Optical phase-gradient metasurfaces have garnered significant attention for enabling flexible light manipulation,with applications across diverse domains.In this work,we will demonstrate that the metasurfaces with pha...Optical phase-gradient metasurfaces have garnered significant attention for enabling flexible light manipulation,with applications across diverse domains.In this work,we will demonstrate that the metasurfaces with phase gradient modulation can be used to achieve illusion optics,featuring the advantages of simple geometric structure and feasible implementation compared with the well-known transformation optics method.The underlying mechanism is the anomalous diffraction law caused by the phase gradient,which provides a theoretical basis for freely manipulating the propagation path of light.By considering a specific example,we will demonstrate that the phase gradient can transform spatial coordinates in real space into illusion space,thereby converting a plane in real space into a curved surface structure in illusion space to achieve the illusion effect.This approach provides a viable alternative to transformation optics for designing illusion devices.展开更多
In this work,ultrasonic surface rolling process(USRP)was utilized to produce a gradient structured layer on 7 B50-T7751 aluminum alloy,and the mechanical properties and corrosion fatigue behavior of treated samples we...In this work,ultrasonic surface rolling process(USRP)was utilized to produce a gradient structured layer on 7 B50-T7751 aluminum alloy,and the mechanical properties and corrosion fatigue behavior of treated samples were studied.These results reveal that underwent USRP,a 425~m thick gradient structure and a 700~m deep compressive residual stress field are created,aluminum grain size become fine(~67 nm),and the corrosion rate of treated surface reduces by 60.08%owing to the combined effect of compressive residual stress and surface nanocrystallization.The corrosion fatigue strength is enhanced to 117%of that of 7 B50 Al alloys by means of USRP due to the introduced compressive residual stress,which is considered as the major favorable factor in suppressing the initiation and early propagation of corrosion fatigue cracks.Besides,the gradient structure is an important factor in providing a significant synergistic contribution to the improvement of corrosion fatigue performance.展开更多
Recycling spent lithium-ion(Li+)batteries is critical for achieving environmental conservation and the strategic recovery of essential resources.Compared with conventional methods for recovering cathode materials,whic...Recycling spent lithium-ion(Li+)batteries is critical for achieving environmental conservation and the strategic recovery of essential resources.Compared with conventional methods for recovering cathode materials,which are energy-intensive and prone to secondary pollution,the direct regeneration approach has emerged as a rapid and highly efficient method,gaining widespread attention in recent years.However,this approach faces major challenges,including degraded electrochemical performances and limited economic value.This study,therefore,proposes a high-value direct regeneration strategy to convert degraded spent LiFePO_(4)(S-LFP)into a gradient manganese(Mn)-doped regenerated LiFe_(0.7)Mn_(0.3)PO_(4)/C(R-LFMP)composite.This method leverages the inherent microcracks and Li vacancies present in S-LFP,likely acting as diffusion channels for the Mn^(2+)/Li^(+)ions.Through a two-step mechanochemical ball-milling and carbothermal reduction process,this approach achieves simultaneous Li replenishment and surface-localised Mn gradient doping with enhanced structural control.Notably,the R-LFMP exhibits an exceptional electrochemical performance.At 0.1 C,it delivers a discharge capacity of 161.4 mA h g^(−1)and an energy density of 563.5 Wh kg^(−1)(representing a 60.5%improvement over S-LFP).Additionally,it maintains 83%capacity retention after 900 cycles at 0.5C,a considerable enhancement compared to commercial LFMP(62%).Furthermore,the regenerated cathode material generates a net profit of$7.102 kg^(−1),surpassing the profitability of conventional recycling methods by 90%.Overall,this study introduces a transformative and sustainable LFP regeneration technology,achieving breakthroughs in electrochemical restoration and high-value recycling,while paving the way for the closed-loop utilisation of LFP-based energy storage systems.展开更多
Suffusion refers to the loss of fineparticles within the soil matrix without any associated volume change,induced by hydrodynamic forces.This study investigated the suffusion of sand-clay mixtures through one-dimensio...Suffusion refers to the loss of fineparticles within the soil matrix without any associated volume change,induced by hydrodynamic forces.This study investigated the suffusion of sand-clay mixtures through one-dimensional soil column experiments under a stepwise increase in hydraulic gradient(i),aiming to evaluate the critical hydraulic gradient(icrit)as a function of the size ratio between sand and clay,clay type,and ionic concentration.It was found that icrit was less than 0.1 for all sand-clay mixtures examined in this study.In addition,the lower peak concentrations of filtrated clay observed in sand-illite mixtures,compared to those of sand-kaolinite mixtures at the same level of i,suggest that illite particles are more susceptible to suffusion.Overall,the observed breakthrough curves,mass fraction of filtrated clay,volume of outflow,and total injection time presented in this study highlight the importance of considering clay type,sand-to-clay size ratio,and ionic concentration when assessing the suffusion behavior of clay-containing soils under a stepwise increase in hydraulic gradient.展开更多
Anammox bacteria in constructed wetlands(CWs)play pivotal role in sustainable nitrogen transformation,yet existing studies lack comprehensive analysis of environmental gradients and microbial interactions,both key fac...Anammox bacteria in constructed wetlands(CWs)play pivotal role in sustainable nitrogen transformation,yet existing studies lack comprehensive analysis of environmental gradients and microbial interactions,both key factors in anammox bacteria enrichment.This study investigated the mechanisms driving anammox bacteria enrichment in lab-scale simulated CWs treating high-nitrogen wastewater,focusing on bacterial community re-sponses across wetland layers with various strategies,including continuous up-flow influent,nitrogen loading increase,effluent recirculation,intermittent influent,and anammox bacteria inoculation.Results showed that total relative and absolute abundances of anammox bacteria ranged from 0.77%to 12.50%and from 0.13 to 6.46×10^(7) copies/g,respectively.Dissolved oxygen and pH had significant positive correlations with the absolute abundance of anammox bacteria,while organic matter and nitrate negatively impacted their relative abundance.Permutational multivariate analysis of variance indicated that spatial heterogeneity explained more variation in anammox bacteria abundance(43.44%)compared to operational strategies(8.58%).In terms of microbial interactions,60 dominant species exhibited potential correlations with anammox bacteria,comprising 170 interactions(105 positive and 65 negative),which suggested that anammox bacteria generally foster cooperative relationships with dominant bacteria.Notably,significant interspecies interactions were observed between Candidatus Kuenenia(dominant anammox bacteria in CWs)and species within the genera Chitinivibrio-nia and Anaerolineaceae,suggesting that microbial interactions primarily manifest as indirect facilitative effects rather than direct mutualistic relationships.Given that the Normalized Stochasticity Ratio in CWs were<50%,this study inferred that environmental gradients have greater influence on anammox bacteria than microbial interactions.展开更多
Gradient microstructures strengthened by serrated Grain Boundaries(GBs)were achieved through a combination of Gradient Strain Deformation(GSD)and Serration Heat Treatment(SHT),with particular focus on microstructural ...Gradient microstructures strengthened by serrated Grain Boundaries(GBs)were achieved through a combination of Gradient Strain Deformation(GSD)and Serration Heat Treatment(SHT),with particular focus on microstructural evolution,underlying mechanisms,and the critical influencing factors.Dynamic recrystallization governed the microstructural evolution in the fine-grained and transition regions during GSD,where multiple nucleation mechanisms were active.Plastic deformation facilitated the dissolution ofγ'phase in fine-grained regions,ultimately resulting in its morphological transformation.During the subsequent SHT,serrated GBs formed within the gradient microstructures produced by prior GSD without disrupting the grain size gradient,thereby enhancing creep resistance.Two distinct mechanisms associated withγ'gbparticles governed the formation of the serrations at GBs.Owing to the stronger dragging effect of grain boundary junctions in fine-grained regions,the amplitude and wavelength of serrations in these regions were smaller than those in coarse-grained regions.Moreover,the formation of serrations exhibited a strong dependence on the inherent properties of the GBs.The random high-angle grain boundaries(HAGBs)with misorientation angles in the range of 30-59°tended to become serrated more easily during SHT due to their high mobility and the accelerated precipitation ofγ'gbparticles at them.Low-ΣHAGBs and low-angle GBs were not prone to form serrations.In particular,serration formation was completely inhibited atΣ3 twin boundaries due to their extremely low mobility and the absence ofγ'gbparticles.展开更多
Fluid dynamic research on rectangular and trapezoidal fins is aimed at increasing heat transfer by means of large surfaces.The trapezoidal cavity form is compared with its thermal and flow performance,and it is reveal...Fluid dynamic research on rectangular and trapezoidal fins is aimed at increasing heat transfer by means of large surfaces.The trapezoidal cavity form is compared with its thermal and flow performance,and it is revealed that trapezoidal fins tend to be more efficient,particularly when material optimization is critical.Motivated by the increasing need for sustainable energy management,this work analyses the thermal performance of inclined trapezoidal and rectangular porous fins utilising a unique hybrid nanofluid.The effectiveness of nanoparticles in a working fluid is primarily determined by their thermophysical properties;hence,optimising these properties can significantly improve overall performance.This study considers the dispersion of Graphene Oxide(GO)and Molybdenum Disulfide in the base fluid,engine oil.Temperature profiles are analysed by altering the radiative,porosity,wet porous,and angle of inclination parameters.Surface and contour plots are constructed by using the Lobatto IIIa Collocation Method with BVP5C solver in MATLAB and Gradient Descent Optimisation to predict the combined heat transfer rate.According to the study,fluid temperature consistently decreases when the angle of inclination,wet porous parameter,porosity parameter,and radiative parameter increase,suggesting significantly improved heat dissipation.The trapezoidal fin consistently exhibits a superior heat transfer mechanism than a rectangular fin.It is found that the trapezoidal fin transmits heat at a rate that is 0.05%higher than that of the rectangular fin.Validation of the present study is done through the comparison of previous studies.This research provides useful design insights for sophisticated engineering uses,including electrical cooling devices,heat exchangers,radiators,and solar heaters.展开更多
This work was to generate landslide susceptibility maps for the Three Gorges Reservoir(TGR) area, China by using different machine learning models. Three advanced machine learning methods, namely, gradient boosting de...This work was to generate landslide susceptibility maps for the Three Gorges Reservoir(TGR) area, China by using different machine learning models. Three advanced machine learning methods, namely, gradient boosting decision tree(GBDT), random forest(RF) and information value(InV) models, were used, and the performances were assessed and compared. In total, 202 landslides were mapped by using a series of field surveys, aerial photographs, and reviews of historical and bibliographical data. Nine causative factors were then considered in landslide susceptibility map generation by using the GBDT, RF and InV models. All of the maps of the causative factors were resampled to a resolution of 28.5 m. Of the 486289 pixels in the area,28526 pixels were landslide pixels, and 457763 pixels were non-landslide pixels. Finally, landslide susceptibility maps were generated by using the three machine learning models, and their performances were assessed through receiver operating characteristic(ROC) curves, the sensitivity, specificity,overall accuracy(OA), and kappa coefficient(KAPPA). The results showed that the GBDT, RF and In V models in overall produced reasonable accurate landslide susceptibility maps. Among these three methods, the GBDT method outperforms the other two machine learning methods, which can provide strong technical support for producing landslide susceptibility maps in TGR.展开更多
In this pap er, a novel size-dep endent functionally graded (FG) cylindrical shell model is develop ed based on the nonlocal strain gradient theory in conjunction with the Gurtin-Murdoch surface elasticity theory . Th...In this pap er, a novel size-dep endent functionally graded (FG) cylindrical shell model is develop ed based on the nonlocal strain gradient theory in conjunction with the Gurtin-Murdoch surface elasticity theory . The new model containing a nonlocal parameter, a material length scale parameter, and several surface elastic constants can capture three typical typ es of size e ects simultaneously , which are the nonlocal stress ef- fect, the strain gradient e ect, and the surface energy e ects. With the help of Hamilton’s principle and rst-order shear deformation theory , the non-classical governing equations and related b oundary conditions are derived. By using the prop osed model, the free vibra- tion problem of FG cylindrical nanoshells with material prop erties varying continuously through the thickness according to a p ower-law distribution is analytically solved, and the closed-form solutions for natural frequencies under various b oundary conditions are obtained. After verifying the reliability of the prop osed model and analytical method by comparing the degenerated results with those available in the literature, the in uences of nonlocal parameter, material length scale parameter, p ower-law index, radius-to-thickness ratio, length-to-radius ratio, and surface e ects on the vibration characteristic of func- tionally graded cylindrical nanoshells are examined in detail.展开更多
Magnetic field gradient tensor technique provides abundant data for delicate inversion of subsurface magnetic susceptibility distribution. Large scale magnetic data inversion imaging requires high speed and accuracy f...Magnetic field gradient tensor technique provides abundant data for delicate inversion of subsurface magnetic susceptibility distribution. Large scale magnetic data inversion imaging requires high speed and accuracy for forward modeling. For arbitrarily distributed susceptibility data on an undulated surface, we propose a fast 3D forward modeling method in the wavenumber domain based on(1) the wavenumber-domain expression of the prism combination model and the Gauss–FFT algorithm and(2) cubic spline interpolation. We apply the proposed 3D forward modeling method to synthetic data and use weighting coefficients in the wavenumber domain to improve the modeling for multiple observation surfaces, and also demonstrate the accuracy and efficiency of the proposed method.展开更多
With the development of gravity gradient full tensor measurement technique,three-dimensional( 3D) inversion based on gravity gradient tensor can provide more accurate information. But the forward calculation of 3D ful...With the development of gravity gradient full tensor measurement technique,three-dimensional( 3D) inversion based on gravity gradient tensor can provide more accurate information. But the forward calculation of 3D full tensor sensitivity matrix is very time-consuming,which restricts its development and application.According to the symmetry of the kernel function,the authors reconstruct the underground source of geological body to avoid repeat computation of the same value,and work out the corresponding relationship between the response of geological body to the observation point and the response of reconstructed geological body to the observation point. According to the relationship,rapid calculation of full tensor gravity sensitivity matrix can be achieved. The model calculation shows that this method can increase the speed of 30-45 times compared with the traditional calculation method. The sensitivity matrix is applied to the multi-component inversion of gravity gradient. The application of this method on the measured data provides the basis for the promotion of the method.展开更多
Compared with conventional well, herringbone-like laterals wells can increase the area of oil release, and can reduce the number of wellhead slots of platforms,?and?also can greatly improve the development efficiency....Compared with conventional well, herringbone-like laterals wells can increase the area of oil release, and can reduce the number of wellhead slots of platforms,?and?also can greatly improve the development efficiency. Based on threshold pressure gradient in heavy oil reservoir,?and?the applied principle of mirror reflection and superposition, the pressure distribution equation of herringbone-like laterals wells is obtained in heavy oil reservoir. Productivity model of herringbone-like laterals wells is proposed by reservoir-wellbore steady seepage. The example shows that the productivity model is great accuracy?to?predict the productivity of herringbone-like laterals wells. The model is used to analyze the branching length, branching angle, branching symmetry, branching position and spacing and their effects on productivity of herringbone-like laterals wells. The principle of optimizing the well shape of herringbone-like laterals wells is proposed.展开更多
Perfect anomalous reflections have been demonstrated in optical phase gradient metasurfaces(PGMs),but they suffer from single-frequency(narrow-band)response due to the intrinsic limitation of natural geometric periodi...Perfect anomalous reflections have been demonstrated in optical phase gradient metasurfaces(PGMs),but they suffer from single-frequency(narrow-band)response due to the intrinsic limitation of natural geometric periodicity.Here,we provide both numerical and analytical evidence that a depth gradient metasurface can achieve discrete ultra-broadband perfect anomalous reflection in the microwave range in the absence of geometric periodicity.Remarkably,by adjusting the operating frequency of the incident wave,the same effect can be steadily obtained via a physically equivalent phase periodicity in the PGM.Based on this mechanism,a perfect retroreflector with a broadband response ranging from 1 GHz to 40 GHz is realized.Our work has promising applications in communication,source tracking,and military satellites.展开更多
Cyber-physical systems(CPS)represent a sophisticated integration of computational and physical components that power critical applications such as smart manufacturing,healthcare,and autonomous infrastructure.However,t...Cyber-physical systems(CPS)represent a sophisticated integration of computational and physical components that power critical applications such as smart manufacturing,healthcare,and autonomous infrastructure.However,their extensive reliance on internet connectivity makes them increasingly susceptible to cyber threats,potentially leading to operational failures and data breaches.Furthermore,CPS faces significant threats related to unauthorized access,improper management,and tampering of the content it generates.In this paper,we propose an intrusion detection system(IDS)optimized for CPS environments using a hybrid approach by combining a natureinspired feature selection scheme,such as Grey Wolf Optimization(GWO),in connection with the emerging Light Gradient Boosting Machine(LightGBM)classifier,named as GWO-LightGBM.While gradient boosting methods have been explored in prior IDS research,our novelty lies in proposing a hybrid approach targeting CPS-specific operational constraints,such as low-latency response and accurate detection of rare and critical attack types.We evaluate GWO-LightGBM against GWO-XGBoost,GWO-CatBoost,and an artificial neural network(ANN)baseline using the NSL-KDD and CIC-IDS-2017 benchmark datasets.The proposed models are assessed across multiple metrics,including accuracy,precision,recall,and F1-score,with an emphasis on class-wise performance and training efficiency.The proposed GWO-LightGBM model achieves the highest overall accuracy(99.73%)for NSL-KDD and(99.61%)for CIC-IDS-2017,demonstrating superior performance in detecting minority classes such as Remote-to-Local(R2L)and Other attacks—commonly overlooked by other classifiers.Moreover,the proposed model consumes lower training time,highlighting its practical feasibility and scalability for real-time CPS deployment.展开更多
The osteochondral(OC)interface exhibits a mineral gradient,varying in thickness by several hundred micrometers across different species.Disruptions in this interface damage OC tissues,leading to osteoarthritis.The nat...The osteochondral(OC)interface exhibits a mineral gradient,varying in thickness by several hundred micrometers across different species.Disruptions in this interface damage OC tissues,leading to osteoarthritis.The natural architecture and composition of native OC interfaces can be replicated using biomaterial scaffolds via regenerative engineering approaches.A novel one-step bioextrusion process was employed to fabricate a unitary synthetic graft(USG),which mimics the native OC interface’s mineral concentration gradient.This novel USG is composed of an agarose-based cartilage layer and a bone layer,consisting of agarose enriched with 20%(200 g/L)hydroxyapatite.The USG features a gradient interface with mineral concentrations transitioning from 0%to 20%(mass fraction),mimicking the transition between the cartilage and bone.Thermogravimetric analysis revealed that the gradient transition lengths of the graft and native OC tissue harvested from bovine knees were similar((647±21)vs.(633±124)μm).The linear viscoelastic properties of the grafts,which were evaluated using strain sweep and frequency sweep tests with oscillatory shear,indicated a dominant storage modulus over loss modulus similar to that of native OC tissues.The compressive and stress relaxation behaviors of the USGs demonstrated that the graft maintained structural integrity under mechanical stress.Viability assays performed after bioextrusion showed that chondrocytes and human fetal osteoblast cells successfully integrated and survived within their designated regions of the graft.The novel USGs exhibit properties similar to native OC tissue and are promising candidates for regenerating OC defects and restoring knee joint functionality.展开更多
The S38C railway axle undergoes induction hardening,resulting in a gradient-distributed microstructure and mechanical properties.The accurate identification of gradient-distributed plastic parameters for the S38C axle...The S38C railway axle undergoes induction hardening,resulting in a gradient-distributed microstructure and mechanical properties.The accurate identification of gradient-distributed plastic parameters for the S38C axle remains a challenging task.To tackle this challenge,the present study proposes a novel approach for identifying the gradient-distributed plastic parameters for the S38C axle by integrating nano-indentation techniques with the machine learning method.Firstly,nano-indentation tests are conducted along the radial direction of the S38C axle to obtain the gradient-distributed load-displacement curves,nano-hardness,and elastic modulus.Subsequently,the dimensionless analysis is performed to obtain the representative stress,strain,and yield stress from load-displacement curves.These parameters are then incorporated into the machine learning method as physical information to identify the gradient-distributed plastic parameters of the S38C axle.The results indicate that the proposed method based on the physics-informed neural network and multi-fidelity neural network successfully identifies the gradient-distributed plastic parameters of the S38C axles and demonstrates superior prediction accuracy and generalization compared with the purely data-driven machine learning method.展开更多
The development of gradient lubrication materials is critical for numerous biomedical applications,particularly in magnifying mechanical properties and service longevity.Herein,we present an innovative approach to fab...The development of gradient lubrication materials is critical for numerous biomedical applications,particularly in magnifying mechanical properties and service longevity.Herein,we present an innovative approach to fabricate biomimetic gradient lubrication hydrogel through the synergistic integration of three-dimensional(3D)printed metal-organic frameworks(MOFs)nanoparticle network hydrogel skeletons with bioinspired lubrication design.Specifically,robust hydrogel skeletons were engineered through single or multi-material 3D printing,followed by the in situ growth of MOFs nanoparticles within this hydrogel network to create a reinforced,load-bearing architecture.Subsequently,biomimetic lubrication capability was enabled by mechanically coupling another lubricating hydrogel within 3D-printed MOFs nanoparticle network hydrogel skeleton.The superficial layer is highly lubricious to ensure low coefficient of friction(~0.1141)and wear resistance(40,000 cycles),while the deeper layer is stiffer to afford the obligatory mechanical support(fracture strength~2.50 MPa).Furthermore,the gradient architecture stiffness of the hydrogel can be modulated by manipulating the spatial distribution of MOFs within the 3D-printed hydrogel skeleton.As a proof-of-concept,biomimetic gradient hydrogel meniscus structures with C-and O-shaped configurations were constructed by leveraging multi-material 3D printing,demonstrating exceptional lubrication performance.This innovative biomimetic design opens new avenues for creating implantable biomedical gradient lubricating materials with reinforced mechanical and lubrication performance.展开更多
Radiative cooling textiles with spectrally selective surfaces offer a promising energy-efficient approach for sub-ambient cooling of outdoor objects and individuals.However,the spectrally selective mid-infrared emissi...Radiative cooling textiles with spectrally selective surfaces offer a promising energy-efficient approach for sub-ambient cooling of outdoor objects and individuals.However,the spectrally selective mid-infrared emission of these textiles significantly hinders their efficient radiative heat exchange with self-heated objects,thereby posing a significant challenge to their versatile cooling applicability.Herein,we present a bicomponent blow spinning strategy for the production of scalable,ultra-flexible,and healable textiles featuring a tailored dual gradient in both chemical composition and fiber diameter.The gradient in the fiber diameter of this textile introduces a hierarchically porous structure across the sunlight incident area,thereby achieving a competitive solar reflectivity of 98.7%on its outer surface.Additionally,the gradient in the chemical composition of this textile contributes to the formation of Janus infrared-absorbing surfaces:The outer surface demonstrates a high mid-infrared emission,whereas the inner surface shows a broad infrared absorptivity,facilitating radiative heat exchange with underlying self-heated objects.Consequently,this textile demonstrates multi-scenario radiative cooling capabilities,enabling versatile outdoor cooling for unheated objects by 7.8℃ and self-heated objects by 13.6℃,compared to commercial sunshade fabrics.展开更多
Transforming urban spatial structures to promote green and low-carbon development is an effective strategy.Although prior studies have examined the impact of urban polycentricity on carbon emissions and economic devel...Transforming urban spatial structures to promote green and low-carbon development is an effective strategy.Although prior studies have examined the impact of urban polycentricity on carbon emissions and economic development,research on its role in the synergistic relationship between these factors regarding carbon emission efficiency is limited.Furthermore,existing literature often overlooks nonlinear effects and interactions with other urban variables.This paper analyzed data from 295 Chinese cities in 2020,calculating urban population polycentricity,population dispersion indices,and carbon emission efficiency.Utilizing local spatial autocorrelation tools,we reveal interactions among urban population polycentricity,dispersion,carbon emissions,and carbon emission efficiency.We then employ a gradient boosting decision tree model(GBDT)to explore nonlinear and synergistic effects of polycentric urbanization.Key findings include:1)polycentric urbanization in Chinese cities exhibits significant spatial differentiation characteristics.The Polycentricity index is relatively high in economically developed eastern coastal regions with an overall low level,carbon emissions are concentrated in industrialized north-central cities and some Yangtze River Delta hubs,and carbon emission efficiency is the highest in the Yangtze River Delta while relatively low in Northeast China;there are significant spatially heterogeneous interaction characteristics among population polycentricity,population dispersion,carbon emissions,and carbon emission efficiency.2)Urban population polycentricity contributes 9.42%to total carbon emissions and 6.24%to carbon emission efficiency.3)The polycentricity index has a nonlinear impact on carbon emissions and carbon emission efficiency:no significant effect when below 0.50 or above 0.55,increased carbon emissions in 0.50-0.53,and reduced carbon emissions with improved efficiency in 0.53-0.55.4)The polycentricity index has an interaction effect with other variables;specifically,when the polycentricity index is between 0.53 and 0.55,its interaction with urban gross domestic product(GDP),urban population,urban built-up area,green coverage rate in built-up areas,urban technological expenditure,and the proportion of the output value of the secondary industry will reduce carbon emissions and improve carbon emission efficiency.These findings enhance the understanding of urban spatial structures and carbon emissions,providing valuable insights for policymakers in developing green and low-carbon strategies.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos.12274313 and 62375234)the Gusu Leading Talent Plan for Scientific and Technological Innovation and Entrepreneurship (Grant No.ZXL2024400)。
文摘Optical phase-gradient metasurfaces have garnered significant attention for enabling flexible light manipulation,with applications across diverse domains.In this work,we will demonstrate that the metasurfaces with phase gradient modulation can be used to achieve illusion optics,featuring the advantages of simple geometric structure and feasible implementation compared with the well-known transformation optics method.The underlying mechanism is the anomalous diffraction law caused by the phase gradient,which provides a theoretical basis for freely manipulating the propagation path of light.By considering a specific example,we will demonstrate that the phase gradient can transform spatial coordinates in real space into illusion space,thereby converting a plane in real space into a curved surface structure in illusion space to achieve the illusion effect.This approach provides a viable alternative to transformation optics for designing illusion devices.
基金supported financially by the National Natural Science Foundation of China(No.51771155)the Equipment Pre-research Field Foundation(No.61409220202).
文摘In this work,ultrasonic surface rolling process(USRP)was utilized to produce a gradient structured layer on 7 B50-T7751 aluminum alloy,and the mechanical properties and corrosion fatigue behavior of treated samples were studied.These results reveal that underwent USRP,a 425~m thick gradient structure and a 700~m deep compressive residual stress field are created,aluminum grain size become fine(~67 nm),and the corrosion rate of treated surface reduces by 60.08%owing to the combined effect of compressive residual stress and surface nanocrystallization.The corrosion fatigue strength is enhanced to 117%of that of 7 B50 Al alloys by means of USRP due to the introduced compressive residual stress,which is considered as the major favorable factor in suppressing the initiation and early propagation of corrosion fatigue cracks.Besides,the gradient structure is an important factor in providing a significant synergistic contribution to the improvement of corrosion fatigue performance.
基金supported by the National Key Research and Development Program of China(2023YFB3809300).
文摘Recycling spent lithium-ion(Li+)batteries is critical for achieving environmental conservation and the strategic recovery of essential resources.Compared with conventional methods for recovering cathode materials,which are energy-intensive and prone to secondary pollution,the direct regeneration approach has emerged as a rapid and highly efficient method,gaining widespread attention in recent years.However,this approach faces major challenges,including degraded electrochemical performances and limited economic value.This study,therefore,proposes a high-value direct regeneration strategy to convert degraded spent LiFePO_(4)(S-LFP)into a gradient manganese(Mn)-doped regenerated LiFe_(0.7)Mn_(0.3)PO_(4)/C(R-LFMP)composite.This method leverages the inherent microcracks and Li vacancies present in S-LFP,likely acting as diffusion channels for the Mn^(2+)/Li^(+)ions.Through a two-step mechanochemical ball-milling and carbothermal reduction process,this approach achieves simultaneous Li replenishment and surface-localised Mn gradient doping with enhanced structural control.Notably,the R-LFMP exhibits an exceptional electrochemical performance.At 0.1 C,it delivers a discharge capacity of 161.4 mA h g^(−1)and an energy density of 563.5 Wh kg^(−1)(representing a 60.5%improvement over S-LFP).Additionally,it maintains 83%capacity retention after 900 cycles at 0.5C,a considerable enhancement compared to commercial LFMP(62%).Furthermore,the regenerated cathode material generates a net profit of$7.102 kg^(−1),surpassing the profitability of conventional recycling methods by 90%.Overall,this study introduces a transformative and sustainable LFP regeneration technology,achieving breakthroughs in electrochemical restoration and high-value recycling,while paving the way for the closed-loop utilisation of LFP-based energy storage systems.
基金supported by the National Research Foundation of Korea(NRF)grants(Grant Nos.RS-2020-NR049594 and RS-2022-NR071877)the Korea Agency for Infrastructure Technology Advancement under the Ministry of Land,Infrastructure and Transport(Grant No.RS-2024-00410248).
文摘Suffusion refers to the loss of fineparticles within the soil matrix without any associated volume change,induced by hydrodynamic forces.This study investigated the suffusion of sand-clay mixtures through one-dimensional soil column experiments under a stepwise increase in hydraulic gradient(i),aiming to evaluate the critical hydraulic gradient(icrit)as a function of the size ratio between sand and clay,clay type,and ionic concentration.It was found that icrit was less than 0.1 for all sand-clay mixtures examined in this study.In addition,the lower peak concentrations of filtrated clay observed in sand-illite mixtures,compared to those of sand-kaolinite mixtures at the same level of i,suggest that illite particles are more susceptible to suffusion.Overall,the observed breakthrough curves,mass fraction of filtrated clay,volume of outflow,and total injection time presented in this study highlight the importance of considering clay type,sand-to-clay size ratio,and ionic concentration when assessing the suffusion behavior of clay-containing soils under a stepwise increase in hydraulic gradient.
基金supported by Natural Science Foundation of Xiamen,China(No.3502Z20227232)the STS Project of Fujian-CAS(No.2023T3018)Bureau of International Cooperation,Chinese Academy of Sciences(No.322GJHZ2022035MI).
文摘Anammox bacteria in constructed wetlands(CWs)play pivotal role in sustainable nitrogen transformation,yet existing studies lack comprehensive analysis of environmental gradients and microbial interactions,both key factors in anammox bacteria enrichment.This study investigated the mechanisms driving anammox bacteria enrichment in lab-scale simulated CWs treating high-nitrogen wastewater,focusing on bacterial community re-sponses across wetland layers with various strategies,including continuous up-flow influent,nitrogen loading increase,effluent recirculation,intermittent influent,and anammox bacteria inoculation.Results showed that total relative and absolute abundances of anammox bacteria ranged from 0.77%to 12.50%and from 0.13 to 6.46×10^(7) copies/g,respectively.Dissolved oxygen and pH had significant positive correlations with the absolute abundance of anammox bacteria,while organic matter and nitrate negatively impacted their relative abundance.Permutational multivariate analysis of variance indicated that spatial heterogeneity explained more variation in anammox bacteria abundance(43.44%)compared to operational strategies(8.58%).In terms of microbial interactions,60 dominant species exhibited potential correlations with anammox bacteria,comprising 170 interactions(105 positive and 65 negative),which suggested that anammox bacteria generally foster cooperative relationships with dominant bacteria.Notably,significant interspecies interactions were observed between Candidatus Kuenenia(dominant anammox bacteria in CWs)and species within the genera Chitinivibrio-nia and Anaerolineaceae,suggesting that microbial interactions primarily manifest as indirect facilitative effects rather than direct mutualistic relationships.Given that the Normalized Stochasticity Ratio in CWs were<50%,this study inferred that environmental gradients have greater influence on anammox bacteria than microbial interactions.
基金co-supported by the National Natural Science Foundation of China(Nos.52305421 and 52175363)the General Research Fund of Hong Kong,China(No.15223520)the projects from the Hong Kong Polytechnic University,China(Nos.4-W418,1-ZE1W,4-WZ4W and 1-CD4H)。
文摘Gradient microstructures strengthened by serrated Grain Boundaries(GBs)were achieved through a combination of Gradient Strain Deformation(GSD)and Serration Heat Treatment(SHT),with particular focus on microstructural evolution,underlying mechanisms,and the critical influencing factors.Dynamic recrystallization governed the microstructural evolution in the fine-grained and transition regions during GSD,where multiple nucleation mechanisms were active.Plastic deformation facilitated the dissolution ofγ'phase in fine-grained regions,ultimately resulting in its morphological transformation.During the subsequent SHT,serrated GBs formed within the gradient microstructures produced by prior GSD without disrupting the grain size gradient,thereby enhancing creep resistance.Two distinct mechanisms associated withγ'gbparticles governed the formation of the serrations at GBs.Owing to the stronger dragging effect of grain boundary junctions in fine-grained regions,the amplitude and wavelength of serrations in these regions were smaller than those in coarse-grained regions.Moreover,the formation of serrations exhibited a strong dependence on the inherent properties of the GBs.The random high-angle grain boundaries(HAGBs)with misorientation angles in the range of 30-59°tended to become serrated more easily during SHT due to their high mobility and the accelerated precipitation ofγ'gbparticles at them.Low-ΣHAGBs and low-angle GBs were not prone to form serrations.In particular,serration formation was completely inhibited atΣ3 twin boundaries due to their extremely low mobility and the absence ofγ'gbparticles.
基金supported by the“Regional Innovation System&Education(RISE)”through the Seoul RISE Center,funded by the Ministry of Education(MOE)and the Seoul Metropolitan Government(2025-RISE-01-027-04).
文摘Fluid dynamic research on rectangular and trapezoidal fins is aimed at increasing heat transfer by means of large surfaces.The trapezoidal cavity form is compared with its thermal and flow performance,and it is revealed that trapezoidal fins tend to be more efficient,particularly when material optimization is critical.Motivated by the increasing need for sustainable energy management,this work analyses the thermal performance of inclined trapezoidal and rectangular porous fins utilising a unique hybrid nanofluid.The effectiveness of nanoparticles in a working fluid is primarily determined by their thermophysical properties;hence,optimising these properties can significantly improve overall performance.This study considers the dispersion of Graphene Oxide(GO)and Molybdenum Disulfide in the base fluid,engine oil.Temperature profiles are analysed by altering the radiative,porosity,wet porous,and angle of inclination parameters.Surface and contour plots are constructed by using the Lobatto IIIa Collocation Method with BVP5C solver in MATLAB and Gradient Descent Optimisation to predict the combined heat transfer rate.According to the study,fluid temperature consistently decreases when the angle of inclination,wet porous parameter,porosity parameter,and radiative parameter increase,suggesting significantly improved heat dissipation.The trapezoidal fin consistently exhibits a superior heat transfer mechanism than a rectangular fin.It is found that the trapezoidal fin transmits heat at a rate that is 0.05%higher than that of the rectangular fin.Validation of the present study is done through the comparison of previous studies.This research provides useful design insights for sophisticated engineering uses,including electrical cooling devices,heat exchangers,radiators,and solar heaters.
基金This work was supported in part by the National Natural Science Foundation of China(61601418,41602362,61871259)in part by the Opening Foundation of Hunan Engineering and Research Center of Natural Resource Investigation and Monitoring(2020-5)+1 种基金in part by the Qilian Mountain National Park Research Center(Qinghai)(grant number:GKQ2019-01)in part by the Geomatics Technology and Application Key Laboratory of Qinghai Province,Grant No.QHDX-2019-01.
文摘This work was to generate landslide susceptibility maps for the Three Gorges Reservoir(TGR) area, China by using different machine learning models. Three advanced machine learning methods, namely, gradient boosting decision tree(GBDT), random forest(RF) and information value(InV) models, were used, and the performances were assessed and compared. In total, 202 landslides were mapped by using a series of field surveys, aerial photographs, and reviews of historical and bibliographical data. Nine causative factors were then considered in landslide susceptibility map generation by using the GBDT, RF and InV models. All of the maps of the causative factors were resampled to a resolution of 28.5 m. Of the 486289 pixels in the area,28526 pixels were landslide pixels, and 457763 pixels were non-landslide pixels. Finally, landslide susceptibility maps were generated by using the three machine learning models, and their performances were assessed through receiver operating characteristic(ROC) curves, the sensitivity, specificity,overall accuracy(OA), and kappa coefficient(KAPPA). The results showed that the GBDT, RF and In V models in overall produced reasonable accurate landslide susceptibility maps. Among these three methods, the GBDT method outperforms the other two machine learning methods, which can provide strong technical support for producing landslide susceptibility maps in TGR.
基金Project supported by the National Natural Science Foundation of China(Nos.11872233 and11472163)the China Scholarship Council(No.201706890041)the Innovation Program of Shanghai Municipal Education Commission(No.2017-01-07-00-09-E00019)
文摘In this pap er, a novel size-dep endent functionally graded (FG) cylindrical shell model is develop ed based on the nonlocal strain gradient theory in conjunction with the Gurtin-Murdoch surface elasticity theory . The new model containing a nonlocal parameter, a material length scale parameter, and several surface elastic constants can capture three typical typ es of size e ects simultaneously , which are the nonlocal stress ef- fect, the strain gradient e ect, and the surface energy e ects. With the help of Hamilton’s principle and rst-order shear deformation theory , the non-classical governing equations and related b oundary conditions are derived. By using the prop osed model, the free vibra- tion problem of FG cylindrical nanoshells with material prop erties varying continuously through the thickness according to a p ower-law distribution is analytically solved, and the closed-form solutions for natural frequencies under various b oundary conditions are obtained. After verifying the reliability of the prop osed model and analytical method by comparing the degenerated results with those available in the literature, the in uences of nonlocal parameter, material length scale parameter, p ower-law index, radius-to-thickness ratio, length-to-radius ratio, and surface e ects on the vibration characteristic of func- tionally graded cylindrical nanoshells are examined in detail.
基金supported by the National Special Plan for the 13th Five-Year Plan of China(No.2017YFC0602204-10)Independent Exploration of the Innovation Project for Graduate Students at Central South University(No.2017zzts176)+3 种基金National Natural Science Foundation of China(Nos.41574127,41404106,and 41674075)Postdoctoral Fund Projects of China(No.2017M622608)National Key R&D Program of China(No.2018YFC0603602)Natural Science Youth Fund Project of the Hunan Province,China(No.2018JJ3642)
文摘Magnetic field gradient tensor technique provides abundant data for delicate inversion of subsurface magnetic susceptibility distribution. Large scale magnetic data inversion imaging requires high speed and accuracy for forward modeling. For arbitrarily distributed susceptibility data on an undulated surface, we propose a fast 3D forward modeling method in the wavenumber domain based on(1) the wavenumber-domain expression of the prism combination model and the Gauss–FFT algorithm and(2) cubic spline interpolation. We apply the proposed 3D forward modeling method to synthetic data and use weighting coefficients in the wavenumber domain to improve the modeling for multiple observation surfaces, and also demonstrate the accuracy and efficiency of the proposed method.
基金Support by Project of Geophysical Comprehensive Survey and Information Extraction of Deep Mineral Resources(2016YFC0600505)
文摘With the development of gravity gradient full tensor measurement technique,three-dimensional( 3D) inversion based on gravity gradient tensor can provide more accurate information. But the forward calculation of 3D full tensor sensitivity matrix is very time-consuming,which restricts its development and application.According to the symmetry of the kernel function,the authors reconstruct the underground source of geological body to avoid repeat computation of the same value,and work out the corresponding relationship between the response of geological body to the observation point and the response of reconstructed geological body to the observation point. According to the relationship,rapid calculation of full tensor gravity sensitivity matrix can be achieved. The model calculation shows that this method can increase the speed of 30-45 times compared with the traditional calculation method. The sensitivity matrix is applied to the multi-component inversion of gravity gradient. The application of this method on the measured data provides the basis for the promotion of the method.
文摘Compared with conventional well, herringbone-like laterals wells can increase the area of oil release, and can reduce the number of wellhead slots of platforms,?and?also can greatly improve the development efficiency. Based on threshold pressure gradient in heavy oil reservoir,?and?the applied principle of mirror reflection and superposition, the pressure distribution equation of herringbone-like laterals wells is obtained in heavy oil reservoir. Productivity model of herringbone-like laterals wells is proposed by reservoir-wellbore steady seepage. The example shows that the productivity model is great accuracy?to?predict the productivity of herringbone-like laterals wells. The model is used to analyze the branching length, branching angle, branching symmetry, branching position and spacing and their effects on productivity of herringbone-like laterals wells. The principle of optimizing the well shape of herringbone-like laterals wells is proposed.
基金supported by the National Natural Science Foundation of China(Grant Nos.12274313,62275184,and 62411540033)Collaborative Innovation Center of Suzhou Nano Science and Technology,Suzhou Basic Research Project(Grant No.SJC2023003)+1 种基金the Gusu Leading Talent Plan for Scientific and Technological Innovation and Entrepreneurship(Grant No.ZXL2024400)the Priority Academic Program Development of Jiangsu Higher Education Institutions.
文摘Perfect anomalous reflections have been demonstrated in optical phase gradient metasurfaces(PGMs),but they suffer from single-frequency(narrow-band)response due to the intrinsic limitation of natural geometric periodicity.Here,we provide both numerical and analytical evidence that a depth gradient metasurface can achieve discrete ultra-broadband perfect anomalous reflection in the microwave range in the absence of geometric periodicity.Remarkably,by adjusting the operating frequency of the incident wave,the same effect can be steadily obtained via a physically equivalent phase periodicity in the PGM.Based on this mechanism,a perfect retroreflector with a broadband response ranging from 1 GHz to 40 GHz is realized.Our work has promising applications in communication,source tracking,and military satellites.
基金supported by Culture,Sports and Tourism R&D Program through the Korea Creative Content Agency grant funded by the Ministry of Culture,Sports and Tourism in 2024(Project Name:Global Talent Training Program for Copyright Management Technology in Game Contents,Project Number:RS-2024-00396709,Contribution Rate:100%).
文摘Cyber-physical systems(CPS)represent a sophisticated integration of computational and physical components that power critical applications such as smart manufacturing,healthcare,and autonomous infrastructure.However,their extensive reliance on internet connectivity makes them increasingly susceptible to cyber threats,potentially leading to operational failures and data breaches.Furthermore,CPS faces significant threats related to unauthorized access,improper management,and tampering of the content it generates.In this paper,we propose an intrusion detection system(IDS)optimized for CPS environments using a hybrid approach by combining a natureinspired feature selection scheme,such as Grey Wolf Optimization(GWO),in connection with the emerging Light Gradient Boosting Machine(LightGBM)classifier,named as GWO-LightGBM.While gradient boosting methods have been explored in prior IDS research,our novelty lies in proposing a hybrid approach targeting CPS-specific operational constraints,such as low-latency response and accurate detection of rare and critical attack types.We evaluate GWO-LightGBM against GWO-XGBoost,GWO-CatBoost,and an artificial neural network(ANN)baseline using the NSL-KDD and CIC-IDS-2017 benchmark datasets.The proposed models are assessed across multiple metrics,including accuracy,precision,recall,and F1-score,with an emphasis on class-wise performance and training efficiency.The proposed GWO-LightGBM model achieves the highest overall accuracy(99.73%)for NSL-KDD and(99.61%)for CIC-IDS-2017,demonstrating superior performance in detecting minority classes such as Remote-to-Local(R2L)and Other attacks—commonly overlooked by other classifiers.Moreover,the proposed model consumes lower training time,highlighting its practical feasibility and scalability for real-time CPS deployment.
基金supported by the School of Engineering and Digital Sciences of Nazarbayev University,Astana,Kazakhstan(to CE)。
文摘The osteochondral(OC)interface exhibits a mineral gradient,varying in thickness by several hundred micrometers across different species.Disruptions in this interface damage OC tissues,leading to osteoarthritis.The natural architecture and composition of native OC interfaces can be replicated using biomaterial scaffolds via regenerative engineering approaches.A novel one-step bioextrusion process was employed to fabricate a unitary synthetic graft(USG),which mimics the native OC interface’s mineral concentration gradient.This novel USG is composed of an agarose-based cartilage layer and a bone layer,consisting of agarose enriched with 20%(200 g/L)hydroxyapatite.The USG features a gradient interface with mineral concentrations transitioning from 0%to 20%(mass fraction),mimicking the transition between the cartilage and bone.Thermogravimetric analysis revealed that the gradient transition lengths of the graft and native OC tissue harvested from bovine knees were similar((647±21)vs.(633±124)μm).The linear viscoelastic properties of the grafts,which were evaluated using strain sweep and frequency sweep tests with oscillatory shear,indicated a dominant storage modulus over loss modulus similar to that of native OC tissues.The compressive and stress relaxation behaviors of the USGs demonstrated that the graft maintained structural integrity under mechanical stress.Viability assays performed after bioextrusion showed that chondrocytes and human fetal osteoblast cells successfully integrated and survived within their designated regions of the graft.The novel USGs exhibit properties similar to native OC tissue and are promising candidates for regenerating OC defects and restoring knee joint functionality.
基金supported by the National Key Research and Development Plan(Grant No.2022YFB3401901)the National Natural Science Foundation of China(Grant Nos.12192210,12192214,12072295,and 12222209)+1 种基金Independent Project of State Key Laboratory of Rail Transit Vehicle System(Grant No.2023TPL-T03)Fundamental Research Funds for the Central Universities(Grant No.2682023CG004).
文摘The S38C railway axle undergoes induction hardening,resulting in a gradient-distributed microstructure and mechanical properties.The accurate identification of gradient-distributed plastic parameters for the S38C axle remains a challenging task.To tackle this challenge,the present study proposes a novel approach for identifying the gradient-distributed plastic parameters for the S38C axle by integrating nano-indentation techniques with the machine learning method.Firstly,nano-indentation tests are conducted along the radial direction of the S38C axle to obtain the gradient-distributed load-displacement curves,nano-hardness,and elastic modulus.Subsequently,the dimensionless analysis is performed to obtain the representative stress,strain,and yield stress from load-displacement curves.These parameters are then incorporated into the machine learning method as physical information to identify the gradient-distributed plastic parameters of the S38C axle.The results indicate that the proposed method based on the physics-informed neural network and multi-fidelity neural network successfully identifies the gradient-distributed plastic parameters of the S38C axles and demonstrates superior prediction accuracy and generalization compared with the purely data-driven machine learning method.
基金support from the National Key Research and Development Program of China(2022YFB4600101)the National Natural Science Foundation of China(52505231 and 52175201)+5 种基金the Key R&D Program of Shandong Province(2024CXPT035)the Research Program of Science and Technology Department of Gansu Province(24JRRA059,24JRRA044 and 24ZDGA014)the Science Fund of Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai(AMGM2024F12)the Innovation and Entrepreneurship Team Prject of YEDA(2021TD007)the Special Supporting Project for Provincial Leading Talents of Yantai,the Major Program(ZYFZFX-2)the Fundamental Research Special Zone Project of the Lanzhou Institute of Chemical Physics,CAS,the Special Research Assistant Project of the Chinese Academy of Sciences,and the Taishan Scholars Program.
文摘The development of gradient lubrication materials is critical for numerous biomedical applications,particularly in magnifying mechanical properties and service longevity.Herein,we present an innovative approach to fabricate biomimetic gradient lubrication hydrogel through the synergistic integration of three-dimensional(3D)printed metal-organic frameworks(MOFs)nanoparticle network hydrogel skeletons with bioinspired lubrication design.Specifically,robust hydrogel skeletons were engineered through single or multi-material 3D printing,followed by the in situ growth of MOFs nanoparticles within this hydrogel network to create a reinforced,load-bearing architecture.Subsequently,biomimetic lubrication capability was enabled by mechanically coupling another lubricating hydrogel within 3D-printed MOFs nanoparticle network hydrogel skeleton.The superficial layer is highly lubricious to ensure low coefficient of friction(~0.1141)and wear resistance(40,000 cycles),while the deeper layer is stiffer to afford the obligatory mechanical support(fracture strength~2.50 MPa).Furthermore,the gradient architecture stiffness of the hydrogel can be modulated by manipulating the spatial distribution of MOFs within the 3D-printed hydrogel skeleton.As a proof-of-concept,biomimetic gradient hydrogel meniscus structures with C-and O-shaped configurations were constructed by leveraging multi-material 3D printing,demonstrating exceptional lubrication performance.This innovative biomimetic design opens new avenues for creating implantable biomedical gradient lubricating materials with reinforced mechanical and lubrication performance.
基金financial support from the National Natural Science Foundation of China(Grant No.52273067,52233006)the Fundamental Research Funds for the Central Universities(Grant No.2232023A-03)+3 种基金the Shuguang Program of Shanghai Education Development Foundation and Shanghai Municipal Education Commission(Grant No.23SG29)the Natural Science Foundation of Shanghai(Grant No.24ZR1402400)the Shanghai Scientific and Technological Innovation Project(Grant No.24520713000)Innovation Program of Shanghai Municipal Education Commission(Grant No.2021-01-07-00-03-E00108).
文摘Radiative cooling textiles with spectrally selective surfaces offer a promising energy-efficient approach for sub-ambient cooling of outdoor objects and individuals.However,the spectrally selective mid-infrared emission of these textiles significantly hinders their efficient radiative heat exchange with self-heated objects,thereby posing a significant challenge to their versatile cooling applicability.Herein,we present a bicomponent blow spinning strategy for the production of scalable,ultra-flexible,and healable textiles featuring a tailored dual gradient in both chemical composition and fiber diameter.The gradient in the fiber diameter of this textile introduces a hierarchically porous structure across the sunlight incident area,thereby achieving a competitive solar reflectivity of 98.7%on its outer surface.Additionally,the gradient in the chemical composition of this textile contributes to the formation of Janus infrared-absorbing surfaces:The outer surface demonstrates a high mid-infrared emission,whereas the inner surface shows a broad infrared absorptivity,facilitating radiative heat exchange with underlying self-heated objects.Consequently,this textile demonstrates multi-scenario radiative cooling capabilities,enabling versatile outdoor cooling for unheated objects by 7.8℃ and self-heated objects by 13.6℃,compared to commercial sunshade fabrics.
基金Under the auspices of National Natural Science Foundation of China(No.42571300)。
文摘Transforming urban spatial structures to promote green and low-carbon development is an effective strategy.Although prior studies have examined the impact of urban polycentricity on carbon emissions and economic development,research on its role in the synergistic relationship between these factors regarding carbon emission efficiency is limited.Furthermore,existing literature often overlooks nonlinear effects and interactions with other urban variables.This paper analyzed data from 295 Chinese cities in 2020,calculating urban population polycentricity,population dispersion indices,and carbon emission efficiency.Utilizing local spatial autocorrelation tools,we reveal interactions among urban population polycentricity,dispersion,carbon emissions,and carbon emission efficiency.We then employ a gradient boosting decision tree model(GBDT)to explore nonlinear and synergistic effects of polycentric urbanization.Key findings include:1)polycentric urbanization in Chinese cities exhibits significant spatial differentiation characteristics.The Polycentricity index is relatively high in economically developed eastern coastal regions with an overall low level,carbon emissions are concentrated in industrialized north-central cities and some Yangtze River Delta hubs,and carbon emission efficiency is the highest in the Yangtze River Delta while relatively low in Northeast China;there are significant spatially heterogeneous interaction characteristics among population polycentricity,population dispersion,carbon emissions,and carbon emission efficiency.2)Urban population polycentricity contributes 9.42%to total carbon emissions and 6.24%to carbon emission efficiency.3)The polycentricity index has a nonlinear impact on carbon emissions and carbon emission efficiency:no significant effect when below 0.50 or above 0.55,increased carbon emissions in 0.50-0.53,and reduced carbon emissions with improved efficiency in 0.53-0.55.4)The polycentricity index has an interaction effect with other variables;specifically,when the polycentricity index is between 0.53 and 0.55,its interaction with urban gross domestic product(GDP),urban population,urban built-up area,green coverage rate in built-up areas,urban technological expenditure,and the proportion of the output value of the secondary industry will reduce carbon emissions and improve carbon emission efficiency.These findings enhance the understanding of urban spatial structures and carbon emissions,providing valuable insights for policymakers in developing green and low-carbon strategies.
