One of the most significant challenges in commercializing organic second-order nonlinear optical(NLO)materials lies in the inherent trade-off between nonlinearity and stability.A key factor in mitigating this compromi...One of the most significant challenges in commercializing organic second-order nonlinear optical(NLO)materials lies in the inherent trade-off between nonlinearity and stability.A key factor in mitigating this compromise is achieving precise temporal synchronization between the formation of the cross-linked network and the establishment of an optimal non-centrosymmetric alignment of the chromophores.Guided by this principle,we developed a series of NLO polymers incorporating multiple ether chains with low rotational energy barriers,which facilitate molecular reorientation during electric field poling,thereby enhancing the NLO response effectively.Combined with an optimized photocrosslinking strategy,the resulting PX4o/PETMP doped film achieved large macroscopic NLO coefficient of 190 pm·V^(-1)and thermal degradation temperature as high as 120℃.This work offers a universal approach to alleviating the“nonlinearity-stability”trade-off in a wide range of polymeric systems.展开更多
The second-order effect of axial force on horizontal vibrating characteristics of a large-diameter pipe pile is theoretically investigated.Governing equations of the pile-soil system are established based on elastodyn...The second-order effect of axial force on horizontal vibrating characteristics of a large-diameter pipe pile is theoretically investigated.Governing equations of the pile-soil system are established based on elastodynamics.Threedimensional wave equations of soil are decoupled through differential transformation and variable separation.Consequently,expressions of soil displacements and horizontal resistances can be obtained.An analytical solution of the pile is derived based on continuity conditions between the pile and soil,subsequently from which expressions of the complex impedances are deduced.Analyses are carried out to examine the second-order effect of axial force on the horizontal vibrating behavior of the pipe pile.Some conclusions can be summarized as follows： stiffness and damping factors are decreased with the application of axial force on the pile head; distributions of the pile horizontal displacement and rotation angle are regenerated due to the second-order effect of the applied axial force; and redistributions of the bending moment and shearing force occur due to the second-order effect of the applied axial force.展开更多
A chiral lanthanide metal-organic framework based on enantiopure camphoric acid （D-H2cam）, [Nd3（D-cam）8（H2O）4Cl]n （1）, has been synthesized and characterized by single-crystal X-ray structural analysis, elemen...A chiral lanthanide metal-organic framework based on enantiopure camphoric acid （D-H2cam）, [Nd3（D-cam）8（H2O）4Cl]n （1）, has been synthesized and characterized by single-crystal X-ray structural analysis, elemental analysis, IR, thermal gravimetric, and X-ray powder diffraction. Crystal data for the title compound are as follows： orthorhombic system, space group P212121 with a = 13.8287（7）, b = 14.0715（7）, c = 25.7403（12） A^°, V = 5008.8（4） A^°3, Mr = 1333.08, Z = 4, F（000） = 2644, Dc = 1.768 g/cm^3, μ（MoKα） = 3.189 mm^-1, the final R = 0.0351 and wR = 0.0814 （I 〉 2σ（I））. Compound 1 displays an 8-connected bcu topology 3D framework and hydrogen-bonding interactions stabilize the solid-state structure. The vibrational circular dichroism （VCD） spectrum and second-order nonlinear optical effect of compound 1 have been studied in the solid state.展开更多
In this paper,we investigate the photon correlations and the statistical properties of light produced by an optical cavity with an embedded quantum well interacting with squeezed light.We show that the squeezed source...In this paper,we investigate the photon correlations and the statistical properties of light produced by an optical cavity with an embedded quantum well interacting with squeezed light.We show that the squeezed source substantially improves the intensity of the emitted light and generates a narrowing and a duplication of the spectrum peaks.With a strong dependence on frequency detuning,the cavity produces considerably squeezed radiation,and perfect squeezing is predicted for weak light–matter interactions.Furthermore,the system under consideration presents a bunching effect of the transmitted radiation resulting from weak pumping of the coherent field.The results obtained may have potential applications in the fields of very accurate measurement and quantum computing.展开更多
We theoretically study the effect of Kerr effect on the second-order nonlinearity induced transparency in a double-resonant optical cavity system.We show that in the presence of the Kerr effect,as the strength of the ...We theoretically study the effect of Kerr effect on the second-order nonlinearity induced transparency in a double-resonant optical cavity system.We show that in the presence of the Kerr effect,as the strength of the Kerr effect increases,the absorption curve exhibits an asymmetric-symmetric-asymmetric transition,and the zero absorption point shifts with the increase of the Kerr effect.Furthermore,by changing the strength of the Kerr effect,we can control the width of the transparent window,and the position of the zero-absorption point and meanwhile change the left and right width of the absorption peak.The asymmetry absorption curve can be employed to improve the quality factor of the cavity when the frequency detuning is tuned to be around the right peak.The simple dependence of the zeroabsorption point on the strength of Kerr effect suggests that the strength of Kerr effect can be measured by measuring the position of the zero-absorption point in a possible application.展开更多
Dynamic equations of motional flexible beam elements were derived considering second-order effect. Non-linear finite element method and three-node Euler-Bernoulli beam elements were used. Because accuracy is higher in...Dynamic equations of motional flexible beam elements were derived considering second-order effect. Non-linear finite element method and three-node Euler-Bernoulli beam elements were used. Because accuracy is higher in non-linear structural analysis,three-node beam elements are used to deduce shape functions and stiffness matrices in dynamic equations of flexible elements. Static condensation method was used to obtain the finial dynamic equations of three-node beam elements. According to geometrical relations of nodal displacements in concomitant and global coordinate system,dynamic equations of elements can be transformed to global coordinate system by concomitant coordinate method in order to build the global dynamic equations. Analyzed amplitude condition of flexible arm support of a port crane,the results show that second-order effect should be considered in kinetic-elastic analysis for heavy load machinery of big flexibility.展开更多
Large magnetic entropy change(△S_(M))can realize a prominent heat transformation under the magnetic field and directly strengthen the efficacy of the magnetocaloric effect,which provides a pioneering environmentally ...Large magnetic entropy change(△S_(M))can realize a prominent heat transformation under the magnetic field and directly strengthen the efficacy of the magnetocaloric effect,which provides a pioneering environmentally friendly solidstate strategy to improve refrigeration capacities and efficiencies.The second-order magnetic transition(SOMT)materials have broader△S_(M) peaks without thermal hysteresis,making them highly attractive in magnetic refrigeration,especially in the room temperature range.Here,we report a significant enhancement of△S_(M) at room temperature in single-crystal Mn_(5)Ge_(3).In this SOMT system,we realize a 60%improvement of-△S_(M)^(max) from 3.5 J/kg·K to 5.6 J/kg·K at T=300 K.This considerable enhancement of△S_(M) is achieved by intentionally introducing strain energy through high-pressure constrained deformation.Both experimental results and Monte Carlo simulations demonstrate that the enhancement of△S_(M) originates from the microscopic strain and lattice deformation induced by strain energy after deformation.This strain energy will reconstruct the energy landscape of this ferromagnetic system and enhance magnetization,resulting in a giant intensity of magnetocaloric responses.Our findings provide an approach to increase magnetic entropy change and may give fresh ideas for exploring advanced magnetocaloric materials.展开更多
A novel transition appeared above thc glass transition temperature of chlorinated polyethylene (CPE) for binaryblends of CPE and additives such as organic small molecules or oligomers. This transition was assigned to ...A novel transition appeared above thc glass transition temperature of chlorinated polyethylene (CPE) for binaryblends of CPE and additives such as organic small molecules or oligomers. This transition was assigned to the dissociation ofintermolecular hydrogen bonds between the polymer ard additive within the edditive rich phase. Of particular interest is thata novel pyramid crystal was observed in the annealed CPE/hindered phenol blends. Another intriguing observation is thatthese polymer/small molecule blends organized by intermolecular hydrogen bonding have several potential properties, suchas shape-memorization, self-restoration, self-adhesiveness and super damping.展开更多
Multifunctional hybrid polymer composites were projected as novel solutions to meet the demands in various industrial applications ranging from automotive to aerospace. This investigation focuses on processing, flexur...Multifunctional hybrid polymer composites were projected as novel solutions to meet the demands in various industrial applications ranging from automotive to aerospace. This investigation focuses on processing, flexural strength and fracture toughness characterization of the glass fabric reinforced epoxy (G-E) composites and graphite/fly ash cenosphere (FAC) modified interface between the epoxy matrix and glass fabric. Hand lay-up followed by compression moulding method was used to fabricate the laminates. Flexural and fracture toughness tests at room temperature, elevated temperature and cryogenic temperature were conducted to assess the flexural strength (FS) and mode-I plane-strain fracture toughness (K<sub>IC</sub>). The experimental and characterization efforts suggest that both graphite and FAC fillers improve bonding at the interface. The study showed that the graphite is more favorable for enhancing FS and KIC of G-E composites. Graphite filled G-E hybrid composites with significant FS and KIC to that of unfilled and FA filled G-E were successfully achieved by incorporating 10 wt% graphite. The incorporation of fillers resulted in improvement of FS, which increased by 43% and 37.7% for 10Gr+G-E and 10FAC+G-E hybrid composites respectively. All composites show a 26% improvement in KIC at cryogenic temperature and a decrease of 12.5% at elevated temperature. According to the SEM observations, fiber debonding from the matrix is suppressed due to the presence and uniform distribution of graphite. In addition, micro-pores, matrix shearing, active toughening mechanisms induced by graphite, such as crack deflection, layer breakage and delamination of graphite layers contributed to the enhanced KIC of hybrid G-E composites.展开更多
We investigated the magnetocaloric effect in commercial Er_(2)O_(3) powders which presents almost no hysteresis losses at low temperature.At a magnetic field change of 5 T,it displays large magnetic entropy change(-Δ...We investigated the magnetocaloric effect in commercial Er_(2)O_(3) powders which presents almost no hysteresis losses at low temperature.At a magnetic field change of 5 T,it displays large magnetic entropy change(-ΔSM)max of 15.02 J/(kg·K)and a refrigerant capacity(RC)of 311 J/K at Neel temperature TN=3.32 K.The magnetic transition was found to be of a second-order.The maximum values of adiabatic temperature change(ΔTad)max reach 0.70 K for a magnetic field change of 1 T.The large value,of(-ASM)max as well as no hysteresis loss,makes Er_(2)O_(3) a promising material as a magnetic refrigerant at low temperature.展开更多
We conducted a detailed analysis of along-trench variations in the flexural bending of the subducting Pacific Plate at the Tonga-Kermadec Trench.Inversions were conducted to obtain best-fitting solutions of trench-axi...We conducted a detailed analysis of along-trench variations in the flexural bending of the subducting Pacific Plate at the Tonga-Kermadec Trench.Inversions were conducted to obtain best-fitting solutions of trench-axis loadings and variations in the effective elastic plate thickness for the analyzed flexural bending profiles.Results of the analyses revealed significant along-trench variations in plate flexural bending:the trench relief(W0)of 1.9 to 5.1 km;trench-axis vertical loading(V0)of-0.5×10^12 to 2.2×10^12 N/m;axial bending moment(M0)of 0.1×10^17 to 2.2×10^17 N;effective elastic plate thickness seaward of the outer-rise region(Te^M)of 20 to 65 km,trench-ward of the outer-rise(Te^M)of 11 to 33 km,and the transition distance(Xr)of 20 to 95 km.The Horizon Deep,the second greatest trench depth in the world,has the greatest trench relief(W0 of 5.1km)and trench-axis loading(V0 of 2.2×10^12N/m);these values are only slightly smaller than that of the Challenger Deep(W0 of 5.7km and V0 of 2.9×10^12N/m)and similar to that of the Sirena Deep(W0 of 5.2 km and V0 of 2.0×10^12 N/m)of the Mariana Trench,suggesting that these deeps are linked to great flexural bending of the subducting plates.Analyses using three independent methods,i.e.,the/inversion,the flexural curvature/yield strength envelope analysis,and the elasto-plastic bending model with normal faults,all yielded similar average Te reduction of 28%-36% and average Te reduction area S△Te of 1195-1402 km^2 near the trench axis.The calculated brittle yield zone depth from the flexural curvature/yield strength envelope analysis is also consistent with the distribution of the observed normal faulting earthquakes.Comparisons of the Manila,Philippine,Tonga-Kermadec,Japan,and Mariana Trenches revealed that the average values Te^M of Te^M and both in general increase with the subducting plate age.展开更多
To investigate the effect of higher modes on the displacement and inner forces in HWBB(hinged wall with buckling-restrained braces in base)-frame structure,distributed parameter models for both the HWBB-hinged frame s...To investigate the effect of higher modes on the displacement and inner forces in HWBB(hinged wall with buckling-restrained braces in base)-frame structure,distributed parameter models for both the HWBB-hinged frame structure and the HWBB-MRF(moment resisting frame)structure are built.The hinged wall is simplified as a flexural beam.BRBs(bucking-restrained braces)are simplified to a rotational spring.MRF is simplified to a shear beam.Vibration equations of distributed parameter models are derived.Natural periods,natural modes of vibration,inner forces and displacements of the distributed parameter models are derived based on the vibration equations using numerical methods.The effect of the relative stiffness ratio and the rotational stiffness ratio on the higher mode effects is investigated.For elastic structures,the global displacement and shear in MRF are predominantly controlled by the first mode,while the shear and bending moment in the wall are significantly affected by higher mode effects.The effect of the yielding of BRB on the inner forces distribution in the HWBB-hinged frame is investigated.The results indicate that the first mode will no longer contribute to the inner forces and the contribution from higher modes to inner forces increases after the BRBs yield.Displacement is not sensitive to higher mode effects and it is controlled by the first mode after the BRBs yield.Parameter analysis demonstrates that the displacement amplitudes are reduced with the increase in the flexural stiffness of the wall before the flexural stiffness reaches a certain value.The first three periods decrease with the increase in the rotational stiffness.With the increase in the rotational stiffness ratio,the contribution from the first mode decreases while contributions from both the second mode and third mode increase.展开更多
Concrete Filled FRP （Reinforced Polymeric Plastic） Tubes （CFFT） and Reinforced Concrete Filled FRP Tubes （RCFFT） are known to have the capability to enhance structural performance in terms of structural stabilit...Concrete Filled FRP （Reinforced Polymeric Plastic） Tubes （CFFT） and Reinforced Concrete Filled FRP Tubes （RCFFT） are known to have the capability to enhance structural performance in terms of structural stability, ductility, as well as chemical resistance when compared with conventional concrete members. In this study, the authors evaluate the structural performance of the CFFT and the RCFFT through flexural tests for the purpose of applying the members as flexural ones. Moreover, the compressive behavior of the CFFT and the RCFFT members was investigated to examine their confinement effects. Based on the experimental and analytical results of the compressive behavior of the members, equations for estimating the ultimate compressive strengths of the CFFT and the RCFFT were proposed. In addition, the degree of improvement on the flexural performance of the RCFFT member strengthened by the FRP was analyzed from the flexural tests.展开更多
In the case of composite girders, an effective cooperation of both parts of the section is influenced by deformability of connectors. Limited flexural stiffness of welded studs, used commonly in bridge structures, doe...In the case of composite girders, an effective cooperation of both parts of the section is influenced by deformability of connectors. Limited flexural stiffness of welded studs, used commonly in bridge structures, does not provide full interaction of a steel beam and a concrete slab. This changes strain distribution in cross-sections of a composite girder and results in redistribution of internal forces in steel and concrete element. In the paper partial interaction index defined on the basis of a neutral axis position, which can be used for verification of steel-concrete interaction in real bridge structures rather than in specimens is proposed. The range of the index value changes, obtained during load testing of a typical steel-concrete composite beam bridge, is presented. The investigation was carried out on a motorway viaduct, consisting of two parallel structures. During the testing values of strains in girders under static and quasi-static loads were measured. The readings from the gauges were used to determine the index, characterizing composite action of the girders. Results of bridge testing under movable load, changing position along the bridge span is presented and obtained in-situ influence functions of strains and index values are commented in the paper.展开更多
基金supported by the National Natural Science Foundation of China(Nos.22235006 and 22475157)Foundation of Hubei Scientific Committee(Nos.2024 AFA021 and 2024BAB014)Fundamental Research Funds for the Central Universities(No.2042025kf0009)。
文摘One of the most significant challenges in commercializing organic second-order nonlinear optical(NLO)materials lies in the inherent trade-off between nonlinearity and stability.A key factor in mitigating this compromise is achieving precise temporal synchronization between the formation of the cross-linked network and the establishment of an optimal non-centrosymmetric alignment of the chromophores.Guided by this principle,we developed a series of NLO polymers incorporating multiple ether chains with low rotational energy barriers,which facilitate molecular reorientation during electric field poling,thereby enhancing the NLO response effectively.Combined with an optimized photocrosslinking strategy,the resulting PX4o/PETMP doped film achieved large macroscopic NLO coefficient of 190 pm·V^(-1)and thermal degradation temperature as high as 120℃.This work offers a universal approach to alleviating the“nonlinearity-stability”trade-off in a wide range of polymeric systems.
基金National Natural Science Foundation of China under Grant Nos.51622803 and 51708064the National Key Research and Development Program of China under Grant No.2016YFE0200100
文摘The second-order effect of axial force on horizontal vibrating characteristics of a large-diameter pipe pile is theoretically investigated.Governing equations of the pile-soil system are established based on elastodynamics.Threedimensional wave equations of soil are decoupled through differential transformation and variable separation.Consequently,expressions of soil displacements and horizontal resistances can be obtained.An analytical solution of the pile is derived based on continuity conditions between the pile and soil,subsequently from which expressions of the complex impedances are deduced.Analyses are carried out to examine the second-order effect of axial force on the horizontal vibrating behavior of the pipe pile.Some conclusions can be summarized as follows： stiffness and damping factors are decreased with the application of axial force on the pile head; distributions of the pile horizontal displacement and rotation angle are regenerated due to the second-order effect of the applied axial force; and redistributions of the bending moment and shearing force occur due to the second-order effect of the applied axial force.
基金supported by National Natural Science Foundation of China(21401147)Basic Research Program of Natural Science from Shaanxi Provincial Government(2015JQ2032)+2 种基金Scientific Research Program from Education Department of Shaanxi Provincial Government(2013JK0654)Opening Foundation from State Key Laboratory of Coordination Chemistry in Nanjing University(201219)the Program for Distinguished Young Scholars of Xi’an Polytechnic University(201403)
文摘A chiral lanthanide metal-organic framework based on enantiopure camphoric acid （D-H2cam）, [Nd3（D-cam）8（H2O）4Cl]n （1）, has been synthesized and characterized by single-crystal X-ray structural analysis, elemental analysis, IR, thermal gravimetric, and X-ray powder diffraction. Crystal data for the title compound are as follows： orthorhombic system, space group P212121 with a = 13.8287（7）, b = 14.0715（7）, c = 25.7403（12） A^°, V = 5008.8（4） A^°3, Mr = 1333.08, Z = 4, F（000） = 2644, Dc = 1.768 g/cm^3, μ（MoKα） = 3.189 mm^-1, the final R = 0.0351 and wR = 0.0814 （I 〉 2σ（I））. Compound 1 displays an 8-connected bcu topology 3D framework and hydrogen-bonding interactions stabilize the solid-state structure. The vibrational circular dichroism （VCD） spectrum and second-order nonlinear optical effect of compound 1 have been studied in the solid state.
文摘In this paper,we investigate the photon correlations and the statistical properties of light produced by an optical cavity with an embedded quantum well interacting with squeezed light.We show that the squeezed source substantially improves the intensity of the emitted light and generates a narrowing and a duplication of the spectrum peaks.With a strong dependence on frequency detuning,the cavity produces considerably squeezed radiation,and perfect squeezing is predicted for weak light–matter interactions.Furthermore,the system under consideration presents a bunching effect of the transmitted radiation resulting from weak pumping of the coherent field.The results obtained may have potential applications in the fields of very accurate measurement and quantum computing.
基金Supported by the Key Scientific Research Plan of Colleges and Universities in Henan Province(23B140006)the National Natural Science Foundation of China(11965017)。
文摘We theoretically study the effect of Kerr effect on the second-order nonlinearity induced transparency in a double-resonant optical cavity system.We show that in the presence of the Kerr effect,as the strength of the Kerr effect increases,the absorption curve exhibits an asymmetric-symmetric-asymmetric transition,and the zero absorption point shifts with the increase of the Kerr effect.Furthermore,by changing the strength of the Kerr effect,we can control the width of the transparent window,and the position of the zero-absorption point and meanwhile change the left and right width of the absorption peak.The asymmetry absorption curve can be employed to improve the quality factor of the cavity when the frequency detuning is tuned to be around the right peak.The simple dependence of the zeroabsorption point on the strength of Kerr effect suggests that the strength of Kerr effect can be measured by measuring the position of the zero-absorption point in a possible application.
文摘Dynamic equations of motional flexible beam elements were derived considering second-order effect. Non-linear finite element method and three-node Euler-Bernoulli beam elements were used. Because accuracy is higher in non-linear structural analysis,three-node beam elements are used to deduce shape functions and stiffness matrices in dynamic equations of flexible elements. Static condensation method was used to obtain the finial dynamic equations of three-node beam elements. According to geometrical relations of nodal displacements in concomitant and global coordinate system,dynamic equations of elements can be transformed to global coordinate system by concomitant coordinate method in order to build the global dynamic equations. Analyzed amplitude condition of flexible arm support of a port crane,the results show that second-order effect should be considered in kinetic-elastic analysis for heavy load machinery of big flexibility.
基金Project supported by the National Key Research and Decelopment Program of China(Grant No.2021YFB3500302)the National Natural Science Foundation of China(Grant Nos.U22A20116 and 52371200)the Innovation Capability Improvement Project of Hebei Province,China(Grant No.22567605H)。
文摘Large magnetic entropy change(△S_(M))can realize a prominent heat transformation under the magnetic field and directly strengthen the efficacy of the magnetocaloric effect,which provides a pioneering environmentally friendly solidstate strategy to improve refrigeration capacities and efficiencies.The second-order magnetic transition(SOMT)materials have broader△S_(M) peaks without thermal hysteresis,making them highly attractive in magnetic refrigeration,especially in the room temperature range.Here,we report a significant enhancement of△S_(M) at room temperature in single-crystal Mn_(5)Ge_(3).In this SOMT system,we realize a 60%improvement of-△S_(M)^(max) from 3.5 J/kg·K to 5.6 J/kg·K at T=300 K.This considerable enhancement of△S_(M) is achieved by intentionally introducing strain energy through high-pressure constrained deformation.Both experimental results and Monte Carlo simulations demonstrate that the enhancement of△S_(M) originates from the microscopic strain and lattice deformation induced by strain energy after deformation.This strain energy will reconstruct the energy landscape of this ferromagnetic system and enhance magnetization,resulting in a giant intensity of magnetocaloric responses.Our findings provide an approach to increase magnetic entropy change and may give fresh ideas for exploring advanced magnetocaloric materials.
文摘A novel transition appeared above thc glass transition temperature of chlorinated polyethylene (CPE) for binaryblends of CPE and additives such as organic small molecules or oligomers. This transition was assigned to the dissociation ofintermolecular hydrogen bonds between the polymer ard additive within the edditive rich phase. Of particular interest is thata novel pyramid crystal was observed in the annealed CPE/hindered phenol blends. Another intriguing observation is thatthese polymer/small molecule blends organized by intermolecular hydrogen bonding have several potential properties, suchas shape-memorization, self-restoration, self-adhesiveness and super damping.
文摘Multifunctional hybrid polymer composites were projected as novel solutions to meet the demands in various industrial applications ranging from automotive to aerospace. This investigation focuses on processing, flexural strength and fracture toughness characterization of the glass fabric reinforced epoxy (G-E) composites and graphite/fly ash cenosphere (FAC) modified interface between the epoxy matrix and glass fabric. Hand lay-up followed by compression moulding method was used to fabricate the laminates. Flexural and fracture toughness tests at room temperature, elevated temperature and cryogenic temperature were conducted to assess the flexural strength (FS) and mode-I plane-strain fracture toughness (K<sub>IC</sub>). The experimental and characterization efforts suggest that both graphite and FAC fillers improve bonding at the interface. The study showed that the graphite is more favorable for enhancing FS and KIC of G-E composites. Graphite filled G-E hybrid composites with significant FS and KIC to that of unfilled and FA filled G-E were successfully achieved by incorporating 10 wt% graphite. The incorporation of fillers resulted in improvement of FS, which increased by 43% and 37.7% for 10Gr+G-E and 10FAC+G-E hybrid composites respectively. All composites show a 26% improvement in KIC at cryogenic temperature and a decrease of 12.5% at elevated temperature. According to the SEM observations, fiber debonding from the matrix is suppressed due to the presence and uniform distribution of graphite. In addition, micro-pores, matrix shearing, active toughening mechanisms induced by graphite, such as crack deflection, layer breakage and delamination of graphite layers contributed to the enhanced KIC of hybrid G-E composites.
文摘We investigated the magnetocaloric effect in commercial Er_(2)O_(3) powders which presents almost no hysteresis losses at low temperature.At a magnetic field change of 5 T,it displays large magnetic entropy change(-ΔSM)max of 15.02 J/(kg·K)and a refrigerant capacity(RC)of 311 J/K at Neel temperature TN=3.32 K.The magnetic transition was found to be of a second-order.The maximum values of adiabatic temperature change(ΔTad)max reach 0.70 K for a magnetic field change of 1 T.The large value,of(-ASM)max as well as no hysteresis loss,makes Er_(2)O_(3) a promising material as a magnetic refrigerant at low temperature.
基金The National Natural Science Foundation of China under contract Nos 41976064,91958211,41890813,91858207,91628301,U1606401,41976066 and 41706056the Programs of the Chinese Academy of Sciences under contract Nos Y4SL021001,QYZDY-SSW-DQC005 and 133244KYSB20180029+1 种基金the National Key Research and Development Program of China under contract Nos2018YFC0309800 and 2018YFC0310100the China Ocean Mineral Resources R&D Association under contract No.DY135-S2-1-04
文摘We conducted a detailed analysis of along-trench variations in the flexural bending of the subducting Pacific Plate at the Tonga-Kermadec Trench.Inversions were conducted to obtain best-fitting solutions of trench-axis loadings and variations in the effective elastic plate thickness for the analyzed flexural bending profiles.Results of the analyses revealed significant along-trench variations in plate flexural bending:the trench relief(W0)of 1.9 to 5.1 km;trench-axis vertical loading(V0)of-0.5×10^12 to 2.2×10^12 N/m;axial bending moment(M0)of 0.1×10^17 to 2.2×10^17 N;effective elastic plate thickness seaward of the outer-rise region(Te^M)of 20 to 65 km,trench-ward of the outer-rise(Te^M)of 11 to 33 km,and the transition distance(Xr)of 20 to 95 km.The Horizon Deep,the second greatest trench depth in the world,has the greatest trench relief(W0 of 5.1km)and trench-axis loading(V0 of 2.2×10^12N/m);these values are only slightly smaller than that of the Challenger Deep(W0 of 5.7km and V0 of 2.9×10^12N/m)and similar to that of the Sirena Deep(W0 of 5.2 km and V0 of 2.0×10^12 N/m)of the Mariana Trench,suggesting that these deeps are linked to great flexural bending of the subducting plates.Analyses using three independent methods,i.e.,the/inversion,the flexural curvature/yield strength envelope analysis,and the elasto-plastic bending model with normal faults,all yielded similar average Te reduction of 28%-36% and average Te reduction area S△Te of 1195-1402 km^2 near the trench axis.The calculated brittle yield zone depth from the flexural curvature/yield strength envelope analysis is also consistent with the distribution of the observed normal faulting earthquakes.Comparisons of the Manila,Philippine,Tonga-Kermadec,Japan,and Mariana Trenches revealed that the average values Te^M of Te^M and both in general increase with the subducting plate age.
基金The National Key Research and Development Program of China(No.2018YFC0705802)the National Natural Science Foundation of China(No.51978165)+1 种基金the Fundamental Research Funds for the Central Universities(No.3205007720)Postgraduate Research and Practice Innovation Program of Jiangsu Province(No.3205007720).
文摘To investigate the effect of higher modes on the displacement and inner forces in HWBB(hinged wall with buckling-restrained braces in base)-frame structure,distributed parameter models for both the HWBB-hinged frame structure and the HWBB-MRF(moment resisting frame)structure are built.The hinged wall is simplified as a flexural beam.BRBs(bucking-restrained braces)are simplified to a rotational spring.MRF is simplified to a shear beam.Vibration equations of distributed parameter models are derived.Natural periods,natural modes of vibration,inner forces and displacements of the distributed parameter models are derived based on the vibration equations using numerical methods.The effect of the relative stiffness ratio and the rotational stiffness ratio on the higher mode effects is investigated.For elastic structures,the global displacement and shear in MRF are predominantly controlled by the first mode,while the shear and bending moment in the wall are significantly affected by higher mode effects.The effect of the yielding of BRB on the inner forces distribution in the HWBB-hinged frame is investigated.The results indicate that the first mode will no longer contribute to the inner forces and the contribution from higher modes to inner forces increases after the BRBs yield.Displacement is not sensitive to higher mode effects and it is controlled by the first mode after the BRBs yield.Parameter analysis demonstrates that the displacement amplitudes are reduced with the increase in the flexural stiffness of the wall before the flexural stiffness reaches a certain value.The first three periods decrease with the increase in the rotational stiffness.With the increase in the rotational stiffness ratio,the contribution from the first mode decreases while contributions from both the second mode and third mode increase.
文摘Concrete Filled FRP （Reinforced Polymeric Plastic） Tubes （CFFT） and Reinforced Concrete Filled FRP Tubes （RCFFT） are known to have the capability to enhance structural performance in terms of structural stability, ductility, as well as chemical resistance when compared with conventional concrete members. In this study, the authors evaluate the structural performance of the CFFT and the RCFFT through flexural tests for the purpose of applying the members as flexural ones. Moreover, the compressive behavior of the CFFT and the RCFFT members was investigated to examine their confinement effects. Based on the experimental and analytical results of the compressive behavior of the members, equations for estimating the ultimate compressive strengths of the CFFT and the RCFFT were proposed. In addition, the degree of improvement on the flexural performance of the RCFFT member strengthened by the FRP was analyzed from the flexural tests.
文摘In the case of composite girders, an effective cooperation of both parts of the section is influenced by deformability of connectors. Limited flexural stiffness of welded studs, used commonly in bridge structures, does not provide full interaction of a steel beam and a concrete slab. This changes strain distribution in cross-sections of a composite girder and results in redistribution of internal forces in steel and concrete element. In the paper partial interaction index defined on the basis of a neutral axis position, which can be used for verification of steel-concrete interaction in real bridge structures rather than in specimens is proposed. The range of the index value changes, obtained during load testing of a typical steel-concrete composite beam bridge, is presented. The investigation was carried out on a motorway viaduct, consisting of two parallel structures. During the testing values of strains in girders under static and quasi-static loads were measured. The readings from the gauges were used to determine the index, characterizing composite action of the girders. Results of bridge testing under movable load, changing position along the bridge span is presented and obtained in-situ influence functions of strains and index values are commented in the paper.
