In this study,a novel polysaccharide GPA-G 2-H was derived from ginseng.Furthermore,the coherent study of its structural characteristics,fermented characteristics in vitro,as well as antioxidant mechanism of fermented...In this study,a novel polysaccharide GPA-G 2-H was derived from ginseng.Furthermore,the coherent study of its structural characteristics,fermented characteristics in vitro,as well as antioxidant mechanism of fermented product FGPA-G 2-H on Aβ25-35-induced PC 12 cells were explored.The structure of GPA-G 2-H was determined by means of zeta potential analysis,FTIR,HPLC,XRD,GC-MS and NMR.The backbone of GPA-G 2-H was mainly composed of→4)-α-D-Glcp-(1→with branches substituted at O-3.Notably,GPA-G 2-H was degraded by intestinal microbiota in vitro with total sugar content and pH value decreasing,and short-chain fatty acids(SCFAs)increasing.Moreover,GPA-G 2-H significantly promoted the proliferation of Lactobacillus,Muribaculaceae and Weissella,thereby making positive alterations in intestinal microbiota composition.Additionally,FGPA-G 2-H activated the Nrf 2/HO-1 signaling pathway,enhanced HO-1,NQO 1,SOD and GSH-Px,while inhabited Keap 1,MDA and LDH,which alleviated Aβ-induced oxidative stress in PC 12 cells.These provide a solid theoretical basis for the further development of ginseng polysaccharides as functional food and antioxidant drugs.展开更多
Based on experiments and first-principles calculations,the microstructures and mechanical properties of as-cast and solution treated Mg-10Gd-4Y-xZn-0.6Zr(x=0,1,2,wt.%)alloys are investigated.The transformation process...Based on experiments and first-principles calculations,the microstructures and mechanical properties of as-cast and solution treated Mg-10Gd-4Y-xZn-0.6Zr(x=0,1,2,wt.%)alloys are investigated.The transformation process of long-period stacking ordered(LPSO)structure during solidification and heat treatment and its effect on the mechanical properties of experimental alloys are discussed.Results reveal that the stacking faults and 18R LPSO phases appear in the as-cast Mg-10Gd-4Y-1Zn-0.6Zr and Mg-10Gd-4Y-2Zn-0.6Zr alloys,respectively.After solution treatment,the stacking faults and 18R LPSO phase transform into 14H LPSO phase.The Enthalpies of formation and reaction energy of 14H and 18R LPSO are calculated based on first-principles.Results show that the alloying ability of 18R is stronger than that of 14H.The reaction energies show that the 14H LPSO phase is more stable than the 18R LPSO.The elastic properties of the 14H and 18R LPSO phases are also evaluated by first-principles calculations,and the results are in good agreement with the experimental results.The precipitation of LPSO phase improves the tensile strength,yield strength and elongation of the alloy.After solution treatment,the Mg-10Gd-4Y-2Zn-0.6Zr alloy has the best mechanical properties,and its ultimate tensile strength and yield strength are 278.7 MPa and 196.4 MPa,respectively.The elongation of Mg-10Gd-4Y-2Zn-0.6Zr reaches 15.1,which is higher than that of Mg-10Gd-4Y0.6Zr alloy.The improving mechanism of elastic modulus by the LPSO phases and the influence on the alloy mechanical properties are also analyzed.展开更多
Objective This study reports the first imported case of Lassa fever(LF)in China.Laboratory detection and molecular epidemiological analysis of the Lassa virus(LASV)from this case offer valuable insights for the preven...Objective This study reports the first imported case of Lassa fever(LF)in China.Laboratory detection and molecular epidemiological analysis of the Lassa virus(LASV)from this case offer valuable insights for the prevention and control of LF.Methods Samples of cerebrospinal fluid(CSF),blood,urine,saliva,and environmental materials were collected from the patient and their close contacts for LASV nucleotide detection.Whole-genome sequencing was performed on positive samples to analyze the genetic characteristics of the virus.Results LASV was detected in the patient’s CSF,blood,and urine,while all samples from close contacts and the environment tested negative.The virus belongs to the lineage IV strain and shares the highest homology with strains from Sierra Leone.The variability in the glycoprotein complex(GPC)among different strains ranged from 3.9%to 15.1%,higher than previously reported for the seven known lineages.Amino acid mutation analysis revealed multiple mutations within the GPC immunogenic epitopes,increasing strain diversity and potentially impacting immune response.Conclusion The case was confirmed through nucleotide detection,with no evidence of secondary transmission or viral spread.The LASV strain identified belongs to lineage IV,with broader GPC variability than previously reported.Mutations in the immune-related sites of GPC may affect immune responses,necessitating heightened vigilance regarding the virus.展开更多
The mechanical and thermodynamic properties of W-Ti alloys(including W_(15)Ti_(1),W_(14)Ti_(2),W_(12)Ti_(4) and W_(8)Ti_(8) alloys)were investigated by the first-principles approach based on density functional theory....The mechanical and thermodynamic properties of W-Ti alloys(including W_(15)Ti_(1),W_(14)Ti_(2),W_(12)Ti_(4) and W_(8)Ti_(8) alloys)were investigated by the first-principles approach based on density functional theory.The results indicate that W-Ti alloys except W_(8)Ti_(8) are thermodynamically stable.The modulus and hardness of W-Ti alloys are smaller than those of pure tungsten and gradually decrease with increasing Ti concentration.However,their B/G ratios and Poisson's ratios exceed those of pure tungsten,suggesting that the introduction of Ti decreases the mechanical strength while enhancing the ductility of W-Ti alloys.The thermal expansion coefficients for W-Ti alloys all surpass those of pure tungsten,indicating that the introduction of titanium exacerbates the thermal expansion behavior of W-Ti alloys.Nevertheless,elevated pressure has the capacity to suppress the thermal expansion tendencies in titanium-doped tungsten alloys.This study offers theoretical insights for the design of nuclear materials by exploring the mechanical and thermodynamic properties of W-Ti alloys.展开更多
With the ongoing depletion of fossil fuels,energy and environmental issues have become increasingly critical,necessitating the search for effective solutions.Catalysis,being one of the hallmarks of modern industry,off...With the ongoing depletion of fossil fuels,energy and environmental issues have become increasingly critical,necessitating the search for effective solutions.Catalysis,being one of the hallmarks of modern industry,offers a promising avenue for researchers.However,the question of how to significantly enhance the performance of catalysts has gradually drawn the attention of scholars.Defect engineering,a commonly employed and effective approach to improve catalyst activity,has become a significant research focus in the catalysis field in recent years.Nonmetal vacancies have received extensive attention due to their simple form.Consequently,exploration of metal vacancies has remained stagnant for a considerable period,resulting in a scarcity of comprehensive reviews on this topic.Therefore,based on the latest research findings,this paper summarizes and consolidates the construction strategies for metal vacancies,characterization techniques,and their roles in typical energy and environmental catalytic reactions.Additionally,it outlines potential challenges in the future,aiming to provide valuable references for researchers interested in investigating metal vacancies.展开更多
2-substituted-1-amino-o-carboranes 2-R-1-NH_(2)-o-C_(2)B_(10)H_(10)(R=CH_(3),1a;R=Ph,1b)were synthesized and the reactions of these compounds with the yttrium dialkyl complex[Y(L)(CH_(2)SiMe3)_(2)](L=[2-(2,5-Me_(2)C_(...2-substituted-1-amino-o-carboranes 2-R-1-NH_(2)-o-C_(2)B_(10)H_(10)(R=CH_(3),1a;R=Ph,1b)were synthesized and the reactions of these compounds with the yttrium dialkyl complex[Y(L)(CH_(2)SiMe3)_(2)](L=[2-(2,5-Me_(2)C_(4)H_(2)N)C_(6)H4NC(Ph)=NDipp]-,Dipp=2,6-iPr_(2)C_(6)H_(3))were investigated.The 1H NMR spectroscopy indicate that the reaction of ytrrium dialkyl complex with one equivalent of 2-R-1-NH_(2)-o-C_(2)B_(10)H_(10) produce the mixture of ytrrium alkyl-amido complex[Y(L)(2-R-1-NH-o-C_(2)B_(10)H_(10))(CH_(2)SiMe3)](R=CH_(3),2a;R=Ph,2b)and bis(amido)complex[Y(L)(2-R-1-NH-o-C_(2)B_(10)H_(10))_(2)](R=CH_(3),3a;R=Ph,3b).The yttrium bridging imido complex[Y(L)(2-CH_(3)-1-N-o-C_(2)B_(10)H_(10))]_(2)(4a)was obtained by heating the mixture at 55℃for 12 h.Complex 3a was isolated and characterized by treating the yttrium dialkyl complex with two equivalents of 1a.The structures of complexes 3a and 4a were verified by single-crystal Xray diffraction.CCDC:2424136,3a;2424137,4a.展开更多
Clays are a constituent of the earth. As a result, the discovery and traditional use of clays in construction and pottery worldwide dates back to antiquity. Guinea has several deposits of clay minerals whose chemical ...Clays are a constituent of the earth. As a result, the discovery and traditional use of clays in construction and pottery worldwide dates back to antiquity. Guinea has several deposits of clay minerals whose chemical and mineralogical compositions have been little studied. Despite lacking of scientific data on these clay minerals, they are used today in pottery and habitat construction. As a step towards promoting the use of clay materials in Guinea, we conducted a study of the physicochemical and mineralogical properties of three natural clays from Kakan in the Republic of Guinea (AKKB, AKKE, AKKO) used in habitat construction. The aims of this work were to better understand their properties, but above all to be able to act on them to improve and broaden their applications, which until now have been limited to construction. These clays were studied by X-ray diffraction (XRD), X-ray fluorescence spectrometry (XRF), moisture content (%W), laser granulometry, Atterberg limits, specific surface area, infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), thermogravimetric analysis and differential thermal analysis (TGA/DTA). These analyses revealed that the main clay minerals present in our samples are kaolinite, illite and, montmorillonite, with the addition of impurities, the most abundant of which is quartz.展开更多
The xylitol dehydrogenase(XDH)is a crucial enzyme involved in the xylose utilization in pentose⁃catabolizing yeasts and fungi.In addition to producing xylulose,XDH can also be employed to develop a biosensor for monit...The xylitol dehydrogenase(XDH)is a crucial enzyme involved in the xylose utilization in pentose⁃catabolizing yeasts and fungi.In addition to producing xylulose,XDH can also be employed to develop a biosensor for monitoring xylitol concentration.In this study,the gene encoding the thermophilic fungus Talaromyces emersonii XDH(TeXDH)was heterologously expressed in Escherichia coli BL21(DE3)at 16℃in the soluble form.Recombinant TeXDH with high purity was purified by using a Ni⁃NTA affinity column.Size⁃exclusion chromatography and SDS⁃PAGE analysis demonstrated that the puri⁃fied recombinant TeXDH exists as a native trimer with a molecular mass of approximately 116 kD,and is composed of three identical subunits,each with a molecular weight of around 39 kD.The TeXDH strictly preferred NAD^(+)as a coenzyme to NADP^(+).The optimal temperature and pH of the TeXDH were 40℃and 10.0,respectively.After EDTA treatment,the enzyme activity of TeXDH decreased to 43.26%of the initial enzyme activity,while the divalent metal ions Mg^(2+)or Ca^(2+)could recover the enzyme activity of TeXDH,reaching 103.32%and 110.69%of the initial enzyme activity,respectively,making them the optimal divalent metal ion cofactors for TeXDH enzyme.However,the divalent metal ions of Mn^(2+),Ni^(2+),Cu^(2+),Zn^(2+),Co^(2+),and Cd^(2+)significantly inhibited the activity of TeXDH.ICP⁃MS and molecular doc⁃king studies revealed that 1 mol/L of TeXDH bound 2 mol/L Zn^(2+)ions and 1 mol/L Mg^(2+)ion.Further⁃more,TeXDH exhibited a high specificity for xylitol,laying the foundation for the development of future xylitol biosensors.展开更多
A trinuclear copper complex [Cu_(3)(L2)_(2)(SO_(4))_(2)(H_(2)O)_(7)]·8H_(2)O(1)(HL2=1-hydroxy-3-(pyrazin-2-yl)-N-(pyrazin-2-ylmethyl)imidazo[1,5-a]pyrazine-8-carboxamide) with a multi-substituted imidazo[1,5-a]py...A trinuclear copper complex [Cu_(3)(L2)_(2)(SO_(4))_(2)(H_(2)O)_(7)]·8H_(2)O(1)(HL2=1-hydroxy-3-(pyrazin-2-yl)-N-(pyrazin-2-ylmethyl)imidazo[1,5-a]pyrazine-8-carboxamide) with a multi-substituted imidazo[1,5-a]pyrazine scaffold was serendipitously prepared from the reaction of the pro-ligand of H_(2)L1(N,N'-bis(pyrazin-2-ylmethyl)pyrazine-2,3-dicarboxamide) with CuSO_(4)·5H_(2O) in aqueous solution at room temperature.Complex 1 was characterized by IR,single-crystal X-ray analysis,and magnetic susceptibility measurements.Single-crystal X-ray analysis reveals that the complex consists of three Cu(Ⅱ) ions,two in situ transformed L2~-ligands,two coordinated sulfates,seven coordinated water molecules,and eight uncoordinated water molecules.Magnetic susceptibility measurement indicates that there are obvious ferromagnetic coupling interactions between the adjacent Cu(Ⅱ) ions in 1.CCDC:1852713.展开更多
Introduction: Diabetes remains a real public health problem today, due to its associated morbidity and mortality. It induces numerous metabolic, biochemical, hematological, and immunological changes, responsible for m...Introduction: Diabetes remains a real public health problem today, due to its associated morbidity and mortality. It induces numerous metabolic, biochemical, hematological, and immunological changes, responsible for multiple complications. The objective of this study was to characterize clinically and biologically type 2 diabetic patients followed at the National Center for Diabetology and Arterial Hypertension of the Central Hospital of Yaoundé. Method: This prospective, cross-sectional, and analytical study took place from April 5 to July 31, 2023 (4 months) on 100 diabetic patients of both sexes (61 women and 39 men), aged from 31 to 88 years. Body Mass Index, systolic and diastolic blood pressure, and cardiac frequency were measured on each of the patients. Subsequently, blood was collected from the patients for the determination of the complete blood count, HBA1c, lipid profile, serum albumin, TNF-α, and IL-6 levels. The data were analyzed using SPSS 17.0 software. Results: The age average of our population was 56.99 ± 11.51 years, the population was primarily female (61%) and primarily between the ages of 55 and 88. 67% of respondents were married. 59% went to secondary school. 73% of them lived in urban areas. 30% were obese and 40% were overweight, with an average BMI of 28.75 kg/m2. 76% of patients took oral antidiabetic medications. HbA1c level average was 8.65%, with 60% having readings above 6.5%. Low hemoglobin and hypochromia were among the abnormalities of red blood cells observed. Lipid profiles revealed low HDL-cholesterol and high triglycerides and cholesterol. Elevated levels of TNF-α and IL-6 indicated inflammation and cardiovascular risk. Conclusion: These results indicate the necessity of focused diabetic care and management on diabetic patients attending the central hospital of Yaoundé, Cameroon.展开更多
Cashew processing in Côte d’Ivoire focuses only on the cashew nut, to the detriment of the apple. Only a very small proportion of the apple is processed into juice. The aim of this work is to enhance the value o...Cashew processing in Côte d’Ivoire focuses only on the cashew nut, to the detriment of the apple. Only a very small proportion of the apple is processed into juice. The aim of this work is to enhance the value of cashew apples by transforming them into jam. Specifically, the aim was first to characterize the sensory properties of cashew apple jam formulations using baobab powder as a source of pectin and then to optimise the formulations. A Box-Behken design with pH, Sugar, and Baobab as factors was used to model and characterize the jam sensory descriptors, and a multivariate analysis with SensomineR was used to characterize the jam formulations. The desirability function was used to optimise the formulations. The results show globally significant regressions at the 0.05 threshold for the sensory descriptors Gelling, Brilliance, Smell, Sweetness, and (-)Astringency, with the exception of (-)Salinity. The R2 coefficients are greater than 80%. The factors studied could have effects on the sensory descriptors of cashew jam formulations. The Baobab had the main effect on the gelling, smell, and astringency of the jams. Brilliance depended on the added sugar. A product effect (p < 0.001) was observed for the descriptors Smell, Gelling, Brilliance, and Sweetness, as these allowed the panelists to find differences between the formulations. Optimum jam formulation can be achieved with 51.56% sugar and 2.12% Baobab at a pH of 3.15. Cashew apple jam using Baobab offers opportunities to add value to apples that have long been abandoned in the field. It would be important to find conditions for prolonged storage of this jam.展开更多
The advancement of electron microscopy technology has driven the development of electron microscopes that can apply mechanical loading while observing samples,providing a valuable tool for In-Situ mechanical character...The advancement of electron microscopy technology has driven the development of electron microscopes that can apply mechanical loading while observing samples,providing a valuable tool for In-Situ mechanical characterization of materials.In response to the need to characterize the evolution of the mechanical behavior of structural materials,such as aerospace materials,in real cryogenic service environments,and to provide an experimental basis for improving their macroscopic cryogenic mechanical properties,the advancement of In-Situ characterization techniques capable of offering both cryogenic environments and mechanical loading has become imperative.There have been scholars using this technique to carry out cryogenic mechanical In-Situ studies of related materials,with experimental studies dominating in general,and a few reviews of mechanical characterization techniques mentioning cryogenic temperatures.In order to make it easier to conduct research using such characterization techniques and to further promote the development of related characterization techniques,this review compiles the previous work and summarizes the electron microscope-based In-Situ characterization techniques for cryogenic micro-and nanomechanics.These techniques primarily include transmission electron microscopy-based cryogenic tensile and indentation methods,as well as scanning electron microscopy-based cryogenic tensile,indentation,compression,and bending methods.Furthermore,the review outlines the prospective future development of In-Situ characterization techniques for cryogenic micro-and nanomechanics.展开更多
The SiO_(2)'-CaO/(CaO+K_(2)O)(S'CK)diagram is an empirically derived major element-based equivalent to the modal IUGS alkali feldspar-quartz-plagioclase classification scheme for granitoids.It employs the cont...The SiO_(2)'-CaO/(CaO+K_(2)O)(S'CK)diagram is an empirically derived major element-based equivalent to the modal IUGS alkali feldspar-quartz-plagioclase classification scheme for granitoids.It employs the content of SiO_(2)and CaO/(CaO+K_(2)O)ratio to approximate the IUGS classification diagram and a normative-based Q'-ANOR plot.Four trends have been superimposed onto the SiO_(2)'-CaO/(CaO+K_(2)O)diagram based on published datasets from the Peninsular Ranges(calcic:C),Tuolumne(calc-alkalic:CA),Sherman(alkali-calcic:AC),and Bjerkreim-Sokndal(alkalic:A)batholiths,which were employed to constrain the positions of the C-CA,CA-AC and AC-A suite boundaries on the SiO_(2)versus(Na_(2)O+K_(2)O-CaO)(or modified alkali-lime index,MALI)granitic classification diagram.A merit of the SiO_(2)'-CaO/(CaO+K_(2)O)plot is identifying rock types comprising a suite and their relative abundances.The distinguished projections of five typical granitoid assemblages,which are summarized by Bonin et al.(2020),demonstrate the ability of SiO_(2)'-CaO/(CaO+K_(2)O)diagram to decipher their petrogenesis.The SiO_(2)'-CaO/(CaO+K_(2)O)plots for the plutonic suites of'known'tectonic settings can reveal their evolution paths and the lithological statistics.Accordingly,it is suggested that the SiO_(2)'-CaO/(CaO+K_(2)O)plot can distinguish the tectonic environments of plutonic suits by comparing the plutonic suites or batholiths of'unknown'tectonic context to the published datasets from granitoid suites formed within'known'tectonic settings.The modified SiO_(2)'-CaO/(CaO+K_(2)O)diagram links the bulk chemical composition of granitoid suites to the likely source,magmatic evolution,and tectonic setting;thus,it may be a useful tectono-magmatic classification scheme for granitoid suites.展开更多
This study focuses on the thermophysical characterizations of composite materials made from polypropylene reinforced with residues and fibers from Borassus wood from Chad. These properties are experimentally determine...This study focuses on the thermophysical characterizations of composite materials made from polypropylene reinforced with residues and fibers from Borassus wood from Chad. These properties are experimentally determined at different temperatures using the hot wire method of the “FP2C” machine, where the hot wire probe is inserted between two specimens. The values of the thermal conductivity in powdered Borassus wood range from 0.170 W/mK to 0.182 W/mK for female wood (FNTF) and from 0.169 W/mK to 0.173 W/mK for male wood. For the female and male fibers, the thermal conductivity values range from 0.137 W/mK to 0.157 W/mK for the female and from 0.138 W/mK to 0.168 W/mK for the male. The thermal effusivity of the residues and fibers of Borassus wood varies from: 509.6 Ws1/2/m2K to 543 Ws1/2/m2K for the powder of female wood and from 524.6 Ws1/2/m2K to 547 Ws1/2/m2K for the powder of male wood. For the fibers of Borassus wood, the values range from 410.6 Ws1/2/m2K to 523.6 Ws1/2/m2K for the female wood fibers and from 420.3 Ws1/2/m2K to 480.3 Ws1/2/m2K for the male wood fibers. These results are important for the applications of Borassus wood residues and fibers in construction works regarding the thermal insulation of habitats.展开更多
Accurately determining the Flade potential(E_(Flade))is of significant importance in the design of novel corrosion-resisting alloys.However,due to the complex nature of the E_(Flade)influenced by several factors inclu...Accurately determining the Flade potential(E_(Flade))is of significant importance in the design of novel corrosion-resisting alloys.However,due to the complex nature of the E_(Flade)influenced by several factors including compositions of the alloys and corrosive solutions,there is currently a lack of truly predictive ab initio model.Here,we established the critical potential condition required for passivation in acidic solutions containing chloride ions(Cl^(-))by developing an ab initio model that incorporates the potential drop from the metal electrode to the solution,considering tunneling of electrons at metal/film interface,breakdown of the film,and electrochemical adsorption reactions at film/solution interface.These parameters were derived from the work function of the alloy substrate and passivation film,the band gap of the passivation film,and the Gibbs free energy of adsorption on the passivation film,all of which can be obtainable from first-principles calculations.This theoretical model has been successfully validated for alloyed stainless steel,exhibiting a remarkable agreement with experimental results.Importantly,enabled by the model,we have identified several alloying elements(i.e.,Ta,W,Os,and Ir)that can effec-tively lower the EFlade of the stainless steel.This work constitutes an important step forward in modeling complex passivation behaviors from first-principles,providing a useful tool for the design of corrosion-resisting alloys.展开更多
Based on first-principles calculation framework,the surface model,anodic dissolution,cathodic oxygen absorption reaction,and other related electrochemical corrosion models of Fe-Ce system were constructed,and the infl...Based on first-principles calculation framework,the surface model,anodic dissolution,cathodic oxygen absorption reaction,and other related electrochemical corrosion models of Fe-Ce system were constructed,and the influencing mechanism Ce doping on the corrosion resistance of Fe-Ce system in the Cl medium environment was analyzed.The results show that Ce doping on the first surface and subsurface inhibits the ionization of Fe atoms and greatly promotes the repassivation process of Fe matrix.Ce doping on the first layer is conducive to preventing the detachment of surface Fe atoms from Fe matrix and delaying the occurrence of corrosion.Ce atoms in the subsurface effectively increase the difficulty of Fe atoms detaching from the matrix at high Cl concentrations.When O diffusion is the controlling link of oxygen absorption reaction,Ce doping has no effects on the reaction rate of cathodic oxygen absorption.Ce doping enhances the electrochemical stability of Fe(100)1and reduces the anodic dissolution rate of Fe matrix,thereby improving its corrosion resistance.展开更多
The title of the online version of the original article was revised.The title of the original article has been revised to:Hydrochemical characterization of surface waters in Northern Tehran:Integrating cluster-based t...The title of the online version of the original article was revised.The title of the original article has been revised to:Hydrochemical characterization of surface waters in Northern Tehran:Integrating cluster-based techniques with Self-Organizing Maps.展开更多
The vacuum reactive wetting and brazing of Er_(2)Si_(2)O_(7)/MoSi_(2) coatings were investigated using a (CoFeNiCrMn)_(88)Nb_(12) high-entropy alloy (HEA) brazing filler. The microstructural evolution and wettability ...The vacuum reactive wetting and brazing of Er_(2)Si_(2)O_(7)/MoSi_(2) coatings were investigated using a (CoFeNiCrMn)_(88)Nb_(12) high-entropy alloy (HEA) brazing filler. The microstructural evolution and wettability of the HEA filler were analyzed, with particular attention to the surface energy, interfacial stability, and electronic properties of the HEA filler/rare earth silicate coating system, as determined by density functional theory (DFT). As Nb diffused into the interface and the ErNbO_(4) phase formed, the wetting angle gradually decreased to 23.12° The effective wetting and spreading of the HEA brazing filler on the rare earth silicate coating surface are strongly correlated with the formation of the ErNbO_(4) phase at the interface. Furthermore, DFT calculations reveal that the interfacial bonding energy between the BCC' and FCC' phases and the ErNbO_(4) phase, after the wetting reaction, is significantly higher than the bonding energy between the initial filler and Er_(2)Si_(2)O_(7). This finding suggests that the formation of the ErNbO_(4) phase improves the wetting and spreading behavior of the filler.展开更多
This review article provides a comprehensive examination of the most recent advances in research on nanoglasses,including the methods used to create these materials,their characteristics,and their diverse range of use...This review article provides a comprehensive examination of the most recent advances in research on nanoglasses,including the methods used to create these materials,their characteristics,and their diverse range of uses.An overview of the current trends in nanoglass research connects them to the Sustainable Development Goals,highlighting the current relevance of this topic.The process of manufacturing nanoglasses is explained in depth,highlighting advanced approaches such as inert gas condensation and severe plastic deformation,among other techniques.The prime focus of this review is on analyzing the various dimensions of nanoglass materials,including their structural dynamics and electrical configurations,and how these features contribute to their exceptional thermal stability and mechanical strength.The magnetic characteristics of nanoglasses are examined,highlighting their potential for driving innovation across multiple industries.The primary emphasis is on the biological usefulness of nanoglasses,specifically examining their bioactivity and interaction with biological components,and emphasizing their growing use in nanoscale biomedical applications.With regard to the practical applications of nanoglasses,there are specific discussions of their contributions to biological evaluation,wound healing,catalysis,and environmental sustainability.There is an emphasis on the durability and resistance of nanoglasses in these contexts.The comprehensive overview of nanoglasses provided in this article highlights their significance as revolutionary materials in fields of science and technology.The potential of nanoglasses to contribute to a future that is more sustainable and health oriented is indicated.The article ends by discussing the future directions for nanoglass research and looks forward to the promising possibilities for further investigation and innovation.展开更多
基金Supported by the National Key Research and Development Program of Traditional Chinese Medicine Modernization Project,China(No.2023YFC3504000)the Science and Technology Development Project of Jilin Province,China(No.20240404043ZP)the Science and Technology Innovation Cooperation Project of Changchun Science and Technology Bureau and Chinese Academy of Sciences,China(No.23SH14)。
文摘In this study,a novel polysaccharide GPA-G 2-H was derived from ginseng.Furthermore,the coherent study of its structural characteristics,fermented characteristics in vitro,as well as antioxidant mechanism of fermented product FGPA-G 2-H on Aβ25-35-induced PC 12 cells were explored.The structure of GPA-G 2-H was determined by means of zeta potential analysis,FTIR,HPLC,XRD,GC-MS and NMR.The backbone of GPA-G 2-H was mainly composed of→4)-α-D-Glcp-(1→with branches substituted at O-3.Notably,GPA-G 2-H was degraded by intestinal microbiota in vitro with total sugar content and pH value decreasing,and short-chain fatty acids(SCFAs)increasing.Moreover,GPA-G 2-H significantly promoted the proliferation of Lactobacillus,Muribaculaceae and Weissella,thereby making positive alterations in intestinal microbiota composition.Additionally,FGPA-G 2-H activated the Nrf 2/HO-1 signaling pathway,enhanced HO-1,NQO 1,SOD and GSH-Px,while inhabited Keap 1,MDA and LDH,which alleviated Aβ-induced oxidative stress in PC 12 cells.These provide a solid theoretical basis for the further development of ginseng polysaccharides as functional food and antioxidant drugs.
基金supported by the National Key Research and Development Program of China[grant No.2018YFB2001800]National Natural Science Foundation of China[grant No.51871184]Dalian High-level Talents Innovation Support Program[grant No.2021RD06]。
文摘Based on experiments and first-principles calculations,the microstructures and mechanical properties of as-cast and solution treated Mg-10Gd-4Y-xZn-0.6Zr(x=0,1,2,wt.%)alloys are investigated.The transformation process of long-period stacking ordered(LPSO)structure during solidification and heat treatment and its effect on the mechanical properties of experimental alloys are discussed.Results reveal that the stacking faults and 18R LPSO phases appear in the as-cast Mg-10Gd-4Y-1Zn-0.6Zr and Mg-10Gd-4Y-2Zn-0.6Zr alloys,respectively.After solution treatment,the stacking faults and 18R LPSO phase transform into 14H LPSO phase.The Enthalpies of formation and reaction energy of 14H and 18R LPSO are calculated based on first-principles.Results show that the alloying ability of 18R is stronger than that of 14H.The reaction energies show that the 14H LPSO phase is more stable than the 18R LPSO.The elastic properties of the 14H and 18R LPSO phases are also evaluated by first-principles calculations,and the results are in good agreement with the experimental results.The precipitation of LPSO phase improves the tensile strength,yield strength and elongation of the alloy.After solution treatment,the Mg-10Gd-4Y-2Zn-0.6Zr alloy has the best mechanical properties,and its ultimate tensile strength and yield strength are 278.7 MPa and 196.4 MPa,respectively.The elongation of Mg-10Gd-4Y-2Zn-0.6Zr reaches 15.1,which is higher than that of Mg-10Gd-4Y0.6Zr alloy.The improving mechanism of elastic modulus by the LPSO phases and the influence on the alloy mechanical properties are also analyzed.
基金supported by Public Health Talent Training and Surport Plan(National Administration of Disease Prevention and Control)Research and application of new technology for rapid monitoring and tracing of emergent infectious diseases among entry-exit population(2024YFFK0056)Monitoring,Early warning and Response of Major Infectious Diseases(2022ZDZX0017).
文摘Objective This study reports the first imported case of Lassa fever(LF)in China.Laboratory detection and molecular epidemiological analysis of the Lassa virus(LASV)from this case offer valuable insights for the prevention and control of LF.Methods Samples of cerebrospinal fluid(CSF),blood,urine,saliva,and environmental materials were collected from the patient and their close contacts for LASV nucleotide detection.Whole-genome sequencing was performed on positive samples to analyze the genetic characteristics of the virus.Results LASV was detected in the patient’s CSF,blood,and urine,while all samples from close contacts and the environment tested negative.The virus belongs to the lineage IV strain and shares the highest homology with strains from Sierra Leone.The variability in the glycoprotein complex(GPC)among different strains ranged from 3.9%to 15.1%,higher than previously reported for the seven known lineages.Amino acid mutation analysis revealed multiple mutations within the GPC immunogenic epitopes,increasing strain diversity and potentially impacting immune response.Conclusion The case was confirmed through nucleotide detection,with no evidence of secondary transmission or viral spread.The LASV strain identified belongs to lineage IV,with broader GPC variability than previously reported.Mutations in the immune-related sites of GPC may affect immune responses,necessitating heightened vigilance regarding the virus.
基金Funded by National Key R&D Program of China(No.2021YFB3802300)the National Natural Science Foundation of China(No.52171045)the Joint Fund(No.8091B022108)。
文摘The mechanical and thermodynamic properties of W-Ti alloys(including W_(15)Ti_(1),W_(14)Ti_(2),W_(12)Ti_(4) and W_(8)Ti_(8) alloys)were investigated by the first-principles approach based on density functional theory.The results indicate that W-Ti alloys except W_(8)Ti_(8) are thermodynamically stable.The modulus and hardness of W-Ti alloys are smaller than those of pure tungsten and gradually decrease with increasing Ti concentration.However,their B/G ratios and Poisson's ratios exceed those of pure tungsten,suggesting that the introduction of Ti decreases the mechanical strength while enhancing the ductility of W-Ti alloys.The thermal expansion coefficients for W-Ti alloys all surpass those of pure tungsten,indicating that the introduction of titanium exacerbates the thermal expansion behavior of W-Ti alloys.Nevertheless,elevated pressure has the capacity to suppress the thermal expansion tendencies in titanium-doped tungsten alloys.This study offers theoretical insights for the design of nuclear materials by exploring the mechanical and thermodynamic properties of W-Ti alloys.
基金financially supported by National Key R&D Program of China(2021YFB3500702)National Natural Science Foundation of China(Nos.21677010 and 51808037)Special fund of Beijing Key Laboratory of Indoor Air Quality Evaluation and Control(No.BZ0344KF21-04).
文摘With the ongoing depletion of fossil fuels,energy and environmental issues have become increasingly critical,necessitating the search for effective solutions.Catalysis,being one of the hallmarks of modern industry,offers a promising avenue for researchers.However,the question of how to significantly enhance the performance of catalysts has gradually drawn the attention of scholars.Defect engineering,a commonly employed and effective approach to improve catalyst activity,has become a significant research focus in the catalysis field in recent years.Nonmetal vacancies have received extensive attention due to their simple form.Consequently,exploration of metal vacancies has remained stagnant for a considerable period,resulting in a scarcity of comprehensive reviews on this topic.Therefore,based on the latest research findings,this paper summarizes and consolidates the construction strategies for metal vacancies,characterization techniques,and their roles in typical energy and environmental catalytic reactions.Additionally,it outlines potential challenges in the future,aiming to provide valuable references for researchers interested in investigating metal vacancies.
文摘2-substituted-1-amino-o-carboranes 2-R-1-NH_(2)-o-C_(2)B_(10)H_(10)(R=CH_(3),1a;R=Ph,1b)were synthesized and the reactions of these compounds with the yttrium dialkyl complex[Y(L)(CH_(2)SiMe3)_(2)](L=[2-(2,5-Me_(2)C_(4)H_(2)N)C_(6)H4NC(Ph)=NDipp]-,Dipp=2,6-iPr_(2)C_(6)H_(3))were investigated.The 1H NMR spectroscopy indicate that the reaction of ytrrium dialkyl complex with one equivalent of 2-R-1-NH_(2)-o-C_(2)B_(10)H_(10) produce the mixture of ytrrium alkyl-amido complex[Y(L)(2-R-1-NH-o-C_(2)B_(10)H_(10))(CH_(2)SiMe3)](R=CH_(3),2a;R=Ph,2b)and bis(amido)complex[Y(L)(2-R-1-NH-o-C_(2)B_(10)H_(10))_(2)](R=CH_(3),3a;R=Ph,3b).The yttrium bridging imido complex[Y(L)(2-CH_(3)-1-N-o-C_(2)B_(10)H_(10))]_(2)(4a)was obtained by heating the mixture at 55℃for 12 h.Complex 3a was isolated and characterized by treating the yttrium dialkyl complex with two equivalents of 1a.The structures of complexes 3a and 4a were verified by single-crystal Xray diffraction.CCDC:2424136,3a;2424137,4a.
文摘Clays are a constituent of the earth. As a result, the discovery and traditional use of clays in construction and pottery worldwide dates back to antiquity. Guinea has several deposits of clay minerals whose chemical and mineralogical compositions have been little studied. Despite lacking of scientific data on these clay minerals, they are used today in pottery and habitat construction. As a step towards promoting the use of clay materials in Guinea, we conducted a study of the physicochemical and mineralogical properties of three natural clays from Kakan in the Republic of Guinea (AKKB, AKKE, AKKO) used in habitat construction. The aims of this work were to better understand their properties, but above all to be able to act on them to improve and broaden their applications, which until now have been limited to construction. These clays were studied by X-ray diffraction (XRD), X-ray fluorescence spectrometry (XRF), moisture content (%W), laser granulometry, Atterberg limits, specific surface area, infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), thermogravimetric analysis and differential thermal analysis (TGA/DTA). These analyses revealed that the main clay minerals present in our samples are kaolinite, illite and, montmorillonite, with the addition of impurities, the most abundant of which is quartz.
基金湖南省教育厅基金优秀青年项目(No.22B0482)湖南科技大学博士启动基金(No.E51992 and E51993)资助。
文摘The xylitol dehydrogenase(XDH)is a crucial enzyme involved in the xylose utilization in pentose⁃catabolizing yeasts and fungi.In addition to producing xylulose,XDH can also be employed to develop a biosensor for monitoring xylitol concentration.In this study,the gene encoding the thermophilic fungus Talaromyces emersonii XDH(TeXDH)was heterologously expressed in Escherichia coli BL21(DE3)at 16℃in the soluble form.Recombinant TeXDH with high purity was purified by using a Ni⁃NTA affinity column.Size⁃exclusion chromatography and SDS⁃PAGE analysis demonstrated that the puri⁃fied recombinant TeXDH exists as a native trimer with a molecular mass of approximately 116 kD,and is composed of three identical subunits,each with a molecular weight of around 39 kD.The TeXDH strictly preferred NAD^(+)as a coenzyme to NADP^(+).The optimal temperature and pH of the TeXDH were 40℃and 10.0,respectively.After EDTA treatment,the enzyme activity of TeXDH decreased to 43.26%of the initial enzyme activity,while the divalent metal ions Mg^(2+)or Ca^(2+)could recover the enzyme activity of TeXDH,reaching 103.32%and 110.69%of the initial enzyme activity,respectively,making them the optimal divalent metal ion cofactors for TeXDH enzyme.However,the divalent metal ions of Mn^(2+),Ni^(2+),Cu^(2+),Zn^(2+),Co^(2+),and Cd^(2+)significantly inhibited the activity of TeXDH.ICP⁃MS and molecular doc⁃king studies revealed that 1 mol/L of TeXDH bound 2 mol/L Zn^(2+)ions and 1 mol/L Mg^(2+)ion.Further⁃more,TeXDH exhibited a high specificity for xylitol,laying the foundation for the development of future xylitol biosensors.
文摘A trinuclear copper complex [Cu_(3)(L2)_(2)(SO_(4))_(2)(H_(2)O)_(7)]·8H_(2)O(1)(HL2=1-hydroxy-3-(pyrazin-2-yl)-N-(pyrazin-2-ylmethyl)imidazo[1,5-a]pyrazine-8-carboxamide) with a multi-substituted imidazo[1,5-a]pyrazine scaffold was serendipitously prepared from the reaction of the pro-ligand of H_(2)L1(N,N'-bis(pyrazin-2-ylmethyl)pyrazine-2,3-dicarboxamide) with CuSO_(4)·5H_(2O) in aqueous solution at room temperature.Complex 1 was characterized by IR,single-crystal X-ray analysis,and magnetic susceptibility measurements.Single-crystal X-ray analysis reveals that the complex consists of three Cu(Ⅱ) ions,two in situ transformed L2~-ligands,two coordinated sulfates,seven coordinated water molecules,and eight uncoordinated water molecules.Magnetic susceptibility measurement indicates that there are obvious ferromagnetic coupling interactions between the adjacent Cu(Ⅱ) ions in 1.CCDC:1852713.
文摘Introduction: Diabetes remains a real public health problem today, due to its associated morbidity and mortality. It induces numerous metabolic, biochemical, hematological, and immunological changes, responsible for multiple complications. The objective of this study was to characterize clinically and biologically type 2 diabetic patients followed at the National Center for Diabetology and Arterial Hypertension of the Central Hospital of Yaoundé. Method: This prospective, cross-sectional, and analytical study took place from April 5 to July 31, 2023 (4 months) on 100 diabetic patients of both sexes (61 women and 39 men), aged from 31 to 88 years. Body Mass Index, systolic and diastolic blood pressure, and cardiac frequency were measured on each of the patients. Subsequently, blood was collected from the patients for the determination of the complete blood count, HBA1c, lipid profile, serum albumin, TNF-α, and IL-6 levels. The data were analyzed using SPSS 17.0 software. Results: The age average of our population was 56.99 ± 11.51 years, the population was primarily female (61%) and primarily between the ages of 55 and 88. 67% of respondents were married. 59% went to secondary school. 73% of them lived in urban areas. 30% were obese and 40% were overweight, with an average BMI of 28.75 kg/m2. 76% of patients took oral antidiabetic medications. HbA1c level average was 8.65%, with 60% having readings above 6.5%. Low hemoglobin and hypochromia were among the abnormalities of red blood cells observed. Lipid profiles revealed low HDL-cholesterol and high triglycerides and cholesterol. Elevated levels of TNF-α and IL-6 indicated inflammation and cardiovascular risk. Conclusion: These results indicate the necessity of focused diabetic care and management on diabetic patients attending the central hospital of Yaoundé, Cameroon.
文摘Cashew processing in Côte d’Ivoire focuses only on the cashew nut, to the detriment of the apple. Only a very small proportion of the apple is processed into juice. The aim of this work is to enhance the value of cashew apples by transforming them into jam. Specifically, the aim was first to characterize the sensory properties of cashew apple jam formulations using baobab powder as a source of pectin and then to optimise the formulations. A Box-Behken design with pH, Sugar, and Baobab as factors was used to model and characterize the jam sensory descriptors, and a multivariate analysis with SensomineR was used to characterize the jam formulations. The desirability function was used to optimise the formulations. The results show globally significant regressions at the 0.05 threshold for the sensory descriptors Gelling, Brilliance, Smell, Sweetness, and (-)Astringency, with the exception of (-)Salinity. The R2 coefficients are greater than 80%. The factors studied could have effects on the sensory descriptors of cashew jam formulations. The Baobab had the main effect on the gelling, smell, and astringency of the jams. Brilliance depended on the added sugar. A product effect (p < 0.001) was observed for the descriptors Smell, Gelling, Brilliance, and Sweetness, as these allowed the panelists to find differences between the formulations. Optimum jam formulation can be achieved with 51.56% sugar and 2.12% Baobab at a pH of 3.15. Cashew apple jam using Baobab offers opportunities to add value to apples that have long been abandoned in the field. It would be important to find conditions for prolonged storage of this jam.
基金supported by the National Natural Science Foundation of China(52301177)。
文摘The advancement of electron microscopy technology has driven the development of electron microscopes that can apply mechanical loading while observing samples,providing a valuable tool for In-Situ mechanical characterization of materials.In response to the need to characterize the evolution of the mechanical behavior of structural materials,such as aerospace materials,in real cryogenic service environments,and to provide an experimental basis for improving their macroscopic cryogenic mechanical properties,the advancement of In-Situ characterization techniques capable of offering both cryogenic environments and mechanical loading has become imperative.There have been scholars using this technique to carry out cryogenic mechanical In-Situ studies of related materials,with experimental studies dominating in general,and a few reviews of mechanical characterization techniques mentioning cryogenic temperatures.In order to make it easier to conduct research using such characterization techniques and to further promote the development of related characterization techniques,this review compiles the previous work and summarizes the electron microscope-based In-Situ characterization techniques for cryogenic micro-and nanomechanics.These techniques primarily include transmission electron microscopy-based cryogenic tensile and indentation methods,as well as scanning electron microscopy-based cryogenic tensile,indentation,compression,and bending methods.Furthermore,the review outlines the prospective future development of In-Situ characterization techniques for cryogenic micro-and nanomechanics.
文摘The SiO_(2)'-CaO/(CaO+K_(2)O)(S'CK)diagram is an empirically derived major element-based equivalent to the modal IUGS alkali feldspar-quartz-plagioclase classification scheme for granitoids.It employs the content of SiO_(2)and CaO/(CaO+K_(2)O)ratio to approximate the IUGS classification diagram and a normative-based Q'-ANOR plot.Four trends have been superimposed onto the SiO_(2)'-CaO/(CaO+K_(2)O)diagram based on published datasets from the Peninsular Ranges(calcic:C),Tuolumne(calc-alkalic:CA),Sherman(alkali-calcic:AC),and Bjerkreim-Sokndal(alkalic:A)batholiths,which were employed to constrain the positions of the C-CA,CA-AC and AC-A suite boundaries on the SiO_(2)versus(Na_(2)O+K_(2)O-CaO)(or modified alkali-lime index,MALI)granitic classification diagram.A merit of the SiO_(2)'-CaO/(CaO+K_(2)O)plot is identifying rock types comprising a suite and their relative abundances.The distinguished projections of five typical granitoid assemblages,which are summarized by Bonin et al.(2020),demonstrate the ability of SiO_(2)'-CaO/(CaO+K_(2)O)diagram to decipher their petrogenesis.The SiO_(2)'-CaO/(CaO+K_(2)O)plots for the plutonic suites of'known'tectonic settings can reveal their evolution paths and the lithological statistics.Accordingly,it is suggested that the SiO_(2)'-CaO/(CaO+K_(2)O)plot can distinguish the tectonic environments of plutonic suits by comparing the plutonic suites or batholiths of'unknown'tectonic context to the published datasets from granitoid suites formed within'known'tectonic settings.The modified SiO_(2)'-CaO/(CaO+K_(2)O)diagram links the bulk chemical composition of granitoid suites to the likely source,magmatic evolution,and tectonic setting;thus,it may be a useful tectono-magmatic classification scheme for granitoid suites.
文摘This study focuses on the thermophysical characterizations of composite materials made from polypropylene reinforced with residues and fibers from Borassus wood from Chad. These properties are experimentally determined at different temperatures using the hot wire method of the “FP2C” machine, where the hot wire probe is inserted between two specimens. The values of the thermal conductivity in powdered Borassus wood range from 0.170 W/mK to 0.182 W/mK for female wood (FNTF) and from 0.169 W/mK to 0.173 W/mK for male wood. For the female and male fibers, the thermal conductivity values range from 0.137 W/mK to 0.157 W/mK for the female and from 0.138 W/mK to 0.168 W/mK for the male. The thermal effusivity of the residues and fibers of Borassus wood varies from: 509.6 Ws1/2/m2K to 543 Ws1/2/m2K for the powder of female wood and from 524.6 Ws1/2/m2K to 547 Ws1/2/m2K for the powder of male wood. For the fibers of Borassus wood, the values range from 410.6 Ws1/2/m2K to 523.6 Ws1/2/m2K for the female wood fibers and from 420.3 Ws1/2/m2K to 480.3 Ws1/2/m2K for the male wood fibers. These results are important for the applications of Borassus wood residues and fibers in construction works regarding the thermal insulation of habitats.
基金supported by the Natural Science Foundation Project of Liaoning province(Nos.2023-MS-017 and 2022-MS-005)the National Science and Technology Major Project(No.J2019-VI-0019-0134)+2 种基金the National Natural Science Foundation of China(Nos.52201028 and 52188101)the Project funded by China Postdoctoral Science Foundation(No.2021M700153)the Special Projects of the Central Government in Guidance of Local Science and Technology Development(No.2024010859-JH6/1006).
文摘Accurately determining the Flade potential(E_(Flade))is of significant importance in the design of novel corrosion-resisting alloys.However,due to the complex nature of the E_(Flade)influenced by several factors including compositions of the alloys and corrosive solutions,there is currently a lack of truly predictive ab initio model.Here,we established the critical potential condition required for passivation in acidic solutions containing chloride ions(Cl^(-))by developing an ab initio model that incorporates the potential drop from the metal electrode to the solution,considering tunneling of electrons at metal/film interface,breakdown of the film,and electrochemical adsorption reactions at film/solution interface.These parameters were derived from the work function of the alloy substrate and passivation film,the band gap of the passivation film,and the Gibbs free energy of adsorption on the passivation film,all of which can be obtainable from first-principles calculations.This theoretical model has been successfully validated for alloyed stainless steel,exhibiting a remarkable agreement with experimental results.Importantly,enabled by the model,we have identified several alloying elements(i.e.,Ta,W,Os,and Ir)that can effec-tively lower the EFlade of the stainless steel.This work constitutes an important step forward in modeling complex passivation behaviors from first-principles,providing a useful tool for the design of corrosion-resisting alloys.
基金Project supported by the National Natural Science Foundation of China(52364044,52204364)Scientific Research Special Project for First-Class Disciplines of Education Department of Inner Mongolia Autonomous Region(YLXKZX-NKD-001,YLXKZX-NKD-011)Basic Scientific Research Business Expenses of Colleges and Universities of Inner Mongolia Autonomous Region(2023QNJS011)。
文摘Based on first-principles calculation framework,the surface model,anodic dissolution,cathodic oxygen absorption reaction,and other related electrochemical corrosion models of Fe-Ce system were constructed,and the influencing mechanism Ce doping on the corrosion resistance of Fe-Ce system in the Cl medium environment was analyzed.The results show that Ce doping on the first surface and subsurface inhibits the ionization of Fe atoms and greatly promotes the repassivation process of Fe matrix.Ce doping on the first layer is conducive to preventing the detachment of surface Fe atoms from Fe matrix and delaying the occurrence of corrosion.Ce atoms in the subsurface effectively increase the difficulty of Fe atoms detaching from the matrix at high Cl concentrations.When O diffusion is the controlling link of oxygen absorption reaction,Ce doping has no effects on the reaction rate of cathodic oxygen absorption.Ce doping enhances the electrochemical stability of Fe(100)1and reduces the anodic dissolution rate of Fe matrix,thereby improving its corrosion resistance.
文摘The title of the online version of the original article was revised.The title of the original article has been revised to:Hydrochemical characterization of surface waters in Northern Tehran:Integrating cluster-based techniques with Self-Organizing Maps.
基金support from the National Natural Science Foundation of China(No.52374402)the National Key Research and Development Program(No.2022YFB3402200)+2 种基金the National Science and Technology Major Project(No.J2022-VII-0003-0045)the Project of Key areas of innovation team in Shaanxi Province(No.2024RS-CXTD-20)the Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University(No.CX2024055).
文摘The vacuum reactive wetting and brazing of Er_(2)Si_(2)O_(7)/MoSi_(2) coatings were investigated using a (CoFeNiCrMn)_(88)Nb_(12) high-entropy alloy (HEA) brazing filler. The microstructural evolution and wettability of the HEA filler were analyzed, with particular attention to the surface energy, interfacial stability, and electronic properties of the HEA filler/rare earth silicate coating system, as determined by density functional theory (DFT). As Nb diffused into the interface and the ErNbO_(4) phase formed, the wetting angle gradually decreased to 23.12° The effective wetting and spreading of the HEA brazing filler on the rare earth silicate coating surface are strongly correlated with the formation of the ErNbO_(4) phase at the interface. Furthermore, DFT calculations reveal that the interfacial bonding energy between the BCC' and FCC' phases and the ErNbO_(4) phase, after the wetting reaction, is significantly higher than the bonding energy between the initial filler and Er_(2)Si_(2)O_(7). This finding suggests that the formation of the ErNbO_(4) phase improves the wetting and spreading behavior of the filler.
基金M.A.F.acknowledges the financing support by Universidad Nacional del Sur(Grant No.PGI 24/Q112 and Grant No.PICT 2021-I-A-00288)Agencia Nacional de Promoción Científica y Tecnológica(ANPCyT)(Grant No.PIP 2021-2023 GI 11220200100317CO).
文摘This review article provides a comprehensive examination of the most recent advances in research on nanoglasses,including the methods used to create these materials,their characteristics,and their diverse range of uses.An overview of the current trends in nanoglass research connects them to the Sustainable Development Goals,highlighting the current relevance of this topic.The process of manufacturing nanoglasses is explained in depth,highlighting advanced approaches such as inert gas condensation and severe plastic deformation,among other techniques.The prime focus of this review is on analyzing the various dimensions of nanoglass materials,including their structural dynamics and electrical configurations,and how these features contribute to their exceptional thermal stability and mechanical strength.The magnetic characteristics of nanoglasses are examined,highlighting their potential for driving innovation across multiple industries.The primary emphasis is on the biological usefulness of nanoglasses,specifically examining their bioactivity and interaction with biological components,and emphasizing their growing use in nanoscale biomedical applications.With regard to the practical applications of nanoglasses,there are specific discussions of their contributions to biological evaluation,wound healing,catalysis,and environmental sustainability.There is an emphasis on the durability and resistance of nanoglasses in these contexts.The comprehensive overview of nanoglasses provided in this article highlights their significance as revolutionary materials in fields of science and technology.The potential of nanoglasses to contribute to a future that is more sustainable and health oriented is indicated.The article ends by discussing the future directions for nanoglass research and looks forward to the promising possibilities for further investigation and innovation.
