An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method（HPCD）, is stud...An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method（HPCD）, is studied by an inductively coupled plasma optical emission spectrometry（ICP-OES） and an inductively coupled plasma mass spectrometry（ICP-MS）. The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error（RE） for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials（GBW07309, GBW07311, GBW07313）, rock reference materials（GBW07103, GBW07104,GBW07105）, and cobalt-rich crust reference materials（GBW07337, GBW07338, GBW07339）, the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation（RSD） and the relative error（RE） are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples.展开更多
Owing to the fact that the coal-beds are with the characteristics of multi-beds, thin single-bed, rapid lateral changes and deep burial, coal-bearing source rocks are difficult to be identified and predicted, especial...Owing to the fact that the coal-beds are with the characteristics of multi-beds, thin single-bed, rapid lateral changes and deep burial, coal-bearing source rocks are difficult to be identified and predicted, especially in the lower exploration deepwater area. In this paper, a new integrative process utilizing geology and geophysics is proposed for better predicting the distribution of coal-bearing source rocks. Coal-beds were identified by the logging responses of“three higher, three lower, and one expand”and carbargilite were recognized by the characteristics of“four higher and one lower”. Based on the above logical decision, coal-beds and carbargilite can be distinguished automatically by cluster analysis of logging curves in verticality. Within the constraints of well-seismic calibration, the coal-beds group also can be detected in horizontality by the integrated representation of“negative phase, higher Q, lower impedance and lower frequency”within the seismic data. However, the distribution of coal-bearing source rocks utilizing geophysical methodology may do not conform to the geological rules of coal accumulation. And then the main geological controlling factors of coal accumulation are comprehensively analyzed as follows：（1） Paleotopography and tectonic subsidence determine the planar range of terrestrial-marine transitional facies markedly;（2） The relative sea level changes affect the accommodation space and shoreline migration, and limit the vertical range of coal-beds. More specifically, the relationship between the accommodation creation rate and the peat accumulation rate is a fundamental control on coal accumulation. The thickest and most widespread coals form where those two factors reached a state of balance;（3） The supply of autochthonous clasts and the distance between deposition places and paleovegetation accumulated area are the critical factor to form abundant coal, which means that if deposition area is close to paleouplift, there would be sufficient organic matters to form abundant source rocks. The results show that the integrated methods can significantly improve prediction accuracy of coal-bearing source rocks, which is suitable for early exploration of western deepwater area of South China Sea.展开更多
In this study, we analyzed the gravity and, magnetic characteristics, and the occurrence of a fault zone and discussed the relationships between the two locations. The results reveal that the subsurface structures str...In this study, we analyzed the gravity and, magnetic characteristics, and the occurrence of a fault zone and discussed the relationships between the two locations. The results reveal that the subsurface structures strikes are different compared with those in the research region. In other words, the geophysical advantageous directions from the gravity and magnetic anomalies are not the same as those caused by the surface structures. The local horizontal gradient results from the gravity and magnetic anomalies show that the majority of earthquakes occur along an intense fault zone, which is a zone of abrupt gravity and negative magnetic change, where the shapes match very well. From the distribution of earthquakes in this area, we find that it has experienced more than 11 earthquake events with magnitude larger than Ms7.0. In addition, water development sites such as Jinshajiang, Lancangjiang, and the Red River and Pearl River watersheds have been hit ten times by earthquakes of this magnitude. It is observed that strong earthquakes occur frequently in the Holocene active fault zone.展开更多
Based on the theory of geomechanics and using geologic analytical methods,analyed the fault characteristics, mechanical properties, displacement mode, tectonic system, structural pattern, activity mode of stress, tect...Based on the theory of geomechanics and using geologic analytical methods,analyed the fault characteristics, mechanical properties, displacement mode, tectonic system, structural pattern, activity mode of stress, tectonic activity, and tectonic evolution ofthe area of the Xiamen submarine tunnel, the strike NWW 295^(。), which is the main unfavorable geological structure that affects the safety of the tunnel construction; the macrogeological prediction concludes that weathered troughs and groundwater-rich zonesformed by its larger-scale fault fracture zones are the main unfavorable geological bodiesprovides a basis for preventing the geo-logical hazards in the tunnel construction.展开更多
We used existing high-resolution gravity and aeromagnetic data to map the crustal units underneath Botswana.The thick sedimentary cover in this region has always been a challenge to understand the geological and tecto...We used existing high-resolution gravity and aeromagnetic data to map the crustal units underneath Botswana.The thick sedimentary cover in this region has always been a challenge to understand the geological and tectonic configuration of unexposed crustal terranes using traditional geological methods.展开更多
Some case studies are presented ranging from geological fakes and frauds,homicides and one environmental forensic case.Fakes may be true geological materials such as created fossils or gems and precious stones,or wher...Some case studies are presented ranging from geological fakes and frauds,homicides and one environmental forensic case.Fakes may be true geological materials such as created fossils or gems and precious stones,or where geological methods are used to analyse fakes,such as the stones or ceramics used in making archaeological or art forgeries(e.g.,mineral pigments in paintings).Fakes have also been created for reasons of academic rivalry,career advancement and religious belief.Fraud commonly involves over-stated claims of ore content associated with mining and the oil and gas industry.The range of geological fakes,the uses of geological methods in detecting fakes,and the extent of fraud in the mining sector are all extensive and sometimes incredible.The homicide is case presented to demonstrate how the types of geological investigation described in the rest of this volume may be applied.We include an environmental forensic case for similar reasons,to show that forensic geology may be applied to more than homicides and fakery.展开更多
基金The China Ocean Mineral Resources Research and Development Association Research Program of the State Oceanic Administration of China under contract No.DY125-13-R-07the National Natural Science Foundation of China under contract Nos 41322036 and 41230960+1 种基金the Shandong Provincial Natural Science Foundation of China under contract No.ZR2014DP009the Special Basic Research Funds for Central Public Research Institutes for The First Institute of Oceanography,State Oceanic Administration of China under contract Nos GY0213G06 and GY02-2012G35
文摘An improved analytical method to determine the content of 52 major, minor and trace elements in marine geological samples, using a HF-HCl-HNO_3 acid system with a high-pressure closed digestion method（HPCD）, is studied by an inductively coupled plasma optical emission spectrometry（ICP-OES） and an inductively coupled plasma mass spectrometry（ICP-MS）. The operating parameters of the instruments are optimized, and the optimal analytical parameters are determined. The influences of optical spectrum and mass spectrum interferences, digestion methods and acid systems on the analytical results are investigated. The optimal spectral lines and isotopes are chosen, and internal standard element of rhodium is selected to compensate for matrix effects and analytical signals drifting. Compared with the methods of an electric heating plate digestion and a microwave digestion, a high-pressure closed digestion method is optimized with less acid, complete digestion,less damage for digestion process. The marine geological samples are dissolved completely by a HF-HCl-HNO_3 system, the relative error（RE） for the analytical results are all less than 6.0%. The method detection limits are 2–40μg/g by the ICP-OES, and 6–80 ng/g by ICP-MS. The methods are used to determine the marine sediment reference materials（GBW07309, GBW07311, GBW07313）, rock reference materials（GBW07103, GBW07104,GBW07105）, and cobalt-rich crust reference materials（GBW07337, GBW07338, GBW07339）, the obtained analytical results are in agreement with the certified values, and both of the relative standard deviation（RSD） and the relative error（RE） are less than 6.0%. The analytical method meets the requirements for determining 52 elements contents of bulk marine geological samples.
基金The Major National Science and Technology Programs in the "Twelfth Five-Year" Plan period under contract No.2011ZX05025-002-02-02the National Natural Science Foundation of China under contract Nos 41472084,41202074 and 41172123the foundation of Key Laboratory of Tectonics and Petroleum Resources (China University of Geosciences) of Ministry of Education under contract No.TPR-2013-13
文摘Owing to the fact that the coal-beds are with the characteristics of multi-beds, thin single-bed, rapid lateral changes and deep burial, coal-bearing source rocks are difficult to be identified and predicted, especially in the lower exploration deepwater area. In this paper, a new integrative process utilizing geology and geophysics is proposed for better predicting the distribution of coal-bearing source rocks. Coal-beds were identified by the logging responses of“three higher, three lower, and one expand”and carbargilite were recognized by the characteristics of“four higher and one lower”. Based on the above logical decision, coal-beds and carbargilite can be distinguished automatically by cluster analysis of logging curves in verticality. Within the constraints of well-seismic calibration, the coal-beds group also can be detected in horizontality by the integrated representation of“negative phase, higher Q, lower impedance and lower frequency”within the seismic data. However, the distribution of coal-bearing source rocks utilizing geophysical methodology may do not conform to the geological rules of coal accumulation. And then the main geological controlling factors of coal accumulation are comprehensively analyzed as follows：（1） Paleotopography and tectonic subsidence determine the planar range of terrestrial-marine transitional facies markedly;（2） The relative sea level changes affect the accommodation space and shoreline migration, and limit the vertical range of coal-beds. More specifically, the relationship between the accommodation creation rate and the peat accumulation rate is a fundamental control on coal accumulation. The thickest and most widespread coals form where those two factors reached a state of balance;（3） The supply of autochthonous clasts and the distance between deposition places and paleovegetation accumulated area are the critical factor to form abundant coal, which means that if deposition area is close to paleouplift, there would be sufficient organic matters to form abundant source rocks. The results show that the integrated methods can significantly improve prediction accuracy of coal-bearing source rocks, which is suitable for early exploration of western deepwater area of South China Sea.
基金supported by the Chinese Earthquake Administration,Institute of Seismology Foundation(IS201326126)Chinese earthquake scientific array exploration northern section of North South Seismic Belt gravity profile Foundation(201308011)
文摘In this study, we analyzed the gravity and, magnetic characteristics, and the occurrence of a fault zone and discussed the relationships between the two locations. The results reveal that the subsurface structures strikes are different compared with those in the research region. In other words, the geophysical advantageous directions from the gravity and magnetic anomalies are not the same as those caused by the surface structures. The local horizontal gradient results from the gravity and magnetic anomalies show that the majority of earthquakes occur along an intense fault zone, which is a zone of abrupt gravity and negative magnetic change, where the shapes match very well. From the distribution of earthquakes in this area, we find that it has experienced more than 11 earthquake events with magnitude larger than Ms7.0. In addition, water development sites such as Jinshajiang, Lancangjiang, and the Red River and Pearl River watersheds have been hit ten times by earthquakes of this magnitude. It is observed that strong earthquakes occur frequently in the Holocene active fault zone.
基金Supported by the National Natural Science Foundation of China(10702072)the Education Department of Hebei Province (Z2006428)Doctoral Foundation of Hebei Normal University of Science & Technology
文摘Based on the theory of geomechanics and using geologic analytical methods,analyed the fault characteristics, mechanical properties, displacement mode, tectonic system, structural pattern, activity mode of stress, tectonic activity, and tectonic evolution ofthe area of the Xiamen submarine tunnel, the strike NWW 295^(。), which is the main unfavorable geological structure that affects the safety of the tunnel construction; the macrogeological prediction concludes that weathered troughs and groundwater-rich zonesformed by its larger-scale fault fracture zones are the main unfavorable geological bodiesprovides a basis for preventing the geo-logical hazards in the tunnel construction.
基金supported by a grant provided by Netherlands Organization for Scientific Research(NWO),grant number ALW-GO-AO/11-30National Scientific Foundation of China(Grant No.U1831132 and 41374024)Innovation Group of Natural Fund of Hubei province(Grant No.2018CFA087).
文摘We used existing high-resolution gravity and aeromagnetic data to map the crustal units underneath Botswana.The thick sedimentary cover in this region has always been a challenge to understand the geological and tectonic configuration of unexposed crustal terranes using traditional geological methods.
文摘Some case studies are presented ranging from geological fakes and frauds,homicides and one environmental forensic case.Fakes may be true geological materials such as created fossils or gems and precious stones,or where geological methods are used to analyse fakes,such as the stones or ceramics used in making archaeological or art forgeries(e.g.,mineral pigments in paintings).Fakes have also been created for reasons of academic rivalry,career advancement and religious belief.Fraud commonly involves over-stated claims of ore content associated with mining and the oil and gas industry.The range of geological fakes,the uses of geological methods in detecting fakes,and the extent of fraud in the mining sector are all extensive and sometimes incredible.The homicide is case presented to demonstrate how the types of geological investigation described in the rest of this volume may be applied.We include an environmental forensic case for similar reasons,to show that forensic geology may be applied to more than homicides and fakery.
