increase of temperature gradient to 20 K·mm^(-1) can eliminate β-segregation, but has no obvious effect on S-segregation. The results also show that 5 at.% Nb addition can expand the β phase region, increase the melting point of the alloy and induce the solidification path to become complicated. The equilibrium solidification path of Ti-45Al-5Nb alloy can be described as L L→β L+β L+β→αα+β_R β→ααα→γα+γα→α_2+γγ_R+(α_2+γ), in which β_R and γ_R mean the residual β and
基金funded by the National Natural Science Foundation of China (No. 41520104003)the National Key R & D Program of China (No. 2016YFC0600403)+1 种基金the China Geological Survey (No. DD20160201)the Fundamental Research Funds for the Central Universities,China University of Geosciences (Wuhan) (Nos. CUGL170404,CUG160232)
文摘The Central Qilian Block is a Precambrian block in the Qilian Orogen,which has long drawn international attention for the study of orogeny and continental dynamics.The Huangyuan Group in the Datong area is one of the Precambrian metamorphic basement units in the Central Qilian Block and reflects metamorphism in the Barrovian garnet zone and sillimanite zone from south to north.Based on detailed fieldwork,this study presents a systematic study of petrography,mineral chemistry and phase equilibria of schists and gneisses from the two metamorphic zones.The garnet metamorphic zone is composed of micaschist,garnet-bearing micaschist and felsic leptynite,with interlayered plagioclase amphibolite.The sillimanite metamorphic zone consists of garnet-bearing biotite micaschist,sillimanite-bearing biotite-plagioclase gneiss and felsic leptynite.Garnet from the garnet metamorphic zone shows growth zoning with increasing almandine and pyrope and decreasing spessartine from core to rim.Garnet from the sillimanite metamorphic zone is almost homogeneous.Towards the outer rim,the contents of almandine and pyrope slightly decrease and grossular slightly increase.Biotite in both metamorphic zones is ferro-biotite.Plagioclase is oligoclase in garnet metamorphic zone and andesine in sillimanite metamorphic zone.Phase equilibrium modeling of a sample from garnet metamorphic zone resulted in a clockwise P-T path with a prograde stage(4.5–5.0 kbar,520–530℃),a peak P stage(9.8–10.2 kbar,560–570℃),a stage of thermal relaxation(8.0–8.5 kbar,580–590℃)and finally a retrograde stage(6.8–7.0 kbar,560–580℃).Thermodynamic modeling of a sample from the sillimanite metamorphic zone indicates a prograde stage(5.5–6.0 kbar,540–550℃)and a peak stage(7.8–8.5 kbar,660–690℃).The results indicate that the Huangyuan Group experienced medium-pressure amphibolite-facies metamorphism,which resulted from continental-continental collision between the Qaidam Block and the Central Qilian Block.
文摘Using the (2+1)-dimensional Broer-Kaup equation as an simple example, a new direct method is developed to find symmetry groups and symmetry algebras and then exact solutions of nonlinear mathematical physical equations.
文摘In the paper [1] the upgrade of the structure of groups has been considered, in which the concept of HX group has been raised. In this paper we will discuss the direct product of HX groups and AX groups on direct product group.
基金This research is supported by the National Natural Science Foundation of China(Nos.30370397 and 60571042).
文摘Stable adsorption and direct electrochemistry of glucose oxidase （COx） occurred on nitric acid （HNO3）-treated multi-walled carbon nanotubcs （MWNTs） instead of as-received MWNTs, demonstrating the critical roles of oxygen-containing groups in stable adsorption and direct electrochemistry of GOx on carbon nanotubcs （CNTs）.
基金Supported by the Education Depart ment Fund of Science and Technology Research (No.104086)
文摘A search algorithm for the detection of a direct path signal in the presence of dense multipath in indoor environment using UWB is Woposed. This algorithm is based on signal correlation and differential coefficient. Statistical analysis of the algorithm is given out and computer simulation results are presented to validate the effectiveness of the algorithm. The results based on the algorithm pml3osed are compared with those based on Maximum Likelihood Estimator（MLE） and Peak Tracking（PT） in the simulation which shows that this algorithm achieves the highest accuracy in most cases and gives out relatively stable results in different Signal Noise Ratio（SNR）.
基金supported by the National Natural Science Foundation of China(Nos.U1703244 and 41672310)the National Natural Science Foundation of China(No.41801038)+6 种基金the State Key Laboratory for Geo Mechanics and Deep Underground Engineering,the China University of Mining and Technology(SKLGDUEK1904)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XDA2003020102)the Major Program of Bureau of International Cooperation,the Chinese Academy of Sciences(131B62KYSB20170012)the National Key Research and Development Program(2017YFC0405101)the Research Project of the State Key Laboratory of Frozen Soils Engineering(Grant No.SKLFSE-ZY-16)the Science and Technology Major Project of Gansu Province(143GKDA007)the Science and Technology Planning Project of Gansu Province(No.18JR3RA376)
文摘A series of directional shear tests on remolded frozen soil was carried out at 10°C by using a hollow cylinder apparatus to study failure criterion under a directional shear-stress path.Directional shear tests were conducted at five shear rates(10,20,30,40,and 50 kPa/min)and five intermediate principal stress coefficients(b=0,0.25,0.5,0.75,and 1),with the mean principal stress(p=4.5 MPa)kept constant.The results show that the torsional strength and the generalized strength both increase with the increase of the shear rates.According to the failure modes of frozen soil under different shear rates,the specimens present obvious plastic failure and shear band;and the torsional shear component dominates the failure modes of hollow cylindrical specimens.A shear rate of 30 kPa/min is chosen as the loading rate in the directional shear tests of frozen soil.The shape of the failure curve in theπplane is dependent on the directional anglesαof the major prin cipal stress.It is reasonable to use the strain-hardening curves to define the deviatoric stress value atγg=15%(generalized shear strain)as the failure criterion of frozen soil under a directional shear-stress path.
基金financially supported by the National Key Research and Development Program of China(Grant No.2017YFC1404200)the Tianjin Key Program of Applied Foundation and Advanced-Tech Research,China(Grant No.18JCZDJC40200)+1 种基金the National High Technology Research and Development Program of China(863 Program,Grant No.2012AA051709)the National Natural Science Foundation of China(Grant No.51509183)
文摘The local scour around a new pile-group foundation of offshore wind turbine subjected to a bi-directional current was physically modeled with a bi-directional flow flume. In a series of experiments, the flow velocity and topography of the seabed were measured based on a system composed of plane positioning equipment and an ADV.Experimental results indicate that the development of the scour hole was fast at the beginning, but then the scour rate decreased until reaching equilibrium. Erosion would occur around each pile of the foundation. In most cases, the scour pits were connected in pairs and the outside widths of the scour holes were larger than the inner widths. The maximum scour depth occurred at the side pile of the foundation for each test. In addition, a preliminary investigation shows that the larger the flow velocity, the larger the scour hole dimensions but the shorter equilibrium time. The field maximum scour depth around the foundation was obtained based on the physical experiments with the geometric length scales of 1:27.0, 1:42.5 and 1:68.0, and it agrees with the scour depth estimated by the HEC-18 equation.
基金Under the auspices of National Social Science Foundation of China (No. 08BJY037)Ph. D. Programs Fundation of Ministry of Education of China (No. 200805581046)Humanities and Social Sciences Project of Ministry of Education of China (No. 09YJC630233)
文摘The organizational structure change of enterprises should be subject to the change of strategy,and strategy change is the reaction to the environment change.This paper studied the expansion strategies and evolution paths of hotel groups in China by a survey in 2007,in which the research objects were 91 hotel groups listed by China Tourist Hotels Association.The conclusions are drawn:based on the two dimensions of unification management function scope and the unification management degree,hotel groups can be divided into four strategic types,including strategically concentrated group,close function group,widespread alliance group and loose union group.Simultaneously there are three different expansion paths:stability path,growth path and undulation path.About 72.5% of Chinese hotel groups have a stability or growth expansion path.
文摘In this paper,based on the symbolic computing system Maple,the direct method for Lie symmetry groupspresented by Sen-Yue Lou [J.Phys.A:Math.Gen.38 (2005) L129] is extended from the continuous differential equationsto the differential-difference equations.With the extended method,we study the well-known differential-difference KPequation,KZ equation and (2+1)-dimensional ANNV system,and both the Lie point symmetry groups and the non-Liesymmetry groups are obtained.
基金Natural Science Research Leading Item ofJiangsu (No.04 DJ110144) Natural Out-standing Younger Science Foundation(No.60225007)and Postdoctoral ScienceFoundation of China(No.20020248024)
文摘Let ARDkCS（v） denote an almost resolvable directed k-cycle system of order v. It is clear that a necessary condition for the existence of an ARDkCS（v） is v=1（mod k）. For k：3,4,5 and 6, the existence of an ARDkCS （v） had been completely solved. This paper shows that there exists an ARD7CS（v） if and only if v≡1 （rood 7） and v≥8.
文摘CO_(2) conversion into value-added products by electro-, photoand plasma catalysis under mild operating conditions(ambient temperature and pressure) is an emerging area to achieve carbon circularity by producing chemicals and fuels using directly renewable energy. Among all CO_(2) conversion approaches, the electrocatalytic reduction of CO_(2) is the most mature technology, capable of achieving high productivity(i.e. high current densities) at large scale, especially for producing carbon monoxide(CO), but with many examples showing selectivity to C_(2) carbon products.
基金the financial supports from the National Natural Science Foundation of China(Nos. 21672154 and 21372164)
文摘The direct Pd-catalyzed β-C（sp3）--H activation and cyclization of aliphatic amides bearing a removable 2-pyridylmethyl directing group with gem-dibromoolefins is described for the first time to construct a variety of γ-lactams, The resulting products with Z- and E-configurations can be easily separated and purified after the reaction, demonstrating the effectiveness and applicability of the method herein developed.
文摘The garnet (Grt) and biotite (Bt) from gneisses of the Ji’ an Group are characterized by diffusion zoning at the rim, but equilibrium composition of metamorphic peak is usually remained in extensive interior area. Garnet with growth zoning is also found in the kyanite zone.In the light of microarea compositional variation of Grt and Bt, the temperatuIe and pressuIe at the progressive, peak and post peak metamorphic stages are determined by correctly using GrtBt thermometer and GASP barometer. On this basis, a counterclockwise P-T-t path can be constructed, which reflects the closing process of an ensialic rift belt in this region during the Early Proterozoic.
基金supported by the National Natural Science Foundation of China(Grant Nos.12205274,12275251,12105270,12205272,12305262,and 12035002)the National Key Laboratory of Plasma Physics(Grant No.JCKYS2024212803)+2 种基金the Fund of the National Key Laboratory of Plasma Physics(Grant No.6142A04230103)the National Key R&D Program of China(Grant No.2023YFA1608400)the National Security Academic Fund(Grant No.U2430207).
文摘Stimulated Raman scattering(SRS)under a new ignition path that combines the advantages of direct-drive(DD)and indirect-drive(ID)schemes is investigated experimentally at the Shenguang-100 kJ facility.The results show that collective SRS in the plasma produced by ablating a polyimide film is detected for the ID beams,but is suppressed by adding a toe before the main pulse of the ID beams.The toe also strongly influences SRS of both the ID and DD beams excited in the plasma generated in the hohlraum.When a toe is used,the SRS spectra of the DD beams show that SRS tends to be excited in lower plasma density,which will result in a lower risk of super-hot electrons.Measurements of hot electrons support this conclusion.This research will help us produce a better pulse design for this new ignition path.
