Optical phase-gradient metasurfaces have garnered significant attention for enabling flexible light manipulation,with applications across diverse domains.In this work,we will demonstrate that the metasurfaces with pha...Optical phase-gradient metasurfaces have garnered significant attention for enabling flexible light manipulation,with applications across diverse domains.In this work,we will demonstrate that the metasurfaces with phase gradient modulation can be used to achieve illusion optics,featuring the advantages of simple geometric structure and feasible implementation compared with the well-known transformation optics method.The underlying mechanism is the anomalous diffraction law caused by the phase gradient,which provides a theoretical basis for freely manipulating the propagation path of light.By considering a specific example,we will demonstrate that the phase gradient can transform spatial coordinates in real space into illusion space,thereby converting a plane in real space into a curved surface structure in illusion space to achieve the illusion effect.This approach provides a viable alternative to transformation optics for designing illusion devices.展开更多
Anammox bacteria in constructed wetlands(CWs)play pivotal role in sustainable nitrogen transformation,yet existing studies lack comprehensive analysis of environmental gradients and microbial interactions,both key fac...Anammox bacteria in constructed wetlands(CWs)play pivotal role in sustainable nitrogen transformation,yet existing studies lack comprehensive analysis of environmental gradients and microbial interactions,both key factors in anammox bacteria enrichment.This study investigated the mechanisms driving anammox bacteria enrichment in lab-scale simulated CWs treating high-nitrogen wastewater,focusing on bacterial community re-sponses across wetland layers with various strategies,including continuous up-flow influent,nitrogen loading increase,effluent recirculation,intermittent influent,and anammox bacteria inoculation.Results showed that total relative and absolute abundances of anammox bacteria ranged from 0.77%to 12.50%and from 0.13 to 6.46×10^(7) copies/g,respectively.Dissolved oxygen and pH had significant positive correlations with the absolute abundance of anammox bacteria,while organic matter and nitrate negatively impacted their relative abundance.Permutational multivariate analysis of variance indicated that spatial heterogeneity explained more variation in anammox bacteria abundance(43.44%)compared to operational strategies(8.58%).In terms of microbial interactions,60 dominant species exhibited potential correlations with anammox bacteria,comprising 170 interactions(105 positive and 65 negative),which suggested that anammox bacteria generally foster cooperative relationships with dominant bacteria.Notably,significant interspecies interactions were observed between Candidatus Kuenenia(dominant anammox bacteria in CWs)and species within the genera Chitinivibrio-nia and Anaerolineaceae,suggesting that microbial interactions primarily manifest as indirect facilitative effects rather than direct mutualistic relationships.Given that the Normalized Stochasticity Ratio in CWs were<50%,this study inferred that environmental gradients have greater influence on anammox bacteria than microbial interactions.展开更多
Radiative cooling textiles with spectrally selective surfaces offer a promising energy-efficient approach for sub-ambient cooling of outdoor objects and individuals.However,the spectrally selective mid-infrared emissi...Radiative cooling textiles with spectrally selective surfaces offer a promising energy-efficient approach for sub-ambient cooling of outdoor objects and individuals.However,the spectrally selective mid-infrared emission of these textiles significantly hinders their efficient radiative heat exchange with self-heated objects,thereby posing a significant challenge to their versatile cooling applicability.Herein,we present a bicomponent blow spinning strategy for the production of scalable,ultra-flexible,and healable textiles featuring a tailored dual gradient in both chemical composition and fiber diameter.The gradient in the fiber diameter of this textile introduces a hierarchically porous structure across the sunlight incident area,thereby achieving a competitive solar reflectivity of 98.7%on its outer surface.Additionally,the gradient in the chemical composition of this textile contributes to the formation of Janus infrared-absorbing surfaces:The outer surface demonstrates a high mid-infrared emission,whereas the inner surface shows a broad infrared absorptivity,facilitating radiative heat exchange with underlying self-heated objects.Consequently,this textile demonstrates multi-scenario radiative cooling capabilities,enabling versatile outdoor cooling for unheated objects by 7.8℃ and self-heated objects by 13.6℃,compared to commercial sunshade fabrics.展开更多
Gradient structures(GS)play a crucial role in achieving a balance between strength and plasticity in metals and alloys.However,there is still a lack of understanding of the mechanisms that maintain a plasticity gradie...Gradient structures(GS)play a crucial role in achieving a balance between strength and plasticity in metals and alloys.However,there is still a lack of understanding of the mechanisms that maintain a plasticity gradient to prevent the premature failure of fine grains in GS materials.In this work,by incorporating experimental data and the Hall-Petch relationship,we develop a size-dependent crystal plasticity model to investigate the deformation mechanisms for enhancing the strength and plasticity in polycrystalline high entropy alloys.The simulations of the GS model align well with the experimental results,exhibiting strong strain and stress gradients to improve the mechanical properties.Under the conditions of significant de-formation incompatibility,the strain gradient predominantly drives the enhancement of plasticity mechanisms.As the de-formation incompatibility decreases,the stress gradient begins to play a significant role in comparison with the strain gradient.This shift is attributed to the regular variations in dislocation density within different domains.As the grain size gradients and loads decrease,the dislocation density becomes more uniform across the domains,hindering the formation of strong domain boundaries.While this may impede the activation of strain gradients,it facilitates the activation of stress gradients as a supplementary measure.By designing multilayered GS structures to alter the distribution of dislocation density,we can control the activation levels of stress and strain gradients,thereby influencing the plasticity mechanisms and mechanical properties of the material.展开更多
Perfect anomalous reflections have been demonstrated in optical phase gradient metasurfaces(PGMs),but they suffer from single-frequency(narrow-band)response due to the intrinsic limitation of natural geometric periodi...Perfect anomalous reflections have been demonstrated in optical phase gradient metasurfaces(PGMs),but they suffer from single-frequency(narrow-band)response due to the intrinsic limitation of natural geometric periodicity.Here,we provide both numerical and analytical evidence that a depth gradient metasurface can achieve discrete ultra-broadband perfect anomalous reflection in the microwave range in the absence of geometric periodicity.Remarkably,by adjusting the operating frequency of the incident wave,the same effect can be steadily obtained via a physically equivalent phase periodicity in the PGM.Based on this mechanism,a perfect retroreflector with a broadband response ranging from 1 GHz to 40 GHz is realized.Our work has promising applications in communication,source tracking,and military satellites.展开更多
Species richness in any area results from the interplay of the processes of speciation,extinction,and dispersal.The relationships between species richness and climate should be considered as an outcome of the effects ...Species richness in any area results from the interplay of the processes of speciation,extinction,and dispersal.The relationships between species richness and climate should be considered as an outcome of the effects of climate on speciation,extinction,and dispersal.Diversificationrate represents the balance of speciation and extinction rates over time.Here,I explore diversificationrates in mosses across geographic and climatic gradients worldwide.Specifically,I investigate latitudinal patterns and climatic associations of the mean diversificationrate of mosses at global,hemispheric,and smaller scales.I findthat the mean diversificationrate of mosses is positively correlated with species richness of mosses,increases with decreasing latitude and increasing mean annual temperature and annual precipitation,and is more strongly associated with mean annual temperature than with annual precipitation.These findingsshed light on variation of species richness in mosses across the world.The negative relationship between species richness and latitude and the positive relationship between species richness and mean diversificationrate in mosses suggest that higher moss species richness at lower latitudes might have resulted,at least to some degree,from higher moss diversificationrates at lower latitudes.展开更多
Liver-directed therapies such as resection,ablation,and embolization offer potentially curative options for patients with primary and metastatic liver tumors as part of multidisciplinary oncology care.However,these tr...Liver-directed therapies such as resection,ablation,and embolization offer potentially curative options for patients with primary and metastatic liver tumors as part of multidisciplinary oncology care.However,these treatments pose significant hepatic decompensation risks,particularly with underlying liver disease and chemotherapy-associated steatohepatitis.Accurate assessment of liver function and portal hypertension(PH)is critical for candidate selection.While Child-Pugh score and model for end-stage liver disease are commonly used,they have substantial limitations.Hepatic venous pressure gradient(HVPG)measurement remains the gold standard for assessing PH but is invasive and not widely available.Endoscopic ultrasound(EUS)guided portal pressure gradient(PPG)measurement has emerged as a promising minimally invasive alternative.EUSPPG demonstrates excellent technical success rates,safety profile,and correlation with HVPG in early studies.By providing direct portal pressure measurement,EUS-PPG offers several advantages over existing methods for prognostication and risk stratification prior to liver-directed therapies,particularly in detecting presinusoidal hypertension.Furthermore,it has potential applications in assessing response to neoadjuvant treatments and guiding adjuvant therapies.However,research is needed to validate its predictive performance and cost-effectiveness in larger prospective cohorts and to establish its accuracy compared to non-invasive assessment of liver function.展开更多
The GH141 superalloy ring-rolled parts often face microstructural inhomogeneity during production.This work investigated the effect of post-dynamic recrystallization on the microstructural evolution of GH141 superallo...The GH141 superalloy ring-rolled parts often face microstructural inhomogeneity during production.This work investigated the effect of post-dynamic recrystallization on the microstructural evolution of GH141 superalloy after gradient thermal deformation to solve the problem of microstructural inhomogeneity.Compression tests involving double cone(DC)samples were conducted at various temperatures to assess the effect of gradient strain on internal grain microstructure variation,which ranged from the rim to the center of the samples.The results demonstrate considerable microstructural inhomogeneity induced by gradient strain in the DC samples.The delay in heat preservation facilitated post-dynamic recrystallization(PDRX)and promoted extensive recrystallization in the DC samples experiencing large gradient strain,which resulted in a homogeneous grain microstructure throughout the samples.During compression at a relatively low temperature,dynamic recrystallization(DRX)was predominantly driven by continuous dynamic recrystallization(CDRX).As the deformation temperature increased,the DRX mechanism changed from CDRX-dominated to being dominated by discontinuous dynamic recrystallization(DDRX).During the delay of the heat preservation process,PDRX was dominated by a static recrystallization mechanism,along with the occurrence of meta-dynamic recrystallization(MDRX)mechanisms.In addition,the PDRX mechanism of twin-induced recrystallization nucleation was observed.展开更多
A widely employed energy technology,known as reverse electrodialysis(RED),holds the promise of delivering clean and renewable electricity from water.This technology involves the interaction of two or more bodies of wa...A widely employed energy technology,known as reverse electrodialysis(RED),holds the promise of delivering clean and renewable electricity from water.This technology involves the interaction of two or more bodies of water with varying concentrations of salt ions.The movement of these ions across a membrane generates electricity.However,the efficiency of these systems faces a challenge due to membrane performance degradation over time,often caused by channel blockages.One potential solution to enhance system efficiency is the use of nanofluidic membranes.These specialized membranes offer high ion exchange capacity,abundant ion sources,and customizable channels with varying sizes and properties.Graphene oxide(GO)-based membranes have emerged as particularly promising candidates in this regard,garnering significant attention in recent literature.This work provides a comprehensive overview of the literature surrounding GO membranes and their applications in RED systems.It also highlights recent advancements in the utilization of GO membranes within these systems.Finally,it explores the potential of these membranes to play a pivotal role in electricity generation within RED systems.展开更多
According to the second law of thermodynamics,spontaneous chemical processes will ultimately reach the equilibrium state with the lowest energy.However,in biological systems,there are numerous highenergy states far fr...According to the second law of thermodynamics,spontaneous chemical processes will ultimately reach the equilibrium state with the lowest energy.However,in biological systems,there are numerous highenergy states far from equilibrium.One typical example is the transmembrane ion-concentration gradient,which plays crucial roles in maintaining homeostasis,regulating cell volume,and enabling cell signaling.Transmembrane ion-concentration gradient is achieved by an active transport process that requires the input of energy and the action of pump proteins.Replicating this process with synthetic supramolecular systems is particularly challenging,requiring both the input of energy and very specific,spatiotemporal control over ion uptake and release.In nature,pump proteins,such as protein-based ion channels,have evolved highly intricate architectures to perform this function.In contrast,Aprahamian and coworkers recently developed a much simpler smallmolecule system that functions as a molecular ion pump,utilizing light energy to pump chloride ions across a hydrophobic barrier against the concentration gradient[1].展开更多
Gradient coil is an essential component of a magnetic resonance imaging(MRI)scanner.To achieve high spatial resolution and imaging speed,a high-efficiency gradient coil with high slew rate is required.In consideration...Gradient coil is an essential component of a magnetic resonance imaging(MRI)scanner.To achieve high spatial resolution and imaging speed,a high-efficiency gradient coil with high slew rate is required.In consideration of the safety and comfort of the patient,the mechanical stability,acoustic noise and peripheral nerve stimulation(PNS)are also need to be concerned for practical use.In our previous work,a high-efficiency whole-body gradient coil set with a hybrid cylindrical-planar structure has been presented,which offers significantly improved coil performances.In this work,we propose to design this transverse gradient coil system with transformed magnetic gradient fields.By shifting up the zero point of gradient fields,the designed new Y-gradient coil could provide enhanced electromagnetic performances.With more uniform coil winding arrangement,the net torque of the new coil is significantly reduced and the generated sound pressure level(SPL)is lower at most tested frequency bands.On the other hand,the new transverse gradient coil designed with rotated magnetic gradient fields produces considerably reduced electric field in the human body,which is important for the use of rapid MR sequences.It's demonstrated that a safer and patient-friendly design could be obtained by using transformed magnetic gradient fields,which is critical for practical use.展开更多
The changes in strain gradient induced by grain boundaries are crucial for enhancing the plasticity of gradient magnesium(Mg)alloys.The change of strain distribution influence by grain boundaries during plastic deform...The changes in strain gradient induced by grain boundaries are crucial for enhancing the plasticity of gradient magnesium(Mg)alloys.The change of strain distribution influence by grain boundaries during plastic deformation of the gradient structure was examined.In this paper,the gradient structure AZ31 Mg-alloy plate with the surface fine grain(FG)to the center coarse grain(CG)was fabricated using hard plate rolling(HPR).The microstructure and strain distribution of Mg-alloy with a gradient structure were analyzed by electron backscatter diffraction(EBSD)and Digital image correlation(DIC)during uniaxial tensile.The findings indicate that the gradient structure sample(GS sample)displays a uniform strain distribution during the tensile process.Coarse-grain sample(CG sample)have obvious strain concentration,which leads to premature fracture.Based on EBSD characterization,low-angle grain boundaries(LAGBs)accumulates in the CG during plastic deformation.Orientation of CG tends to the(0001)basal.At the same time,the density of geometrically necessary dislocations(GNDs)inside CG has changed,which improves the Heterogeneous deformation induced(HDI)stress of gradient structure.During the uniaxial tensile,LAGBs accumulates in CG and changes the strain distribution of the gradient structure,which induces the accumulation of GNDs,and hence improving the properties of the GS Mg-alloy.These findings unveil the mechanism of strength-plasticity synergism of GS alloys from a new perspective and offer insights into the application of GS in Mg-alloys.展开更多
In this paper,we propose a three-term conjugate gradient method for solving unconstrained optimization problems based on the Hestenes-Stiefel(HS)conjugate gradient method and Polak-Ribiere-Polyak(PRP)conjugate gradien...In this paper,we propose a three-term conjugate gradient method for solving unconstrained optimization problems based on the Hestenes-Stiefel(HS)conjugate gradient method and Polak-Ribiere-Polyak(PRP)conjugate gradient method.Under the condition of standard Wolfe line search,the proposed search direction is the descent direction.For general nonlinear functions,the method is globally convergent.Finally,numerical results show that the proposed method is efficient.展开更多
The morphological distribution of absorbent in composites is equally important with absorbents for the overall electromagnetic properties,but it is often ignored.Herein,a comprehensive consideration including electrom...The morphological distribution of absorbent in composites is equally important with absorbents for the overall electromagnetic properties,but it is often ignored.Herein,a comprehensive consideration including electromagnetic component regulation,layered arrangement structure,and gradient concentration distribution was used to optimize impedance matching and enhance electromagnetic loss.On the microscale,the incorporation of magnetic Ni nanoparticles into MXene nanosheets(Ni@MXene)endows suitable intrinsic permittivity and permeability.On the macroscale,the layered arrangement of Ni@MXene increases the effective interaction area with electromagnetic waves,inducing multiple reflection/scattering effects.On this basis,according to the analysis of absorption,reflection,and transmission(A-R-T)power coefficients of layered composites,the gradient concentration distribution was constructed to realize the impedance matching at low-concentration surface layer,electromagnetic loss at middle concentration interlayer and microwave reflection at high-concentration bottom layer.Consequently,the layered gradient composite(LG5-10-15)achieves complete absorption coverage of X-band at thickness of 2.00-2.20 mm with RL_(min) of-68.67 dB at 9.85 GHz in 2.05 mm,which is 199.0%,12.6%,and 50.6%higher than non-layered,layered and layered descending gradient composites,respectively.Therefore,this work confirms the importance of layered gradient structure in improving absorption performance and broadens the design of high-performance microwave absorption materials.展开更多
A terrain-following coordinate （a-coordinate） in which the computational form of pressure gradient force （PGF） is two-term （the so-called classic method） has significant PGF errors near steep terrain. Using the ...A terrain-following coordinate （a-coordinate） in which the computational form of pressure gradient force （PGF） is two-term （the so-called classic method） has significant PGF errors near steep terrain. Using the covariant equations of the a-coordinate to create a one-term PGF （the covariant method） can reduce the PGF errors. This study investigates the factors inducing the PGF errors of these two methods, through geometric analysis and idealized experiments. The geometric analysis first demonstrates that the terrain slope and the vertical pressure gradient can induce the PGF errors of the classic method, and then generalize the effect of the terrain slope to the effect of the slope of each vertical layer （φ）. More importantly, a new factor, the direction of PGF （a）, is proposed by the geometric analysis, and the effects of φ and a are quantified by tan φ.tan a. When tan φ.tan a is greater than 1/9 or smaller than -10/9, the two terms of PGF of the classic method are of the same order but opposite in sign, and then the PGF errors of the classic method are large. Finally, the effects of three factors on inducing the PGF errors of the classic method are validated by a series of idealized experiments using various terrain types and pressure fields. The experimental results also demonstrate that the PGF errors of the covariant method are affected little by the three factors.展开更多
The cobalt-free Mn-based Li-rich layered oxide material has the advantages of low cost,high energy density,and good performance at low temperatures,and is the promising choice for energy storage batteries.However,the ...The cobalt-free Mn-based Li-rich layered oxide material has the advantages of low cost,high energy density,and good performance at low temperatures,and is the promising choice for energy storage batteries.However,the long-cycling stability of batteries needs to be improved.Herein,the Mn-based Li-rich cathode materials with small amounts of Li2 MnO3 crystal domains and gradient doping of Al and Ti elements from the surface to the bulk have been developed to improve the structure and interface stability.Then the batteries with a high energy density of 600 Wh kg^(-1),excellent capacity retention of 99.7%with low voltage decay of 0.03 mV cycle^(-1) after 800 cycles,and good rates performances can be achieved.Therefore,the structure and cycling stability of low voltage Mn-based Li-rich cathode materials can be significantly improved by the bulk structure design and interface regulation,and this work has paved the way for developing low-cost and high-energy Mn-based energy storage batteries with long lifetime.展开更多
Soil microbial communities are key factors in maintaining ecosystem multifunctionality(EMF).However,the distribution patterns of bacterial diversity and how the different bacterial taxa and their diversity dimensions ...Soil microbial communities are key factors in maintaining ecosystem multifunctionality(EMF).However,the distribution patterns of bacterial diversity and how the different bacterial taxa and their diversity dimensions affect EMF remain largely unknown.Here,we investigated variation in three measures of diversity(alpha diversity,community composition and network complexity)among rare,intermediate,and abundant taxa across a latitudinal gradient spanning five forest plots in Yunnan Province,China and examined their contributions on EMF.We aimed to characterize the diversity distributions of bacterial groups across latitudes and to assess the differences in the mechanisms underlying their contributions to EMF.We found that multifaceted diversity(i.e.,diversity assessed by the three different metrics)of rare,intermediate,and abundant bacteria generally decreased with increasing latitude.More importantly,we found that rare bacterial taxa tended to be more diverse,but they contributed less to EMF than intermediate or abundant bacteria.Among the three dimensions of diversity we assessed,only community composition significantly affected EMF across all locations,while alpha diversity had a negative effect,and network complexity showed no significant impact.Our study further emphasizes the importance of intermediate and abundant bacterial taxa as well as community composition to EMF and provides a theoretical basis for investigating the mechanisms by which belowground microorganisms drive EMF along a latitudinal gradient.展开更多
This study addresses the challenge of real-time resistivity gradient measurement in the Czochralski(CZ)silicon production process.Due to the inability to directly measure this parameter,we propose a Long Short-Term Me...This study addresses the challenge of real-time resistivity gradient measurement in the Czochralski(CZ)silicon production process.Due to the inability to directly measure this parameter,we propose a Long Short-Term Memory soft-sensing model based on Convolutional Neural Network(CNN)and attention mechanism(CNN-ALSTM)that enhances traditional LSTM by integrating CNN and attention mechanism to overcome time lag variations during silicon pulling.The CNN module extracts spatial features from multi-source sensor data,while the attention-enhanced LSTM(ALSTM)dynamically adjusts historical parameter weights,enabling accurate resistivity gradient prediction.Experiments with real production data show that CNN-ALSTM outperforms SVR,FNN,RNN,XGBoost,and GRU,improving prediction accuracy by 11.76%,16.67%,21.05%,30.23%,and 9.09%,respectively.This soft-sensing approach enhances real-time monitoring and optimization of monocrystalline silicon growth.展开更多
We combine gradient data from the Macao Science Satellite-1(MSS-1),CHAllenging Minisatellite Payload(CHAMP),Swarm-A,and Swarm-C satellites to develop a 110-degree lithospheric magnetic field model.We then comprehensiv...We combine gradient data from the Macao Science Satellite-1(MSS-1),CHAllenging Minisatellite Payload(CHAMP),Swarm-A,and Swarm-C satellites to develop a 110-degree lithospheric magnetic field model.We then comprehensively evaluate the performance of the model by power spectral comparisons,correlation analyses,sensitivity matrix assessments,and comparisons with existing lithospheric field models.Results showed that using near east–west gradient data from MSS-1 significantly enhances the model correlation in the spherical harmonic degree(N) range of 45–60 while also mitigating the decline in correlation at higher degrees(N > 60).Furthermore,the unique orbital characteristics of MSS-1 enable its gradient data to provide substantial contributions to modeling in the mid-to low-latitude regions.With continued data acquisition from MSS-1 and further optimization of data processing methods,the performance of the model is expected to improve.展开更多
Rolling contact fatigue performance is among the most important issues for applications of bearing steels.In this work,a recently developed surface modification technique,surface mechanical rolling treatment,was appli...Rolling contact fatigue performance is among the most important issues for applications of bearing steels.In this work,a recently developed surface modification technique,surface mechanical rolling treatment,was applied on a rare-earth addition bearing steel.And rolling contact fatigue behavior of treated samples was compared with that of as-received counterparts at different contacting stresses.The results demonstrated that a 700μm-thick gradient nanostructured surface layer is produced on samples by surface mechanical rolling treatment.The grain size decreases while the microhardness increases gradually with decreasing depth,reaching~23 nm and~10.2 GPa,respectively,at the top surface.Consequently,the rolling contact fatigue property is significantly enhanced.The characteristic life of treated samples is~3.2 times that of untreated counterparts according to Weibull curves at 5.6 GPa.Analyses of fatigue mechanisms demonstrated that the gradient nanostructured surface layer might not only retard material degradation and microcrack formation,but also prolong the steady-state elastic response stage under rolling contact fatigue.展开更多
基金supported by the National Natural Science Foundation of China (Grant Nos.12274313 and 62375234)the Gusu Leading Talent Plan for Scientific and Technological Innovation and Entrepreneurship (Grant No.ZXL2024400)。
文摘Optical phase-gradient metasurfaces have garnered significant attention for enabling flexible light manipulation,with applications across diverse domains.In this work,we will demonstrate that the metasurfaces with phase gradient modulation can be used to achieve illusion optics,featuring the advantages of simple geometric structure and feasible implementation compared with the well-known transformation optics method.The underlying mechanism is the anomalous diffraction law caused by the phase gradient,which provides a theoretical basis for freely manipulating the propagation path of light.By considering a specific example,we will demonstrate that the phase gradient can transform spatial coordinates in real space into illusion space,thereby converting a plane in real space into a curved surface structure in illusion space to achieve the illusion effect.This approach provides a viable alternative to transformation optics for designing illusion devices.
基金supported by Natural Science Foundation of Xiamen,China(No.3502Z20227232)the STS Project of Fujian-CAS(No.2023T3018)Bureau of International Cooperation,Chinese Academy of Sciences(No.322GJHZ2022035MI).
文摘Anammox bacteria in constructed wetlands(CWs)play pivotal role in sustainable nitrogen transformation,yet existing studies lack comprehensive analysis of environmental gradients and microbial interactions,both key factors in anammox bacteria enrichment.This study investigated the mechanisms driving anammox bacteria enrichment in lab-scale simulated CWs treating high-nitrogen wastewater,focusing on bacterial community re-sponses across wetland layers with various strategies,including continuous up-flow influent,nitrogen loading increase,effluent recirculation,intermittent influent,and anammox bacteria inoculation.Results showed that total relative and absolute abundances of anammox bacteria ranged from 0.77%to 12.50%and from 0.13 to 6.46×10^(7) copies/g,respectively.Dissolved oxygen and pH had significant positive correlations with the absolute abundance of anammox bacteria,while organic matter and nitrate negatively impacted their relative abundance.Permutational multivariate analysis of variance indicated that spatial heterogeneity explained more variation in anammox bacteria abundance(43.44%)compared to operational strategies(8.58%).In terms of microbial interactions,60 dominant species exhibited potential correlations with anammox bacteria,comprising 170 interactions(105 positive and 65 negative),which suggested that anammox bacteria generally foster cooperative relationships with dominant bacteria.Notably,significant interspecies interactions were observed between Candidatus Kuenenia(dominant anammox bacteria in CWs)and species within the genera Chitinivibrio-nia and Anaerolineaceae,suggesting that microbial interactions primarily manifest as indirect facilitative effects rather than direct mutualistic relationships.Given that the Normalized Stochasticity Ratio in CWs were<50%,this study inferred that environmental gradients have greater influence on anammox bacteria than microbial interactions.
基金financial support from the National Natural Science Foundation of China(Grant No.52273067,52233006)the Fundamental Research Funds for the Central Universities(Grant No.2232023A-03)+3 种基金the Shuguang Program of Shanghai Education Development Foundation and Shanghai Municipal Education Commission(Grant No.23SG29)the Natural Science Foundation of Shanghai(Grant No.24ZR1402400)the Shanghai Scientific and Technological Innovation Project(Grant No.24520713000)Innovation Program of Shanghai Municipal Education Commission(Grant No.2021-01-07-00-03-E00108).
文摘Radiative cooling textiles with spectrally selective surfaces offer a promising energy-efficient approach for sub-ambient cooling of outdoor objects and individuals.However,the spectrally selective mid-infrared emission of these textiles significantly hinders their efficient radiative heat exchange with self-heated objects,thereby posing a significant challenge to their versatile cooling applicability.Herein,we present a bicomponent blow spinning strategy for the production of scalable,ultra-flexible,and healable textiles featuring a tailored dual gradient in both chemical composition and fiber diameter.The gradient in the fiber diameter of this textile introduces a hierarchically porous structure across the sunlight incident area,thereby achieving a competitive solar reflectivity of 98.7%on its outer surface.Additionally,the gradient in the chemical composition of this textile contributes to the formation of Janus infrared-absorbing surfaces:The outer surface demonstrates a high mid-infrared emission,whereas the inner surface shows a broad infrared absorptivity,facilitating radiative heat exchange with underlying self-heated objects.Consequently,this textile demonstrates multi-scenario radiative cooling capabilities,enabling versatile outdoor cooling for unheated objects by 7.8℃ and self-heated objects by 13.6℃,compared to commercial sunshade fabrics.
基金supported by the National Natural Science Foundation of China(Grant Nos.12372069,12172123,and 12072109)the Natural Science Foundation of Hunan Province(Grant No.2022JJ20001)the Hunan Provincial Innovation Foundation for Postgraduate(Grant No.CX20220378).
文摘Gradient structures(GS)play a crucial role in achieving a balance between strength and plasticity in metals and alloys.However,there is still a lack of understanding of the mechanisms that maintain a plasticity gradient to prevent the premature failure of fine grains in GS materials.In this work,by incorporating experimental data and the Hall-Petch relationship,we develop a size-dependent crystal plasticity model to investigate the deformation mechanisms for enhancing the strength and plasticity in polycrystalline high entropy alloys.The simulations of the GS model align well with the experimental results,exhibiting strong strain and stress gradients to improve the mechanical properties.Under the conditions of significant de-formation incompatibility,the strain gradient predominantly drives the enhancement of plasticity mechanisms.As the de-formation incompatibility decreases,the stress gradient begins to play a significant role in comparison with the strain gradient.This shift is attributed to the regular variations in dislocation density within different domains.As the grain size gradients and loads decrease,the dislocation density becomes more uniform across the domains,hindering the formation of strong domain boundaries.While this may impede the activation of strain gradients,it facilitates the activation of stress gradients as a supplementary measure.By designing multilayered GS structures to alter the distribution of dislocation density,we can control the activation levels of stress and strain gradients,thereby influencing the plasticity mechanisms and mechanical properties of the material.
基金supported by the National Natural Science Foundation of China(Grant Nos.12274313,62275184,and 62411540033)Collaborative Innovation Center of Suzhou Nano Science and Technology,Suzhou Basic Research Project(Grant No.SJC2023003)+1 种基金the Gusu Leading Talent Plan for Scientific and Technological Innovation and Entrepreneurship(Grant No.ZXL2024400)the Priority Academic Program Development of Jiangsu Higher Education Institutions.
文摘Perfect anomalous reflections have been demonstrated in optical phase gradient metasurfaces(PGMs),but they suffer from single-frequency(narrow-band)response due to the intrinsic limitation of natural geometric periodicity.Here,we provide both numerical and analytical evidence that a depth gradient metasurface can achieve discrete ultra-broadband perfect anomalous reflection in the microwave range in the absence of geometric periodicity.Remarkably,by adjusting the operating frequency of the incident wave,the same effect can be steadily obtained via a physically equivalent phase periodicity in the PGM.Based on this mechanism,a perfect retroreflector with a broadband response ranging from 1 GHz to 40 GHz is realized.Our work has promising applications in communication,source tracking,and military satellites.
文摘Species richness in any area results from the interplay of the processes of speciation,extinction,and dispersal.The relationships between species richness and climate should be considered as an outcome of the effects of climate on speciation,extinction,and dispersal.Diversificationrate represents the balance of speciation and extinction rates over time.Here,I explore diversificationrates in mosses across geographic and climatic gradients worldwide.Specifically,I investigate latitudinal patterns and climatic associations of the mean diversificationrate of mosses at global,hemispheric,and smaller scales.I findthat the mean diversificationrate of mosses is positively correlated with species richness of mosses,increases with decreasing latitude and increasing mean annual temperature and annual precipitation,and is more strongly associated with mean annual temperature than with annual precipitation.These findingsshed light on variation of species richness in mosses across the world.The negative relationship between species richness and latitude and the positive relationship between species richness and mean diversificationrate in mosses suggest that higher moss species richness at lower latitudes might have resulted,at least to some degree,from higher moss diversificationrates at lower latitudes.
文摘Liver-directed therapies such as resection,ablation,and embolization offer potentially curative options for patients with primary and metastatic liver tumors as part of multidisciplinary oncology care.However,these treatments pose significant hepatic decompensation risks,particularly with underlying liver disease and chemotherapy-associated steatohepatitis.Accurate assessment of liver function and portal hypertension(PH)is critical for candidate selection.While Child-Pugh score and model for end-stage liver disease are commonly used,they have substantial limitations.Hepatic venous pressure gradient(HVPG)measurement remains the gold standard for assessing PH but is invasive and not widely available.Endoscopic ultrasound(EUS)guided portal pressure gradient(PPG)measurement has emerged as a promising minimally invasive alternative.EUSPPG demonstrates excellent technical success rates,safety profile,and correlation with HVPG in early studies.By providing direct portal pressure measurement,EUS-PPG offers several advantages over existing methods for prognostication and risk stratification prior to liver-directed therapies,particularly in detecting presinusoidal hypertension.Furthermore,it has potential applications in assessing response to neoadjuvant treatments and guiding adjuvant therapies.However,research is needed to validate its predictive performance and cost-effectiveness in larger prospective cohorts and to establish its accuracy compared to non-invasive assessment of liver function.
基金supported by Shandong Provincial Natural Science Foundation of China(Nos.ZR2024JQ020 and ZR2021QE102)the Taishan Scholars Program of Shandong Province,China(Nos.tsqn202211115,tsqn201909081,and tsqn202306162)+2 种基金the National Natural Science Foundation of China(No.52274397)Yantai high-end talent introduction“Double Hundred Plan”,China(2021)the Graduate Innovation Foundation of Yantai University,China(No.KGIFYTU2520).
文摘The GH141 superalloy ring-rolled parts often face microstructural inhomogeneity during production.This work investigated the effect of post-dynamic recrystallization on the microstructural evolution of GH141 superalloy after gradient thermal deformation to solve the problem of microstructural inhomogeneity.Compression tests involving double cone(DC)samples were conducted at various temperatures to assess the effect of gradient strain on internal grain microstructure variation,which ranged from the rim to the center of the samples.The results demonstrate considerable microstructural inhomogeneity induced by gradient strain in the DC samples.The delay in heat preservation facilitated post-dynamic recrystallization(PDRX)and promoted extensive recrystallization in the DC samples experiencing large gradient strain,which resulted in a homogeneous grain microstructure throughout the samples.During compression at a relatively low temperature,dynamic recrystallization(DRX)was predominantly driven by continuous dynamic recrystallization(CDRX).As the deformation temperature increased,the DRX mechanism changed from CDRX-dominated to being dominated by discontinuous dynamic recrystallization(DDRX).During the delay of the heat preservation process,PDRX was dominated by a static recrystallization mechanism,along with the occurrence of meta-dynamic recrystallization(MDRX)mechanisms.In addition,the PDRX mechanism of twin-induced recrystallization nucleation was observed.
基金Key Research and Development Program of Zhejiang Province,Grant/Award Number:2021C04019National Natural Science Foundation of China,Grant/Award Number:U20A20338Natural Science Foundation of Zhejiang Province,Grant/Award Number:LQ21H180012.
文摘A widely employed energy technology,known as reverse electrodialysis(RED),holds the promise of delivering clean and renewable electricity from water.This technology involves the interaction of two or more bodies of water with varying concentrations of salt ions.The movement of these ions across a membrane generates electricity.However,the efficiency of these systems faces a challenge due to membrane performance degradation over time,often caused by channel blockages.One potential solution to enhance system efficiency is the use of nanofluidic membranes.These specialized membranes offer high ion exchange capacity,abundant ion sources,and customizable channels with varying sizes and properties.Graphene oxide(GO)-based membranes have emerged as particularly promising candidates in this regard,garnering significant attention in recent literature.This work provides a comprehensive overview of the literature surrounding GO membranes and their applications in RED systems.It also highlights recent advancements in the utilization of GO membranes within these systems.Finally,it explores the potential of these membranes to play a pivotal role in electricity generation within RED systems.
基金financial supports of National Natural Science Foundation of China(22171226)Natural Science Basic Research Program of Shaanxi(2022JC-06).
文摘According to the second law of thermodynamics,spontaneous chemical processes will ultimately reach the equilibrium state with the lowest energy.However,in biological systems,there are numerous highenergy states far from equilibrium.One typical example is the transmembrane ion-concentration gradient,which plays crucial roles in maintaining homeostasis,regulating cell volume,and enabling cell signaling.Transmembrane ion-concentration gradient is achieved by an active transport process that requires the input of energy and the action of pump proteins.Replicating this process with synthetic supramolecular systems is particularly challenging,requiring both the input of energy and very specific,spatiotemporal control over ion uptake and release.In nature,pump proteins,such as protein-based ion channels,have evolved highly intricate architectures to perform this function.In contrast,Aprahamian and coworkers recently developed a much simpler smallmolecule system that functions as a molecular ion pump,utilizing light energy to pump chloride ions across a hydrophobic barrier against the concentration gradient[1].
基金supported by the Instrument Developing Project of Magnetic Resonance Union of Chinese Academy of Sciences,Grant No.2022GZL002.
文摘Gradient coil is an essential component of a magnetic resonance imaging(MRI)scanner.To achieve high spatial resolution and imaging speed,a high-efficiency gradient coil with high slew rate is required.In consideration of the safety and comfort of the patient,the mechanical stability,acoustic noise and peripheral nerve stimulation(PNS)are also need to be concerned for practical use.In our previous work,a high-efficiency whole-body gradient coil set with a hybrid cylindrical-planar structure has been presented,which offers significantly improved coil performances.In this work,we propose to design this transverse gradient coil system with transformed magnetic gradient fields.By shifting up the zero point of gradient fields,the designed new Y-gradient coil could provide enhanced electromagnetic performances.With more uniform coil winding arrangement,the net torque of the new coil is significantly reduced and the generated sound pressure level(SPL)is lower at most tested frequency bands.On the other hand,the new transverse gradient coil designed with rotated magnetic gradient fields produces considerably reduced electric field in the human body,which is important for the use of rapid MR sequences.It's demonstrated that a safer and patient-friendly design could be obtained by using transformed magnetic gradient fields,which is critical for practical use.
基金supported by the Natural Science Foundation of Heilongjiang Province(JQ2022E004)。
文摘The changes in strain gradient induced by grain boundaries are crucial for enhancing the plasticity of gradient magnesium(Mg)alloys.The change of strain distribution influence by grain boundaries during plastic deformation of the gradient structure was examined.In this paper,the gradient structure AZ31 Mg-alloy plate with the surface fine grain(FG)to the center coarse grain(CG)was fabricated using hard plate rolling(HPR).The microstructure and strain distribution of Mg-alloy with a gradient structure were analyzed by electron backscatter diffraction(EBSD)and Digital image correlation(DIC)during uniaxial tensile.The findings indicate that the gradient structure sample(GS sample)displays a uniform strain distribution during the tensile process.Coarse-grain sample(CG sample)have obvious strain concentration,which leads to premature fracture.Based on EBSD characterization,low-angle grain boundaries(LAGBs)accumulates in the CG during plastic deformation.Orientation of CG tends to the(0001)basal.At the same time,the density of geometrically necessary dislocations(GNDs)inside CG has changed,which improves the Heterogeneous deformation induced(HDI)stress of gradient structure.During the uniaxial tensile,LAGBs accumulates in CG and changes the strain distribution of the gradient structure,which induces the accumulation of GNDs,and hence improving the properties of the GS Mg-alloy.These findings unveil the mechanism of strength-plasticity synergism of GS alloys from a new perspective and offer insights into the application of GS in Mg-alloys.
基金Supported by the Science and Technology Project of Guangxi(Guike AD23023002)。
文摘In this paper,we propose a three-term conjugate gradient method for solving unconstrained optimization problems based on the Hestenes-Stiefel(HS)conjugate gradient method and Polak-Ribiere-Polyak(PRP)conjugate gradient method.Under the condition of standard Wolfe line search,the proposed search direction is the descent direction.For general nonlinear functions,the method is globally convergent.Finally,numerical results show that the proposed method is efficient.
基金support for this work by Key Research and Development Project of Henan Province(Grant.No.241111232300)the National Natural Science Foundation of China(Grant.No.52273085 and 52303113)the Open Fund of Yaoshan Laboratory(Grant.No.2024003).
文摘The morphological distribution of absorbent in composites is equally important with absorbents for the overall electromagnetic properties,but it is often ignored.Herein,a comprehensive consideration including electromagnetic component regulation,layered arrangement structure,and gradient concentration distribution was used to optimize impedance matching and enhance electromagnetic loss.On the microscale,the incorporation of magnetic Ni nanoparticles into MXene nanosheets(Ni@MXene)endows suitable intrinsic permittivity and permeability.On the macroscale,the layered arrangement of Ni@MXene increases the effective interaction area with electromagnetic waves,inducing multiple reflection/scattering effects.On this basis,according to the analysis of absorption,reflection,and transmission(A-R-T)power coefficients of layered composites,the gradient concentration distribution was constructed to realize the impedance matching at low-concentration surface layer,electromagnetic loss at middle concentration interlayer and microwave reflection at high-concentration bottom layer.Consequently,the layered gradient composite(LG5-10-15)achieves complete absorption coverage of X-band at thickness of 2.00-2.20 mm with RL_(min) of-68.67 dB at 9.85 GHz in 2.05 mm,which is 199.0%,12.6%,and 50.6%higher than non-layered,layered and layered descending gradient composites,respectively.Therefore,this work confirms the importance of layered gradient structure in improving absorption performance and broadens the design of high-performance microwave absorption materials.
基金jointly supported by the National Basic Research Program of China[973 Program,grant number 2015CB954102]National Natural Science Foundation of China[grant numbers41305095 and 41175064]
文摘A terrain-following coordinate （a-coordinate） in which the computational form of pressure gradient force （PGF） is two-term （the so-called classic method） has significant PGF errors near steep terrain. Using the covariant equations of the a-coordinate to create a one-term PGF （the covariant method） can reduce the PGF errors. This study investigates the factors inducing the PGF errors of these two methods, through geometric analysis and idealized experiments. The geometric analysis first demonstrates that the terrain slope and the vertical pressure gradient can induce the PGF errors of the classic method, and then generalize the effect of the terrain slope to the effect of the slope of each vertical layer （φ）. More importantly, a new factor, the direction of PGF （a）, is proposed by the geometric analysis, and the effects of φ and a are quantified by tan φ.tan a. When tan φ.tan a is greater than 1/9 or smaller than -10/9, the two terms of PGF of the classic method are of the same order but opposite in sign, and then the PGF errors of the classic method are large. Finally, the effects of three factors on inducing the PGF errors of the classic method are validated by a series of idealized experiments using various terrain types and pressure fields. The experimental results also demonstrate that the PGF errors of the covariant method are affected little by the three factors.
基金supported by the National Key R&D Program of China(No.2022YFB2404400)the National Natural Science Foundation of China(Nos.U23A20577,52372168,92263206 and 21975006)+1 种基金the“The Youth Beijing Scholars program”(No.PXM2021_014204_000023)the Beijing Natural Science Foundation(Nos.2222001 and KM202110005009).
文摘The cobalt-free Mn-based Li-rich layered oxide material has the advantages of low cost,high energy density,and good performance at low temperatures,and is the promising choice for energy storage batteries.However,the long-cycling stability of batteries needs to be improved.Herein,the Mn-based Li-rich cathode materials with small amounts of Li2 MnO3 crystal domains and gradient doping of Al and Ti elements from the surface to the bulk have been developed to improve the structure and interface stability.Then the batteries with a high energy density of 600 Wh kg^(-1),excellent capacity retention of 99.7%with low voltage decay of 0.03 mV cycle^(-1) after 800 cycles,and good rates performances can be achieved.Therefore,the structure and cycling stability of low voltage Mn-based Li-rich cathode materials can be significantly improved by the bulk structure design and interface regulation,and this work has paved the way for developing low-cost and high-energy Mn-based energy storage batteries with long lifetime.
基金supported by the Fundamental Research Funds of Chinese Academy of Forestry(Nos.CAFYBB2022SY037,CAFYBB2021ZA002 and CAFYBB2022QC002)the Basic Research Foundation of Yunnan Province(Grant No.202201AT070264).
文摘Soil microbial communities are key factors in maintaining ecosystem multifunctionality(EMF).However,the distribution patterns of bacterial diversity and how the different bacterial taxa and their diversity dimensions affect EMF remain largely unknown.Here,we investigated variation in three measures of diversity(alpha diversity,community composition and network complexity)among rare,intermediate,and abundant taxa across a latitudinal gradient spanning five forest plots in Yunnan Province,China and examined their contributions on EMF.We aimed to characterize the diversity distributions of bacterial groups across latitudes and to assess the differences in the mechanisms underlying their contributions to EMF.We found that multifaceted diversity(i.e.,diversity assessed by the three different metrics)of rare,intermediate,and abundant bacteria generally decreased with increasing latitude.More importantly,we found that rare bacterial taxa tended to be more diverse,but they contributed less to EMF than intermediate or abundant bacteria.Among the three dimensions of diversity we assessed,only community composition significantly affected EMF across all locations,while alpha diversity had a negative effect,and network complexity showed no significant impact.Our study further emphasizes the importance of intermediate and abundant bacterial taxa as well as community composition to EMF and provides a theoretical basis for investigating the mechanisms by which belowground microorganisms drive EMF along a latitudinal gradient.
文摘This study addresses the challenge of real-time resistivity gradient measurement in the Czochralski(CZ)silicon production process.Due to the inability to directly measure this parameter,we propose a Long Short-Term Memory soft-sensing model based on Convolutional Neural Network(CNN)and attention mechanism(CNN-ALSTM)that enhances traditional LSTM by integrating CNN and attention mechanism to overcome time lag variations during silicon pulling.The CNN module extracts spatial features from multi-source sensor data,while the attention-enhanced LSTM(ALSTM)dynamically adjusts historical parameter weights,enabling accurate resistivity gradient prediction.Experiments with real production data show that CNN-ALSTM outperforms SVR,FNN,RNN,XGBoost,and GRU,improving prediction accuracy by 11.76%,16.67%,21.05%,30.23%,and 9.09%,respectively.This soft-sensing approach enhances real-time monitoring and optimization of monocrystalline silicon growth.
基金the support of the National Natural Science Foundation of China (Nos. 42250103, 41974073, and 41404053)the Macao Foundation and the preresearch project of Civil Aerospace Technologies (Nos. D020308 and D020303)funded by China’s National Space Administration, the Specialized Research Fund for State Key Laboratories。
文摘We combine gradient data from the Macao Science Satellite-1(MSS-1),CHAllenging Minisatellite Payload(CHAMP),Swarm-A,and Swarm-C satellites to develop a 110-degree lithospheric magnetic field model.We then comprehensively evaluate the performance of the model by power spectral comparisons,correlation analyses,sensitivity matrix assessments,and comparisons with existing lithospheric field models.Results showed that using near east–west gradient data from MSS-1 significantly enhances the model correlation in the spherical harmonic degree(N) range of 45–60 while also mitigating the decline in correlation at higher degrees(N > 60).Furthermore,the unique orbital characteristics of MSS-1 enable its gradient data to provide substantial contributions to modeling in the mid-to low-latitude regions.With continued data acquisition from MSS-1 and further optimization of data processing methods,the performance of the model is expected to improve.
基金The financial supports by the Chinese Academy of Sciences(Nos.XDC04030300 and XDB0510303)CAS-HK Joint Laboratory of Nanomaterials and MechanicsShenyang National Laboratory for Materials Science are acknowledged.
文摘Rolling contact fatigue performance is among the most important issues for applications of bearing steels.In this work,a recently developed surface modification technique,surface mechanical rolling treatment,was applied on a rare-earth addition bearing steel.And rolling contact fatigue behavior of treated samples was compared with that of as-received counterparts at different contacting stresses.The results demonstrated that a 700μm-thick gradient nanostructured surface layer is produced on samples by surface mechanical rolling treatment.The grain size decreases while the microhardness increases gradually with decreasing depth,reaching~23 nm and~10.2 GPa,respectively,at the top surface.Consequently,the rolling contact fatigue property is significantly enhanced.The characteristic life of treated samples is~3.2 times that of untreated counterparts according to Weibull curves at 5.6 GPa.Analyses of fatigue mechanisms demonstrated that the gradient nanostructured surface layer might not only retard material degradation and microcrack formation,but also prolong the steady-state elastic response stage under rolling contact fatigue.
