Micro-grinding has been widely used in aerospace and other industry.However,the small diameter of the micro-grinding tool has limited its machining performance and efficiency.In order to solve the above problems,micro...Micro-grinding has been widely used in aerospace and other industry.However,the small diameter of the micro-grinding tool has limited its machining performance and efficiency.In order to solve the above problems,micro-structure has been applied on the micro-grinding tool.A morphology modeling has been established in this study to characterize the surface of microstructured micro-grinding tool,and the grinding performance of micro-structured micro-grinding tool has been analyzed through undeformed chip thickness,abrasive edge width,and effective distance between abrasives.Then deviation analysis,path optimization and parameter optimization of microchannel array precision grinding have been finished to improve processing quality and efficiency,and the deflection angle has the most obvious effects on the rectangular slot depth,micro-structured micro-grinding tool could reduce 10%surface roughness and 20%grinding force compared to original micro-grinding tool.Finally,the microchannel array has been machined with a size deviation of 2μm and surface roughness of 0.2μm.展开更多
High-performance 24CrNiMo steel was fabricated using Laser Powder Bed Fusion (LPBF). Subsequent quenching treatment was applied and the influence of quenching temperatures on micro-structure evolution and properties w...High-performance 24CrNiMo steel was fabricated using Laser Powder Bed Fusion (LPBF). Subsequent quenching treatment was applied and the influence of quenching temperatures on micro-structure evolution and properties was systematically characterised and analysed. The micro-structure of the as-built steel consisted of two parts. The first part comprised martensite with twins combined with ω-Fe nano-particles, and the second part consisted of lower bainite in the molten pool, as well as upper bainite, granular bainite and tempered martensite in the heat-affected zone. With the quenching temperatures varying from 800℃ to 950℃, the micro-structure gradually transformed from acicular ferrite + martensite to tempered martensite +θ-Fe3C carbides, and the grain size exhibited noticeable growth. Moreover, quenching treatments could eliminate the anisotropy and inhomogeneity of the micro-structure. The rod-shaped nanosized η-Fe2C and θ-Fe3C precipitates were clearly observed, which were converted from ω-Fe and distributed at multiple angles in the lath. The size and number of nano-precipitates, triggered by the high self-tempering degree of martensite, gradually increased. The relationships among grain size, the twins, dislocation density and nano-precipitation and the dramatically improved performance of quenched samples were analysed using strengthening mechanisms. After quenching at 850℃, the as-built 24CrNiMo steel attained ultra-high mechanical properties including hardness, Ultimate Tensile Strength (UTS), Elongation (El) and impact energy with values of 480.9 HV_(1), 1611.4 MPa, 9.8% and 42.8 J, respectively. Meanwhile, both the wear and thermal fatigue resistance increased by approximately 40%. This study demonstrated that LPBF-fabricated 24CrNiMo steel, with matching good performances, can be achieved using a subsequent one-step quenching process.展开更多
Next-generation fire safety systems demand precise detection and motion recognition of flames.In-sensor computing,which integrates sensing,memory,and processing capabilities,has emerged as a key technology in flame de...Next-generation fire safety systems demand precise detection and motion recognition of flames.In-sensor computing,which integrates sensing,memory,and processing capabilities,has emerged as a key technology in flame detection.However,the implementation of hardware-level functional demonstrations based on artificial vision systems in the solar-blind ultraviolet(UV)band(200-280 nm)is hindered by the weak detection capability.Here,we propose Ga_(2)O_(3)/In_(2)Se_(3) heterojunctions for the ferroelectric(abbreviation:Fe)optoelectronic sensor(abbreviation:OES)array(5×5 pixels),which is capable of ultraweak UV light detection with an ultrahigh detectivity through ferroelectric regulation and features in configurable multimode functionality.The Fe-OES array can directly sense different flame motions and simulate the non-spiking gradient neurons of insect visual system.Moreover,the flame signal can be effectively amplified in combination with leaky integration-and-fire neuron hardware.Using this Fe-OES system and neuromorphic hardware,we successfully demonstrate three flame processing tasks:achieving efficient flame detection across all time periods with terminal and cloud-based alarms;flame motion recognition with a lightweight convolutional neural network achieving 96.47%accuracy;and flame light recognition with 90.51%accuracy by means of a photosensitive artificial neural system.This work provides effective tools and approaches for addressing a variety of complex flame detection tasks.展开更多
MPHPB was prepared from melamine,phenylphosphonic acid and boric acid,and its flame retardant effect in PE was investigated.Compared to the intermediate product(melamine phenyl hypophosphite(MPHP)),the residual char i...MPHPB was prepared from melamine,phenylphosphonic acid and boric acid,and its flame retardant effect in PE was investigated.Compared to the intermediate product(melamine phenyl hypophosphite(MPHP)),the residual char increased from 17.9% of MPHP to 41.2% of MPHPB at 800℃.The limiting oxygen index(LOI)of PE/20%MPHPB is 23.6%,which reaches V-0 rating.After the addition of 20%MPHPB,the total heat release(THR),peak heat release rate(pK-HRR),and average effective thermal combustion rates(av-EHC)of PE decreased.Additionally,characterizations including the pyrolysis gas chromatography-mass spectrometry(Py-GC-MS),scanning electron microscopy(SEM),raman spectroscopy test(LRS)and fourier transform infrared(FT-IR)were taken to investigate the flame retardant mechanism,and the results show that MPHPB plays roles in both gas and condensed phases.展开更多
By combining the merits of radiative cooling(RC)and evaporation cooling(EC),radiative coupled evaporative cooling(REC)has attracted considerable attention for sub-ambient cooling purposes.However,for outdoor devices,t...By combining the merits of radiative cooling(RC)and evaporation cooling(EC),radiative coupled evaporative cooling(REC)has attracted considerable attention for sub-ambient cooling purposes.However,for outdoor devices,the interior heating power would increase the working temperature and fire risk,which would suppress their above-ambient heat dissipation capabilities and passive water cycle properties.In this work,we introduced a REC design based on an all-in-one photonic hydrogel for above-ambient heat dissipation and flame retardancy.Unlike conventional design RC film for heat dissipation with limited cooling power and fire risk,REC hydrogel can greatly improve the heat dissipation performance in the daytime with a high workload,indicating a 12.0℃lower temperature than the RC film under the same conditions in the outdoor experiment.In the nighttime with a low workload,RC-assisted adsorption can improve atmospheric water harvesting to ensure EC in the daytime.In addition,our REC hydrogel significantly enhanced flame retardancy by absorbing heat without a corresponding temperature rise,thus mitigating fire risks.Thus,our design shows a promising solution for the thermal management of outdoor devices,delivering outstanding performance in both heat dissipation and flame retardancy.展开更多
Although poly(urethane-urea)elastomers(PUEs)possess excellent mechanical properties and durability,their inherent flammability and inability to self-repair after damage significantly limits their applications in high-...Although poly(urethane-urea)elastomers(PUEs)possess excellent mechanical properties and durability,their inherent flammability and inability to self-repair after damage significantly limits their applications in high-end fields.To address this challenge,this study employs a supramolecular chemistry approach by simultaneously incorporating multiple hydrogen bonds as dynamic cross-linking points and a phosphorus-nitrogen synergistic flame-retardant structure into the poly(urethane-urea)network.The multiple hydrogen bonds endow the material with efficient intrinsic self-healing capability,while the phosphorus-nitrogen flame retardant ensures outstanding thermal stability and flame resistance,leading to the successful synthesis of a high-performance multifunctional poly(urethane-urea)elastomer.Experimental results demonstrated that when the content of the flame retardant diethyl(2-((2-aminoethyl)amino)ethyl)phosphoramidate(DEPTA)was 10 wt%,the resulting PUE/10%DEPTA achieved a V-0 rating in the vertical burning test,with a limiting oxygen index(LOI)of 30%.Concurrently,the elastomer maintained good toughness,exhibiting a tensile strength of 27.3 MPa,an elongation at break of 601%,and a self-healing efficiency of up to 94.46%.This breakthrough shows significant promise for advanced engineering applications that demand fire safety,structural durability,and extended service life through self-repair.展开更多
Bio-based 2,5-furandicarboxylic acid polyesters offer significant promise for reducing energy and environmental crises.However,their intrinsic flammability remains a critical limitation,and conventional flame-retardan...Bio-based 2,5-furandicarboxylic acid polyesters offer significant promise for reducing energy and environmental crises.However,their intrinsic flammability remains a critical limitation,and conventional flame-retardant strategies often compromise their mechanical properties,hindering their practical applications.Herein,a 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide(DOPO)-based comonomer(DDP)was used to synthesize flame-retardant poly(ethylene furandicarboxylate-co-phosphaphenanthrene)(PEFDn).The covalent integration of DDP confers intrinsic flame retardancy,avoiding the plasticization and migration issues associated with additive-type systems.Upon thermal decomposition,the DOPO-derived moieties release phosphoric acid and radical scavengers,promoting char formation and suppressing flame propagation.Furthermore,density functional theory(DFT)calculations combined with non-covalent interaction(NCI)analysis revealed that DOPO dimer molecules adopt a stable parallel-displaced π-π stacking configu ration,potentially facilitating microphase separation and enhancing the energy dissipation capability.PEFD_(10)achieves a UL-94 V-0 rating while simultaneously increasing impact toughness from 1.5 kJ/m^(2) to 14.7 kJ/m^(2).Im portantly,PEFDn maintained acceptable oxygen-barrier properties.PEFD10 also exhibited high transparency and UV-shielding performance.The combination of intrinsic flame safety,im pact-toughness resistance,UV shielding,and an oxygen barrier ensures reliable protection of electrical components and long-term operational stability.The integration of multiple critical properties within a single bio-based material represents a novel approach fo r enabling sustainable polymer solutions for high-pe rformance electrical applications.展开更多
Driven by the increasing demand for high-energy-density batteries in electric vehicles and portable electronics,lithium metal batteries have made significant breakthroughs[1–3].While critical challenges associated wi...Driven by the increasing demand for high-energy-density batteries in electric vehicles and portable electronics,lithium metal batteries have made significant breakthroughs[1–3].While critical challenges associated with lithium metal anodes in liquid electrolytes(e.g.,dendrite growth,interface instability)have hindered commercialization[4–6],solid electrolyte systems have shown promise in mitigating these issues.Among these,solid polymer electrolytes(SPEs)have emerged as a viable solution for enabling stable quasisolid-state lithium metal batteries[7–9].展开更多
In order to investigate a gradient nano/micro-structured surface layer on pure copper produced by severe plasticity roller burnishing （SPRB） and grain refinement mechanism, the microstructure characteristics and mat...In order to investigate a gradient nano/micro-structured surface layer on pure copper produced by severe plasticity roller burnishing （SPRB） and grain refinement mechanism, the microstructure characteristics and material properties of sample at various depths from the topmost surface were investigated by SEM, TEM, XRD, OM etc. The experimental results show that the gradient nano/micro-structure was introduced into the surface layer of over 100μm in thickness. The remarkable increase in hardness near the topmost surface was mainly attributed to the reduced grain size. The equiaxed nano-sized grains were in random orientation and the most of their boundaries were low-angle grain boundaries （LAGBs）. The coarse grains are refined into the few micro-sized grains by dislocation activities;deformation twinning was found to be the primary form for the formation of submicron grains;the formation of nanostructure was dominated by dislocation activities accompanied with rotation of grains in local region.展开更多
Nowadays,the superior detection performance of semiconductor neutron detectors is a challenging task.In this paper,we deal with a novel GaN micro-structured neutron detector(GaN-MSND)and compare three different method...Nowadays,the superior detection performance of semiconductor neutron detectors is a challenging task.In this paper,we deal with a novel GaN micro-structured neutron detector(GaN-MSND)and compare three different methods such as the method of modulating the trench depth,the method of introducing dielectric layer and p-type inversion region to improve the width of depletion region(W).It is observed that the intensity of electric field can be modulated by scaling the trench depth.On the other hand,the electron blocking region is formed in the detector enveloped with a dielectric layer.Furthermore,the introducing of p-type inversion region produces new p/n junction,which not only promotes the further expansion of the depletion region but also reduces the intensity of electric field produced by main junction.It can be realized that all these methods can considerably enhance the working voltage as well as W.Of them,the improvement on W of GaN-MSND with the p-type inversion region is the most significant and the value of W could reach 12.8μm when the carrier concentration of p-type inversion region is 10^17 cm^-3.Consequently,the value of W is observed to improve 200%for the designed GaN-MSND as compared with that without additional design.This work ensures to the researchers and scientific community the fabrication of GaN-MSND having superior detection limit in the field of intense radiation.展开更多
In this paper,we report the study of the process of fabricating a multi-layermetal micro-structure using UV-LIGA overlay technology,includingmask fabrication,substrate treatment,and UV-LIGA overlay processes.To solve ...In this paper,we report the study of the process of fabricating a multi-layermetal micro-structure using UV-LIGA overlay technology,includingmask fabrication,substrate treatment,and UV-LIGA overlay processes.To solve the process problems in the masking procedure,the swelling problemof the first layer of SU-8 thick photoresist was studied experimentally.The 5μmline-width compensation and closed 20μmand 30μmisolation strips were designed and fabricated around the micro-structure pattern.The pore problemin the Ni micro-electroforming layer was analyzed and the electroforming parameters were improved.The pH value of the electroforming solution should be controlled between 3.8 and 4.4 and the current density should be below 3 A/dm^2.To solve the problems of high inner stress and incomplete development of the micro-cylinder hole array with a diameter of 30μm,the lithography process was optimized.The pre-baking temperature was increased via gradient heating and rose every 5℃ from 65℃ to 85℃ and then remained at 85℃ for 50 min–1 h.In addition,the full contact exposure was used.Finally,a multi-layer metal micro-structure with high precision and good quality of microelectroforming layer was fabricated using UV-LIGA overlay technology.展开更多
A low-power CO_2 laser is used to deposit Fe powder and mixture of Fe andcarbon powder on substrates respectively, and the macro and micro-structure of the formed samplesare investigated. It is demonstrated that most ...A low-power CO_2 laser is used to deposit Fe powder and mixture of Fe andcarbon powder on substrates respectively, and the macro and micro-structure of the formed samplesare investigated. It is demonstrated that most grains of these samples are equi-axed. This isderived from the high nucleation velocity in the shallow melt pool besides rapid solidification ofthe liquid-state alloy or metal. Bainitic structure, combination of pearlite and ferrite structureand ferrite structure are seen respectively in the samples involving various amounts of carbon owingto no martensitic transformation in these small samples.展开更多
To obtain the form error of micro-structured surfaces robustly and accurately, a form er- ror evaluation method was developed based on the real coded genetic algorithm （RCGA）. The meth- od employed the average squar...To obtain the form error of micro-structured surfaces robustly and accurately, a form er- ror evaluation method was developed based on the real coded genetic algorithm （RCGA）. The meth- od employed the average squared distance as the matching criterion. The point to surface distance was achieved by use of iterative method and the modeling of RCGA for the surface matching was also presented in detail. Parameter selection for RCGA including the crossover rate and population size was discussed. Evaluation results of series simulated surfaces without form error show that this method can achieve the accuracy of root mean square deviation （ Sq ） less than 1 nm and surface pro- file error （ St ） less than 4 nm. Evaluation of the surfaces with different simulated errors illustrates that the proposed method can also robustly obtain the form error with nano-meter precision. The e- valuation of actual measured surfaces further indicates that the proposed method is capable of pre- cisely evaluating micro-structured surfaces.展开更多
Ni-rich layered material is a kind of high-capacity cathode to meet the requirement of electric vehicles.As for the typical LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) material,the particle formation is significant for electroche...Ni-rich layered material is a kind of high-capacity cathode to meet the requirement of electric vehicles.As for the typical LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) material,the particle formation is significant for electrochemical properties of the cathode.In this work,the structure,morphology,and electrochemical performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) secondary particles and single crystals were systematically studied.A lower Ni^(2+)/Ni^(3+)molar ratio of 0.66 and a lower residual alkali content of 0.228wt%were achieved on the surface of the single crystals.In addition,the single crystals showed a discharge capacity of 191.6 mAh/g at 0.2 C(~12 mAh/g lower than that of the secondary particles)and enhanced the electrochemical stability,especially when cycled at 50℃ and in a wider electrochemical window(between 3.0 and 4.4 V vs.Li+/Li).The LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) secondary particles were suitable for applications requiring high specific capacity,whereas single crystals exhibited better stability,indicating that they are more suitable for use in long life requested devices.展开更多
Adopting a nano-and micro-structuring approach to fully unleashing the genuine potential of electrode active material benefits in-depth understandings and research progress toward higher energy density electrochemical...Adopting a nano-and micro-structuring approach to fully unleashing the genuine potential of electrode active material benefits in-depth understandings and research progress toward higher energy density electrochemical energy stor-age devices at all technology readiness levels.Due to various challenging issues,especially limited stability,nano-and micro-structured(NMS)electrodes undergo fast electrochemical performance degradation.The emerging NMS scaffold design is a pivotal aspect of many electrodes as it endows them with both robustness and electrochemical performance enhancement,even though it only occupies comple-mentary and facilitating components for the main mechanism.However,extensive efforts are urgently needed toward optimizing the stereoscopic geometrical design of NMS scaffolds to minimize the volume ratio and maximize their functionality to fulfill the ever-increasing dependency and desire for energy power source supplies.This review will aim at highlighting these NMS scaffold design strategies,summariz-ing their corresponding strengths and challenges,and thereby outlining the potential solutions to resolve these challenges,design principles,and key perspectives for future research in this field.Therefore,this review will be one of the earliest reviews from this viewpoint.展开更多
The sub-vertical meso-and micro-structures and fabrics developed in coesite-bearing foliated eclogites in the Taohang （桃行） area, southeastern Shandong （山东）, China. The diagnostic structures and fabrics, includ...The sub-vertical meso-and micro-structures and fabrics developed in coesite-bearing foliated eclogites in the Taohang （桃行） area, southeastern Shandong （山东）, China. The diagnostic structures and fabrics, including penetrative foliation or mylonitic foliation containing mineral and stretching lineations, as well as sheath-like folds, appear to be the development of anastomosing UHP eciogite-facies shear belt arrays hosting massive eelogites. Textural relationships and mineral assem-blages indicate that the deformation of foliated eclogites developed closely after the formation of the massive eclogite, prior to the development of the granulite/amphibolite-facies symplectites and coronas, occurring over a very wide pressure range of （31-8）×10^2 MPa. It presents the structural records of the tectonometamorphic processes as being responsible for the earliest stages of exhumation of the UHP metamorphic rocks. Extensive regional field observations show that the meso-and micro-structures and fabrics recognized in the foliated eclogites at Taohang are remarkably similar or consistent in the whole Dabie （大别）-Sulu （苏鲁） UHP metamorphic belt. This article, thus, supports the idea that the earliest stages of exhumation of the UHP metamorphic rocks, from mantle depths to the Moho or the mantle-crust boundary layering, may be attributed mainly to a sub-vertical extrusion and ductile flow along the subduction channel, belonging to a syn-collision exhumation at about 235 to 220 Ma.展开更多
A novel flower-like hydrated magnesium carbonate hydroxide, Mg5 （CO3 ）4 （OH）2·4H2O, with micro-structure composed of individual thin nano-sheets was synthesized using a facile solution route without the use o...A novel flower-like hydrated magnesium carbonate hydroxide, Mg5 （CO3 ）4 （OH）2·4H2O, with micro-structure composed of individual thin nano-sheets was synthesized using a facile solution route without the use of template or organic surfactant. Reaction time has an important effect on the final morphology of the product. The micro-structure and morphology of Mg5 （CO3）4 （OH）2·4H2O were characterized by means of X-ray diffractometry （XRD）, fieldemission scanning electron microscopy（FE-SEM）. Brunauer-Emmett-Teller（BET） surface areas of the samples were also measured. The probable formation mechanism of flower-like micro-structure was discussed. It was found that Mg5 （CO3）4（ OH）2·4H2O with flower-like micro-structure was a novel and efficient catalyst for the synthesis of diphenyl carbonate （DPC） by transesterification of dimethyl carbonate （DMC） with phenol.展开更多
In this article, the convection dominated convection-diffusion problems with the periodic micro-structure are discussed. A two-scale finite element scheme based on the homogenization technique for this kind of problem...In this article, the convection dominated convection-diffusion problems with the periodic micro-structure are discussed. A two-scale finite element scheme based on the homogenization technique for this kind of problems is provided. The error estimates between the exact solution and the approximation solution, of the homogenized equation or the two-scale finite element scheme are analyzed. It is shown that the scheme provided in this article is convergent for any fixed diffusion coefficient 5, and it may be convergent independent of δ under some conditions. The numerical results demonstrating the theoretical results are presented in this article.展开更多
A three-dimensional dynamic model for nano/micro-fabrications of silicon was presented. With the developed model, the fabrication process of silicon on nothing（SON） structure was quantitatively investigated. We empl...A three-dimensional dynamic model for nano/micro-fabrications of silicon was presented. With the developed model, the fabrication process of silicon on nothing（SON） structure was quantitatively investigated. We employ a diffuse interface model that incorporates the mechanism of surface diffusion. The mechanism of the fabrication is systematically integrated for high reliability of computational analysis. A semi-implicit Fourier spectral scheme is applied for high efficiency and numerical stability. Moreover, the theoretical analysis provides the guidance that is ordered by the fundamental geometrical design parameters to guide different fabrications of SON structures. The performed simulations suggest a substantial potential of the presented model for a reliable design technology of nano/micro-fabrications.展开更多
A new standard parametric modeling method of the micro-structure of plain woven composite is proposed. It is based on good analysis of the mechanical property of the yarn, weaving law of plain woven, and other factors...A new standard parametric modeling method of the micro-structure of plain woven composite is proposed. It is based on good analysis of the mechanical property of the yarn, weaving law of plain woven, and other factors. The method implements a woven fabric composite visual engineering modeling process standardization, and it gives five steps to calculate the key micro-structural parameters of the yarn including the cross-section and the trajectory of the central Line. On the basis, the digital model of a plain woven composite has been constructed. The experimental result shows that the forecast for the mechanical property of the model using finite-element simulation analysis is consistent with the actual value. The shape and the structure of the model are also consistent with the solid.展开更多
基金co-supported by the Enterprise Innovation and Development Joint Program of the National Natural Science Foundation of China(No.U20B2032)Open Project Funding of State Key Laboratory for High Performance Tools(GXNGJSKL-2024-08)+1 种基金Open Foundation of the State Key Laboratory of Intelligent Manufacturing Equipment and Technology(IMETKF2023005)Introduced Innovative Scientific Research Team Project of Zhongshan(the tenth batch)(CXTD2023008)。
文摘Micro-grinding has been widely used in aerospace and other industry.However,the small diameter of the micro-grinding tool has limited its machining performance and efficiency.In order to solve the above problems,micro-structure has been applied on the micro-grinding tool.A morphology modeling has been established in this study to characterize the surface of microstructured micro-grinding tool,and the grinding performance of micro-structured micro-grinding tool has been analyzed through undeformed chip thickness,abrasive edge width,and effective distance between abrasives.Then deviation analysis,path optimization and parameter optimization of microchannel array precision grinding have been finished to improve processing quality and efficiency,and the deflection angle has the most obvious effects on the rectangular slot depth,micro-structured micro-grinding tool could reduce 10%surface roughness and 20%grinding force compared to original micro-grinding tool.Finally,the microchannel array has been machined with a size deviation of 2μm and surface roughness of 0.2μm.
基金co-supported by the National Key Research and Development Program of China (No. 2022YFB4600500)the National Natural Science Foundation of China (No. 52235006)
文摘High-performance 24CrNiMo steel was fabricated using Laser Powder Bed Fusion (LPBF). Subsequent quenching treatment was applied and the influence of quenching temperatures on micro-structure evolution and properties was systematically characterised and analysed. The micro-structure of the as-built steel consisted of two parts. The first part comprised martensite with twins combined with ω-Fe nano-particles, and the second part consisted of lower bainite in the molten pool, as well as upper bainite, granular bainite and tempered martensite in the heat-affected zone. With the quenching temperatures varying from 800℃ to 950℃, the micro-structure gradually transformed from acicular ferrite + martensite to tempered martensite +θ-Fe3C carbides, and the grain size exhibited noticeable growth. Moreover, quenching treatments could eliminate the anisotropy and inhomogeneity of the micro-structure. The rod-shaped nanosized η-Fe2C and θ-Fe3C precipitates were clearly observed, which were converted from ω-Fe and distributed at multiple angles in the lath. The size and number of nano-precipitates, triggered by the high self-tempering degree of martensite, gradually increased. The relationships among grain size, the twins, dislocation density and nano-precipitation and the dramatically improved performance of quenched samples were analysed using strengthening mechanisms. After quenching at 850℃, the as-built 24CrNiMo steel attained ultra-high mechanical properties including hardness, Ultimate Tensile Strength (UTS), Elongation (El) and impact energy with values of 480.9 HV_(1), 1611.4 MPa, 9.8% and 42.8 J, respectively. Meanwhile, both the wear and thermal fatigue resistance increased by approximately 40%. This study demonstrated that LPBF-fabricated 24CrNiMo steel, with matching good performances, can be achieved using a subsequent one-step quenching process.
基金supported by the Major Program(JD)of Hubei Province under Grant No.2023BAA009the National Natural Science Foundation of China(Grant No.22105162)+1 种基金the Natural Science Foundation of Hubei Province(Grant No.2023AFB623)the Original Exploration Seed Fund of Hubei University。
文摘Next-generation fire safety systems demand precise detection and motion recognition of flames.In-sensor computing,which integrates sensing,memory,and processing capabilities,has emerged as a key technology in flame detection.However,the implementation of hardware-level functional demonstrations based on artificial vision systems in the solar-blind ultraviolet(UV)band(200-280 nm)is hindered by the weak detection capability.Here,we propose Ga_(2)O_(3)/In_(2)Se_(3) heterojunctions for the ferroelectric(abbreviation:Fe)optoelectronic sensor(abbreviation:OES)array(5×5 pixels),which is capable of ultraweak UV light detection with an ultrahigh detectivity through ferroelectric regulation and features in configurable multimode functionality.The Fe-OES array can directly sense different flame motions and simulate the non-spiking gradient neurons of insect visual system.Moreover,the flame signal can be effectively amplified in combination with leaky integration-and-fire neuron hardware.Using this Fe-OES system and neuromorphic hardware,we successfully demonstrate three flame processing tasks:achieving efficient flame detection across all time periods with terminal and cloud-based alarms;flame motion recognition with a lightweight convolutional neural network achieving 96.47%accuracy;and flame light recognition with 90.51%accuracy by means of a photosensitive artificial neural system.This work provides effective tools and approaches for addressing a variety of complex flame detection tasks.
基金Funded by the Natural Science Foundation of Guangdong(Nos.2014A030313241,2014B090901068,and 2016A010103003)。
文摘MPHPB was prepared from melamine,phenylphosphonic acid and boric acid,and its flame retardant effect in PE was investigated.Compared to the intermediate product(melamine phenyl hypophosphite(MPHP)),the residual char increased from 17.9% of MPHP to 41.2% of MPHPB at 800℃.The limiting oxygen index(LOI)of PE/20%MPHPB is 23.6%,which reaches V-0 rating.After the addition of 20%MPHPB,the total heat release(THR),peak heat release rate(pK-HRR),and average effective thermal combustion rates(av-EHC)of PE decreased.Additionally,characterizations including the pyrolysis gas chromatography-mass spectrometry(Py-GC-MS),scanning electron microscopy(SEM),raman spectroscopy test(LRS)and fourier transform infrared(FT-IR)were taken to investigate the flame retardant mechanism,and the results show that MPHPB plays roles in both gas and condensed phases.
基金financially supported by the Science and Technology Innovation Program of Hunan Province(2024RC3003)the Central South University Innovation-Driven Research Programme(2023CXQD012)the Initiative for Sustainable Energy for its financial support。
文摘By combining the merits of radiative cooling(RC)and evaporation cooling(EC),radiative coupled evaporative cooling(REC)has attracted considerable attention for sub-ambient cooling purposes.However,for outdoor devices,the interior heating power would increase the working temperature and fire risk,which would suppress their above-ambient heat dissipation capabilities and passive water cycle properties.In this work,we introduced a REC design based on an all-in-one photonic hydrogel for above-ambient heat dissipation and flame retardancy.Unlike conventional design RC film for heat dissipation with limited cooling power and fire risk,REC hydrogel can greatly improve the heat dissipation performance in the daytime with a high workload,indicating a 12.0℃lower temperature than the RC film under the same conditions in the outdoor experiment.In the nighttime with a low workload,RC-assisted adsorption can improve atmospheric water harvesting to ensure EC in the daytime.In addition,our REC hydrogel significantly enhanced flame retardancy by absorbing heat without a corresponding temperature rise,thus mitigating fire risks.Thus,our design shows a promising solution for the thermal management of outdoor devices,delivering outstanding performance in both heat dissipation and flame retardancy.
文摘Although poly(urethane-urea)elastomers(PUEs)possess excellent mechanical properties and durability,their inherent flammability and inability to self-repair after damage significantly limits their applications in high-end fields.To address this challenge,this study employs a supramolecular chemistry approach by simultaneously incorporating multiple hydrogen bonds as dynamic cross-linking points and a phosphorus-nitrogen synergistic flame-retardant structure into the poly(urethane-urea)network.The multiple hydrogen bonds endow the material with efficient intrinsic self-healing capability,while the phosphorus-nitrogen flame retardant ensures outstanding thermal stability and flame resistance,leading to the successful synthesis of a high-performance multifunctional poly(urethane-urea)elastomer.Experimental results demonstrated that when the content of the flame retardant diethyl(2-((2-aminoethyl)amino)ethyl)phosphoramidate(DEPTA)was 10 wt%,the resulting PUE/10%DEPTA achieved a V-0 rating in the vertical burning test,with a limiting oxygen index(LOI)of 30%.Concurrently,the elastomer maintained good toughness,exhibiting a tensile strength of 27.3 MPa,an elongation at break of 601%,and a self-healing efficiency of up to 94.46%.This breakthrough shows significant promise for advanced engineering applications that demand fire safety,structural durability,and extended service life through self-repair.
基金financially supported by the National Key Research and Development Program of China(No.2021YFB3700300)the National Natural Science Foundation of China(Nos.52573017 and U21B2093)+1 种基金Key Research and Development Program of Ningbo(No.2022Z200)the Zhejiang Provincial Natural Science Foundation(No.LY23E030005)。
文摘Bio-based 2,5-furandicarboxylic acid polyesters offer significant promise for reducing energy and environmental crises.However,their intrinsic flammability remains a critical limitation,and conventional flame-retardant strategies often compromise their mechanical properties,hindering their practical applications.Herein,a 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide(DOPO)-based comonomer(DDP)was used to synthesize flame-retardant poly(ethylene furandicarboxylate-co-phosphaphenanthrene)(PEFDn).The covalent integration of DDP confers intrinsic flame retardancy,avoiding the plasticization and migration issues associated with additive-type systems.Upon thermal decomposition,the DOPO-derived moieties release phosphoric acid and radical scavengers,promoting char formation and suppressing flame propagation.Furthermore,density functional theory(DFT)calculations combined with non-covalent interaction(NCI)analysis revealed that DOPO dimer molecules adopt a stable parallel-displaced π-π stacking configu ration,potentially facilitating microphase separation and enhancing the energy dissipation capability.PEFD_(10)achieves a UL-94 V-0 rating while simultaneously increasing impact toughness from 1.5 kJ/m^(2) to 14.7 kJ/m^(2).Im portantly,PEFDn maintained acceptable oxygen-barrier properties.PEFD10 also exhibited high transparency and UV-shielding performance.The combination of intrinsic flame safety,im pact-toughness resistance,UV shielding,and an oxygen barrier ensures reliable protection of electrical components and long-term operational stability.The integration of multiple critical properties within a single bio-based material represents a novel approach fo r enabling sustainable polymer solutions for high-pe rformance electrical applications.
基金supported by the National Natural Science Foundation of China(22279028,21975063,22421001)the Natural Science Foundation of Hebei Province(B2021205019)the 333 Project of Hebei Province(C20231106)。
文摘Driven by the increasing demand for high-energy-density batteries in electric vehicles and portable electronics,lithium metal batteries have made significant breakthroughs[1–3].While critical challenges associated with lithium metal anodes in liquid electrolytes(e.g.,dendrite growth,interface instability)have hindered commercialization[4–6],solid electrolyte systems have shown promise in mitigating these issues.Among these,solid polymer electrolytes(SPEs)have emerged as a viable solution for enabling stable quasisolid-state lithium metal batteries[7–9].
基金Project(50975095)supported by the National Natural Science Foundation of ChinaProject(2012ZM0048)supported by the Fundamental Research Funds for the Central Universities,China
文摘In order to investigate a gradient nano/micro-structured surface layer on pure copper produced by severe plasticity roller burnishing （SPRB） and grain refinement mechanism, the microstructure characteristics and material properties of sample at various depths from the topmost surface were investigated by SEM, TEM, XRD, OM etc. The experimental results show that the gradient nano/micro-structure was introduced into the surface layer of over 100μm in thickness. The remarkable increase in hardness near the topmost surface was mainly attributed to the reduced grain size. The equiaxed nano-sized grains were in random orientation and the most of their boundaries were low-angle grain boundaries （LAGBs）. The coarse grains are refined into the few micro-sized grains by dislocation activities;deformation twinning was found to be the primary form for the formation of submicron grains;the formation of nanostructure was dominated by dislocation activities accompanied with rotation of grains in local region.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11675198,11875097,11975257,61774072,61574026,and 61971090)the National Key Research and Development Program of China(Grant Nos.2016YFB0400600 and2016YFB0400601)+2 种基金the Fundamental Research Funds for the Central Universities,China(Grant No.DUT19LK45)the China Postdoctoral Science Foundation(Grant No.2016M591434)the Science and Technology Plan of Dalian City,China(Grant No.2018J12GX060).
文摘Nowadays,the superior detection performance of semiconductor neutron detectors is a challenging task.In this paper,we deal with a novel GaN micro-structured neutron detector(GaN-MSND)and compare three different methods such as the method of modulating the trench depth,the method of introducing dielectric layer and p-type inversion region to improve the width of depletion region(W).It is observed that the intensity of electric field can be modulated by scaling the trench depth.On the other hand,the electron blocking region is formed in the detector enveloped with a dielectric layer.Furthermore,the introducing of p-type inversion region produces new p/n junction,which not only promotes the further expansion of the depletion region but also reduces the intensity of electric field produced by main junction.It can be realized that all these methods can considerably enhance the working voltage as well as W.Of them,the improvement on W of GaN-MSND with the p-type inversion region is the most significant and the value of W could reach 12.8μm when the carrier concentration of p-type inversion region is 10^17 cm^-3.Consequently,the value of W is observed to improve 200%for the designed GaN-MSND as compared with that without additional design.This work ensures to the researchers and scientific community the fabrication of GaN-MSND having superior detection limit in the field of intense radiation.
文摘In this paper,we report the study of the process of fabricating a multi-layermetal micro-structure using UV-LIGA overlay technology,includingmask fabrication,substrate treatment,and UV-LIGA overlay processes.To solve the process problems in the masking procedure,the swelling problemof the first layer of SU-8 thick photoresist was studied experimentally.The 5μmline-width compensation and closed 20μmand 30μmisolation strips were designed and fabricated around the micro-structure pattern.The pore problemin the Ni micro-electroforming layer was analyzed and the electroforming parameters were improved.The pH value of the electroforming solution should be controlled between 3.8 and 4.4 and the current density should be below 3 A/dm^2.To solve the problems of high inner stress and incomplete development of the micro-cylinder hole array with a diameter of 30μm,the lithography process was optimized.The pre-baking temperature was increased via gradient heating and rose every 5℃ from 65℃ to 85℃ and then remained at 85℃ for 50 min–1 h.In addition,the full contact exposure was used.Finally,a multi-layer metal micro-structure with high precision and good quality of microelectroforming layer was fabricated using UV-LIGA overlay technology.
文摘A low-power CO_2 laser is used to deposit Fe powder and mixture of Fe andcarbon powder on substrates respectively, and the macro and micro-structure of the formed samplesare investigated. It is demonstrated that most grains of these samples are equi-axed. This isderived from the high nucleation velocity in the shallow melt pool besides rapid solidification ofthe liquid-state alloy or metal. Bainitic structure, combination of pearlite and ferrite structureand ferrite structure are seen respectively in the samples involving various amounts of carbon owingto no martensitic transformation in these small samples.
基金Supported by the Programme of Introducing Talents of Discipline to Universities (B07018)
文摘To obtain the form error of micro-structured surfaces robustly and accurately, a form er- ror evaluation method was developed based on the real coded genetic algorithm （RCGA）. The meth- od employed the average squared distance as the matching criterion. The point to surface distance was achieved by use of iterative method and the modeling of RCGA for the surface matching was also presented in detail. Parameter selection for RCGA including the crossover rate and population size was discussed. Evaluation results of series simulated surfaces without form error show that this method can achieve the accuracy of root mean square deviation （ Sq ） less than 1 nm and surface pro- file error （ St ） less than 4 nm. Evaluation of the surfaces with different simulated errors illustrates that the proposed method can also robustly obtain the form error with nano-meter precision. The e- valuation of actual measured surfaces further indicates that the proposed method is capable of pre- cisely evaluating micro-structured surfaces.
基金This work was financially supported by the National Natural Science Foundation of China(No.21706292)Hunan Provincial Science and Technology Plan Project,China(No.2016TP1007)+1 种基金Hunan Provincial Natural Science Foundation of China(No.2020JJ4107)Kai Han acknowledges the support from Innovation-Driven Project of Central South University(No.2020CX037).
文摘Ni-rich layered material is a kind of high-capacity cathode to meet the requirement of electric vehicles.As for the typical LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) material,the particle formation is significant for electrochemical properties of the cathode.In this work,the structure,morphology,and electrochemical performance of LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) secondary particles and single crystals were systematically studied.A lower Ni^(2+)/Ni^(3+)molar ratio of 0.66 and a lower residual alkali content of 0.228wt%were achieved on the surface of the single crystals.In addition,the single crystals showed a discharge capacity of 191.6 mAh/g at 0.2 C(~12 mAh/g lower than that of the secondary particles)and enhanced the electrochemical stability,especially when cycled at 50℃ and in a wider electrochemical window(between 3.0 and 4.4 V vs.Li+/Li).The LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2) secondary particles were suitable for applications requiring high specific capacity,whereas single crystals exhibited better stability,indicating that they are more suitable for use in long life requested devices.
基金The authors acknowledge support from the German Research Foundation(DFG:LE 2249/5-1)the Sino-German Center for Research Promotion(GZ1579)+1 种基金Yunnan Fundamental Research Projects(202201AW070014)Jiajia Qiu and Yu Duan appreciate support from the China Scholarship Council(No.201908530218&202206990027).
文摘Adopting a nano-and micro-structuring approach to fully unleashing the genuine potential of electrode active material benefits in-depth understandings and research progress toward higher energy density electrochemical energy stor-age devices at all technology readiness levels.Due to various challenging issues,especially limited stability,nano-and micro-structured(NMS)electrodes undergo fast electrochemical performance degradation.The emerging NMS scaffold design is a pivotal aspect of many electrodes as it endows them with both robustness and electrochemical performance enhancement,even though it only occupies comple-mentary and facilitating components for the main mechanism.However,extensive efforts are urgently needed toward optimizing the stereoscopic geometrical design of NMS scaffolds to minimize the volume ratio and maximize their functionality to fulfill the ever-increasing dependency and desire for energy power source supplies.This review will aim at highlighting these NMS scaffold design strategies,summariz-ing their corresponding strengths and challenges,and thereby outlining the potential solutions to resolve these challenges,design principles,and key perspectives for future research in this field.Therefore,this review will be one of the earliest reviews from this viewpoint.
基金supported by the National Natural Science Foundation of China (Nos. 40372094 and 49972067)
文摘The sub-vertical meso-and micro-structures and fabrics developed in coesite-bearing foliated eclogites in the Taohang （桃行） area, southeastern Shandong （山东）, China. The diagnostic structures and fabrics, including penetrative foliation or mylonitic foliation containing mineral and stretching lineations, as well as sheath-like folds, appear to be the development of anastomosing UHP eciogite-facies shear belt arrays hosting massive eelogites. Textural relationships and mineral assem-blages indicate that the deformation of foliated eclogites developed closely after the formation of the massive eclogite, prior to the development of the granulite/amphibolite-facies symplectites and coronas, occurring over a very wide pressure range of （31-8）×10^2 MPa. It presents the structural records of the tectonometamorphic processes as being responsible for the earliest stages of exhumation of the UHP metamorphic rocks. Extensive regional field observations show that the meso-and micro-structures and fabrics recognized in the foliated eclogites at Taohang are remarkably similar or consistent in the whole Dabie （大别）-Sulu （苏鲁） UHP metamorphic belt. This article, thus, supports the idea that the earliest stages of exhumation of the UHP metamorphic rocks, from mantle depths to the Moho or the mantle-crust boundary layering, may be attributed mainly to a sub-vertical extrusion and ductile flow along the subduction channel, belonging to a syn-collision exhumation at about 235 to 220 Ma.
基金Supported by the National Natural Science Foundation of China(Nos.20671011,20331010,90406002and90406024)the 111 Project(No.B07012)the Key Laboratory of Structural Chemistry Foundation(No.060017).
文摘A novel flower-like hydrated magnesium carbonate hydroxide, Mg5 （CO3 ）4 （OH）2·4H2O, with micro-structure composed of individual thin nano-sheets was synthesized using a facile solution route without the use of template or organic surfactant. Reaction time has an important effect on the final morphology of the product. The micro-structure and morphology of Mg5 （CO3）4 （OH）2·4H2O were characterized by means of X-ray diffractometry （XRD）, fieldemission scanning electron microscopy（FE-SEM）. Brunauer-Emmett-Teller（BET） surface areas of the samples were also measured. The probable formation mechanism of flower-like micro-structure was discussed. It was found that Mg5 （CO3）4（ OH）2·4H2O with flower-like micro-structure was a novel and efficient catalyst for the synthesis of diphenyl carbonate （DPC） by transesterification of dimethyl carbonate （DMC） with phenol.
基金the Special Funds for Major State Basic Research Projects （No.G2000067102） National Natural Science Foundation of China （No.60474027）.
文摘In this article, the convection dominated convection-diffusion problems with the periodic micro-structure are discussed. A two-scale finite element scheme based on the homogenization technique for this kind of problems is provided. The error estimates between the exact solution and the approximation solution, of the homogenized equation or the two-scale finite element scheme are analyzed. It is shown that the scheme provided in this article is convergent for any fixed diffusion coefficient 5, and it may be convergent independent of δ under some conditions. The numerical results demonstrating the theoretical results are presented in this article.
基金the National Natural Science Foundation of China(No.51775154)the ZheJiang Provincial Natural Science Foundation of China(No.LZ15E050004)
文摘A three-dimensional dynamic model for nano/micro-fabrications of silicon was presented. With the developed model, the fabrication process of silicon on nothing（SON） structure was quantitatively investigated. We employ a diffuse interface model that incorporates the mechanism of surface diffusion. The mechanism of the fabrication is systematically integrated for high reliability of computational analysis. A semi-implicit Fourier spectral scheme is applied for high efficiency and numerical stability. Moreover, the theoretical analysis provides the guidance that is ordered by the fundamental geometrical design parameters to guide different fabrications of SON structures. The performed simulations suggest a substantial potential of the presented model for a reliable design technology of nano/micro-fabrications.
文摘A new standard parametric modeling method of the micro-structure of plain woven composite is proposed. It is based on good analysis of the mechanical property of the yarn, weaving law of plain woven, and other factors. The method implements a woven fabric composite visual engineering modeling process standardization, and it gives five steps to calculate the key micro-structural parameters of the yarn including the cross-section and the trajectory of the central Line. On the basis, the digital model of a plain woven composite has been constructed. The experimental result shows that the forecast for the mechanical property of the model using finite-element simulation analysis is consistent with the actual value. The shape and the structure of the model are also consistent with the solid.
