With the development of modern society,people put forward higher requirements for building safety,which makes the construction project face new challenges.Reinforced concrete frame structure as a common engineering ty...With the development of modern society,people put forward higher requirements for building safety,which makes the construction project face new challenges.Reinforced concrete frame structure as a common engineering type,although the construction technology has been relatively mature,but its earthquake collapse ability still needs to be strengthened.This paper analyzes the specific factors that affect the seismic collapse ability of reinforced concrete frame structure,summarizes the previous research results,and puts forward innovative application of fiber-reinforced polymer(FRP)composite materials,play the role of smart materials,improve the isolation and energy dissipation devices,etc.,to promote the continuous optimization of reinforced concrete frame structure design,and show better seismic performance.展开更多
To ensure the operational safety of railways in the landslide-prone areas of mountainous regions,a large-scale model test and numerical simulation were conducted to study the bending moment distribution,internal force...To ensure the operational safety of railways in the landslide-prone areas of mountainous regions,a large-scale model test and numerical simulation were conducted to study the bending moment distribution,internal force distribution,deformation development,and crack propagation characteristics of a framed anti-sliding structure(FAS)under landslide thrust up to the point of failure.Results show that the maximum bending moment and its increase rate in the fore pile are greater than those in the rear pile,with the maximum bending moment of the fore pile approximately 1.1 times that of the rear pile.When the FAS fails,the displacement at the top of the fore pile is significantly greater,about 1.27 times that of the rear pile in the experiment.Major cracks develop at locations corresponding to the peak bending moments.Small transverse cracks initially appear on the upper surface at the intersection between the primary beam and rear pile and then spread to the side of the structure.At the failure stage,major cracks are observed at the pil-beam intersections and near the anchor points.Strengthening flexural stiffness at intersections where major cracks occur can improve the overall thrust-deformation coordination of the FAS,thereby maximizing its performance.展开更多
The reaction of Mg^(2+)and 5-{1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl}terephthalic acid(H_(2)L)leads to two metal-organic frameworks,[Mg(L)(DMF)_(2)(H_(2)O)_(2)]_(2)·5DMF·2H_(2)O(1)with a 1D structure and...The reaction of Mg^(2+)and 5-{1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl}terephthalic acid(H_(2)L)leads to two metal-organic frameworks,[Mg(L)(DMF)_(2)(H_(2)O)_(2)]_(2)·5DMF·2H_(2)O(1)with a 1D structure and[Mg_(2)(L)_(2)(DMSO)_(3)(H_(2)O)](2)with a 2D(4,4)-net structure.Interestingly,the two compounds exhibit distinct luminescent responses to external mechanical stimuli.1 exhibited exceptional resistance mechanical chromic luminescence(RMCL),which can be attributed to the predominant hydrogen bonds and the presence of high-boiling-point solvent molecules within its structure.2 had a reversible MCL property,which can be attributed to the dominantπ-πweak interactions,coupled with the reversible destruction/restoration of its crystallinity under grinding/fumigation.CCDC:2410963,1;2410964,2.展开更多
The authors regret that the original publication of this paper did not include Jawad Fayaz as a co-author.After further discussions and a thorough review of the research contributions,it was agreed that his significan...The authors regret that the original publication of this paper did not include Jawad Fayaz as a co-author.After further discussions and a thorough review of the research contributions,it was agreed that his significant contributions to the foundational aspects of the research warranted recognition,and he has now been added as a co-author.展开更多
In this work,the synthesis of uniform zeolitic imidazolate framework-coated Mo-glycerate spheres and their subsequent conversion into hierarchical architecture containing bimetallic selenides heterostructures and nitr...In this work,the synthesis of uniform zeolitic imidazolate framework-coated Mo-glycerate spheres and their subsequent conversion into hierarchical architecture containing bimetallic selenides heterostructures and nitrogen-doped carbon shell are reported.Selenization temperature plays a significant role in determining the phases,morphology,and lithium-ion storage performance of the composite.Notably,the optimal electrode demonstrates an ultrahigh reversible capacity of 1298.2 mAh/g after 100 cycles at 0.2 A/g and an outstanding rate capability with the capacity still maintained 505.7 mAh/g after 300 cycles at 1.0 A/g,surpassing the calculated theoretical capacity according to individual component and most of the reported MoSe@C-or ZnSe@C-based anodes.Furthermore,ex-situ X-ray diffraction patterns reveal the combined conversion and alloying reaction mechanisms of the composite.展开更多
Six new lanthanide complexes:[Ln(3,4-DEOBA)3(4,4'-DM-2,2'-bipy)]2·2C_(2)H_(5)OH,[Ln=Dy(1),Eu(2),Tb(3),Sm(4),Ho(5),Gd(6);3,4-DEOBA-=3,4-diethoxybenzoate,4,4'-DM-2,2'-bipy=4,4'-dimethyl-2,2'...Six new lanthanide complexes:[Ln(3,4-DEOBA)3(4,4'-DM-2,2'-bipy)]2·2C_(2)H_(5)OH,[Ln=Dy(1),Eu(2),Tb(3),Sm(4),Ho(5),Gd(6);3,4-DEOBA-=3,4-diethoxybenzoate,4,4'-DM-2,2'-bipy=4,4'-dimethyl-2,2'-bipyridine]were successfully synthesized by the volatilization of the solution at room temperature.The crystal structures of six complexes were determined by single-crystal X-ray diffraction technology.The results showed that the complexes all have a binuclear structure,and the structures contain free ethanol molecules.Moreover,the coordination number of the central metal of each structural unit is eight.Adjacent structural units interact with each other through hydrogen bonds and further expand to form 1D chain-like and 2D planar structures.After conducting a systematic study on the luminescence properties of complexes 1-4,their emission and excitation spectra were obtained.Experimental results indicated that the fluorescence lifetimes of complexes 2 and 3 were 0.807 and 0.845 ms,respectively.The emission spectral data of complexes 1-4 were imported into the CIE chromaticity coordinate system,and their corre sponding luminescent regions cover the yellow light,red light,green light,and orange-red light bands,respectively.Within the temperature range of 299.15-1300 K,the thermal decomposition processes of the six complexes were comprehensively analyzed by using TG-DSC/FTIR/MS technology.The hypothesis of the gradual loss of ligand groups during the decomposition process was verified by detecting the escaped gas,3D infrared spectroscopy,and ion fragment information detected by mass spectrometry.The specific decomposition path is as follows:firstly,free ethanol molecules and neutral ligands are removed,and finally,acidic ligands are released;the final product is the corresponding metal oxide.CCDC:2430420,1;2430422,2;2430419,3;2430424,4;2430421,5;2430423,6.展开更多
In this study,a novel polysaccharide GPA-G 2-H was derived from ginseng.Furthermore,the coherent study of its structural characteristics,fermented characteristics in vitro,as well as antioxidant mechanism of fermented...In this study,a novel polysaccharide GPA-G 2-H was derived from ginseng.Furthermore,the coherent study of its structural characteristics,fermented characteristics in vitro,as well as antioxidant mechanism of fermented product FGPA-G 2-H on Aβ25-35-induced PC 12 cells were explored.The structure of GPA-G 2-H was determined by means of zeta potential analysis,FTIR,HPLC,XRD,GC-MS and NMR.The backbone of GPA-G 2-H was mainly composed of→4)-α-D-Glcp-(1→with branches substituted at O-3.Notably,GPA-G 2-H was degraded by intestinal microbiota in vitro with total sugar content and pH value decreasing,and short-chain fatty acids(SCFAs)increasing.Moreover,GPA-G 2-H significantly promoted the proliferation of Lactobacillus,Muribaculaceae and Weissella,thereby making positive alterations in intestinal microbiota composition.Additionally,FGPA-G 2-H activated the Nrf 2/HO-1 signaling pathway,enhanced HO-1,NQO 1,SOD and GSH-Px,while inhabited Keap 1,MDA and LDH,which alleviated Aβ-induced oxidative stress in PC 12 cells.These provide a solid theoretical basis for the further development of ginseng polysaccharides as functional food and antioxidant drugs.展开更多
Developing novel building blocks with predictable side-chain orientations and minimal intramolecular interactions is essential for peptide-based self-assembling materials.Traditional structures likeα-helices andβ-sh...Developing novel building blocks with predictable side-chain orientations and minimal intramolecular interactions is essential for peptide-based self-assembling materials.Traditional structures likeα-helices andβ-sheets rely on such interactions for stability,limiting control over exposed interacting moieties.Here,we reported a novel,frame-like peptide scaffold that maintains exceptional stability without intramolecular interactions.This structure exposes its backbone and orients side chains for hierarchical self-assembly into micron-scale cubes.By introducing mutations at specific sites,we controlled packing orientations,offering new options for tunable self-assembly.Our scaffold provides a versatile platform for designing advanced peptide materials,with applications in nanotechnology and biomaterials.展开更多
Experimental studies were conducted on two high-strength steel plate-frame structures with different truss spacings under various impact velocities to investigate the dynamic mechanical properties of hull plate-frame ...Experimental studies were conducted on two high-strength steel plate-frame structures with different truss spacings under various impact velocities to investigate the dynamic mechanical properties of hull plate-frame structures under drop weight impact.The results showed that decreasing the main beam spacing can effectively increase the structural stiffness,reduce the maximum deformation,and increase the damage range.Furthermore,to simulate the impact tests accurately,static and dynamic tensile tests at different strain rates were carried out,and the Cowper-Symonds model parameters were fitted via experimental data.The material properties obtained from the tensile tests were used as inputs for numerical simulations with the numerical results coincide with the experimental results.A systematic analysis and discussion were conducted on the effects of truss spacing and truss width on the dynamic response of the reinforced plates,and an optimal range for the ratio of truss spacing to truss width was proposed.In addition,a mesh size sensitivity analysis for ship hull plate frame collision simulations was performed.The applicability of the EPS,MMC,and RTCL failure criteria in the simulation of plate-frame structures was investigated via finite element simulations of falling weight impact tests.The research findings provide a reference for ship hull structure design and resilience assessment.展开更多
To investigate the possible geometric structure of the proton,an improved stringy proton model is constructed beyond the smallest distance approximation and treats the constituent(up and down)quark-initiated gluon tub...To investigate the possible geometric structure of the proton,an improved stringy proton model is constructed beyond the smallest distance approximation and treats the constituent(up and down)quark-initiated gluon tubes separately,where the constituent quarks are connected by gluon tubes which merge at the Fermat point of the quark triangle.The exclusive diffractive vector meson production process in electron-proton deep inelastic scattering is used to test the stringy structure of the proton.We calculate the coherent and incoherent differential cross sections of the exclusive diffractive J/Ψphotoproduction in the framework of Color Glass Condensate.The results show that our calculations are in good agreement with HERA data.Especially,our results give a better description of the HERA data at small t as compared to the ones from the hot spot model where the constituent quarks are independently distributed in the proton.Meanwhile,the radius of the proton resulting from the improved stringy proton model is coincident with the one from fitting to the data from GlueX Collaboration at Jefferson Lab,which indicates that the predictive power of the stringy proton model is significantly improved once it goes beyond the smallest distance approximation and treats the constituent quarks separately,instead of using the same profile for the up and down quarks initiated gluon tubes.Moreover,we assume that the transverse shape of the gluon tube satisfies Gaussian distribution,and explore the distribution width of the individual gluon tubes.We find an interesting result that the up quark-initiated gluon tube seems to have a larger distribution width than the down quarkinitiated gluon tube,which is favored by the HERA data.展开更多
To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content ...To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.展开更多
Fine-grained nuclear graphite is a key material in high-temperature gas-cooled reactors(HTGRs).During air ingress accidents,core graphite components undergo severe oxidation,threatening structural integrity.Therefore,...Fine-grained nuclear graphite is a key material in high-temperature gas-cooled reactors(HTGRs).During air ingress accidents,core graphite components undergo severe oxidation,threatening structural integrity.Therefore,understanding the oxidation behavior of nuclear graphite is essential for reactor safety.The influence of oxidation involves multiple factors,including temperature,sample size,oxidant,impurities,filler type and size,etc.The size of the filler particles plays a crucial role in this study.Five ultrafine-and superfine-grained nuclear graphite samples(5.9-34.4μm)are manufactured using identical raw materials and manufacturing processes.Isothermal oxidation tests conducted at 650℃-750℃ are used to study the oxidation behavior.Additionally,comprehensive characterization is performed to analyze the crystal structure,surface morphology,and nanoscale to microscale pore structure of the samples.Results indicate that oxidation behavior cannot be predicted solely based on filler grain size.Reactive site concentration,characterized by active surface area,dominates the chemical reaction kinetics,whereas pore tortuosity,quantified by the structural parameterΨ,plays a key role in regulating oxidant diffusion.These findings clarify the dual role of microstructure in oxidation mechanisms and establish a theoretical and experimental basis for the design of high-performance nuclear graphite capable of long-term service in high-temperature gas-cooled reactors.展开更多
Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is p...Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is proposed.The electric field applied between the template and the substrate drives the contact,tilting,filling,and holding processes.By accurately controlling the introduced included angle between the flexible template and the substrate,tilted nanostructures with a controllable angle are imprinted onto the substrate,although they are vertical on the template.By flexibly adjusting the electric field intensity and the included angle,large-area uniform-tilted,gradient-tilted,and high-angle-tilted nanostructures are fabricated.In contrast to traditional replication,the morphology of the nanoimprinting structure is extended to customized control.This work provides a cost-effective,efficient,and versatile technology for the fabrication of various large-area tilted metasurface structures.As an illustration,a tilted nanograting with a high coupling efficiency is fabricated and integrated into augmented reality displays,demonstrating superior imaging quality.展开更多
Vacancy defects,as fundamental disruptions in metallic lattices,play an important role in shaping the mechanical and electronic properties of aluminum crystals.However,the influence of vacancy position under coupled t...Vacancy defects,as fundamental disruptions in metallic lattices,play an important role in shaping the mechanical and electronic properties of aluminum crystals.However,the influence of vacancy position under coupled thermomechanical fields remains insufficiently understood.In this study,transmission and scanning electron microscopy were employed to observe dislocation structures and grain boundary heterogeneities in processed aluminum alloys,suggesting stress concentrations and microstructural inhomogeneities associated with vacancy accumulation.To complement these observations,first-principles calculations and molecular dynamics simulations were conducted for seven single-vacancy configurations in face-centered cubic aluminum.The stress response,total energy,density of states(DOS),and differential charge density were examined under varying compressive strain(ε=0–0.1)and temperature(0–600 K).The results indicate that face-centered vacancies tend to reduce mechanical strength and perturb electronic states near the Fermi level,whereas corner and edge vacancies appear to have weaker effects.Elevated temperatures may partially restore electronic uniformity through thermal excitation.Overall,these findings suggest that vacancy position exerts a critical but position-dependent influence on coupled structure-property relationships,offering theoretical insights and preliminary experimental support for defect-engineered aluminum alloy design.展开更多
Aqueous zinc-ion batteries(AZIBs)have garnered considerable attention as promising post-lithium energy storage technologies owing to their intrinsic safety,cost-effectiveness,and competitive gravimetric energy density...Aqueous zinc-ion batteries(AZIBs)have garnered considerable attention as promising post-lithium energy storage technologies owing to their intrinsic safety,cost-effectiveness,and competitive gravimetric energy density.However,their practical commercialization is hindered by critical challenges on the anode side,including dendrite growth and parasitic reactions at the anode/electrolyte interface.Recent studies highlight that rational electrolyte structure engineering offers an effective route to mitigate these issues and strengthen the electrochemical performance of the zinc metal anode.In this review,we systematically summarize state-of-the-art strategies for electrolyte optimization,with a particular focus on the zinc salts regulation,electrolyte additives,and the construction of novel electrolytes,while elucidating the underlying design principles.We further discuss the key structure–property relationships governing electrolyte behavior to provide guidance for the development of next-generation electrolytes.Finally,future perspectives on advanced electrolyte design are proposed.This review aims to serve as a comprehensive reference for researchers exploring high-performance electrolyte engineering in AZIBs.展开更多
Porous carbon microspheres are widely regarded as a superior CO_(2) adsorbent due to their exceptional efficiency and affordability.However,better adsorption performance is very attractive for porous carbon microspher...Porous carbon microspheres are widely regarded as a superior CO_(2) adsorbent due to their exceptional efficiency and affordability.However,better adsorption performance is very attractive for porous carbon microspheres.And modification of the pore structure is one of the effective strategies.In this study,multi-cavity mesoporous carbon microspheres were successfully synthesized by the synergistic method of soft and hard templates,during which a phenolic resin with superior thermal stability was employed as the carbon precursor and a mixture of silica sol and F108 as the mesoporous template.Carbon microspheres with multi-cavity mesoporous structures were prepared,and all the samples showed highly even mesopores,with diameters around 12 nm.The diameter of these microspheres decreased from 396.8 nm to about 182.5 nm with the increase of silica sol.After CO_(2) activation,these novel carbon microspheres(APCF0.5-S1.75)demonstrated high specific surface area(983.3 m^(2)/g)and remarkable CO_(2) uptake of 4.93 mmol/g at 0℃ and1 bar.This could be attributed to the unique multi-cavity structure,which offers uniform mesoporous pore channels,minimal CO_(2) transport of and a greater number of active sites for CO_(2) adsorption.展开更多
Classical computation of electronic properties in large-scale materials remains challenging.Quantum computation has the potential to offer advantages in memory footprint and computational scaling.However,general and v...Classical computation of electronic properties in large-scale materials remains challenging.Quantum computation has the potential to offer advantages in memory footprint and computational scaling.However,general and viable quantum algorithms for simulating large-scale materials are still limited.We propose and implement random-state quantum algorithms to calculate electronic-structure properties of real materials.Using a random state circuit on a small number of qubits,we employ real-time evolution with first-order Trotter decomposition and Hadamard test to obtain electronic density of states,and we develop a modified quantum phase estimation algorithm to calculate real-space local density of states via direct quantum measurements.Furthermore,we validate these algorithms by numerically computing the density of states and spatial distributions of electronic states in graphene,twisted bilayer graphene quasicrystals,and fractal lattices,covering system sizes from hundreds to thousands of atoms.Our results manifest that the random-state quantum algorithms provide a general and qubit-efficient route to scalable simulations of electronic properties in large-scale periodic and aperiodic materials.展开更多
Based on the Independent Continuous Mapping method （ICM）, a topological optimization model with continuous topological variables is built by introducing three filter functions for element weight, element allowable s...Based on the Independent Continuous Mapping method （ICM）, a topological optimization model with continuous topological variables is built by introducing three filter functions for element weight, element allowable stress and element stiffness, which transform the 0-1 type discrete topological variables into continuous topological variables between 0 and 1. Two methods for the filter functions are adopted to avoid the structural singularity and recover falsely deleted elements： the weak material element method and the tiny section element method. Three criteria （no structural singularity, no violated constraints and no change of structural weight） are introduced to judge iteration convergence. These criteria allow finding an appropriate threshold by adjusting a discount factor in the iteration procedure. To improve the efficiency, the original optimization model is transformed into a dual problem according to the dual theory and solved in its dual space. By using MSC/Nastran as the structural solver and MSC/Patran as the developing platform, a topological optimization software of frame structures is accomplished. Numerical examples show that the ICM method is very efficient for the topological optimization of frame structures.展开更多
According to the Code for Seismic Design of Buildings （GB50011-2001）, ten typical reinforced concrete （RC） frame structures, used as school classroom buildings, are designed with different seismic fortification in...According to the Code for Seismic Design of Buildings （GB50011-2001）, ten typical reinforced concrete （RC） frame structures, used as school classroom buildings, are designed with different seismic fortification intensities （SFIs） （SFI=6 to 8.5） and different seismic design categories （SDCs） （SDC=B and C）. The collapse resistance of the frames with SDC=B and C in terms of collapse fragility curves are quantitatively evaluated and compared via incremental dynamic analysis （IDA）. The results show that the collapse resistance of structures should be evaluated based on both the absolute seismic resistance and the corresponding design seismic intensity. For the frames with SFI from 6 to 7.5, because they have relatively low absolute seismic resistance, their collapse resistance is insufficient even when their corresponding SDCs are upgraded from B to C. Thus, further measures are needed to enhance these structures, and some suggestions are proposed.展开更多
Based on a typical prototype of a soil slope in engineering practice, a numerical model of a three-stage soil slope supported by the anchor frame structure was established by means of FLAC3D code. The dynamic response...Based on a typical prototype of a soil slope in engineering practice, a numerical model of a three-stage soil slope supported by the anchor frame structure was established by means of FLAC3D code. The dynamic responses of three-stage soil slope and frame structure were studied by performing a series of bidirectional Wenchuan motions in terms of the failure mode of three-stage structure, the acceleration of soil slope, the displacement of frame structure, and the anchor stress of frame structure. The response accelerations in both horizontal and vertical directions are the most largely amplified at the slope top of each stage subjected to different shaking cases. The platforms among the stages reduce the amplification effect of response acceleration. The residual displacement of frame structure increases significantly as the intensity of shaking case increases. The frame structure at each stage presents a combined displacement mode consisting of a translation and a rotation around the vertex. The anchor stress of frame structure is mainly increased by the first intense pulse of Wenchuan seismic wave, and it is sensitive to the intensity of shaking case. The anchor stress of frame structure at the first stage is the most considerably enlarged by earthquake loading.展开更多
文摘With the development of modern society,people put forward higher requirements for building safety,which makes the construction project face new challenges.Reinforced concrete frame structure as a common engineering type,although the construction technology has been relatively mature,but its earthquake collapse ability still needs to be strengthened.This paper analyzes the specific factors that affect the seismic collapse ability of reinforced concrete frame structure,summarizes the previous research results,and puts forward innovative application of fiber-reinforced polymer(FRP)composite materials,play the role of smart materials,improve the isolation and energy dissipation devices,etc.,to promote the continuous optimization of reinforced concrete frame structure design,and show better seismic performance.
基金The National Natural Science Foundation of China(No.52078427).
文摘To ensure the operational safety of railways in the landslide-prone areas of mountainous regions,a large-scale model test and numerical simulation were conducted to study the bending moment distribution,internal force distribution,deformation development,and crack propagation characteristics of a framed anti-sliding structure(FAS)under landslide thrust up to the point of failure.Results show that the maximum bending moment and its increase rate in the fore pile are greater than those in the rear pile,with the maximum bending moment of the fore pile approximately 1.1 times that of the rear pile.When the FAS fails,the displacement at the top of the fore pile is significantly greater,about 1.27 times that of the rear pile in the experiment.Major cracks develop at locations corresponding to the peak bending moments.Small transverse cracks initially appear on the upper surface at the intersection between the primary beam and rear pile and then spread to the side of the structure.At the failure stage,major cracks are observed at the pil-beam intersections and near the anchor points.Strengthening flexural stiffness at intersections where major cracks occur can improve the overall thrust-deformation coordination of the FAS,thereby maximizing its performance.
文摘The reaction of Mg^(2+)and 5-{1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl}terephthalic acid(H_(2)L)leads to two metal-organic frameworks,[Mg(L)(DMF)_(2)(H_(2)O)_(2)]_(2)·5DMF·2H_(2)O(1)with a 1D structure and[Mg_(2)(L)_(2)(DMSO)_(3)(H_(2)O)](2)with a 2D(4,4)-net structure.Interestingly,the two compounds exhibit distinct luminescent responses to external mechanical stimuli.1 exhibited exceptional resistance mechanical chromic luminescence(RMCL),which can be attributed to the predominant hydrogen bonds and the presence of high-boiling-point solvent molecules within its structure.2 had a reversible MCL property,which can be attributed to the dominantπ-πweak interactions,coupled with the reversible destruction/restoration of its crystallinity under grinding/fumigation.CCDC:2410963,1;2410964,2.
文摘The authors regret that the original publication of this paper did not include Jawad Fayaz as a co-author.After further discussions and a thorough review of the research contributions,it was agreed that his significant contributions to the foundational aspects of the research warranted recognition,and he has now been added as a co-author.
基金supported by the National Natural Science Foundation of China(No.22265017)the Open Fund of Key Laboratory of Eco-functional Polymer Materials of the Ministry of Education(No.KF-21-04).
文摘In this work,the synthesis of uniform zeolitic imidazolate framework-coated Mo-glycerate spheres and their subsequent conversion into hierarchical architecture containing bimetallic selenides heterostructures and nitrogen-doped carbon shell are reported.Selenization temperature plays a significant role in determining the phases,morphology,and lithium-ion storage performance of the composite.Notably,the optimal electrode demonstrates an ultrahigh reversible capacity of 1298.2 mAh/g after 100 cycles at 0.2 A/g and an outstanding rate capability with the capacity still maintained 505.7 mAh/g after 300 cycles at 1.0 A/g,surpassing the calculated theoretical capacity according to individual component and most of the reported MoSe@C-or ZnSe@C-based anodes.Furthermore,ex-situ X-ray diffraction patterns reveal the combined conversion and alloying reaction mechanisms of the composite.
文摘Six new lanthanide complexes:[Ln(3,4-DEOBA)3(4,4'-DM-2,2'-bipy)]2·2C_(2)H_(5)OH,[Ln=Dy(1),Eu(2),Tb(3),Sm(4),Ho(5),Gd(6);3,4-DEOBA-=3,4-diethoxybenzoate,4,4'-DM-2,2'-bipy=4,4'-dimethyl-2,2'-bipyridine]were successfully synthesized by the volatilization of the solution at room temperature.The crystal structures of six complexes were determined by single-crystal X-ray diffraction technology.The results showed that the complexes all have a binuclear structure,and the structures contain free ethanol molecules.Moreover,the coordination number of the central metal of each structural unit is eight.Adjacent structural units interact with each other through hydrogen bonds and further expand to form 1D chain-like and 2D planar structures.After conducting a systematic study on the luminescence properties of complexes 1-4,their emission and excitation spectra were obtained.Experimental results indicated that the fluorescence lifetimes of complexes 2 and 3 were 0.807 and 0.845 ms,respectively.The emission spectral data of complexes 1-4 were imported into the CIE chromaticity coordinate system,and their corre sponding luminescent regions cover the yellow light,red light,green light,and orange-red light bands,respectively.Within the temperature range of 299.15-1300 K,the thermal decomposition processes of the six complexes were comprehensively analyzed by using TG-DSC/FTIR/MS technology.The hypothesis of the gradual loss of ligand groups during the decomposition process was verified by detecting the escaped gas,3D infrared spectroscopy,and ion fragment information detected by mass spectrometry.The specific decomposition path is as follows:firstly,free ethanol molecules and neutral ligands are removed,and finally,acidic ligands are released;the final product is the corresponding metal oxide.CCDC:2430420,1;2430422,2;2430419,3;2430424,4;2430421,5;2430423,6.
基金Supported by the National Key Research and Development Program of Traditional Chinese Medicine Modernization Project,China(No.2023YFC3504000)the Science and Technology Development Project of Jilin Province,China(No.20240404043ZP)the Science and Technology Innovation Cooperation Project of Changchun Science and Technology Bureau and Chinese Academy of Sciences,China(No.23SH14)。
文摘In this study,a novel polysaccharide GPA-G 2-H was derived from ginseng.Furthermore,the coherent study of its structural characteristics,fermented characteristics in vitro,as well as antioxidant mechanism of fermented product FGPA-G 2-H on Aβ25-35-induced PC 12 cells were explored.The structure of GPA-G 2-H was determined by means of zeta potential analysis,FTIR,HPLC,XRD,GC-MS and NMR.The backbone of GPA-G 2-H was mainly composed of→4)-α-D-Glcp-(1→with branches substituted at O-3.Notably,GPA-G 2-H was degraded by intestinal microbiota in vitro with total sugar content and pH value decreasing,and short-chain fatty acids(SCFAs)increasing.Moreover,GPA-G 2-H significantly promoted the proliferation of Lactobacillus,Muribaculaceae and Weissella,thereby making positive alterations in intestinal microbiota composition.Additionally,FGPA-G 2-H activated the Nrf 2/HO-1 signaling pathway,enhanced HO-1,NQO 1,SOD and GSH-Px,while inhabited Keap 1,MDA and LDH,which alleviated Aβ-induced oxidative stress in PC 12 cells.These provide a solid theoretical basis for the further development of ginseng polysaccharides as functional food and antioxidant drugs.
基金supported by the National Basic Research Program of China 973 Program(Nos.2021YFA0910803,2021YFC2103900)the National Natural Science Foundation of China(No.21977011)+4 种基金the Natural Science Foundation of Guangdong Province(Nos.2022A1515010996 and 2020A1515011544)the Shenzhen Science and Technology Innovation Committee(Nos.RCJC20200714114433053,JCYJ20180507181527112 and JCYJ20200109140406047)the Shenzhen-Hong Kong Institute of Brain Science-Shenzhen Fundamental Research Institutions(No.2019SHIBS0004)the Shenzhen Fundamental Research Program(No.GXWD20201231165807007–20200827170132001)Tian Fu Jin Cheng Laboratory(Advanced Medical Center)Group Racing Project(No.TFJC2023010008)。
文摘Developing novel building blocks with predictable side-chain orientations and minimal intramolecular interactions is essential for peptide-based self-assembling materials.Traditional structures likeα-helices andβ-sheets rely on such interactions for stability,limiting control over exposed interacting moieties.Here,we reported a novel,frame-like peptide scaffold that maintains exceptional stability without intramolecular interactions.This structure exposes its backbone and orients side chains for hierarchical self-assembly into micron-scale cubes.By introducing mutations at specific sites,we controlled packing orientations,offering new options for tunable self-assembly.Our scaffold provides a versatile platform for designing advanced peptide materials,with applications in nanotechnology and biomaterials.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.52171311 and 5227127).
文摘Experimental studies were conducted on two high-strength steel plate-frame structures with different truss spacings under various impact velocities to investigate the dynamic mechanical properties of hull plate-frame structures under drop weight impact.The results showed that decreasing the main beam spacing can effectively increase the structural stiffness,reduce the maximum deformation,and increase the damage range.Furthermore,to simulate the impact tests accurately,static and dynamic tensile tests at different strain rates were carried out,and the Cowper-Symonds model parameters were fitted via experimental data.The material properties obtained from the tensile tests were used as inputs for numerical simulations with the numerical results coincide with the experimental results.A systematic analysis and discussion were conducted on the effects of truss spacing and truss width on the dynamic response of the reinforced plates,and an optimal range for the ratio of truss spacing to truss width was proposed.In addition,a mesh size sensitivity analysis for ship hull plate frame collision simulations was performed.The applicability of the EPS,MMC,and RTCL failure criteria in the simulation of plate-frame structures was investigated via finite element simulations of falling weight impact tests.The research findings provide a reference for ship hull structure design and resilience assessment.
基金supported by the National Natural Science Foundation of China under Grant No.12165004 and and Key Grant No.12061141008the Basic and Applied Basic Research Project of Guangzhou Science and Technology Bureau under Grant No.202201011324+1 种基金the Education Department of Guizhou Province under Grant No.QJJ[2022]016the National Key Research and Development Program of China under Grant Nos.2024YFA1610800 and 2022YFA1602103。
文摘To investigate the possible geometric structure of the proton,an improved stringy proton model is constructed beyond the smallest distance approximation and treats the constituent(up and down)quark-initiated gluon tubes separately,where the constituent quarks are connected by gluon tubes which merge at the Fermat point of the quark triangle.The exclusive diffractive vector meson production process in electron-proton deep inelastic scattering is used to test the stringy structure of the proton.We calculate the coherent and incoherent differential cross sections of the exclusive diffractive J/Ψphotoproduction in the framework of Color Glass Condensate.The results show that our calculations are in good agreement with HERA data.Especially,our results give a better description of the HERA data at small t as compared to the ones from the hot spot model where the constituent quarks are independently distributed in the proton.Meanwhile,the radius of the proton resulting from the improved stringy proton model is coincident with the one from fitting to the data from GlueX Collaboration at Jefferson Lab,which indicates that the predictive power of the stringy proton model is significantly improved once it goes beyond the smallest distance approximation and treats the constituent quarks separately,instead of using the same profile for the up and down quarks initiated gluon tubes.Moreover,we assume that the transverse shape of the gluon tube satisfies Gaussian distribution,and explore the distribution width of the individual gluon tubes.We find an interesting result that the up quark-initiated gluon tube seems to have a larger distribution width than the down quarkinitiated gluon tube,which is favored by the HERA data.
基金Supported by the Science and Technology Cooperation and Exchange special project of Cooperation of Shanxi Province(202404041101014)the Fundamental Research Program of Shanxi Province(202403021212333)+3 种基金the Joint Funds of the National Natural Science Foundation of China(U24A20555)the Lvliang Key R&D of University-Local Cooperation(2023XDHZ10)the Initiation Fund for Doctoral Research of Taiyuan University of Science and Technology(20242026)the Outstanding Doctor Funding Award of Shanxi Province(20242080).
文摘To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.
基金supported by the National Key Research and Development Program of China(2024YFA1612900)the National Natural Science Foundation of China(Grant No.52103365 and No.12375270)the Guangdong Innovative and Entrepreneurial Research Team Program,China(Grant No.2021ZT09L227).
文摘Fine-grained nuclear graphite is a key material in high-temperature gas-cooled reactors(HTGRs).During air ingress accidents,core graphite components undergo severe oxidation,threatening structural integrity.Therefore,understanding the oxidation behavior of nuclear graphite is essential for reactor safety.The influence of oxidation involves multiple factors,including temperature,sample size,oxidant,impurities,filler type and size,etc.The size of the filler particles plays a crucial role in this study.Five ultrafine-and superfine-grained nuclear graphite samples(5.9-34.4μm)are manufactured using identical raw materials and manufacturing processes.Isothermal oxidation tests conducted at 650℃-750℃ are used to study the oxidation behavior.Additionally,comprehensive characterization is performed to analyze the crystal structure,surface morphology,and nanoscale to microscale pore structure of the samples.Results indicate that oxidation behavior cannot be predicted solely based on filler grain size.Reactive site concentration,characterized by active surface area,dominates the chemical reaction kinetics,whereas pore tortuosity,quantified by the structural parameterΨ,plays a key role in regulating oxidant diffusion.These findings clarify the dual role of microstructure in oxidation mechanisms and establish a theoretical and experimental basis for the design of high-performance nuclear graphite capable of long-term service in high-temperature gas-cooled reactors.
基金supported by National Natural Science Foundation of China(No.52025055 and 52275571)Basic Research Operation Fund of China(No.xzy012024024).
文摘Tilted metasurface nanostructures,with excellent physical properties and enormous application potential,pose an urgent need for manufacturing methods.Here,electric-field-driven generative-nanoimprinting technique is proposed.The electric field applied between the template and the substrate drives the contact,tilting,filling,and holding processes.By accurately controlling the introduced included angle between the flexible template and the substrate,tilted nanostructures with a controllable angle are imprinted onto the substrate,although they are vertical on the template.By flexibly adjusting the electric field intensity and the included angle,large-area uniform-tilted,gradient-tilted,and high-angle-tilted nanostructures are fabricated.In contrast to traditional replication,the morphology of the nanoimprinting structure is extended to customized control.This work provides a cost-effective,efficient,and versatile technology for the fabrication of various large-area tilted metasurface structures.As an illustration,a tilted nanograting with a high coupling efficiency is fabricated and integrated into augmented reality displays,demonstrating superior imaging quality.
基金supported by the Research Project on Strengthening the Construction of an Important Ecological Security Barrier in Northern China by Higher Education Institutions in the Inner Mongolia Autonomous Region(STAQZX202313)the Inner Mongolia Autonomous Region Education Science‘14th Five-Year Plan’2024 Annual Research Project(NGJGH2024635).
文摘Vacancy defects,as fundamental disruptions in metallic lattices,play an important role in shaping the mechanical and electronic properties of aluminum crystals.However,the influence of vacancy position under coupled thermomechanical fields remains insufficiently understood.In this study,transmission and scanning electron microscopy were employed to observe dislocation structures and grain boundary heterogeneities in processed aluminum alloys,suggesting stress concentrations and microstructural inhomogeneities associated with vacancy accumulation.To complement these observations,first-principles calculations and molecular dynamics simulations were conducted for seven single-vacancy configurations in face-centered cubic aluminum.The stress response,total energy,density of states(DOS),and differential charge density were examined under varying compressive strain(ε=0–0.1)and temperature(0–600 K).The results indicate that face-centered vacancies tend to reduce mechanical strength and perturb electronic states near the Fermi level,whereas corner and edge vacancies appear to have weaker effects.Elevated temperatures may partially restore electronic uniformity through thermal excitation.Overall,these findings suggest that vacancy position exerts a critical but position-dependent influence on coupled structure-property relationships,offering theoretical insights and preliminary experimental support for defect-engineered aluminum alloy design.
基金supported by the Natural Science Foundation of China(Nos.52125202,52202100,and U24A2065)the Natural Science Foundation of Jiangsu Province(BK20243016)Fundamental Research Funds for the Central Universities,China Postdoctoral Science Foundation(No.2024T171166).
文摘Aqueous zinc-ion batteries(AZIBs)have garnered considerable attention as promising post-lithium energy storage technologies owing to their intrinsic safety,cost-effectiveness,and competitive gravimetric energy density.However,their practical commercialization is hindered by critical challenges on the anode side,including dendrite growth and parasitic reactions at the anode/electrolyte interface.Recent studies highlight that rational electrolyte structure engineering offers an effective route to mitigate these issues and strengthen the electrochemical performance of the zinc metal anode.In this review,we systematically summarize state-of-the-art strategies for electrolyte optimization,with a particular focus on the zinc salts regulation,electrolyte additives,and the construction of novel electrolytes,while elucidating the underlying design principles.We further discuss the key structure–property relationships governing electrolyte behavior to provide guidance for the development of next-generation electrolytes.Finally,future perspectives on advanced electrolyte design are proposed.This review aims to serve as a comprehensive reference for researchers exploring high-performance electrolyte engineering in AZIBs.
基金supported by the National Key R&D Program of China(No.2021YFB3501102).
文摘Porous carbon microspheres are widely regarded as a superior CO_(2) adsorbent due to their exceptional efficiency and affordability.However,better adsorption performance is very attractive for porous carbon microspheres.And modification of the pore structure is one of the effective strategies.In this study,multi-cavity mesoporous carbon microspheres were successfully synthesized by the synergistic method of soft and hard templates,during which a phenolic resin with superior thermal stability was employed as the carbon precursor and a mixture of silica sol and F108 as the mesoporous template.Carbon microspheres with multi-cavity mesoporous structures were prepared,and all the samples showed highly even mesopores,with diameters around 12 nm.The diameter of these microspheres decreased from 396.8 nm to about 182.5 nm with the increase of silica sol.After CO_(2) activation,these novel carbon microspheres(APCF0.5-S1.75)demonstrated high specific surface area(983.3 m^(2)/g)and remarkable CO_(2) uptake of 4.93 mmol/g at 0℃ and1 bar.This could be attributed to the unique multi-cavity structure,which offers uniform mesoporous pore channels,minimal CO_(2) transport of and a greater number of active sites for CO_(2) adsorption.
基金supported by the Major Project for the Integration of ScienceEducation and Industry (Grant No.2025ZDZX02)。
文摘Classical computation of electronic properties in large-scale materials remains challenging.Quantum computation has the potential to offer advantages in memory footprint and computational scaling.However,general and viable quantum algorithms for simulating large-scale materials are still limited.We propose and implement random-state quantum algorithms to calculate electronic-structure properties of real materials.Using a random state circuit on a small number of qubits,we employ real-time evolution with first-order Trotter decomposition and Hadamard test to obtain electronic density of states,and we develop a modified quantum phase estimation algorithm to calculate real-space local density of states via direct quantum measurements.Furthermore,we validate these algorithms by numerically computing the density of states and spatial distributions of electronic states in graphene,twisted bilayer graphene quasicrystals,and fractal lattices,covering system sizes from hundreds to thousands of atoms.Our results manifest that the random-state quantum algorithms provide a general and qubit-efficient route to scalable simulations of electronic properties in large-scale periodic and aperiodic materials.
基金The project supported by the National Natural Science Foundation of China (10472003)Beijing Natural Science Foundation (3042002)
文摘Based on the Independent Continuous Mapping method （ICM）, a topological optimization model with continuous topological variables is built by introducing three filter functions for element weight, element allowable stress and element stiffness, which transform the 0-1 type discrete topological variables into continuous topological variables between 0 and 1. Two methods for the filter functions are adopted to avoid the structural singularity and recover falsely deleted elements： the weak material element method and the tiny section element method. Three criteria （no structural singularity, no violated constraints and no change of structural weight） are introduced to judge iteration convergence. These criteria allow finding an appropriate threshold by adjusting a discount factor in the iteration procedure. To improve the efficiency, the original optimization model is transformed into a dual problem according to the dual theory and solved in its dual space. By using MSC/Nastran as the structural solver and MSC/Patran as the developing platform, a topological optimization software of frame structures is accomplished. Numerical examples show that the ICM method is very efficient for the topological optimization of frame structures.
基金National Science Foundation of China Under Grant No.90815025&51178249the National Key Technologies R&D Program Under Grant No.2009BAJ28B01&2006BAJ03A02-01+1 种基金Tsinghua University Research Funds No.2010THZ02-1the Program for New Century Excellent Talents in University
文摘According to the Code for Seismic Design of Buildings （GB50011-2001）, ten typical reinforced concrete （RC） frame structures, used as school classroom buildings, are designed with different seismic fortification intensities （SFIs） （SFI=6 to 8.5） and different seismic design categories （SDCs） （SDC=B and C）. The collapse resistance of the frames with SDC=B and C in terms of collapse fragility curves are quantitatively evaluated and compared via incremental dynamic analysis （IDA）. The results show that the collapse resistance of structures should be evaluated based on both the absolute seismic resistance and the corresponding design seismic intensity. For the frames with SFI from 6 to 7.5, because they have relatively low absolute seismic resistance, their collapse resistance is insufficient even when their corresponding SDCs are upgraded from B to C. Thus, further measures are needed to enhance these structures, and some suggestions are proposed.
基金Projects(51878667,51678571)supported by the National Natural Science Foundation of ChinaProject(2018zzts657)supported by the Central South University Postgraduates’Innovation,ChinaProject(2018JJ2517)supported by the Hunan Provincial Natural Science Foundation of China。
文摘Based on a typical prototype of a soil slope in engineering practice, a numerical model of a three-stage soil slope supported by the anchor frame structure was established by means of FLAC3D code. The dynamic responses of three-stage soil slope and frame structure were studied by performing a series of bidirectional Wenchuan motions in terms of the failure mode of three-stage structure, the acceleration of soil slope, the displacement of frame structure, and the anchor stress of frame structure. The response accelerations in both horizontal and vertical directions are the most largely amplified at the slope top of each stage subjected to different shaking cases. The platforms among the stages reduce the amplification effect of response acceleration. The residual displacement of frame structure increases significantly as the intensity of shaking case increases. The frame structure at each stage presents a combined displacement mode consisting of a translation and a rotation around the vertex. The anchor stress of frame structure is mainly increased by the first intense pulse of Wenchuan seismic wave, and it is sensitive to the intensity of shaking case. The anchor stress of frame structure at the first stage is the most considerably enlarged by earthquake loading.
